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Coal geology and assessment of resources and reserves in the Little Snake River Coal Field and Red Desert Assessment Area, Greater Green River Basin, Wyoming

The U.S. Geological Survey is studying regional-scale assessments of resources and reserves of primary coal beds in the major coal bed basins in the United States to help formulate policy for Federal, State, and local energy and land use. This report summarizes the geology and coal resources and reserves in the Little Snake River coal field and Red Desert assessment area in the Greater Green River Basin, southwestern Wyoming. These areas are contiguous and referred to as the “assessment area” in this report. The assessment area covers about 2,300 square miles of the eastern section of the 15,400-square-mile Greater Green River Basin. This area was prioritized for assessment because no comprehensive resource assessment had previously been completed in the area; abundant, previously unavailable drill hole data from cooperators and stakeholders became available; and there are active coal mines in the Greater Green River Basin area producing from some of the same formations as those found in the assessment area. Coal-bearing Eocene, Paleocene, and Upper Cretaceous formations have a composite thickness of more than 11,000 feet in the assessment area. Stratigraphic sequences that contain multiple coal beds within a formation or member are referred to as coal zones in this report. Paleogene coal beds are found within coal zones in the Eocene Wasatch Formation and the Paleocene Fort Union Formation. Cretaceous coal beds are within coal zones in the Lance, Almond, and Allen Ridge Formations. A total of 4,214 drill holes and measured sections were used to construct a geologic database for this assessment. From these data, 7 coal zones containing 55 individual coal beds were identified. Not all 55 coal beds were assessed; only those beds that were at least 3 feet thick and had at least a 2-square-mile areal extent were considered. Using a geology-based assessment methodology, the U.S. Geological Survey estimated original, available, and recoverable coal resources for 33 coal beds that met those criteria. An original resource of 73.2 billion short tons of coal was calculated for the 33 coal beds that met the criteria in the assessment area. To be considered extractable by surface mining methods, coal beds had to be equal to or greater than 3 feet thick and less than 300 feet deep. Of the 73.2 billion short tons (BST), 19.3 BST were determined to be recoverable resources, of which approximately 2.1 BST were considered as recoverable resources by surface mining methods at a stripping ratio of 10:1 or less. (defined as recoverable resources for this assessment, based on economic modeling and regional mining analogs). Recoverable resources for underground mining methods (coal 8 to 15 feet thick and between 300 and 3,000 feet deep) totaled 17.2 BST. Out of the 19.3 BST assessed as recoverable coal resources, approximately 167 million short tons (MST) were considered to be reserves. Within the 7 coal zones, the Wasatch coal zone contains an original resource of about 6.8 BST billion short tons of coal, of which 2.6 BST are considered a recoverable resource and approximately 26.7 MST are considered reserves. The Overland coal zone, in the Fort Union Formation, contains an original resource of approximately 23 BST of coal, of which 8.4 BST are considered a recoverable resource and approximately 74 MST are considered reserves. The China Butte coal zone, in the Fort Union Formation, contains an original resource of 36.2 BST of coal, of which 6.3 BST are considered a recoverable resource and approximately 5.5 MST are considered reserves. The Almond coal zone, in the Almond Formation, contains an original resource of 7.0 BST, of which approximately 2.0 BST are considered a recoverable resource and 61 MST are considered reserves. Resources were not calculated for the coal zones within the Niland Tongue of the Wasatch Formation or the Cretaceous Lance and Allen Ridge Formations because the coal beds in those zones are relatively thin, discontinuous, and have a limited areal extent.

Wyoming↗

Geochemistry of groundwater in the eastern Snake River Plain aquifer, Idaho National Laboratory and vicinity, eastern Idaho

Nuclear research activities at the U.S. Department of Energy (DOE) Idaho National Laboratory (INL) in eastern Idaho produced radiochemical and chemical wastes that were discharged to the subsurface, resulting in detectable concentrations of some waste constituents in the eastern Snake River Plain (ESRP) aquifer. These waste constituents may pose risks to the water quality of the aquifer. In order to understand these risks to water quality the U.S. Geological Survey, in cooperation with the DOE, conducted a study of groundwater geochemistry to improve the understanding of hydrologic and chemical processes in the ESRP aquifer at and near the INL and to understand how these processes affect waste constituents in the aquifer. Geochemistry data were used to identify sources of recharge, mixing of water, and directions of groundwater flow in the ESRP aquifer at the INL. The geochemistry data were analyzed from 167 sample sites at and near the INL. The sites included 150 groundwater, 13 surface-water, and 4 geothermal-water sites. The data were collected between 1952 and 2012, although most data collected at the INL were collected from 1989 to 1996. Water samples were analyzed for all or most of the following: field parameters, dissolved gases, major ions, dissolved metals, isotope ratios, and environmental tracers. Sources of recharge identified at the INL were regional groundwater, groundwater from the Little Lost River (LLR) and Birch Creek (BC) valleys, groundwater from the Lost River Range, geothermal water, and surface water from the Big Lost River (BLR), LLR, and BC. Recharge from the BLR that may have occurred during the last glacial epoch, or paleorecharge, may be present at several wells in the southwestern part of the INL. Mixing of water at the INL primarily included mixing of surface water with groundwater from the tributary valleys and mixing of geothermal water with regional groundwater. Additionally, a zone of mixing between tributary valley water and regional groundwater, trending southwesterly, extended from near the northeastern boundary of the INL to the southern boundary of the INL. Groundwater flow directions for regional groundwater were southwesterly, and flow directions for tributary groundwater were southeasterly upon entering the ESRP, but eventually began to flow southwesterly in a direction parallel with regional groundwater. Several discrepancies were identified from comparison of sources of recharge determined from geochemistry data and backward particle tracking with a groundwater-flow model. Some discrepancies observed in the particle tracking results included representation of recharge from BC near the north INL boundary, groundwater from the BC valley not extending far enough south, regional groundwater that extends too far west in the southern part of the INL, and no representation of recharge from geothermal water in model layer 1 or recharge from the BLR in the southwestern part of the INL.

