Geology ReportsSearch

SEARCH · Geology Reports

Results for “Hydological Processes”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

381 records · Page 18Linked to original sources

Seismic techniques and suggested instrumentation to monitor volcanoes

Introduction Changes in the pressure or location of magma can stress or break surrounding rocks and trigger flow of nearby waters and gases, causing seismic signals, such as discrete earthquakes and tremor. These phenomena are types of seismic unrest that commonly precede eruption and can be used to forecast volcanic activity. Mass movements at the surface, including avalanches, debris flows, and lahars, may also generate seismic signals that are specifically addressed in chapter H , this volume (Thelen and others, 2024). Our focus in this chapter is to determine the levels of instrumentation recommended to produce high-quality, well-constrained seismic observations important for early warning of impending eruptions, detecting changes in ongoing eruptions, and characterizing other hazardous volcanic events. There are emerging techniques and new types of instrumentation, such as distributed acoustic sensing or rotational seismometers, that we do not consider here. These types of instrumentation show promise for monitoring but still require maturation before being considered more generally in volcano monitoring. Most of the capabilities mentioned below are universal for all types of volcanic systems, although some are best applied to stratovolcanoes with an apical single vent. In some settings, such as calderas or shield volcanoes, we must broaden coverage to include multiple possible storage regions or vent locations. As an example, Thelen (2014) discretized the long rift zones of shield volcanoes in Hawaiʻi as a set of evenly spaced “vents.” In this construct, each vent comes with recommendations, and several thousand network configurations were simulated to assess the effect on network quality levels and to determine the most efficient network design. The same process could be applied in a caldera setting or a volcanic field, where an evenly spaced grid of potential vents is considered. Localized recommendations for each unique system are beyond the scope of this report and left up to local experts to assess based on the conditions, restrictions, and requirements of each volcano.

Scientific Investigations Report

Waters divided: A history of alluvial fan research and a view of its future

Flows exiting confined valleys tend to deposit sediment in fan-shaped landforms. Where deposition is wholly or largely by the tractive forces of flowing water, these landforms are called alluvial fans. They are the product of the progressive division of water and sediment downfan, from slopes that may exceed 0.10 to distal slopes that may be below 0.01. Channel depths also tend to decline, from values that approach one to several meters at steep fanheads, to a few decimeters at distal fan margins. The result is a radiating, depositional ramp where confined or unconfined flows transport sediment from source basins to bounding streams, subsiding basins, or stable platforms. Where streams or subsiding basins consume the sediment supply from the source basin, the fan may approach a steady form whose extent and distal slope are set by stream location or subsidence rate. Where boundary conditions do not remove sediment, the fan may prograde out to long distances and low slopes (<0.01). Theoretical and experimental work over the past several decades support the notion that alluvial fan long-profiles become steeper as sediment supply increases or transport capacity decreases, and increasingly concave upward as the rate of bed material deposition decreases downfan. Grainsize distributions of alluvial fans seem to span the range observed in alluvial rivers, with no processes that uniquely identify them, apart from the distributary pattern of deposition. Bed sand cover tends to increase downfan in arid-region fans, with an absence of systematic downfan fining of coarser grain sizes. Surficial mapping and geochronology have demonstrated that fan deposition varies greatly through time, arguably from climate variations that alter hillslope sediment supply. The combination of surficial mapping and hydraulic modeling with high-resolution topography can now produce detailed flood susceptibility maps. The effective use of these maps to protect lives and property, however, depends on answering many of the enduring questions about the mechanics of how water and sediment divide down alluvial fans.

Book chapter

Mapping karst groundwater flow paths and delineating recharge areas for springs in the Little Sequatchie and Pryor Cove watersheds, Tennessee

