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Decadal trends and occurrence of geogenic constituents and mixtures in groundwater across the continental United States

Worldwide, about 50% of the population is served by groundwater-sourced drinking water. Numerous groundwater quality assessments have found that geogenic constituents are among the most common contaminants in drinking-water aquifers. Documenting changing groundwater quality is a crucial aspect of water availability assessments. We assess trends and occurrence of geogenic constituent concentrations in groundwater across the continental United States using 3 decades of data from the U.S. Geological Survey’s National Water Quality Network. Thousands of groundwater wells were grouped into agricultural, urban, or domestic supply network types. Although most networks and constituents had no statistically significant change in concentration, many had increasing concentration trends, elevated concentrations, or both. Lithium, sodium, radium, sulfate, and uranium had increasing trends in more than 10% of the study networks. Urban and domestic well networks had increasing lithium and sodium trends more often than agricultural networks. Manganese most commonly increased in domestic well networks; uranium more commonly increased in agricultural and urban networks. Elevated concentration mixtures were widespread, and mixture complexities appeared to increase over time. Our results indicate that more than 2.3 million domestic-well users may be affected by elevated concentrations of one or more geogenic constituents.

continental United States

Factors affecting the distribution of water-bearing fractures in the bedrock aquifers of West Virginia

Bedrock aquifers cover 23,601 square miles within the State of West Virginia and comprise 97.4 percent of the surficial area within the State; the remaining 2.6 percent (621 square miles) consists of alluvial sand-and-gravel and glacial outwash aquifers bordering the State’s major rivers. While West Virginia’s alluvial aquifers have been studied extensively, bedrock aquifers have only been characterized for studies completed in a few areas in Jefferson, McDowell, and Monroe Counties. Bedrock aquifers are water supplies for public supply, agriculture, industry, and residential homeowner use. In this study, the U.S. Geological Survey, in cooperation with the West Virginia Department of Environmental Protection Division of Water and Waste Management, provides a statewide assessment of the occurrence and distribution of fractures within bedrock aquifers of the State and the various topographic, physiographic, and lithologic influences controlling the occurrence and distribution of bedrock fractures. The results of this study provide an increased understanding of the distribution of fractures in bedrock aquifers in West Virginia and help to verify trends that have been suspected for many years but were never well documented or verified by data. The results confirmed that the density of fractures and those that were determined to be water bearing decrease significantly with depth. A statistically significant difference in the density of fractures was observed at a depth of 215 feet for wells in the Appalachian Plateaus Physiographic Province’s and in the Valley and Ridge Physiographic Province’s aquifers; a higher density of fractures and water-bearing fractures were above a depth of 215 feet than below that depth. This is an important consideration when drilling wells for residential, commercial, industrial, or agricultural water supply. Abandoned underground coal mines are commonly believed to form large pools of water in the interconnected mine entries in abandoned room and pillar coal mines. Such pools of water can and do exist in abandoned underground coal mines, but many mines lack open entries and are held up by overburden strata and pillars that can collapse and form aquifers comprised of vast interconnected rubble zones (gob), especially in older mines. Data assessed for this study showed that shale-corrected values of effective porosity for limestone aquifers in West Virginia had a median value of 2 percent and an average value of 4 percent and generally are mineralized with low effective porosity. Argillaceous or sandy limestone has a median shale-corrected porosity of 4 percent and an average shale-corrected porosity of 5 percent. The median and average shale-corrected porosity of sandstone aquifers was estimated to be 14 percent, but the median shale-corrected porosity for argillaceous or calcareous sandstone was 5 percent and the average shale-corrected porosity for argillaceous or calcareous sandstone was 6 percent. Even though shale has a relatively high total sonic porosity compared to other lithologies, shale and siltstone had relatively low shale-corrected porosity, ranging from 0 to 2 percent. Well yields were previously documented to be highest in valley settings, lowest on hilltops, and intermediate on hillsides. Transmissivity data provided by this study confirm this general pattern within the Appalachian Plateaus Province; however, the Valley and Ridge Province does not follow this pattern. While still lowest on hilltop settings, the highest well yields were in hillside settings. The trend for the Valley and Ridge Province was likely skewed because of 9 high-yield wells specifically targeting deeper thin limestone units, such as the Tonoloway and Helderberg Limestones, at depths with transmissivity in excess of 2,000 feet squared per day in Mineral County, West Virginia, or targeting karst aquifers in Berkeley, Jefferson, or Greenbrier Counties, West Virginia. Finally, water-bearing fractures have been hypothesized to comprise a small number of all fractures within a typical bedrock well in West Virginia. Data collected for this study support this theory. A total of 3,403 fractures were identified during this study; 3,151 (92.6 percent) of those fractures are low-transmissive, and only 252 (7.4 percent) fractures are water-bearing. Even though a well may contain many fractures, less than 8 percent are considered water-bearing fractures.

