SEARCH · Geology Reports

Results for “Polar Research”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 289 records · Page 16Linked to original sources

USGS2014

Temporal and spatial distributions of cold-water corals in the Drake Passage: insights from the last 35,000 years

Scleractinian corals have a global distribution ranging from shallow tropical seas to the depths of the Southern Ocean. Although this distribution is indicative of the corals having a tolerance to a wide spectrum of environmental conditions, individual species seem to be restricted to a much narrower range of ecosystem variables. One way to ascertain the tolerances of corals, with particular focus on the potential impacts of changing climate, is to reconstruct their growth history across a range of environmental regimes. This study examines the spatial and temporal distribution of the solitary scleractinian corals Desmophyllum dianthus, Gardineria antarctica, Balanophyllia malouinensis, Caryophyllia spp. and Flabellum spp. from five sites in the Drake Passage which cross the major frontal zones. A rapid reconnaissance radiocarbon method was used to date more than 850 individual corals. Coupled with U-Th dating, an age range of present day back to more than 100 thousand years was established for corals in the region. Within this age range there are distinct changes in the temporal and spatial distributions of these corals, both with depth and latitude, and on millennial timescales. Two major patterns that emerge are: (1) D. dianthus populations show clear variability in their occurrence through time depending on the latitudinal position within the Drake Passage. North of the Subantarctic Front, D. dianthus first appears in the late deglaciation (~17,000 years ago) and persists to today. South of the Polar Front, in contrast, early deglacial periods, with a few modern occurrences. A seamount site between the two fronts exhibits characteristics similar to both the northern and southern sites. This shift across the frontal zones within one species cannot yet be fully explained, but it is likely to be linked to changes in surface productivity, subsurface oxygen concentrations, and carbonate saturation state. (2) at locations where multiple genera were dated, differences in age and depth distribution of the populations provide clear evidence that each genus has unique environmental requirements to sustain its population.

Deep-Sea Research Part II: Topical Studies in Ocea↗

USGS2009

Compact Reconnaissance Imaging Spectrometer for Mars investigation and data set from the Mars Reconnaissance Orbiter's primary science phase

The part of the Compact Reconnaissance Imaging Spectrometer (CRISM) for Mars investigation conducted during the Mars Reconnaissance Orbiter's (MRO's) primary science phase was a comprehensive investigation of past aqueous environments, structure of the planet's crust, past climate, and current meteorology. The measurements to implement this investigation include over 9500 targeted observations of surface features taken at spatial resolutions of better than 40 m/pixel, monitoring of seasonal variations in atmospheric aerosols and trace gases, and acquisition of a 200 m/pixel map covering over 55% of Mars in 72 selected wavelengths under conditions of relatively low atmospheric opacity. Key results from these data include recognition of a diversity of aqueous mineral-containing deposits, discovery of a widespread distribution of phyllosilicates in early to middle Noachian units, the first definitive detection of carbonates in bedrock, new constraints on the sequence of events that formed Hesperian-aged, sulfate-rich layered deposits, characterization of seasonal polar processes, and monitoring of the 2007 global dust event. Here we describe CRISM's science investigations during the Primary Science Phase, the data sets that were collected and their calibration and uncertainties, and how they have been processed and made available to the scientific community. We also describe the ongoing investigation during MRO's extended science phase. Copyright 2009 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗

USGS1998

Paleomagnetism, paleogeographic origins, and uplift history of the Coast Range ophiolite at Mount Diablo, California

Divergent paleogeographic origins have been proposed for the Coast Range ophiolite of western California which are testable using paleomagnetic methods. Paleomagnetic data for Middle Jurassic pillow lavas and diabase sills of the Coast Range ophiolite at Mount Diablo, northern California, indicate that they contain two components of remanent magnetization. The characteristic directions have normal and reversed polarities and apparently are carried by Ti-poor magnetite. This magnetization is inferred to have been acquired during emplacement and seafloor alteration at an ancient spreading ridge. The paleolatitude calculated from its structurally corrected mean direction is 20°N ± 9° and agrees with the expected direction for stable North America; this result is also consistent with the concordant paleolatitude (32°N ± 8°) recently determined for Upper Jurassic Coast Range ophiolite at Stanley Mountain in southern California. In addition, clockwise vertical axis rotation of Mount Diablo (143° ± 11°) is indicated by the characteristic magnetization direction. An overprint component is inferred to have been acquired during uplift of Mount Diablo since the Miocene.

