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At least 307 records · Page 17Linked to original sources
USGS1998

Water-quality assessment of the Central Arizona Basins, Arizona and northern Mexico – Environmental setting and overview of water quality

The Central Arizona Basins study area in central and southern Arizona and northern Mexico is one of 60 study units that are part of the U.S. Geological Survey's National Water-Quality Assessment program. The purpose of this report is to describe the physical, chemical, and environmental characteristics that may affect water quality in the Central Arizona Basins study area and present an overview of water quality. Covering 34,700 square miles, the study area is characterized by generally north to northwestward-trending mountain ranges separated by broad, gently sloping alluvial valleys. Most of the perennial rivers and streams are in the northern part of the study area. Rivers and streams in the south are predominantly intermittent or ephemeral and flow in response to precipitation such as summer thunderstorms. Effluent-dependent streams do provide perennial flow in some reaches. The major aquifers in the study area are in the basin-fill deposits that may be as much as 12,000 feet thick. The 1990 population in the study area was about 3.45 million, and about 61 percent of the total was in Maricopa County (Phoenix and surrounding cities). Extensive population growth over the past decade has resulted in a twofold increase in urban land areas and increased municipal water use; however, agriculture remains the major water use. Seventy-three percent of all water with drawn in the study area during 1990 was used for agricultural purposes. The largest rivers in the study area-the Gila, Salt, and Verde-are perennial near their headwaters but become intermittent downstream because of impoundments and artificial diversions. As a result, the Central Arizona Basins study area is unique compared to less arid basins because the mean surface-water outflow is only 528 cubic feet per second from a total drainage area of 49,650 square miles. Peak flows in the northern part of the study area are the result of snowmelt runoff; whereas, summer thunderstorms account for the peak flows in the southern part. Ground water is the primary water supply in most of Arizona and the only source of drinking water used by communities in the southern half of the study area. Years of overpumping have caused water tables in basin fill to drop below once-perennial streams leaving streambeds dry, water too deep to pump economically, pumping of poorer quality water with depth, and earth fissures resulting from subsidence after dewatering of sediments. Natural processes-such as leaching of trace elements and major ions from geologic formations-and human activities-such as mining, agriculture, and urban development-have major effects on the quality of surface-water and ground-water resources in the Central Arizona Basins study area. Surface-water quality standards in Arizona are based on the designated use of the water such as full or partial body contact, fish consumption, aquatic and wildlife uses, and agriculture. Maintaining the biological integrity (health) of surface waters in Arizona is an important part of ensuring that these waters are suitable for designated uses. Important water-quality issues for surface water that are somewhat unique to Arizona include: (1) streamflows and riparian environments sustained by effluent from municipal wastewater-treatment plants that contains high concentrations of nutrients, potentially toxic trace elements and organic compounds, and fecal bacteria; (2) industrial, mining, agricultural, and municipal sources of contamination from Mexico; and (3) unpredictable high flows from major summer thunder storms causing stream-channel changes; high suspended-sediment concentrations and loads; sewage overflows; and breaching, erosion, and washout of landfills and mining operations. The quality of water in aquifers that are protected for drinking- water use is subject to standards that are in most cases equal to or more stringent than the primary drinking-water regulations of the U.S. Environmental Protection Agency. The general che

Arizona↗
USGS2011

Sediment dynamics and the burial and exhumation of bedrock reefs along an emergent coastline as elucidated by repetitive sonar surveys: Northern Monterey Bay, CA

