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At least 289 records · Page 16Linked to original sources

GIS-based method for estimating surficial groundwater levels in coastal Virginia using limited information

In many coastal areas, high water tables are present, complicating installation of some stormwater best management practices (BMPs) that rely on infiltration. Regional estimates of the seasonal high water table (SHWT) often rely on sources such as soil surveys taken over a decade ago; these data are static and do not account for groundwater withdrawals or other anthropogenic impacts. To improve estimates of the SHWT, we developed a GIS-based methodology relying on surface water elevations. Data sources included a 1.5-m (5.0 ft) resolution Lidar-derived digital elevation model (DEM), aerial imagery, and publicly available shapefiles of water boundaries. Twenty-six groundwater monitoring wells were screened to eliminate well locations influenced by pumping, yielding 22 wells. In coastal Virginia, tidal water bodies and ditches form terminal boundaries for discharge from the water-table aquifers and permit water table elevations to be fixed at the landward boundaries of surface water bodies. Water table elevations interpolated from well data and boundary elevations were used to create a triangulated irregular network representing the water table elevations for November 2012, which was the date of the DEM. An adjustment factor, calculated from the highest recorded April water table depth from long-term groundwater monitoring data, was added to estimate the SHWT elevation. SHWT elevations were subtracted from the DEM to yield SHWT depth, which was compared with long-term monitoring well data, yielding an R2 value of 0.91. Residual errors were random, although the method underpredicted the highest expected SHWT and overpredicted the median SHWT. The SHWT depth map was validated by using water table depths from 57 soil borings at 10 different sites, and consistently matched observations better than available soil survey estimates. The SHWT depth map could be useful for BMP siting and feasibility studies in similar hydrogeological settings.

Virginia↗

Water quality at Chaco Culture National Historical Park and the potential effects of hydrocarbon extraction

Study region Chaco Culture National Historical Park (CCNHP) is in the San Juan Basin of northwestern New Mexico, U.S.A. Its only water supply is in Gallup Sandstone aquifer, stratigraphically surrounded by layers long targeted for oil and natural gas extraction. Study focus To assess groundwater flow direction, age, mixing between aquifers, and whether hydrocarbons extraction may affect water quality, we completed a geochemical groundwater sampling campaign. Groundwater at 11 sites was analyzed for major ions, hydrocarbon associated volatile organic carbon (VOC) compounds, noble gases, and the isotope systems δ 2 H, δ 18 O, 87 Sr/ 86 Sr, δ 13 C, and 14 C. New hydrological insights for the region Results demonstrate that all sampled groundwaters are exceedingly old and geochemically evolved, with a median 14 C age of ∼41,000 years before present and a north flowing path. Three lines of evidence suggest mixing between aquifers through relatively impermeable shale units and mixing with hydrocarbons: 1) noble gases are fractionated likely through mixing with connate water expelled during hydrocarbon genesis; 2) several wells—including the park’s main supply well—contained trace amounts of hydrocarbon related VOC compounds; and 3) major ion analysis shows mixing trends between aquifers. We hypothesize that cross-aquifer mixing may be facilitated through the region’s numerous hydrocarbon related boreholes. Whether our findings are the result of oil and gas extraction or represent the natural state of the aquifers will require more research.

New Mexico↗

Hydrologic effects on water level changes associated with episodic fault creep near Parkfield, California

