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Temporal and spatial comparison of coal mine ventilation methane emissions and mitigation quantified using PRISMA satellite data and on-site measurements

Emission monitoring at the facility level (bottom-up, BU) is key for accurate reporting of coal mine methane (CMM) emissions. Recent advances in aerial and satellite observations (top-down, TD) indicate that these methods have the potential to support CMM emissions monitoring and reporting of, as well as track the effectiveness of, mitigation actions. That said, studies have shown discrepancies between BU and TD estimations. Performing TD monitoring with concurrent BU measurements at the same mines may help address the observed discrepancies and improve quantification methods to narrow the gap between BU and TD data. This paper presents a comparison of concurrent BU-TD methane emission fluxes monitored from two ventilation shafts at a southwestern Virginia, USA, longwall mine to complement the existing body of studies on satellite-based monitoring of coal mines by incorporating continuous ground-based monitoring with concurrent TD monitoring of methane emission fluxes to address the gap and provide valuable insights into temporal emission patterns. The shafts were monitored on multiple dates between 2020 and 2023. BU monitoring was performed at the exhaust fans, while TD quantifications used PRISMA hyperspectral satellite data and two different wind reanalysis datasets (i.e., GEOS-FP and ERA5). This mine also offered a unique opportunity for BU-TD comparisons before and after ventilation air methane (VAM) oxidizer operation, which was installed at one of the shafts in 2022. The results showed that TD-estimated mean fluxes were generally lower than BU data, which were attributed to quantification difficulties associated with the low albedo caused by heavy vegetation and the terrain of the area. However, despite the discrepancies in mean emissions, both the interquartile range and the data range of the distributions generally overlapped, and the estimates correctly showed the emission trends.

Virginia

A model uncertainty quantification protocol for evaluating the value of observation data

The history-matching approach to parameter estimation with models enables a powerful offshoot analysis of data worth—using the uncertainty of a model forecast as a metric for the worth of data. Adding observation data will either have no impact on forecast uncertainty or will reduce it. Removing existing data will either have no impact on forecast uncertainty or will increase it. The history-matching framework makes it possible to perform this quantitative analysis leveraging the connections among observations, model parameters, and model forecasts. We show this behavior on a specific groundwater flow model of the Mississippi Alluvial Plain and show where the analysis can be informative for considering the potential design of an observation network based on existing or potential observations.

Scientific Investigations Report

Evaluating groundwater quality influences from oil field operations and other anthropogenic activities in an urban setting, Santa Fe Springs, California

Groundwater quality is often affected by anthropogenic activities in urban settings. This study examines groundwater quality in and around the Santa Fe Springs Oil Field in Los Angeles County, California, where oil and gas production commonly intersects with high density industrial, commercial and residential land uses. Utilizing a combination of new and historical data, we evaluated potential pathways that would allow for oil field formation fluids to migrate into groundwater and whether mixing may have occurred based on the distribution of groundwater and oil field formation fluid tracers in samples. Samples were analyzed for a wide array of constituents including volatile organic compounds, light hydrocarbons, major ions, and various isotopic compositions. Despite evidence of oil field infrastructure providing potential pathways of migration via uncemented annular spaces, casing breaches and historical disposal of oil field formation water in surface ponds, the distribution and occurrence of stable isotopes of water, chloride, boron, and total dissolved solids do not indicate mixing of oil field formation water and groundwater. However, methane isotopic signatures and the presence of heavier alkanes suggest gas from oil-bearing formations have migrated from depth via oil field well infrastructure. Volatile organic compound detections were mainly from manufactured compounds unrelated to oil and gas production, with a relatively limited number of petroleum hydrocarbons also detected. Volatile organic compounds were generally found in wells tapping shallow, modern aged groundwater, indicating anthropogenic activities occurring at or near land surface as the source. Study results suggest that while oil field infrastructure provides migration pathways for oil field formation fluids to be introduced into groundwater, urban land uses not related to oil and gas production are the primary drivers of groundwater quality degradation.

