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Characterizing the sponge grounds of Grays Canyon, Washington, USA

Deep-sea sponge grounds are relatively understudied ecosystems that may provide key habitats for a large number of fish and invertebrates including commercial species. Glass sponge grounds have been discovered from the tropics to polar regions but there are only a few places with high densities of dictyonine sponges. Dictyonine glass sponges have a fused skeleton, which stays intact when they die and in some areas the accumulation of successive generations of sponges leads to the formation of reefs. In 2010 and 2016, we surveyed an area near Grays Canyon in Washington, USA, where dense aggregations of glass sponges and potential sponge reefs were discovered in 2007. Our primary aims were to make a preliminary assessment of whether the glass sponges form reefs at this location, characterize the sponge assemblage present at this site and examine associations between the sponges and commercially important species. Multibeam mapping and sub-bottom profiling indicate that the glass sponges at this site do not form reefs and are mostly attached to hard substrates. Analysis of photographs collected by an autonomous underwater vehicle and samples collected by a remotely operated vehicle guided by telepresence revealed the presence of two abundant dictyonine sponge species at this site, Heterochone calyx and Aphrocallistes vastus (mean densities = 1.43 ± 0.057 per 10 m2, max = 24 per 10 m2). We also observed a large number of non-reef-building glass sponges and various demosponges including a potentially new species in the genus Acarnus. A diverse fish assemblage was recorded at this site including eight species of rockfish. Rockfish abundance was positively related to sponge abundance. Spot prawns (Pandalus platyceros) were also abundant and were strongly associated with sponges. Despite not finding sponge reefs, this is an ecologically significant area. Further research is necessary to determine the environmental factors that give rise to the abundance of large dictyonine sponges at this location and also to determine if other similar sponge grounds exist along the west coast of the United States.

Washington↗

A new strategy for earthquake focal mechanisms using waveform-correlation-derived relative polarities and cluster analysis: Application to the 2014 Long Valley Caldera earthquake swarm

In microseismicity analyses, reliable focal mechanisms can typically be obtained for only a small subset of located events. We address this limitation here, presenting a framework for determining robust focal mechanisms for entire populations of very small events. To achieve this, we resolve relative P and S wave polarities between pairs of waveforms by using their signed correlation coefficients—a by-product of previously performed precise earthquake relocation. We then use cluster analysis to group events with similar patterns of polarities across the network. Finally, we apply a standard mechanism inversion to the grouped data, using either catalog or correlation-derived P wave polarity data sets. This approach has great potential for enhancing analyses of spatially concentrated microseismicity such as earthquake swarms, mainshock-aftershock sequences, and industrial reservoir stimulation or injection-induced seismic sequences. To demonstrate its utility, we apply this technique to the 2014 Long Valley Caldera earthquake swarm. In our analysis, 85% of the events (7212 out of 8494 located by Shelly et al . [2016]) fall within five well-constrained mechanism clusters, more than 12 times the number with network-determined mechanisms. Of the earthquakes we characterize, 3023 (42%) have magnitudes smaller than 0.0. We find that mechanism variations are strongly associated with corresponding hypocentral structure, yet mechanism heterogeneity also occurs where it cannot be resolved by hypocentral patterns, often confined to small-magnitude events. Small (5–20°) rotations between mechanism orientations and earthquake location trends persist when we apply 3-D velocity models and might reflect a geometry of en echelon, interlinked shear, and dilational faulting.

California↗

The post-emergence period for denning polar bears: Phenology and influence on cub survival