West Virginia

In-situ geochronology using LA-ICP-MS/MS: Application of the Lu-Hf system in carbonate, apatite and fluorite

Geochronology is a fundamental tool for reconstructing earth history and constraining the timing of ore deposit formation. Traditionally, U-rich minerals like zircon, titanite, monazite and apatite have been analysed to determine the timing of mineralization and alteration events. However, not all deposits or alteration assemblages contain these minerals, and the U-Pb system can be disturbed due to open system behaviour. We present a methodology for obtaining in-situ Lu-Hf dates from various minerals to demonstrate the potential for dating ore deposits that lack U-rich minerals. Carbonate, apatite and fluorite minerals from different tectonic settings and geological environments were analysed. We acquired Lu-Hf and REE (rare earth element) data from carbonate minerals from a carbonatite orebody and dike samples from the Mountain Pass REE carbonatite deposit in California, USA. We also tested a ‘double-dating’ method, where U-Th-Pb dates and Lu-Hf dates were obtained from the same analysis of apatite from rocks in the Michigan’s Great Lakes Tectonic Zone. Preliminary results for Lu-Hf dating of fluorite from carbonatite rocks in the Lemitar Mountains of New Mexico are also included. The analytical methodology shows promising results in each of these cases where there is sufficient parent Lu and U and measurable daughter Hf and Pb respectively.

Conference Paper

Revision of ModelMuse to support the use of PEST software with MODFLOW and SUTRA models

Executive Summary ModelMuse is a graphical user interface for several groundwater modeling programs. ModelMuse was updated to generate the input files for the parameter estimation software suite PEST. The software is used with MODFLOW or SUTRA models to run PEST-based parameter estimation and display the updated model inputs after parameter estimation. The PEST input files can also be used with the PEST++ version 5 software suite. Parameter estimation typically requires defining the parameters being adjusted during calibration and observations for assessing calibration quality. After a parameter is defined in ModelMuse, it can be applied to all or part of a model dataset. Pilot points—a parameterization device that facilitates higher levels of parameterization—can be used to assign spatially variable distributions of model inputs. Parameters can be applied to temporally varying features, such as boundary conditions, by either applying them to all the values in a series in one step or by applying separate parameters to individual members of a series. ModelMuse allows the definition of many observation types from various model output files. For MODFLOW 6 and SUTRA models, new options were added to ModelMuse to allow it to display the changed input after parameter estimation is complete. For MODFLOW–2005 and MODFLOW–NWT models, ModelMuse can import an entire model for visualization. An example illustrates the use of PEST with a MODFLOW 6 model in ModelMuse.

Techniques and Methods

Bathymetric and velocimetric surveys at highway bridges crossing the Missouri River near Kansas City, Missouri, August 8–9, 2023

Bathymetric and velocimetric data were collected by the U.S. Geological Survey, in cooperation with the Missouri Department of Transportation, near 8 bridge crossings of the Missouri River near Kansas City, Missouri, on August 8–9, 2023. A multibeam echosounder mapping system was used to obtain channel-bed elevations for river reaches that extended about 1,550 to 1,640 feet longitudinally and generally extended laterally across the active channel from bank to bank during low floodflow to nonflood conditions. These surveys provided the channel geometry and hydraulic conditions of the river at the time of the surveys and provided characteristics of scour holes, which may be useful in developing or verifying predictive guidelines or equations for computing potential scour depth. The data collected from the surveys may also be useful to the Missouri Department of Transportation as a record of low floodflow conditions in regards to the stability and integrity of the bridges with respect to bridge scour. Bathymetric data were collected around every in-channel pier. Scour holes were at most piers where bathymetry could be obtained, except for those piers on banks or surrounded by riprap. All the bridge sites in this study were surveyed and documented in previous studies. The average difference between the bathymetric surfaces ranged from 0.07 to 4.16 feet higher in 2023 than 2019, which indicates overall deposition between the survey dates, as might be expected based purely on streamflow at the time of the survey. However, the average difference between the bathymetric surfaces ranged from 1.44 feet higher to 1.88 feet lower in 2023 than 2015, which indicates a dynamic equilibrium of scour and deposition overall between those surveys, despite the lower flow conditions in 2023. Similarly, the average difference between the bathymetric surfaces ranged from 3.18 feet higher to 5.19 feet lower in 2023 than 2011, which indicates a relative equilibrium between scour and deposition overall, albeit the trend was toward scour as might be expected because of the substantial flood event in 2011. Riprap blankets and alignment to flow had a substantial effect on the size of the scour hole for a given pier. Piers that were partially or fully surrounded by riprap blankets had scour holes that were substantially smaller (to nonexistent) compared to piers with no rock or riprap and effectively mitigated the scour holes historically observed at these piers. Several of the structures had piers that were skewed to primary approach flow. At most of the structures, the scour hole was deeper and longer on the side of the pier with impinging flow than the leeward side, with some amount of deposition on the leeward side, as typically observed at piers skewed to approach flow.