Journal of Geophysical Research B: Solid Earth↗

USGS2008

Hydrocarbon lakes on Titan: Distribution and interaction with a porous regolith

Synthetic Aperture Radar (SAR) images of Titan's north polar region reveal quasi‐circular to complex features which are interpreted to be liquid hydrocarbon lakes. We investigate methane transport in Titan's hydrologic cycle using the global distribution of lake features. As of May 2007, the SAR data set covers ∼22% of the surface and indicates multiple lake morphologies which are correlated across the polar region. Lakes are limited to latitudes above 55°N and vary from <10 to more than 100,000 km 2 . The size and location of lakes provide constraints on parameters associated with subsurface transport. Using porous media properties inferred from Huygens probe observations, timescales for flow into and out of observed lakes are shown to be in the tens of years, similar to seasonal cycles. Derived timescales are compared to the time between collocated SAR observations in order to consider the role of subsurface transport in Titan's hydrologic cycle.

Geophysical Research Letters↗

USGS1998

Paleomagnetism of the Miocene intrusive suite of Kidd Creek: Timing of deformation in the Cascade arc, southern Washington

Paleomagnetic study of the intrusive suite of Kidd Creek in the southern Washington Cascades (23 sites in dikes and sills) was undertaken to help determine if these rocks are comagmatic and whether they postdate regional folding of the volcanic arc. Fission track and 40 Ar- 39 Ar age determinations indicate an age of ∼12.7 Ma (middle Miocene) for these rocks. The similarity of normal-polarity characteristic directions for most samples corroborate the available geochemical data indicating that these rocks are most likely comagmatic. Reversed-polarity directions for samples from four sites, however, show that emplacement of Kidd Creek intrusions spanned at least one reversal of the geomagnetic field. The paleomagnetic directions for the dikes and sills fail a fold test at the 99% confidence level indicating that the Kidd Creek rocks postdate regional folding. The mean in situ direction also indicates that the Kidd Creek and older rocks have been rotated 22°±6° clockwise about a vertical or near-vertical axis from the expected Miocene direction. Compression and regional folding of the Cascade arc in southern Washington therefore had ended by ∼12 Ma prior to the onset of deformation resulting in rotation of these rocks.

Journal of Geophysical Research B: Solid Earth↗

USGS2016

PhasePApy: A robust pure Python package for automatic identification of seismic phases

We developed a Python phase identification package: the PhasePApy for earthquake data processing and near‐real‐time monitoring. The package takes advantage of the growing number of Python libraries including Obspy. All the data formats supported by Obspy can be supported within the PhasePApy. The PhasePApy has two subpackages: the PhasePicker and the Associator, aiming to identify phase arrival onsets and associate them to phase types, respectively. The PhasePicker and the Associator can work jointly or separately. Three autopickers are implemented in the PhasePicker subpackage: the frequency‐band picker, the Akaike information criteria function derivative picker, and the kurtosis picker. All three autopickers identify picks with the same processing methods but different characteristic functions. The PhasePicker triggers the pick with a dynamic threshold and can declare a pick with false‐pick filtering. Also, the PhasePicker identifies a pick polarity and uncertainty for further seismological analysis, such as focal mechanism determination. Two associators are included in the Associator subpackage: the 1D Associator and 3D Associator, which assign phase types to picks that can best fit potential earthquakes by minimizing root mean square (rms) residuals of the misfits in distance and time, respectively. The Associator processes multiple picks from all channels at a seismic station and aggregates them to increase computational efficiencies. Both associators use travel‐time look up tables to determine the best estimation of the earthquake location and evaluate the phase type for picks. The PhasePApy package has been used extensively for local and regional earthquakes and can work for active source experiments as well.

