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Ground Water Atlas of the United States: Segment 2, Arizona, Colorado, New Mexico, Utah

This chapter of the Ground Water Atlas of the United States describes the aquifers in Arizona, Colorado, New Mexico, and Utah. These four States, which comprise Segment 2 of this Atlas, are located in the Southwestern United States and extend from the rolling grasslands of the Great Plains on the east across the Rocky Mountains and Continental Divide to the desert basins of the Southwest. The 425,000-square-mile area ranges in altitude from about 14,400 feet above sea level in the Rocky Mountains of Colorado to about 100 feet near the lower Colorado River in southwestern Arizona. All the ground water in Segment 2 ultimately is derived from infiltration of precipitation, which varies considerably with the altitude and topography of the area. The Great Plains Physiographic Province of the Central United States extends into eastern Colorado and New Mexico (fig. 1), where flat to rolling prairie (fig. 2) with scattered hills and bluffs gradually rises westward to 5,000 to 7,000 feet above sea level and abruptly gives way to the frontal ranges of the Rocky Mountains in the Southern Rocky Mountain and Basin and Range Physiographic Provinces. West of the frontal ranges in Colorado and northern New Mexico are additional and higher mountain ranges generally oriented north-south but with many spurs and extensions oriented in other directions. The many ranges of the Rocky Mountains are separated by valleys and high mountain parks (fig. 3). Colorado contains about three-fourths of the Nation's land area above 10,000 feet and has 53 mountain peaks higher than 14,000 feet. Most of these high peaks are located near the Continental Divide (fig. 1), which extends approximately north-south through central Colorado and western New Mexico. The altitude of the divide decreases in southern New Mexico to less than 4,500 feet in a few areas. Farther westward, the mountains are less prevalent and are interspersed with broad structural basins. These basins and the broad valleys of the middle Colorado River and its tributaries form the irregular intermontane topography of the Colorado Plateaus Physiographic Province (fig. 4). Plateaus and high mesas are formed where the surface has been dissected by rugged canyons carved by the Colorado River and its tributaries (fig. 5). The largest of these canyons-the Grand Canyon-extends about 220 miles southwestward from the mouth of the Little Colorado River in Arizona and ranges from 4 to 18 miles in width and from 2,700 to 5,700 feet in depth below the rim. Small mountain ranges and intervening broad desert valleys of the Basin and Range Physiographic Province are prevalent to the west and south of the Colorado Plateaus in western Utah, southern Arizona, and southern New Mexico (fig. 1). These mountain ranges generally protrude 3,000 to 6,000 feet above the surrounding valley floor (fig. 6) and commonly extend from 20 to 50 miles in a north or northwesterly direction. Small parts of the Middle Rocky Mountains and Wyoming Basin Physiographic Provinces extend into northwestern Colorado and northeastern Utah (fig. 1). The topography, geology, and hydrology of the two areas are described in Chapter 1 of this Atlas. Four of the Nation's major river systems have headwaters in the mountainous areas of Segment 2. The South Platte River of the Missouri River system drains the eastern slope of northern Colorado; the Arkansas River and its tributary, the Canadian River, drain southeastern Colorado and northeastern New Mexico; the Rio Grande and its tributary, the Pecos River, drain south-central Colorado and central New Mexico; and the Colorado River and its tributaries drain Arizona, eastern Utah, Northwestern New Mexico, and western Colorado (fig. 1). Western Utah is drained by numerous streams that terminate in local desert basins, the Great Salt Lake, or other local lakes and reservoirs. Because the Great Salt Lake lies in the Great Basin, which is the largest closed basin in North America, it has no outlet to the sea. The salinity of the lake water is about 20 percent or about 6 times the salinity of seawater. Most of Segment 2 is sparsely populated. The average population density of counties is less than 8 persons per square mile in about 65 percent of the four-State area (fig. 7). Population densities range from less than 0.5 person per square mile in a few rural counties to more than 4 ,000 persons per square mile in populous urban areas. The 1990 population of the four States was about 10 million; almost 70 percent of this population was in Arizona and Colorado. Most land in Segment 2 is undeveloped forest grassland, or desert shrubland, much of which is used for livestock grazing. Land used for production of commercial crops primarily is in eastern Colorado and eastern New Mexico.

Arizona, Colorado, New Mexico, Utah

Vulnerability of ground water to contamination, northern Bexar County, Texas

The Trinity aquifer, composed of Lower Cretaceous carbonate rocks, largely controls the ground-water hydrology in the study area of northern Bexar County, Texas. Discharge from the Trinity aquifer recharges the downgradient, hydraulically connected Edwards aquifer one of the most permeable and productive aquifers in the Nation and the sole source of water for more than a million people in south-central Texas. The unconfined, karstic outcrop of the Edwards aquifer makes it particularly vulnerable to contamination resulting from urbanization that is spreading rapidly northward across an "environmentally sensitive" recharge zone of the Edwards aquifer and its upgradient "catchment area," composed mostly of the less permeable Trinity aquifer. A better understanding of the Trinity aquifer is needed to evaluate water-management decisions affecting the quality of water in both the Trinity and Edwards aquifers. A study was made, therefore, in cooperation with the San Antonio Water System to assess northern Bexar County's vulnerability to ground-water contamination. The vulnerability of ground water to contamination in this area varies with the effects of five categories of natural features (hydrogeologic units, faults, caves and (or) sinkholes, slopes, and soils) that occur on the outcrop and in the shallow subcrop of the Glen Rose Limestone. Where faults affect the rates of recharge or discharge or the patterns of ground-water flow in the Glen Rose Limestone, they likewise affect the risk of water-quality degradation. Caves and sinkholes generally increase the vulnerability of ground water to contamination, especially where their occurrences are concentrated. The slope of land surface can affect the vulnerability of ground water by controlling where and how long a potential contaminant remains on the surface. Disregarding the exception of steep slopes which are assumed to have no soil cover the greater the slope, the less the risk of ground-water contamination. Because most soils in the study area are uniformly thin, they have only minimal effect on the vulnerability of ground water to contamination. The results of hydrogeologic mapping during the present study divide the outcrop of the Glen Rose Limestone into five mappable intervals, labeled (youngest to oldest) A through E. Of these intervals, only the middle (C) and the lowermost (E) generally provide appreciable permeability. The vulnerability assessment provided herein was determined by combining the presumed effects of selected natural features (with individual vulnerability ratings ranging from 0 through 35) using a grid-based, multilayer system of digital datasets and geographic information system analysis. The resulting vulnerability map comprises composite vulnerability ratings that range from 26 through 104. The relatively less vulnerable areas those containing no faults, sinkholes, or caves occupy about 92 percent of the study area. The most vulnerable areas are those containing both a fault and one or more caves. The distribution of the most vulnerable areas which trend from southwest to northeast, roughly parallel to the Balcones fault zone occur mainly where faults intersect caves.

Texas

Hydrogeology, hydrologic budget, and water chemistry of the Medina Lake area, Texas

A three-phase study of the Medina Lake area in Texas was done to assess the hydrogeology and hydrology of Medina and Diversion Lakes combined (the lake system) and to determine what fraction of seepage losses from the lake system might enter the regional ground-water-flow system of the Edwards and (or) Trinity aquifers. Phase 1 consisted of revising the geologic framework for the Medina Lake area. Results of field mapping show that the upper member of the Glen Rose Limestone underlies Medina Lake and the intervening stream channel from the outflow of Medina Lake to the midpoint of Diversion Lake, where the Diversion Lake fault intersects Diversion Lake. A thin sequence of strata consisting primarily of the basal nodular and dolomitic members of the Kainer Formation of the Edwards Group, is present in the southern part of the study area. On the southern side of Medina Lake, the contact between the upper member of the Glen Rose Limestone and the basal nodular member is approximately 1,000 feet above mean sea level, and the contact between the basal nodular member and the dolomitic member is approximately 1,050 feet above mean sea level. The most porous and permeable part of the basal nodular member is about 1,045 feet above mean sea level. At these altitudes, Medina Lake is in hydrologic connection with rocks in the Edwards aquifer recharge zone, and Medina Lake appears to lose more water to the ground-water system along this bedding plane contact. Hydrologic budgets calculated during phase 2 for Medina Lake, Diversion Lake, and Medina/Diversion Lakes combined indicate that: (1) losses from Medina and Diversion Lakes can be quantified; (2) a portion of those losses are entering the Edwards aquifer; and (3) losses to the Trinity aquifer in the Medina Lake area are minimal and within the error of the hydrologic budgets. Hydrologic budgets based on streamflow, precipitation, evaporation, and change in lake storage were used to quantify losses (recharge) to the ground-water system from Medina Lake, Diversion Lake, and Medina/Diversion Lakes combined during October 1995–September 1996. Water losses from Medina Lake to the Edwards/Trinity aquifers ranged from -14.0 to 135 acre-feet per day; Diversion Lake ranged from -1.2 to 93.1 acre-feet per day; and Medina/Diversion Lakes combined ranged from 36.1 to 119 acre-feet per day. Monthly average recharge during December 1995–July 1996 was estimated using an alternative method developed during this study (current study method) and compared to monthly average recharge during December 1995–July 1996 estimated using the existing USGS method and the Trans-Texas method. Recharge to the Edwards aquifer estimated using the current study method was about 69 and 73 percent of the recharge estimated using the USGS and Trans-Texas methods, respectively. The USGS and Trans-Texas methods overestimated recharge from Medina Lake compared to the recharge estimated with the current study method when Medina Lake stage was between about 1,027 and 1,032 feet above mean sea level and underestimated recharge from Medina Lake when lake stage was between about 1,036 and 1,045 feet above mean sea level. The USGS and Trans-Texas methods underestimated recharge from Diversion Lake compared to the recharge estimated with the current study method when Diversion Lake stage was greater than 913 feet above mean sea level and overestimated recharge from Diversion Lake when lake stage was less than 913 feet above mean sea level. The water quality of Medina Lake and Medina River and in selected wells and springs in the Edwards and Trinity aquifers was characterized during phase 3 of the study. Environmental isotope analyses and geochemical modeling also were used to determine where water losses from the lake system might be entering the ground-water-flow system. Isotopic ratios of deuterium, oxygen, and strontium were analyzed in selected surface-water, lake-water, and ground-water samples to trace the isotopic “signature” of the lake water as it mixes with the ground water and to determine the fraction of lake water and ground water in selected Edwards aquifer wells. Isotopic data and geochemical modeling were used to show that lake water is moving into the Edwards aquifer in two fault blocks in the eastern Medina storage unit. One fault block is bounded on the north by the Vandenburg School fault and on the south by the Haby Crossing fault, and the second fault block is bounded on the north by the Diversion Lake fault and on the south by the Haby Crossing fault. In selected Edwards aquifer wells located southwest of Medina Lake and west of Diversion Lake, the proportion of lake water ranged from about 10 to 45 percent. Geochemical modeling using NETPATH confirms the degree of mixing between lake water and aquifer water shown by the isotopes.