Kansas, Missouri

Water-quality assessment of the Ozark Plateaus study unit, Arkansas, Kansas, Missouri, and Oklahoma — Nutrients, bacteria, organic carbon, and suspended sediment in surface water, 1993-95

Nutrient, bacteria, organic carbon, and suspended- sediment samples were collected from 1993-95 at 43 surface-water-quality sampling sites within the Ozark Plateaus National Water- Quality Assessment Program study unit. Most surface-water-quality sites have small or medium drainage basins, near-homogenous land uses (primarily agricultural or forest), and are located predominantly in the Springfield and Salem Plateaus. The water-quality data were analyzed using selected descriptive and statistical methods to determine factors affecting occurrence in streams in the study unit. Nitrogen and phosphorus fertilizer use increased in the Ozark Plateaus study unit for the period 1965-85, but the application rates are well below the national median. Fertilizer use differed substantially among the major river basins and physiographic areas in the study unit. Livestock and poultry waste is a major source of nutrient loading in parts of the study unit. The quantity of nitrogen and phosphorus from livestock and poultry wastes differed substantially among the river basins of the study unit's sampling network. Eighty six municipal sewage-treatment plants in the study unit have effluents of 0.5 million gallons per day or more (for the years 1985-91). Statistically significant differences existed in surface-water quality that can be attributed to land use, physiography, and drainage basin size. Dissolved nitrite plus nitrate, total phosphorus, fecal coliform bacteria, and dissolved organic carbon concentrations generally were larger at sites associated with agricultural basins than at sites associated with forested basins. A large difference in dissolved nitrite plus nitrate concentrations occurred between streams draining basins with agricultural land use in the Springfield and Salem Plateaus. Streams draining both small and medium agricultural basins in the Springfield Plateau had much larger concentrations than their counterparts in the Salem Plateau. Drainage basin size was not a significant factor in affecting total phosphorus, fecal coliform bacteria, or dissolved organic carbon concentrations. Suspended-sediment concentrations generally were small and indicative of the clear water in streams in the Ozark Plateaus. A comparison of the dissolved nitrite plus nitrate, total phosphorus, and fecal coliform data collected at the fixed and synoptic sites indicates that generally the data for streams draining basins of similar physiography, land-use setting, and drainage basin size group together. Many of the variations are most likely the result of differences in percent agricultural land use between the sites being compared or are discharge related. The relation of dissolved nitrite plus nitrate, total phosphorus, and fecal coliform concentration to percent agricultural land use has a strong positive 2 Water-Quality Assessment-Nutrients, Bacteria, Organic Carbon, and Suspended Sediment in Surface Water, 1993-95 correlation, with percent agricultural land use accounting for between 42 and 60 percent of the variation in the observed concentrations.

Arkansas, Kansas, Missouri, Oklahoma

A multidisciplinary approach that considers occurrence, geochemistry, bioavailability, and toxicity to prioritize critical minerals for environmental research

Critical minerals (or critical elements) are minerals or elements that are essential to global security and development and have supply chains vulnerable to disruption. In general, knowledge of the environmental behavior and health effects of critical elements is needed to support the development of safe and environmentally responsible supplies. This knowledge includes identifying potential consequences of increased critical element production and use, alternative critical element sources such as mine wastes, and adverse effects of critical elements on ecosystem condition and organismal health. Here we identify significant data gaps in the understanding of critical elements in surficial and aquatic environments, and the need, given the large number of commodities (50) identified on the 2022 critical minerals list for the United States, for an approach to prioritize them for study of their environmental fate and effects. We propose a multidisciplinary approach for this prioritization, considering measures of occurrence, geochemistry, bioavailability, and toxicity. We describe relatively easy-to-obtain metrics for each of these topic areas and demonstrate the utility of this integrated prioritization approach using indium and zinc as examples. This approach facilitates prioritizing research with a focus on those critical elements that are most mobile in the environment, bioavailable, toxic, or simply lacking data in these categories.

