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The distribution of bromide in water in the Floridan aquifer system, Duval County, northeastern Florida

Although Duval County, Florida, has ample ground-water resources for public supply, the potential exists for a problem with excessive disinfectant by-products. These disinfectant by-products result from the treatment of raw water containing low concentrations of bromide and naturally occurring organic compounds. Because of this potential problem, the relation of bromide concentrations to aquifer tapped, well location and depth, and chemical characteristics of water in the Floridan aquifer system underlying Duval County were studied to determine if these relations could be applied to delineate water with low-bromide concentrations for future supplies. In 1992, water samples from 106 wells that tap the Floridan aquifer system were analyzed for bromide and major dissolved constituents. A comparison of bromide concentrations from the 1992 sampling with data from earlier studies (1979-80) indicates that higher bromide concentrations were detected during the earlier studies. The difference between the old and new data is probably because of a change in analytical methodology in the analysis of samples. Bromide concentrations exceeded the detection limit (0.10 milligrams per liter) in water from 28 of the 106 wells (26 percent) sampled in 1992. The maximum concentration was 0.56 milligrams per liter. There were no relations between bromide and major dissolved constituents, well depth, or aquifer tapped that would be useful for determining bromide concentrations. Areal patterns of bromide occurrence are not clearly defined, but areas with relatively high bromide concentrations tend to be located in a triangular area near the community of Sunbeam, Florida, and along the St. Johns River throughout Duval County.

Florida

Pesticide occurrence in shallow groundwater in three regions of agricultural land use: Baldwin County, the Wiregrass region, and the Tennessee River valley region of Alabama, 2009–20

As part of a cooperative investigation between the U.S. Geological Survey and the Alabama Department of Agriculture and Industries, a network of 22 groundwater wells were sampled from 2014 through 2020 for about 230 pesticide and pesticide degradate compounds. Wells were located in three regions of intensive agricultural land use in Alabama: Baldwin County, the Wiregrass region, and the Tennessee River valley region. Metolachlor sulfonic acid, a degradate of the herbicide metolachlor, was the most frequently detected compound, occurring in about 70 percent of the samples. Three other compounds, metolachlor, atrazine, and 2-chloro-4-isopropylamino-6-amino-s-triazine, were also detected in more than half of the samples. Metolachlor and its degradates accounted for 33 of the 50 greatest compound concentrations study-wide, including the maximum pesticide concentration across all compounds (62,500 nanograms per liter). The frequency and magnitude of detections of many specific pesticide compounds varied among the three regions, but all detected pesticide concentrations were well below the U.S. Environmental Protection Agency maximum contaminant levels and applicable human health benchmarks. Sample results were combined with results of previous (2009–13) sampling to provide a continuous time-series of data for 2009–20. More than half of the 289 pesticide compounds analyzed during 2009–20 were not detected in any samples. Only four compounds were detected at great enough frequency throughout the 10 sampling years to evaluate patterns of change through time. Metolachlor and its degradate, metolachlor sulfonic acid, were frequently detected in all regions. Atrazine and its degradate, 2-chloro-4-isopropylamino-6-amino-s-triazine, were also detected in wells from all regions, but the variability and magnitude of concentrations were greatest in the Tennessee River valley region. No apparent temporal pattern in concentrations was found.

Alabama

Peri-Gondwanan sediment in the Arkoma Basin derived from the north: The detrital zircon record of a uniquely concentrated non-Laurentian source signal in the late Paleozoic

