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USGS2003

Trends in chemical concentration in sediment cores from three lakes in New Jersey and one lake on Long Island, New York

Sediment cores were extracted from three lakes in northeastern New Jersey and one lake on western Long Island, New York, as part of the U.S. Geological Survey National Water-Quality Assessment Program. Sediment layers were dated by use of cesium-137 (137Cs), copper, lead, or dichlorodiphenyl-trichloroethane (DDT) profiles. Sediment layers were analyzed for seven selected trace elements, including arsenic, cadmium, chromium, lead, mercury, nickel, and zinc, and five hydrophobic organochlorine compounds, including chlordane, dieldrin, total DDT, total polychlorinated biphenyls (PCBs), and total polycyclic aromatic hydrocarbons (PAHs). All seven trace elements were detected throughout the cores from all four lakes. Concentrations of all elements, except arsenic, were elevated in the three cores from lakes within urbanized watersheds (Packanack Lake, Orange Reservoir, and Newbridge Pond) relative to the concentrations in the lake core collected below the largely forested, reference watershed (Clyde Potts Reservoir). Results of trend analyses indicate that concentrations of all trace elements, with the exception of arsenic and lead, were relatively constant throughout the core from the minimally urbanized Clyde Potts Reservoir. In urban lakes, significant upward trends in concentrations from deeper to shallower sediments were observed either to peak concentrations or throughout the core for all elements, with the exception of chromium at all lakes and arsenic and nickel at Orange Reservoir. This finding indicates that changes in population and land use in the urbanized watersheds over the period of sedimentary record have contributed to upward trends in trace-element concentrations. Although downward trends in concentrations were observed for some trace elements in the years after their concentrations peaked, concentrations of all trace elements in urban lake cores were higher in the most recently deposited sediments than at the base of each respective core. Lead concentrations over time were highly correlated with the population in the vicinity of the lake until the concentration peak in sediment deposited in the mid-1970’s. Concentrations of lead in lake sediment appear to be closely related to the use of leaded gasoline because lead concentrations generally decreased after the use of leaded gasoline was phased-out in the mid-1970’s. Zinc concentrations were highly correlated with population over the entire length of the core. In general, zinc concentrations increased in the three urbanized watersheds, probably in response to increasing population and vehicular use. This trend was not evident at Clyde Potts Reservoir, however, where vehicular traffic in the watershed is minimal. Detectable concentrations of chlordane, total DDT, and total PCBs were present in cores from all lakes; however, dieldrin was detected only in the Newbridge Pond and Packanack Lake cores. Concentrations generally were higher in cores from the urbanized Newbridge Pond and Orange Reservoir watersheds than in those from the minimally urbanized Clyde Potts Reservoir watershed. With the exception of chlordane in the Clyde Potts and Orange Reservoir cores, concentrations of the four organochlorine compounds had significant downward trends from peak concentrations to recently deposited sediment or non-significant trends throughout the core. On the basis of these findings and as a result of regulatory actions prohibiting the production and use of these compounds, downward trends in sedimentary concentrations are expected to continue; however, the persistence of these compounds indicates that a substantial amount of time may be required to purge them from the watersheds. Concentrations of PAHs in sediment generally increased with population growth and urbanization, probably as a result of increased fossil-fuel combustion (gasoline and home-heating fuels and other uses (roads and parking lots paved with asphalt) associated with increased urban development and vehicular traffic. This finding is supported by low concentrations of PAHs in Packanack Lake sediments in the 1930’s, before the watershed was urbanized and when automobiles were comparatively rare. As vehicular use and urbanization increase in these watersheds, the general increase of PAH concentrations in lake sediments can be expected to continue. Data from this study indicate that changes in population, land use, and chemical use in the urbanized watersheds over the period of sedimentary record have contributed to upward trends in concentrations of trace elements and hydrophobic organic compounds. Although downward trends were observed for some constituents in the years after their concentrations peaked, concentrations of most constituents in urban lake cores were higher in the most recently deposited sediments than at the base of each respective core and in the reference lake cores. Similar trends in concentrations of these constituents have been observed in sediment cores from other urban lakes across the United States.

New Jersey, New York↗

USGS2012

Simulated effects of alternative withdrawal strategies on groundwater flow in the unconfined Kirkwood-Cohansey aquifer system, the Rio Grande water-bearing zone, and the Atlantic City 800-foot sand in the Great Egg Harbor and Mullica River Basins, New Jersey