As part of the Parkfield, California, earthquake prediction experiment, water level is monitored in a well 460 m from the main trace of the San Andreas fault on Middle Mountain, in the preparation zone of the anticipated Parkfield earthquake. The well configuration allows water level to be monitored in two fluid reservoirs at depths of 85 and 250 m below land surface. During 1987, water level changes were recorded during 12 of the 18 episodes of accelerated fault creep detected by a creep meter spanning the fault trace 750 m northwest of the well. The creep-related water level changes in the shallow reservoir have durations of less than 1 day, whereas in the deeper reservoir the changes persist for as long as 2 months. These data suggest that the transient nature of the water level changes in the shallow interval is due to vertical flow to the water table and is not evidence that creep events propagate past the well. Phase leads of earth tidal constituents in the water level data from the shallow interval relative to the same constituents in the local volume strain tide support the interpretation of significant flow to the water table at periods of 1 day or less. The form of the water level changes in the deep interval is affected by horizontal flow to the well bore. This effect can be removed from the water level records using a theoretical response curve constrained by the phases of earth tidal constituents in the deep interval relative to the local volume strain tide. For the events where the signal in the shallow interval has been large enough to measure, the sizes of the simultaneous water level changes in the two reservoirs are consistent with the same amounts of volume strain occurring at both depths.

Journal of Geophysical Research Solid Earth↗

Quantifying background nitrate removal mechanisms in an agricultural watershed with contrasting subcatchment baseflow concentrations

Numerous studies have documented the linkages between agricultural nitrogen loads and surface water degradation. In contrast, potential water quality improvements due to agricultural best management practices are difficult to detect because of the confounding effect of background nitrate removal rates, as well as the groundwater-driven delay between land surface action and stream response. To characterize background controls on nitrate removal in two agricultural catchments, we calibrated groundwater travel time distributions with subsurface environmental tracer data to quantify the lag time between historic agricultural inputs and measured baseflow nitrate. We then estimated spatially distributed loading to the water table from nitrate measurements at monitoring wells, using machine learning techniques to extrapolate the loading to unmonitored portions of the catchment to subsequently estimate catchment removal controls. Multiple models agree that in-stream processes remove as much as 75% of incoming loads for one subcatchment while removing <20% of incoming loads for the other. The use of a spatially variable loading field did not result in meaningfully different optimized parameter estimates or model performance when compared with spatially constant loading derived directly from a county-scale agricultural nitrogen budget. Although previous studies using individual well measurements have shown that subsurface denitrification due to contact with a reducing argillaceous confining unit plays an important role in nitrate removal, the catchment-scale contribution of this process is difficult to quantify given the available data. Nonetheless, the study provides a baseline characterization of nitrate transport timescales and removal mechanisms that will support future efforts to detect water quality benefits from ongoing best management practice implementation.

Maryland↗

Formation pressure and fluid flow measurements in marine gas hydrate reservoirs, NGHP-02 expedition, offshore India

Open Hole Modular Dynamic Testing (MDT) measurements were conducted in a gas hydrate-bearing sand-rich reservoir offshore India during the National Gas Hydrate Program 02 (NGHP-02) Expedition. The primary goal of this test was to obtain effective reservoir petrophysical properties in the presence of gas hydrates. The test plan included a series of pre-hydrate dissociation flow and build-up (shut-in) tests, and an attempt to dissociate gas hydrate in a sand-rich reservoir by depressurization to collect formation fluid samples and to further characterize in situ gas hydrate stability conditions. Schlumberger’s wireline MDT tool was used in a dual-packer configuration to isolate the formation being tested. This paper presents the results of the open hole MDT measurements that were conducted in Hole NGHP-02-23-C in Krishna-Godavari Basin at a water depth of 2553.5 m. The MDT dual packer test was conducted in 27 cm (10.63 in) diameter open hole section of the borehole within a 1-m interval isolated between two inflatable packers with the midpoint of the test interval at 2853.0 meter below rig floor (mbrf) (271.0 meter below sea floor (mbsf)). This was the first gas hydrate MDT test ever conducted in ultradeep water to characterize a gas hydrate reservoir system. Pre-hydrate dissociation testing was performed with a drawdown period (depressurization) of 20 minutes followed by a build-up (shut-in) of 20 minutes. The measured formation pressure was 4090.7 psia and the formation fluid (i.e., water) mobility was calculated at 1.98 mD/cP. During the second dissociation phase of the same test a maximum pressure drawdown of 840 psia was achieved; however, falling short of the 1120 psia drawdown required for dissociation. During the dissociation test the flow line pressure stabilized at a flowing pressure of 3250 psia which can be attributed to the relatively high mobility of the free water phase in the hydrate-bearing reservoir. Good quality formation pressure and near well bore mobility data was acquired that yielded a “high confidence” reservoir effective radial permeability-thickness product of 0.2 mD.m (or a horizontal effective permeability of 0.1 mD assuming a reservoir thicknees of 1.8 m) using pressure transient analysis (radial flow regime was achieved) despite unstable borehole conditions and complex operations in these shallow unconsolidated sedimentary sections.