The Little Sequatchie River and Pryor Cove Branch, in southern Tennessee, drain the eastern escarpment of the Cumberland Plateau to the Sequatchie River near the southern end of the Sequatchie Valley. The Little Sequatchie River is the largest tributary to the Sequatchie River by drainage area, covering over 120 square miles. The hydrology of the two drainage areas has been largely altered by karst processes, which has caused the majority of the streams to sink at the contact between the Mississippian Pennington Formation and the underlying Mississippian Bangor Limestone. The U.S. Geological Survey, in cooperation with the U.S. Fish and Wildlife Service and Tennessee Department of Environment and Conservation, initiated a study in 2021 to map the karst groundwater pathways in both watersheds in order to delineate recharge areas for several springs. One of these springs, Sequatchie Cave, represents a significant habitat for two Species of Greatest Conservation Need, the Glyphopsyche sequatchie (Sequatchie caddisfly) and the federally endangered Marstonia ogmorhaphe (royal marstonia). Springs and springflow-dominated streams in the Little Sequatchie River valley and Pryor Cove also provide water for agricultural practices and serve as a drinking water source for nearby communities. During the study, a total of 25 dye injections were conducted over eight rounds from January 2022 through March 2023. Dye traces from these injections helped to delineate recharge areas for six major springs, ranging from 7.3 to 65.2 square miles in area. The majority of the dye traces remained subsurface (from sinkpoint to recovery site) for long distances, with karst groundwater travelling nearly 8 miles before resurfacing. The dye traces also had rapid traveltimes, often travelling hundreds to thousands of feet per hour. The goal of this project was to provide scientific data related to karst groundwater pathways and spring recharge areas to aid State and Federal agencies in making informed decisions to protect and preserve this unique and vulnerable karst system.

Tennessee

Aeromagnetic and magnetotelluric imaging of west-central Idaho and the Stibnite-Yellow Pine mining district: A regional to district perspective

Aeromagnetic and magnetotelluric (MT) data are used to better understand the geology and mineral resources near the Stibnite-Yellow Pine mining district in central Idaho. The reduced-to-pole (RTP) transformation of regional-scale aeromagnetic data shows that allochthonous island-arc rocks west of the Salmon River suture are significantly more magnetic than the Laurentian continental rocks east of the suture and that the granitoids of the Idaho batholith have moderate to low magnetization in both early, metaluminous, and late, peraluminous phases. Application of tilt derivative to aeromagnetic data highlights major crustal-scale structures. The 5-km upward continued magnetic data indicate island-arc rocks have deep magnetic sources. The 110-km-long MT profile images resistivity structure to depths around 30 km. At shallow depths, resistivity corresponds to mapped geologic units, with moderate resistivities underlying volcanic and roof-pendant metasedimentary rocks and moderate to high resistivities occurring beneath the Idaho batholith. Crustal-scale moderate resistivities beneath the suture image the results of tectonomagmatic processes that accompanied suturing and translating allochthonous terranes. Low resistivity values beneath and fringing the batholith are derived from metasedimentary rocks that may have served as a melt source and reductant during melt generation and provided metals during later ore formation. In the Stibnite-Yellow Pine mining district, a high-resolution aeromagnetic compilation is shown to correlate with mapped lithologies and mineral deposit-related structures. The RTP transform distinguishes magnetic and nonmagnetic granitoid phases of the Idaho batholith. The tilt derivative highlights metasedimentary rocks, some of which are favorable ore hosts. The Meadow Creek fault hosts the Stibnite and Hangar Flats deposits and is imaged as a magnetic low due to hydrothermal alteration. Reconstructions of magnetic anomaly offsets and orebodies indicate around 3 km of post-95 Ma dextral separation, with some or all of the offset inferred to postdate the main Au mineralization episode (61–66 Ma).

Idaho

Insights on gas hydrate formation and growth within an interbedded sand reservoir from well logging at the Qiongdongnan Basin, South China Sea

Although variable well log resolution and its control on saturation estimation has been studied, it has not been directly applied to a specific location to explore the nature of gas hydrate within a sand reservoir. We applied in-situ measurements of resistivities, neutron porosity, and gamma ray at two sites in the Qiongdongnan Basin, South China Sea (QDN-W05–2021 and QDN-W08–2021) to investigate the reservoir parameters of a hydrate-bearing sand reservoir. Our results show that gas hydrate is distributed in 5 zones with a total thickness of 10.7 m and an average saturation of 69% at the QDN-W05–2021 site, while they are distributed in 2 zones with a total thickness of 4.3 m and an average saturation of 49% at the QDN-W08–2021 site. We found that variances in saturations estimated from lateral-extra deep button (RX), phase shift (P40H-P40L), and attenuation (A40H-A40L) resistivities within the laterally mapped continuous sand body were affected by the nature of gas hydrate occurrences. Results indicate gas hydrate forms and accumulates at the center of the sand layer and tends to be less or not present toward the top and base. Integrated with seismic data, the in-situ measurements provide insights in the evolution of a mushroom-shaped, hydrate-gas reservoir system. In the system, free gas is likely horizontally transported from the top-center of the gas chimney to the surrounding areas in the early stage dominated by a warm-gas environment, whereas hydrate forms in the opposite pathway starting from the surrounding areas in the following stage with temperature reducing. Our study suggests that high-resolution in-situ measurements not only are a tool to identify the physical properties, but also can be used to help explain the physical process of hydrate growth and accumulation.

