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USGS1991

Hydrogeologic inferences from drillers' logs and from gravity and resistivity surveys in the Amargosa Desert, southern Nevada

The Amargosa Desert of southern Nevada, in the Basin and Range province, is hydraulically downgradient from Yucca Mountain, the potential site of a repository for high-level nuclear waste. Groundwater flow paths and flow rates beneath the Amargosa Desert are controlled in part by the total saturated thickness and the hydraulic properties of basin-fill alluvial sediments. Drillers' logs of water wells completed in alluvium were analyzed to help characterize the hydrogeologic framework underlying the Amargosa Desert. Fractions of coarse-grained sediments, calculated from each of these logs, were contoured using a universal-kriging routine to interpolate values. Results from a previous electrical sounding survey also were contoured, including the estimated depth to Paleozoic (?) basement rocks. The vertical electric sounding results were obtained from individual depth-to-resistivity profiles, from which the average resistivity of the total profile and the resistivity of the upper 75 m were calculated. The distribution and variations in average resistivity of the total depth correlated reasonably well with the distribution of variations in regional gravity. Patterns of contours of the resistivity of the upper 75 m of alluvium were similar to patterns of regional contours of the predominant cation (sodium) in ground water. Gravity lows correspond in some places to the presence of lacustrine, eolian, or marsh surface deposits, which may function as barriers to groundwater flow. Gravity lows also correspond to areas with thick basin-fill sediments, which was corroborated by depth-to-basement data determined from vertical electric soundings. Depths to Paleozoic (?) basement rocks may be as much as 1600 m based on data from the resistivity survey, which were corroborated in part by seismic-refraction survey data. Small variations exist in the percentage of the basin fill that is saturated. The unsaturated zone is always < 15% of the alluvial column. Analysis of depth-to-water and hydrochemical data, in conjunction with average resistivity data for the upper 75 m of alluvium, suggest a hydrologic barrier near the center of the Amargosa Desert.

Nevada↗

USGS2007

Role of aquifer heterogeneity in fresh groundwater discharge and seawater recycling: An example from the Carmel coast, Israel

A case study is shown in which the pattern of submarine groundwater discharge and of seawater recycling is controlled by local hydrogeological variability. The coastal aquifer in Dor Bay is composed of two units: a partly confined calcaranitic sandstone (Kurkar) and an overlying loose sand. Groundwater in the Kurkar has elevated activities of 222 Rn (∼390 dpm/L) and relatively low 224 Ra/ 223 Ra activity ratios (3–4), while the sand groundwater is significantly less radiogenic (6–90 dpm/L) and shows higher 224 Ra/ 223 Ra ratios. Groundwater discharging from sand-covered areas of the bay has salinities of 16–31 and an average 222 Rn activity of 168 dpm/L, which lies on a mixing line between Rn-rich Kurkar fresh water and Rn-poor seawater. Another key observation is that seawater infiltrates to some extent into onshore sand groundwater, while the fresh water within the submarine Kurkar can be traced up to 40 m offshore. This implies that while fresh water mainly discharges from the Kurkar unit, seawater recycling is limited to the loose sand, and that the discharge from sand-covered areas is a mixture of Kurkar water with recycled seawater. Advection rates from the bay floor were calculated from Rn time series and found to vary between 0 and 36 cm/d, correlating negatively with bay water depth. The average flux was 8.1 cm/d, and it did not seem to change much during March, May, and July 2006. The average amount of fresh water discharging to the bay was 5.0 m 3 /d per meter of shoreline. Radon activity in the sand groundwater also fluctuates due to influx of Kurkar-type groundwater.