Journal of Marine and Petroleum Geology↗

A prelanding assessment of the ice table depth and ground ice characteristics in Martian permafrost at the Phoenix landing site

We review multiple estimates of the ice table depth at potential Phoenix landing sites and consider the possible state and distribution of subsurface ice. A two-layer model of ice-rich material overlain by ice-free material is consistent with both the observational and theoretical lines of evidence. Results indicate ground ice to be shallow and ubiquitous, 2-6 cm below the surface. Undulations in the ice table depth are expected because of the thermodynamic effects of rocks, slopes, and soil variations on the scale of the Phoenix Lander and within the digging area, which can be advantageous for analysis of both dry surficial soils and buried ice-rich materials. The ground ice at the ice table to be sampled by the Phoenix Lander is expected to be geologically young because of recent climate oscillations. However, estimates of the ratio of soil to ice in the ice-rich subsurface layer suggest that that the ice content exceeds the available pore space, which is difficult to reconcile with existing ground ice stability and dynamics models. These high concentrations of ice may be the result of either the burial of surface snow during times of higher obliquity, initially high-porosity soils, or the migration of water along thin films. Measurement of the D/H ratio within the ice at the ice table and of the soil-to-ice ratio, as well as imaging ice-soil textures, will help determine if the ice is indeed young and if the models of the effects of climate change on the ground ice are reasonable.

Journal of Geophysical Research E: Planets↗

Setting an effective TMDL: Sediment loading and effects of suspended sediment on fish

The Agricultural Drainage and Pesticide Transport model was used to examine the relationship between fish and suspended sediment in the context of a proposed total maximum daily load ( TMDL ) in two agricultural watersheds in Minnesota. During a 50-year simulation, Wells Creek, a third-order cold water stream, had an estimated 1,164 events (i.e., one or more consecutive days of estimated sediment loading ) and the Chippewa River, a fourth-order warm water stream, had 906 events of measurable suspended sediment . Sublethal thresholds were exceeded for 970 events and lethal levels for 194 events for brown trout in Wells Creek, whereas adult nonsalmonidis would have experienced sublethal levels for 923 events and lethal levels for 241 events. Sublethal levels were exceeded for 756 events and lethal thresholds were exceeded for 150 events in the Chippewa River. Nonsalmonids would have experienced 15 events of mortality between 0 and 20 percent in Wells Creek. In the Chippewa River, there were 35 events of mortality between 0 and 20 percent and one event in which mortality could have exceeded 20 percent. The Minnesota Pollution Control Agency has proposed listing stream reaches as being impaired for turbidity at 25 NTU, which is approximately 46 mg suspended sediment /l. We estimated that 46 mg/l would be exceeded approximately 30 days in a year (d/yr) in both systems. A TMDL of 46 mg SS/l may be too high to ensure that stream fishes are not negatively affected by suspended sediment . We recommend that an indicator incorporating the duration of exposure be applied.