Idaho↗

Evaluation of chemical and hydrologic processes in the eastern Snake River Plain Aquifer based on results from geochemical modeling, Idaho National Laboratory, eastern Idaho

Nuclear research activities at the U.S. Department of Energy (DOE) Idaho National Laboratory (INL) produced liquid and solid chemical and radiochemical wastes that were disposed to the subsurface resulting in detectable concentrations of some waste constituents in the eastern Snake River Plain (ESRP) aquifer. These waste constituents may affect the water quality of the aquifer and may pose risks to the eventual users of the aquifer water. To understand these risks to water quality the U.S. Geological Survey, in cooperation with the DOE, conducted geochemical mass-balance modeling of the ESRP aquifer to improve the understanding of chemical reactions, sources of recharge, mixing of water, and groundwater flow directions in the shallow (upper 250 feet) aquifer at the INL. Modeling was conducted using the water chemistry of 127 water samples collected from sites at and near the INL. Water samples were collected between 1952 and 2017 with most of the samples collected during the mid-1990s. Geochemistry and isotopic data used in geochemical modeling consisted of dissolved oxygen, carbon dioxide, major ions, silica, aluminum, iron, and the stable isotope ratios of hydrogen, oxygen, and carbon. Geochemical modeling results indicated that the primary chemical reactions in the aquifer were precipitation of calcite and dissolution of plagioclase (An 60 ) and basalt volcanic glass. Secondary minerals other than calcite included calcium montmorillonite and goethite. Reverse cation exchange, consisting of sodium exchanging for calcium on clay minerals, occurred near site facilities where large amounts of sodium were released to the ESRP aquifer in wastewater discharge. Reverse cation exchange acted to retard the movement of wastewater-derived sodium in the aquifer. Regional groundwater inflow was the primary source of recharge to the aquifer underlying the Northeast and Southeast INL Areas. Birch Creek (BC), the Big Lost River (BLR), and groundwater from BC valley provided recharge to the North INL Area, and the BLR and groundwater from BC and Little Lost River (LLR) valleys provided recharge to the Central INL Area. The BLR, groundwater from the BLR and LLR valleys and the Lost River Range, and precipitation provided recharge to the Northwest and Southwest INL Areas. The primary source of recharge west and southwest of the INL was groundwater inflow from BLR valley. Upwelling geothermal water was a small source of recharge at two wells. Aquifer recharge from surface water in the northern, central, and western parts of the INL indicated that the aquifer in these areas was a dynamic, open system, whereas the aquifer in the eastern part of the INL, which receives little recharge from surface water, was a relatively static and closed system. Sources of recharge identified from isotope ratios and geochemical modeling (major ion concentrations) were nearly identical for the North, Northeast, Southeast, and Central INL Areas, which indicated that both methods probably accurately identified the sources of recharge in these areas. Conversely, isotope ratios indicated that the BLR and groundwater from the LLR valley provided most recharge to the western parts of the Northwest and Southwest INL Areas, whereas geochemical modeling results indicated a smaller area of recharge from the BLR and groundwater from the LLR valley, a larger area of recharge from the Lost River Range, and recharge of groundwater from the BLR valley that extended to the west INL boundary. The results from geochemical modeling probably were more accurate because major ion concentrations, but not isotope ratios, were available to characterize groundwater from the BLR valley and the Lost River Range. Sources of recharge identified with a groundwater flow model (using particle tracking) and geochemical modeling were similar for the Northeast and Southeast INL Areas. However, differences between the models were that the geochemical model represented (1) recharge of groundwater from the Lost River Range in the western part of the INL, whereas the flow model did not, (2) recharge of groundwater from the BC and BLR valleys extending farther south and east, respectively, than the flow model, and (3) more recharge from the BLR in the Southwest INL Area than the flow model. Mixing of aquifer water beneath the INL included (1) mixing of regional groundwater and water from the BC valley in the Northeast and Southeast INL Areas and (2) mixing of surface water (primarily from the BLR) and groundwater across much of the North, Central, Northwest, and Southwest INL Areas. Localized recharge from precipitation mixed with groundwater in the Northwest and Southwest INL Areas, and localized upwelling geothermal water mixed with groundwater in the Central and Northeast INL Areas. Flow directions of regional groundwater were south in the eastern part of the INL and south-southwest at downgradient locations. Groundwater from the BC and LLR valleys initially flowed southeast before changing to south-southwest flow directions that paralleled regional groundwater, and groundwater from the BLR valley initially flowed south before changing to a southsouthwest direction. Wastewater-contaminated groundwater flowed south from the Idaho Nuclear Technology and Engineering Center (INTEC) infiltration ponds in a narrow plume, with the percentage of wastewater in groundwater decreasing due to dilution, dispersion, and (or) degradation from about 60‒80 percent wastewater 0.7‒0.8 mile (mi) south of the INTEC infiltration ponds to about 1.4 percent wastewater about 15.5 mi south of the INTEC infiltration ponds. Wastewater contaminated groundwater flowed southeast and then southwest from the Naval Reactors Facility industrial waste ditch, with the percentage of wastewater in groundwater decreasing from about 100 percent wastewater adjacent to the waste ditch to about 2 percent wastewater about 0.6 mi south of the waste ditch.