Groundwater is essential for water supply and plays a critical role in maintaining the environmental health of freshwater and estuarine ecosystems in the Atlantic Coastal basins of New Jersey. The unconfined Kirkwood-Cohansey aquifer system and the confined Atlantic City 800-foot sand are major sources of groundwater in the area, and each faces different water-supply concerns. The U.S. Geological Survey (USGS), in cooperation with the New Jersey Department of Environmental Protection (NJDEP), conducted a study to simulate the effects of withdrawals in the Kirkwood-Cohansey aquifer system, the Atlantic City 800-foot sand, and the Rio Grande water-bearing zone and to evaluate potential scenarios. The study area encompasses Atlantic County and parts of Burlington, Camden, Gloucester, Ocean, Cape May, and Cumberland Counties. The major hydrogeologic units affecting water supply in the study area are the surficial Kirkwood-Cohansey aquifer system, a thick diatomaceous clay confining unit in the upper part of Kirkwood Formation; the Rio Grande water-bearing zone; and the Atlantic City 800-foot sand of the Kirkwood Formation. Hydrogeologic data from 18 aquifer tests and specific capacity data from 230 wells were analyzed to provide horizontal hydraulic conductivity of the aquifers. Groundwater withdrawals are greatest from the Kirkwood-Cohansey aquifer system, and 65 percent of the water is used for public supply. Groundwater withdrawals from the Atlantic City 800-foot sand are about half those from the Kirkwood-Cohansey aquifer system. Ninety-five percent of the withdrawals from the Atlantic City 800-foot sand is used for public supply. Data from six streamgaging stations and 51 low-flow partial record sites were used to estimate base flow in the area. Base flow ranges from 60 to 92 percent of streamflow. A groundwater flow model of the Kirkwood-Cohansey aquifer system, the Rio Grande water-bearing zone, and the Atlantic City 800-foot sand was developed and calibrated using water-level data from 148 wells and base-flow data from 22 gaging or low-flow partial record stations. The Kirkwood-Cohansey aquifer system within the Great Egg Harbor River and the Mullica River Basins was simulated on a monthly basis from 1998 through 2006. An existing regional model of the New Jersey Coastal Plain was revised to provide boundary conditions for the Great Egg Harbor and Mullica River Basin model (referred to as the Great Egg-Mullica model). In the Great Egg-Mullica model, monthly groundwater recharge rates used in the model ranged from 10-15 inches per year in 2001 to 20-25 inches per year in 2005. The mean-absolute error for 10 of the 14 long-term hydrographs used in model calibration was less than 5 ft. Groundwater flow budgets for the Great Egg-Mullica model calibration periods, May 2005 and September 2006, and for the entire model calibration period 1998 to 2006, showed that nearly 70 percent of the water entering the Atlantic City 800-foot sand came from the horizontal connection with the Kirkwood-Cohansey aquifer system in updip areas. The groundwater flow model was used to simulate scenarios under three possible conditions: average 1998 to 2006 withdrawals (Average scenario), full-allocation withdrawals (Full Allocation scenario), and projected 2050-demand withdrawals (2050 Demand scenario). Withdrawals in the Full Allocation scenario are nearly twice the withdrawals from the Average scenario, primarily because of the potential for large agricultural withdrawals if all allocations are used. Withdrawals for the 2050 Demand scenario are about 50 percent greater than those for the Average scenario, primarily due to expected increases in withdrawals for public supply. Monthly base-flow depletion criteria were determined using the Low-Flow Margin method, currently under consideration by NJDEP, to estimate available water on an annual basis at the Hydrologic Unit Code 11 (HUC11) level and to determine whether a water-supply deficit exists. Simulations of various groundwater-withdrawal scenarios were made using the calibrated model, and results were compared with baseline conditions (no withdrawals) to determine where and when base-flow deficits may be occurring and may be expected to occur in the future. Scenarios were simulated to assess base-flow depletion that could occur from different groundwater-withdrawal situations. In the Average scenario, deficits occurred in 7 of the 14 subbasins. In the Full Allocation scenario, deficits occurred in 11 of the subbasins. In the 2050 Demand scenario, deficits occurred in 9 of the 14 subbasins. The largest deficits occurred in the Absecon Creek subbasin because the base-flow depletion criteria for this subbasin is small due to the surface-water diversions that are already occurring there and because existing groundwater withdrawals in the subbasin have resulted in base-flow depletion under current (1998-2006) conditions. Three adjusted scenarios, variations of the Average, Full Allocation, and 2050 Demand scenarios, were simulated; for the adjusted scenarios, the withdrawals were modified in stages with the intent to successively eliminate or minimize the base-flow deficits. Modifications included shifting withdrawals to a deeper part of the Kirkwood-Cohansey aquifer system, implementing seasonal conjunctive use of shallow and deep aquifers, and specifying reductions in withdrawals within a HUC11 subbasin in deficit. The adjusted scenarios are intended to show the relative effectiveness of each of the three approaches in reducing the deficits. Most of the deficits under the Average, Full Allocation, and 2050 Demand scenarios were eliminated by reductions in withdrawals or allocations. Shifting withdrawals to a deeper part of the Kirkwood-Cohansey aquifer system or seasonal conjunctive use did not eliminate deficits for any subbasin. Reductions in withdrawals accounted for more than 95 percent of the total reduction of deficits in all but one subbasin.