Seismological Research Letters↗

USGS1996

Non-double-couple earthquake mechanisms at the Geysers geothermal area, California

Inverting P- and S-wave polarities and P:SH amplitude ratios using linear programming methods suggests that about 20% of earthquakes at The Geysers geothermal area have significantly non-double-couple focal mechanisms, with explosive volumetric components as large as 33% of the seismic moment. This conclusion contrasts with those of earlier studies, which interpreted data in terms of double couples. The non-double-couple mechanisms are consistent with combined shear and tensile faulting, possibly caused by industrial water injection. Implosive mechanisms, which might be expected because of rapid steam withdrawal, have not been found. Significant compensated-linear-vector-dipole (CLVD) components in some mechanisms may indicate rapid fluid flow accompanying crack opening. Copyright 1996 by the American Geophysical Union.

California↗

USGS2012

Infrared spectra and crystal chemistry of scapolites: implications for Martian mineralogy

Near‐infrared and midinfrared spectra of a wide range of scapolite compositions were studied to determine the cause of the 2.36‐μm features that have been correlated with similar features in the near‐IR spectrum of Mars. We attribute the 2.36−μm features to vibrations caused by HCO 3 − and HSO 4 − in the anion sites of scapolite. The 2.36‐μm absorption complex consists of four overlapping bands with the following assignments: absorptions at 2.33 and 2.35 μm are attributed to combinations of hydroxyl stretches and a O‐H … O bend from HCO 3 − , absorptions at 2.39 and 2.41 μm are attributed to combinations of hydroxyl stretches and a O‐H ··· O bend from HSO 4 − . The relative intensities of all four bands vary according to the HCO 3 − /HSO 4 − ratio and disordered anion site occupancy. Oriented single‐crystal polarized spectra of a bicarbonate‐bisulfate bearing scapolite show that the 3.9‐μm hydrogen bond stretch, from HCO 3 − , is polarization controlled. This verifies that HCO 3 − is an intimate part of the scapolite crystal structure and that hydrogen in HCO 3 − is forming hydrogen bonds with T 1 framework oxygens. The association of yellow fluorescence, attributed to S 2 − in the anion site, with vibrational features of HCO 3 − and HSO 4 − in the rims and fractures of scapolite grains suggests that some common geochemical process is incorporating these ions into the crystal structure during later stage alteration of scapolite. The positional disorder of HCO 3 − and HSO 4 − in the low‐symmetry anion site of scapolite gives the 2.36‐μm band complex a unique spectral signature not likely to be duplicated in any other mineral.

Journal of Geophysical Research↗

USGS2012

Paleomagnetic investigation of some volcanic rocks from the McMurdo volcanic province, Antarctica

Paleomagnetic data for lava flows from sporadic but long-lived eruptions in the McMurdo Sound region are combined with previously published geologic and geochronologic data to determine the general eruptive sequence of the area. Lava flows in the Walcott Bay area were erupted during the Gauss Normal, Matuyama Reversed, and Brunhes Normal Polarity Chrons. The youngest flows on Black Island probably erupted near the boundary between the Gilbert and Gauss chrons. The most recent activity was concentrated on the volcanic edifices of Mounts Morning and Discovery and on Ross Island where Mount Erebus is currently active. Combining virtual geomagnetic poles calculated for 39 units sampled during this study with those of eight flows that were published previously yields a mean paleomagnetic pole at 87.3°N, 317.3°E (α 95 = 6.3°). The ancient geomagnetic field dispersion about this mean pole is 23.5°, with upper and lower limits of 95% confidence equal to 27.4° and 20.5°, respectively. This value probably is a reasonable estimate of secular variation for the Antarctic continent during Pliocene and Pleistocene time.

Journal of Geophysical Research Solid Earth↗

USGS2012

Paleomagnetic constraints on rotation within Mount Abbot quadrangle, central Sierra Nevada, California