Texas

Wind River subbasin restoration: Annual report of U.S. Geological Survey activities January 2014 through December 2014

Executive Summary The Wind River subbasin in southwest Washington State provides habitat for a population of wild Lower Columbia River steelhead Oncorhynchus mykiss , which are listed as threatened under the Endangered Species Act. No hatchery steelhead have been planted in the Wind River subbasin since 1994, and hatchery adults are estimated to be less than one percent of adults in any year (Thomas Buehrens, Washington Department of Fish and Wildlife, personal communication). Numerous restoration actions have been implemented in the subbasin, including the removal of Hemlock Dam on Trout Creek in 2009. We used Passive Integrated Transponder (PIT) tagging and a series of instream PIT-tag interrogation systems (PTIS) to investigate life-histories, populations, and efficacy of habitat restoration actions for these steelhead. Data from our study, and companion work by Washington Department of Fish and Wildlife (WDFW), will contribute to Bonneville Power Administration’s (BPA) Research Monitoring and Evaluation (RM&E) Program Strategy of Fish Population Status Monitoring ( www.cbfish.org/ProgramStrategy.mvc/ViewProgramStrategySummary/1 ), specifically the sub-strategies of: 1) Assessing the Status and Trends of Diversity of Natural Origin Fish Populations and to Uncertainties Research regarding differing life histories of a wild steelhead population, 2) Assessing the Status and Trend of Adult Natural Origin Fish Populations, and 3) Monitoring and Evaluating the Effectiveness of Tributary Habitat Actions Relative to Environmental, Physical, or Biological Performance Objectives. During summer 2014, we PIT-tagged steelhead parr in headwater areas of the Wind River subbasin to investigate life-history diversity, specifically to compare fate of those juvenile steelhead that move downstream prior to smolting with those that remain in their natal areas until smolting. A series of instream PTISs monitored movement of these fish. We added a new multi-antenna PTIS on Trout Creek and made improvements to two of our smaller tributary PTISs during 2014. Detections at the instream PTISs showed trends of parr emigration during summer and fall, in addition to the expected movement of parr and smolts in spring. Long-term monitoring of PIT-tagged fish will provide information on contribution of various life-history strategies to smolt production and adult returns, as well as helping to identify factors influencing parr movement. Movements of PIT-tagged adult steelhead were tracked with our instream PTISs. These data will contribute to a better understanding of timing and distribution of spawning by this population of wild steelhead within the Wind River subbasin. Additionally, these data have provided information on timing of adult movements to various parts of the watershed, which is allowing us to assess adult use of tributary watersheds within the Wind River subbasin. These data are contributing to evaluating steelhead response to the removal of Hemlock Dam from Trout Creek. Hemlock Dam, which was located at rkm 2.0 of Trout Creek, was removed in summer 2009 and had contributed to hydrologic impairment of Trout Creek and potentially caused some deterrent to upstream adult steelhead migration. Evaluating restoration efforts is of interest to many managers and agencies so that funding and time are allocated for best results. The evaluation of various life-histories of Lower Columbia River steelhead within the Wind River subbasin provides information to better track populations, and more effectively direct habitat restoration and water allocation planning. Increasingly detailed Viable Salmonid Population information (Crawford and Rumsey 2009), such as that provided by PIT-tagging and instream PTISs networks like those we build and operate in the Wind River subbasin, provide data to better inform policy and management, as life-history strategies and production bottlenecks are identified and understood.

Washington

Application of multiple isotopic and geochemical tracers for investigation of recharge, salinization, and residence time of water in the Souss-Massa aquifer, southwest of Morocco

Groundwater and surface water in Souss-Massa basin in the west-southern part of Morocco is characterized by a large variation in salinity, up to levels of 37 g L-1. The high salinity coupled with groundwater level decline pose serious problems for current irrigation and domestic water supplies as well as future exploitation. A combined hydrogeologic and isotopic investigation using several chemical and isotopic tracers such as Br/Cl, ??18O, ??2H, 3H, 87Sr/86Sr, ??11B, and 14C was carried out in order to determine the sources of water recharge to the aquifer, the origin of salinity, and the residence time of water. Stable isotope, 3H and 14C data indicate that the high Atlas mountains in the northern margin of the Souss-Massa basin with high rainfall and low ??18O and ??2H values (-6 to -8??? and -36 to -50???) is currently constitute the major source of recharge to the Souss-Massa shallow aquifer, particularly along the eastern part of the basin. Localized stable isotope enrichments offset meteoric isotopic signature and are associated with high nitrate concentrations, which infer water recycling via water agricultural return flows. The 3H and 14C data suggest that the residence time of water in the western part of the basin is in the order of several thousands of years; hence old water is mined, particularly in the coastal areas. The multiple isotope analyses and chemical tracing of groundwater from the basin reveal that seawater intrusion is just one of multiple salinity sources that affect the quality of groundwater in the Souss-Massa aquifer. We differentiate between modern seawater intrusion, salinization by remnants of seawater entrapped in the middle Souss plains, recharge of nitrate-rich agricultural return flow, and dissolution of evaporate rocks (gypsum and halite minerals) along the outcrops of the high Atlas mountains. The data generated in this study provide the framework for a comprehensive management plan in which water exploitation should shift toward the eastern part of the basin where current recharge occurs with young and high quality groundwater. In contrast, we argued that the heavily exploited aquifer along the coastal areas is more vulnerable given the relatively longer residence time of the water and salinization processes in this part of the aquifer. ?? 2008 Elsevier B.V. All rights reserved.

Journal of Hydrology

222Rn transport in a fractured crystalline rock aquifer: Results from numerical simulations

Dissolved 222Rn concentrations in ground water from a small wellfield underlain by fractured Middle Proterozoic Pikes Peak Granite southwest of Denver, Colorado range from 124 to 840 kBq m-3 (3360-22700 pCi L-1). Numerical simulations of flow and transport between two wells show that differences in equivalent hydraulic aperture of transmissive fractures, assuming a simplified two-fracture system and the parallel-plate model, can account for the different 222Rn concentrations in each well under steady-state conditions. Transient flow and transport simulations show that 222Rn concentrations along the fracture profile are influenced by 222Rn concentrations in the adjoining fracture and depend on boundary conditions, proximity of the pumping well to the fracture intersection, transmissivity of the conductive fractures, and pumping rate. Non-homogeneous distribution (point sources) of 222Rn parent radionuclides, uranium and 226Ra, can strongly perturb the dissolved 222Rn concentrations in a fracture system. Without detailed information on the geometry and hydraulic properties of the connected fracture system, it may be impossible to distinguish the influence of factors controlling 222Rn distribution or to determine location of 222Rn point sources in the field in areas where ground water exhibits moderate 222Rn concentrations. Flow and transport simulations of a hypothetical multifracture system consisting of ten connected fractures, each 10 m in length with fracture apertures ranging from 0.1 to 1.0 mm, show that 222Rn concentrations at the pumping well can vary significantly over time. Assuming parallel-plate flow, transmissivities of the hypothetical system vary over four orders of magnitude because transmissivity varies with the cube of fracture aperture. The extreme hydraulic heterogeneity of the simple hypothetical system leads to widely ranging 222Rn values, even assuming homogeneous distribution of uranium and 226Ra along fracture walls. Consequently, it is concluded that 222Rn concentrations vary, not only with the geometric and stress factors noted above, but also according to local fracture aperture distribution, local groundwater residence time, and flux of 222Rn from parent radionuclides along fracture walls.