Environmental Science & Technology

Bathymetric and velocimetric surveys at highway bridges crossing the Missouri and Mississippi Rivers on the periphery of Missouri, June 13–22, 2022

Bathymetric and velocimetric data were collected by the U.S. Geological Survey, in cooperation with the Missouri Department of Transportation, near seven bridges at six highway crossings of the Missouri and Mississippi Rivers on the periphery of Missouri from June 13–22, 2022. A multibeam echosounder mapping system was used to obtain channel-bed elevations for river reaches about 1,640 feet longitudinally and generally extending laterally across the active channel from bank to bank during minor flood-flow conditions. These surveys provided channel geometry and hydraulic conditions at the time of the surveys and provided characteristics of scour holes that may be useful in developing or verifying predictive guidelines or equations for computing potential scour depth. These data also may be useful to the Missouri Department of Transportation as a minor flood-flow assessment of the bridges for stability and integrity issues with respect to bridge scour during floods. Bathymetric data were collected around every in-channel pier. Scour holes were present at most piers for which bathymetry could be obtained, except those on banks or surrounded by riprap. Occasionally, scour holes were minor and difficult to discern from nearby dunes and ripples. All bridge sites in this study were surveyed and documented in previous studies. Although partial exposure of substructural support elements was observed at several piers, at most sites the exposure most likely is minimal compared to the overall substructure that remains buried in bed material at these piers. The notable exceptions are piers 12 and 13 at structure L0135 on State Highway 51 at Chester, Illinois, where the bedrock material was fully exposed around the piers. The average difference between the bathymetric surfaces between 2022 and 2018 varied from 0.41 foot higher to 1.86 feet lower. Between 2022 and 2014, the average difference between the bathymetric surfaces varied from 1.02 feet higher to 4.69 feet lower. Only the two sites on the Missouri River and the Caruthersville site were surveyed in 2011; for those sites, the average difference between the bathymetric surfaces varied from 5.83 feet higher to 1.34 feet lower. The most substantial overall net gain of sediment in a reach was between 2011 and 2022 at structure A1700 near Caruthersville, Mo. (site 38). This result was expected because structure A1700 is downstream from the confluences of the Missouri and Ohio Rivers, and therefore subject to the largest streamflows, the largest streamflow fluctuations, and the most substantial sediment flux, as has historically been observed at this site. The presence of riprap blankets, pier size and nose shape, and alignment to flow had a substantial effect on the size of the scour hole observed for a given pier. Piers that were surrounded by riprap blankets had scour holes that were substantially smaller (to nonexistent) compared to piers at which no rock or riprap were present. New riprap blankets were surveyed at pier 3 of structure L0098 at Brownville, Nebraska, and at piers 15–18 of structure A1700 near Caruthersville, Mo., that effectively mitigated the scour holes historically observed at these piers. Narrow piers having round or sharp noses that were aligned with flow often had scour holes that were difficult to discern from nearby bed features, whereas piers having wide or blunt noses resulted in larger, deeper scour holes. Several of the structures had piers that were skewed to primary approach flow. Scour holes near these piers consistently displayed greater depth on the side of the pier with impinging flow and deposition on the leeward side of the pier.