Idaho↗

Determining three-dimensional hydrologic processes in the eastern Snake River Plain aquifer using geochemical mass-balance modeling, Idaho National Laboratory, eastern Idaho, with contributions by Treinen, K.C.

Waste constituents discharged to the eastern Snake River Plain aquifer at the U.S. Department of Energy (DOE) Idaho National Laboratory (INL) pose risks to the water quality of the aquifer. To understand these risks, the U.S. Geological Survey, in cooperation with the DOE, used geochemical mass-balance modeling to identify three-dimensional hydrologic processes in that portion of the aquifer underlying the southwestern part of the INL that affect the movement of groundwater and waste constituents. Modeling was performed using water chemistry of 74 water samples collected from 30 wells. Fifty-four of the water samples were collected from 11 wells equipped with multilevel monitoring systems with vertically discrete sampling zones that encompass the upper 750 feet of the aquifer. Water samples from these multilevel wells were collected during 2007‒13, a period when conditions in the aquifer were approximately steady-state because there was little or no recharge from the Big Lost River. The primary source of water in groundwater at the multilevel wells during 2007‒13 was the Big Lost River. Other sources of water include groundwater from the Little Lost River valley, precipitation, and wastewater. Horizontal groundwater-flow directions appear to be similar in both the shallow and deep parts of the aquifer, and surface-water sources of water in most deep groundwater shows that groundwater moves downward. Surface-water sources of water in deep groundwater noticeably decrease within and below the Matuyama flow and associated sedimentary interbeds, which indicates that these units are semi-impermeable and retard the downward movement of groundwater.

Idaho↗

Evaluation of hydrologic processes in the eastern Snake River Plain aquifer using uranium and strontium isotopes, Idaho National Laboratory, eastern Idaho

Waste constituents discharged to the eastern Snake River Plain aquifer at the U.S. Department of Energy (DOE) Idaho National Laboratory (INL) pose risks to the water quality of the aquifer. To understand these risks, the U.S. Geological Survey, in cooperation with the DOE, is conducting geochemical studies to better understand the hydrologic processes at the INL that affect the movement of groundwater and waste constituents. In this study, we used natural uranium ( 234 U/ 238 U) and strontium ( 87 Sr/ 86 Sr) isotope ratios of surface water and groundwater to identify the sources of water, the mixing of different source waters, and the flow directions in the shallow part (upper 250 feet) of the aquifer at the INL. Samples were collected from 17 sites at and near the INL that represent the source-water contributions to the aquifer. These source-water sites included surface water, regional groundwater, and springs. Groundwater samples from 63 sites were collected at and near the INL. For all sites, sample collection dates ranged from 1979 to 2019, but groundwater samples collected at the INL are representative of wet climate cycles when the Big Lost River (BLR) was flowing onto the INL. The 234 U/ 238 U activity ratios and 87 Sr/ 86 Sr from groundwater at the INL were plotted on graphs within ternary mixing webs in which the three end members of the mixing web represented specific sources of recharge. The large number of sources of recharge required numerous mixing webs, representing various geographic locations at the INL, so that each mixing web represented an area with just three sources of recharge. Considerations for determining the sources of recharge to groundwater sites included chemical signatures in addition to 234 U/ 238 U and 87 Sr/ 86 Sr, hydrologic context, and geographic location. The mixing webs were used to estimate the percentage of recharge from specific sources to groundwater at wells. The results of this study identified groundwater from the Lemhi Range as a source of recharge to the INL, which was a previously unsuspected source of recharge. The estimated spatial distribution of recharge from the BLR and groundwater from the Lost River Range also decreased and increased, respectively, relative to the spatial distribution estimated from an earlier study. Upwelling geothermal water was identified at only one well, which indicates that the upward movement of deep groundwater to the shallow part of the aquifer is largely nonexistent. Mixing between surface water and groundwater, different groundwater recharge sources, or both is ubiquitous at the INL. Mixing of water fully explains the distribution of 234 U/ 238 U and 87 Sr/ 86 Sr in groundwater at the INL and thus renders unnecessary the hypothesis that fast and slow flow zones at the INL are required to explain the distribution of 234 U/ 238 U and 87 Sr/ 86 Sr.

Idaho↗

Geologic map of upper cretaceous and tertiary strata and coal stratigraphy of the Paleocene Fort Union Formation, Rawlins-Little Snake River area, south-central Wyoming

This report provides a map and detailed descriptions of geologic formations for a 1,250 square mile region in the Rawlins-Little Snake River coal field in the eastern part of the Washakie and Great Divide Basins of south-central Wyoming. Mapping of geologic formations and coal beds was conducted at a scale of 1:24,000 and compiled at a scale of 1:100,000. Emphasis was placed on coal-bearing strata of the China Butte and Overland Members of the Paleocene Fort Union Formation. Surface stratigraphic sections were measured and described and well logs were examined to determine the lateral continuity of individual coal beds; the coal-bed stratigraphy is shown on correlation diagrams. A structure contour and overburden map constructed on the uppermost coal bed in the China Butte Member is also provided.