Journal of the American Water Resources Associatio↗

Determination of subsurface fluid contents at a crude-oil spill site

Measurement of the fluid-content distribution at sites contaminated by immiscible fluids, including crude oil, is needed to better understand the movement of these fluids in the subsurface and to provide data to calibrate and verify numerical models and geophysical methods. A laboratory method was used to quantify the fluid contents of 146 core sections retrieved from boreholes aligned along a 120-m longitudinal transect at a crude-oil spill site near Bemidji, Minnesota, U.S.A. The 47-mm-diameter, minimally disturbed cores spanned a 4-m vertical interval contaminated by oil. Cores were frozen on site in a dry ice-alcohol bath to prevent redistribution and loss of fluids while sectioning the cores. We gravimetrically determined oil and water contents using a two-step method: (1) samples were slurried and the oil was removed by absorption onto strips of hydrophobic porous polyethylene (PPE); and (2) the samples were oven-dried to remove the water. The resulting data show sharp vertical gradients in the water and oil contents and a clearly defined oil body. The subsurface distribution is complex and appears to be influenced by sediment heterogeneities and water-table fluctuations. The center of the oil body has depressed the water-saturated zone boundary, and the oil is migrating laterally within the capillary fringe. The oil contents are as high as 0.3cm 3 cm −3 , which indicates that oil is probably still mobile 10 years after the spill occurred. The thickness of oil measured in wells suggests that accumulated thickness in wells is a poor indicator of the actual distribution of oil in the subsurface. Several possible sources of error are identified with the field and laboratory methods. An error analysis indicates that adsorption of water and sediment into the PPE adds as much as 4% to the measured oil masses and that uncertainties in the calculated sample volume and the assumed oil density introduce an additional ±3% error when the masses are converted to fluid contents.

Journal of Contaminant Hydrology↗

Soil disturbance as a driver of increased stream salinity in a semiarid watershed undergoing energy development

Salinization is a global threat to the quality of streams and rivers, but it can have many causes. Oil and gas development were investigated as one of several potential causes of changes in the salinity of Muddy Creek, which drains 2470 km2 of mostly public land in Wyoming, U.S.A. Stream discharge and salinity vary with seasonal snowmelt and define a primary salinity-discharge relationship. Salinity, measured by specific conductance, increased substantially in 2009 and was 53-71% higher at low discharge and 33-34% higher at high discharge for the years 2009-2012 compared to 2005-2008. Short-term processes (e.g., flushing of efflorescent salts) cause within-year deviations from the primary relation but do not obscure the overall increase in salinity. Dissolved elements associated with increased salinity include calcium, magnesium, and sulfate, a composition that points to native soil salts derived from marine shales as a likely source. Potential causes of the salinity increase were evaluated for consistency by using measured patterns in stream chemistry, slope of the salinity-discharge relationship, and inter-annual timing of the salinity increase. Potential causes that were inconsistent with one or more of those criteria included effects from precipitation, evapotranspiration, reservoirs, grazing, irrigation return flow, groundwater discharge, discharge of energy co-produced waters, and stream habitat restoration. In contrast, surface disturbance of naturally salt-rich soil by oil and gas development activities, such as pipeline, road, and well pad construction, is a reasonable candidate for explaining the salinity increase. As development continues to expand in semiarid lands worldwide, the potential for soil disturbance to increase stream salinity should be considered, particularly where soils host substantial quantities of native salts.

Journal of Hydrology: Regional Studies↗

Comparative assessment of groundwater quality in the Tangshan region of the People's Republic of China and similar areas in the U.S.

Groundwater quality with respect to nitrate, major inorganic constituents, stable isotopes, and tritium was assessed in the agricultural Tangshan region in the Hai He River Basin of the People's Republic of China and compared with three regions in the U.S.: the Delmarva Peninsula of Delaware, Maryland, and Virginia; the San Joaquin Valley of California; and the Sacramento Valley of California. The China and U.S. regions are similar in size and land use, but have different climatic conditions and patterns of water use for irrigation. The Tangshan region has been in agricultural production for a much longer time, probably several centuries, than the three U.S. regions; however, the widespread use of synthetic fertilizers and other soil amendments probably started at a similar time in all four regions. In all four regions, median nitrate concentrations were generally below the U.S. drinking water standard of 10 mg/l of nitrate as nitrogen. However, higher concentrations and a greater range were evident for the Tangshan region. In the water samples collected from a shallow aquifer in the Tangshan region (over 25% of all samples), nitrate concentrations exceeded the Chinese standard of 20 mg/l, whereas few comparative samples (2.6%) collected in the U.S. exceeded 20 mg/l. In Tangshan, relatively low nitrate, which is indicative of uncontaminated background concentrations, was measured in older water of deeper wells. Recently recharged water was detected in wells drilled as deep as 150 m. Nitrate concentrations above background levels were also measured in water samples from these wells. In addition to nitrate, the agricultural area of the Tangshan region has been affected by elevated total dissolved solids and iron, the latter attributed to widespread application of animal wastes and sewage deposited on the land surface, which lead to oxygen depletion in the subsurface environment and dissolution of iron. The elevated total dissolved solids of the Tangshan study area could not be attributed to any one process.