During the assembly of Pangea, peri-Gondwanan terranes collided with the eastern and southern margins of Laurentia and brought with them unique detrital zircon U-Pb signatures. Discriminating between individual peri-Gondwanan terranes in the detrital record is difficult due to their similar geologic histories. However, characterization of this provenance is critical for understanding late Paleozoic sediment routing during development of Pangea. Along southeastern Laurentia, in the Arkoma Basin (present-day Arkansas and eastern Oklahoma, southeastern United States), we identified Middle Pennsylvanian (Desmoinesian) strata that exhibit a concentrated peri-Gondwanan detrital zircon signature (e.g., ca. 800–550 Ma). Although several southern peri-Gondwanan terranes (e.g., Maya, Suwannee) are closer to the Arkoma Basin, geologic data, such as predominantly north-to-south paleocurrents and proximal-to-distal facies relationships in these Desmoinesian strata, support a northern source (e.g., Ganderia, Avalonia, Meguma). Further evidence of a northern source comes from detrital zircon source mapping, which reveals the persistence of this peri-Gondwanan signal in depocenters to the north of the basin after the signal had diminished in the Arkoma Basin. To this end, bottom-up detrital zircon source modeling, source mapping, regional stratigraphy, paleocurrent data, and sandstone petrography allow us to reconstruct the evolution of this Middle Pennsylvanian (Desmoinesian) sediment pathway in the context of intraplate and plate-margin tectonic activity. This reconstruction documents processes affecting Earth’s surface (e.g., tectonics, climate) during the assembly of Pangea and describes in detail part of a dynamic continental-scale drainage system.

Geosphere

Floods of February 1989 in Tennessee

Rainfall amounts of over 5 inches the night of February 13 and the morning of February 14, 1989, caused flooding in areas of Middle and West Tennessee. The towns of Lebanon in Middle Tennessee and Obion in West Tennessee were most severely affected. Most of the business district in Lebanon and many residential areas in Obion were flooded. Recurrence intervals for 24-hour rainfall totals were as high as 25 years at some sites but most peak discharges had recurrence intervals of less than 10 years. Rainfall amounts for the period February 13-20, 1989, peak stages and discharges for this flood, the peak of record, and a list of discharge measurements made during the flood are documented in this report.

Tennessee

Status of water-level altitudes and long-term and short-term water-level changes in the Chicot and Evangeline (undifferentiated) and Jasper aquifers, greater Houston area, Texas, 2024

Since the early 1900s, groundwater withdrawn from the primary aquifers that compose the Gulf Coast aquifer system—the Chicot, Evangeline, and Jasper aquifers—has been an important source of water in the greater Houston area, Texas. This report, prepared by the U.S. Geological Survey in cooperation with the Harris-Galveston Subsidence District, City of Houston, Fort Bend Subsidence District, Lone Star Groundwater Conservation District, and Brazoria County Groundwater Conservation District, is one in an annual series of reports depicting the status of water-level altitudes and water-level changes in these aquifers in the greater Houston area. In this report, the Chicot and Evangeline aquifers are treated as a single aquifer for the purposes of providing annual assessments of regional-scale water-level altitudes and water-level changes over time. In 2024, shaded depictions of estimated water-level altitudes for the Chicot and Evangeline aquifers (undifferentiated) ranged from about 301 feet (ft) below the North American Vertical Datum of 1988 (NAVD 88) to about 184 ft above NAVD 88. The largest decline in water-level altitudes depicted by the 1977–2024 long-term water-level-change map was in south-central Montgomery County. In comparison, the 1990–2024 long-term water-level-change map depicts the largest declines in water-level altitudes in an area northwest of The Woodlands and in an area of northern Waller County. The largest rise in water-level altitudes for 1977–2024 is depicted in an area of east-central Harris County, whereas the largest rise in water-level altitudes for 1990–2024 is depicted in an area of central Harris County. The 5-year short-term water-level-change map depicts the largest declines in several parts of the study area, but these declines are concentrated primarily in northern Fort Bend County, southwestern Harris County, and south-central Montgomery County. The largest rise for 2019–24 is depicted at a well in northern Fort Bend County. The 1-year short-term water-level-change map depicts the largest declines at a well in northern Fort Bend County and a well in west-central Harris County. The largest rise for 2023–24 is depicted at a well in east-central Fort Bend County. In 2024, shaded depictions of estimated water-level altitudes for the Jasper aquifer ranged from about 255 ft below NAVD 88 to about 321 ft above NAVD 88. The 2000–24 long-term water-level-change map depicts the largest water-level decline in an area of central San Jacinto County; the largest rise is depicted in an area of central Grimes County. The 5-year short-term water-level-change map depicts the largest declines across parts of central and southern Montgomery County and at one well in north-central Harris County. The largest rise for 2019–24 is depicted at a well centered on the Montgomery-Grimes County line. The 1-year short-term water-level-change map depicts the largest declines at two wells in south-central Montgomery County and one well in northwestern Montgomery County on the west side of Lake Conroe. The largest rises during 2023–24 are depicted at one well in northwestern Montgomery County and one well in south-central Montgomery County.