The regional photolineament pattern in Mount Abbot quadrangle in the central Sierra Nevada is sigmoidal in plan view. The fractures in the southwest section of the quadrangle, near Florence Lake, strike N10°–20°E, while those in the central section, along Bear Creek, strike N50°–70°E and those in the northeast strike N25°–40°E. A paleomagnetic investigation was undertaken to determine if this sigmoidal pattern was formed by kinking of originally straight photolineaments after the rock mass cooled below the blocking temperature. If the inner limb of the kink rotated 40°–60° clockwise with respect to the outer limbs, then there should be a similar difference in the paleomagnetic declinations between the Florence Lake and Bear Creek areas. The paleomagnetic results indicate a clockwise difference in declination of 13.4°±7° of the Bear Creek area with respect to Florence Lake. Thus the sigmoidal pattern could not have formed entirely by rotation after cooling below the blocking temperature. It is also possible that the observed declination discrepancy is due to tilting, apparent polar wander, or paleomagnetic dispersion instead of rotation. Sigmoidal patterns, formed by kink folding, occur on the outcrop scale with inner limb rotations of 15°–30°; three of these kinks were sampled to test the paleomagnetic method in an area of demonstrable rotation. The data from these sites indicate that although no difference in declination is evident, a reheating event may have occurred which could have removed any rotation from the paleomagnetic record. Reheating, possibly due to the circulation of hydrothermal fluids, may have been causally related to the outcrop scale kinking, since reheating is not observed away from the outcrop scale kinks. The data further indicate that there may have been continuous deformation of the rock mass during the formation of the kinks.

Journal of Geophysical Research B: Solid Earth↗

USGS2021

Wastewater disposal has not significantly altered the regional stress state in southern Kansas

Wastewater disposal is primarily responsible for the increased seismicity rate since ~2013 in southern Kansas. Previous work that used shear wave splitting (SWS) in southern Kansas interpreted a ~90º temporal rotation in the fast polarization direction and attributed it to increased pore pressures resulting from fluid injection. However, this interpreted rotation coincided with a change in the stations used to make the SWS measurements. We investigate the temporal variability of fast azimuths in southern Kansas by making SWS measurements on earthquake families with similar source-receiver paths recorded on a stable local seismic network. We select high-quality SWS measurements by investigating the stability of results across 65 different frequency bands between 0.5-15 Hz. We find that the fast polarization direction in southern Kansas is relatively constant with an average ENE (~N79ºE) orientation between 2014-2017. Our fast polarization measurements are primarily a reflection of the maximum principal horizontal stress direction (SHmax). We observe a slight spatial change in SHmax to the NE (~N55°E) near the Nemaha Ridge in Oklahoma. However, we do not observe any significant temporal rotation of SHmax or variation in delay time (i.e., crack density) in southern Kansas, contrary to the earlier study. The previously interpreted ~90º rotation may either be a reflection of a very local stress change or a misinterpretation of SWS results potentially due to the use of inconsistent source-receiver paths. Our SWS measurements cover the period of peak wastewater disposal and seismicity rates and suggest an absence of significant temporal rotations in the local anisotropy and stress orientations associated with wastewater disposal.

Kansas↗

USGS2012

Precise U‐Pb ages of Duluth Complex and related mafic intrusions, northeastern Minnesota: Geochronological insights to physical, petrogenetic, paleomagnetic, and tectonomagmatic processes associated with the 1.1 Ga Midcontinent Rift System

Precise resolution of the timing of igneous activity is crucial to understanding the dynamic processes associated with continental rifting. Mafic intrusive rocks constitute a major portion of the exposed 1100 Ma (Keweenawan) Midcontinent Rift system in northeastern Minnesota; however, prior to this study, geochronological data were insufficient to allow rigorous interpretation of intrusive histories and their relationships to extrusive suites. Eight anorthositic and gabbroic intrusives were chosen to represent both the temporal and spatial ranges of plutonic activity that formed the Duluth Complex and related mafic intrusions. U‐Pb isotopic analyses from zircons and baddeleyites result in U‐Pb concordant ages with little or no ambiguity introduced by inherited components, Pb loss or common Pb. The earliest Keweenawan plutonism exposed in Minnesota occurs along the northeastern flank of the Duluth Complex as a series of layered gabbros (Nathan's layered series) emplaced at 1106.9 ± 0.6 Ma. This sequence of gabbro sheets shares temporal, spatial, and compositional similarities with the nearby Logan sills in Ontario. Four Duluth Complex anorthositic and troctolitic series samples from widely separated areas have unresolvable ages between 1099.3 ± 0.3 and 1098.6 ± 0.5 Ma, indicating a very short duration for peak intrusive activity (0.5–1 m.y.). The unresolvable ages between anorthositic and troctolitic plutons suggest that these two magma series are more closely related than previously modeled and argue strongly for the need to reexamine their fundamental petrogenetic relationships. These dates also imply that the major reverse‐to‐normal magnetic polarity switch, used throughout the rift system as an important correlation tool, occurred prior to 1099 Ma. This date is several million years earlier than previously suspected and emphasizes the need for further paleomagnetic and geochronological data from the overlying volcanics. Much of the hypabyssal intrusive suite within the volcanic pile overlying Duluth Complex plutons may be significantly younger than the main pulse of plutonic activity. Two hypabyssal bodies, the Sonju Lake intrusion and gabbro at Silver Bay, were emplaced at 1096.1 ± 0.8 Ma and 1095.8 ± 1.2 Ma, respectively. Dates reported here and in previous studies support the concept of episodic tectonomagmatic rift development where magmatism was apparently concentrated in episodes of short duration (<1–3 m.y.) interspersed with longer hiatuses (2–8 m.y.).