Marine Geology

An empirical Green’s function approach for isolating directivity effects in earthquake ground-motion amplitudes

In this study, we apply an empirical Green’s function (eGf) method within a ground‐motion modeling framework to mitigate trade‐offs between source, path, and site effects. Many physical processes contribute to spatial variations in observed ground motions, including earthquake radiation pattern, directivity, variable path attenuation, and site effects. Current nonergodic ground‐motion models use spatially varying coefficients for path and site effects, but they do not address trade‐offs with complex earthquake source effects. To quantify the influence of directivity on ground‐motion amplitudes, we use records from multiple smaller earthquakes with epicenters near that of a larger event. We use these small magnitude events as eGfs and estimate repeatable path and site effects at individual stations, assuming that the average adjustments are not controlled by directivity. We adjust residuals from the larger earthquake using the eGf terms, isolating effects related to the rupture. This method clearly enhances the observed broadband directivity observed in the 2022 M 5.1 and 2007 M 5.4 Alum Rock earthquake ground motions, reinforcing the conclusion that their ruptures were unilateral. For the 2004 M 6.0 Parkfield earthquake, we find a bilateral rupture model better fits the data because variations in rupture velocity, slip rate, and slip distribution seem to have a stronger effect on the ground motions than rupture direction alone. Applying eGf adjustments reduces the standard deviation of the rupture models over the three earthquakes by 32% on average and by up to 57% for the 2022 Alum Rock earthquake, confirming we have effectively removed repeatable effects related to the wave propagation path and site response. We propose a novel measure of the frequency‐dependent directivity amplification strength as the reduction in ground‐motion residual variability gained by fitting a directivity model; for the three earthquakes considered, this parameter varies between 25% and 75%, indicating that directivity can strongly influence ground motions and should be considered in ground‐motion modeling.

California

Alteration mapping in granitic gneiss using handheld geophysical and geochemical instruments: Implications for iron oxide-apatite and rare earth elements exploration

The Adirondack Mountains of New York, U.S.A. contain iron oxide-apatite (IOA) mineral deposits with variable concentrations of rare earth elements (REE). The IOA mineral deposits are typically hosted in the Lyon Mountain Granite Gneiss and are spatially correlated with extensive Na metasomatism (albitization) of the surrounding country rocks, although some mineral deposits also occur in metagabbro, paragneiss, and anorthosite hosts. The location of albitization zones is key to finding new IOA mineral deposits and better understanding the mineralization processes associated with their genesis. However, the Na alteration zones are generally not visibly identifiable in outcrop or hand specimens because the color and textural changes are subtle and are thus difficult to map. Here, we discuss the results from testing two spectroscopic techniques (handheld, field gamma-ray spectroscopy, and portable X-ray fluorescence (pXRF)) to characterize albitization zones surrounding IOA mineral deposits. The gamma-ray and pXRF spectrometers successfully distinguished the relative intensity of alteration in the Lyon Mountain Granite Gneiss based on the K abundance. The measured K content decreases towards the IOA mineral deposits, and the magnitude and width of the gradient are similar along the strike of each mineral deposit. Elevated Th and U values are present in host rocks adjacent to REE-bearing IOA mineral deposits. The pXRF and gamma-ray spectrometer K values are remarkably consistent with laboratory-based, whole-rock XRF compositional data and, therefore, useful for semi-quantitative analysis. Notably, albitization aureoles are consistent around REE-rich and REE-poor mineral deposits, suggesting that saline fluids are essential for the petrogenesis of IOA mineral deposits but may not be critical to REE mineralization. Ultimately, this study demonstrates the utility of handheld gamma-ray and pXRF spectrometry for identifying otherwise cryptic albitization gradients associated with IOA mineral deposits in granitic gneiss.