Texas

Lithium resource in the Smackover Formation brines of Southern Arkansas

Lithium-rich brine deposits occur throughout the United States, including in the Smackover Formation. The concentration of lithium in Smackover Formation brines was predicted across southern Arkansas by using a machine-learning model that incorporated lithium concentration data and geologic information. Between 5.1 and 19.0 million metric tons of lithium are calculated to be present in the brines of the Smackover Formation in southern Arkansas. The range in possible total lithium reflects the uncertainty in machine-learning predictions of lithium concentrations and the range of Smackover Formation porosity. This estimate quantifies the in-place lithium resource and does not consider the technological and economic feasibility of extracting the lithium from the brines.

Arkansas

Decadal trends in the quality of groundwater used for public drinking-water supply in California, 2004–2023, California groundwater ambient monitoring and assessment program, priority basin project

This study provides a comprehensive assessment of decadal changes in the quality of groundwater used for public drinking-water supply at 444 monitoring sites across California during 2004–2023. We assessed decadal step trends in groundwater quality for 145 water-quality constituents and geochemical indicators statewide and across geographic and land-use based network groups. We evaluated the statistical significance of directional changes (predominant increase or decrease of constituent concentrations) and the magnitude of those changes across all network groups. Uranium showed the most widespread directional and high-magnitude increases of all constituents with regulatory benchmarks statewide, particularly in the agriculture-dominated Central Valley as well as urban- and desert-dominated regions of Southern California. Fluoride and perchlorate showed the most widespread directional and high-magnitude decreases of all constituents with regulatory benchmarks statewide, which were also most pronounced in Southern California. Although arsenic and nitrate did not often register significant directional changes across network groups, they showed widespread, high-magnitude changes in both directions (increase and decrease) at levels often exceeding 10 percent of respective regulatory benchmarks statewide. Triazine herbicides (atrazine and simazine) and the gasoline oxygenate methyl tert-butyl ether (MTBE) showed significant directional decreases statewide, but not at levels considered to be of high magnitude compared to respective regulatory benchmarks. We observed significant directional and high-magnitude increases of total dissolved solids (TDS) statewide, which were most pronounced in agricultural areas. Analysis of explanatory geochemical indicators indicated that prevalent statewide increases of alkalinity and calcium were the predominant components of the observed statewide increases in TDS by mass. Widespread increases in groundwater alkalinity and calcium across agricultural and urban areas may be related, in part, to warm-season irrigation and other anthropogenic factors that have shifted soil weathering dynamics over the long term. Increasing alkalinity concentrations were related to increasing uranium concentrations, particularly in areas with aquifer materials derived from granitic rocks. Conversely, increasing calcium concentrations were related to decreasing fluoride concentrations, particularly in areas where fluoride occurred naturally at elevated concentrations. Decrease of perchlorate, triazine herbicides, and MTBE are likely related to decreased anthropogenic source inputs over time and natural attenuation in aquifers.

EarthArXiv

Peak streamflow trends and their relation to changes in climate in Illinois, Iowa, Michigan, Minnesota, Missouri, Montana, North Dakota, South Dakota, and Wisconsin