Among polar bears ( Ursus maritimus ), only parturient females den for extended periods, emerging from maternal dens in spring after having substantially depleted their energy reserves during a fast that can exceed 8 months. Although den emergence coincides with a period of increasing prey availability, polar bears typically do not depart immediately to hunt, but instead remain at the den for up to a month. This delay suggests that there are likely adaptive advantages to remaining at the den between emergence and departure, but the influence of the timing and duration of this post-emergence period on cub survival has not been evaluated previously. We used temperature and location data from 70 denning bears collared within the Southern Beaufort Sea and Chukchi Sea subpopulations to estimate the phenology of the post-emergence period. We evaluated the influence of various spatial and temporal features on duration of the post-emergence period and evaluated the potential influence of post-emergence duration on litter survival early in the spring following denning. For dens that likely contained viable cubs at emergence ( n = 56), mean den emergence occurred on 16 March (SE = 1.4 days) and mean departure on 24 March (SE = 1.6 days), with dates typically occurring later in the Chukchi Sea relative to Southern Beaufort Sea and on land relative to sea ice. Mean duration of the post-emergence period was 7.9 days (SE = 1.4) for bears that were observed with cubs later in the spring, which was over 4 times longer than duration of those observed without cubs (1.9 days). Litter survival in the spring following denning ( n = 31 dens) increased from 0.5 to 0.9 when duration of the post-emergence period increased by ~4 days and other variables were held at mean values. Our limited sample size and inability to verify cub presence at emergence suggests that future research is merited to improve our understanding of this relationship. Nonetheless, our results highlight the importance of the post-emergence period in contributing to reproductive success and can assist managers in developing conservation and mitigation strategies in denning areas, which will be increasingly important as human activities expand in the Arctic.

Journal of Mammalogy↗

Surface properties of Mars' polar layered deposits and polar landing sites

On December 3, 1999, the Mars Polar Lander and Mars Microprobes will land on the planet's south polar layered deposits near (76°S, 195°W) and conduct the first in situ studies of the planet's polar regions. The scientific goals of these missions address several poorly understood and globally significant issues, such as polar meteorology, the composition and volatile content of the layered deposits, the erosional state and mass balance of their surface, their possible relationship to climate cycles, and the nature of bright and dark aeolian material. Derived thermal inertias of the southern layered deposits are very low (50-100 J m -2 s -1/2 K -1 ), suggesting that the surface down to a depth of a few centimeters is generally fine grained or porous and free of an appreciable amount of rock or ice. The landing site region is smoother than typical cratered terrain on ∼1 km pixel -1 Viking Orbiter images but contains low-relief texture on ∼5 to 100 m pixel -1 Mariner 9 and Mars Global Surveyor images. The surface of the southern deposits is older than that of the northern deposits and appears to be modified by aeolian erosion or ablation of ground ice.

Journal of Geophysical Research E: Planets↗

Sewage contamination in the upper Mississippi River as measured by the fecal sterol, coprostanol

The molecular sewage indicator, coprostanol, was measured in bed sediments of the Mississippi River for the purpose of determining sewage contamination. Coprostanol is a non-ionic, non-polar, organic molecule that associates with sediments in surface waters, and concentrations of coprostanol in bed sediments provide an indication of long-term sewage loads. Because coprostanol concentrations are dependent on particle size and percent organic carbon, a ratio between coprostanol (sewage sources) and cholestanol + cholesterol (sewage and non-sewage sources) was used to remove the biases related to particle size and percent organic carbon. The dynamics of contaminant transport in the Upper Mississippi River are influenced by both hydrologic and geochemical parameters. A mass balance model incorporating environmental parameters such as river and tributary discharge, suspended sediment concentration, fraction of organic carbon, sedimentation rates, municipal discharges and coprostanol decay rates was developed that describes coprostanol concentrations and therefore, expected patterns of municipal sewage effects on the Upper Mississippi River. Comparison of the computed and the measured coprostanol concentrations provides insight into the complex hydrologic and geochemical processes of contaminant transport and the ability to link measured chemical concentrations with hydrologic characteristics of the Mississippi River.

Water Research↗

Seismic source mechanism of degassing bursts at Kilauea volcano, Hawaii: Results from waveform inversion in the 10–50 s band