California

Prediction of the probability of elevated nitrate concentrations at groundwater depths used for drinking-water supply in the Puget Sound basin, Washington, 2004–19

The Puget Sound basin encompasses the 13,700-square-mile area that drains to the Puget Sound and the adjacent marine waters of Washington State. Well more than 4 million people live within the basin, with numbers continuing to increase, who rely on the basin’s natural resources including groundwater. The Puget Sound Partnership was created by a Washington State statute to implement a science-based recovery of the Puget Sound to help address impacts to these resources. As part of the recovery, the partnership developed the Puget Sound Vital Signs as measures of ecosystem health that guide the assessment of progress toward Puget Sound recovery goals. The Puget Sound Partnership Leadership Council adopted a Drinking Water Vital Sign associated with human health and quality of life, recognizing certain indicators as integral to the sustainability of Puget Sound recovery efforts. One such Vital Sign indicator was the vulnerability of groundwater throughout the aquifers of the Puget Sound basin to elevated nitrate concentrations as defined by the probability of exceeding 2 milligrams/liter (mg/L) at a specific location and well depth. The U.S. Geological Survey (USGS) led the effort to characterize groundwater vulnerability. For this study, groundwater vulnerability refers to a probability with which a contaminant applied at or near the land surface can migrate to the aquifer of interest for a given set of land-use practices. Nitrate concentration data were selected for evaluation because elevated nitrate concentrations are typically caused by anthropogenic activities and have been associated with deleterious impacts on human health. To identify groundwater vulnerability to elevated nitrate concentrations, logistic regression was used to relate anthropogenic (human associated) and natural variables to the occurrence of elevated nitrate concentrations in untreated groundwater from large public water supply system wells found within the Washington State Department of Health Sentry database. Variables that were analyzed included well depth, soil hydraulic conductivity, precipitation, population density, fertilizer application amounts, and land-use types. Statistically significant models that predicted the probabilities of groundwater nitrate concentrations greater than 2 mg/L based on the predictor variables were created for the time periods 2000–04, 2005–09, 2010–14, and 2015–19. For all time periods, well depth and a measure of the abundance of urban and agricultural land over or near the well consistently helped explain the vulnerability of the well to elevated nitrate concentrations defined as a probability of exceeding 2 mg/L of nitrate. Precipitation and (or) soil hydraulic conductivity were also important predictor variables in the models. The models for each time period were used to create maps of groundwater vulnerability at 150- and 300-foot depths throughout the Puget Sound basin. As expected, the most vulnerable locations were associated with shallower well depths and increased agriculture and urban land cover. Across all four time periods, groundwater vulnerability throughout the Puget Sound was low, with probabilities of exceeding 2 mg/L concentrations of nitrate at depths at 150 and 300 feet typically less than 50 percent. Results also found a slight decrease in probabilities of elevated nitrate concentrations throughout the basin over time. More specifically, additional statistical tests found that groundwater with probabilities of less than about 60 percent declined from 2000 to 2019 and represented more than 75 percent of the modeled Puget Sound basin aquifer. Wells with greater than 60 percent probability increased over the same time period but represented only about 25 percent of the aquifer. The maps and statistical analysis presented in the study provide valuable and informative evaluation of the vulnerability of groundwater in the Puget Sound basin to elevated nitrate concentrations. The probability maps do not represent measured nitrate concentrations in groundwater, but rather they present the probability that nitrate concentrations exceed 2 mg/L. The models and predictions from this study are a viable indicator for the Puget Sound Partnership’s Healthy Human Population—Drinking Water Vital Sign. The logistic regression modeling approach presented here benefits water managers by allowing them to assess temporal trends in a range of probabilities, explore vulnerability changes as new regional land cover and anthropogenic data are generated, and distinguish vulnerabilities at different depths within the aquifer.