Missouri

Late Jurassic igneous rocks in south-central Arizona and north-central Sonora: Magmatic accompaniment of crustal extension

In Middle Jurassic time, the region of south-central Arizona and north-central Sonora was part of a continental magmatic arc. In early Late Jurassic time, this magmatic arc gradually gave way to a extensional regime. Late Jurassic rifting was accompanied by magmatism, typically small in volume relative to the preceding arc phase, and with mildly alkaline compositions. These igneous rocks, the 158- to 146-Ma Ko Vaya Suite, make up much or most of the Comobabi, Artesa, Quijotoa, and Brownell Mountains and Sierra del Cobre. The bimodal Ko Vaya Suite constitutes volcanic to shallow plutonic complexes comprising chiefly trachyandesite and volcanic wacke; monzodiorite; rhyolite porphyry; distinctive, compositionally and texturally heterogeneous, quartzpoor granite (the Ko Vaya Granite); A-type perthite granite and quartz syenite; aphyric intrusive rhyolite; and locally abundant hematite veins. Alteration, particularly potassic alteration, is widespread. Minimally altered samples of granite and quartz syenite have the composition of trachyte or trachydacite and alkali rhyolite. The Ko Vaya Suite is nonconformably overlain by the latest Jurassic Sand Wells Formation, approximately correlative with the Glance Conglomerate, the basal unit of the Bisbee Group. The Ko Vaya Suite is in some ways analogous to the coeval Independence dike swarm of eastern California, but less diffuse. We infer that the Ko Vaya Suite represents especially intense or focused Late Jurassic extensional magmatism.

Arizona, Sonora

Groundwater-storage change in the north Phoenix aquifer, Arizona, 2020–23

The city of Phoenix, Arizona, relies primarily on surface water for municipal water supply. The city also maintains wells to withdraw groundwater, particularly in times of drought and reduced surface-water supply, and to recharge groundwater when excess surface water is available. As of 2023, withdrawals from the aquifer in the northeastern part of the city are a small volume of water, less than 3,000 acre-feet in most years. Each year a similar volume of water is recharged through injection wells. The withdrawal wells are permitted to produce in total more than 20,000 acre-feet per year; increased pumping could lead to future groundwater-storage declines. To better understand groundwater-storage change in the north Phoenix aquifer, a repeat microgravity monitoring network was established in 2020. Measurements of changes in Earth’s gravity provide a direct, non-invasive measurement of subsurface mass change. Groundwater-storage changes were small during the 2020–23 study period, consistent with the relatively small volumes of pumping and recharge. Groundwater levels measured in monitoring wells were stable or increased slightly during this period, although the number of monitoring wells within the area of the gravity monitoring network is sparse. In total, about 15,000 acre-feet of water were pumped and 31,000 acre-feet recharged through injection in the north Phoenix aquifer during the 2020–22 period. Within the monitored area, groundwater storage increased by a small amount, about 1,000 acre-feet, in 2020, and decreased by a larger amount, about 6,000 acre-feet, each year in 2021 and 2022. Storage decreased at 89 of 102 stations from 2020 to 2023. Groundwater-storage decreases greater than the volume of net pumping indicate down-gradient subflow from the aquifer is greater than recharge plus incoming subflow, drying of the unsaturated zone resulting from decreased land-surface recharge, or both. At present (2023), the aquifer appears able to store and supply the relatively small amounts of water needed without excessive drawdown or harmful effects, such as land subsidence and surface inundation. If pumping or recharge increases in the future, the established repeat microgravity network is well suited to capture the spatial extent and magnitude of groundwater-storage changes in the aquifer.

Arizona

ShakeAlert®—Communication, education, outreach and technical engagement strategic vision