Flood-frequency analysis, also called peak-flow frequency or flood-flow frequency analysis, is essential to water resources management applications including critical structure design and floodplain mapping. Federal guidelines for doing flood-frequency analyses are presented in a U.S. Geological Survey Techniques and Methods report known as Bulletin 17C. A basic assumption within Bulletin 17C is that for drainage basins without major hydrologic alterations, statistical properties of the distribution of annual peak streamflows (peak flows) are stationary; that is, the mean, variance, and skew are constant. The stationarity assumption has been widely accepted within the flood-frequency community; however, a better understanding of long-term climatic persistence and concerns about potential climate change and land-use change has caused a reexamination of the stationarity assumption. This work is part of that reexamination. The stationarity assumption is a concern because flood-frequency analyses that do not incorporate observed trends and abrupt changes may result in a poor representation of the true flood risk. Bulletin 17C does not offer guidance for incorporating nonstationarities when estimating floods, and it describes a need for studies that incorporate changing climate or basin characteristics. In response to this need and a history of concern regarding nonstationarity peak flows in the region, this study was done to assess potential nonstationarity in peak flows in the north-central United States. This report summarizes the methods used to detect hydroclimatic changes in peak-flow data in the study region. Four periods were selected for analysis of peak flow, daily streamflow, and climate data. The periods are (1) a 100-year period, 1921–2020; (2) a 75-year period, 1946–2020; (3) a 50-year period, 1971–2020; and (4) a 30-year period, 1991–2020. The starting point for these analyses was the initial data analysis of peak flow described in Bulletin 17C, which includes plotting the peak flow and checking for autocorrelation, monotonic trends, and changes points. Analyses were added to examine additional features in the data. Results are provided in a U.S. Geological Survey data release. The study limitations are documented for users of the results.

Scientific Investigations Report

Decadal trends in the quality of groundwater used for public drinking-water supply in California, 2004–23, California Groundwater Ambient Monitoring and Assessment Program, Priority Basin Project

This study provides a comprehensive assessment of decadal changes in the quality of groundwater used for public drinking-water supply at 444 monitoring sites across California during 2004–23. We assessed decadal step trends in groundwater quality for 145 water-quality constituents and geochemical indicators statewide and across geographic and land-use based network groups. We evaluated the statistical significance of directional changes (predominant increase or decrease of constituent concentrations) and the magnitude of those changes across all network groups. Uranium showed the most widespread directional and high-magnitude increases of all constituents with regulatory benchmarks statewide, particularly in the agriculture-dominated Central Valley as well as urban-and desert-dominated regions of Southern California. Fluoride and perchlorate showed the most widespread directional and high-magnitude decreases of all constituents with regulatory benchmarks statewide, which were also most pronounced in Southern California. Although arsenic and nitrate did not often register significant directional changes across network groups, they showed widespread, high-magnitude changes in both directions (increase and decrease) at levels often exceeding 10 percent of respective regulatory benchmarks statewide. Triazine herbicides (atrazine and simazine) and the gasoline oxygenate methyl tert -butyl ether showed significant directional decreases statewide, but not at levels considered to be of high magnitude compared to respective regulatory benchmarks. We observed significant directional and high-magnitude increases of total dissolved solids statewide, which were most pronounced in agricultural areas. Analysis of explanatory geochemical indicators indicated that prevalent statewide increases of alkalinity and calcium were the predominant components of the observed statewide increases in total dissolved solids by mass. Widespread increases in groundwater alkalinity and calcium across agricultural and urban areas may be related, in part, to warm-season irrigation and other anthropogenic factors that have shifted soil weathering dynamics over the long term. Increasing alkalinity concentrations were related to increasing uranium concentrations, particularly in areas with aquifer materials derived from granitic rocks. Conversely, increasing calcium concentrations were related to decreasing fluoride concentrations, particularly in areas where fluoride occurred naturally at elevated concentrations. Decrease of perchlorate, triazine herbicides, and methyl tert -butyl ether are likely related to decreased anthropogenic source inputs over time and natural attenuation in aquifers.

California

Resurvey of the Marble Canyon and Bridge Canyon dam sites in Grand Canyon National Park—Changes in sediment storage and evidence supporting the occurrence of bedrock incision through the mid-20th century

