Fifty years of progress in petrography and petrology, 1876-1926
No abstract available.
Conference Paper↗
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Petrology of fluvial sands from the Amazonian foreland basin, Peru and Bolivia: Discussion
No abstract available.
Amazonian Foreland Basin↗
Vapor saturation and accumulation in magmas of the 1989-1990 eruption of Redoubt Volcano, Alaska
The 1989–1990 eruption of Redoubt Volcano, Alaska, provided an opportunity to compare petrologic estimates of SO 2 and Cl emissions with estimates of SO 2 emissions based on remote sensing data and estimates of Cl emissions based on plume sampling. In this study, we measure the sulfur and chlorine contents of melt inclusions and matrix glasses in the eruption products to determine petrologic estimates of SO 2 and Cl emissions. We compare the results with emission estimates based on COSPEC and TOMS data for SO 2 and data for Cl/SO 2 in plume samples. For the explosive vent clearing period (December 14–22, 1989), the petrologic estimate for SO 2 emission is 21,000 tons, or ~12% of a TOMS estimate of 175,000 tons. For the dome growth period (December 22, 1989 to mid-June 1990), the petrologic estimate for SO 2 emission is 18,000 tons, or ~3% of COSPEC-based estimates of 572,000–680,000 tons. The petrologic estimates give a total SO 2 emission of only 39,000 tons compared to an integrated TOMS/COSPEC emission estimate of ~1,000,000 tons for the whole eruption, including quiescent degassing after mid-June 1990. Petrologic estimates also appear to underestimate Cl emissions, but apparent HCl scavenging in the plume complicates Cl emission comparisons. Several potential sources of ‘excess sulfur’ often invoked to explain petrologic SO 2 deficits are concluded to be unlikely for the 1989–1990 Redoubt eruption — e.g., breakdown of sulfides, breakdown of anhydrite, release of SO 2 from a hydrothermal system, degassing of commingled infusions of basalt in the magma chamber, and syn-eruptive degassing of sulfur from melt present in non-erupted magma. Leakage and/or diffusion of sulfur from melt inclusions do not provide convincing explanations for the petrologic SO 2 deficits either. The main cause of low petrologic estimates for SO 2 is that melt inclusions do not represent the total sulfur content of the Redoubt magmas, which were vapor-saturated magmas carrying most of their sulfur in an accumulated vapor phase. Almost all the sulfur of the SO 2 emissions was present prior to emission as accumulated magmatic vapor at 6–10 km depth in the magma that supplied the eruption; whole-rock normalized concentrations of gaseous excess S in these magmas remained at ~0.2 wt.% throughout the eruption, equivalent to ~0.7 vol.% at depth. Data for CO 2 emissions during the eruption indicate that CO 2 at whole-rock concentrations of ~0.6 wt.% in the erupted magma was a key factor in creating the vapor saturation and accumulation condition making a vapor phase source of excess sulfur possible at depth. When explosive volcanism involves magma with accumulated vapor, melt inclusions do not provide a sufficient basis for predicting SO 2 emissions. Thus, petrologic estimates made for SO 2 emissions during explosive eruptions of the past may be too low and may significantly underestimate impacts on climate and the chemistry of the atmosphere.
Journal of Volcanology and Geothermal Research↗
Depths in a day - A new era of rapid-response Raman-based barometry using fluid inclusions
Rapid-response petrological monitoring is a major advance for volcano observatories, allowing them to build and validate models of plumbing systems that supply eruptions in near-real-time. The depth of magma storage has recently been identified as high-priority information for volcanic observatories, yet this information is not currently obtainable via petrological monitoring methods on timescales relevant to eruption response. Fluid inclusion barometry (using micro-thermometry or Raman spectroscopy) is a well-established petrological method to estimate magma storage depths and has been proposed to have potential as a rapid-response monitoring tool, although this has not been formally demonstrated. To address this deficiency, we performed a near-real-time rapid-response simulation for the September 2023 eruption of Kīlauea, Hawaiʻi. We show that Raman-based fluid inclusion barometry can robustly determine reservoir depths within a day of receiving samples — a transformative timescale that has not previously been achieved by petrological methods. Fluid inclusion barometry using micro-thermometric techniques has typically been limited to systems with relatively deep magma storage (>0.4 g/cm 3 or >7 km) where measurements of CO 2 density are easy and accurate because the CO 2 fluid homogenizes into the liquid phase. Improvements of the accuracy of Raman spectroscopy measurements of fluids with low CO 2 density over the past couple of decades has enabled measurements of fluid inclusions from shallower magmatic systems. However, one caveat of examining shallower systems is that the fraction of H 2 O in the fluid may be too high to reliably convert CO 2 density to pressure. To test the global applicability of rapid response fluid inclusion barometry, we compiled a global melt inclusion dataset (>4000 samples) and calculate the fluid composition at the point of vapor saturation (X H 2 O ). We show that fluid inclusions in crystal-hosts from mafic compositions (<57 wt. % SiO 2 ) — likely representative of magmas recharging many volcanic systems worldwide — trap fluids with X H 2 O low enough to make fluid inclusion barometry useful at many of the world’s most active and hazardous mafic volcanic systems (e.g., Iceland, Hawaiʻi, Galápagos Islands, East African Rift, Réunion, Canary Islands, Azores, Cabo Verde).