Scientific World Journal↗

Mapping habitat suitability rangewide for headwater stream-associated torrent salamanders

In the moist, coniferous forests of Oregon and Washington, a dense network of headwater streams supports high levels of amphibian species endemism and diversity, including the torrent salamanders ( Rhyacotriton spp.). The Columbia and Cascade torrent salamanders ( R. kezeri and R. cascadae , respectively) are species of greatest conservation need, but current information is insufficient for an adequate status assessment. We aimed to determine the current distributional extent, occurrence, and abundance of both species across their respective ranges, and to characterize watershed-scale habitat suitability. We conducted rangewide surveys for both species and used a novel, robust model development and refinement process to characterize habitat suitability based on climatic, topographic, forest-structure, hydrological, and water-balance drivers of their distributions. Results supported interspecific differences in rangewide occurrence and abundance patterns, as well as ecological associations that provide insights into potentially divergent patterns of resilience. Topographic, water-balance, and streamflow metrics were top predictors of Columbia torrent occurrences, whereas metrics of seasonal temperature and atmospheric moisture were top predictors of Cascade torrent occurrences. Our findings can inform regional conservation planning efforts to identify likely climate refugia and habitat-connectivity pathways for gene flow and watershed-scale ecological resilience.

Oregon, Washington↗

Rhodamine-WT dye losses in a mountain stream environment

A significant fraction of rhodamine WT dye was lost during a short term multitracer injection experiment in a mountain stream environment. The conservative anion chloride and the sorbing cation lithium were concurrently injected. In-stream rhodamine WT concentrations were as low as 45 percent of that expected, based on chloride data. Concentration data were available from shallow‘wells’dug near the stream course and from a seep of suspected return flow. Both rhodamine WT dye and lithium were nonconservative with respect to the conservative chloride, with rhodamine WT dye closely following the behavior of the sorbing lithium. Nonsorption and sorption mechanisms for rhodamine WT loss in a mountain stream were evaluated in laboratory experiments. Experiments evaluating nonsorption losses indicated minimal losses by such mechanisms. Laboratory experiments using sand and gravel size streambed sediments show an appreciable capacity for rhodamine WT sorption. The detection of tracers in the shallow wells and seep indicates interaction between the stream and the flow in the surrounding subsurface, intergravel water, system. The injected tracers had ample opportunity for intimate contact with materials shown in the laboratory experiments to be potentially sorptive. It is suggested that in the study stream system, interaction with streambed gravel was a significant mechanism for the attenuation of rhodamine WT dye (relative to chloride).