Scientific Investigations Map↗

Regional potentiometric-surface map of the Great Basin carbonate and alluvial aquifer system in Snake Valley and surrounding areas, Juab, Millard, and Beaver Counties, Utah, and White Pine and Lincoln Counties, Nevada

Water-level measurements from 190 wells were used to develop a potentiometric-surface map of the east-central portion of the regional Great Basin carbonate and alluvial aquifer system in and around Snake Valley, eastern Nevada and western Utah. The map area covers approximately 9,000 square miles in Juab, Millard, and Beaver Counties, Utah, and White Pine and Lincoln Counties, Nevada. Recent (2007-2010) drilling by the Utah Geological Survey and U.S. Geological Survey has provided new data for areas where water-level measurements were previously unavailable. New water-level data were used to refine mapping of the pathways of intrabasin and interbasin groundwater flow. At 20 of these locations, nested observation wells provide vertical hydraulic gradient data and information related to the degree of connection between basin-fill aquifers and consolidated-rock aquifers. Multiple-year water-level hydrographs are also presented for 32 wells to illustrate the aquifer system's response to interannual climate variations and well withdrawals.

Utah, Nevada↗

Use of short-term (5-Minute) and long-term (18-Hour) leaching tests to characterize, fingerprint, and rank mine-waste material from historical mines in the Deer Creek, Snake River, and Clear Creek Watersheds in and around the Montezuma Mining District, Colorado

Precipitation-induced runoff from historical mine-waste located adjacent to the headwaters of the Snake River, Deer Creek, Saints John Creek, Grizzly Gulch, Stevens Gulch, and Leavenworth Creek contributes to the degradation of water quality in these streams. Because historical mine-waste piles have had long-term exposure to the atmosphere, it is surmised that runoff from these piles, induced by meteorological events such as cloudbursts and snowmelt, may cause mobility of acid and metals into a watershed due to dissolution of soluble minerals. For this study, 13 mine-waste composite samples from various mine-wastes in these drainage basins were leached using both a short-term and a long-term leach test. Analytical results from this combination of leach tests are tools that allow the investigator to quantify (fingerprint) which geochemical components could be expected in runoff from these piles if they were leached by a cloudburst (5-minute leach test), as well as what the ?worst-case? geochemical profile would look like if the material were subject to extended leaching and breakdown of the mine-waste material (18-hour leach test). Also, this combination of leach tests allows the geoscientist the ability to see geochemical changes in the mine-waste leachate over time. That is, does the leachate become more or less acidic over time; does the specific conductance increase or decrease; and are there changes in the concentrations of major or trace elements? Further, use of a ranking scheme described herein will aid in prediction of which historical mine-waste piles have the greatest potential for impact on a watershed should runoff occur. Because of long-term weathering of these historical mine-waste piles, geochemical profiles, leachate time-trends, and relative ranking of the mine-wastes produced from analysis of the leachates are Hageman_SIR_2508.doc 1 7/21/2004 2:50 PM indicative of how the mine-waste piles can be expected to act in the environment and may help to identify the ?bad actors??this may aid in understanding the reasons for water-quality differences between the drainages.

Scientific Investigations Report↗

A conceptual model of ground-water flow in the eastern Snake River Plain aquifer at the Idaho National Laboratory and vicinity with implications for contaminant transport

Ground-water flow in the west-central part of the eastern Snake River Plain aquifer is described in a conceptual model that will be used in numerical simulations to evaluate contaminant transport at the Idaho National Laboratory (INL) and vicinity. The model encompasses an area of 1,940 square miles (mi2) and includes most of the 890 mi2 of the INL. A 50-year history of waste disposal associated with research activities at the INL has resulted in measurable concentrations of waste contaminants in the aquifer. A thorough understanding of the fate and movement of these contaminants in the subsurface is needed by the U.S. Department of Energy to minimize the effect that contaminated ground water may have on the region and to plan effectively for remediation. Three hydrogeologic units were used to represent the complex stratigraphy of the aquifer in the model area. Collectively, these hydrogeologic units include at least 65 basalt-flow groups, 5 andesite-flow groups, and 61 sedimentary interbeds. Three rhyolite domes in the model area extend deep enough to penetrate the aquifer. The rhyolite domes are represented in the conceptual model as low permeability, vertical pluglike masses, and are not included as part of the three primary hydrogeologic units. Broad differences in lithology and large variations in hydraulic properties allowed the heterogeneous, anisotropic basalt-flow groups, andesite-flow groups, and sedimentary interbeds to be grouped into three hydrogeologic units that are conceptually homogeneous and anisotropic. Younger rocks, primarily thin, densely fractured basalt, compose hydrogeologic unit 1; younger rocks, primarily of massive, less densely fractured basalt, compose hydrogeologic unit 2; and intermediate-age rocks, primarily of slightly-to-moderately altered, fractured basalt, compose hydrogeologic unit 3. Differences in hydraulic properties among adjacent hydrogeologic units result in much of the large-scale heterogeneity and anisotropy of the aquifer in the model area, and differences in horizontal and vertical hydraulic conductivity in individual hydrogeologic units result in much of the small-scale heterogeneity and anisotropy of the aquifer in the model area. The inferred three-dimensional geometry of the aquifer in the model area is very irregular. Its thickness generally increases from north to south and from west to east and is greatest south of the INL. The interpreted distribution of older rocks that underlie the aquifer indicates large changes in saturated thickness across the model area. The boundaries of the model include physical and artificial boundaries, and ground-water flows across the boundaries may be temporally constant or variable and spatially uniform or nonuniform. Physical boundaries include the water-table boundary, base of the aquifer, and northwest mountain-front boundary. Artificial boundaries include the northeast boundary, southeast-flowline boundary, and southwest boundary. Water flows into the model area as (1) underflow (1,225 cubic feet per second (ft3/s)) from the regional aquifer (northeast boundary-constant and nonuniform), (2) underflow (695 ft3/s) from the tributary valleys and mountain fronts (northwest boundary-constant and nonuniform), (3) precipitation recharge (70 ft3/s) (constant and uniform), streamflow-infiltration recharge (95 ft3/s) (variable and nonuniform), wastewater return flows (6 ft3/s) (variable and nonuniform), and irrigation-infiltration recharge (24 ft3/s) (variable and nonuniform) across the water table (water-table boundary-variable and nonuniform), and (4) upward flow across the base of the aquifer (44 ft3/s) (uniform and constant). The southeast-flowline boundary is represented as a no-flow boundary. Water flows out of the model area as underflow (2,037 ft3/s) to the regional aquifer (southwest boundary-variable and nonuniform) and as ground-water withdrawals (45 ft3/s) (water table boundary-variable and nonuniform). Ground-water flow i