Washington

Geospatial PDF map of the compilation of GIS data for the mineral industries of select countries in the Indo-Pacific region

Introduction In 2024, the U.S. Geological Survey's (USGS) National Minerals Information Center (NMIC) completed the project titled "Compilation of geospatial data for the mineral industries of select countries in the Indo-Pacific." This project aimed to leverage the expertise and capabilities of the NMIC to collect, synthesize, and interpret geospatial data to inform on the extractive resources of select countries in the Indo-Pacific region (area of study) and expand the NMIC's understanding on the impact of mineral industry of these countries in the global economy. The 19 countries of interest in the Indo-Pacific study area include Bangladesh, Bhutan, Brunei, Burma, Fiji, Malaysia, Mongolia, Nauru, New Caledonia, New Zealand, Papua New Guinea, Philippines, Singapore, Solomon Islands, South Korea (Republic of Korea), Sri Lanka, Taiwan, Timor-Leste, and Vietnam. The primary objective of this effort was to create a fully attributed Geographic Information System (GIS) portraying existing mining infrastructure, resources, and production capacities across the Indo-Pacific study area as well as highlight mineral production and processing sites under development and potential areas of future extractive industry operations and development in the region. The compiled GIS geodatabase with supporting documentation including comprehensive metadata was published as a USGS data release titled "Compilation of Geospatial Data (GIS) for the Mineral Industries of Select Countries in the Indo-Pacific." This georeferenced portable document format (GeoPDF) map sheet presents a new geographic information product containing a partial representation of the GIS data. This GeoPDF map provides a visual comparison of the distribution of mineral industry GIS data, which contributes to a deeper understanding of the intersections and complexities of the extractive industries within the select countries in the Indo-Pacific region.

Open-File Report

Global variability of the composition and temperature at the 410-km discontinuity from receiver function analysis of dense arrays

Seismic boundaries caused by phase transitions between olivine polymorphs in Earth's mantle provide thermal and compositional markers that inform mantle dynamics. Seismic studies of the mantle transition zone often use either global averaging with sparse arrays or regional sampling from a single dense array. The intermediate approach of this study utilizes many densely spaced seismic arrays distributed around the globe. We systematically compute teleseismic P-to-S receiver functions for each seismic array and invert for the 1-D seismic velocity structure of the mantle transition zone beneath each array to facilitate a comparison between densely sampled regions. We stack 3,600 receiver functions on average at 67 arrays in total. The stack is used in a probabilistic inversion to estimate the mantle transition zone interface depths and velocities beneath each array. We focus on the 410-km discontinuity (410) because it is a prominent seismic interface that is clearly linked to a single mineral phase transition between olivine and wadsleyite. The depths and velocity contrasts of the 410 are mapped to temperatures and compositions using mineral physics constraints. The depth of the 410 ranges from ∼405–440 km, which is consistent with a ∼360 K temperature range in a dry mantle and a ∼260 K temperature range in a wet mantle (2 wt. % water). The Vs contrast across the 410 ranges from ∼2.5–8 %, which is consistent with ∼20–70 vol. % olivine composition in a dry mantle and ∼25–80 vol. % in a wet mantle. The bulk composition of the upper mantle near the 410-km discontinuity is typically considered to be well-mixed because there is no thermodynamic impediment to convection at the olivine to wadsleyite phase transition. However, the wide range of inferred olivine content from our study suggests that there are large lateral variations in the bulk composition of the upper mantle near the 410-km discontinuity.

Earth and Planetary Science Letters

Potentially toxic elements in wild Agassiz’s desert tortoises: Tissue concentrations and association with disease

Background: Desert tortoise ( Gopherus agassizii ) populations have continued to decline due to infectious and other diseases, predation, and habitat alteration. The potential contribution of minerals and heavy metals to tortoise health and susceptibility to disease remains uncertain. Objective: The objective of this study was to evaluate the results of elemental analysis of trace minerals and macrominerals in scute keratin, kidney, and liver tissue from ill and dying desert tortoises salvaged for necropsy between 1993 and 2000. Methods: Salvaged tortoises were categorized by age (adult, juvenile), geographic location, and primary disease based on necropsy findings. A subset of tortoises that were injured or killed by vehicular trauma or predation but with no notable pathologic abnormalities were used as controls. A panel of 21 trace minerals and 6 macrominerals was analyzed in scute keratin, kidney, and liver tissue samples by inductively-coupled plasma spectrometry and atomic absorption spectrophotometry. Results: Necropsies were done on 46 tortoises, including 9 juveniles salvaged from 5 regions in the Colorado and Mojave deserts of California. Primary diseases were cutaneous dyskeratosis (n=9), infection/ inflammation (n=8), malnutrition (n=7), mycoplasmosis (n=5), and urolithiasis (n=3); 14 tortoises were classified as controls. Concentrations of elements differed significantly by tissue, age, desert region, and disease (P < 0.05). Tortoises with cutaneous dyskeratosis had significantly higher Se concentrations, primarily in keratin and liver, than tortoises with other diseases (P < 0.001). Juveniles were more likely than adults to have high Pb, Sn, and Zn levels (P < 0.05). All tortoises had detectable levels of more than one potentially toxic heavy metal, including As, Cd, Cr, Hg, Ni, Pb, Sn and V. Conclusions: Potentially toxic elements are frequently found in tissue from tortoises in desert regions of California, with significantly higher concentrations in diseased tortoises. Metal exposure from soils, mining, historic and ongoing military activities, and other human activities could increase susceptibility to disease in desert tortoises.