Carmel Coast, Dor Bay↗

USGS2011

Using Cl/Br ratios and other indicators to assess potential impacts on groundwater quality from septic systems: A review and examples from principal aquifers in the United States

A detailed review was made of chemical indicators used to identify impacts from septic tanks on groundwater quality. Potential impacts from septic tank leachate on groundwater quality were assessed using the mass ratio of chloride–bromide (Cl/Br), concentrations of selected chemical constituents, and ancillary information (land use, census data, well depth, soil characteristics) for wells in principal aquifers of the United States. Chemical data were evaluated from 1848 domestic wells in 19 aquifers, 121 public-supply wells in 6 aquifers, and associated monitoring wells in four aquifers and their overlying hydrogeologic units. Based on previously reported Cl/Br ratios, statistical comparisons between targeted wells (where Cl/Br ratios range from 400 to 1100 and Cl concentrations range from 20 to 100 mg/L) and non-targeted wells indicated that shallow targeted monitoring and domestic wells (<20 m depth below land surface) had a significantly ( p < 0.05) higher median percentage of houses with septic tanks (1990 census data) than non-targeted wells. Higher ( p = 0.08) median nitrate–N concentration (3.1 mg/L) in oxic (dissolved oxygen concentrations >0.5 mg/L) shallow groundwater from target domestic wells, relative to non-target wells (1.5 mg/L), corresponded to significantly higher potassium, boron, chloride, dissolved organic carbon, and sulfate concentrations, which may also indicate the influence of septic-tank effluent. Impacts on groundwater quality from septic systems were most evident for the Eastern Glacial Deposits aquifer and the Northern High Plains aquifer that were associated with the number of housing units using septic tanks, high permeability of overlying sediments, mostly oxic conditions, and shallow wells. Overall, little or no influence from septic systems were found for water samples from the deeper public-supply wells. The Cl/Br ratio is a useful first-level screening tool for assessing possible septic tank influence in water from shallow wells (<20 m) with the range of 400–1100. The use of this ratio would be enhanced with information on other chloride sources, temporal variability of chloride and bromide concentrations in shallow groundwater, knowledge of septic-system age and maintenance, and the use of multiple tracers (combination of additional chemical and microbiological indicators).

Journal of Hydrology↗

USGS2007

Hydrogeology and paths of flow in the carbonate bedrock aquifer, northwestern Indiana

The U.S. Geological Survey (USGS) is assessing the ground.water resources of the carbonate bedrock aquifers in Indiana and Ohio as part of their Regional Aquifer Systems Analysis program. Part of this assessment includes the determination of unknown aspects of the hydraulic characteristics, boundaries, and flow paths of the carbonate aquifer. To accomplish this, the USGS drilled three wells through the carbonate aquifer near the Kankakee River in northwestern Indiana. Geophysical logs were used to help determine depths and thicknesses for testing and to help describe geology at the three wells. Packer tests were used to determine direction of ground-water flow and to provide data for an analysis of the distribution of transmissivity in the carbonate aquifer. Transmissivity of the carbonates is associated with two physical characteristics of the rocks: fractures and interconnected porosity. Almost all of the transmissivity is derived from horizontal fracturing; however, only a few of the fractures present in the carbonate are transmissive. Some transmissivity is associated with a zone of fossiliferous, vuggy dolomite, which yields water from the rock matrix. Most of the transmissivity is associated with large fractures and solution crevices in the upper 30 feet of the bedrock; less transmissivity is associated with the deeper vuggy reef material, even where extensively fractured. Transmissivity of individual fractures and fossiliferous zones ranges from 300 to 27,000 feet squared per day. The aquifer bottom is defined by a lack of transmissive fractures and an increased shale content near the contact of the Silurian and Ordovician sections. Water-level data from the three wells indicate that flow is horizontal at well site 1 north of the Kankakee River, upward at well site 2 near the river, and downward at well site 3 south of the river. Most of the flow occurs in the upper part of the carbonate bedrock where fracturing and solution-enlarged crevices are most developed. Water levels indicate the the Kankakee River is a hydrologic boundary for the regional carbonate bedrock aquifer.