Journal of Hydrology

Wind River Subbasin Restoration, annual report of U.S. Geological Survey activities: Parr monitoring and instream passive integrated transponder detection, January 1, 2015 – December 31, 2015

We used Passive Integrated Transponder (PIT)-tagging and a series of instream PIT-tag interrogation systems (PTIS) to investigate life-histories, populations, and efficacy of habitat restoration actions for steelhead Oncorhynchus mykiss in the Wind River subbasin, WA. Our tagging focused on parr in headwater areas of the subbasin and our PTISs provide information on movement of these parr, which is primarily, but not exclusively downstream. The PTISs also provide data on life-history aspects of other steelhead life-stages. The Wind River subbasin in southwest Washington State provides habitat for a population of wild Lower Columbia River steelhead and is an excellent watershed for long-term studies of population dynamics and responses to restoration of this wild population. Much data on steelhead population metrics have been gathered from the Wind River providing information on habitat restoration actions and ongoing research into steelhead life histories. Additionally, the Wind River is an excellent control watershed of an exclusivly wild steelhead population to which basins with hatchery programs can compare. No hatchery steelhead have been planted in the Wind River subbasin since 1994, and hatchery adults are estimated to be less than one percent of adults in any year (pers comm. Thomas Buehrens, Washington Department of Fish and Wildlife). Numerous restoration actions have been implemented in the subbasin, including the removal of Hemlock Dam on Trout Creek in 2009. Data from our study, and companion work by Washington Department of Fish and Wildlife (WDFW), will contribute to Bonneville Power Administration’s (BPA) Research Monitoring and Evaluation (RM&E) Program Strategy of Fish Population Status Monitoring (www.cbfish.org/ProgramStrategy.mvc/ViewProgramStrategySummary/1), specifically the sub-strategies of: 1) Assessing the Status and Trends of Diversity of Natural Origin Fish Populations and to uncertainties research regarding differing life histories of a wild steelhead population, 2) Assessing the Status and Trend of Adult Natural Origin Fish Populations, and 3) Monitoring and Evaluating the Effectiveness of Tributary Habitat Actions Relative to Environmental, Physical, or Biological Performance Objectives. During summer 2015, we sampled and PIT-tagged age-0 and age-1 steelhead parr in headwater areas of the Wind River subbasin to characterize population traits and investigate variable life-histories, including growth and parr movement downstream prior to smolting. Throughout the year, we maintained a series of instream PTISs to monitor movement of tagged steelhead parr, smolts, and adults. Detections at the instream PTISs showed trends of parr 8 emigration during summer and fall, in addition to the expected movement of parr and smolts in spring. These data are increasing our understanding of varied life histories of juvenile steelhead; paired with other steelhead population work in the subbasin we hope to better understand the factors influencing parr movements. Monitoring of PIT-tagged fish over multiple years is providing information on contribution of various life-history strategies to smolt production and adult returns, as well as identifying factors influencing parr movement. Movements of PIT-tagged adult steelhead were also monitored with our instream PTISs. These data have provided information on timing of adult movements to various parts of the watershed, which allows us to assess adult returns to tributary watersheds within the Wind River subbasin. Determination of adult use of tributary watersheds is providing data to contribute to evaluation of the efficacy of the removal of Hemlock Dam on Trout Creek. Hemlock Dam, located at rkm 2.0 of Trout Creek was removed in summer 2009 and had contributed to hydrologic impairment of Trout Creek. Evaluating restoration efforts is of interest to many managers and agencies so that funding and time are allocated for best results. The evaluation of various life-his

Washington

Sample descriptions and geophysical logs for cored well BP-3-USGS, Great Sand Dunes National Park and Preserve, Alamosa County, Colorado

The BP-3-USGS well was drilled at the southwestern corner of Great Sand Dunes National Park in the San Luis Valley, south-central Colorado, 68 feet (ft, 20.7 meters [m]) southwest of the National Park Service’s boundary-piezometer (BP) well 3. BP-3-USGS is located at latitude 37°43ʹ18.06ʺN. and longitude 105°43ʹ39.30ʺW., at an elevation of 7,549 ft (2,301 m). The well was drilled through poorly consolidated sediments to a depth of 326 ft (99.4 m) in September 2009. Water began flowing from the well after penetrating a clay-rich layer that was first intercepted at a depth of 119 ft (36.3 m). The base of this layer, at an elevation of 7,415 ft (2,260 m) above sea level, likely marks the top of a regional confined aquifer recognized throughout much of the San Luis Valley. Approximately 69 ft (21 m) of core was recovered (about 21 percent), almost exclusively from clay-rich zones. Coarser grained fractions were collected from mud extruded from the core barrel or captured from upwelling drilling fluids. Natural gamma-ray, full waveform sonic, density, neutron, resistivity, spontaneous potential, and induction logs were acquired. The well is now plugged and abandoned. This report presents lithologic descriptions from the well samples and core, along with a compilation and basic data processing of the geophysical logs. The succession of sediments in the well can be generalized into three lithologic packages: (1) mostly sand from the surface to about 77 ft (23.5 m) depth; (2) interbedded sand, silt, and clay, decreasing in overall grain size downward, from 77 to 232 ft (23.5 to 70.7 m) depth; and (3) layers of massive clay alternating with layers of fine sand to silt from 232 to 326 ft (70.7 to 99.4 m), the total depth of the well. The topmost clay layers of the deepest package have a blue tint, prompting a correlation with the “blue clay” of the San Luis Valley that is commonly considered as the top of the confined aquifer. However, a confining clay was intercepted 113 ft (34.4 m) higher than the blue clay in BP-3-USGS. Most of the geophysical logs have good correspondence to the lithologic variations in the well. Exceptions are the gamma-ray log, which is likely affected by naturally occurring radiation from abundant volcanic detritus, and one interval within the deepest lithologic package, which appears to be abnormally electrically conductive. Resistivity logs and variations in sand versus clay content within the well are consistent with electrical resistivity models derived from time-domain electromagnetic geophysical surveys for the area. In particular, the topmost blue clay corresponds to a strong electrical conductor that is prominent in the electromagnetic geophysical data throughout the park and vicinity. BP-3-USGS was sited to test hypotheses developed from geophysical studies and to answer questions about the history and evolution of Pliocene and Pleistocene Lake Alamosa, which is represented by lacustrine deposits sampled by the well. The findings reported here represent a basis from which future studies can answer these questions and address other important scientific questions in the San Luis Valley regarding geologic history and climate change, groundwater hydrology, and geophysical interpretation.

Colorado

Groundwater and surface-water interactions near White Bear Lake, Minnesota, through 2011

The U.S. Geological Survey, in cooperation with the White Bear Lake Conservation District, the Minnesota Pollution Control Agency, the Minnesota Department of Natural Resources, and other State, county, municipal, and regional planning agencies, watershed organizations, and private organizations, conducted a study to characterize groundwater and surface-water interactions near White Bear Lake through 2011. During 2010 and 2011, White Bear Lake and other lakes in the northeastern part of the Twin Cities Metropolitan Area were at historically low levels. Previous periods of lower water levels in White Bear Lake correlate with periods of lower precipitation; however, recent urban expansion and increased pumping from the Prairie du Chien-Jordan aquifer have raised the question of whether a decline in precipitation is the primary cause for the recent water-level decline in White Bear Lake. Understanding and quantifying the amount of groundwater inflow to a lake and water discharge from a lake to aquifers is commonly difficult but is important in the management of lake levels. Three methods were used in the study to assess groundwater and surface-water interactions on White Bear Lake: (1) a historical assessment (1978-2011) of levels in White Bear Lake, local groundwater levels, and their relation to historical precipitation and groundwater withdrawals in the White Bear Lake area; (2) recent (2010-11) hydrologic and water-quality data collected from White Bear Lake, other lakes, and wells; and (3) water-balance assessments for White Bear Lake in March and August 2011. An analysis of covariance between average annual lake-level change and annual precipitation indicated the relation between the two variables was significantly different from 2003 through 2011 compared with 1978 through 2002, requiring an average of 4 more inches of precipitation per year to maintain the lake level. This shift in the linear relation between annual lake-level change and annual precipitation indicated the net effect of the non-precipitation terms on the water balance has changed relative to precipitation. The average amount of precipitation required each year to maintain the lake level has increased from 33 inches per year during 1978-2002 to 37 inches per year during 2003-11. The combination of lower precipitation and an increase in groundwater withdrawals can explain the change in the lake-level response to precipitation. Annual and summer groundwater withdrawals from the Prairie du Chien-Jordan aquifer have more than doubled from 1980 through 2010. Results from a regression model constructed with annual lake-level change, annual precipitation minus evaporation, and annual volume of groundwater withdrawn from the Prairie du Chien-Jordan aquifer indicated groundwater withdrawals had a greater effect than precipitation minus evaporation on water levels in the White Bear Lake area for all years since 2003. The recent (2003-11) decline in White Bear Lake reflects the declining water levels in the Prairie du Chien-Jordan aquifer; increases in groundwater withdrawals from this aquifer are a likely cause for declines in groundwater levels and lake levels. Synoptic, static groundwater-level and lake-level measurements in March/April and August 2011 indicated groundwater was potentially flowing into White Bear Lake from glacial aquifers to the northeast and south, and lake water was potentially discharging from White Bear Lake to the underlying glacial and Prairie du Chien-Jordan aquifers and glacial aquifers to the northwest. Groundwater levels in the Prairie du Chien-Jordan aquifer below White Bear Lake are approximately 0 to 19 feet lower than surface-water levels in the lake, indicating groundwater from the aquifer likely does not flow into White Bear Lake, but lake water may discharge into the aquifer. Groundwater levels from March/April to August 2011 declined more than 10 feet in the Prairie du Chien-Jordan aquifer south of White Bear Lake and to the north in Hugo, Minnesota. Water-quality analyses of pore water from nearshore lake-sediment and well-water samples, seepage-meter measurements, and hydraulic-head differences measured in White Bear Lake also indicated groundwater was potentially flowing into White Bear Lake from shallow glacial aquifers to the east and south. Negative temperature anomalies determined in shallow waters in the water-quality survey conducted in White Bear Lake indicated several shallow-water areas where groundwater may be flowing into the lake from glacial aquifers below the lake. Cool lake-sediment temperatures (less than 18 degrees Celsius) were measured in eight areas along the northeast, east, south, and southwest shores of White Bear Lake, indicating potential areas where groundwater may flow into the lake. Stable isotope analyses of well-water, precipitation, and lake-water samples indicated wells downgradient from White Bear Lake screened in the glacial buried aquifer or open to the Prairie du Chien-Jordan aquifer receive a mixture of surface water and groundwater; the largest surface-water contributions are in wells closer to White Bear Lake. A wide range in oxygen-18/oxygen-16 and deuterium/protium ratios was measured in well-water samples, indicating different sources of water are supplying water to the wells. Well water with oxygen-18/oxygen-16 and deuterium/protium ratios that plot close to the meteoric water line consisted mostly of groundwater because deuterium/protium ratios for most groundwater usually are similar to ratios for rainwater and snow, plotting close to meteoric water lines. Well water with oxygen-18/oxygen-16 and deuterium/protium ratios that plot between the meteoric water line and ratios for the surface-water samples from White Bear Lake consists of a mixture of surface water and groundwater; the percentage of each source varies relative to its ratios. White Bear Lake is the likely source of the surface water to the wells that have a mixture of surface water and groundwater because (1) it is the only large, deep lake near these wells; (2) these wells are near and downgradient from White Bear Lake; and (3) these wells obtain their water from relatively deep depths, and White Bear Lake is the deepest lake in that area. The percentages of surface-water contribution to the three wells screened in the glacial buried aquifer receiving surface water were 16, 48, and 83 percent. The percentages of surface-water contribution ranged from 5 to 79 percent for the five wells open to the Prairie du Chien-Jordan aquifer receiving surface water; wells closest to White Bear Lake had the largest percentages of surface-water contribution. Water-balance analysis of White Bear Lake in March and August 2011 indicated a potential discharge of 2.8 and 4.5 inches per month, respectively, over the area of the lake from the lake to local aquifers. Most of the sediments from a 12.4-foot lake core collected at the deepest part of White Bear Lake consisted of silts, sands, and gravels likely slumped from shallower waters, with a very low amount of low-permeability, organic material.