California

Importance of fish in the diet of Adélie penguins across multiple life stages

Over recent decades, the Adélie penguin ( Pygoscelis adeliae ) population has grown across most of its range, the exception being the northern coast of the western Antarctic Peninsula (WAP). In the Ross Sea, the very large Cape Crozier colony grew to reach ~9% of the global population. Demographic factors driving the Cape Crozier trend have yet to be identified. However, low chick fledging mass - a negative influence in the northern WAP where the diet is mostly less-energy-dense krill - is not showing an effect in the Cape Crozier colony. Previously, we hypothesized that Cape Crozier fledglings, and post-breeding adults, must be finding sufficient higher-quality prey once free of the prey-depleted colony foraging area, with subsequent higher survival. Here we explore penguin diet within and outside the colony foraging area using stable isotope analysis (SIA) of feathers: those grown by post-breeding adults outside the foraging area, prior to moult, compared to those of near-fledged chicks raised on meals obtained within the foraging area. Second, we explore whether a major difference occurs between breeding and post-breeding diet of adults from a small, nearby colony (Cape Royds) that exploits a smaller, little-depleted preyscape. Finally, we compare the results to SIA analyses published by others to explore whether the pre-moult diet of Ross Island adults, mostly foraging within the north-eastern Ross Sea, compares with that of adults nesting in the southern WAP (Bellingshausen Sea coast). At the latter, populations are not decreasing, with diet containing an appreciable contribution of fish. The results confirmed that fish contributed greatly to chick diets at both Ross Island colonies (δ 15 N 10.6–11.4). Once adults were released from central-place foraging, SIA levels (δ 15 N 9.7–12.9) were similar to those of the southern WAP. Foraging on energy-dense fish in coastal Antarctic waters could be one reason Adélie penguins are among the most abundant and therefore most ecologically successful penguin species.

Antarctic Science

Groundwater flowpath characteristics drive variability in per- and polyfluoroalkyl substances (PFAS) loading across a stream-wetland system

Groundwater-dependent ecosystems in areas with industrial land use are at risk of exposure to a PFAS chemicals. We investigated one such system with several known PFAS source areas, where high and low permeability sediments (glacial) coupled with groundwater-lake and groundwater/surface-water interactions created complex ‘source to seep’ dynamics. Using heat-tracing and chemical methods, numerous preferential groundwater discharge zones were identified and sampled across the upper Quashnet River stream-wetland system in Mashpee, MA, USA, downgradient of Joint Base Cape Cod (JBCC). Surface-water and groundwater samples were analyzed for 40 PFAS compounds between March and October 2022. Samples were collected from groundwater seeps identified as preferential discharge points (PDPs), wells upgradient of the stream-wetland system, contributing flow-through kettle lakes, and along Quashnet River surface-waters. PFAS from sampled waters contained perfluorinated carboxylates (PFPea, PFHxA, PFNA), perfluorinated sulfonates (PFBS, PFPeS, PFHxS, PFOS), fluorotelomer sulfonates (6:2, 8:2 FtS), and perfluoroalkyl sulfonamides (PFOSA). Samples from PDPs and wells had measured PFAS concentrations ranging from non-detect to 4677 ng/L ng/L (mean = 418 ng/L, std. = 709 ng/L), and a range of deuterium excess values (3.2 to 15.9 per mil) indicative of varying degrees of groundwater-lake interaction prior to groundwater flowpath emergence at PDPs. Correlations ( p < 0.01) between deuterium excess, %PFAS precursors, and terminal PFAS compounds highlighted potential precursor transformations associated with lake-groundwater exchange along flowpaths sourcing PDPs. However, some seepages had higher total PFAS concentrations (>1000 ng/L) than upgradient kettle lakes despite showing lake (evaporative) isotopic signatures, indicating the potential for groundwater flowpath convergence at wetland discharge zones and the influence of lakebed PFAS precursor reactions. Results from these synoptic surveys address gaps in the existing PFAS literature by demonstrating the importance of subsurface fate and transport on PFAS compound concentrations and mass loading in preferential groundwater discharge zones.