The current (March 2008 to February 2009) summit eruptive activity at Kilauea Volcano is characterized by explosive degassing bursts accompanied by very long period (VLP) seismic signals. We model the source mechanisms of VLP signals in the 10–50 s band using data recorded for 15 bursts with a 10‐station broadband network deployed in the summit caldera. To determine the source centroid location and source mechanism, we minimize the residual error between data and synthetics calculated by the finite difference method for a point source embedded in a homogeneous medium that takes topography into account. The VLP signals associated with the bursts originate in a source region ∼1 km below the eastern perimeter of Halemaumau pit crater. The observed waveforms are well explained by the combination of a volumetric component and a vertical single force component. For the volumetric component, several source geometries are obtained which equally explain the observed waveforms. These geometries include (1) a pipe dipping 64° to the northeast; (2) two intersecting cracks including an east striking crack (dike) dipping 80° to the north, intersecting a north striking crack (another dike) dipping 65° to the east; (3) a pipe dipping 58° to the northeast, intersecting a crack dipping 48° to the west–southwest; and (4) a pipe dipping 57° to the northeast, intersecting a pipe dipping 58° to the west–southwest. Using the dual‐crack model as reference, the largest volume change obtained among the 15 bursts is ∼24,400 m 3 , and the maximum amplitude (peak to peak) of the force is ∼20 GN. Each burst is marked by a similar sequence of deflation and inflation, trailed by decaying oscillations of the volumetric source. The vertical force is initially upward, synchronous with source deflation, then downward, synchronous with source reinflation, followed by oscillations with polarity opposite to the volumetric oscillations. This combination of force and volume change is attributed to pressure and momentum changes induced during a fluid dynamic source mechanism involving the ascent, expansion, and burst of a large slug of gas within the upper ∼150 m of the magma conduit. As the slug expands upon approach to the surface and more liquid becomes wall supported by viscous shear forces, the pressure below the slug decreases, inducing conduit deflation and an upward force on the Earth. The final rapid slug expansion and burst stimulate VLP and LP oscillations of the conduit system, which slowly decay due to viscous dissipation and elastic radiation. Consideration of the fluid dynamic arguments leads us to prefer the dual‐crack VLP source model as it is the only candidate model capable of producing plausible values of length scales and pressure changes. The magnitudes of the vertical forces observed in the 15 bursts appear consistent with slug masses of 10 4 to 10 6 kg.

Hawaii↗

Origin and properties of hydrothermal tremor at Lone Star Geyser, Yellowstone National Park, USA

Geysers are rare geologic features that intermittently discharge liquid water and steam driven by heating and decompression boiling. The cause of variability in eruptive styles and the associated seismic signals are not well understood. Data collected from five broadband seismometers at Lone Star Geyser, Yellowstone National Park are used to determine the properties, location, and temporal patterns of hydrothermal tremor. The tremor is harmonic at some stages of the eruption cycle and is caused by near‐periodic repetition of discrete seismic events. Using the polarization of ground motion, we identify the location of tremor sources throughout several eruption cycles. During preplay episodes (smaller eruptions preceding the more vigorous major eruption), tremor occurs at depths of 7–10 m and is laterally offset from the geyser's cone by ~5 m. At the onset of the main eruption, tremor sources migrate laterally and become shallower. As the eruption progresses, tremor sources migrate along the same path but in the opposite direction, ending where preplay tremor originates. The upward and then downward migration of tremor sources during eruptions are consistent with warming of the conduit followed by evacuation of water during the main eruption. We identify systematic relations among the two types of preplays, discharge, and the main eruption. A point‐source moment tensor fit to low‐frequency waveforms of an individual tremor event using half‐space velocity models indicates average V S ≳ 0.8 km/s, source depths ~4–20 m, and moment tensors with primarily positive isotropic and compensated linear vector dipole moments.

Wyoming↗

H-binding of size- and polarity-fractionated soil and lignite humic acids after removal of metal and ash components

A fractionation technique, combining dialysis removal of metal and ash components with hydrofluoric acid and pH 10 citrate buffer followed by chromatography of dialysis permeate on XAD-8 resin at decreasing pH values, has been applied to lignite humic acid (lignite-HA) and soil humic acid (soil-HA). H-binding data and non ideal competitive adsorption-Donnan model parameters were obtained for the HA fractions by theoretical analysis of H-binding data which reveal a significant increase of the carboxyl and the phenolic charge for the lignite-HA fractions vs. the parental lignite humic acid (L Parental HA). The fractionated lignite-HA material consisted mainly of permeate fractions, some of which were fulvic acid-like. The fractionated soil-HA material consisted mainly of large macromolecular structures that did not permeate the dialysis membrane during deashing. Chargeable groups had comparable concentrations in soil-HA fractions and parental soil humic acid (S Parental HA), indicating minimal interference of ash components with carboxyl and phenolic (and/or enolic) groups. Fractionation of HA, combined with theoretical analysis of H-binding, can distinguish the supramolecular vs. macromolecular nature of fractions within the same parental HA.