Executive Summary In 2006, the U.S. Geological Survey (USGS) began directly supporting ShakeAlert ® research and in 2012 the ShakeAlert demonstration system began testing ( Given and others, 2018 ). The ShakeAlert earthquake early warning (EEW) system is a partnership between the U.S. Geological Survey (USGS) and the three West Coast States (Washington, Oregon, and California) served by the ShakeAlert System, which is part of the larger Advanced National Seismic System (ANSS). With more than 143 million people exposed to potentially damaging shaking in the United States ( Jaiswal and others, 2015 ), earthquakes are a national hazard. Most of our Nation’s earthquake risk is concentrated in the highly populated areas on the active plate tectonic boundaries on the West Coast of the conterminous United States. ShakeAlert is the first public alert system in the United States to provide rapid mass notification of earthquake detection, potentially offering seconds of warning before strong shaking arrives. A few seconds may not seem like much time, but the information in ShakeAlert Messages can be used to trigger automated actions that can prevent injury or death, reduce immediate damage, and speed recovery from earthquakes. The information product issued by the ShakeAlert system is called a ShakeAlert Message and is one of the information products and tools of the ANSS. The ShakeAlert System includes the USGS component, plus the pathways by which ShakeAlert-powered products and (or) services are delivered to end users. Alerts can be delivered to cell phones or be used to trigger automated systems to protect equipment, facilities, and infrastructure, such as slowing or stopping a train. ShakeAlert-powered automated actions can include fire house doors that can be opened to prevent jamming, heavy equipment (for example, trains, elevators, and cranes) that can be automatically stopped or parked in safe positions, and pipeline valves that can be closed to prevent surges and spills. A few seconds of warning also may be sufficient for people to take protective actions, such as drop, cover, and hold on or modified protective actions for a broad range of populations. Advance training may increase the benefit of a speedy response to an alert. Outreach and education about EEW may raise awareness of the overall earthquake threat and how people can best react when they receive an alert or feel shaking. ShakeAlert communication, education, outreach, and technical engagement (CEO&TE) efforts are highly collaborative and essential for the success of the ShakeAlert System. This strategic vision informs how the vast ShakeAlert CEO&TE Community operates and works together. The CEO&TE Community delineates a strategic framework that is intended to set the path for a long-term, sustainable approach to CEO&TE through three focus areas and five priorities. Focus Areas Technical engagement.— The objective of this focus area is to expand and broaden ShakeAlert technical engagement and implementation. External engagement.— This focus area targets engagement in long-term communication, education, and outreach planning, implementation, and evaluation. Internal engagement.— The purpose of this focus area is to build and sustain a robust infrastructure to optimize collaboration, information sharing, and project planning among the community of stakeholders charged with implementing ShakeAlert CEO&TE. Priorities The enumeration of the five priorities listed below does not suggest priority ranking. Public safety, preparedness, and resilience; Technical implementation and engagement; Consistent messaging and communication; Integration with other Federal and State earthquake hazards products; and Educational resources development and dissemination. This strategic vision is a tangible outcome of collaboration among many stakeholders beginning in July 2016. Since then, the work of the ShakeAlert CEO&TE Community has grown into an international effort. The USGS has developed, tested, and implemented a broad spectrum of communication, education, and outreach tools and resources—all of which recognize that seconds matter when it comes to safety and mitigating harm from earthquake hazards. The CEO&TE social science research effort has provided invaluable insights into the ShakeAlert System’s human interface. USGS-licensed technical partners develop, test, and implement real-world applications using ShakeAlert Messages. The success of ShakeAlert CEO&TE efforts is predicated on robust collaboration across numerous agencies, organizations, and groups. As such, this strategic vision outlines a “partnership model” that delineates roles and responsibilities to ensure alignment with focus areas and priorities. The partnership model includes the CEO&TE lead agency (USGS); its principal partners (State agencies and university partners); its implementation partners (for example, technical partners who build systems to deliver ShakeAlert-powered products and (or) services [focus area one]), earthquake education partners who work to increase public preparedness for seismic events (focus area two); and other organizations that work together to enhance the adoption and effectiveness of the ShakeAlert System. These partners collaborate and convene through a variety of working groups and forums, which are also described in this strategic vision and align with focus area three (internal engagement). The CEO&TE Community collaboratively developed its operating principles and a consensus-based, decision-making strategic framework to guide its collective work. Performance metrics are used to continually measure success. Ultimately, the USGS and ShakeAlert CEO&TE Community are advancing the ShakeAlert System that as of the publication of this strategic vision to “provide earthquake early warning for all” serves more than 50 million people.

Circular

Ambient flow and transport in long-screened, sand-packed wells: Insights into cross contamination and wellbore flow

The presence of long-screened wells with a surrounding sand pack can have a major effect on the redistribution of contaminants in groundwater, particularly when the wells are set in low-hydraulic conductivity aquifers. Such redistribution, or cross contamination, can occur through vertical flow and advective transport or by in-well mixing via multiple non-advective transport processes. A multi-method approach, including the use of single borehole dilution tracer (SBDT) logging, was undertaken to estimate vertical transport of trichloroethylene (TCE) in 8 discontinued remedial extraction wells, all constructed with long screens (100 ft, or 30.6 m long) and surrounding sand packs, at Site 25, Edwards Air Force Base, California. The site is within an enclosed drainage basin that is underlain primarily by quartz-monzonite-granitic rocks in various states of weathering. Prior to this study, little information was available on the depths of fracture zones intersecting the wellbores. Results indicate that because of in-well mixing processes, a potential redistribution of TCE of up to 9 g/d per well occurs as a consequence of leaving the wells inactive (unpumped) and unsealed, as measured by SBDT logging. Simulations of flow made with a generic model of the site show that if the wells were to be sealed with well liners, with the intent of reducing vertical TCE transport but the sand pack left intact, TCE transport decreases by 53% overall compared to leaving the wells unlined.