New Jersey↗

USGS2012

Nutrient concentrations and loads in the northeastern United States - Status and trends, 1975-2003

The U.S. Geological Survey (USGS) National Water-Quality Assessment Program (NAWQA) began regional studies in 2003 to synthesize information on nutrient concentrations, trends, stream loads, and sources. In the northeastern United States, a study area that extends from Maine to central Virginia, nutrient data were evaluated for 130 USGS water-quality monitoring stations. Nutrient data were analyzed for trends in flow-adjusted concentrations, modeled instream (non-flow-adjusted) concentrations, and stream loads for 32 stations with 22 to 29 years of water-quality and daily mean streamflow record during 1975-2003 (termed the long-term period), and for 46 stations during 1993-2003 (termed the recent period), by using a coupled statistical model of streamflow and water quality developed by the USGS. Recent trends in flow-adjusted concentrations of one or more nutrients also were analyzed for 90 stations by using Tobit regression. Annual stream nutrient loads were estimated, and annual nutrient yields were calculated, for 47 stations for the long-term and recent periods, and for 37 additional stations that did not have a complete streamflow and water-quality record for 1993-2003. Nutrient yield information was incorporated for 9 drainage basins evaluated in a national NAWQA study, for a total of 93 stations evaluated for nutrient yields. Long-term downward trends in flow-adjusted concentrations of total nitrogen and total phosphorus (18 and 19 of 32 stations, respectively) indicate regional improvements in nutrient-related water-quality conditions. Most of the recent trends detected for total phosphorus were upward (17 of 83 stations), indicating possible reversals to the long-term improvements. Concentrations of nutrients in many streams persist at levels that are likely to affect aquatic habitat adversely and promote freshwater or coastal eutrophication. Recent trends for modeled instream concentrations, and modeled reference concentrations, were evaluated relative to ecoregion-based nutrient criteria proposed by the U.S. Environmental Protection Agency. Instream concentrations of total nitrogen and total phosphorus persist at levels higher than proposed criteria at more than one-third and about one-half, respectively, of the 46 stations analyzed. Long-term trends in nutrient loads were primarily downward, with downward trends in total nitrogen and total phosphorus loads detected at 12 and 17 of 32 stations, respectively. Upward trends were rare, with one upward trend for total nitrogen loads and none for total phosphorus. Trends in loads of nitrite-plus-nitrate nitrogen included 7 upward and 8 downward trends among 32 stations. Downward trends in loads of ammonia nitrogen and total Kjeldahl nitrogen were detected at all six stations evaluated. Long-term downward trends detected in four of the five largest drainage basins evaluated include: total nitrogen loads for the Connecticut, Delaware, and James Rivers; total Kjeldahl nitrogen and ammonia nitrogen loads for the Susquehanna River; ammonia nitrogen and nitrite-plus-nitrate nitrogen loads for the James River; and total phosphorus loads for the Connecticut and Delaware Rivers. No trends in load were detected for the Potomac River. Nutrient yields were evaluated relative to the extent of land development in 93 drainage basins. The undeveloped land-use category included forested drainage basins with undeveloped land ranging from 75 to 100 percent of basin area. Median total nitrogen yields for the 27 undeveloped drainage basins evaluated, including 9 basins evaluated in a national NAWQA study, ranged from 290 to 4,800 pounds per square mile per year (lb/mi 2 /yr). Total nitrogen yields even in the most pristine drainage basins may be elevated relative to natural conditions, because of high rates of atmospheric deposition of nitrogen in parts of the northeastern United States. Median total phosphorus yields ranged from 12 to 330 lb/mi 2 /yr for the 26 undeveloped basins evaluated. The undeveloped category includes some large drainage basins with point-source discharges and small percentages of developed land; in these basins, streamflow from undeveloped headwater areas dilutes streamflow in more urbanized reaches, and dampens but does not eliminate the point-source "signal" of higher nutrient loads. Median total nitrogen yields generally do not exceed 1,700 lb/mi 2 /yr, and median total phosphorus yields generally do not exceed 100 lb/mi 2 /yr, in the drainage basins that are least affected by human land-use and waste-disposal practices. Agricultural and urban land use has increased nutrient yields substantially relative to undeveloped drainage basins. Median total nitrogen yields for 24 agricultural basins ranged from 1,700 to 26,000 lb/mi 2 /yr, and median total phosphorus yields ranged from 94 to 1,000 lb/mi 2 /yr. The maximum estimated total nitrogen and total phosphorus yields, 32,000 and 16,000 lb/mi 2 /yr, respectively, for all stations in the region were in small (less than 50 square miles (mi 2 )) agricultural drainage basins. Median total nitrogen yields ranged from 1,400 to 17,000 lb/mi 2 /yr in 26 urbanized drainage basins, and median total phosphorus yields ranged from 43 to 1,900 lb/mi 2 /yr. Urbanized drainage basins with the highest nutrient yields are generally small (less than 300 mi2) and are drained by streams that receive major point-source discharges. Instream nutrient loads were evaluated relative to loads from point-source discharges in four drainage basins: the Quinebaug River Basin in Connecticut, Massachusetts, and Rhode Island; the Raritan River Basin in New Jersey; the Patuxent River Basin in Maryland; and the James River Basin in Virginia. Long-term downward trends in nutrient loads, coupled with similar trends in flow-adjusted nutrient concentrations, indicate long-term reductions in the delivery of most nutrients to these streams. However, the absence of recent downward trends in load for most nutrients, coupled with instream concentrations that exceed proposed nutrient criteria in several of these waste-receiving streams, indicates that challenges remain in reducing delivery of nutrients to streams from point sources. During dry years, the total nutrient load from point sources in some of the drainage basins approached or equaled the nutrient load transported by the stream.