Environmental Science and Pollution Research↗

Seismovolcanic signals at Deception Island volcano, Antarctica: Wave field analysis and source modeling

The seismovolcanic signals associated with the volcanic activity of Deception Island (Antarctica), recorded during three Antarctic summers (1994–1995, 1995–1996 and 1996–1997), are analyzed using a dense small-aperture (500 m) seismic array. The visual and spectral classification of the seismic events shows the existence of long-period and hybrid isolated seismic events, and of low-frequency, quasi-monochromatic and spasmodic continuous tremors. All spectra have the highest amplitudes in the frequency band between 1 and 4 Hz, while hybrids and spasmodic tremors have also significant amplitudes in the high-frequency band (4–10 Hz). The array analysis indicates that almost all the well-correlated low-frequency signals share similar array parameters (slowness and back azimuth) and have the same source area, close to the array site. The polarization analysis shows that phases at high-frequency are mostly composed of P waves, and those phases dominated by low frequencies can be interpreted as surface waves. No clear shear waves are evidenced. From the energy evaluation, we have found that the reduced displacement values for surface and body waves are confined in a narrow interval. Volcano-tectonic seismicity is located close to the array, at a depth shallower than 1 km. The wave-field properties of the seismovolcanic signals allow us to assume a unique source model, a shallow resonating fluid-filled crack system at a depth of some hundreds of meters. All of the seismic activity is interpreted as the response of a reasonably stable stationary geothermal process. The differences observed in the back azimuth between low and high frequencies are a near-field effect. A few episodes of the degassification process in an open conduit were observed and modeled with a simple organ pipe.

Journal of Geophysical Research: Solid Earth↗

Eolian features in the Western Desert of Egypt and some applications to Mars

Relations of landform types to wind regimes, bedrock composition, sediment supply, and topography are shown by field studies and satellite photographs of the Western Desert of Egypt. This desert, which lies at the core of the largest hyperarid region on earth, provides analogs of Martian wind-formed features. These include sand dunes, alternating light and dark streaks, knob ‘shadows,’ and yardangs. Surface particles have been segregated by wind into deposits (dunes, sand sheets, and light streaks) that can be differentiated by their grain size distributions, surface shapes, and colors. Throughgoing sand of mostly fine to medium grain size is migrating southward in longitudinal dune belts and barchan chains whose long axes lie parallel to the prevailing northerly winds, but topographic variations such as scarps and depressions strongly influence the zones of deposition and dune morphology. Sand from the longitudinal dunes on the plains is commonly redistributed into barchans in the depressions. These barchans are generally simple crescents that are morphologically similar to many of the dunes seen on Viking orbiter pictures of the north polar sand sea on mars. Light streaks are depositional features consisting of dune belts and elongate sheets of coarse to medium sand and granules. Intervening dark streaks are erosional features consisting of strips of desert-varnished bedrock and lag gravel surfaces exposed between the sand deposits. The shape of both light and dark streaks is controlled by wind flow around topographic highs. Dark zones (shadows) in the lee of mountains, hills, and knobs are erosional products from the topographic highs; they change shape only in response to movement of the adjacent lighter-colored sand deposits. Streamlined yardangs carved in crystalline limestone constitute one of the largest yardang fields on earth. Yardangs occur also in sandstone of the Nubian Series and in lacustrine sediments. The variables that affect the patterns of wind erosion and deposition in the Western Desert are topographic effects on wind velocities and directions, resistance of the bedrock, sand supply, and climatic change with time; vegetation is essentially absent and is not a controlling factor.