Journal of the American Water Resources Associatio↗

Instruments and methods acoustic televiewer logging in glacier boreholes

The acoustic televiewer is a geophysical logging instrument that is deployed in a water-filled borehole and operated while trolling. It generates a digital, magnetically oriented image of the borehole wall that is developed from the amplitudes and transit times of acoustic waves emitted from the tool and reflected at the water-wall interface. The transit-time data are also converted to radial distances, from which cross-sectional views of the borehole shape can be constructed. Because the televiewer is equipped with both a three-component magnetometer and a two-component inclinometer, the borehole's trajectory in space is continuously recorded as well. This instrument is routinely used in mining and hydrogeologic applications, but in this investigation it was deployed in two boreholes drilled into Upper Fremont Glacier, Wyoming, U.S.A. The acoustic images recorded in this glacial setting are not as clear as those typically obtained in rocks, due to a lower reflection coefficient for water and ice than for water and rock. Results indicate that the depth and orientation of features intersecting the boreholes can be determined, but that interpreting their physical nature is problematic and requires corroborating information from inspection of cores. Nevertheless, these data can provide some insight into englacial structural characteristics. Additional information derived from the cross-sectional geometry of the borehole, as well as from its trajectory, may also be useful in studies concerned with stress patterns and deformation processes.

Journal of Glaciology↗

Shallow groundwater and soil chemistry response to 3 years of subsurface drip irrigation using coalbed-methane-produced water

Disposal of produced waters, pumped to the surface as part of coalbed methane (CBM) development, is a significant environmental issue in the Wyoming portion of the Powder River Basin, USA. High sodium adsorption ratios (SAR) of the waters could degrade agricultural land, especially if directly applied to the soil surface. One method of disposing of CBM water, while deriving beneficial use, is subsurface drip irrigation (SDI), where acidified CBM waters are applied to alfalfa fields year-round via tubing buried 0.92 m deep. Effects of the method were studied on an alluvial terrace with a relatively shallow depth to water table (∼3 m). Excess irrigation water caused the water table to rise, even temporarily reaching the depth of drip tubing. The rise corresponded to increased salinity in some monitoring wells. Three factors appeared to drive increased groundwater salinity: (1) CBM solutes, concentrated by evapotranspiration; (2) gypsum dissolution, apparently enhanced by cation exchange; and (3) dissolution of native Na–Mg–SO 4 salts more soluble than gypsum. Irrigation with high SAR (∼24) water has increased soil saturated paste SAR up to 15 near the drip tubing. Importantly though, little change in SAR has occurred at the surface.

Wyoming↗

Methods to quality assure, plot, summarize, interpolate, and extend groundwater-level information—Examples for the Mississippi River Valley alluvial aquifer

Large-scale computational investigations of groundwater levels are proposed to accelerate science delivery through a workflow spanning database assembly, statistics, and information synthesis and packaging. A water-availability study of the Mississippi River alluvial plain, and particularly the Mississippi River Valley alluvial aquifer (MRVA), is ongoing. Software (visGWDBmrva) has been released as part of the study that demonstrates groundwater informatics for the aquifer. Considerable water-level data collected by multiple agencies over a seven-state area exist (18,903 wells; 287,272 measurements [April 22, 2019]). Data and metadata quality assurance methods, basic statistics, hydrograph visualization, outlier identification, hypothesis testing, and time-series modeling are described. Two approaches (generalized additive models [GAMs] and support vector machines [SVMs]) are used for data interpolation and extension to monthly water-level estimates. Numerical congruence between GAM and SVM estimates will be useful to limit inclusion of monthly estimates from subsequent science activities.

Mississippi River valley↗

Experimental studies in stream-aquifer interaction along the Arkansas River in Central Kansas - Field testing and analysis

During the last several years, streamflows of a number of Kansas streams have been reduced as a result of groundwater declines. In order to better understand and quantify stream-aquifer interrelationships, an eight-day comprehensive stream-aquifer pumping test, followed by recovery monitoring, was conducted along the Arkansas River near Great Bend, Kansas. In addition to water level monitoring in numerous observation wells, streamflow data, streambed hydraulic gradients, neutron probe-based water content of dewatered sediments, water chemistry and other data were collected. The alluvial aquifer is shown to be highly transmissive ( T = 1803 m 2 d −1 ) with the pumping stress (9538 m 3 d −1 ) having a radius of influence larger than 1.77 km, impacting both the aquifer levels and the streamflow in the nearby Arkansas River. Drawdown and recharge boundary effects were observed in all observation wells, including those on the opposite side of the river. The alluvial aquifer did not exhibit a water table behavior and responded as a leaky confined aquifer. A semiconfining clay layer less than 3 m thick and an additional recharge source from a nearby stream-alluvial system were the probable causes of the observed phenomena. Actual streamflow depletion is shown to be appreciably less than the computed depletion based on analytical solutions.