Minnesota

Geology, hydrology, and water quality in the Fresno area, California

The Fresno area comprises about 1.400 square miles lying west of the foothills of the Sierra Nevada and east of the trough of the San Joaquin Valley. The rainfall averages less than 10 inches per year causing agricultural development to depend mainly on surface-water deliveries and ground-water pumpage. Surface-water deliveries and ground-water pumpage, however, vary considerably from year to year. For example, in agricultural year 1958 (April 1, 1958-March 31, 1959) surface-water deliveries were about 1,340,000 acre-feet and agricultural ground-water pumpage was about 1,740,000 acre-feet, but in agricultural year 1960 deliveries were only about 560,000 acre-feet and pumpage was about 2,520,000 acre-feet. Alluvial fans are the dominant geomorphic features in the area. Small alluvial fans have been formed near the foothills by the deposits from the numerous intermittent streams that lie both north and south of the Kings River. Thicker and much more extensive alluvial fans have been formed under most of the area by deposits from the San Joaquin and Kings Rivers. Geologic units in the area consist of consolidated rocks and unconsolidated deposits. In turn, consolidated rocks consist of basement complex of pre-Tertiary age and marine and continental sedimentary rocks of Cretaceous and Tertiary age. Unconsolidated deposits are of both Tertiary and Quaternary age. Most of the geologic units dip gently southwestward approximately paralleling the back slope of the Sierra Nevada. Although some of these geologic units are faulted, especially in the deep subsurface, faulting has not affected the occurrence and movement of fresh ground water. The basement complex crops out along the eastern border of the area and yields only small amounts of water to wells; the marine and continental sedimentary rocks do not crop out in the area and do not yield any water to wells. The unconsolidated deposits are divided into an older series of Tertiary and Quaternary age, and a younger series of Quaternary age. The continental deposits of Tertiary and Quaternary age crop out beneath the extreme southeastern part of the area and yield small amounts of water to wells, and the deposits of Quaternary age crop out over most of the area and yield more than 90 percent of the water pumped from wells. The deposits of Quaternary age in turn are divided into older alluvium, lacustrine and marsh deposits, younger alluvium, flood-basin deposits. and sand dunes. The older alluvium is by far the most important aquifer in the Fresno area. It consists of intercalated lenses of clay, silt, silty and sandy clay, clayey and silty sand, sand, gravel, cobbles, and boulders, and in general it is fine grained near the trough of the valley and beneath the alluvial fans of intermittent streams. In the older alluvium, yields to wells range from less than 20 gpm (gallons per minute) to more than 3,000 gpm. The lacustrine and marsh deposits occur only in the subsurface in the western part of the area. Consisting mostly of silt and clay, they are virtually impermeable and thus restrict the vertical movement of water. These deposits from oldest to youngest are designated the E-clay, the C-clay, and the A-clay. The E-clay is the thickest and most extensive of all the lacustrine and marsh deposits. Because the clays tend to confine ground water in the Fresno area, five water bodies are recognized. These are the unconfined water body, the shallow water body, the confined water body below the A-clay, the confined water body below the C-clay, and the confined water body below the E-clay. The unconfined water body underlies most of the Fresno area. The shallow and confined water bodies underlie parts of the extreme western part of the area. There, heads in successively underlying water bodies are less than those in overlying water bodies, indicating that some ground water moves slowly downward through the clays. From agricultural years 1957 to 1962, outflow in the area exceeded inflow. As a result, for this period, the Fresno area had a net deficit of about 2,890,000 acre-feet. This deficit was made up for mostly by a decline in ground water stored. Water levels in all water bodies have been declining over the years, yet when streamflow and canal deliveries are large they show a general rise. The general movement of ground water in the Fresno area is toward the southwest, although pumping depressions near Fresno and near the western part of the area, cause ground water to move northward, southward, and westward toward them.

California

Wind River Subbasin Restoration, Annual report of U.S. Geological Survey activities, January 2016 through December 2016

We used Passive Integrated Transponder (PIT)-tagging and a series of instream PIT-tag interrogation systems (PTISs) to investigate life-histories, populations, and efficacy of habitat restoration actions for steelhead Oncorhynchus mykiss in the Wind River subbasin, WA. Our tagging focused on parr in headwaters areas of the subbasin and our instream readers provided information on movement of these parr and other life-stages of tagged steelhead. The Wind River subbasin in southwest Washington State provides habitat for a population of wild Lower Columbia River steelhead and is an excellent watershed for long-term studies of population dynamics and responses to restoration of this wild population. No hatchery steelhead have been planted in the Wind River subbasin since 1994, and hatchery adults are estimated to be less than one percent of adults in any year (pers comm. Thomas Buehrens, Washington Department of Fish and Wildlife). Numerous restoration actions have been implemented in the subbasin, including the removal of Hemlock Dam on Trout Creek in 2009. Data from our study, and companion work by Washington Department of Fish and Wildlife (WDFW), will contribute to Bonneville Power Administration’s (BPA) Research Monitoring and Evaluation (RM&E) Program Strategy of Fish Population Status Monitoring (www.cbfish.org/ProgramStrategy.mvc/ViewProgramStrategySummary/1), specifically the substrategies of: 1) Assessing the Status and Trends of Diversity of Natural Origin Fish Populations and to Uncertainties Research regarding differing life histories of a wild steelhead population, 2) Assessing the Status and Trend of Adult Natural Origin Fish Populations, and 3) Monitoring and Evaluating the Effectiveness of Tributary Habitat Actions Relative to Environmental, Physical, or Biological Performance Objectives. During summer 2016, we sampled and PIT-tagged age-0 and age-1 steelhead parr in headwater areas of the Wind River subbasin to characterize population traits and investigate variable life-histories, including growth and parr movement downstream prior to smolting. Repeat sampling and smolt traps provide opportunities for recapture, and instream PTISs and Columbia River infrastructure provide opportunity for detection of PIT-tagged fish. Throughout the year, we maintained a series of instream PTISs to monitor movement of tagged steelhead parr, smolts, and adults. During 2016, we repaired or replaced much of our instream PTIS infrastructure that had been damaged or destroyed during a large flood event in December 2015. This included moving our upper Wind River detection site (WRU) about a kilometer downstream to a location we hope to be less susceptible to damage in high flows and that will allow grid power connection for more reliable winter operations. Detections at the instream PTISs showed trends of parr emigration during summer and fall, in addition to the expected movement of parr and smolts in spring. These data are increasing our understanding of varied life histories of juvenile steelhead; paired with other steelhead population work in the subbasin we hope to begin to understand some of the factors which may influence parr movements. Long-term monitoring of PIT-tagged fish over multiple years is providing information on contribution of various life-history strategies to smolt production and adult returns, as well as helping to identify factors influencing parr movement. Movements of PIT-tagged adult steelhead were also tracked with our instream PTISs. These data have provided information on timing of adult movements to various parts of the watershed, which is allowing us to assess adult returns to tributary watersheds within the Wind River subbasin. Determination of adult use of tributary watersheds is providing data to contribute to evaluation of the efficacy of the removal of Hemlock Dam on Trout Creek. Hemlock Dam, located at rkm 2.0 of Trout Creek was removed in summer 2009 and had contributed to hydrologic impairment of Trout Creek Evaluating restoration efforts is of interest to many managers and agencies so that funding and time are allocated for best results. The evaluation of various life-histories of Lower Columbia River steelhead within the Wind River subbasin will provide information to better track populations, and to direct habitat restoration and water allocation planning. Increasingly detailed Viable Salmonid Population information, such as that provided by PIT-tagging and instream PTISs networks like those we are building and operating in the Wind River subbasin, will provide data to inform policy and management, as life-history strategies and production bottlenecks are identified and understood.