New York

Estimating agricultural irrigation water consumption for the High Plains aquifer region with integrated energy- and water-balance evapotranspiration modeling approaches

Estimation of irrigation water use provides essential information for the management and conservation of agricultural water resources. Conventionally, water use data are created based on reports and surveys from water users, whereas manual records may not be complete due to lacking flow meters, measurement gaps, inconsistent methods across regions, and time- and cost-consuming data processing. Alternatively, spatially explicit estimation of irrigation water use can be conducted efficiently using remote sensing evapotranspiration (ET) modeling approaches. In this study, we created a gridded blue water evapotranspiration (BWET) dataset to estimate historical irrigation water consumption (1986 – 2020) in the croplands across the United States High Plains aquifer region. The BWET data were generated by integrating an energy-balance ET model [Operational Simplified Surface Energy Balance model (SSEBop)] and a water-balance ET model [Vegetation ET model (VegET)]. BWET in croplands indicates crop consumptive use of irrigation water extracted from surface water and groundwater resources. The BWET estimates were compared with reported irrigation water use data for all counties within the aquifer region. The results revealed high agreement between growing season (May – September) BWET and annual water withdrawal at county level. Specifically, correlation coefficients of volumetric BWET and water withdrawal were 0.90 and 0.96, respectively, for the entire aquifer region and western Kansas. The timeseries of BWET and water withdrawal showed similar temporal trends and high covariations. The BWET estimates were systematically lower than the water withdrawal measurements, which was primarily attributed to blue water losses in the irrigation system. The irrigation efficiency, calculated as the ratio of BWET to water withdrawal depth, was 0.57 and 0.74 for the entire aquifer region and western Kansas, respectively. This study demonstrates the capability of using satellite-based ET models (e.g., SSEBop and VegET) to efficiently estimate crop water consumption and evaluate irrigation efficiency at landscape, county, and regional scales.

Colorado, Kansas, Nebraska, New Mexico, Oklahoma,

Environmental monitoring of groundwater, surface water, and soil at the Ammonium Perchlorate Rocket Motor Destruction Facility at the Letterkenny Army Depot, Chambersburg, Pennsylvania, 2021

Letterkenny Army Depot in Chambersburg, Pennsylvania, built an Ammonium Perchlorate Rocket Motor Destruction (ARMD) Facility in 2016 to centralize rocket motor destruction and contain all waste during the destruction process. The U.S. Geological Survey has collected environmental samples from groundwater, surface water, and soils at ARMD since 2016. During 2021, samples were collected from four groundwater wells in September, one surface-water site in October, and five soil sites in November near the facility. Samples were analyzed for nutrients, trace metals, major ions, total volatile organic compounds, and perchlorate. Perchlorate was not detected in any 2021 samples. Groundwater results showed no constituents exceeded any U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL). Dissolved arsenic (As) was detected in one well above the reporting detection level (RDL) of 3 micrograms per liter (μg/L) at 5.4 μg/L but below its MCL of 10 μg/L. Dissolved iron (Fe) was the only inorganic constituent measured above an EPA secondary maximum contaminant level (SMCL). All groundwater samples collected in 2021 exceeded the Fe SMCL of 300 μg/L, with concentrations ranging from 390 μg/L to 3,500 μg/L. Surface-water data collected during 2021 showed no measured constituents in the surface-water sample that exceeded any EPA MCL or SMCL. Soil samples collected from 2016 through 2021 showed all concentrations of As exceeded the EPA soil screening levels of 3 milligrams per kilogram (mg/kg) but did not exceed the Pennsylvania medium-specific concentrations for As of 61 mg/kg. Arsenic concentrations in 2021 ranged from 9.1 mg/kg to 12.9 mg/kg. The 2021 results for the ARMD Facility indicate no increases in concentrations of reported compounds compared to data from 2016 to 2020. The contained burn treatment facility for demilitarization of rocket motors during 2021 appears to have operated without elevating concentrations of target compounds compared to previous years.