Indiana↗

USGS2010

Trends and transformation of nutrients and pesticides in a Coastal Plain aquifer system, United States

Four local-scale sites in areas with similar corn (Zea mays L.) and soybean [Glycine max (L.) Merr.] agriculture were studied to determine the effects of different hydrogeologic settings of the Northern Atlantic Coastal Plain (NACP) on the transport of nutrients and pesticides in groundwater. Settings ranged from predominantly well-drained soils overlying thick, sandy surficial aquifers to predominantly poorly drained soils with complex aquifer stratigraphy and high organic matter content. Apparent age of groundwater, dissolved gases, N isotopes, major ions, selected pesticides and degradates, and geochemical environments in groundwater were studied. Agricultural chemicals were the source of most dissolved ions in groundwater. Specific conductance was strongly correlated with reconstructed nitrate (the sum of N in nitrate and N gas) (R 2 = 0.81, p < 0.0001), and is indicative of the relative degree of agricultural effects on groundwater. Trends in nitrate were primarily related to changes in manure and fertilizer use at the well-drained sites where aquifer conditions were consistently oxic. Nitrate was present in young groundwater but completely removed over time through denitrification at the poorly drained sites where there were variations in chemical input and in geochemical environment. Median concentrations of atrazine (6-chloro-N-ethyl-N'-(1- methylethyl)-1,3,5-triazine-2,4-diamine), metolachlor (2-chloro-N-(2-ethyl-6- methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide), and some of their common degradates were higher at well-drained sites than at poorly drained sites, with concentrations of degradates generally higher than those of the parent compounds at all sites. An increase in the percentage of deethylatrazine to total atrazine over time at one well-drained site may be related to changes in manure application. Copyright ?? 2010 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗

USGS2007

Linking ground-water age and chemistry data along flow paths: Implications for trends and transformations of nitrate and pesticides

Tracer-based ground-water ages, along with the concentrations of pesticides, nitrogen species, and other redox-active constituents, were used to evaluate the trends and transformations of agricultural chemicals along flow paths in diverse hydrogeologic settings. A range of conditions affecting the transformation of nitrate and pesticides (e.g., thickness of unsaturated zone, redox conditions) was examined at study sites in Georgia, North Carolina, Wisconsin, and California. Deethylatrazine (DEA), a transformation product of atrazine, was typically present at concentrations higher than those of atrazine at study sites with thick unsaturated zones but not at sites with thin unsaturated zones. Furthermore, the fraction of atrazine plus DEA that was present as DEA did not increase as a function of ground-water age. These findings suggest that atrazine degradation occurs primarily in the unsaturated zone with little or no degradation in the saturated zone. Similar observations were also made for metolachlor and alachlor. The fraction of the initial nitrate concentration found as excess N2 (N2 derived from denitrification) increased with ground-water age only at the North Carolina site, where oxic conditions were generally limited to the top 5??m of saturated thickness. Historical trends in fluxes to ground water were evaluated by relating the times of recharge of ground-water samples, estimated using chlorofluorocarbon concentrations, with concentrations of the parent compound at the time of recharge, estimated by summing the molar concentrations of the parent compound and its transformation products in the age-dated sample. Using this approach, nitrate concentrations were estimated to have increased markedly from 1960 to the present at all study sites. Trends in concentrations of atrazine, metolachlor, alachlor, and their degradates were related to the timing of introduction and use of these compounds. Degradates, and to a lesser extent parent compounds, were detected in ground water dating back to the time these compounds were introduced.