Report

Hydrogeologic characterization of the Modesto Area, San Joaquin Valley, California

Hydrogeologic characterization was done to develop an understanding of the hydrogeologic setting near Modesto by maximizing the use of existing data and building on previous work in the region. A substantial amount of new lithologic and hydrologic data are available that allow a more complete and updated characterization of the aquifer system. In this report, geologic units are described, a database of well characteristics and lithology is developed and used to update the regional stratigraphy, a water budget is estimated for water year 2000, a three-dimensional spatial correlation map of aquifer texture is created, and recommendations for future data collection are summarized. The general physiography of the study area is reflected in the soils. The oldest soils, which have low permeability, exist in terrace deposits, in the interfan areas between the Stanislaus, Tuolumne, and Merced Rivers, at the distal end of the fans, and along the San Joaquin River floodplain. The youngest soils have high permeability and generally have been forming on the recently deposited alluvium along the major stream channels. Geologic materials exposed or penetrated by wells in the Modesto area range from pre-Cretaceous rocks to recent alluvium; however, water-bearing materials are mostly Late Tertiary and Quaternary in age. A database containing information from more than 3,500 drillers'logs was constructed to organize information on well characteristics and subsurface lithology in the study area. The database was used in conjunction with a limited number of geophysical logs and county soil maps to define the stratigraphic framework of the study area. Sequences of red paleosols were identified in the database and used as stratigraphic boundaries. Associated with these paleosols are very coarse grained incised valley-fill deposits. Some geophysical well logs and other sparse well information suggest the presence of one of these incised valley-fill deposits along and adjacent to the Tuolumne River east of Modesto, a feature that may have important implications for ground-water flow and transport in the region. Although extensive work has been done by earlier investigators to define the structure of the Modesto area aquifer system, this report has resulted in some modification to the lateral extent of the Corcoran Clay and the regional dip of the Mehrten Formation. Well logs in the database indicating the presence of the Corcoran Clay were used to revise the eastern extent of the Corcoran Clay, which lies approximately parallel to the axis of valley. The Mehrten Formation is distinguished in the well-log database by its characteristic black sands consisting of predominantly andesitic fragments. Black sands in wells listed in the database indicate that the formation may lie as shallow as 120 meters (400 feet) below land surface under Modesto, approximately 90 meters (300 feet) shallower than previously thought. The alluvial aquifer system in the Modesto area comprises an unconfined to semiconfined aquifer above and east of the Corcoran Clay confining unit and a confined aquifer beneath the Corcoran Clay. The unconfined aquifer is composed of alluvial sediments of the Modesto, Riverbank, and upper Turlock Lake formations. The unconfined aquifer east of the Corcoran Clay becomes semiconfined with depth due to the numerous discontinuous clay lenses and extensive paleosols throughout the aquifer thickness. The confined aquifer is composed primarily of alluvial sediments of the Turlock Lake and upper Mehrten Formations, extending from beneath the Corcoran Clay to the base of fresh water. Ground water in the unconfined to semiconfined aquifer flows to the west and southwest. The primary source of present-day recharge is percolating excess irrigation water. The primary ground-water discharge is extensive ground-water pumping in the unconfined to semiconfined aquifer, imposing a significant component of vertical flow in the system. A water budget was calculated for water year 2000 using a land-use approach. During water year 2000, the total water supply in the Modesto area was more than 2.5 billion m3 (cubic meter) (2 million acre-ft [acre-foot]). Surface-water deliveries accounted for 60 percent of the total water supply, whereas ground-water pumpage accounted for 40 percent. Ninety-four percent of the water supply was used to meet irrigation demand and approximately 6 percent was used to meet urban demand. The total recharge in the model area was estimated at 1.4 billion m3 (1,100,000 acre-ft). The largest component of recharge is from excess irrigation water (58 percent); precipitation in excess of crop requirements accounted for 41 percent of the recharge. Geostatistical methods were used to develop a spatial correlation model of the percentage of coarse-grained texture in the Modesto area. The mean percentage coarse-grained texture calculated for each depth increment indicates a regional trend of decreasing coarse-grained texture with increasing depth, which is consistent with increasingly consolidated sediments with depth in the study area. The three-dimensional kriged estimates of percentage coarse-grained texture show significant heterogeneity in the texture of the sedimentary deposits. Assuming the hydraulic conductivity is correlated to the texture, the kriged result implies significant heterogeneity in the hydrogeologic framework.

California

An update of hydrologic conditions and distribution of selected constituents in water, Eastern Snake River Plain aquifer and perched groundwater zones, Idaho National Laboratory, Idaho, emphasis 2016–18

Since 1952, wastewater discharged to infiltration ponds (also called percolation ponds) and disposal wells at the Idaho National Laboratory (INL) has affected water quality in the eastern Snake River Plain (ESRP) aquifer and perched groundwater zones underlying the INL. The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, maintains groundwater-monitoring networks at the INL to determine hydrologic trends and to delineate the movement of radiochemical and chemical wastes in the aquifer and in perched groundwater zones. This report presents an analysis of water-level and water-quality data collected from the ESRP aquifer and perched groundwater wells in the USGS groundwater monitoring networks during 2016–18. From March–May 2015 to March–May 2018, water levels in wells completed in the ESRP aquifer declined in the northern part of the INL and increased in the southwestern part. Water-level decreases ranged from 0.5 to 3.0 feet (ft) in the northern part of the INL and increases ranged from 0.5 to 3.0 ft in the southwestern part. Detectable concentrations of radiochemical constituents in water samples from wells in the ESRP aquifer at the INL generally decreased or remained constant during 2016–18. Decreases in concentrations were attributed to radioactive decay, changes in waste-disposal methods, and dilution from recharge and underflow. In 2018, concentrations of tritium in water samples collected from 46 of 111 aquifer wells were greater than the reporting level of three times the sample standard deviation and ranged from 260±50 to 5,100±190 picocuries per liter (pCi/L). Tritium concentrations in water from 10 wells completed in deep perched groundwater above the ESRP aquifer near the Advanced Test Reactor (ATR) Complex generally were greater than or equal to the reporting level during at least one sampling event during 2016–18, and concentrations ranged from 150 ±50 to 12,900 ±200 pCi/L. Concentrations of strontium-90 in water from 17 of 60 ESRP aquifer wells sampled during April or October 2018 exceeded the reporting level, ranging from 2.2±0.7 to 363±19 pCi/L. Strontium-90 was not detected in the ESRP aquifer beneath the ATR Complex. During at least one sampling event during 2016–18, concentrations of strontium-90 in water from eight wells completed in deep perched groundwater above the ESRP aquifer at the ATR Complex equaled or exceeded the reporting levels, and concentrations ranged from 0.57±0.17 to 34.3±1.2 pCi/L. During 2016–18, concentrations of cesium-137 were less than the reporting level in all but one ESRP aquifer well, and concentrations of plutonium-238, -239, and -240 (undivided), and americium-241 were less than the reporting level in water samples from all ESRP aquifer wells. In April 2009, the dissolved chromium concentration in water from one ESRP aquifer well, USGS 65, south of the ATR Complex equaled the maximum contaminant level (MCL) of 100 micrograms per liter (μg/L). In April 2018, the concentration of chromium in water from that well had decreased to 76.0 μg/L, less than the MCL. Concentrations in water samples from 62 other ESRP aquifer wells sampled ranged from less than 0.6 to 21.6 μg/L. During 2016–18, dissolved chromium was detected in water from all wells completed in deep perched groundwater above the ESRP aquifer at the ATR Complex, and concentrations ranged from 4.2 to 98.8 μg/L. In 2018, concentrations of sodium in water from most ESRP aquifer wells in the southern part of the INL were greater than the western tributary background concentration of 8.3 milligrams per liter (mg/L). After the new percolation ponds were put into service in 2002 southwest of the Idaho Nuclear Technology and Engineering Center (INTEC), concentrations of sodium in water samples from the Rifle Range well increased steadily until 2008, when concentrations generally began decreasing. The increases and decreases were attributed to disposal variability in the new percolation ponds. During 2016–18, dissolved sodium concentrations in water from 18 wells completed in deep perched groundwater above the ESRP aquifer at the ATR Complex ranged from 6.37 to 143 mg/L. In 2018, concentrations of chloride in most water samples from ESRP aquifer wells south of the INTEC and at the Central Facilities Area exceeded the background concentrations. Chloride concentrations in water from wells south of the INTEC generally have decreased since 2002 when chloride disposal to the old percolation ponds was discontinued. After the new percolation ponds southwest of the INTEC were put into service in 2002, concentrations of chloride in water samples from one well rose steadily until 2008 then began decreasing. During 2016–18, dissolved chloride concentrations in deep perched groundwater above the ESRP aquifer from 18 wells at the ATR Complex ranged from 3.89 to 176 mg/L. In 2018, sulfate concentrations in water samples from ESRP aquifer wells in the south-central part of the INL exceeded the background concentration of sulfate and ranged from 22 to 151 mg/L. The greater-than-background concentrations in water from these wells probably resulted from sulfate disposal at the ATR Complex infiltration ponds or the old INTEC percolation ponds. In 2018, sulfate concentrations in water samples from wells near the Radioactive Waste Management Complex (RWMC) mostly were greater than background concentrations and could have resulted from well construction techniques and (or) waste disposal at the RWMC or the ATR complex. The maximum dissolved sulfate concentration in shallow perched groundwater above the ESRP aquifer near the ATR Complex was 215 mg/L in well CWP 3 in April 2016. During 2018, dissolved sulfate concentrations in water from wells completed in deep perched groundwater above the ESRP aquifer near the cold-waste ponds at the ATR Complex ranged from 65.8 to 171 mg/L. In 2018, concentrations of nitrate in water from most ESRP aquifer wells at and near the INTEC exceeded the western tributary background concentration of 0.655 mg/L. Concentrations of nitrate in wells southwest of the INTEC and farther away from the influence of disposal areas and the Big Lost River show a general decrease in nitrate concentration through time. Two wells south of the INTEC show increasing trends that could be the result of wastewater beneath the INTEC tank farm being mobilized to the aquifer. During 2016–18, water samples from several ESRP aquifer wells were collected and analyzed for volatile organic compounds (VOCs). Sixteen VOCs were detected. At least 1 and as many as 7 VOCs were detected in water samples from 15 wells. The primary VOCs detected include carbon tetrachloride, trichloromethane, tetrachloroethene, 1,1,1-trichloroethane, and trichloroethene. In 2016–18, concentrations for all VOCs were less than their respective MCLs for drinking water, except carbon tetrachloride in water from two wells and trichloroethene in one well. During 2016–18, variability and bias were evaluated from 37 replicate and 15 blank quality-assurance samples. Results from replicate analyses were investigated to evaluate sample variability. Constituents with acceptable reproducibility were major ions, trace elements, nutrients, and VOCs. All radiochemical constituents had acceptable reproducibility except for gross alpha- and beta-particle radioactivity. The gross alpha- and beta-particle radioactivity samples that did not meet reproducibility criteria had low concentrations. Bias from sample contamination was evaluated from equipment, field, and source-solution blanks. Cadmium had a concentration slightly greater than its reporting level in a source-solution blank, and chloride and ammonia had concentrations that were slightly greater than their respective reporting levels in field and equipment blanks. Subtracting concentrations of chloride and ammonia in field blanks from the concurrently collected equipment blank indicates that adjusted concentrations for chloride and ammonia in the equipment blanks were less than their respective reporting levels. Therefore, no sample bias was observed for any of the sample periods.