Connecticut;Delaware;Maine;Maryl;Massachusetts;New↗

USGS2012

Quality of water from crystalline rock aquifers in New England, New Jersey, and New York, 1995-2007

Crystalline bedrock aquifers in New England and parts of New Jersey and New York (NECR aquifers) are a major source of drinking water. Because the quality of water in these aquifers is highly variable, the U.S. Geological Survey (USGS) statistically analyzed chemical data on samples of untreated groundwater collected from 117 domestic bedrock wells in New England, New York, and New Jersey, and from 4,775 public-supply bedrock wells in New England to characterize the quality of the groundwater. The domestic-well data were from samples collected by the USGS National Water-Quality Assessment (NAWQA) Program from 1995 through 2007. The public-supply-well data were from samples collected for the U.S. Environmental Protection Agency (USEPA) Safe Drinking Water Act (SDWA) Program from 1997 through 2007. Chemical data compiled from the domestic wells include pH, specific conductance, dissolved oxygen, alkalinity, and turbidity; 6 nitrogen and phosphorus compounds, 14 major ions, 23 trace elements, 222 radon gas (radon), 48 pesticide compounds, and 82 volatile organic compounds (VOCs). Additional samples were collected from the domestic wells for the analysis of gross alpha- and gross beta-particle radioactivity, radium isotopes, chlorofluorocarbon isotopes, and the dissolved gases methane, carbon dioxide, nitrogen, and argon. Chemical data compiled from the public-supply wells include pH, specific conductance, nitrate, iron, manganese, sodium, chloride, fluoride, arsenic, uranium, radon, combined radium ( 226 radium plus 228 radium), gross alpha-particle radioactivity, and methyl tert -butyl ether (M t BE). Patterns in fluoride, arsenic, uranium, and radon distributions were discernable when the data were compared to lithology groupings of the bedrock, indicating that the type of bedrock has an effect on the quality of groundwater from NECR aquifers. Fluoride concentrations were significantly higher in groundwater samples from the alkali granite, peraluminous granite, and metaluminous granite lithology groups than from samples in the other lithology groups. Water samples from 1.4 percent of 2,167 studied wells had fluoride concentrations that were equal to or greater than the maximum contaminant level (MCL) of 4 milligrams per liter (mg/L) and 7.5 percent of the wells had fluoride concentrations that were equal to or greater than the secondary MCL of 2 mg/L. For arsenic, groundwater samples from the calcareous metasedimentary rocks in the New Hampshire-Maine geologic province, peraluminous granite, and pelitic rocks lithology groups had higher concentrations than did samples from the other lithology groups. Water samples from 13.3 percent of 2,054 studied wells had arsenic concentrations that were equal to or greater than the MCL of 10 micrograms per liter (μg/L), about double the national rate of occurrence in community-supply systems and in domestic wells of the United States. Uranium concentrations were significantly higher in groundwater samples from the peraluminous granite, alkali granite, and calcareous metasedimentary rocks in the New Hampshire-Maine geologic province lithology groups than from samples in the other lithology groups. Water samples from 14.2 percent of 556 studied wells had uranium concentrations equal to or greater than the MCL of 30 μg/L. Radon activities were equal to or greater than the proposed MCL of 300 picocuries per liter (pCi/L) in 95 percent of 943 studied wells, and 33 percent of the wells had radon activities were equal to or greater than the proposed alternative maximum contaminant level (AMCL) of 4,000 pCi/L. Radon activities exceeded the proposed AMCL in 20 percent or more of groundwater samples in each of the studied lithology groups with a minimum of 9 samples, but radon activities were significantly higher in groundwater samples from the alkali granite, peraluminous granite, and Narragansett basin metasedimentary rocks lithology groups. Water samples from 3.2 percent of 564 studied wells had combined radium activities equal to or greater than the MCL of 5 pCi/L; however, combined radium activities were not significantly different among the studied lithology groups. Land use and population density also were evaluated to explain patterns in water quality. Concentrations of nitrate, sodium, chloride, and MtBE from the studied wells were significantly greater in areas of high population density (≥50 persons per square kilometer) than in areas of low population density (<50 persons per square kilometer). Concentrations of sodium, chloride, and M t BE from the studied wells were significantly greater in areas classified as developed (urban lands) than in areas classified as undeveloped (forested), agricultural, or mixed (no dominant land use). Nitrate concentrations from the public-supply wells were not significantly different among the four land use categories, but nitrate concentrations from the domestic wells were significantly greater in areas classified as developed than in areas classified as undeveloped, agricultural, or mixed. Chloride to bromide mass ratios in the domestic well samples indicate that the groundwater was probably affected by at least three halogen sources: local precipitation and recharge waters, remnant seawater and connate waters evolved from seawater, and recharge waters affected by road salt. The groundwater in the NECR aquifers generally contained low concentrations of nitrate, VOCs, and pesticides. Less than 1 percent of water samples from 4,781 studied wells had concentrations of nitrate greater than the MCL of 10 mg/L. Less than 1 percent of water samples from 1,299 studied wells exceeded the USEPA advisory level of 20 to 40 μg/L for M t BE. None of the other studied VOCs exceeded a human health benchmark. M t BE (36 percent frequency detection) and chloroform (32.9 percent frequency detection) were the most frequently detected (>0.02 μg/L) VOCs in the domestic wells. M t BE was detected more often in water samples with apparent ages of less than 25 years than in water samples with apparent ages greater than 25 years. This finding is consistent with the time period of high M t BE use in areas in the United States where reformulated gasoline was mandated. The largest pesticide concentration was an estimated concentration of 0.06 μg/L for the herbicide metolachlor. Deethylatrazine, a degradate of atrazine, (18 percent frequency detection) and atrazine (8 percent frequency detection) were the only pesticide compounds detected (>0.001 μg/L) in more than 3 percent of the domestic wells. None of the detected pesticide compounds exceeded human health benchmarks. Concentrations of nitrate and gross alpha-particle activities were significantly greater in the water samples from the domestic wells than in samples from the public-supply wells. Concentrations of sodium, chloride, iron, manganese, and uranium were significantly greater in the water samples from the public-supply wells than in the samples from the domestic wells. One possible explanation may be related to differences in field processing (filtered samples from the domestic wells compared to unfiltered samples from the public-supply wells). The high frequency of detections for a wide variety of manmade and naturally occurring contaminants in both domestic and public-supply wells shows the vulnerability of NECR aquifers to contamination. The highly variable water quality and the association with highly variable lithology of crystalline bedrock underscores the importance of testing individual wells to determine if concentrations for the most commonly detected contaminants exceed human health benchmarks.