Journal of Geophysical Research Solid Earth↗

Early Cretaceous paleolatitude of the Yukon-Koyukuk province, Alaska

We report results from a paleomagnetic study of the Yukon-Koyukuk province, a key region for reconstructing the Cretaceous paleogeography of northern Alaska and northeastern Asia. The province lies between the displaced continental fragment of Arctic Alaska and the accreted terranes of southern Alaska. Although Lower Cretaceous volcanogenic rocks of the Yukon-Koyukuk province preserve primary remanent magnetizations, the primary component is masked by a pervasive overprint. The over-printing magnetization, which has dual polarity, was acquired after a Late Cretaceous orogeny left the region highly deformed. By fitting planes to tilt-corrected thermal demagnetization data and solving for the best intersection of the corresponding remagnetization circles, we separated the primary component, presumably a vestige of the original thermoremanent magnetization, from the overprinting component of the natural remanence. The primary magnetization corresponds to a mean paleopole of Early Cretaceous age at 60.2°N, 159°E. The mean paleolatitude is 69°N with the 95% confidence ellipse ranging from 60° to 75°N. This analysis was successful because the tilt corrections of the sampled strata had sufficient variation to ensure a strong intersection of the remagnetization circles. We infer that Lower Cretaceous rocks of the Brooks Range and the Yukon-Koyukuk province were once separated by a wide ocean basin that was closed by subduction, probably during the Cretaceous. The northern limb of the Angayucham terrane, which lies between the Brooks Range and the Yukon-Koyukuk province, may contain remnants of the now-closed ocean basin.

Journal of Geophysical Research Solid Earth↗

Mars Global Surveyor Thermal Emission Spectrometer experiment: Investigation description and surface science results

The Thermal Emission Spectrometer (TES) investigation on Mars Global Surveyor (MGS) is aimed at determining (1) the composition of surface minerals, rocks, and ices; (2) the temperature and dynamics of the atmosphere; (3) the properties of the atmospheric aerosols and clouds; (4) the nature of the polar regions; and (5) the thermophysical properties of the surface materials. These objectives are met using an infrared (5.8- to 50-μm) interferometric spectrometer, along with broadband thermal (5.1- to 150-μm) and visible/near-IR (0.3- to 2.9-μm) radiometers. The MGS TES instrument weighs 14.47 kg, consumes 10.6 W when operating, and is 23.6×35.5×40.0 cm in size. The TES data are calibrated to a 1-σ precision of 2.5 −6 ×10 −8 W cm −2 sr −1 /cm −1 , 1.6×10 −6 W cm −2 sr −1 , and ∼0.5 K in the spectrometer, visible/near-IR bolometer, and IR bolometer, respectively. These instrument subsections are calibrated to an absolute accuracy of ∼4×10 −8 W cm −2 sr −1 /cm −1 (0.5 K at 280 K), 1–2%, and ∼1–2 K, respectively. Global mapping of surface mineralogy at a spatial resolution of 3 km has shown the following: (1) The mineralogic composition of dark regions varies from basaltic, primarily plagioclase feldspar and clinopyroxene, in the ancient, southern highlands to andesitic, dominated by plagioclase feldspar and volcanic glass, in the younger northern plains. (2) Aqueous mineralization has produced gray, crystalline hematite in limited regions under ambient or hydrothermal conditions; these deposits are interpreted to be in-place sedimentary rock formations and indicate that liquid water was stable near the surface for a long period of time. (3) There is no evidence for large-scale (tens of kilometers) occurrences of moderate-grained (>50-μm) carbonates exposed at the surface at a detection limit of ∼10%. (4) Unweathered volcanic minerals dominate the spectral properties of dark regions, and weathering products, such as clays, have not been observed anywhere above a detection limit of ∼10%; this lack of evidence for chemical weathering indicates a geologic history dominated by a cold, dry climate in which mechanical, rather than chemical, weathering was the significant form of erosion and sediment production. (5) There is no conclusive evidence for sulfate minerals at a detection limit of ∼15%. The polar region has been studied with the following major conclusions: (1) Condensed CO 2 has three distinct end-members, from fine-grained crystals to slab ice. (2) The growth and retreat of the polar caps observed by MGS is virtually the same as observed by Viking 12 Martian years ago. (3) Unique regions have been identified that appear to differ primarily in the grain size of CO 2 ; one south polar region appears to remain as black slab CO 2 ice throughout its sublimation. (4) Regional atmospheric dust is common in localized and regional dust storms around the margin and interior of the southern cap. Analysis of the thermophysical properties of the surface shows that (1) the spatial pattern of albedo has changed since Viking observations, (2) a unique cluster of surface materials with intermediate inertia and albedo occurs that is distinct from the previously identified low-inertia/bright and high-inertia/dark surfaces, and (3) localized patches of high-inertia material have been found in topographic lows and may have been formed by a unique set of aeolian, fluvial, or erosional processes or may be exposed bedrock.