Idaho

An update of hydrologic conditions and distribution of selected constituents in water, eastern Snake River Plain aquifer and perched groundwater zones, Idaho National Laboratory, Idaho, emphasis 2009–11

Since 1952, wastewater discharged to infiltration ponds (also called percolation ponds) and disposal wells at the Idaho National Laboratory (INL) has affected water quality in the eastern Snake River Plain (ESRP) aquifer and perched groundwater zones underlying the INL. The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, maintains groundwater monitoring networks at the INL to determine hydrologic trends, and to delineate the movement of radiochemical and chemical wastes in the aquifer and in perched groundwater zones. This report presents an analysis of water-level and water-quality data collected from aquifer, multilevel monitoring system (MLMS), and perched groundwater wells in the USGS groundwater monitoring networks during 2009–11. Water in the ESRP aquifer primarily moves through fractures and interflow zones in basalt, generally flows southwestward, and eventually discharges at springs along the Snake River. The aquifer primarily is recharged from infiltration of irrigation water, infiltration of streamflow, groundwater inflow from adjoining mountain drainage basins, and infiltration of precipitation. From March–May 2009 to March–May 2011, water levels in wells generally declined in the northern part of the INL. Water levels generally rose in the central and eastern parts of the INL. Detectable concentrations of radiochemical constituents in water samples from aquifer wells or MLMS equipped wells in the ESRP aquifer at the INL generally decreased or remained constant during 2009–11. Decreases in concentrations were attributed to radioactive decay, changes in waste-disposal methods, and dilution from recharge and underflow. In 2011, concentrations of tritium in groundwater from 50 of 127 aquifer wells were greater than or equal to the reporting level and ranged from 200±60 to 7,000±260 picocuries per liter. Tritium concentrations from one or more discrete zones from four wells equipped with MLMS were greater than or equal to reporting levels in water samples collected at various depths. Tritium concentrations in water from wells completed in shallow perched groundwater at the Advanced Test Reactor Complex (ATR Complex) were less than the reporting levels. Tritium concentrations in deep perched groundwater at the ATR Complex equaled or exceeded the reporting level in 12 wells during at least one sampling event during 2009–11 at the ATR Complex. Concentrations of strontium-90 in water from 20 of 76 aquifer wells sampled during April or October 2011 exceeded the reporting level. Strontium-90 was not detected within the ESRP aquifer beneath the ATR Complex. During at least one sampling event during 2009–11, concentrations of strontium-90 in water from 10 wells completed in deep perched groundwater at the ATR Complex equaled or exceeded the reporting levels. During 2009–11, concentrations of plutonium-238, and plutonium-239, -240 (undivided), and americium-241 were less than the reporting level in water samples from all aquifer wells and in all wells equipped with MLMS. Concentrations of cesium-137 were equal to or slightly above the reporting level in 8 aquifer wells and from 2 wells equipped with MLMS. The concentration of chromium in water from one well south of the ATR Complex was 97 micrograms per liter (μg/L) in April 2011, just less than the maximum contaminant level (MCL) of 100 μg/L. Concentrations of chromium in water samples from 69 other wells sampled ranged from 0.8 μg/L to 25 μg/L. During 2009–11, dissolved chromium was detected in water from 15 wells completed in perched groundwater at the ATR Complex. In 2011, concentrations of sodium in water from most wells in the southern part of the INL were greater than the background concentration of 10 milligrams per liter (mg/L); the highest concentrations were at or near the Idaho Nuclear Engineering and Technology Center (INTEC). After the newpercolation ponds were put into service in 2002 southwest of the INTEC, concentrations of sodium in water samples from the Rifle Range well rose steadily until 2008, when the concentrations generally began decreasing. The increases and decreases were attributed to disposal variability in the new percolation ponds. Concentrations of sodium in most wells equipped with MLMS generally were consistent with depth. During 2011, dissolved sodium concentrations in water from 17 wells completed in deep perched groundwater at the ATR Complex ranged from 6 to 146 mg/L. In 2011, concentrations of chloride in most water samples from aquifer wells south of the INTEC and at the Central Facilities Area exceeded the background concentrations of 15 mg/L, but were less than the secondary MCL of 250 mg/L. Chloride concentrations in water from wells south of the INTEC have generally increased because of increased chloride disposal to the old percolation ponds since 1984 when discharge of wastewater to the INTEC disposal well was discontinued. After the new percolation ponds were put into service in 2002 southwest of the INTEC, concentrations of chloride in water samples from one well rose steadily until 2008 then began decreasing. Chloride concentrations in water from all but one well completed in the ESRP aquifer at or near the ATR Complex were less than background and ranged between 10 and 14 mg/L during 2011, similar to concentrations detected during the 2006–08 reporting period. During 2011, chloride concentrations in water from two aquifer wells at the Radioactive Waste Management Complex (RWMC) were slightly greater than concentrations detected during the 2006–08 reporting period. The vertical distribution of chloride concentrations in wells equipped with MLMS were generally consistent within zones during 2009–11 and ranged from about 8 to 20 mg/L. During April 2011, dissolved chloride concentrations in shallow perched groundwater at the ATR Complex ranged from 7 to 13 mg/L in water from three wells. Dissolved chloride concentrations in deep perched groundwater at the ATR Complex during 2011 ranged from 4 to 54 mg/L. In 2011, sulfate concentrations in water samples from 11 aquifer wells in the south-central part of the INL equaled or exceeded the background concentration of sulfate and ranged from 40 to 167 mg/L. The greater-than-background concentrations in water from these wells probably resulted from sulfate disposal at the ATR Complex infiltration ponds or the old INTEC percolation ponds. In 2011, sulfate concentrations in water samples from two wells near the RWMC were greater than background levels and could have resulted from well construction techniques and (or) waste disposal at the RWMC. The vertical distribution of sulfate concentrations in three wells near the southern boundary of the INL was generally consistent with depth, and ranged between 19 and 25 mg/L. The maximum dissolved sulfate concentration in shallow perched groundwater near the ATR Complex was 400 mg/L in well CWP 1 in April 2011. During 2009–11, the maximum concentration of dissolved sulfate in deep perched groundwater at the ATR Complex was 1,550 mg/L in a well located west of the chemical-waste pond. In 2011, concentrations of nitrate in water from most wells at and near the INTEC exceeded the regional background concentrations of 1 mg/L and ranged from 1.6 to 5.95 mg/L. Concentrations of nitrate in wells south of INTEC and farther away from the influence of disposal areas and the Big Lost River show a general decrease in nitrate concentrations through time. During 2009–11, water samples from 30 wells were collected and analyzed for volatile organic compounds (VOCs). Six VOCs were detected. At least one and up to five VOCs were detected in water samples from 10 wells. The primary VOCs detected include carbon tetrachloride, chloroform, tetrachloroethylene, 1,1,1-trichloroethane, and trichloroethylene. In 2011, concentrations for all VOCs were less than their respective MCL for drinking water, except carbon tetrachloride in water from two wells. During 2009–11, variability and bias were evaluated from 56 replicate and 16 blank quality-assurance samples. Results from replicate analyses were investigated to evaluate sample variability. Constituents with acceptable reproducibility were stable isotope ratios, major ions, nutrients, and VOCs. All radiochemical constituents and trace metals had acceptable reproducibility except for gross beta-particle radioactivity, aluminum, antimony, and cobalt. Bias from sample contamination was evaluated from equipment, field, container, and source-solution blanks. No detectable constituent concentrations were reported for equipment blanks of the thief samplers and sampling pipes or for the source-solution and field blanks. Equipment blanks of bailers had detectable concentrations of strontium-90, sodium, chloride, and sulfate, and the container blank had a detectable concentration of dichloromethane.