Massachusetts

Submarine groundwater discharge creates cold‐water refugia that can mitigate exposure of heat stress in nearshore corals

Coral reef mortality around the world is accelerating due to human activities and rising sea temperatures that cause bleaching, which is expected to become more frequent. Our ability to predict which corals will be most resilient, however, remains limited due to insufficient information characterizing nearshore temperature and habitat conditions. In this study, we examine how submarine groundwater discharge (SGD) reduces nearshore water temperatures and exposure of corals to heat stress, complementing the understanding that SGD can adversely affect coral when it contains elevated nutrient concentrations. Data from fixed nearshore sensors and vertical depth profiles along ~100 km of the western shoreline of the Island of Hawai’i from 2003 to 2014 demonstrate that submarine groundwater discharge (SGD) can reduce nearshore water temperatures by 1 °C–5°C and create estuarine-like conditions with salinities as low as 20 PSU, where the prevalent coral species, Pocillopora meandrina, Porites lobata , and Montipora capitata , thrive. Time-series temperature records reveal that exposure to high ambient ocean temperatures, which are known to initiate bleaching events, are reduced up to 5%–46% of the time. Coral health surveys indicated coral bleaching in response to moderately high annual temperatures in 2010 and 2011, with more colonies affected farther from cold, SGD-fed waters. Synthesis of these results, along with coral response data following the more extreme marine heat wave of 2014–2015, demonstrates lower coral loss and greater coral recovery near groundwater seeps, particularly those with higher flux and influence on reducing nearshore water temperatures. Our results demonstrate that SGD may therefore provide a beneficial ecosystem service and enhance coral reef resilience, particularly where human-related nutrient additions to groundwater can be mitigated. The implications of our findings are relevant across tropical coasts where groundwater inputs can be substantial, such as the Caribbean and Indo-Pacific, and contribute to improving our understanding of coral sensitivity to gradients in temperature and nutrient stress. Improved management of groundwater resources could thus be vital to local–regional strategies for mitigating future heat stress.

Hawaii

Bottom-up characterization of geologic methane emissions in the San Juan Basin in the southwestern USA

Methane is a potent greenhouse gas that plays an important role in atmospheric chemistry and global warming. The current global methane budget has large uncertainties, and a better understanding of the budget would help to guide strategies for reducing anthropogenic emissions to fight climate change. Natural geologic methane emissions are a particularly poorly constrained source, with top-down estimates from 14 C in ice cores suggesting much lower geologic emissions than bottom-up scaling of direct flux measurements. Our study aims to contribute to resolving this discrepancy through improved bottom-up characterization of geologic methane seepage in the San Juan Basin in southwestern Colorado and northwestern New Mexico, USA. We performed 983 new flux chamber measurements in this basin during summer 2022 and winter 2023 field campaigns. Our results, in combination with prior measurements, suggest that natural seepage in the San Juan Basin only occurs on or near the Fruitland coal outcrop. Specifically, our new measurements confirm previous measurements of seepage along the northwestern exposure of the Fruitland outcrop in Colorado (a known hydrodynamic overpressure region) and for the first time, identified seepage locations along the southernmost Fruitland outcrop exposure in New Mexico, in association with a coal cleat and a fault. Overall, seepage along the Fruitland coal outcrop is heterogeneously distributed, with both positive and negative (interpreted as microbial soil sink) methane fluxes. Features that are hypothesized to be predictive of seepage (e.g., faults) were not associated with positive methane fluxes in areas outside of the Fruitland outcrop. Our best estimate for total geologic methane seepage in the San Juan Basin from spatial interpolation and statistical upscaling is approximately 0.14 Tg CH 4 /yr, with a range from 0.029 to 0.48 Tg CH 4 /yr. This best-estimate value is lower than a previous bottom-up estimate from a gridded seepage inventory, but higher than a previous top-down estimate.