Two high-resolution bathymetric and acoustic backscatter sonar surveys were conducted along the energetic emergent inner shelf of northern Monterey Bay, CA, USA, in the fall of 2005 and the spring of 2006 to determine the impact of winter storm waves, beach erosion, and river floods on biologically-important siliclastic bedrock reef habitats. The surveys extended from water depths of 4 m to 22 m and covered an area of 3.14 km2, 45.8% of which was bedrock, gravel, and coarse-grained sand and 54.2% was fine-grained sand. Our analyses of the bathymetric and acoustic backscatter data demonstrates that during the 6 months between surveys, 11.4% of the study area was buried by fine-grained sand while erosion resulted in the exposure of bedrock or coarse-grained sand over 26.5% of the study area. The probability of burial decreased with increasing water depth and rugosity; the probability of exhumation increased with increasing wave-induced near-bed shear stress, seabed slope and rugosity. Much of the detected change was at the boundary between bedrock and unconsolidated sediment due to sedimentation and erosion burying or exhuming bedrock, respectively. In a number of cases, however, the change in seabed character was apparently due to changes in sediment grain size when scour exposed what appeared to be an underlying coarser-grained lag or the burial of coarser-grained sand and gravel by fine-grained sand. These findings suggest that, in some places, (a) burial and exhumation of nearshore bedrock reefs along rocky, energetic inner shelves occurs over seasonal timescales and appears related to intrinsic factors such as seabed morphology and extrinsic factors such as wave forces, and (b) single acoustic surveys typically employed for geologic characterization and/or habitat mapping may not adequately characterize the geomorphologic and sedimentologic nature of these types of environments that typify most of the Pacific Ocean and up to 50% of the world's coastlines.

Monterey Bay↗
USGS2019

Pesticides and pollinators: A socioecological synthesis

The relationship between pesticides and pollinators , while attracting no shortage of attention from scientists, regulators, and the public, has proven resistant to scientific synthesis and fractious in matters of policy and public opinion. This is in part because the issue has been approached in a compartmentalized and intradisciplinary way, such that evaluations of organismal pesticide effects remain largely disjoint from their upstream drivers and downstream consequences. Here, we present a socioecological framework designed to synthesize the pesticide-pollinator system and inform future scholarship and action. Our framework consists of three interlocking domains-pesticide use, pesticide exposure, and pesticide effects–each consisting of causally linked patterns, processes, and states. We elaborate each of these domains and their linkages, reviewing relevant literature and providing empirical case studies. We then propose guidelines for future pesticide-pollinator scholarship and action agenda aimed at strengthening knowledge in neglected domains and integrating knowledge across domains to provide decision support for stakeholders and policymakers. Specifically, we emphasize (1) stakeholder engagement, (2) mechanistic study of pesticide exposure, (3) understanding the propagation of pesticide effects across levels of organization, and (4) full-cost accounting of the externalities of pesticide use and regulation. Addressing these items will require transdisciplinary collaborations within and beyond the scientific community, including the expertise of farmers, agrochemical developers, and policymakers in an extended peer community.

Science of the Total Environment↗
USGS2022

Measured efficacy, bioaccumulation, and leaching of a transfluthrin-based insecticidal paint: A case study with a nuisance, nonbiting aquatic insect

BACKGROUND Pest management professionals will require a diverse, adaptive abatement toolbox to combat advanced challenges from disease vector and nuisance insect populations. Designed for post-application longevity, insecticidal paints offer extended residual effects on targeted insect pest populations; a measured understanding of active ingredient bioavailability over time is valuable to fully assess treatment efficacy and potential environmental risks. This study was initiated because a nuisance net-spinning caddisfly, Smicridea fasciatella , is lowering the quality of life for riverfront residents at the type locality. RESULTS We tested the efficacy and potential mobility of a transfluthrin-based paint (a.i. 0.50%), comparing the impacts of UV exposure and substrate texture over time. Direct UV exposure decreased efficacy (β ± S.E. = 0.008 ± 0.001, P < 0.001) and a coarse texture maintained greater efficacy (β ± S.E. = −3.7 ± 1.3, P = 0.004) over time. Notably, the coarse texture + indirect UV treatment maintained 100% mortality after 240 days. UV exposure and substrate texture did not have a significant impact on leachate concentrations over time, and successive immersion tests indicated a two-phase emission pattern. Bioaccumulation increased with time on the cuticle of dead adult S. fasciatella ; after 24 h of direct exposure the concentration of transfluthrin was 25.3 ± 0.9 ng/caddisfly with a maximum concentration of 345 ng/caddisfly after 7 days. CONCLUSION Our predictions were validated with measured, time-dependent impacts on efficacy, leachability, and bioaccumulation. Because of the mobility of active ingredient in the environment, insecticidal paints merit low-impact protocols to improve public health outcomes and environmental safety. © 2022 Society of Chemical Industry.