Idaho

Hydrology and simulation of ground-water flow in the Aguadilla to Rio Camuy area, Puerto Rico

The aquifers of the Aguadilla to Rio Camuy area, in the northwestern part of Puerto Rico, are the least developed of those on the north coast, and relatively little information is available concerning the ground-water system. The present study, which was part of a comprehensive appraisal of the ground-water resources of the North Coast Province, attempts to interpret the hydrology of the area within the constraints of available data. The study area consists of an uplifted rolling plain that is 200 to 400 feet above sea level and a heavily forested, karst upland. The only major streams in the area are the Rfo Camuy and the Rio Guajataca. Most water used in the area is obtained from Lago de Guajataca, just south of the study area, and ground-water use is minimal (less than 5 million gallons per day). Sedimentary rocks of Tertiary age, mainly limestone and calcareous clays, comprise the aquifers of the Aguadilla to Rio Camuy area. The rocks generally dip from 4 to 7 degrees to the north, and the total sedimentary rock sequence may be as much as 6,000 feet thick near the Atlantic coast. Baseflows for the Rio Camuy are 58 cubic feet per second near Bayaney and 72 cubic feet per second near Hatillo. The ground-water discharge to the Rio Camuy between these stations is estimated to be 15 cubic feet per second, or 2.6 cubic feet per second per linear mile. The flow of the Rio Guajataca is regulated by the Guajataca Dam at Lago de Guajataca. Ground-water discharge to the Rio Guajataca between the dam and the coast is estimated to be about 17 cubic feet per.second, based on the average ground-water discharge per linear mile estimated for the Rio Camuy. Both water-table and artesian aquifers are present in the Aguadilla to Rio Camuy area; how-ever, most ground water occurs within the watertable aquifer, which was the primary focus of this study. The top of the confining unit, below the water-table aquifer, generally is within the unnamed upper member of the Cibao Formation; however, it is within the Los Puertos Formation in the eastern part of the study area. The water-table aquifer primarily is composed of rocks of the Aymam6n Limestone and the Los Puertos Formation. The estimated saturated thickness of the water-table aquifer ranges from zero at the southern limit of the aquifer to more than 600 feet south of Isabela. Hydraulic conductivity of the Aymam6n Limestone, based on specific-capacity test data for seven wells, ranges from about 1 to about 25 feet per day and averages 7.5 feet per day. Hydraulic conductivity of the Los Puertos Formation, based on specific-capacity test data for four wells, generally was less than 7 feet. per day. The average hydraulic-conductivity value for both the Aymam6n Limestone and the Los Puertos Formation, based on specific-capacity test data, is estimated to be about 6.0 feet per day. These hydraulic-conductivity values are much less than average values for the water-table aquifer reported for other parts of the North Coast Province. Transmissivity values, based on the average hydraulic-conductivity value for the aquifer derived from specific-capacity tests, range from zero to about 4,000 feet squared per day; however, these values were adjusted upward during model calibration. Ground water generally moves from the highlands in the south toward the sea to the north and west, and locally, to streams. A major groundwater divide extends from the southeastern corner of the study area to the northwest, and separates flow north and east into the study area from flow to the southwest toward the Rio Culebrinas. Nearly all recharge to the aquifer is from infiltration of rainfall into the karst uplands. Discharge from the aquifer primarily occurs as leakage to streams and to the sea, and to a lesser degree as flow to wells. A two-layer, three-dimensional, steady-state, numerical model was constructed to simulateground-water flow in the water-table aquifer between Aguadilla and the R/o Camuy area. A basic a

Water-Resources Investigations Report

Geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers within northern Bexar and Comal Counties, Texas

During 2014–16, the U.S. Geological Survey, in cooperation with the Edwards Aquifer Authority, documented the geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers within northern Bexar and Comal Counties, Texas. The Edwards and Trinity aquifers are major sources of water for agriculture, industry, and urban and rural communities in south-central Texas. Both the Edwards and Trinity are classified as major aquifers by the State of Texas. The purpose of this report is to present the geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers within northern Bexar and Comal Counties, Tex. The report includes a detailed 1:24,000-scale hydrostratigraphic map, names, and descriptions of the geology and hydrostratigraphic units (HSUs) in the study area. The scope of the report is focused on geologic framework and hydrostratigraphy of the outcrops and hydrostratigraphy of the Edwards and Trinity aquifers within northern Bexar and Comal Counties, Tex. In addition, parts of the adjacent upper confining unit to the Edwards aquifer are included. The study area, approximately 866 square miles, is within the outcrops of the Edwards and Trinity aquifers and overlying confining units (Washita, Eagle Ford, Austin, and Taylor Groups) in northern Bexar and Comal Counties, Tex. The rocks within the study area are sedimentary and range in age from Early to Late Cretaceous. The Miocene-age Balcones fault zone is the primary structural feature within the study area. The fault zone is an extensional system of faults that generally trends southwest to northeast in south-central Texas. The faults have normal throw, are en echelon, and are mostly downthrown to the southeast. The Early Cretaceous Edwards Group rocks were deposited in an open marine to supratidal flats environment during two marine transgressions. The Edwards Group is composed of the Kainer and Person Formations. Following tectonic uplift, subaerial exposure, and erosion near the end of Early Cretaceous time, the area of present-day south-central Texas was again submerged during the Late Cretaceous by a marine transgression resulting in deposition of the Georgetown Formation of the Washita Group. The Early Cretaceous Edwards Group, which overlies the Trinity Group, is composed of mudstone to boundstone, dolomitic limestone, argillaceous limestone, evaporite, shale, and chert. The Kainer Formation is subdivided into (bottom to top) the basal nodular, dolomitic, Kirschberg Evaporite, and grainstone members. The Person Formation is subdivided into (bottom to top) the regional dense, leached and collapsed (undivided), and cyclic and marine (undivided) members. Hydrostratigraphically the rocks exposed in the study area represent a section of the upper confining unit to the Edwards aquifer, the Edwards aquifer, the upper zone of the Trinity aquifer, and the middle zone of the Trinity aquifer. The Pecan Gap Formation (Taylor Group), Austin Group, Eagle Ford Group, Buda Limestone, and Del Rio Clay are generally considered to be the upper confining unit to the Edwards aquifer. The Edwards aquifer was subdivided into HSUs I to VIII. The Georgetown Formation of the Washita Group contains HSU I. The Person Formation of the Edwards Group contains HSUs II (cyclic and marine members [Kpcm], undivided), III (leached and collapsed members [Kplc,] undivided), and IV (regional dense member [Kprd]), and the Kainer Formation of the Edwards Group contains HSUs V (grainstone member [Kkg]), VI (Kirschberg Evaporite Member [Kkke]), VII (dolomitic member [Kkd]), and VIII (basal nodular member [Kkbn]). The Trinity aquifer is separated into upper, middle, and lower aquifer units (hereinafter referred to as “zones”). The upper zone of the Trinity aquifer is in the upper member of the Glen Rose Limestone. The middle zone of the Trinity aquifer is formed in the lower member of the Glen Rose Limestone, Hensell Sand, and Cow Creek Limestone. The regionally extensive Hammett Shale forms a confining unit between the middle and lower zones of the Trinity aquifer. The lower zone of the Trinity aquifer consists of the Sligo and Hosston Formations, which do not crop out in the study area. The upper zone of the Trinity aquifer is subdivided into five informal HSUs (top to bottom): cavernous, Camp Bullis, upper evaporite, fossiliferous, and lower evaporite. The middle zone of the Trinity aquifer is composed of the (top to bottom) Bulverde, Little Blanco, Twin Sisters, Doeppenschmidt, Rust, Honey Creek, Hensell, and Cow Creek HSUs. The underlying Hammett HSU is a regional confining unit between the middle and lower zones of the Trinity aquifer. The lower zone of the Trinity aquifer is not exposed in the study area. Groundwater recharge and flow paths in the study area are influenced not only by the hydrostratigraphic characteristics of the individual HSUs but also by faults and fractures and geologic structure. Faulting associated with the Balcones fault zone (1) might affect groundwater flow paths by forming a barrier to flow that results in water moving parallel to the fault plane, (2) might affect groundwater flow paths by increasing flow across the fault because of fracturing and juxtaposing porous and permeable units, or (3) might have no effect on the groundwater flow paths. The hydrologic connection between the Edwards and Trinity aquifers and the various HSUs is complex. The complexity of the aquifer system is a combination of the original depositional history, bioturbation, primary and secondary porosity, diagenesis, and fracturing of the area from faulting. All of these factors have resulted in development of modified porosity, permeability, and transmissivity within and between the aquifers. Faulting produced highly fractured areas that have allowed for rapid infiltration of water and subsequently formed solutionally enhanced fractures, bedding planes, channels, and caves that are highly permeable and transmissive. The juxtaposition resulting from faulting has resulted in areas of interconnectedness between the Edwards and Trinity aquifers and the various HSUs that form the aquifers.

Texas

Hydrogeology, water chemistry, and transport processes in the zone of contribution of a public-supply well in Albuquerque, New Mexico, 2007-9