Environmental Earth Sciences

The U.S. Geological Survey National Water Quality Network—Groundwater, 2024

The U.S. Geological Survey (USGS) operates a National Water Quality Network (NWQN) to monitor trends in groundwater quality and assess emerging contaminants of concern. It is a “network of networks” with 81 subnetworks being sampled on a decadal time scale. Each year, 8 of the subnetworks are sampled. Subnetworks have 20–30 wells each and include studies of domestic supply wells or shallow groundwater (20–50 feet deep) underlying urban land use or agricultural land use. Currently there are 2,089 wells in the network. All wells are sampled for physical properties, nutrients, major ions, trace elements, per- and polyfluoroalkyl substances (PFAS), and a subset of wells are sampled for pesticides, volatile organic compounds, radionuclides, and microbiological contaminants.

Contiguous United States

Managing basin-scale carbon sequestration: A tragedy of the commons approach

The Tragedy of the Commons is a well studied problem in the literature of ecology, economics, and environmental policy which illustrates the deleterious consequences of managing common pool resources when individual and social incentives are misaligned. In this work, we apply a simple model of carbon sequestration in a deep saline aquifer by two neighboring geologic CO 2 storage (GCS) operators to begin investigating if a Tragedy of the Commons framework applies to GCS. Specifically, we consider the pressure space as a “commons” because the injection by each firm at its own well increases the downhole injection pressure at both wells. We assume that a firm will decrease its injection rate if the downhole pressure at its well exceeds a predefined maximum (i.e., exceeds the “pressure limit”). With this assumption in place, we find that the same injection flowrates are optimal for both wells, regardless of whether they are owned by the same firm or competing firms. This suggests that GCS may not be best represented by a pure Tragedy of the Commons framework under our initial assumptions. However, there could be economic incentives or contractual obligations that may result in either or both GCS operators being unwilling to reduce their injection rates. Thus, we conclude the conference paper with a discussion of future extensions of our approach that may demonstrate closer alignment with the Tragedy of the Commons, including explicit definitions of pore-space rights, firm uncertainty regarding the parameters of the Theis equation, and the potential role of unitization.

Conference Paper

Only very strong shaking can break a tree

A handful of credible accounts, both recent and historical, describe trees being broken during earthquakes. Apart from landslides and tsunamis, such accounts are uncommon, suggesting that trees break only when ground acceleration is extreme or when trees are especially vulnerable to breakage. Here, I consider the question: what ground acceleration is required to break a living tree? I present simplified first‐principles calculations, considering the properties of common trees, focusing on tall, thin trees that can be approximated as uniform vertical cantilevers. The results suggest that, possibly excepting tall trees with heavy canopies, standing trees can only be broken by shaking approaching or exceeding 1 g , as anticipated by the rarity of documented accounts of snapped trees. I briefly consider several well‐documented instances of tree damage during strong earthquakes, drawing inferences about local ground motions.

The Seismic Record

Rapid emplacement of the Keaiwa Lava Flow of 1823 from the Great Crack in the Southwest Rift Zone of Kilauea volcano