Pest Management Science↗
USGS2000

Occurrence of cotton herbicides and insecticides in playa lakes of the High Plains of West Texas

During the summer of 1997, water samples were collected and analyzed for pesticides from 32 playa lakes of the High Plains that receive drainage from both cotton and corn agriculture in West Texas. The major cotton herbicides detected in the water samples were diuron, fluometuron, metolachlor, norflurazon, and prometryn. Atrazine and propazine, corn and sorghum herbicides, were also routinely detected in samples from the playa lakes. Furthermore, the metabolites of all the herbicides studied were found in the playa lake samples. In some cases, the concentration of metabolites was equal to or exceeded the concentration of the parent compound. The types of metabolites detected suggested that the parent compounds had been transported to and had undergone degradation in the playa lakes. The types of metabolites and the ratio of metabolites to parent compounds may be useful in indicating the time that the herbicides were transported to the playa lakes. The median concentration of total herbicides was 7.2 μg/l, with the largest total concentrations exceeding 30 μg/l. Organophosphate insecticides were detected in only one water sample. Further work will improve the understanding of the fate of these compounds in the playa lake area.

Science of Total Environment↗
USGS2021

Complex sedimentary processes in large coastal embayments and their potential for coastal morphological and paleo tropical cyclone studies: A case study from Choctawhatchee Bay Western Florida, U.S.A

Storminess and sea-level can both have a significant impact on landforms in cyclone-prone coastal regions, although much of our understanding comes from short-timescale modern observations. This study aims to understand the variability of sediment transport and deposition in the Choctawhatchee Bay/Santa Rosa Island in the northern Gulf of Mexico, establishing the dominant sediment transport processes and morphological response of the barrier system to long-term variations in storminess and rising sea-levels. Here, we study the spatial and temporal changes in physicochemical properties of the sedimentary record of Choctawhatchee Bay to examine the character and fidelity of records of storm impacts spanning the Holocene. Proxies for marine and terrestrial conditions in the cores situated closer to the present barrier (proximal) show that sedimentation in coastal areas and marine influence of the bay during the last ~8000 yrs. were mainly determined by barrier response to the Holocene transgression and changes in storminess. In contrast, sedimentation close to the landward shore was governed by terrigenous input. The correlation of grain size and terrigenous proxies with regional hurricane records indicates that hinterland erosion by the rainfall during hurricane events is likely the dominant terrigenous sediment transport mechanism in areas close to the landward shore of the bay. These results suggest that sediment archives in large coastal deposition environments are equally suitable for sea level and cyclone modulated coastal morphological studies and paleo tropical cyclone studies, depending on the location, selected with an understanding of sedimentation processes in the vicinity.