Scientific Investigations Report↗

Statistical Stationarity of Sediment Interbed Thicknesses in a Basalt Aquifer, Idaho National Laboratory, Eastern Snake River Plain, Idaho

The statistical stationarity of distributions of sedimentary interbed thicknesses within the southwestern part of the Idaho National Laboratory (INL) was evaluated within the stratigraphic framework of Quaternary sediments and basalts at the INL site, eastern Snake River Plain, Idaho. The thicknesses of 122 sedimentary interbeds observed in 11 coreholes were documented from lithologic logs and independently inferred from natural-gamma logs. Lithologic information was grouped into composite time-stratigraphic units based on correlations with existing composite-unit stratigraphy near these holes. The assignment of lithologic units to an existing chronostratigraphy on the basis of nearby composite stratigraphic units may introduce error where correlations with nearby holes are ambiguous or the distance between holes is great, but we consider this the best technique for grouping stratigraphic information in this geologic environment at this time. Nonparametric tests of similarity were used to evaluate temporal and spatial stationarity in the distributions of sediment thickness. The following statistical tests were applied to the data: (1) the Kolmogorov-Smirnov (K-S) two-sample test to compare distribution shape, (2) the Mann-Whitney (M-W) test for similarity of two medians, (3) the Kruskal-Wallis (K-W) test for similarity of multiple medians, and (4) Levene's (L) test for the similarity of two variances. Results of these analyses corroborate previous work that concluded the thickness distributions of Quaternary sedimentary interbeds are locally stationary in space and time. The data set used in this study was relatively small, so the results presented should be considered preliminary, pending incorporation of data from more coreholes. Statistical tests also demonstrated that natural-gamma logs consistently fail to detect interbeds less than about 2-3 ft thick, although these interbeds are observable in lithologic logs. This should be taken into consideration when modeling aquifer lithology or hydraulic properties based on lithology.

Scientific Investigations Report↗

Multilevel groundwater monitoring of hydraulic head and temperature in the eastern Snake River Plain aquifer, Idaho National Laboratory, Idaho, 2009–10

During 2009 and 2010, the U.S. Geological Survey’s Idaho National Laboratory Project Office, in cooperation with the U.S. Department of Energy, collected quarterly, depth-discrete measurements of fluid pressure and temperature in nine boreholes located in the eastern Snake River Plain aquifer. Each borehole was instrumented with a multilevel monitoring system consisting of a series of valved measurement ports, packer bladders, casing segments, and couplers. Multilevel monitoring at the Idaho National Laboratory has been ongoing since 2006. This report summarizes data collected from three multilevel monitoring wells installed during 2009 and 2010 and presents updates to six multilevel monitoring wells. Hydraulic heads (heads) and groundwater temperatures were monitored from 9 multilevel monitoring wells, including 120 hydraulically isolated depth intervals from 448.0 to 1,377.6 feet below land surface. Quarterly head and temperature profiles reveal unique patterns for vertical examination of the aquifer’s complex basalt and sediment stratigraphy, proximity to aquifer recharge and discharge, and groundwater flow. These features contribute to some of the localized variability even though the general profile shape remained consistent over the period of record. Major inflections in the head profiles almost always coincided with low-permeability sediment layers and occasionally thick sequences of dense basalt. However, the presence of a sediment layer or dense basalt layer was insufficient for identifying the location of a major head change within a borehole without knowing the true areal extent and relative transmissivity of the lithologic unit. Temperature profiles for boreholes completed within the Big Lost Trough indicate linear conductive trends; whereas, temperature profiles for boreholes completed within the axial volcanic high indicate mostly convective heat transfer resulting from the vertical movement of groundwater. Additionally, temperature profiles provide evidence for stratification and mixing of water types along the southern boundary of the Idaho National Laboratory. Vertical head and temperature change were quantified for each of the nine multilevel monitoring systems. The vertical head gradients were defined for the major inflections in the head profiles and were as high as 2.1 feet per foot. Low vertical head gradients indicated potential vertical connectivity and flow, and large gradient inflections indicated zones of relatively low vertical connectivity. Generally, zones that primarily are composed of fractured basalt displayed relatively small vertical head differences. Large head differences were attributed to poor vertical connectivity between fracture units because of sediment layering and/or dense basalt. Groundwater temperatures in all boreholes ranged from 10.2 to 16.3˚C. Normalized mean hydraulic head values were analyzed for all nine multilevel monitoring wells for the period of record (2007-10). The mean head values suggest a moderately positive correlation among all boreholes, which reflects regional fluctuations in water levels in response to seasonality. However, the temporal trend is slightly different when the location is considered; wells located along the southern boundary, within the axial volcanic high, show a strongly positive correlation.