The Keaīwa Lava Flow of 1823 in the Southwest Rift Zone of Kīlauea volcano is unusual for its expansive pāhoehoe sheet flow morphology and lack of constructive vent topography, despite having a similar tholeiitic basalt composition to other lavas erupted from Kīlauea. This lava flow issued from a ∼10-km-long continuous fissure now known as the Great Crack, and has an unusually thin sheet flow morphology with margin thicknesses of ∼15–110 cm (average of 42 cm). Based on field observations of the lava flow at its fissure vent (e.g., drain-back features), we propose that the Great Crack formed, or at least significantly widened, just prior to and syn-eruptively with this 1823 eruption. The absence of pyroclastic cones or spatter ramparts indicates that the eruption consisted of a rapid outpouring of relatively degassed lava as the fissure unzipped. The rapidly moving lava flow overtopped pre-existing tumuli and scoria cones (e.g., Lava Plastered Cones) up to ∼10 m tall. Glass and whole-rock chemistry yield homogeneous compositions for the lavas erupted from the Great Crack, with glass compositions of 6.40 ± 0.10 wt% MgO and whole-rock compositions of 7.39 ± 0.07 wt% MgO. Lava pads erupted from a short western fissure system are richer in mafic minerals (e.g., olivine and clinopyroxene), and show slightly more MgO-rich whole-rock compositions (7.79 ± 0.05 wt%). MgO-in-glass thermometry on juvenile spatter yield eruption temperatures of 1153 ± 13°C that are typical of Kīlauea lavas. Thus, the extensive sheet-like lava flow morphology is not a direct consequence of unusual magmatic or rheological conditions (i.e., low viscosity). Instead, the flow morphology is associated with high effusion rates caused by sudden drainage of uprift magma as it erupted from the Great Crack. Lava flow modeling on a 2-m-resolution digital elevation model indicates that a minimum bulk effusion rate of ∼5800 m 3 /s (∼3500 m 3 /s dense rock equivalent) and a minimum flow velocity of ∼11 m/s are required for the lava flow to overcome the topography of the Lava Plastered Cones. This effusion rate is among the highest inferred for eruptions in Hawaiʻi and around the world. This study highlights a less frequent eruption style at Hawaiian volcanoes characterized by a sudden outpouring of lava from an unusual fissure system. Local eyewitness accounts indicate that the 1823 eruption was preceded by seismicity. Given the complex magmatic-volcanic-tectonic relations across Kīlauea, we speculate that the south flank could have slipped over one or more events that ultimately triggered unzipping of the Great Crack and passive release of briefly stored uprift magma. An eruption similar to 1823 at Kīlauea or Mauna Loa, with an eruptive timeframe that could be as short as an hour, with high effusion rates and rapid flow front velocities, would not easily allow for a timely response.

Hawaii

Statistical approaches for modeling correlated grade and tonnage distributions and applications for mineral resource assessments

Correlations between grade and tonnage exist in mineral resource data compiled from published reports, but they are not always addressed during quantitative assessment of undiscovered mineral resources. Failure to account for correlated grade and tonnage distributions can result in geologically unrealistic assessment results. Current software tools simulate univariate ore tonnage and multivariate resource grades of undiscovered deposits independently. As a result, analysts are forced to rely on ad-hoc solutions to minimize the correlation issues by: 1) creating subsets of data with restricted criteria; 2) truncating grade and tonnage distributions; and 3) testing model robustness using exploratory data analysis. While these methods represent pragmatic solutions, the statistical solutions presented here provide additional options to address real correlations in grade and tonnage data used for mineral resource assessments. We present a modified version of the MapMark4 package in R that introduces two alternatives for modeling grade and tonnage distributions, consisting of a multivariate solution that accounts for correlations between ore tonnage and metal grades and an empirical solution that utilizes simple random sampling with replacement to reproduce coupled grades and tonnages from the input data. We present simulations for contained ore and metal for three case studies representing tungsten skarn, komatiite-hosted nickel, and sediment-hosted carbonate amagmatic zinc-lead (Mississippi Valley-type) deposits. Employing the methods presented here yields quantitative mineral resource assessment results that more closely reflect the empirical distributions of grades and tonnages observed in nature and expands the applicability of these tools for ongoing critical mineral resource assessments.

Applied Computing and Geosciences

Where will the cat cross the road? Comparing camera and GPS-based models for identifying wildlife corridors

Designing effective wildlife corridors is a critical conservation challenge in fragmented landscapes. GPS-based step selection functions strongly predict dispersal corridors and connectivity, but GPS collaring can be expensive and invasive. Camera-based occupancy models are widely used for connectivity analyses but may involve trade-offs in data resolution. Despite widespread use of both approaches, few studies have directly compared them using concurrent datasets. We developed a stacked single-species, single-season occupancy model and a Circuitscape connectivity surface for mountain lions (Puma concolor) on Washington’s Olympic Peninsula, USA, and compared them with a connectivity surface from an existing integrated step selection function. Both models predicted mountain lion GPS locations well, with binned Spearman rank correlations of 1 for Circuitscape and 0.96 for the step selection function, though step selection better identified habitat use by dispersers. Connectivity predictions were moderately correlated across the landscape ( r = 0.26), but agreement was strongest in human-dominated areas most critical for corridor planning. We conclude that GPS-based approaches are advantageous when data collection is feasible and the focus is on dispersal or fine-scale movement. However, camera-based approaches may be preferable for multi-species monitoring, large spatial and temporal scales, noninvasive sampling, when resources are limited, or when fine-scale or dispersal-specific inference is not required.

Washington