Michigan, Minnesota, Ontario, Wisconsin↗

USGS2011

Cold-water coral distributions in the Drake Passage area from towed camera observations - Initial interpretations

Seamounts are unique deep-sea features that create habitats thought to have high levels of endemic fauna, productive fisheries and benthic communities vulnerable to anthropogenic impacts. Many seamounts are isolated features, occurring in the high seas, where access is limited and thus biological data scarce. There are numerous seamounts within the Drake Passage (Southern Ocean), yet high winds, frequent storms and strong currents make seafloor sampling particularly difficult. As a result, few attempts to collect biological data have been made, leading to a paucity of information on benthic habitats or fauna in this area, particularly those on primarily hard-bottom seamounts and ridges. During a research cruise in 2008 six locations were examined (two on the Antarctic margin, one on the Shackleton Fracture Zone, and three on seamounts within the Drake Passage), using a towed camera with onboard instruments to measure conductivity, temperature, depth and turbidity. Dominant fauna and bottom type were categorized from 200 randomized photos from each location. Cold-water corals were present in high numbers in habitats both on the Antarctic margin and on the current swept seamounts of the Drake Passage, though the diversity of orders varied. Though the Scleractinia (hard corals) were abundant on the sedimented margin, they were poorly represented in the primarily hard-bottom areas of the central Drake Passage. The two seamount sites and the Shackleton Fracture Zone showed high numbers of stylasterid (lace) and alcyonacean (soft) corals, as well as large numbers of sponges. Though data are preliminary, the geological and environmental variability (particularly in temperature) between sample sites may be influencing cold-water coral biogeography in this region. Each area observed also showed little similarity in faunal diversity with other sites examined for this study within all phyla counted. This manuscript highlights how little is understood of these isolated features, particularly in Polar regions.

PLoS ONE↗

USGS1998

Estimation of Mars radar backscatter from measured surface rock populations

Reanalysis of rock population data at the Mars Viking Lander sites has yielded updated values of rock fractional surface coverage (about 0.16 at both sites, including outcrops) and new estimates of rock burial depths and axial ratios. These data are combined with a finite difference time domain (FDTD) numerical scattering model to estimate diffuse backscatter due to rocks at both the Lander 1 (VL1) and Lander 2 (VL2) sites. We consider single scattering from both surface and subsurface objects of various shapes, ranging from an ideal sphere to an accurate digitized model of a terrestrial rock. The FDTD cross-section calculations explicitly account for the size, shape, composition, orientation, and burial state of the scattering object, the incident wave angle and polarization, and the composition of the surface. We calculate depolarized specific cross sections at 12.6 cm wavelength due to lossless rock-like scatterers of about 0.014 at VL1 and 0.023 at VL2, which are comparable to the measured ranges of 0.019–0.032 and 0.012–0.018, respectively. We also discuss the variation of the diffuse cross section as the local angle of incidence, θ i , changes. Numerical calculations for a limited set of rock shapes indicate a marked difference between the angular backscattering behavior of wavelength-scale surface and subsurface rocks: while subsurface rocks scatter approximately as a cosine power law, surface rocks display a complex variation, often with peak backscattering at high incidence angles (θ i = 70°–75°).