Idaho↗

Optimization of water-level monitoring networks in the eastern Snake River Plain aquifer using a kriging-based genetic algorithm method

Long-term groundwater monitoring networks can provide essential information for the planning and management of water resources. Budget constraints in water resource management agencies often mean a reduction in the number of observation wells included in a monitoring network. A network design tool, distributed as an R package, was developed to determine which wells to exclude from a monitoring network because they add little or no beneficial information. A kriging-based genetic algorithm method was used to optimize the monitoring network. The algorithm was used to find the set of wells whose removal leads to the smallest increase in the weighted sum of the (1) mean standard error at all nodes in the kriging grid where the water table is estimated, (2) root-mean-squared-error between the measured and estimated water-level elevation at the removed sites, (3) mean standard deviation of measurements across time at the removed sites, and (4) mean measurement error of wells in the reduced network. The solution to the optimization problem (the best wells to retain in the monitoring network) depends on the total number of wells removed; this number is a management decision. The network design tool was applied to optimize two observation well networks monitoring the water table of the eastern Snake River Plain aquifer, Idaho; these networks include the 2008 Federal-State Cooperative water-level monitoring network (Co-op network) with 166 observation wells, and the 2008 U.S. Geological Survey-Idaho National Laboratory water-level monitoring network (USGS-INL network) with 171 wells. Each water-level monitoring network was optimized five times: by removing (1) 10, (2) 20, (3) 40, (4) 60, and (5) 80 observation wells from the original network. An examination of the trade-offs associated with changes in the number of wells to remove indicates that 20 wells can be removed from the Co-op network with a relatively small degradation of the estimated water table map, and 40 wells can be removed from the USGS-INL network before the water table map degradation accelerates. The optimal network designs indicate the robustness of the network design tool. Observation wells were removed from high well-density areas of the network while retaining the spatial pattern of the existing water-table map.

Idaho↗

Iodine-129 in the eastern Snake River Plain aquifer at and near the Idaho National Laboratory, Idaho, 2010-12

From 1953 to 1988, approximately 0.941 curies of iodine-129 ( 129 I) were contained in wastewater generated at the Idaho National Laboratory (INL) with almost all of this wastewater discharged at or near the Idaho Nuclear Technology and Engineering Center (INTEC). Most of the wastewater containing 129 I was discharged directly into the eastern Snake River Plain (ESRP) aquifer through a deep disposal well until 1984; lesser quantities also were discharged into unlined infiltration ponds or leaked from distribution systems below the INTEC. During 2010–12, the U.S. Geological Survey in cooperation with the U.S. Department of Energy collected groundwater samples for 129 I from 62 wells in the ESRP aquifer to track concentration trends and changes for the carcinogenic radionuclide that has a 15.7 million-year half-life. Concentrations of 129 I in the aquifer ranged from 0.0000013±0.0000005 to 1.02±0.04 picocuries per liter (pCi/L), and generally decreased in wells near the INTEC, relative to previous sampling events. The average concentration of 129 I in groundwater from 15 wells sampled during four different sample periods decreased from 1.15 pCi/L in 1990–91 to 0.173 pCi/L in 2011–12. All but two wells within a 3-mile radius of the INTEC showed decreases in concentration, and all but one sample had concentrations less than the U.S. Environmental Protection Agency maximum contaminant level of 1 pCi/L. These decreases are attributed to the discontinuation of disposal of 129 I in wastewater and to dilution and dispersion in the aquifer. The decreases in 129 I concentrations, in areas around INTEC where concentrations increased between 2003 and 2007, were attributed to less recharge near INTEC either from less flow in the Big Lost River or from less local snowmelt and anthropogenic sources. Although wells near INTEC sampled in 2011–12 showed decreases in 129 I concentrations compared with previously collected data, some wells south and east of the Central Facilities Area, near the site boundary, and south of the INL showed small increases. These slight increases are attributed to variable discharge rates of wastewater that eventually moved to these well locations as a pulse of water from a particular disposal period. Wells sampled for the first time around the Naval Reactors Facility had 129 I concentrations slightly greater than background concentrations in the ESRP aquifer. These concentrations are attributed to possible leakage from landfills at the Naval Reactors Facility or seepage from air emission deposits from INTEC, or both. In 2012, the U.S. Geological Survey collected discrete groundwater samples from 25 zones in 11 wells equipped with multilevel monitoring systems to help define the vertical distribution of 129 I in the aquifer. Concentrations ranged from 0.000006±0.000004 to 0.082±0.003 pCi/L. Two new wells completed in 2012 showed variability of up to one order of magnitude of concentrations of 129 I among various zones. Two other wells showed similar concentrations of 129 I in all three zones sampled. Concentrations were well less than the maximum contaminant level in all zones.