Pennsylvania

Capturing the uncertainty of seismicity observations in earthquake rate estimates: Implications for probabilistic seismic hazard analysis and the USGS National Seismic Hazard Model

The rate of earthquakes in a region is a fundamental input to Probabilistic Seismic Hazard Analysis. We present a Monte Carlo method for computing that rate from seismicity catalogs while including a range of data and analysis uncertainties. This method is applied to regions for which the b value is assumed to be spatially invariant. Each region is broken down into epochs for which each epoch is estimated to have a uniform magnitude of completeness ( ⁠⁠ M c ). The distribution of earthquake rates for M ≥ M c is determined for each epoch by considering the Poisson likelihood of rates given the number of observed earthquakes with M ≥ M c ⁠ . We use a Monte Carlo process to include the uncertainty in b , ⁠ M c , and individual event magnitudes. The result for each epoch is the joint distribution of the Poisson rate of earthquakes with magnitudes larger than the minimum value used to calculate hazard ( ⁠⁠ M 1 ) and the Gutenberg–Richter b values, which control the extrapolation to other magnitudes. The rate for each region is either the duration‐weighted average over the epochs or, to better capture temporal variations, we also consider mixture models. The mixture models also provide an avenue to allow temporal variations in b values. To implement this joint distribution in a logic tree, we use the mean and 95% confidence branches, each of which is parameterized with an M ≥ M 1 rate and b value. We explore different ways of defining those branches, as well as non‐Gutenberg–Richter branches, and their impact on hazard estimates. The mean hazard, but not the fractiles, is robust with respect to these choices. To illustrate these new methods, we use synthetic data and catalogs from recent U.S. Geological Survey National Seismic Hazard Models for the Central and Eastern United States and for Puerto Rico and the U.S. Virgin Islands.

central and eastern United States, Puerto Rico, U.

The δ13C signature of dissolved organic and inorganic carbon reveals complex carbon transformations within a salt marsh

Coastal wetlands have high rates of atmospheric CO 2 uptake, which is subsequently respired back to the atmosphere, stored as organic matter within flooded, anoxic soils, or exported to the coastal ocean. Transformation of fixed carbon occurs through a variety of subsurface aerobic and anaerobic microbial processes, and results in a large inventory of dissolved carbon. Carbon source and the roles of aerobic respiration, sulfate reduction, and methane cycling were evaluated within salt marsh peat and the underlying sandy subterranean estuary. There is a large increase in dissolved inorganic carbon (DIC, 7,350 ± 3,900 μmol L −1 ), dissolved organic carbon (DOC, 1,040 ± 1,480 μmol L −1 ) and CH 4 (14.5 ± 33.3 μmol L −1 ) within the marsh porewaters compared to creek waters. Alkalinity production (5,730 ± 2,170 μeq L −1 ) and sulfate removal (1,810 ± 1,970 μmol L −1 ) indicate anaerobic respiration, however, relative contributions from the various decomposition pathways cannot be identified due to overlapping geochemical signatures. The δ 13 C of the DOC (−29.0 ± 3.7‰) and DIC (−11.2 ± 1.1‰) produced within the marsh differed from the bulk soil organic matter δ 13 C (−14.5 ± 0.2‰). We explore a variety of mechanisms that could result in co-occurring depleted δ 13 C-DOC and enriched δ 13 C-DIC compared to the bulk soil organic carbon pool and salt marsh vegetation, including selective mineralization, production of δ 13 C-depleted bacterial biomass, and methane-derived DOC. While important questions remain about carbon cycling pathways, we found evidence of a cryptic methane cycle. Alteration of the δ 13 C of carbon species complicates source attribution in solid and dissolved phases and careful consideration should be used when carbon is partitioned between in situ salt marsh production and external marine and terrestrial sources.

Massachusetts

Limited evidence of late Quaternary tectonic surface deformation in the eastern Tennessee seismic zone, USA