Journal of Geophysical Research E: Planets↗

USGS2002

Arctic Refuge coastal plain terrestrial wildlife research summaries

In 1980, when the U.S. Congress enacted the Alaska National Interest Lands Conservation Act (ANILCA), it also mandated a study of the coastal plain of the Arctic National Wildlife Refuge. Section 1002 of ANILCA stated that a comprehensive inventory of fish and wildlife resources would be conducted on 1.5 million acres of the Arctic Refuge coastal plain (1002 Area). Potential petroleum reserves in the 1002 Area were also to be evaluated from surface geological studies and seismic exploration surveys. Results of these studies and recommendations for future management of the Arctic Refuge coastal plain were to be prepared in a report to Congress. In 1987, the Department of the Interior published the Arctic National Wildlife Refuge, Alaska, Coastal Plain Resource Assessment - Report and Recommendations to the Congress of the United States and Final Environmental Impact Statement. This report to Congress identified the potential for oil and gas production (updated* most recently by the U.S. Geological Survey in 2001), described the biological resources, and evaluated the potential adverse effects to fish and wildlife resources. The 1987 report analyzed the potential environmental consequences of five management alternatives for the coastal plain, ranging from wilderness designation to opening the entire area to lease for oil and gas developement. The report's summary recommended opening the 1002 Area to an orderly oil and gas leasing program, but cautioned that adverse effects to some wildlife populations were possible. Congress did not act on this recommendation nor any other alternative for the 1002 Area, and scientists continued studies of key wildlife species and habitats on the coastal plain of the Arctic Refuge and surrounding areas. This report contains updated summaries of those scientific investigations of caribou, muskoxen, predators (grizzly bears, wolves, golden eagles), polar bears, snow geese, and their wildlife habitats. Contributions to this report were made by scientists affiliated with the U.S. Geological Survey; U.S. Fish and Wildlife Service; Alaska Department of Fish and Game; University of Alaska-Fairbanks; Canadian Wildlife Service; Yukon Department of Renewable Resources; and the Northwest Territories Department of Resources, Wildlife, and Economic Development. Sections of the report presenting new information on caribou and forage plants were peer-reviewed by three independent, non-affiliated scientists. The remaining sections summarize previously published peer-reviewed scientific papers and were reviewed by a single independent scientist. The U.S. Geological Survey and the U.S. Fish and Wildlife Service collaborated in the publication of this report.

Alaska, Northwest Territories, Yukon Territory↗

USGS1987

The inventory and distribution of water on Mars

Terrain softening, fretted channels, debris flows, and closed depressions indicate that at least the upper 2 km of the cratered uplands at high latitudes (>30??) contain ice in amounts that exceed the porosity, estimated to be 10-20 percent. Theoretical studies, and lack of these features in the cratered uplands at low latitudes, suggest that the upper 1 km of the uplands at low latitudes is ice poor. However, valley networks indicate that water was present near the surface early in the planet's history, although in amounts smaller than at high latitudes. On the basis of these observations, the entire upper 1 km, planet-wide is estimated to have contained 75-125 meters of water at the end of heavy bombardment. From the volume of water needed to cut the circum-Chryse channels, and assuming uniform planet-wide distribution of water, the deep megaregolith is estimated to have contained at least 350 meters of water at the end of heavy bombardment, thereby giving a total minimum inventory of 425-475 meters planet-wide. Most of the water lost from the low latitude uplands by diffusion and in cutting the valley networks is now believed to be in the polar layered terrains. Most of the water involved in cutting the outflow channels is in the low-lying northern plains where a variety of features that have been attributed to ground ice is present. Since the end of heavy bombardment, a large fraction of the planet's surface has been overplated with water-poor volcanics, of which we have samples in the SNC meteorites. The younger volcanics have reacted extensively with the old volatile-rich basement. Part of the 10-20 bars of CO2 and 0.1 to 0.3 bars of N2 outgassed with the water was lost during heavy bombardment by impact erosion of the atmosphere and other processes. The remaining was fixed carbonates and nitrates and folded deep into the megaregolith during heavy bombardment. ?? 1987.