Hawaii↗
Organic matter variations in transgressive and regressive shales
Organic matter in the Upper Cretaceous Mancos Shale adjacent to the Tocito Sandstone in the San Juan Basin of New Mexico was characterized using organic petrology and organic geochemistry. Differences in the organic matter found in these regressive and transgressive offshore marine sediments have been documented and assessed within a sequence stratigraphic framework. The regressive Lower Mancos Shale below the Tocito Sandstone contains abundant well preserved phytoclasts and correspondingly low hydrogen indices. Total organic carbon values for the regressive shale are low. Sediments from the transgressive systems tract (Tocito Sandstone and overlying Upper Mancos Shale) contain less terrestrially derived organic matter, more amorphous non-structured protistoclasts, higher hydrogen indices and more total organic carbon. Advanced stages of degradation are characteristic of the phytoclasts found in the transgressive shale. Amorphous material in the transgressive shale fluoresces strongly while that found in the regressive shale is typically non-fluorescent. Data from pyrolysis-gas chromatography confirm these observations. These differences are apparently related to the contrasting depositional styles that were active on the shelf during regression and subsequent transgression. It is suggested that data from organic petrology and organic geochemistry provide greater resolution in sedimentologic and stratigraphic interpretations, particularly when working with basinward, fine-grained sediments. Petroleum source potential for the regressive Lower Mancos Shale below the Tocito Sandstone is poor. Based on abundant fluorescent amorphous material, high hydrogen indices, and high total organic carbon, the transgressive Upper Mancos Shale above the Tocito Sandstone possesses excellent source potential. This suggests that appreciable source potential can be found in offshore, fine-grained sediments of the transgressive systems tract below the condensed section and associated downlap surface. Organic petrology can be used to accurately predict petroleum source potential. The addition of simple fluorescence microscopy greatly enhances this predictive ability because non-generative amorphous material is generally non-fluorescent. Organic petrology must also be used to properly evaluate the utility of T max from programmed pyrolysis as a thermal maturity indicator. Organic matter dominated by autochthonous amorphous protistoclasts exhibits lower T max values than that which is composed of mostly phytoclasts.
New Mexico↗
The ~1.85 Ga carbonatite in north China and its implications on the evolution of the Columbia supercontinent
Mantle-derived carbonatites provide a unique window in the understanding of mantle characteristics and dynamics, as well as insight into the assembly and breakup of supercontinents. As a petrological indicator of extensional tectonic regimes, Archean/Proterozoic carbonatites provide important constraints on the timing of the breakup of ancient supercontinents. The majority of the carbonatites reported worldwide are Phanerozoic, in part because of the difficulty in recognizing Archean/Proterozoic carbonatites, which are characterized by strong foliation and recrystallization, and share broad petrologic similarities with metamorphosed sedimentary lithologies. Here, we report the recognition of a ~1.85 Ga carbonatite in Chaihulanzi area of Chifeng in north China based on systematic geological, petrological, geochemical, and baddeleyite U-Pb geochronological results. The carbonatite occurs as dikes or sills emplaced in Archean metasedimentary rocks and underwent intense deformation. Petrological and SEM/EDS results show that calcite and dolomite are the dominant carbonate minerals long with minor and varied amounts of Mg-rich mafic minerals, including forsterite (with Fo N 98), phlogopite, diopside, and an accessory amount of apatite, baddeleyite, spinel, monazite, and ilmenite. The relatively high silica content together with the non-arc and OIB-like trace element signatures of the carbonatite indicates a hot mantle plume as the likely magma source. The depleted Nd isotopic signatures suggest that plume upwelling might be triggered by the accumulation of recycled crust in the deep mantle. As a part of the global-scale Columbia supercontinent, the Proterozoic tectonic evolution of the North China Craton (NCC) provides important insights into the geodynamics governing amalgamation and fragmentation of the supercontinent. The Paleo-Mesoproterozoic boundary is the key point of tectonic transition from compressional to extensional settings in the NCC. The newly identified ~1.85 Ga carbonatite provides a direct link between the long-lasting super continental breakup and plume activity, which might be sourced from the “slab graveyard,” continental crustal slabs subducted into asthenosphere, beneath the supercontinent. The carbonatite provides a precise constraint of the initiation of the continental breakup at ~1.85 Ga.