Florida↗
USGS2026

Compounding of 100-year coastal floods by rainfall in an urban environment

Coastal and pluvial flooding are both becoming more prevalent and severe due to climate change and urbanization in floodplains. The co-occurrence of these flood drivers is generally assumed to exacerbate the resulting flood impacts, a result referred to as compound flooding. However, few observational or modeling studies have investigated the circumstances under which this occurs. Here, we study the impacts of these combined flood drivers and evaluate the implicit hypothesis of official flood maps, which is that rainfall has a negligible impact on the flood depth and flooded area due to a 100 year coastal flood. A coastal system model, configured to capture coastal and pluvial flood drivers, is used. We evaluate the flooding for different urban landform types, including coastal landfill (human-made land), convergent areas (topographic depressions) and other urban terrain, within a model domain covering the Jamaica Bay watershed of New York City. A scenario-based strategy is adopted with a 100 year coastal flood as a control simulation, to which we add a set of realistic scenarios of rainfall data from historical tropical cyclones. We also apply a joint probability analysis framework with historical data to evaluate the probability of these compound coastal-pluvial scenarios. Results reveal cases where the pluvial driver compounds the coastal flood through expansion of the flood zone, with a 17% chance of rainfall increasing the flood area by 6%–38%, and a 5% chance of an increase of 61%–73%. It is rare that floods are significantly deepened but when deepening occurs, it is more common for the convergent zone than for the coastal landfill. These findings quantitatively assess the potential of the pluvial driver to exacerbate flooding, which may influence emergency management strategies such as evacuation plans, shelter arrangements, and related preparedness measures.

New York↗
USGS2017

Building translational ecology communities of practice: insights from the field

Translational ecology (TE) prioritizes the understanding of social systems and decision contexts in order to address complex natural resource management issues. Although many practitioners in applied fields employ translational tactics, the body of literature addressing such approaches is limited. We present several case studies illustrating the principles of TE and the diversity of its applications. We anticipate that these examples will help others develop scientific products that decision makers can use “off the shelf” when solving critical ecological and social challenges. Our collective experience suggests that research of such immediate utility is rare. Long‐term commitment to working directly with partners to develop and reach shared goals is central to successful translation. The examples discussed here highlight the benefits of translational processes, including actionable scientific results, more informed policy making, increased investment in science‐driven solutions, and inspiration for partnerships. We aim to facilitate future TE‐based projects and build momentum for growing this community of practice.

Frontiers in Ecology and the Environment↗
USGS2022

The role of organic matter diversity on the Re-Os systematics of organic-rich sedimentary units: Insights into the controls of isochron age determinations from the lacustrine Green River Formation

The range of 187 Re/ 188 Os values measured from samples of five organic-rich lacustrine mudstones units in the Eocene Green River Formation in the easternmost Uinta Basin covaries with organic matter diversity driven by changing water column conditions. A set of samples from the Douglas Creek Member has the highest pristane/phytane ratio and lowest β-carotane/ n -C 30 ratio compared to overlying units, indicating deposition in an oxic-anoxic environment with low salinity that would have allowed for the accumulation of a diverse assemblage of aquatic organisms. These samples define the broadest 187 Re/ 188 Os range of 1504. In contrast, samples from the R6 and Mahogany zones possess lower pristane/phytane ratios and higher β-carotane/ n -C 30 ratios indicating deposition in a more restricted lacustrine environment with elevated salinities and alkalinities that would have limited aquatic organic matter diversity. The R6 and Mahogany zones have the narrowest range of 187 Re/ 188 Os values measured in this study of 254.9 and 154.6, respectively. As noted by previous workers, these results suggest that organic matter diversity plays a primary role in determining the range of 187 Re/ 188 Os ratios in a sample set, and in turn the uncertainty of Re-Os age determinations from organic-rich sedimentary rocks. The Re-Os data from the R3 zone and R6 zone yield ages of 49.7 ± 3.4 Ma and 42.0 ± 18 Ma, respectively, which are statistically indistinguishable based on 2σ uncertainty from three previously reported Re-Os age determinations and those provided by 40 Ar/ 39 Ar geochronology of interbedded volcanic ash beds. Although the age uncertainty is high, these findings further highlight the importance of Re-Os geochronology in lacustrine basins, particularly those with thick mudstone successions that lack volcanic ash layers, reliable biostratigraphy , or magnetostratigraphic control. In these cases, even ages with large uncertainties can be useful to constrain burial history and thermal history models. Together, the initial 187 Os/ 188 Os ratios of five sets of samples analyzed from the Uinta Basin define the largest Os isotope stratigraphic record from any lacustrine basin compiled to date and record a shift from a value of 1.40 to 1.48 between the R3 and R4 zones in the lower part of the Parachute Creek Member. This small shift may signify a change in the chemical weathering products that entered the lake preserved 20 to 50 m above the contact between the Douglas Creek and the lower Parachute Creek members during a period when the basin transitioned from a shallow lake with mostly open hydrology to an alkaline lake with more frequent basin restrictions.