Journal of Geophysical Research E: Planets↗

Measurement of soil carbon oxidation state and oxidative ratio by 13 C nuclear magnetic resonance

The oxidative ratio (OR) of the net ecosystem carbon balance is the ratio of net O 2 and CO 2 fluxes resulting from photosynthesis, respiration, decomposition, and other lateral and vertical carbon flows. The OR of the terrestrial biosphere must be well characterized to accurately estimate the terrestrial CO 2 sink using atmospheric measurements of changing O 2 and CO 2 levels. To estimate the OR of the terrestrial biosphere, measurements are needed of changes in the OR of aboveground and belowground carbon pools associated with decadal timescale disturbances (e.g., land use change and fire). The OR of aboveground pools can be measured using conventional approaches including elemental analysis. However, measuring the OR of soil carbon pools is technically challenging, and few soil OR data are available. In this paper we test three solid-state nuclear magnetic resonance (NMR) techniques for measuring soil OR, all based on measurements of the closely related parameter, organic carbon oxidation state (C ox ). Two of the three techniques make use of a molecular mixing model which converts NMR spectra into concentrations of a standard suite of biological molecules of known C ox . The third technique assigns C ox values to each peak in the NMR spectrum. We assess error associated with each technique using pure chemical compounds and plant biomass standards whose C ox and OR values can be directly measured by elemental analyses. The most accurate technique, direct polarization solid-state 13 C NMR with the molecular mixing model, agrees with elemental analyses to ??0.036 C ox units (??0.009 OR units). Using this technique, we show a large natural variability in soil C ox and OR values. Soil C ox values have a mean of -0.26 and a range from -0.45 to 0.30, corresponding to OR values of 1.08 ?? 0.06 and a range from 0.96 to 1.22. We also estimate the OR of the carbon flux from a boreal forest fire. Analysis of soils from nearby intact soil profiles imply that soil carbon losses associated with the fire had an OR of 1.09 1 (??0.00 3 ). Fire appears to be a major factor driving the soil C pool to higher oxidation states and lower OR values. Episodic fluxes caused by disturbances like fire may have substantially different ORs from ecosystem respiration fluxes and therefore should be better quantified to reduce uncertainties associated with our understanding of the global atmospheric carbon budget. Copyright 2009 by the American Geophysical Union.

Journal of Geophysical Research G: Biogeosciences↗

Paleomagnetic and palynologic analyses of Albian to Santonian strata at Bayn Shireh, Burkhant, and Khuren Dukh, eastern Gobi Desert, Mongolia

Cretaceous terrestrial sediments deposited in a series of intracratonic basins across the Gobi Desert region of southern Mongolia and northern China contain a unique and diverse vertebrate fauna. In 1996 an expedition jointly sponsored by the Mongolian Paleontological Center and the Hayashibara Museum of Natural Sciences revisited a number of famous vertebrate fossil localities in the eastern Gobi region of Mongolia and, as part of a broad geological and paleontological study, collected a series of paleomagnetic samples from measured sections at Bayn Shireh, Burkhant and Khuren Dukh, as well as from an unmeasured locality adjacent to Khuren Dukh. Expedition members also collected palynologic samples from Khuren Dukh and the adjacent locality. Paleomagnetic analysis shows that all the sites from which samples were collected display detrital remnant magnetization that is consistently normal in polarity. The measured Cretaceous magnetic directions are oriented to the east or northeast of the present day expected direction (declination 356.2??, inclination 65.2??), and they are wholly concordant with that expected for a mid-latitude Northern Hemisphere sampling locality, and with the directions for this period reported by other workers. These results, when considered in tandem with the known biostratigraphy, strongly suggest that the sedimentary deposits at all four localities in the eastern Gobi correlate to the normal polarity chron 34 (the Cretaceous Long Normal), which ranges in age from approximately 121 to 83.5 million years. Previous vertebrate, invertebrate and palynological data from Khuren Dukh suggest that the lower and middle parts of the stratigraphic interval exposed there (which have been assigned to the Shinekhudag Formation) are 'Khukhtekian' in age and correspond to the Aptian-Albian interval that can be broadly correlated to the older, Early Cretaceous part of the Cretaceous Long Normal, C34n. New palynologic data presented here indicate that these strata are no older than middle to late Albian. The rocks at Bayn Shireh (the Bayn Shireh Formation) have been assigned a 'Baynshirenian' biostratigraphic age that may range from Cenomanian to early Campanian. The magnetostratigraphy results presented here indicate that the strata at both the Bayn Shireh and Burkhant localities do not cross the Santonian/Campanian Stage boundary, however, as this is believed to lie at, or very near, the C34n/C33r reversal boundary. Thus, the Bayn Shireh Formation was most likely deposited near the end of the Cretaceous Long Normal Interval, no later than the latest Santonian.