Gondwana Research↗
The onset of metamorphism in ordinary and carbonaceous chondrites
Ordinary and carbonaceous chondrites of the lowest petrologic types were surveyed by X-ray mapping techniques. A variety of metamorphic effects were noted and subjected to detailed analysis using electron microprobe, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and cathodoluminescence (CL) methods. The distribution of Cr in FeO-rich olivine systematically changes as metamorphism increases between type 3.0 and type 3.2. Igneous zoning patterns are replaced by complex ones and Cr-rich coatings develop on all grains. Cr distributions in olivine are controlled by the exsolution of a Cr-rich phase, probably chromite. Cr in olivine may have been partly present as tetrahedrally coordinated Cr 3+ . Separation of chromite is nearly complete by petrologic type 3.2. The abundance of chondrules showing an inhomogeneous distribution of alkalis in mesostasis also increases with petrologic type. TEM shows this to be the result of crystallization of albite. Residual glass compositions systematically change during metamorphism, becoming increasingly rich in K. Glass in type I chondrules also gains alkalis during metamorphism. Both types of chondrules were open to an exchange of alkalis with opaque matrix and other chondrules. The matrix in the least metamorphosed chondrites is rich in S and Na. The S is lost from the matrix at the earliest stages of metamorphism due to coalescence of minute grains. Progressive heating also results in the loss of sulfides from chondrule rims and increases sulfide abundances in coarse matrix assemblages as well as inside chondrules. Alkalis initially leave the matrix and enter chondrules during early metamorphism. Feldspar subsequently nucleates in the matrix and Na re-enters from chondrules. These metamorphic trends can be used to refine classification schemes for chondrites. Cr distributions in olivine are a highly effective tool for assigning petrologic types to the most primitive meteorites and can be used to subdivide types 3.0 and 3.1 into types 3.00 through 3.15. On this basis, the most primitive ordinary chondrite known is Semarkona, although even this meteorite has experienced a small amount of metamorphism. Allan Hills (ALH) A77307 is the least metamorphosed CO chondrite and shares many properties with the ungrouped carbonaceous chondrite Acfer 094. Analytical problems are significant for glasses in type II chondrules, as Na is easily lost during microprobe analysis. As a result, existing schemes for chondrule classification that are based on the alkali content of glasses need to be revised.
Meteoritics and Planetary Science↗
Unmixing multiple metamorphic muscovite age populations with powder X-ray diffraction and 40Ar/39Ar analysis
A combination of modal estimates from powder X-ray diffraction (XRD) experiments and argon isotopic data shows that muscovite 40 Ar/ 39 Ar total gas age correlates with muscovite composition near the retrograde Bald Mountain shear zone (BMSZ) in Claremont, New Hampshire, and that the shear zone was active at ∼245 Ma. Petrologic study demonstrates that chemical disequilibrium is preserved in muscovite grains in these samples. The recognition of this preservation is critical to the interpretation of the 40 Ar/ 39 Ar step-heating experiments, which never produce age plateaus and yield spectra with steps that range in age by ∼20 Ma. Petrographic, compositional, and crystallographic data all indicate that the age spectra reflect dissolution of metastable Na-rich muscovite and precipitation of stable Na-poor muscovite associated with deformation in the BMSZ.Comparison of whole rock and muscovite concentrate XRD patterns from individual samples demonstrates that the mineral separation process can fractionate these muscovite populations. Therefore, four muscovite concentrates of varying magnetic susceptibility were prepared from a single hand sample, analyzed by XRD, and dated. These four splits define a mixing line that resolves end-member ages of 244.5 ± 4.2 Ma and 302.5 ± 12.5 Ma (1σ). Although the ages are imprecise, the petrologically supported conclusion that these schists preserve two discrete ages is distinct from an interpretation that the spectra reflect cooling through closure at ∼270 Ma, as might be concluded in the absence of petrologic characterization. The XRD results also demonstrate that, even well above anchizone conditions, petrologic information relevant to 40 Ar/ 39 Ar dating is observable in subtle variations in the crystallography of muscovite grains.