Colorado, Utah, Wyoming↗
USGS2026

Towards global mapping of dynamic surface water extents using Sentinel-1 SAR data

We introduce a fully automated and scalable method for mapping surface water extents from single-acquisition Sentinel-1 synthetic aperture radar (SAR) imagery. This approach integrates adaptive thresholding of radiometric terrain-corrected SAR backscatter data, fuzzy-logic classification, region growing, dark land estimation, and a bimodality test to minimize false positives in low-backscattering areas and false negatives in high-backscattering areas. By combining these steps, the algorithm achieves classification accuracies exceeding 85% in detecting surface water extents across diverse environmental conditions. Accuracy was first assessed at meter scale using 52 PlanetScope scenes acquired worldwide in September–October 2019; the algorithm achieved 93% overall accuracy, 86% user's accuracy, and 94% producer's accuracy. Global robustness was then evaluated by processing every Sentinel-1 acquisition from 1 to 12 November 2023 and cross-comparing the resulting maps with 6561 temporally matched observational products for end-users from remote sensing analysis (OPERA) dynamic surface water extent from Harmonized Landsat and Sentinel-2 (DSWx-HLS) products. This large-scale test yielded 90% user's and 94% producer's accuracies, confirming reliable performance at continental extent. Additional case studies demonstrate the algorithm's ability to handle surface water extent in sand-dominated deserts, to track seasonal amplitude in Folsom Lake (California), drought-induced loss in Cerro Prieto Reservoir (Mexico), and rapid filling of the Grand Ethiopian Renaissance Dam. These results show that the method scales across local to global domains and maintains high accuracy, providing a practical tool for near-real-time monitoring of floods, droughts, and water-resource management. Because the approach is sensor-agnostic, it can be ported to forthcoming L- and S-band missions such as NASA-ISRO synthetic aperture radar (NISAR), broadening its applicability to future hydrologic observations.

Remote Sensing of Environment↗
USGS2012

Flood risk awareness during the 2011 floods in the central United States: showcasing the importance of hydrologic data and interagency collaboration

Floods have long had a major impact on society and the environment, evidenced by the more than 1,500 federal disaster declarations since 1952 that were associated with flooding. Calendar year 2011 was an epic year for floods in the United States, from the flooding on the Red River of the North in late spring to the Ohio, Mississippi, and Missouri River basin floods in the spring and summer to the flooding caused by Hurricane Irene along the eastern seaboard in August. As a society, we continually seek to reduce flood impacts, with these efforts loosely grouped into two categories: mitigation and risk awareness. Mitigation involves such activities as flood assessment, flood control implementation, and regulatory activities such as storm water and floodplain ordinances. Risk awareness ranges from issuance of flood forecasts and warnings to education of lay audiences about the uncertainties inherent in assessing flood probability and risk. This paper concentrates on the issue of flood risk awareness, specifically the importance of hydrologic data and good interagency communication in providing accurate and timely flood forecasts to maximize risk awareness. The 2011 floods in the central United States provide a case study of the importance of hydrologic data and the value of proper, timely, and organized communication and collaboration around the collection and dissemination of that hydrologic data in enhancing the effectiveness of flood forecasting and flood risk awareness.