The ~300-km-long eastern Tennessee seismic zone (ETSZ), USA, is the second-most seismically active region east of the Rocky Mountains. Seismicity generally occurs below the Paleozoic fold-and-thrust belt within the Mesoproterozoic basement, at depths of 5–26 km, and earthquake magnitudes during the instrumental record have been moment magnitude ( M w )≤4.8. Evidence of surface deformation may not exist or be difficult to detect because of the vegetated and soil-mantled landscape, landslides, locally steep topography, anthropogenic landscape modification, or long, irregular recurrence intervals between surface-rupturing earthquakes. Despite the deep seismicity, analog models indicate that accumulation of strike-slip or oblique-slip displacement at depth could be expected to propagate upward through the Paleozoic section, producing a detectable surficial signal of distributed faulting. To identify potential surface deformation, we interrogated the landscape at different spatial scales. We evaluated morphotectonic and channel metrics, such as channel sinuosity and catchment-scale hypsometry. Additionally, we mapped possible fault-related topographic features on 1-m lidar. Finally, we integrated our observations with available bedrock and Quaternary surficial mapping and subsurface geophysical data. At a regional scale, most morphotectonic and channel metrics have a strong lithologic control. Within smaller regions of similar lithology, we observe changes in landscape metrics like channel sinuosity and catchment-scale hypsometry that spatially correlate with new lineaments identified in this study and previously mapped east–west Cenozoic faults. These faults have apparent left-lateral offsets, are optimally oriented to slip in the current stress field, and match kinematics from recent focal mechanisms, but do not clearly preserve evidence of late Pleistocene or Holocene tectonic surface deformation. Most newly mapped lineaments might be explained by either tectonic or non-tectonic origins, such as fluvial or karst processes. We also re-evaluated a previously described paleoseismic site and interpret that the exposure does not record evidence of late Pleistocene faulting but instead is explained by fluvial stratigraphy.

Tennessee

Navigating uncertainty and competing objectives: Spring chinook salmon recovery in the upper Willamette river

Globally, anadromous fish populations are threatened with extinction due to multiple factors, including river impoundments that block migration, widespread alteration of physical habitat, temperature, and flow regimes, commercial and recreational harvest, changes in biological communities, and long-term climate trends. In this synthesis, we describe how physical and biological factors, policy and law, and public resource allocation affect management of spring-run Chinook Salmon ( Oncorhynchus tshawytscha ) in the Upper Willamette River (UWR), Oregon, USA. Efforts to restore salmon populations often involve trade-offs, for example, water management decisions must account for flood control, agricultural and municipal water use, and management of other species. UWR Chinook Salmon recovery efforts are also governed by multiple laws, policies, and action agencies that in some cases have incongruent objectives. Competing and conflicting objectives, combined with uncertainty regarding the outcomes of proposed management actions, create significant challenges for decision makers. Resource limitations, regulatory constraints, and incongruent objectives have created challenges for managers in the UWR, but opportunities exist for improved adaptive management and collaboration, which could build trust and engagement among stakeholders and ultimately support the successful implementation of decision tools. A suite of decision support tools that have been used in the Willamette River basin and elsewhere across the range of Pacific salmon have the potential to enhance decision processes. These tools can be effective when decision makers and stakeholders commit to long-term, collaborative utilization of the tools for decision making, and when available resources and regulatory environments are conducive to implementation and adaptive refinement of both the decision-support tools and management plans. The general biological and institutional principles discussed for UWR Chinook Salmon in this work apply more generally to populations of anadromous fishes across their range, especially to populations in highly regulated river systems.

Oregon

Relating systematic molecular and textural properties of graptolite pyrolyzed via gold tube hydrous pyrolysis: Implications for thermal proxies in lower Paleozoic marine shales

A series of gold tube pyrolysis experiments (72 h, 300–550 °C, 50 MPa) conducted on a graptolite-rich lower Paleozoic marine shale generated pyrolysis residues for a comprehensive evaluation of the molecular and structural variability of three types of graptolite periderm. Organic petrology, Raman spectroscopy, and field emission scanning electron microscopy (FE-SEM) with energy dispersive spectroscopy (EDS) were combined to evaluate the thermal evolution process. The three types of graptolite periderm, namely granular, non-granular, and nodular graptolite, were analyzed by Raman spectroscopy wherein point measurements were obtained after the maceral was identified and the location verified by organic petrology. Distinct thermal evolution pathways among non-granular, granular, and nodular graptolite periderms were recorded. The evolution patterns of the Raman parameters, particularly D1 and G bands, highlight the differences in geochemical composition of the graptolite periderm types and the alteration of molecular structure with increasing thermal maturity. Raman parameters D1 (position of the D1 peak), G-FWHM (full width at half maximum of the G peak), and ratios D1-FWHM/G-FWHM (full width at half maximum of the D1 peak ratioed to G-FWHM) and A D1 /A G (ratio of D1 and G peak intensities) showed effectiveness in assessing thermal maturity. Bireflectance with increasing gold tube pyrolysis temperature followed a hierarchy: non-granular > granular > nodular, reflecting different molecular alignment intensities. Qualitative FE-SEM evaluation showed that fine-grained mineral inclusions (primarily Fe-sulfide as determined via EDS) were associated with the graptolite populations, with granular graptolite containing greater amounts of coarser-grained (e.g., ∼300–1400 nm) mineral inclusions relative to non-granular and nodular graptolite, which contain finer-grained (e.g., ∼100–200 nm) inclusions difficult to resolve with optical microscopy. These findings are investigated to highlight the mechanisms that drive organic matter evolution within graptolite during thermal maturation, as well as to explore some of the limitations of using spectroscopic parameters as thermal maturity proxies.