Journal of Contaminant Hydrology↗

USGS2024

Indications of preferential groundwater seepage feeding northern peatland pools

Groundwater seepage from underlying permeable glacial sedimentary structures, such as eskers, has been hypothesized to directly feed pools in northern peat bogs. These hypotheses directly contradict classical peat bog models for ombrogenous systems, wherein meteoric water is the sole water input to these systems. Variations in the underlying mineral sediment in contact with the peat imply that unrecognized hydrogeologic connectivity may exist with pools in northern peat bogs, particularly where high permeability materials are in contact with the peat. Seepage dynamics originating from these structural variations were investigated using a suite of thermal and hydrogeophysical methods deployed around pools in a peat bog of northeastern Maine, USA. Thermal characterization methods mapped anomalies that were confirmed as matrix seepage or preferential flow pathways (PFPs). Geochemical methods were employed at identified thermal anomalies to confirm upwelling of solute-rich groundwater. Conduits around pools were associated with surficial terminations of suspected peat pipes, based on the inference of pathways extending down into the peat, that focus flow through PFPs in the peat matrix. Discharge also occurred through the peat matrix adjacent to suspected pipe structures and matrix seepage rates were quantified using analysis of diurnal temperature signals recorded at multiple depths. Seepage rates, with a maximum of nearly 0.4 m/d, were measured at localized points around pools. Periods of synchronized temperatures paired with highly muted diurnal temperature signals, recorded in diurnal temperature with depth data, were interpreted qualitatively as activation of strong upward discharge rates through suspected peat pipes. These time periods correlated strongly with local precipitation events around the peatland. Ground-penetrating radar surveys revealed discontinuities in the low permeability glacio-marine clay at the mineral sediment-peat interface, interpreted to be regional glacial esker deposits, which were located beneath and around pools. Heat tracing, specific conductance contrasts, seepage rates, and trace metal concentrations all imply groundwater seepage originating from underlying permeable glacial esker deposits and directly sourcing pools. Preferential groundwater inputs into northern peat bogs may play a key role in developing and maintaining pool systems, with enhanced solute transport impacting peatland ecology, water resources, and carbon cycling.

Maine↗

USGS1996

Hydrogeology of the Hawaii Scientific Drilling Project borehole KP-1 2. Groundwater geochemistry and regional flow patterns

A series of downhole and surface water samples were taken from the 1‐km‐deep KP‐1 borehole located on the eastern flank of the island of Hawaii. Early samples from depths of more than 700 m showed salinities nearly equivalent to seawater but having anomalous cation concentrations that are attributed to ion exchange between formation fluids and residual drilling mud clays. Later deep samples found only minor variations from seawater cation chemistry that are consistent with low‐temperature weathering of basalts; δ 18 O values are equivalent to seawater values and are consistent with this interpretation. Carbon 14 activities of dissolved inorganic carbonate indicate a water age ranging from 5890 to 7170 years B.P. and fluid transport rates of 1.8 to 2.2 m/yr. Fluid samples from perforations at 310 m in the borehole demonstrate that a freshwater aquifer is present at the Mauna Kea/Mauna Loa interface; borehole resistivity logs indicate that it is ∼200 m thick. Although it has not yet been possible to obtain samples of the freshwater zone without contamination from the deep saline fluids, the chloride concentrations of the low‐salinity zone are estimated using a mixing enthalpy calculation to be less than 100 mg/L. Light stable isotope data indicate that the fresh water at 320 m is derived from recharge entering the island at an average elevation of 2000 m. Inferred 14 C activities of the dissolved bicarbonate in the freshwater zone indicate an average calibrated age of 2200 years B.P. and an average fluid velocity of at least 14 m/yr. A regional water flow model is proposed that suggests that the fresh water found at the 320‐m depth is derived from rainfall recharge from the middle elevations of Mauna Kea volcano. This rainfall is channeled beneath the Mauna Loa lavas by the thick soil layer separating the two volcanoes. A second shallow fresh‐to‐brackish water zone, derived from Mauna Loa recharge, is also inferred to exist below the carbonate formation that underlies the shallow basal lens. The results of our preliminary study of the groundwater system below the KP‐1 drill site demonstrate that intervolcano and interflow aquicludes can have a substantial impact on water circulation and discharge from young island volcanoes.

Journal of Geophysical Research B: Solid Earth↗

USGS1993

Hydrologic and land-use factors associated with herbicides and nitrate in near-surface aquifers