Connecticut, Maine, Massachusetts, New Hampshire, ↗

USGS2008

Occurrence of organic compounds and trace elements in the upper Passaic and Elizabeth Rivers and their tributaries in New Jersey, July 2003 to February 2004: Phase II of the New Jersey toxics reduction workplan for New York-New Jersey Harbor

Samples of surface water and suspended sediment were collected from the Passaic and Elizabeth Rivers and their tributaries in New Jersey from July 2003 to February 2004 to determine the concentrations of selected chlorinated organic and inorganic constituents. This sampling and analysis was conducted as Phase II of the New York-New Jersey Harbor Estuary Workplan—Contaminant Assessment and Reduction Program (CARP), which is overseen by the New Jersey Department of Environmental Protection. Phase II of the New Jersey Workplan was conducted to define upstream tributary and point sources of contaminants in those rivers sampled during Phase I work, with special emphasis on the Passaic and Elizabeth Rivers. Samples were collected from three groups of tributaries: (1) the Second, Third, and Saddle Rivers; (2) the Pompton and upper Passaic Rivers; and (3) the West Branch and main stem of the Elizabeth River. The Second, Third, and Saddle Rivers were sampled near their confluence with the tidal Passaic River, but at locations not affected by tidal flooding. The Pompton and upper Passaic Rivers were sampled immediately upstream from their confluence at Two Bridges, N.J. The West Branch and the main stem of the Elizabeth River were sampled just upstream from their confluence at Hillside, N.J. All tributaries were sampled during low-flow discharge conditions using the protocols and analytical methods for organic constituents used in low-flow sampling in Phase I. Grab samples of streamflow also were collected at each site and were analyzed for trace elements (mercury, methylmercury, cadmium, and lead) and for suspended sediment, particulate organic carbon, and dissolved organic carbon. The measured concentrations and available historical suspended-sediment and stream-discharge data (where available) were used to estimate average annual loads of suspended sediment and organic compounds in these rivers. Total suspended-sediment loads for 1975–2000 were estimated using rating curves developed from historical U.S. Geological Survey (USGS) suspended-sediment and discharge data, where available. Average annual loads of suspended sediment, in millions of kilograms per year (Mkg/yr), were estimated to be 0.190 for the Second River, 0.23 for the Third River, 1.00 for the Saddle River, 1.76 for the Pompton River, and 7.40 for the upper Passaic River. On the basis of the available discharge records, the upper Passaic River was estimated to provide approximately 60 percent of the water and 80 percent of the total suspended-sediment load at the Passaic River head-of-tide, whereas the Pompton River provided roughly 20 percent of the total suspended-sediment load estimated at the head-of-tide. The combined suspended-sediment loads of the upper Passaic and Pompton Rivers (9.2 Mkg/yr), however, represent only 40 percent of the average annual suspended-sediment load estimated for the head-of-tide (23 Mkg/yr) at Little Falls, N.J. The difference between the combined suspended-sediment loads of the tributaries and the estimated load at Little Falls represents either sediment trapped upriver from the dam at Little Falls, additional inputs of suspended sediment downstream from the tributary confluence, or uncertainty in the suspended-sediment and discharge data that were used. The concentrations of total suspended sediment-bound polychlorinated biphenyls (PCBs) in the tributaries to the Passaic River were 194 ng/g (nanograms per gram) in the Second River, 575 ng/g in the Third River, 2,320 ng/g in the Saddle River, 200 ng/g in the Pompton River, and 87 ng/g in the upper Passic River. The dissolved PCB concentrations in the tributaries were 563 pg/L (picograms per liter) in the Second River, 2,510 pg/L in the Third River, 