Cretaceous Research↗

Topographic stress perturbations in southern Davis Mountains, west Texas 1. Polarity reversal of principal stresses

We have applied a previously developed analytical stress model to interpret subsurface stress conditions inferred from acoustic televiewer logs obtained in two municipal water wells located in a valley in the southern Davis Mountains near Alpine, Texas. The appearance of stress-induced breakouts with orientations that shift by 90° at two different depths in one of the wells is explained by results from exact solutions for the effects of valleys on gravity and tectonically induced subsurface stresses. The theoretical results demonstrate that above a reference depth termed the hinge point, a location that is dependent on Poisson's ratio, valley shape, and magnitude of the maximum horizontal tectonic stress normal to the long axis of the valley, horizontal stresses parallel to the valley axis are greater than those normal to it. At depths below this hinge point the situation reverses and horizontal stresses normal to the valley axis are greater than those parallel to it. Application of the theoretical model at Alpine is accommodated by the fact that nearby earthquake focal mechanisms establish an extensional stress regime with the regional maximum horizontal principal stress aligned perpendicular to the valley axis. We conclude that the localized stress field associated with a valley setting can be highly variable and that breakouts need to be examined in this context when estimating the orientations and magnitudes of regional principal stresses.

Texas↗

Travel times of P and S from the global digital seismic networks: Implications for the relative variation of P and S velocity in the mantle

We present new data sets of P and S arrival times which have been handpicked from long-period vertical and transverse component recordings of the various global seismic networks. Using events which occurred from 1976 to 1994 results in ∼38,000 globally well-distributed measurements of teleseismic P and ∼41,000 measurements of S . These data are particularly useful for looking at the relative variation of S and P velocities in the lower mantle. We describe both the measurement techniques and the gross characteristics of the data sets. The size of our data sets allows us to exploit the internal consistency of the data to identify outliers using a summary ray analysis. Since the polarity of each arrival is also known, we can construct fault plane solutions and/or compare with polarities predicted by the Harvard centroid moment tensor solutions to further diagnose phase misidentification. This analysis results in ∼5% of the data being identified as outliers. An analysis of variance indicates that the S residual travel times are dominated by the effects of three-dimensional structure but the P data have comparable contributions from noise and source mislocation effects. The summary ray analysis reveals the basic character of lower mantle structure, and there are large-scale patterns in both the S and P data sets that correlate quite well with each other. This analysis suggests that on average, d ln v s / d ln v p is an increasing function of depth in the mantle going from a value of ∼1.7 at the top of the lower mantle to an apparent value of 4 near the base of the mantle. This latter extreme value of R seems to result mainly from data which sample one region in the lowermost mantle under the central Pacific, where large positive S residuals are associated with very small P residuals. Such an anomaly cannot be thermal in origin.

Journal of Geophysical Research B: Solid Earth↗

Mudstone sedimentation at high latitudes: Ice as a transport medium for mud and supplier of nutrients