New Hampshire↗
Near-real-time geochemical monitoring of Hawaiian volcanoes using energy dispersive X-ray fluorescence (EDXRF)
Syn-eruption geochemical monitoring during volcanic activity is an important component of integrated volcanic monitoring. Volcanoes on the Island of Hawai‘i are primarily monitored by the U.S. Geological Survey’s Hawaiian Volcano Observatory using instrumental networks, field surveys, satellite observations, and petrologic monitoring. In collaboration with the University of Hawaiʻi at Hilo, an important component of this monitoring is near-real-time (generally within 24 h of sample collection) bulk-rock geochemistry using benchtop energy-dispersive X-ray fluorescence (EDXRF). Bulk-rock geochemistry, coupled with additional petrologic and geophysical analyses, are used to track eruption dynamics to help facilitate identification and understanding of changes that signal the onset of potentially hazardous activity. In this paper, we present EDXRF methodology for bulk-rock analysis used to evaluate the 2018 Kīlauea and 2022 Mauna Loa eruptions and compare this technique to other geochemical methods. Syn-eruption geochemical monitoring using EDXRF provides reliable quantitative data that is important for understanding eruption dynamics. Critical to this process are calibrating the instrument for analysis over the same range of compositions expected during volcanic activity, compiling a relevant database from past eruptions on the same instrument for comparison, and having the physical infrastructure and trained personnel to complete the analyses in a timely fashion. In addition to the scientific goals of petrologic monitoring, near-real-time geochemical analysis in Hawaii provides important information about the nature of on-going eruptions and informs decision-makers and the public about associated evolving hazards.
Hawaii↗
Multivariate analyses of Erzgebirge granite and rhyolite composition: Implications for classification of granites and their genetic relations
High-precision major, minor and trace element analyses for 44 elements have been made of 329 Late Variscan granitic and rhyolitic rocks from the Erzgebirge metallogenic province of Germany. The intrusive histories of some of these granites are not completely understood and exposures of rock are not adequate to resolve relationships between what apparently are different plutons. Therefore, it is necessary to turn to chemical analyses to decipher the evolution of the plutons and their relationships. A new classification of Erzgebirge plutons into five major groups of granites, based on petrologic interpretations of geochemical and mineralogical relationships (low-F biotite granites; low-F two-mica granites; high-F, high-P2O5 Li-mica granites; high-F, low-P2O5 Li-mica granites; high-F, low-P2O5 biotite granites) was tested by multivariate techniques. Canonical analyses of major elements, minor elements, trace elements and ratio variables all distinguish the groups with differing amounts of success. Univariate ANOVA's, in combination with forward-stepwise and backward-elimination canonical analyses, were used to select ten variables which were most effective in distinguishing groups. In a biplot, groups form distinct clusters roughly arranged along a quadratic path. Within groups, individual plutons tend to be arranged in patterns possibly reflecting granitic evolution. Canonical functions were used to classify samples of rhyolites of unknown association into the five groups. Another canonical analysis was based on ten elements traditionally used in petrology and which were important in the new classification of granites. Their biplot pattern is similar to that from statistically chosen variables but less effective at distinguishing the five groups of granites. This study shows that multivariate statistical techniques can provide significant insight into problems of granitic petrogenesis and may be superior to conventional procedures for petrological interpretation.
Computers & Geosciences↗
Organic geochemical study of sequences overlying coal seams; example from the Mansfield Formation (Lower Pennsylvanian), Indiana
Roof successions above two coal seams from the Mansfield Formation (Lower Pennsylvanian) in the Indiana portion of the Illinois Basin have been studied with regard to sedimentary structures, organic petrology and organic geochemistry. The succession above the Blue Creek Member of the Mansfield Formation is typical of the lithologies covering low-sulphur coals (< 1%) in the area studied, whereas the succession above the unnamed Mansfield coal is typical of high-sulphur coals (>2.%). The transgressive-regressive packages above both seams reflect the periodic inundation of coastal mires by tidal flats and creeks as inferred from bioturbation and sedimentary structures such as tidal rhythmites and clay-draped ripple bedforms. Geochemistry and petrology of organic facies above the Blue Creek coal suggest that tidal flats formed inland in fresh-water environments. These overlying fresh water sediments prevented saline waters from invading the peat, contributing to low-sulphur content in the coal. Above the unnamed coal, trace fossils and geochemical and petrological characteristics of organic facies suggest more unrestricted seaward depositional environment. The absence of saline or typically marine biomarkers above this coal is interpreted as evidence of very short periods of marine transgression, as there was not enough time for establishment of the precursor organisms for marine biomarkers. However, sufficient time passed to raise SO 4 2− concentration in pore waters, resulting in the formation of authigenic pyrite and sulphur incorparation into organic matter.