2,270 pg/L in the Saddle River, 887 pg/L in the Pompton River, and 1,000 pg/L in the upper Passaic River. Combined with the sediment loads and discharge, these concentrations resulted in annual loads of suspended sediment-bound PCBs, in grams per year (g/yr), of 37 in the Second River; 132 in the Third River; 2,320 in the Saddle River; 352 in the Pompton River; and 644 in the upper Passaic River. Annual loads of dissolved PCBs, in grams per year, are 9.2 in the Second River; 47 in the Third River; 212 in the Saddle River; 349 in the Pompton River; and 549 in the upper Passaic River. Concentrations of total suspended sediment-bound polychlorinated dibenzo-p-dioxins and polychlorinated dibenzo-p-difurans (PCDD/PCDFs) were 6,000 pg/g (picograms per gram) in the Second River; 11,300 pg/g in the Third River; 37,700 pg/g in the Saddle River; 7,140 pg/g in the Pompton River; and 9,640 pg/g in the upper Passaic River. Total toxic equivalence quotients (TEQs), which included PCDD/PCDFs and coplanar PCBs, ranged from 2.7 pg/g in the Second River to 132 pg/g (as 2,3,7,8-TCDD) in the Saddle River. Average annual loads of PCDD/PCDFs were from 1.1 g/yr in the Second River to 71 g/yr in the upper Passaic River. The load of TEQs (as 2,3,7,8-TCDD) from PCDD/PCDFs and coplanar PCBs in the tributaries were 0.5 mg/yr (milligrams per year) in the Second River, 5.8 mg/yr in the Third River, 130 mg/yr in the Saddle River, 46 mg/yr in the Pompton River, and 100 mg/yr in the upper Passaic River. These loads represent an addition to the TEQ load estimated to cross the head-of-tide of 0.1 percent by the Second River, 0.7 percent by the Third River, and 15 percent by the Saddle River. Loads of sediment-bound trace elements mercury, methylmercury, lead, and cadmium were calculated using concentrations obtained from grab samples, which were assumed to represent average annual concentrations in these rivers. Loads of sediment-bound mercury were estimated to be 1,200 g/yr in the Second River; 130 g/yr in the Third River; 4,200 g/yr in the Saddle River; 3,400 g/yr in the Pompton River; and 6,500 g/yr in the upper Passaic River. Loads of sediment-bound lead were estimated to be 56 kg/yr (kilograms per year) in the Second River; 89 kg/yr in the Third River; 1,140 kg/yr in the Saddle River; 310 kg/yr in the Pompton River; and 1,040 kg/yr in the upper Passaic River. Loads of sediment-bound cadmium were estimated to be 1 kg/yr in the Second River; 0.59 kg/yr in the Third River; 60 kg/yr in the Saddle River; 16 kg/yr in the Pompton River; and 11 kg/yr in the upper Passaic River. These loads indicate the importance of the sediment-bound contributions of organic compounds and trace elements to the upper Passaic and Saddle Rivers. Concentrations of suspended sediment-bound PCBs in the main stem and the West Branch of the Elizabeth River were 806 ng/g and 3,100 ng/g, respectively, representing loads of 40 g/yr and 1,150 g/yr, respectively. These loads were estimated using assumed discharge conditions. Concentrations of suspended sediment-bound PCDD/PCDFs were 7,270 pg/g and 9,980 pg/g in the main stem and West Branch, respectively, representing average annual loads of 0.36 g/yr and 3.7 g/yr, respectively. Total TEQ loads (sum of PCDD/PCDFs and PCBs) were 2.1 mg/yr (as 2,3,7,8-TCDD) in the main stem and 34 mg/yr in the West Branch, respectively. These load estimates, however, were directly related to the assumed annual discharge for the two branches. Long-term measurement of stream discharge and suspended-sediment concentrations would be needed to verify these loads. On the basis of the concentrations measured in this work, it appears that the West Branch is the principal source of PCBs, PCDD/PCDFs, total TEQs, and metals to the main stem of the Elizabeth River. Additional sources of these constituents may exist between the confluence and the head-of-tide.

New Jersey, New York↗

USGS2016

Assessment of groundwater availability in the Northern Atlantic Coastal Plain aquifer system From Long Island, New York, to North Carolina