International Journal of Coal Geology

Assessing potential effects of oil and gas development activities on groundwater quality near and overlying the Elk Hills and North Coles Levee Oil Fields, San Joaquin Valley, California

Groundwater resources are utilized near areas of intensive oil and gas development in California’s San Joaquin Valley. In this study, we examined chemical and isotopic data to assess if thermogenic gas or saline water from oil producing formations have mixed with groundwater near the Elk Hills and North Coles Levee Oil Fields in the southwestern San Joaquin Valley. Major ion concentrations and stable isotope compositions were largely consistent with natural processes, including mixing of different recharge sources and water-rock interactions. Trace methane concentrations likely resulted from microbial rather than thermogenic sources. Trace concentrations of benzene and other dissolved hydrocarbons in three wells had uncertain sources that could occur naturally or be derived from oil and gas development activities or other anthropogenic sources. In the mid-1990s, two industrial supply wells had increasing Cl and B concentrations likely explained by mixing with up to 15 percent saline oil-field water injected for disposal in nearby injection disposal wells. Shallow groundwater along the western margin of Buena Vista Lake Bed had elevated Cl, B, and SO 4 concentrations that could be explained by accumulation of salts during natural wetting and drying cycles or, alternatively, legacy surface disposal of saline oil-field water in upgradient ephemeral drainages. This study showed that groundwater had relatively little evidence of thermogenic gas or saline water from oil and gas sources in most parts of the study area. However, the evidence for groundwater mixing with injected disposal water, and possibly legacy surface disposal water, demonstrates produced water management practices as a potential risk factor for groundwater-quality degradation near oil and gas fields. Additional studies in the San Joaquin Valley and elsewhere could improve understanding of such risks by assessing the locations, volumes, and types of produced water disposal practices used during the life of oil fields.

California

Oligocene–Miocene northward growth of the Tibetan Plateau: Insights from intermontane basins in the West Qinling Belt, NW China

Growth of the Tibetan Plateau, Earth’s broadest and highest elevation collisional system, shapes orographic barriers, reorganizes drainage networks, and influences surface erosion and sediment delivery, whose changes in space and provenance feed back to intracontinental tectonic processes. Studies of interior basins within the northern Tibetan Plateau provide new sediment accumulation, provenance, paleodrainage, and deformation timing data that enable a reconstruction of the far-field tectono-geomorphic evolution of the rising Tibetan Plateau. Along the northern plateau margin, topographic growth in the West Qinling Belt is inferred to have initiated in the Eocene, nearly coeval with the India-Asia collision, as well as in the late Miocene. However, geological knowledge about the intervening period remains at present enigmatic, and the kinematics and dynamics are uncertain. This study presents a multidisciplinary data set from the intermontane Anhua-Huicheng Basin (AHB; Gansu Province, China) to fill this gap. Magnetostratigraphic dating, regional mapping, and sedimentological analysis imply that contractional deformation and thrust-top basin systems formed within the West Qinling Belt in the Oligocene (not later than ca. 24 Ma). A combination of observations including paleocurrent changes, detrital zircon U-Pb age variations, and appearance of growth strata along the Anhua-Huicheng Basin reveal the rapid uplift of the West Qinling Belt at ca. 15 Ma. Sedimentation in the intermontane basins ended after the late Miocene (ca. 8 Ma), when the region experienced intrabasinal deformation, uplift, and erosion with the establishment of an external drainage system. Since the late Miocene, the growth of the West Qinling Belt reached a climax with the lack of substantial contractional deformation in Cenozoic sequences heralding the onset of the modern kinematic regime and attainment of high elevation. Observed transitions in the tectonostratigraphy and paleodrainage define different phases of deformation and plateau-wide shifts in stress reorganization, which led to the northward growth and later lateral expansion of the Tibetan Plateau.