Kansas↗

Estimating formation properties from early-time oscillatory water levels in a pumped well

Hydrologists often attempt to estimate formation properties from aquifer tests for which only the hydraulic responses in a pumped well are available. Borehole storage, turbulent head losses, and borehole skin, however, can mask the hydraulic behavior of the formation inferred from the water level in the pumped well. Also, in highly permeable formations or in formations at significant depth below land surface, where there is a long column of water in the well casing, oscillatory water levels may arise during the onset of pumping to further mask formation responses in the pumped well. Usually borehole phenomena are confined to the early stages of pumping or recovery, and late-time hydraulic data can be used to estimate formation properties. In many instances, however, early-time hydraulic data provide valuable information about the formation, especially if there are interferences in the late-time data. A mathematical model and its Laplace transform solution that account for inertial influences and turbulent head losses during pumping is developed for the coupled response between the pumped borehole and the formation. The formation is assumed to be homogeneous, isotropic, of infinite areal extent, and uniform thickness, with leakage from an overlying aquifer, and the screened or open interval of the pumped well is assumed to fully penetrate the pumped aquifer. Other mathematical models of aquifer flow can also be coupled with the equations describing turbulent head losses and the inertial effects on the water column in the pumped well. The mathematical model developed in this paper is sufficiently general to consider both underdamped conditions for which oscillations arise, and overdamped conditions for which there are no oscillations. Through numerical inversion of the Laplace transform solution, type curves from the mathematical model are developed to estimate formation properties through comparison with the measured hydraulic response in the pumped well. The mathematical model is applied to estimate formation properties from a singlewell test conducted near Waialua, Oahu, Hawaii. At this site, both the drawdown and recovery showed oscillatory water levels in the pumped well, and a step-drawdown test showed that approximately 86% of the drawdown is attributed to turbulent head losses. Analyses at this site using late-time drawdown data were confounded by the noise present in the measured water levels due primarily to nearby irrigation wells and ocean tides. By analyzing the early-time oscillatory recovery data at the Waialua site, upper and lower bounds were placed on the transmissivity, T, storage coefficient, S, and the leakance of the confining unit, K′/B′. The upper and lower bounds on T differ by a factor of 2. Upper and lower bounds on S and K′/B′ are much larger, because drawdown stabilized relatively quickly after the onset of pumping.

Journal of Hydrology↗

Hydrologic landscapes on the Delmarva Peninsula - Part 2: Estimates of base-flow nitrogen load to Chesapeake Bay

ABSTRACT: The relation between landscape characteristics and water chemistry on the Delmarva Peninsula can be determined through a principal-component analysis of basin characteristics. Two basin types were defined by factor scores: (1) well-drained basins, characterized by combinations of a low percentage of forest cover, a low percentage of poorly drained soil, and elevated channel slope; and (2) poorly drained basins, characterized by a combinations of an elevated percentage of forest cover, an elevated percentage of poorly drained soil, and low channel slopes. Results from base-flow sampling of 29 basins during spring 1991 indicate that water chemistry of the two basin types differ significantly. Concentrations of calcium, magnesium, potassium, alkalinity, chloride, and nitrate are elevated in well-drained basins, and specific conductance is elevated. Concentrations of aluminum, dissolved organic carbon, sodium, and silica are elevated in poorly drained basins whereas specific conductance is low. The chemical patterns found in well-drained basins can be attributed to the application of agricultural chemicals, and those in poorly drained basins can be attributed to ground-water flowpaths. These results indicate that basin types determined by a quantitative analysis of basin characteristics can be related statistically to differences in base-flow chemistry, and that the observed statistical differences can be related to major processes that affect water chemistry.

Journal of the American Water Resources Associatio↗