Selected herbicides, atrazine (2-chloro-4-ethylamino-6-isopropylamino-s-triazine) metabolites, and NO − 3 were examined in near-surface unconsolidated and bedrock aquifers in the midcontinental USA to study the hydrogeologic, spatial, and seasonal distribution of these contaminants. Groundwater samples were collected from 303 wells during the spring and late summer of 1991. At least one herbicide or atrazine metabolite was detected in 24% of the samples collected for herbicide analysis (reporting limit 0.05 µ g/L). No herbicide concentration exceeded the USEPA's maximum contaminant level (MCL) or health advisory level. The most frequently detected compound was the at razine metabolite deethylatrazine [2-amino-4-chloro-6-(isopropylamino)-s-triazine] followed by atrazine, deisopropylatrazine [2-amino-4-chloro-6-(ethylamino)-s-triazine], prometon (2,4-bis(isopropylamino)-6-methyoxy-s-triazine), metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1methylethyl)acetamide], alachlor [2-chloro-N-(2,6-diethylphenyl)-N-(methoxymethyl)acetamide], metribuzin [4-amino-6-( tert -butyl)-3-methylthio- as -triazine-5(4H)-one], simazine [2-chloro-4,6-bis(ethylamino)-s-triazine], and cyanazine [2-[[4-chloro-6-(ethylamino)-1,3,5-triazin-2-yl]amino]-2-methylpropionitrile]. Nitrite plus nitrate, as nitrogen (N), exceeding 3.0 mg/L (excess NO − 3 ), was found in 29% of the samples, and 6% had − 3 exceeding the MCL of 10 mg/L. Ammonium as N was detected in excess of 0.01 mg/L in 78% of the samples. A nonlinear increase in the frequency of atrazine detection occurred with decreases in reporting limit. The frequency of atrazine residue detection (atrazine + deethylatrazine + deisopropylatrazine) was 25% greater than for atrazine alone. Herbicide detections and excess NO − 3 were notably lacking in the eastern part of the study region where it was estimated that herbicide and fertilizer use were among the largest in the region. Prometon, the second most frequently detected herbicide, was associated with non-agricultural land use. Herbicide and excess NO − 3 were more frequent in unconsolidated aquifers than in bedrock aquifers. Aquifer depth, as direct measurement of proximity to recharge sources, was inversely related to frequency of herbicide detection and excess NO − 3 .

Journal of Environmental Quality↗

USGS2008

Application of multiple isotopic and geochemical tracers for investigation of recharge, salinization, and residence time of water in the Souss-Massa aquifer, southwest of Morocco

Groundwater and surface water in Souss-Massa basin in the west-southern part of Morocco is characterized by a large variation in salinity, up to levels of 37 g L-1. The high salinity coupled with groundwater level decline pose serious problems for current irrigation and domestic water supplies as well as future exploitation. A combined hydrogeologic and isotopic investigation using several chemical and isotopic tracers such as Br/Cl, ??18O, ??2H, 3H, 87Sr/86Sr, ??11B, and 14C was carried out in order to determine the sources of water recharge to the aquifer, the origin of salinity, and the residence time of water. Stable isotope, 3H and 14C data indicate that the high Atlas mountains in the northern margin of the Souss-Massa basin with high rainfall and low ??18O and ??2H values (-6 to -8??? and -36 to -50???) is currently constitute the major source of recharge to the Souss-Massa shallow aquifer, particularly along the eastern part of the basin. Localized stable isotope enrichments offset meteoric isotopic signature and are associated with high nitrate concentrations, which infer water recycling via water agricultural return flows. The 3H and 14C data suggest that the residence time of water in the western part of the basin is in the order of several thousands of years; hence old water is mined, particularly in the coastal areas. The multiple isotope analyses and chemical tracing of groundwater from the basin reveal that seawater intrusion is just one of multiple salinity sources that affect the quality of groundwater in the Souss-Massa aquifer. We differentiate between modern seawater intrusion, salinization by remnants of seawater entrapped in the middle Souss plains, recharge of nitrate-rich agricultural return flow, and dissolution of evaporate rocks (gypsum and halite minerals) along the outcrops of the high Atlas mountains. The data generated in this study provide the framework for a comprehensive management plan in which water exploitation should shift toward the eastern part of the basin where current recharge occurs with young and high quality groundwater. In contrast, we argued that the heavily exploited aquifer along the coastal areas is more vulnerable given the relatively longer residence time of the water and salinization processes in this part of the aquifer. ?? 2008 Elsevier B.V. All rights reserved.