Leadership and Management in Engineering↗
USGS2026

Effects of human activity on Khumbu Glacier: Towards a sustainable Everest Base Camp

The Everest Base Camp (EBC), a critical staging area for mountaineers attempting to summit Mount Everest, has seen a significant increase in human activity over the past few decades. The increasing number of climbers, trekkers, and support staff, particularly at the campsite area, has intensified environmental impacts on the Khumbu Glacier. This study investigates the effects of human activity at EBC, focusing on three contributors to glacier melt: global climate change, local fossil fuel consumption, and human urinary discharge. Through field data collected during the spring 2023 climbing season, this study examines the energy released through the use of liquefied petroleum gas (LPG), kerosene, and petrol for cooking, heating, and electricity, as well as the heat generated by human urinary discharge. The total heat energy released from these activities at EBC in the spring of 2023 was 849,174 ± 179,774 MJ, which would be sufficient to melt 2492 ± 528 tons of glacier ice and snow. Trends in land surface temperature at EBC and adjacent environments during the 1991–2023 period were calculated from Landsat 5, 7, and 9 satellite data. The 32-year Landsat record reveals that EBC surface temperature increased by 0.28 °C year −1 , which was roughly twice the rate of warming at the surface of Khumbu Glacier adjacent to EBC and about 15% higher than the temperature increase of the debris-covered terrain immediately to the north of EBC. The findings suggest that addressing these anthropogenic influences could help to preserve the Khumbu Glacier and support the sustainability of mountaineering in the region. This paper also takes a transformative approach and explores stable and safer locations in case there is a necessity to relocate the current EBC. Two sites have been identified southwest of the existing EBC, which, unlike the current supraglacial site, are situated on stable ground.

Everest Base Camp, Khumbu Glacier↗
USGS2016

Mortality monitoring design for utility-scale solar power facilities

Introduction Solar power represents an important and rapidly expanding component of the renewable energy portfolio of the United States (Lovich and Ennen, 2011; Hernandez and others, 2014). Understanding the impacts of renewable energy development on wildlife is a priority for the U.S. Fish and Wildlife Service (FWS) in compliance with Department of Interior Order No. 3285 (U.S. Department of the Interior, 2009) to “develop best management practices for renewable energy and transmission projects on the public lands to ensure the most environmentally responsible development and delivery of renewable energy.” Recent studies examining effects of renewable energy development on mortality of migratory birds have primarily focused on wind energy (California Energy Commission and California Department of Fish and Game, 2007), and in 2012 the FWS published guidance for addressing wildlife conservation concerns at all stages of land-based wind energy development (U.S. Fish and Wildlife Service, 2012). As yet, no similar guidelines exist for solar development, and no published studies have directly addressed the methodology needed to accurately estimate mortality of birds and bats at solar facilities. In the absence of such guidelines, ad hoc methodologies applied to solar energy projects may lead to estimates of wildlife mortality rates that are insufficiently accurate and precise to meaningfully inform conversations regarding unintended consequences of this energy source and management decisions to mitigate impacts. Although significant advances in monitoring protocols for wind facilities have been made in recent years, there remains a need to provide consistent guidance and study design to quantify mortality of bats, and resident and migrating birds at solar power facilities (Walston and others, 2015). In this document, we suggest methods for mortality monitoring at solar facilities that are based on current methods used at wind power facilities but adapted for the unique conditions encountered at solar facilities. In particular, unlike at wind-power facilities, the unimpeded access to almost all areas within the facilities, the typically flat terrain, and general absence of thick vegetation allow distance-sampling techniques (Buckland and others, 2001, 2004) to be exploited to advantage at industrial solar sites. These protocols build on the work of Nicolai and others (2011), and as our understanding and techniques for monitoring improve, the methods may be further modified to incorporate improvements in the future. We present case studies based on monitoring methods currently implemented at different utility-scale solar facilities to illustrate how distance-sampling techniques may improve overall detectability without substantially increasing costs. Every facility is unique, and the protocols presented may be adapted based on specific monitoring objectives and conditions at each site. We provide guidance for designing monitoring programs whose objective it is to estimate the total number of bird and bat fatalities occurring at a facility over an extended period of time. We address spatial variation in causes of mortality, as well as potential sources of imperfect detection, for example, animals falling in or moving to unsearched areas, carcasses removed by predators, and carcasses missed by searchers. We suggest methods to estimate and account for each source of imperfect detection. This document focuses on monitoring design only and does not discuss approaches for estimating mortality from collected data. The development of statistically sound estimators relevant to the solar context is a current topic of research, although there are already strong foundations for estimation with distance-sampling methods in similar open, arid environments (Anderson and others, 2001; Freilich and others, 2005). Nonetheless, if protocols described in this document are followed, the resulting data will be adequate and sufficient for estimating mortality using newly formulated estimators.