Advances in Space Research↗

USGS2020

Fluorescence spectroscopy of ancient sedimentary organic matter via confocal laser scanning microscopy (CLSM)

Fluorescence spectroscopy via confocal laser scanning microscopy (CLSM) was used to analyze ancient sedimentary organic matter, including Tasmanites microfossils in Devonian shale and Gloecapsomorpha prisca ( G. prisca ) in Ordovician kukersite from North American basins. We examined fluorescence emission as a function of excitation laser wavelength, sample orientation, and with respect to location within individual organic entities and in transects across bedded organic matter. Results from spectral scans of the same field of view in Tasmanites with different laser lines showed progressive red-shift in emission maxima with longer excitation wavelengths. This result indicates steady-state Tasmanites fluorescence emission is an overlapping combination of emission from multiple fluorophore functions. Stokes shift decreased with increasing excitation wavelength, further suggesting the presence of multiple fluorophore functions with different S 1 → S 0 transition energies. This observation also indicates that at longer excitation wavelengths, less absorbed light energy is dissipated via collisional transfer than at shorter excitation wavelengths and may suggest fewer polar functions are preferentially absorbing. Confirming earlier results, emission spectra observed from high fluorescence intensity regions (fold apices) in individual Tasmanites are blue-shifted relative to emission from other locations in the same microfossil. We suggest high intensity emission is from photoselective alignment of polarized excitation with the fluorophore absorption and emission transition moment. The blue shift observed in regions of high intensity emission may be due to relative absence or realignment of polar species, e.g., bridging ether or ester functions, although variations in O abundance could not be confirmed with preliminary time-of-flight secondary ion mass spectrometry (TOF-SIMS) analysis. Tasmanites occurring in consolidated sediments are flattened from original spherical morphology and, in optical microscopy, this burial deformation results in generally parallel extinction (strain-influenced) and positive elongation. The deformation also induces fluorescence anisotropy observed as variations in emission wavelength when individual Tasmanites are measured from their long axis parallel to bedding, whereas this effect is absent in bedding-normal view. Transects from G. prisca -rich source layers into adjacent reservoir layers show decrease in fluorescence intensity and spectral red-shift (increase in full-width half-maximum with increasing red portion of the half-width). These results may suggest an increase in fluorescence quenching across the source-to-reservoir transition zone, consistent with an increase in aromaticity following petroleum expulsion and migration. These observations are supported by increasing reflectance values measured across similar micro-scale transects. Our results highlight the applicability of CLSM as a broad and under-utilized approach for the characterization of sedimentary organic matter and are discussed with perspective toward petroleum processes and thermal indices research.

International Journal of Coal Geology↗

USGS2016

Timing and composition of continental volcanism at Harrat Hutaymah, western Saudi Arabia

Harrat Hutaymah is an alkali basalt volcanic field in north-central Saudi Arabia, at the eastern margin of a large Neogene continental, intraplate magmatic province. Lava flow, tephra and spatter cone compositions in the field include alkali olivine basalts and basanites. These compositions contrast with the predominantly tholeiitic, fissure-fed basalts found along the eastern margin of the Red Sea. The Hutaymah lava flows were erupted through Proterozoic arc-associated plutonic and meta-sedimentary rocks of the Arabian shield, and commonly contain a range of sub-continental lithospheric xenoliths, although the lavas themselves show little indication of crustal contamination. Previous radiometric dating of this volcanic field (a single published K–Ar age; 1.8 Ma) is suspiciously old given the field measurement of normal magnetic polarity only (i.e. Brunhes interval, ≤ 780 Ka). We report new age determinations on 14 lava flows by the 40Ar–39Ar laser step heating method, all younger than ~ 850 Ka, to better constrain the time frame of volcanism, and major, trace and rare earth element compositions to describe the chemical variation of volcanic activity at Harrat Hutaymah. Crystal fractionation was dominated by olivine ± clinopyroxene at a range of upper mantle and crustal pressures. Rapid ascent and eruption of magma is indicated by the array of lower crustal and lithospheric xenoliths observed in lava flows and tephra. Modeling suggests 1–7% melting of an enriched asthenospheric mantle source occurred beneath Harrat Hutaymah under a relatively thick lithospheric cap (60–80 km).

Harrat Hutaymah↗