International Journal of Coal Geology↗
Volcanic history of the San Juan Mountains, Colorado, as indicated by potassium-argon dating
Volcanic rocks in the San Juan Mountains constitute the largest erosional remnant of a once nearly continuous volcanic field that extended over much of the southern Rocky Mountains and adjacent areas in Oligocene and later time. Recent regional studies have shown that the gross petrologic evolution throughout the San Juan remnant of this field was relatively simple, with initial intermediate lavas and breccias, followed closely in time by more silicic ash-flow tuffs, and ending with a bimodal association of basalt and rhyolite. More limited data from other remnants of the original field indicate a similar evolution. In the San Juan field, voluminous early lavas and breccias - mainly alkali andesite, rhyodacite, and mafic quartz latite - were erupted from numerous scattered central volcanoes onto an eroded tectonically stable terrane. They formed mostly during the interval 35 to 30 m.y. ago, but some probably were erupted earlier and others up to several million years later. About 30 m.y. ago, major volcanic activity changed to explosive ash-flow eruptions of quartz latite and low-silica rhyolite that persisted until about 26 m.y. ago. Source areas for the ash flows are marked by large calderas in the central and western San Juan Mountains. Two groups of lavas and associated rocks of intermediate composition intertongue with the ash-flow sequence: (1) quartz latitic lavas that were erupted in and adjacent to caldera structures and are genetically related to the ash-flow activity; and (2) other, generally more mafic lavas and related rocks that are widely distributed without evident structural relation to the ash-flow eruptive centers. The second group apparently represents a continuation of the early intermediate activity into the period of major ash-flow eruption. In the early Miocene the character of volcanism changed notably. Whereas the Oligocene volcanics are predominantly intermediate lavas and related silicic differentiates, the younger rocks are largely a bimodal association of basalt and high-silica alkali rhyolite. Basalt and minor rhyolite were erupted intermittently through the Miocene and Pliocene, and at one time formed a widespread thin veneer over the older volcanic terrane. The marked contrast between the Oligocene intermediate to low-silica rhyolitic magmas and the later basaltic and rhyolitic magmas implies either different conditions of magma generation or processes of differentiation for the two suites. This petrologic change coincides approximately in time with nearby development of the Rio Grande depression, a major rift that is the local expression of widespread late Cenozoic crustal extension. Whatever the cause of the petrologic change, the progression from predominantly intermediate to bimodal basalt-rhyolite volcanism, approximately concurrent with initiation of late Tertiary crustal extension, appears characteristic of Cenozoic volcanism for much of the western interior United States. © 1970, The Geological Society of America, Inc.
Colorado↗
Quaternarymagmatism in the Cascades - Geologic perspectives
Foreward The Cascade magmatic arc is a belt of Quaternary volcanoes that extends 1,250 km from Lassen Peak in northern California to Meager Mountain in Canada, above the subduction zone where the Juan de Fuca Plate plunges beneath the North American Plate. This Professional Paper presents a synthesis of the entire volcanic arc, addressing all 2,300 known Quaternary volcanoes, not just the 30 or so visually prominent peaks that comprise the volcanic skyline. Study of Cascade volcanoes goes back to the geological explorers of the late 19th century and the seminal investigations of Howel Williams in the 1920s and 1930s. However, major progress and application of modern scientific methods and instrumentation began only in the 1970s with the advent of systematic geological, geophysical, and geochemical studies of the entire arc. Initial stimulus from the USGS Geothermal Research Program was enhanced by the USGS Volcano Hazards Program following the 1980 eruption of Mount St. Helens. Together, these two USGS Programs have provided more than three decades of stable funding, staffing, and analytical support. This Professional Paper summarizes the resultant USGS data sets and integrates them with the parallel contributions of other investigators. The product is based upon an all-encompassing and definitive geological database, including chemical and isotopic analyses to characterize the rocks and geochronology to provide the critical time constraints. Until now, this massive amount of data has not been summarized, and a systematic and uniform interpretation firmly grounded in geological fact has been lacking. Herein lies the primary utility of this Cascade volume. It not only will be the mandatory starting point for new workers, but also will provide essential geological context to broaden the perspectives of current investigators of specific Cascade volcanoes. Wes Hildreth's insightful understanding of volcanic processes and his uncompromising scientific integrity make him uniquely qualified to present this synthesis. During more than three decades of volcanological studies, he has carried out