Idaho↗

Chemical constituents in groundwater from multiple zones in the eastern Snake River Plain aquifer, Idaho National Laboratory, Idaho, 2009-13

From 2009 to 2013, the U.S. Geological Survey’s (USGS) Idaho National Laboratory (INL) Project office, in cooperation with the U.S. Department of Energy, collected water-quality samples from multiple water-bearing zones in the eastern Snake River Plain aquifer. Water samples were collected from 11 monitoring wells completed in about 250–750 feet of the upper part of the aquifer, and samples were analyzed for selected major ions, trace elements, nutrients, radiochemical constituents, and stable isotopes. Each well was equipped with a multilevel monitoring system containing four to seven sampling ports that were each isolated by permanent packer systems. The sampling ports were installed in aquifer zones that were highly transmissive and that represented the water chemistry of the top three to five model layers of a steady-state and transient groundwater‑flow model. The groundwater-flow model and water chemistry are being used to better define movement of wastewater constituents in the aquifer. The water-chemistry composition of all sampled zones for the five new multilevel wells is calcium plus magnesium bicarbonate. One of the zones in well USGS 131A has a slightly different chemistry from the rest of the zones and wells and the difference is attributed to more wastewater influence from the Idaho Nuclear Technology and Engineering Center. One well, USGS 135, was not influenced by wastewater disposal and consisted of mostly older water in all of its zones. Tritium concentrations in relation to basaltic flow units indicate the presence of wastewater influence in multiple basalt flow groups; however, tritium is most abundant in the South Late Matuyama flow group in the southern boundary wells. The concentrations of wastewater constituents in deep zones in wells Middle 2051, USGS 132, USGS 105, and USGS 103 support the concept of groundwater flow deepening in the southwestern corner of the INL, as indicated by the INL groundwater-flow model.

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Multilevel groundwater monitoring of hydraulic head and temperature in the eastern Snake River Plain aquifer, Idaho National Laboratory, Idaho, 2011-13

From 2011 to 2013, the U.S. Geological Survey’s Idaho National Laboratory (INL) Project Office, in cooperation with the U.S. Department of Energy, collected depth-discrete measurements of fluid pressure and temperature in 11 boreholes located in the eastern Snake River Plain aquifer. Each borehole was instrumented with a multilevel monitoring system (MLMS) consisting of a series of valved measurement ports, packer bladders, casing segments, and couplers. Multilevel monitoring at the INL has been ongoing since 2006 and this report summarizes data collected from 2011 to 2013 in 11 multilevel monitoring wells. Hydraulic head (head) and groundwater temperature data were collected from 11 multilevel monitoring wells, including 177 hydraulically isolated depth intervals from 448.0 to 1,377.6 feet below land surface. One port (port 3) within borehole USGS 134 was not monitored because of a valve failure. Head and temperature profiles reveal unique patterns for vertical examination of the aquifer’s complex basalt and sediment stratigraphy, proximity to aquifer recharge and discharge, and groundwater flow. These features contribute to some of the localized variability even though the general profile shape remained consistent over the period of record. Twenty-two major head inflections were described for 9 of 11 MLMS boreholes and almost always coincided with low‑permeability sediment layers and occasionally thick layers of dense basalt. However, the presence of a sediment layer or dense basalt layer was insufficient for identifying the location of a major head change within a borehole without knowing the true areal extent and relative transmissivity of the lithologic unit. Temperature profiles for boreholes completed within the Big Lost Trough indicate linear conductive trends; whereas, temperature profiles for boreholes completed within volcanic rift zones and near the southern boundary of the Idaho National Laboratory, indicate mostly convective heat transfer. Select boreholes along the southern boundary show a temperature reversal and cooler water deeper in the aquifer resulting from the vertical movement of groundwater. Vertical head and temperature change were quantified for each of the 11 multilevel monitoring systems. Vertical head gradients defined for the major inflections in the head profiles were as high as 2.9 feet per foot. In general, fractured basalt zones displayed relatively small vertical head differences and show a high occurrence within volcanic rift zones. Poor connectivity between fractures and higher vertical gradients were generally attributed to sediment layers and layers of dense basalt, or both. Groundwater temperatures in all boreholes ranged from 10.8 to 16.3 °C. Normalized mean head values were analyzed for all 11 multilevel monitoring wells for the period of record (2007–13). The mean head values suggest a moderately positive correlation among all boreholes and generally reflect regional fluctuations in water levels in response to seasonal climatic changes. Boreholes within volcanic rift zones and near the southern boundary (USGS 103, USGS 105, USGS 108, USGS 132, USGS 135, USGS 137A) display a temporal correlation that is strongly positive. Boreholes in the Big Lost Trough display some variations in temporal correlations that may result from proximity to the mountain front to the northwest and episodic flow in the Big Lost River drainage system. For example, during June 2012, boreholes MIDDLE 2050A and MIDDLE 2051 showed head buildup within the upper zones when compared to the June 2010 profile event, which correlates to years when surface water was reported for the Big Lost River several months preceding the measurement period. With the exception of borehole USGS 134, temporal correlation between MLMS wells completed within the Big Lost Trough is generally positive. Temporal correlation for borehole USGS 134 shows the least agreement with other MLMS boreholes located within the Big Lost Trough; however, borehole USGS 134 is close to the mountain front where tributary valley subsurface inflow is suspected.