Executive Summary The U.S. Geological Survey began a multiyear regional assessment of groundwater availability in the Northern Atlantic Coastal Plain (NACP) aquifer system in 2010 as part of its ongoing regional assessments of groundwater availability of the principal aquifers of the Nation. The goals of this national assessment are to document effects of human activities on water levels and groundwater storage, explore climate variability effects on the regional water budget, and provide consistent and integrated information that is useful to those who use and manage the groundwater resource. As part of this nationwide assessment, the USGS evaluated available groundwater resources within the NACP aquifer system from Long Island, New York, to northeastern North Carolina. The northern Atlantic Coastal Plain physiographic province depends heavily on groundwater to meet agricultural, industrial, and municipal needs. The groundwater assessment of the NACP aquifer system included an evaluation of how water use has changed over time; this evaluation primarily used groundwater budgets and development of a numerical modeling tool to assess system responses to stresses from future human uses and climate trends. This assessment focused on multiple spatial and temporal scales to examine changes in groundwater pumping, storage, and water levels. The regional scale provides a broad view of the sources and demands on the system with time. The sub-regional scale provides an evaluation of the differing response of the aquifer system across geographic areas allowing for closer examination of the interaction between different aquifers and confining units and the changes in these interactions under pumping and recharge conditions in 2013 and hydrologic stresses as much as 45 years in the future. By focusing on multiple scales, water-resource managers may utilize this study to understand system response to changes as they affect the system as a whole. The NACP aquifer system extends from Long Island to northeastern North Carolina, and includes aquifers primarily within New York, New Jersey, Delaware, Maryland, Virginia, and North Carolina. The seaward-dipping sedimentary wedge that underlies the northern Atlantic Coastal Plain physiographic province forms a complex groundwater system. Although the NACP aquifer system is recognized by the U.S. Geological Survey as one of the smallest of the 66 principal aquifer systems in the Nation, it ranks 13th overall in terms of total groundwater withdrawals and is 7th in population served. Despite abundant precipitation [about 45 inches per year (in/yr)], the supply of fresh surface water in this region is limited because many of the surface waters in this area are brackish estuaries, contributing to why many communities in the northern Atlantic Coastal Plain physiographic province rely heavily on groundwater to meet their water needs. Increases in population and changes in land use during the past 100 years have resulted in diverse increased demands for freshwater throughout the northern Atlantic Coastal Plain physiographic province with groundwater serving as a vital source of drinking water for the nearly 20 million people who live in the region. Total groundwater withdrawal in 2013 was estimated to be about 1,300 million gallons per day (Mgal/d) and accounts for about 40 percent of the drinking water supply with the densely populated areas tending to have the highest rates of withdrawals and, therefore, being most susceptible to effects from these withdrawals over time. Water levels in many of the confined aquifers are decreasing by as much as 2 feet per year (ft/yr) in response to extensive development and subsequent increased withdrawals throughout the region. Total water-level decreases (drawdowns) are more than 100 feet (ft) in some aquifers from their predevelopment (before 1900) levels. These drawdowns extend across state lines and under the Chesapeake and Delaware Bays, creating the potential for interstate aquifer management issues. Regional water-resources managers in the northern Atlantic Coastal Plain physiographic province face challenges beyond competing local domestic, industrial, agricultural, and environmental demands for water. Large changes in regional water use have made the State-level management of aquifer resources more difficult because of hydrologic effects that extend beyond State boundaries. The northern Atlantic Coastal Plain physiographic province is underlain by a wedge of unconsolidated to partially consolidated sediments that are typically thousands of feet thick along the coastline with a maximum thickness of about 10,000 ft near the edge of the continental shelf. The NACP aquifer system consists of nine confined aquifers and nine confining units capped by an unconfined surficial aquifer that is bounded laterally from the west by the contact between Coastal Plain sediments and the upland Piedmont bedrock. This aquifer system extends to the east to the limit of the Continental Shelf, however, the boundary between fresh and saline groundwater is considered to be much closer to the shoreline and varies vertically by aquifer. Precipitation over the region for average conditions from 2005 to 2009 is about 61,800 Mgal/d, but about 70 percent of it is lost to evapotranspiration resulting in an inflow of about 19,600 Mgal/d entering the groundwater system as aquifer recharge. Most of this recharge enters the aquifer system and flows through the shallow unconfined aquifer and either discharges to streams or directly to coastal waters without reaching the deep, confined aquifer system. In addition to recharge from precipitation, other sources of water include the return of wastewater from domestic septic systems of about 240 Mgal/d, about 60 Mgal/d of water released from storage in the confined system, and about 30 Mgal/d of lateral inflow at the boundary between freshwater and saltwater in response to pumping for conditions in 2013. The outflow needed to balance the inflows was subdivided between streamflow, discharge to tidal portions of streams, and coastal discharge. The hydrologic budget developed for current [2013] conditions determined that 93 percent of the total outflow was to surface waters with about 70 percent divided evenly between streamflow and shallow coastal discharge and 23 percent as discharge to tidal waters. The remaining 7 percent of the total outflow components include withdrawals from both the surficial and confined aquifers of the groundwater system. The groundwater availability assessment of the NACP aquifer system highlights the importance of analyses at both the regional and local scales to understand how changes in land use, water use, and climate have affected groundwater resources and how these resources may change in the future. The investigation included assessments of the regional changes in water levels and budgets across State lines, the importance of considering storage change in the confining units, the response of the aquifer system to a continuation of current [2013] hydrologic stresses into the future, and the potential effects of climate change and sea-level rise on the aquifer system. The Potomac aquifer group includes two of the most widely used aquifers in the NACP aquifer system, the Potomac-Patapsco and Potomac-Patuxent regional aquifers, providing about 24 