comprehensive investigations of Mount Adams, Mount Baker, the Three Sisters, and the Simcoe Mountains Volcanic Field. He also brings a broad experience in other volcanic arcs, having conducted integrated field and laboratory investigations at several major volcanic centers in the Andes and the Aleutian arcs. His expertise and perspective have been further enhanced by in-depth petrologic studies of caldera environments, primarily in Long Valley, California, and Yellowstone. On the basis of all these field and laboratory investigations and exhaustive literature searches, he has published three definitive petrologic syntheses addressing the passage and transformation of basaltic magmas from their mantle sources through the crust to form the many types of volcanic manifestations at the Earth's surface. A major strength of this Professional Paper is that it adheres to data first and foremost, and only then correlates these data with relevant theories. Petrological and geophysical interpretation is left to the later sections of the volume, and even there is never allowed to stray from the pertinent databases. Hildreth's interpretations are not just idle speculations, but are carefully reasoned inferences firmly based on his thorough evaluation of the observational geological data. Professional Paper 1744 should not be skimmed lightly, in the hope that the salient points will quickly rub off. Instead, every section, indeed every paragraph, presents scholarly observations and insightful interpretations that demand careful and thoughtful study. This volume will influence and guide the course of Cascade investigations for decades to come.
British Columbia, California, Oregon, Washington↗
The Novarupta-Katmai eruption of 1912 - largest eruption of the twentieth century; centennial perspectives
The explosive outburst at Novarupta (Alaska) in June 1912 was the 20th century's most voluminous volcanic eruption. Marking its centennial, we illustrate and document the complex eruptive sequence, which was long misattributed to nearby Mount Katmai, and how its deposits have provided key insights about volcanic and magmatic processes. It was one of the few historical eruptions to produce a collapsed caldera, voluminous high-silica rhyolite, wide compositional zonation (51-78 percent SiO 2 ), banded pumice, welded tuff, and an aerosol/dust veil that depressed global temperature measurably. It emplaced a series of ash flows that filled what became the Valley of Ten Thousand Smokes, sustaining high-temperature metal-transporting fumaroles for a decade. Three explosive episodes spanned ~60 hours, depositing ~17 km 3 of fallout and 11±2 km 3 of ignimbrite, together representing ~13.5 km 3 of zoned magma. No observers were nearby and no aircraft were in Alaska, and so the eruption narrative was assembled from scattered villages and ship reports. Because volcanology was in its infancy and the early investigations (1915-23) were conducted under arduous expeditionary conditions, many provocative misapprehensions attended reports based on those studies. Fieldwork at Katmai was not resumed until 1953, but, since then, global advances in physical volcanology and chemical petrology have gone hand in hand with studies of the 1912 deposits, clarifying the sequence of events and processes and turning the eruption into one of the best studied in the world. To provide perspective on this century-long evolution, we describe the geologic and geographic setting of the eruption - in a remote, sparsely inhabited wilderness; we review the cultural and scientific contexts at the time of the eruption and early expeditions; and we compile a chronology of the many Katmai investigations since 1912. Products of the eruption are described in detail, including eight layers of regionwide fallout, nine packages of ash flows, and three lava domes that followed the explosive pyroclastic episodes. Changes in the proportions of coerupting rhyolite, dacite, and andesite pumice documented for the fallout and ash-flow successions, which are locally interbedded, permit close correlation of those synchronously emplaced sequences and their varied facies. Petrological correlation of the sequence of deposits near Novarupta with ash layers at Kodiak village, 170 km downwind, where three episodes of ashfall were recorded (to the hour), provides key constraints on timing of the eruptive events. Syneruptive collapse of a kilometer-deep caldera took place atop Mount Katmai, a stratovolcano centered 10 km east of the eruption site at Novarupta, owing to drainage of magma from beneath the Katmai edifice. Correlation of ~50 earthquakes recorded at distant seismic stations (including 14 shocks of magnitude 6.0 to 7.0) to fitful caldera collapse provides further constraints on eruption timing, because layers of nonjuvenile breccia and mud ejected from Mount Katmai during collapse pulses are intercalated with the pumice-fall layers from Novarupta. Structure of the Novarupta vent, a 2-km-wide depression backfilled by welded tuff and inferred to be funnel-shaped at depth, is described in detail, as is the 4-km-wide caldera at Mount Katmai. Discussions are also provided concerning: (1) the impact on global climate of the great mass of sulfur-poor but halogen-rich aerosol ejected into the atmosphere by the rhyolite-dominated