Open-File Report↗
USGS2001

The influence of biological soil crusts on mineral uptake by associated vascular plants

Soil surfaces dominated by cyanobacteria and cyanolichens (such as Collema sp.) are widespread in deserts of the world. The influence of these biological soil crusts on the uptake of bioessential elements is reported for the first time for six seed plants of the deserts of Utah. This sample almost doubles the number of species for which the influence of biological soil crusts on mineral uptake of associated vascular plants is known. These new case studies, and others previously published, demonstrate that cyanobacterial or cyanobacteria- Collema crusts significantly alter uptake by plants of many bioessential elements. In studies now available, these crusts always increase the N content of associated seed plants. Uptake of Cu, K, Mg, and Zn is usually (>70% of reported cases) increased in the presence of the biological soil crusts. Soil crusts are generally negatively associated with Fe and P levels in associated seed plant tissue, while plant tissue levels of Ca, Mn, and Na are positively as often as negatively associated with the presence of soil crusts. Increases in bioessential elements in vascular plant tissue from biologically-crusted areas are greatest for short-lived herbs that are rooted primarily within the surface soil, the horizon most influenced by crustal organisms. The mineral content of a deeply rooted shrub ( Coleogyne ramosissima ) was less influenced by co-occurrence of biological soil crusts.

Utah↗
USGS2020

Development of a submerged aquatic vegetation growth model in the Coupled Ocean–Atmosphere–Wave–Sediment Transport (COAWST v3.4) model

The coupled biophysical interactions between submerged aquatic vegetation (SAV), hydrodynamics (currents and waves), sediment dynamics, and nutrient cycling have long been of interest in estuarine environments. Recent observational studies have addressed feedbacks between SAV meadows and their role in modifying current velocity, sedimentation, and nutrient cycling. To represent these dynamic processes in a numerical model, the presence of SAV and its effect on hydrodynamics (currents and waves) and sediment dynamics was incorporated into the open-source Coupled Ocean–Atmosphere–Wave–Sediment Transport (COAWST) model. In this study, we extend the COAWST modeling framework to account for dynamic changes of SAV and associated epiphyte biomass. Modeled SAV biomass is represented as a function of temperature, light, and nutrient availability. The modeled SAV community exchanges nutrients, detritus, dissolved inorganic carbon, and dissolved oxygen with the water-column biogeochemistry model. The dynamic simulation of SAV biomass allows the plants to both respond to and cause changes in the water column and sediment bed properties, hydrodynamics, and sediment transport (i.e., a two-way feedback). We demonstrate the behavior of these modeled processes through application to an idealized domain and then apply the model to a eutrophic harbor where SAV dieback is a result of anthropogenic nitrate loading and eutrophication. These cases demonstrate an advance in the deterministic modeling of coupled biophysical processes and will further our understanding of future ecosystem change.

Geoscientific Model Development↗
USGS2019

Success of lake restoration depends on spatial aspects of nutrient loading and hydrology

Many aquatic ecosystems have deteriorated due to human activities and their restoration is often troublesome. It is proposed here that the restoration success of deteriorated lakes critically depends on hitherto largely neglected spatial heterogeneity in nutrient loading and hydrology. A modelling approach is used to study this hypothesis by considering four lake types with contrasting nutrient loading (point versus diffuse) and hydrology (seepage versus drainage). By comparing the longterm effect of common restoration measures (nutrient load reduction, lake flushing or biomanipulation) in these four lake types, we found that restoration through reduction of nutrient loading is effective in all cases. In contrast, biomanipulation only works in seepage lakes with diffuse nutrient inputs, while lake flushing will even be counterproductive in lakes with nutrient point sources. The main conclusion of the presented analysis is that a priori assessment of spatial heterogeneity caused by nutrient loading and hydrology is essential for successful restoration of lake ecosystems.