GSA Bulletin

The eruptive behavior of distributed volcanism forming low shield edifices—A case study of Sentinel-Arlington volcanic field, U.S.A.

Distributed volcanic fields are present in various tectonic settings worldwide, and their characteristics reflect differing influences from magmatic and tectonic processes. In the southwestern United States alone, there are 37 Quaternary distributed volcanic fields. After the primary period of extensional tectonics in the southern Basin and Range 15–5 million years ago, the Sentinel-Arlington volcanic field developed in southwestern Arizona between 4 and 1 million years ago. The Sentinel-Arlington volcanic field consists primarily of low relief shield volcanoes, a type of distributed volcanism with poorly understood temporal evolution. The Sentinel-Arlington volcanic field is less than 200 kilometers (km) from the Colorado Plateau, Gulf of California, and southern San Andreas Fault system. This work identifies and examines controls on the emplacement of the Sentinel-Arlington volcanic field by documenting shallow and surficial structures as well as eruption characteristics and style through time. The Sentinel-Arlington volcanic field consists of 21 volcanoes with a total of 33 vents over an area of about 770 square kilometers (km 2 ). The prominence of low relief shield volcanoes may be explained by ascent of basaltic magmas through thin Basin and Range crust, without much crustal contamination, and low viscosities common to mafic compositions. Typical eruption characteristics involve the construction of low relief shield volcanoes followed by Strombolian fissure eruptions at the summits or near-summit medial areas that produce scoria lapilli, which may weld to form agglomerate. The total lifetime erupted volume of about 4.3 cubic kilometers (km 3 ) represents an average eruptive flux of approximately 2x10 -3 km 3 per thousand years (k.y.). This erupted volume is low relative to Neogene basaltic intraplate distributed volcanic fields worldwide, which typically range from 10 -3 to 1 km 3 k.y. -1 . Sentinel-Arlington volcanic field eruptions were likely triggered by intermittent rejuvenation of transient magmatic zones that exist in thinned crust. Instantaneous flux from point sources feeding the lava flows is estimated to be on the order of 10 -1 to 10 cubic meters per second.

Arizona

Distribution of ancient carbon in groundwater and soil gas from degradation of petroleum near the Red Hill Bulk Fuel Storage Facility, O‘ahu, Hawai‘i

The groundwater below the Red Hill Bulk Fuel Storage Facility (the facility) in Oʻahu, Hawaiʻi, contains fuel compounds from past spills. This study used carbon-14 analyses to distinguish fuel-derived carbon from background carbon, along with other biodegradation indicators, to address two goals: (1) determine the extent and migration direction of groundwater affected by residual fuel below the facility and (2) determine if residual fuel locations in the subsurface could be identified by analyzing soil gas at the surface above the facility. Groundwater from 19 wells was sampled between September 2022 and April 2023. Nonvolatile dissolved organic carbon (NVDOC) from a well presumed to be unaffected by past spills contained 38 percent ancient carbon indicating a natural source of ancient carbon in the subsurface. The NVDOC concentrations and ancient carbon percentages indicate fuel biodegradation products are likely present on the north and south of Red Hill with the greatest effects at well RHMW02 near the 2014 spill site. The NVDOC concentrations are almost three times higher than diesel range organic (DRO) concentrations in groundwater from the same sites. Major ion data indicate that iron reduction is an important biodegradation process. Soil probe samples and soil carbon traps were used to determine the carbon-14 content of soil carbon dioxide. Ancient carbon from fuel biodegradation was not detected at any soil probe or carbon trap site in contrast to a 2017 study which reported ancient carbon detections. A reanalysis of the 2017 results using a range of local values for background carbon-14 indicates that ancient carbon from fuel biodegradation was probably only detected in lower tunnel exhaust system samples and not in any soil carbon trap samples. Measurements of carbon dioxide efflux with a dynamic closed chamber were highly variable. The soil gas results indicate that soil gas measurements at land surface were not useful for detecting residual fuel at the facility.

Hawaii