eruption; (2) chemical and mineralogical effects of the fumarolic acid gases; and (3) the timing of several syneruptive landslide deposits sandwiched within the pumice-fall sequence. Secondary posteruption phenomena characterized include impounded lakes, ash-rich debris flows, phreatic craters on the ignimbrite sheet, responses of glaciers to the fallout blanket and to beheading by caldera collapse, growth of new glaciers inside the caldera, and gradual filling of the caldera lake. Structure, composition, and ages of the several andesite-dacite stratovolcanoes, closely clustered near Novarupta, all of which remain fumarolically and seismically active, are summarized. But among them only Mount Katmai extends compositionally to include basalt and rhyolite. The petrological affinities of 1912 magmas erupted at Novarupta with pre-1912 Katmai lavas are outlined, and various chemical, mineralogical, isotopic, and experimental data are assembled to construct a model of preeruptive magma storage beneath Mount Katmai. The monograph concludes by comparing the 1912 eruption with several other well-studied large explosive eruptions, 14 of them historical and 9 prehistoric. Finally, we retrospectively review the historical difficulties in understanding what had actually taken place at Katmai in 1912 and the century of progress in volcano science that has allowed most of it to be figured out.
Alaska;British Columbia;Washington;Yukon↗
Phase equilibrium of a high-SiO2, andesite at fO2 = RRO: Implications for Augustine volcano and other high-fO2 arc andesites
Understanding the impact of magmatic plumbing systems on explosive volcanic activity is important for hazard management. This study describes phase equilibria experiments using a high-silica andesite (HSA; SiO 2 = 62.5 wt%) from the 2006 eruption of Augustine Volcano, Alaska. Experiments were conducted under H 2 O saturated conditions, f 0 2 "> f 0 2 f02 = RRO (Re–ReO 2 or ~ Ni–NiO + 2), at pressures of 50–200 MPa ( P Total = P H2O ), and at temperatures of 800–1060 ° C. Run durations varied from 23 to 539 h, inversely scaled with temperature. The natural Augustine HSA phase assemblage (plagioclase, two pyroxenes, Fe–Ti oxides, magnesio-hornblende) was reproduced at 860–880 ° C and 120–200 MPa. Comparing experimental and natural glass and plagioclase compositions further refined those conditions to ~ 870 °C and 120–170 MPa. Crystallization of euhedral quartz was accompanied by biotite and small amounts of cummingtonite at T ≤ 850 °C. The relatively high temperature appearance of these typically low- T phases indicates that higher f 0 2 "> f 0 2 f02 could enhance their stability. The storage conditions estimated from our experiments compare well with previous magma plumbing system models for Augustine from geophysical and petrological data. The refined experimental pressure range suggests a storage depth of 4.6–6.6 km, assuming a crustal density of 2650 kg/m 3 . The strong petrological and geochemical similarities between the products of the 2006, 1986, and 1976 eruptions suggest that the Augustine magmatic system had generally consistent crystallization conditions for the HSA lithology during that > 30-year time interval. The experimental results broad implications for understanding higher f 0 2 "> f 0 2 magmas at andesitic arc volcanoes.
Alaska↗
Constraining magma storage conditions of the Toba magmatic system: A plagioclase and amphibole perspective
Silicic magma reservoirs are responsible for producing the largest explosive eruptions in the geologic record. Petrologic and geochronological data provide evidence for these systems spending substantial periods of time (10 4 –10 5 yrs) within the upper crust prior to eruption; however, the long-term thermochemical evolution of these systems is not fully understood, as existing petrologic data make it challenging to quantify the time interval a magmatic system has spent at certain temperatures, or its “thermal history”. Here, we investigate the 74 ka Youngest Toba Tuff (YTT), one of the largest explosive eruptions in the geologic record, to better constrain the long-term thermal evolution of its magmatic system. We combine forward models of Sr diffusion in plagioclase and hornblende, mineral thermometry, and pre-existing trace-element evolution models to quantify the thermochemical evolution of the YTT magmatic system. We find that plagioclase crystals record decades to centuries of storage at temperatures 750 C, while hornblende records up to 6200 years at the same temperatures. Hornblende crystallizes at temperatures around 820 C and adjusting our diffusion modeling to this temperature results in no more than 900 years at initial crystallization conditions. Combined with previous trace-element modeling work, these results indicate that although there was chemical diversity for long durations in the YTT magma system sufficient to produce unique composition eruptive products, the entire system was experiencing a relatively similar thermal history that did not allow for large bodies of eruptible magma to be present for long periods ( 10 2 –10 3 years). Rather, we suggest that magmas within the YTT magmatic system were stored for long durations at thermal conditions where they were uneruptible and only remobilized within a few centuries prior to eruption.