Colorado, New Mexico

Hyperspectral narrowband imaging spectroscopy: A new paradigm for Earth observation

This editorial introduces the Special Issue entitled “Hyperspectral Narrowband Imaging Spectroscopy: A New Paradigm for Earth Observation” in the August 2026 issue of Photogrammetric Engineering & Remote Sensing (PE&RS), the flagship journal of the American Society for Photogrammetry and Remote Sensing (ASPRS). This volume represents the fourth dedicated hyperspectral special issue published in PE&RS, following earlier contributions by Thenkabail et al. (2025, 2024a, 2024b), and continues ASPRS’s commitment to advancing cutting‑edge imaging spectroscopy research and its applications across Earth system science. Remote sensing is undergoing one of the most profound transformations in its history. The emergence of hyperspectral narrowband (HNB) imaging spectroscopy data, capable of acquiring hundreds of contiguous, narrow spectral bands, has shifted the discipline from observing Earth in a handful of broad spectral windows to capturing continuous spectral signatures of the Planet. This transition marks a decisive break from the multispectral paradigm that has dominated satellite remote sensing for nearly five decades, driven by the advent of new orbital imaging spectrometers such as EnMAP, PRISMA, and NASA’s EMIT, and by the forthcoming Surface Biology and Geology (SBG) mission ((Pires Silva et al., 2026; Bourriz et al., 2025; Thenkabail et al., 2025; Chabrillat et al., 2024; Aneece et al., 2024; Dave et al., 2024; Thenkabail et al., 2024a; Thenkabail et al., 2024b; Thenkabail, 2024a; Thenkabail, 2024b; Thompson et al., 2022; Kokaly et al., 2022; Aneece & Thenkabail, 2022; Cawse Nicholson et al., 2021; Guanter et al., 2021; Vangi et al., 2021; Thenkabail et al., 2021). These missions (e.g., Table 1) deliver unprecedented spectral fidelity, improved signal to noise ratios, and global coverage capabilities, enabling a new era of quantitative, spectroscopy based Earth observation. Where multispectral broadbands (MBBs) provide only a few discrete measurements along the electromagnetic spectrum, HNB systems deliver rich, diagnostic information that enables scientists to characterize Earth’s surface with unprecedented biochemical, biophysical, and structural detail (Figure 1a, 1b). The implications for environmental monitoring, agriculture, water resources, and mineral exploration are profound. Several overarching themes emerge: • Spectral fidelity matters. The ability to preserve subtle absorption features is essential for mineral mapping, vegetation trait retrieval, and biochemical modeling. • AI and deep learning are indispensable. From destriping to classification, modern analytics must be scalable, label‑efficient, and capable of exploiting the full spectral–spatial richness of HNB data. • Physics‑based and data‑driven approaches must converge. Radiative transfer models such as PROSAIL, enhanced with localized soil parameterizations, remain foundational for biophysical retrievals and model‑based inference. • Dimensionality reduction and feature extraction are critical. Techniques such as L1‑ISOMAP demonstrate that intelligent manifold learning can unlock the structure of fused, high‑dimensional datasets. • Next‑generation architectures must be interactive and multimodal. ICTNet exemplifies the future of hyperspectral classification: hybrid, synergistic, and capable of modeling both local textures and global spectral dependencies.