Science of the Total Environment↗
USGS2024

Studies of the Reactivity of the Ferrihydrite Surface by Iron Isotopic Exchange and Mössbauer Spectroscopy

Two-line ferrihydrite is an important adsorbent of many toxics in natural and anthropogenic systems; however, the specific structural sites responsible for the high adsorption capacity are not well understood. A combination of chemical and spectroscopic techniques have been employed in this study to gain further insight into the structural nature of sites at the ferrihydrite surface. The kinetics of iron isotopic exchange demonstrated that there are at least two types of iron sites in ferrihydrite. One population of sites, referred to as labile sites, approached iron isotopic equilibrium within 24 hr in 59 Fe-NTA solutions, while the second population of sites, referred to as non-labile , exhibited a much slower rate of isotopic exchange. Adsorbed arsenate reduced the degree of exchange by labile sites, indicating that the anion blocked or greatly inhibited the rate of exchange of these sites. Mössbauer spectra were collected from a variety of samples including 56 Fe-ferrihydrite samples with 57 Fe in labile sites, samples containing 57 Fe throughout the structure, and samples with 57 Fe in non-labile sites. The spectra showed characteristic broad doublets signifying poor structural order. Refined fits of the spectra indicated that labile sites have larger quadrupole splitting, hence more local distortion, than non-labile sites. In all cases, the spectra demonstrated some degree of asymmetry, indicating a distribution of Fe environments in ferrihydrite. Overall spectral findings, combined with recent EXAFS results (Waychunas et al. , 1993), indicate that labile sites likely are more reactive (with respect to iron isotopic exchange) because they have fewer neighboring Fe octahedra and are therefore bound less strongly to the ferrihydrite structure. The labile population of sites probably is composed of end sites of the dioctahedral chain structure of 2-line ferrihydrite, which is a subset of the entire population of surface sites. Mössbauer spectra of samples containing adsorbed arsenate indicated that the anion may slightly decrease the distortion of labile sites and stabilized the structure as a whole by bidentate bonding.

Clays and Clay Minerals↗
USGS1978

Conceptual models in exploration geochemistry-The Basin and Range Province of the Western United States and Northern Mexico

This summary of geochemical exploration in the Basin and Range Province is another in the series of reviews of geochemical-exploration applications covering a large region; this series began in 1975 with a summary for the Canadian Cordillera and Canadian Shield, and was followed in 1976 by a similar summary for Scandinavia (Norden). Rather than adhering strictly to the type of conceptual models applied in those papers, we have made use of generalized landscape geochemistry models related to the nature of concealment of ore deposits. This study is part of a continuing effort to examine and evaluate geochemical-exploration practices in different areas of the world. Twenty case histories of the application of geochemical exploration in both district and regional settings illustrate recent developments in techniques and approaches. Along with other published reports these case histories, exemplifying generalized models of concealed deposits, provide data used to evaluate geochemical-exploration programs and specific sample media. Because blind deposits are increasingly sought in the Basin and Range Province, the use of new sample media or anomaly-enhancement techniques is a necessity. Analysis of vapors or gases emanating from blind deposits is a promising new technique. Certain fractions of stream sediments show anomalies that are weak or not detected in conventional minus 80-mesh fractions. Multi-element analysis of mineralized bedrock may show zoning patterns that indicate depth or direction of ore. Examples of the application of these and other, more conventional methods are indicated in the case histories. The final section of this paper contains a brief evaluation of the applications of all types of sample media to geochemical exploration in the arid environment of the Basin and Range Province. ?? 1978.

Journal of Geochemical Exploration↗