Sumatra↗
Eruptive stratigraphy of the Tatara-San Pedro complex, 36°S, sourthern volcanic zone, Chilean Andes: Reconstruction method and implications for magma evolution at long-lived arc volcanic centers
The Quaternary Tatara–San Pedro volcanic complex (36°S, Chilean Andes) comprises eight or more unconformity-bound volcanic sequences, representing variably preserved erosional remnants of volcanic centers generated during ∼930 ky of activity. The internal eruptive histories of several dominantly mafic to intermediate sequences have been reconstructed, on the basis of correlations of whole-rock major and trace element chemistry of flows between multiple sampled sections, but with critical contributions from photogrammetric, geochronologic, and paleomagnetic data. Many groups of flows representing discrete eruptive events define internal variation trends that reflect extrusion of heterogeneous or rapidly evolving magma batches from conduit–reservoir systems in which open-system processes typically played a large role. Long-term progressive evolution trends are extremely rare and the magma compositions of successive eruptive events rarely lie on precisely the same differentiation trend, even where they have evolved from similar parent magmas by similar processes. These observations are not consistent with magma differentiation in large long-lived reservoirs, but they may be accommodated by diverse interactions between newly arrived magma inputs and multiple resident pockets of evolved magma and/or crystal mush residing in conduit-dominated subvolcanic reservoirs. Without constraints provided by the reconstructed stratigraphic relations, the framework for petrologic modeling would be far different. A well-established eruptive stratigraphy may provide independent constraints on the petrologic processes involved in magma evolution—simply on the basis of the specific order in which diverse, broadly cogenetic magmas have been erupted. The Tatara–San Pedro complex includes lavas ranging from primitive basalt to high-SiO 2 rhyolite, and although the dominant erupted magma type was basaltic andesite (∼52–55 wt % SiO 2 ) each sequence is characterized by unique proportions of mafic, intermediate, and silicic eruptive products. Intermediate lava compositions also record different evolution paths, both within and between sequences. No systematic long-term pattern is evident from comparisons at the level of sequences. The considerable diversity of mafic and evolved magmas of the Tatara–San Pedro complex bears on interpretations of regional geochemical trends. The variable role of open-system processes in shaping the compositions of evolved Tatara–San Pedro complex magmas, and even some basaltic magmas, leads to the conclusion that addressing problems such as arc magma genesis and elemental fluxes through subduction zones on the basis of averaged or regressed reconnaissance geochemical datasets is a tenuous exercise. Such compositional indices are highly instructive for identifying broad regional trends and first-order problems, but they should be used with extreme caution in attempts to quantify processes and magma sources, including crustal components, implicated in these trends.
Andes Mountains, Tatara-San Pedro Volcanic Complex↗
Kilauea east rift zone magmatism: An episode 54 perspective
On January 29 30, 1997, prolonged steady-state effusion of lava from Pu'u'O'o was briefly disrupted by shallow extension beneath Napau Crater, 1 4 km uprift of the active Kilauea vent. A 23-h-long eruption ( episode 54 ) ensued from fissures that were overlapping or en echelon with eruptive fissures formed during episode 1 in 1983 and those of earlier rift zone eruptions in 1963 and 1968. Combined geophysical and petrologic data for the 1994 1999 eruptive interval, including episode 54 , reveal a variety of shallow magmatic conditions that persist in association with prolonged rift zone eruption. Near-vent lava samples document a significant range in composition, temperature and crystallinity of pre-eruptive magma. As supported by phenocryst liquid relations and Kilauea mineral thermometers established herein, the rift zone extension that led to episode 54 resulted in mixture of near-cotectic magma with discrete magma bodies cooled to ≤1100°C. Mixing models indicate that magmas isolated beneath Napau Crater since 1963 and 1968 constituted 32 65% of the hybrid mixtures erupted during episode 54 . Geophysical measurements support passive displacement of open-system magma along the active east rift conduit into closed-system rift -reservoirs along a shallow zone of extension. Geophysical and petrologic data for early episode 55 document the gradual flushing of episode 54 related magma during magmatic recharge of the edifice.
Hawaii↗