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Hydrologic influences on water-level changes in the Eastern Snake River Plain aquifer at and near the Idaho National Laboratory, Idaho, 1949-2014

The U.S. Geological Survey, in cooperation with the U.S. Department of Energy, has maintained a water-level monitoring program at the Idaho National Laboratory (INL) since 1949 to systematically measure water levels to provide long-term information on groundwater recharge, discharge, movement, and storage in the eastern Snake River Plain (ESRP) aquifer. During 2014, water levels in the ESRP aquifer reached all-time lows for the period of record, prompting this study to assess the effect that future water-level declines may have on pumps and wells. Water-level data were compared with pump-setting depth to determine the hydraulic head above the current pump setting. Additionally, geophysical logs were examined to address changes in well productivity with water-level declines. Furthermore, hydrologic factors that affect water levels in different areas of the INL were evaluated to help understand why water-level changes occur. Review of pump intake placement and 2014 water-level data indicates that 40 wells completed within the ESRP aquifer at the INL have 20 feet (ft) or less of head above the pump. Nine of the these wells are located in the northeastern and northwestern areas of the INL where recharge is predominantly affected by irrigation, wet and dry cycles of precipitation, and flow in the Big Lost River. Water levels in northeastern and northwestern wells generally show water-level fluctuations of as much as 4.5 ft seasonally and show declines as much as 25 ft during the past 14 years. In the southeastern area of the INL, seven wells were identified as having less than 20 ft of water remaining above the pump. Most of the wells in the southeast show less decline over the period of record compared with wells in the northeast; the smaller declines are probably attributable to less groundwater withdrawal from pumping of wells for irrigation. In addition, most of the southeastern wells show only about a 1–2 ft fluctuation seasonally because they are less influenced by groundwater withdrawals for irrigation. In the southwestern area of the INL, 24 wells were identified as having less than 20 ft of water remaining above the pump. Wells in the southwest also only show small 1–2 ft fluctuations seasonally because of a lack of irrigation influence. Wells show larger fluctuation in water levels closer to the Big Lost River and fluctuate in response to wet and dry cycles of recharge to the Big Lost River. Geophysical logs indicate that most of the wells evaluated will maintain their current production until the water level declines to the depth of the pump. A few of the wells may become less productive once the water level gets to within about 5 ft from the top of the pump. Wells most susceptible to future drought cycles are those in the northeastern and northwestern areas of the INL.

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An update of hydrologic conditions and distribution of selected constituents in water, eastern Snake River Plain aquifer and perched groundwater zones, Idaho National Laboratory, Idaho, emphasis 2012-15

Since 1952, wastewater discharged to in ltration ponds (also called percolation ponds) and disposal wells at the Idaho National Laboratory (INL) has affected water quality in the eastern Snake River Plain (ESRP) aquifer and perched groundwater zones underlying the INL. The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, maintains groundwater-monitoring networks at the INL to determine hydrologic trends and to delineate the movement of radiochemical and chemical wastes in the aquifer and in perched groundwater zones. This report presents an analysis of water-level and water-quality data collected from the ESRP aquifer, multilevel monitoring system (MLMS) wells in the ESRP aquifer, and perched groundwater wells in the USGS groundwater monitoring networks during 2012-15.

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Iodine-129 in the Eastern Snake River Plain aquifer at and near the Idaho National Laboratory, Idaho, 2017–18

From 1953 to 1988, approximately 0.941 curies of iodine-129 ( 129 I) were contained in wastewater generated at the Idaho National Laboratory, with almost all of it discharged at or near the Idaho Nuclear Technology and Engineering Center (INTEC). Until 1984, most of the wastewater was discharged directly into the eastern Snake River Plain (ESRP) aquifer through a deep disposal well; however, some wastewater was also discharged into unlined infiltration ponds or leaked from distribution systems below the INTEC. During 2017–18, the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, collected samples for 129 I from 30 wells that monitor the ESRP aquifer to track concentrations and changes of the carcinogenic radionuclide that has a 15.7 million-year half-life. Concentrations of 129 I in the aquifer ranged from 0.000016 ± 0.000001 to 0.88+/- 0.03 picocuries per liter (pCi/L), and concentrations generally decreased in wells near the INTEC as compared with previously collected samples. The average concentration of 15 wells sampled during 5 different sample periods decreased from 1.15 pCi/L in 1990–91 to 0.168 pCi/L in 2017–18, but average concentrations were similar to 2011–12 within analytical uncertainty. All but four wells within a 3-mile radius of the INTEC showed decreases in concentration, and all samples had concentrations less than the U.S. Environmental Protection Agency’s maximum contaminant level of 1 pCi/L. These decreases are attributed to the discontinuation of disposal of 129 I in wastewater and to dilution and dispersion in the aquifer. Some wells southeast of INTEC showed increasing trends; these increases were attributed to variable transmissivity. Although wells near INTEC sampled in 2017–18 showed decreases in concentrations compared with data collected previously, some wells south of the INL boundary showed small increases. These increases are attributed to historical variable discharge rates of wastewater that eventually moved to these well locations as a pulse of water from a particular disposal period.

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