Journal of Hydrology↗

USGS2010

Hydrogeology of the potsdam sandstone in northern New York

The Potsdam Sandstone of Cambrian age forms a transboundary aquifer that extends across northern New York and into southern Quebec. The Potsdam Sandstone is a gently dipping sequence of arkose, subarkose, and orthoquartzite that unconformably overlies Precambrian metamorphic bedrock. The Potsdam irregularly grades upward over a thickness of 450 m from a heterogeneous feldspathic and argillaceous rock to a homogeneous, quartz-rich and matrix-poor rock. The hydrogeological framework of the Potsdam Sandstone was investigated through an analysis of records from 1,500 wells and geophysical logs from 40 wells, and through compilation of GIS coverages of bedrock and surficial geology, examination of bedrock cores, and construction of hydrogeological sections. The upper several metres of the sandstone typically is weathered and fractured and, where saturated, readily transmits groundwater. Bedding-related fractures in the sandstone commonly form sub-horizontal flow zones of relatively high transmissivity. The vertical distribution of sub-horizontal flow zones is variable; spacings of less than 10 m are common. Transmissivity of individual flow zones may be more than 100 m 2 /d but typically is less than 10 m 2 /d. High angle fractures, including joints and faults, locally provide vertical hydraulic connection between flow zones. Hydraulic head gradients in the aquifer commonly are downward; a laterally extensive series of sub-horizontal flow zones serve as drains for the groundwater flow system. Vertical hydraulic head differences between shallow and deep flow zones range from 1 m to more than 20 m. The maximum head differences are in recharge areas upgradient from the area where the Chateauguay and Chazy Rivers, and their tributaries, have cut into till and bedrock. Till overlies the sandstone in much of the study area; its thickness is generally greatest in the western part, where it may exceed 50 m. A discontinuous belt of bedrock pavements stripped of glacial drift extends across the eastern part of the study area; the largest of these is Altona Flat Rock. Most recharge to the sandstone aquifer occurs in areas of thin, discontinuous till and exposed bedrock; little recharge occurs in areas where this unit is overlain by thick till and clay. Discharge from the sandstone aquifer provides stream and river baseflow and is the source of many springs. A series of springs that are used for municipal bottled water and fish-hatchery supply discharge from 1,000 to 5,000 L/min adjacent to several tributaries east of the Chateauguay River. The major recharge areas for the Chateauguay springs are probably upgradient to the southeast, where the till cover is thin or absent.

New York↗

USGS2006

Location and timing of river-aquifer exchanges in six tributaries to the Columbia River in the Pacific Northwest of the United States

The flow of water between rivers and contiguous aquifers influences the quantity and quality of water resources, particularly in regions where precipitation and runoff are unevenly distributed through the year, such as the Columbia Basin (CB) in northwestern United States. Investigations of basin hydrogeology and gains and losses of streamflow for six rivers in the CB were reviewed to characterize general patterns in the timing and location of river-aquifer exchanges at a reach-scale (0.5-150 km) and to identify geologic and geomorphic features associated with the largest exchanges. Ground-water discharge to each river, or the gain in streamflow, was concentrated spatially: more than one-half of the total gains along each river segment were contributed from reaches that represented no more than 30% of the total segment length with the largest and most concentrated gains in rivers in volcanic terrains. Fluvial recharge of aquifers, or losses of streamflow, was largest in rivers in sedimentary basins where unconsolidated sediments form shallow aquifers. Three types of geologic or geomorphic features were associated with the largest exchanges: (1) changes in the thickness of unconsolidated aquifers; (2) contacts between lithologic units that represent contrasts in permeability; and (3) channel forms that increase the hydraulic gradient or cross-sectional area of flow paths between a river and shallow ground-water. The down-valley component of ground-water flow and its vertical convergence on or divergence from a riverbed account for large streamflow gains in some reaches and contrast with the common assumption of lateral ground-water discharge to a river that penetrates completely through the aquifer. Increased ground-water discharge was observed during high-flow periods in reaches of four rivers indicating that changes in ground-water levels can be more important than stage fluctuations in regulating the direction and magnitude of river-aquifer exchanges and that assumptions about ground-water discharge during high flow periods used for base-flow separation must be verified. Given the variety of geologic terrains in the CB, the spatial and temporal patterns of river-aquifer exchanges provide a framework for investigations in other regions that includes a focus on reaches where the largest exchanges are likely to occur, integration of ground-water and surface-water data, and verification of assumptions regarding ground-water flow direction and temporal variation of exchanges. ?? 2006 Elsevier B.V. All rights reserved.