The National Water-Quality Assessment Program (NAWQA) of the U.S. Geological Survey began a series of groundwater studies in 2001 in representative aquifers across the Nation in order to increase understanding of the factors that affect transport of anthropogenic and natural contaminants (TANC) to public-supply wells. One of 10 regional-scale TANC studies was conducted in the Middle Rio Grande Basin (MRGB) in New Mexico, where a more detailed local-scale study subsequently investigated the hydrogeology, water chemistry, and factors affecting the transport of contaminants in the zone of contribution of one 363-meter (m) deep public-supply well in Albuquerque. During 2007 through 2009, samples were collected for the local-scale study from 22 monitoring wells and 3 public-supply (supply) wells for analysis of major and trace elements, arsenic speciation, nutrients, dissolved organic carbon, volatile organic compounds (VOCs), dissolved gases, stable isotopes, and tracers of young and old water. To study groundwater chemistry and ages at various depths within the aquifer, the monitoring wells were divided into three categories: (1) each shallow well was screened across the water table or had a screen midpoint within 18.3 m of the water level in the well; (2) each intermediate well had a screen midpoint between about 27.1 and 79.6 m below the water level in the well; and (3) each deep well had a screen midpoint about 185 m or more below the water level in the well. The 24-square-kilometer study area surrounding the "studied supply well" (SSW), one of the three supply wells, consists of primarily urban land within the MRGB, a deep alluvial basin with an aquifer composed of unconsolidated to moderately consolidated deposits of sand, gravel, silt, and clay. Conditions generally are unconfined, but are semiconfined at depth. Groundwater withdrawals for public supply have substantially changed the primary direction of flow from northeast to southwest under predevelopment conditions, to west to east under modern conditions. Analysis of age tracers indicates that groundwater from most sampled wells is dominated by old (pre-1950) water, ranging in mean age from about 4,000 years to more than 22,000 years, but includes a fraction of young (post-1950) recharge. Patterns in chemical and isotopic data are consistent with the conclusions that shallow groundwater in the area typically includes a fraction that evaporated prior to recharge and (or) flushed accumulated solutes out of the unsaturated zone during recharge, and that shallow groundwater has mixed to deeper parts of the aquifer, which receives recharge mainly by seepage from the Rio Grande. Among shallow and intermediate wells that produced water with a fraction of young recharge, that fraction ranged between 1.5 and 46 percent. Samples from the two deep wells had groundwater ages exceeding 18,000 years, with no fraction of young recharge. Two supply wells (including the SSW) had a fraction of young recharge, which ranged between about 3 and 11 percent, despite mean groundwater ages exceeding 10,000 years. The fraction of young recharge to the SSW varied seasonally, probably because seasonal pumping patterns affected local hydraulic gradients and (or) because of flow through the well bore when the SSW is not pumping. Well-bore flow data collected during winter (low-pumping season) indicated that about 61 percent of the water pumped from the SSW entered the well from the intermediate part of the aquifer, and that the remaining 39 percent entered from the deep part of the aquifer. Volatile organic compounds (VOCs) were detected in samples from most shallow and intermediate monitoring wells and from two of three supply wells, including the SSW. Detected VOCs were primarily chlorinated solvents or their degradation products. Many of the wells in which most of these VOCs were detected are located near known sites of solvent contamination that were targeted for sampling because trichloroethylene (TCE) and cis-1,2-dichloroethylene had been detected in the SSW, and several of these wells may have become contaminated at least partly because of enhanced vertical migration associated with the pumping of and (or) direct migration down deep well bores. Except for TCE in the sample from a shallow monitoring well, all detections of VOCs were at concentrations below Maximum Contaminant Levels (MCLs) set by the U.S. Environmental Protection Agency. Concentrations of all VOCs detected in the supply wells were less than one-tenth of the corresponding MCLs. However, the presence of VOCs in all but deep groundwater, including the detection of chloroform (a chlorination byproduct) in several shallow wells, indicates that groundwater in the study area commonly is affected by human activities, even to substantial depths. The only natural contaminant detected at concentrations near or above its MCL was arsenic, which has been detected at elevated concentrations across broad areas of the MRGB. Concentrations of arsenic, present primarily as arsenate, exceeded the MCL of 10 micrograms per liter (μg/L) in water from the two deep wells (one of which had the highest concentration, 35 μg/L), from one intermediate well, and from two supply wells, including the SSW. Water-quality and solid-phase data from this study are consistent with elevated arsenic concentrations in groundwater being related to pH-dependent desorption of arsenic from ferric oxyhydroxides in sediments in deep parts of the aquifer. Concentrations of nitrate ranged between 1.3 and 5.4 milligrams per liter (mg/L) in water from shallow wells screened across the water table, but were less than 0.9 mg/L in water from all but one deeper well. Nitrogen isotopes and chloride/bromide ratios for shallow wells were consistent with natural soil nitrogen. Nitrate concentrations and nitrogen isotopes indicated that denitrification is occurring at intermediate aquifer depths, and that the progress of the denitrification reaction typically is greatest for wells that include a fraction of groundwater associated with particular recharge sources or with known sites of contamination contributing organic compounds that can provide a carbon source for microbial respiration. Overall, hydrologic and chemical data from the study area indicate that young recharge is reaching the aquifer across broad areas and is migrating from shallow to intermediate depths of the aquifer as a result of mixing that is associated with human development of groundwater. Consequently, groundwater that human activities in the urban study area have affected is present at depths that are within the screened intervals of public-supply wells, resulting in detections of VOCs and implying greater vulnerability to anthropogenic contamination than might be assumed based on the dominantly old age of the regional groundwater. However, the fractions of old groundwater that public-supply wells produce substantially dilute the anthropogenic contaminants, while contributing natural contaminants (primarily arsenic) to the wells. Based on data from the SSW, vulnerability of public-supply wells to natural and anthropogenic contaminants in the area changes through time, including with seasonal changes in pumping stresses that alter the fractions of young and old water being contributed to wells.

New Mexico

Effects of runoff controls on the quantity and quality of urban runoff at two locations in Austin, Texas

Rapid urban development in the Austin metropolitan area, Texas, is causing concern about increasing peak discharges from storm runoff and the degradation of the quality of water in receiving streams, lakes, and aquifers. In an attempt to decrease peak discharges and improve water quality, runoff controls are being required in some watersheds. This report summarizes the precipitation, streamflow, and water-quality data collected from September 1982 to September 1984 upstream and downstream from runoff controls at two locations, and presents the effects of these runoff controls on streamflow and the quality of runoff water. The two controls are a detention and filtering pond near Barton Creek Square Shopping Center, a large shopping center southwest of downtown Austin, and a grass-swale control in the Al ta Vista Planned Unit Development, a multipie-family housing area. At Barton Creek Square Shopping Center, rainfall for the storms analyzed ranged from 0.14 to 2.88 inches. The rainfall rate for the September 7, 1983, storm exceeded the 100-year return period for the 5- and 10-minute duration and was equal to the 50-year return period for the 15-minute duration. Peak discharge at the inflow station to the detention pond was closely related to the maximum rainfall during a 5-minute period and occurred about 10 minutes later. The maximum inflow at this station was 185 cubic feet per second and appeared to be the limit of the storm sewer system. For small- and moderate-sized storms, the runoff is contained in the detention pond and passes through a filter system. Runoff from large storms overflows into the drop outlet. For storms contained in the pond, peak discharges at the outflow station generally were less than 3.1 cubic feet per second. As time passed, the outflow peak discharges tended to decrease as a result of reduced permeability of the filter. Cleaning the filter appeared to increase the peak flows but did not restore them to the previous level. The runoff-rainfall ratio averaged 0.85 at the inflow station and 0.36 at the outflow station. A water budget shows unexplained losses to average 20 percent. At the Barton Creek Square Shopping Center, discharge-weighted densities of fecal-col iform and fecal-streptococci bacteria and discharge-weighted concentrations of biochemical oxygen demand, chemical oxygen demand, total organic carbon, suspended solids, total ammonia plus organic nitrogen, and total phosphorus generally were larger in the inflow than in the outflow. Discharge-weighted concentrations of dissolved lead, dissolved iron, and dissolved zinc generally were small in both the inflow and outflow; however, the larger discharge-weighted concentrations of these constituents generally were found in the inflow. Discharge-weighted concentrations of volatile dissolved solids were smaller in the inflow than in the outflow for 10 of the 22 storms analyzed. Discharge-weighted concentrations of total nitrite plus nitrate nitrogen and dissolved solids generally were much smaller in the inflow than in the outflow. It is likely that organic and ammonia nitrogen trapped in the pond from previous storms and in the inflow water as it flows through the pond is being oxidized to nitrite and nitrate nitrogen. Similarly, dissolved solids retained in the filter or on the bed of the pond from previous storms are being leached to the outflow. Measured peak concentrations or densities of most constituents in the inflow were significantly larger than those in the outflow for most constituents. An exception was noted for concentrations of total nitrite plus nitrate which were larger in the outflow than the inflow as indicated by discrete sample analysis for six storms. Loads of most constituents and total numbers of bacteria were significantly larger in the inflow than in the outflow. The total numbers of bacteria were reduced by approximately 80 percent. Average removal efficiencies for suspended solids, biochemical oxygen demand, total phosphorus, total organic carbon, chemical oxygen demand, and dissolved zinc ranged between 60 and 80 percent. The average loads of dissolved solids were approximately 13 percent larger in the outflow than the inflow. Average loads of total nitrite plus nitrate nitrogen were approximately 110 percent larger in the outflow than in the inflow. The increase in loads of these constituents is due to material being leached from the bed of the pond or from the filter system. At Al ta Vista, rainfall for the storms analyzed ranged from 0.25 to 2.00 inches. The maximum rainfall intensity was 0.30 inch for a 5-minute interval. The runoff-rainfall ratio averaged 0.42 and appeared to be evenly distributed about the mean ratio line. The peak discharge at the inflow station to the grass-covered swale area was 0.93 cubic foot per second. Inaccuracies of discharge at the outflow station and variations in the ungaged drainage area with the size of the storm prevented a hydrologic analysis of the basin above this station. Discharge-weighted concentrations of total phosphorus were larger in the outflow than in the inflow for each of the 19 storms analyzed. Discharge-weighted concentrations of dissolved solids, volatile dissolved solids, biochemical oxygen demand, chemical oxygen demand, and total organic carbon were larger in the outflow than in the inflow for at least 12 of the 19 storms analyzed. Discharge-weighted densities of fecal streptococci were decreased between the inflow and outflow, with discharge-weighted densities of fecal streptococci being less in the outflow for 15 of the 19 storms analyzed. Because of the relatively small variations in concentrations and densities of constituents between the inflow and outflow sites, and because of the errors in discharge at the outflow gage, it is not feasible to determine the effect of the grass-covered swales on discharge-weighted concentrations and densities of water-quality constituents. Discrete concentrations or densities of most constituents were not decreased. Peak concentrations of dissolved solids in the outflow exceeded peak concentrations in the inflow for all five of the storms analyzed with discrete samples. Peak concentrations of suspended solids, total ammonia plus organic nitrogen, total nitrite plus nitrate nitrogen, total nitrogen, and dissolved iron were larger in the outflow than in the inflow for four of the five storms analyzed. Load-removal efficiencies of water-quality constituents could not be determined because of inaccuracies in measuring discharge at the outflow site,

Texas