percent of the total groundwater used in the region. Withdrawals from large pumping centers in this deep, confined aquifer group have resulted in substantial decreases in water-levels across state lines, particularly between southern Virginia and northeastern North Carolina as well as between southern New Jersey and northern Delaware where water levels in the Potomac-Patapsco aquifer have decreased by as much as 200 ft and 50 ft, respectively from predevelopment to current [2013] conditions. This response in water levels also is reflected in changes in water budgets where, for example, about 20 percent of the total response to pumping in Virginia is met by inducing flow from adjacent States. Understanding and quantifying these hydrologic effects that extend beyond State boundaries is critical for the State- and regional-level management of aquifer resources. The cumulative storage loss from the intervening confining units throughout the entire NACP aquifer system was about 35 percent of the total storage loss from predevelopment to current [2013] conditions. In geographic areas such as Delmarva Peninsula, Maryland, and New Jersey, the water released from storage in the confining units makes up the majority of the total storage release from the groundwater system and is becoming proportionally more important over time as the surficial aquifer approaches equilibrium with respect to pumping and recharge stresses as of 2013. Storage loss from the confining units is of particular concern because, unlike in the sands that comprise the confined aquifers, water removed from the clayey confining unit sediments cannot be replenished as these units gradually compress. This non-recoverable storage loss, if great enough, can result in land subsidence where these units are thick and the release from storage is relatively large and contributes to increased concerns for sea-level rise in areas such as the lower portion of the Chesapeake Bay. Groundwater usage increased dramatically in the NACP aquifer system during post-World War II era from the mid-1940s to early the 1980s, with withdrawals increasing from about 400 Mgal/d to more than 1,300 Mgal/d. Although groundwater withdrawals have been relatively constant since the early 1980s, about half of the total groundwater withdrawn from the NACP aquifer system since 1900 was withdrawn in the past 30 years. An analysis of the response of the groundwater system to a continuation of the current [2013] pumping for an additional 30 years into the future shows that the flow system continues to adjust in terms of changes in water budget components, water levels, and the boundary between freshwater and saltwater as it approaches equilibrium. The largest change in water budget components is the reduction in the amount of water released from storage. Across the entire NACP aquifer system, the reduction of storage release from 7 to 4 percent of the total water budget change is accounted for by reductions in groundwater discharge to streams and coastal waters. Locally, a similar response is calculated for each of the geographic areas except for Virginia where the amount of water released from storage accounts for about 25 percent of the total change in water budget. This finding suggests that the groundwater flow system in Virginia is not approaching equilibrium under the current [2013] stresses and, therefore, water levels will continue to decrease even if the pumping remains constant. An analysis of the change in water levels in the Potomac-Patapsco aquifer as pumping is continued 30 years into the future reveals that the largest decreases in water levels throughout the NACP aquifer system will occur in the southern Virginia and northeastern North Carolina parts of the study area. It is these areas that also see the greatest potential for increased lateral movement of saline groundwater in the deep, confined portion of the groundwater flow system in response to a continuation of the current [2013] pumping rates. The potential effects of long-term climate change and variability on the hydrologic system and availability of water resources in the NACP aquifer system continue to be of serious societal concern. These concerns include the effects of changes in aquifer recharge and in sea-level rise on the groundwater flow system. An assessment of the potential effects of a prolonged drought during current [2013] pumping conditions indicated that the reductions in recharge associated with droughts, including additional irrigation withdrawals required to meet increased crop water demand, have the greatest effects on water levels and streamflows in the surficial aquifer, and changes in water levels in the confined aquifers primarily resulted from the increased withdrawals associated with increased irrigation pumping; this response was most apparent in the Delmarva Peninsula. These results suggest that water levels may not be susceptible to the effects of droughts in the confined aquifers of the NACP aquifer system not used for irrigation, unlike in the unconfined surficial aquifer. A second analysis also was conducted to assess the effects of sea-level rise on the groundwater system throughout the northern Atlantic Coastal Plain physiographic province because recent analyses of the relative rates of sea-level rise along the Atlantic coast indicate that the Mid-Atlantic region represents a hot spot with anomalously higher rates of sea-level rise than observed elsewhere in the United States. Groundwater levels rose from 0 to 3 ft in response to a 3-ft simulated change in sea-level position, with the largest response occurring along the shoreline and away from non-tidal streams. About 37 percent (or 10,000 square miles) of the area of the northern Atlantic Coastal Plain physiographic province may experience about a 0.5-ft or more increase in water levels with the 3-ft increase in sea-level position, whereas about 18 percent (almost 5,000 square miles) of land of the northern Atlantic Coastal Plain physiographic province may experience a 2-ft or more increase in water levels with the 3-ft increase in sea-level position. These increases in the water table are of particular concern in low-lying areas where the unsaturated (vadose) zone is already thin, thus creating concerns for groundwater inundation of subsurface infrastructure, such as basements, septic systems, and subway systems. This increase in the water table also will likely alter the distribution of groundwater discharge to surface-water bodies thus increasing groundwater flow to streams that would have otherwise discharged directly to coastal waters. Throughout the NACP aquifer system, this redistribution of groundwater discharge results in an additional 2 percent of base flow in streams. Although the increases in groundwater discharge to streams (and corresponding decreases in discharge to coastal waters) calculated for the entire NACP aquifer system and its geographic areas represent only a small increase compared with current [2013] conditions, this redistribution of groundwater discharge from the coast to streams locally can alter the delivery of freshwater input to coastal receiving waters and have ecohydrological implications on the sensitive ecosystems which rely on a balance of groundwater discharge and surface-water flow.

Delaware, Maryland, New Jersey, New York, North Ca↗