Photogrammetric Engineering and Remote Sensing (PE

Sedimentological and geochemical characterization of lacustrine deposits of the Babouri-Figuil basin, northern Cameroon: Implications for source rocks distribution and petroleum exploration

The West and Central African Rift System (WCARS) refers to the series of Cretaceous rift basins where commercial hydrocarbon accumulations have been discovered. Some of the WCARS frontier basins are currently being investigated to increase our understanding of these basins in light of new commercial discoveries. The present study was performed in the Babouri-Figuil Basin (BFB), which is genetically related to the WCARS and constitutes an area of interest in terms of petroleum prospecting, where the distribution of petroleum source rocks and potential targets for petroleum exploration across the entire basin is poorly understood. For the current study, an integrated facies analysis along with organic and inorganic geochemical techniques were applied to the basin's Cretaceous deposits with the aim of reconstructing the paleodepositional environment, assessing factors that triggered the input of organic matter, and providing a spatial overview of the organic matter accumulation in the basin based on outcrop samples. An alluvial fan-lacustrine-braided river system is inferred from the facies analysis of the stratigraphic sequence consisting of conglomerate, sandstone, siltstone, limestone, marlstone, and claystone. Bulk analysis of organic matter reveals that black shale and massive claystone are the main prospective petroleum source rocks in the basin. Inorganic geochemical analyses reveal the influence of anoxic conditions, moderate to high primary productivity, and low terrigenous inputs in organic matter enrichment. The formations rich in organic matter are predominantly concentrated in the western and eastern parts of the basin which may represent areas with depressions, characterized by high accommodation space. In terms of the regional context of the WCARS rift basins, typical hydrocarbon exploration in the BFB may target basal-conglomerate, sandstone beds situated directly above or/and interbedded with the Lower Cretaceous source rocks, and the Upper Cretaceous sandstone beds. Basement rocks (granite, granodiorite, and gneisses) and oil shale deposits may represent potential unconventional hydrocarbon exploration. The current integrated study provides an insight that should guide future hydrocarbon exploration campaigns in the basin.

Babouri-Figuil basin

Estimating the probability of export restrictions to inform mineral criticality

To assess risks associated with advanced technologies’ supply chain disruptions, governmental agencies and others have developed mineral “criticality” assessments, with criticality described using the economic impact and probability of supply chain disruptions. Previous work developed subjective supply risk indicators to approximate this probability, typically combining several factors such as supply diversity and trading partners’ political stability, where indicator weightings can substantially impact results. This work explicitly quantifies export barrier probability using an ensemble of machine learning classifiers, with probability estimates informed by exogenous variables, including prior barrier implementation and global export dominance. Major differences in high-probability countries and commodities are observed across models, but the ensemble method highlights Indonesia, China, Tanzania, and the United States as particularly high risk. The Supplementary Data File provides export barrier probability estimates for each analyzed country-commodity pair, enabling a direct, quantitative, objective contribution to assessing mineral criticality, enhancing risk identification and prioritization for policymakers.

Resources, Conservation, and Recycling

The abandoned mine inventory of the United States—A brief summary

The Infrastructure Investment and Jobs Act of 2021 required the Secretary of the Interior to establish a program to inventory abandoned hard-rock mines in the United States. The Department of the Interior’s Office of Environmental Policy and Compliance asked the U.S. Geological Survey’s Mineral Deposit Database project (USMIN) to use existing data sources to build an inventory of all individual abandoned mine features in the United States. In addition to feature locations, this new database documents the surface land management agency, associated physical and environmental hazards, and any completed mitigation efforts. This information will improve risk assessment and support land management efforts, including hazard mitigation, ecosystem restoration planning, and reclamation. This fact sheet provides a brief overview of USMIN’s collaborative efforts with Federal, State, and Tribal agencies to build a comprehensive and authoritative national inventory of abandoned mine features.

Fact Sheet

Estimating the probability of export restrictions to inform mineral criticality

As demand for advanced technologies rises, mineral commodities will increase in geopolitical importance. To assess risks associated with mineral commodity supply chain disruptions, governmental agencies and others have developed "criticality" assessments, with criticality described using the economic impact and probability of supply chain disruptions. In previous work, subjective supply risk indicators were developed to approximate this probability, typically combining several factors such as supply diversity and political stability of trading partners, where indicator weightings can substantially impact results. This work explicitly quantifies trade barrier probability using an ensemble of several machine learning classifiers, with probability estimates informed by exogenous variables such as prior trade barrier implementation and global export dominance. Major differences in the high-probability countries and commodities are observed across models, but the ensemble method highlights Indonesia, China, Tanzania, and the United States as particularly high risk. This approach enables a direct, quantitative, objective approach to assessing trade barrier probability, enhancing risk identification and prioritization for policymakers.