Journal of Hydrology↗

USGS2014

High-resolution delineation of chlorinated volatile organic compounds in a dipping, fractured mudstone: depth- and strata-dependent spatial variability from rock-core sampling

Synthesis of rock-core sampling and chlorinated volatile organic compound (CVOC) analysis at five coreholes, with hydraulic and water-quality monitoring and a detailed hydrogeologic framework, was used to characterize the fine-scale distribution of CVOCs in dipping, fractured mudstones of the Lockatong Formation of Triassic age, of the Newark Basin in West Trenton, New Jersey. From these results, a refined conceptual model for more than 55 years of migration of CVOCs and depth- and strata-dependent rock-matrix contamination was developed. Industrial use of trichloroethene (TCE) at the former Naval Air Warfare Center (NAWC) from 1953 to 1995 resulted in dense non-aqueous phase liquid (DNAPL) TCE and dissolved TCE and related breakdown products, including other CVOCs, in underlying mudstones. Shallow highly weathered and fractured strata overlie unweathered, gently dipping, fractured strata that become progressively less fractured with depth. The unweathered lithology includes black highly fractured (fissile) carbon-rich strata, gray mildly fractured thinly layered (laminated) strata, and light-gray weakly fractured massive strata. CVOC concentrations in water samples pumped from the shallow weathered and highly fractured strata remain elevated near residual DNAPL TCE, but dilution by uncontaminated recharge, and other natural and engineered attenuation processes, have substantially reduced concentrations along flow paths removed from sources and residual DNAPL. CVOCs also were detected in most rock-core samples in source areas in shallow wells. In many locations, lower aqueous concentrations, compared to rock core concentrations, suggest that CVOCs are presently back-diffusing from the rock matrix. Below the weathered and highly fractured strata, and to depths of at least 50 meters (m), groundwater flow and contaminant transport is primarily in bedding-plane-oriented fractures in thin fissile high-carbon strata, and in fractured, laminated strata of the gently dipping mudstones. Despite more than 18 years of pump and treat (P&T) remediation, and natural attenuation processes, CVOC concentrations in aqueous samples pumped from these deeper strata remain elevated in isolated intervals. DNAPL was detected in one borehole during coring at a depth of 27 m. In contrast to core samples from the weathered zone, concentrations in core samples from deeper unweathered and unfractured strata are typically below detection. However, high CVOC concentrations were found in isolated samples from fissile black carbon-rich strata and fractured gray laminated strata. Aqueous-phase concentrations were correspondingly high in samples pumped from these strata via short-interval wells or packer-isolated zones in long boreholes. A refined conceptual site model considers that prior to P&T remediation groundwater flow was primarily subhorizontal in the higher-permeability near surface strata, and the bulk of contaminant mass was shallow. CVOCs diffused into these fractured and weathered mudstones. DNAPL and high concentrations of CVOCs migrated slowly down in deeper unweathered strata, primarily along isolated dipping bedding-plane fractures. After P&T began in 1995, using wells open to both shallow and deep strata, downward transport of dissolved CVOCs accelerated. Diffusion of TCE and other CVOCs from deeper fractures penetrated only a few centimeters into the unweathered rock matrix, likely due to sorption of CVOCs on rock organic carbon. Remediation in the deep, unweathered strata may benefit from the relatively limited migration of CVOCs into the rock matrix. Synthesis of rock core sampling from closely spaced boreholes with geophysical logging and hydraulic testing improves understanding of the controls on CVOC delineation and informs remediation design and monitoring.

New Jersey, New York, Pennsylvania↗