Controls on mudstone deposition at high latitudes are poorly known relative to low latitudes. In recent sediments deposited in these environments, ice significantly influences sediment transport and primary productivity. The products of ice transport are relatively well known in glacimarine settings, but are less well known from below melting sea ice. This latter setting is significant as today it is associated with high primary organic productivity. The aim of this study is to assess how sea ice might have controlled lithofacies variability and organic-matter distribution and preservation in an ancient marine, siliciclastic mudstone-dominated succession deposited at high latitudes. Combined sedimentary logging, optical and electron optical (back-scatte red electron imagery), geochemical, and isotopic methods were used to determine sample variability in forty-five samples collected from the Lower Cretaceous succession in the Mikkelsen Bay State #1 borehole (North Slope, Alaska). The succession overall fines upward and contains muddy sandstones and sand- and silt-bearing, clay-rich mudstones towards its base in contrast to clay-rich and clay-dominated mudstones towards its top. Some of the mudstone units exhibit thin (< 5 mm), relic-beds that fine upward weakly. In some units small (0.5 mm), bed-parallel silt-filled microburrows disrupt depositional laminae whereas in others pervasive burrowing completely obliterates original depositional textures. Many of the units are pelleted. These mudstones are unusual in that they contain minor but very striking outsize grains, composed of subrounded to rounded sand and granule-size material. In addition, they are good petroleum source rocks, with between 2.8 and 5.9 wt % total organic carbon, of predominantly Type II kerogen. The organic matter has an isotopic signature ranging from -25.4??? ??13C to -28.1??? ??13C. Thin tuffs (< 20 mm) and carbonate-cemented units are also present. Given the absence of significant polar ice in the Early Cretaceous the outsized grains are interpreted to have been deposited from a combination of melting, dirty anchor, and fast ice. The mud fraction, which forms the bulk of the sediment, is interpreted to have been deposited from melting, sediment-laden frazil ice, and fast ice. After deposition sediments were partially reworked by bottom currents generated by brine rejection during sea ice formation. Sympagic organisms, grazing on algae and bacteria both within and below the ice, pelleted the sediment. Bioturbation, which varies through the succession, indicates that sedimentation probably occurred beneath a predominantly oxic or dysoxic water column. In this setting productivity was fueled by nutrients released from melting sea ice in the marginal ice zone. The good petroleum source potential of these mudstones is attributed to high organic productivity coupled to episodic and rapid sedimentation rather than existence of bottom-water anoxia linked to upwelling. Because sea-ice rafting was probably the dominant sediment transport mechanism it is not appropriate to use sequence stratigraphic methodology to predict lithofacies variability in this environment. Copyright ?? 2005, SEPM (Society for Sedimentary Geology).

Journal of Sedimentary Research↗

Design and methods of the Midwest Stream Quality Assessment (MSQA), 2013

During 2013, the U.S. Geological Survey (USGS) National Water-Quality Assessment Project (NAWQA), in collaboration with the USGS Columbia Environmental Research Center, the U.S. Environmental Protection Agency (EPA) National Rivers and Streams Assessment (NRSA), and the EPA Office of Pesticide Programs assessed stream quality across the Midwestern United States. This Midwest Stream Quality Assessment (MSQA) simultaneously characterized watershed and stream-reach water-quality stressors along with instream biological conditions, to better understand regional stressor-effects relations. The MSQA design focused on effects from the widespread agriculture in the region and urban development because of their importance as ecological stressors of particular concern to Midwest region resource managers. A combined random stratified selection and a targeted selection based on land-use data were used to identify and select sites representing gradients in agricultural intensity across the region. During a 14-week period from May through August 2013, 100 sites were selected and sampled 12 times for contaminants, nutrients, and sediment. This 14-week water-quality “index” period culminated with an ecological survey of habitat, periphyton, benthic macroinvertebrates, and fish at all sites. Sediment was collected during the ecological survey for analysis of sediment chemistry and toxicity testing. Of the 100 sites, 50 were selected for the MSQA random stratified group from 154 NRSA sites planned for the region, and the other 50 MSQA sites were selected as targeted sites to more evenly cover agricultural and urban stressor gradients in the study area. Of the 50 targeted sites, 12 were in urbanized watersheds and 21 represented “good” biological conditions or “least disturbed” conditions. The remaining 17 targeted sites were selected to improve coverage of the agricultural intensity gradient or because of historical data collection to provide temporal context for the study. This report provides a detailed description of the MSQA study components, including surveys of ecological conditions, routine water sampling, deployment of passive polar organic compound integrative samplers, and stream sediment sampling at all sites. Component studies that were completed to provide finer scale temporal data or more extensive analysis at selected sites, included continuous water-quality monitoring, daily pesticide sampling, laboratory and in-stream water toxicity testing efforts, and deployment of passive suspended-sediment samplers.

Illinois, Indiana, Iowa, Kansas, Kentucky, Michiga↗