SSRN

Inference of pattern-based geological CO2 sequestration and oil recovery potential in a commingled main pay and residual oil zone CO2-EOR flood

Several detailed studies have shown that residual oil zones (ROZs) can present significant resources for additional hydrocarbon recovery as well as subsurface carbon dioxide (CO 2 ) sequestration via enhanced oil recovery by injecting CO 2 (CO 2 -EOR). Field development strategies included new wells drilled dedicated to main pay zones (MPZ) and ROZs, or existing wells in MPZs deepened to ROZs for commingled injection-production using different well patterns. The latter presented a challenge when discerning the injection and production from each of the zones, and for subsequent quantification of CO 2 sequestration and EOR potential from different patterns and from the field. In this paper, an innovative method for analyzing commingled injections and productions from MPZs and ROZs, with application to pattern-based data from four staggered line drive patterns in Wasson Field's Denver Unit, Texas, USA, was developed. Decline curve and ratio-trend methods were used as means of history-matching and forecasting. Cumulative production-time and cumulative production-rate data for oil, gas, and water, as well as water-oil ratio (WOR) and gas-oil ratio (GOR), were analyzed along with injection data for time intervals covering major injection events in MPZ, or MPZ and ROZ combined. A combined analysis enabled inference of allocation of fluids into different zones during WAG (water alternating gas) injection and thereby estimation of CO 2 storage, utilization, and retention in different zones as a function of total injection. Results show that ROZs generally present higher CO 2 sequestration potential compared to MPZs, and a comparable incremental oil recovery factor of ∼20%, on average. Results based on ratio analysis further show that while the WOR trend of the pattern production is mostly dominated and controlled by ROZ, GOR is controlled by both intervals. Although the method relying on decline curves and the approach used in zonal fluid allocations are subject to their limitations, this study presents a practical and innovative well-pattern-based method to infer and forecast CO 2 sequestration and oil recovery quantities and fluid ratios from MPZs and ROZs in commingled operations and highlight the added potential offered by ROZs.

Texas

Influence of inherited structure on flexural extension in foreland basin systems: Evidence from the northern Arkoma basin and southern Ozark dome, USA

Extensional faults are key components of foreland basin systems. They form within the upper crust in response to flexure of the lithosphere and accommodate subsidence within the foredeep and forebulge depozones. Such faults are excellent proxies for orogenic system evolution and control the distribution of natural resources and hazards. However, the spatiotemporal evolution of flexural extension has not been documented previously at a regional scale, thereby limiting our understanding of underlying geodynamic controls. Here, we resolve late Paleozoic flexural extension in the northern Arkoma basin and southern Ozark dome, USA. We synthesize a large database of previous mapping, existing research, subsurface data, and geophysical data into 3D geologic and 2D kinematic models. Mesh surfaces representing several key horizons from the Carboniferous Period (ca. 335-306 Ma) were constructed. These surfaces were built from oil and gas well tops (n = ∼10,000) and surface geologic map contacts using an advanced kriging method. The mesh surfaces are offset by a complex 3D fault network, allowing detailed analysis of along-strike and down-dip variations in fault displacement. Analysis of the 3D model reveals a regular and repeated fault segmentation pattern wherein E -W striking, left- and foreland-stepping en échelon normal faults are segmented by inherited NE striking basement faults. Maximum vertical separation along the E -W normal faults is generally focused between the inherited NE-trending faults. This suggests that the inherited basement faults delocalized extensional strain during late Paleozoic normal faulting. Maximum vertical separation and fault localization may correlate to areas with high-amplitude positive magnetic anomalies interpreted as Mesoproterozoic granitic rocks. Speculative covariance of magnetic anomalies and fault displacements implies that the relatively strong basement granite concentrated stress, leading to localized faulting within the relatively thin sedimentary cover. Lastly, we show that flexural extension migrated southeast to northwest from the Chesterian-Morrowan (ca. 335-319 Ma) to the Desmoinesian (ca. 306 Ma). The migratory flexural extension may be explained by diachronous loading during Pangean assembly, or by synchronous loading but variable load compensation due to inherent factors.

Arkansas, Oklahoma