The Bureau of Reclamation developed an extensive plan for a network of dams, water tunnels, and hydropower plants in and around Grand Canyon, Arizona, in the 1940s through 1960s. The two largest of these planned dams were the Marble Canyon and Bridge Canyon Dams on the Colorado River. Though these dams were ultimately never built, Reclamation conducted extensive topographic, bathymetric, and subsurface exploration work at the sites proposed for these dams in the 1940s and 1950s. Resurveys of these dam sites were conducted between 1998 and 2021 to determine the changes in sediment storage at these dam sites caused by the upstream construction and operation of Glen Canyon Dam and by the recession of Lake Mead, the reservoir impounded by Hoover Dam. The resurveys of the Marble Canyon dam sites indicate that the post-1950s changes in sediment storage at these dam sites are broadly consistent with flux-based estimates of voluminous sand erosion from Marble Canyon since the 1963 closure of Glen Canyon Dam. These resurveys also suggest that the pre-dam longitudinal variation in sediment thickness over bedrock played a key role in determining the locations of the sand erosion induced by Glen Canyon Dam; more sand eroded from locations where more sand was present in the 1950s. The resurvey of the Bridge Canyon dam sites indicates that the Colorado River’s incision of the Lake Mead delta is regulated both by bed-sediment grain size and downstream hydraulic controls. Finally, analyses of bed-sediment thickness and sedimentological data at the dam sites, and observations of bed scour and gravel transport, suggest that sufficient bedrock was exposed to allow bedrock incision during commonly recurring pre-dam snowmelt floods that entrained small boulders into transport.

Arizona

Site response in the Walnut Creek–Concord region of the San Francisco Bay, California: Ground motion amplification in a fault-bounded basin

Thirty‐seven portable accelerometers were deployed in the eastern San Francisco Bay communities of Walnut Creek and Concord to study site response in a fault‐bounded, urban, sedimentary basin. Local earthquakes were recorded for a period of two years from 2017 to 2019 resulting in 101 well‐recorded events. Site response is estimated by two methods: the reference site spectral ratio method and a source‐site spectral inversion method. The reference site spectral ratio method allows investigation of the variability of site amplification with source azimuth and frequency. The source‐site spectral inversion method yields the best least‐squares fit to site response for a database of ground‐motion records. Both methods show substantial amplification in the Walnut Creek–Concord basin below 2 Hz indicating strong surface‐wave development. Greater amplification is seen for sources aligned along the long axis of the basin. Inversion using close‐in sources at short distances yields lower amplification at longer periods than the entire data set due to reduced surface‐wave generation for steeper angles of incidence. Inversion of site response spectra for shallow shear‐wave velocity using a global search algorithm yields V S30 values consistent with generalized mapping results based on geology and topography but with greater variability due to local site variations. 3D finite‐element modeling shows greater amplification in the Walnut Creek–Concord basin with a basin‐edge effect likely contributing to higher ground motions. Topography is also seen to lead to increased scattering and shadowing effects.

California

Smectite-rich horizons in Inceptisols trigger shallow landslides in tropical granitic terranes

Puerto Rico was affected by >70,000 landslides in the wake of 2017 Hurricane Maria, and landslide prevalence was especially high in the Utuado region in the Cordillera Central. Landslide density was highest where soil parent material is granodiorite; landslide slip surfaces tended to be shallow (<60 cm), and often were mobilized rapidly and with long runout distances. This study combines field observations with soil mineralogy (bulk and clay fractions), soil geochemistry (bulk fraction), and soil strength as determined by field cone penetrometer testing (CPT) to test the hypothesis that clay-rich subsoil horizons function as slip planes when water-logged. Soil pits were excavated to depths of ∼200 cm in Ultisols on an undulating plateau and to ∼100 cm in Inceptisols on steep slopes (36-43 o ) that flank the plateau and cone penetrometer tests (CPT) were done within 2 m of the soil pit. Six pits were located adjacent to scarps from previous landslides, enabling analysis of soil profiles downward through extrapolated slip surfaces. Results from X-ray diffraction (XRD), X-ray fluorescence (XRF) and thermogravimetric analysis (TGA) indicate that soils are heterogeneous, often with subsoil horizons enriched in clay minerals and immobile elements (Al, Fe, Ti). Inceptisols on steep slopes often contain smectite-rich horizons at 30–60 cm depth that appear to function as slip surfaces; in other Inceptisols, such horizons are not present and landslide susceptibility is potentially lower. In Ultisols, soil mineralogy is dominated by kaolinite with minor halloysite, and increased kaolinite content at soil depths ≥80 cm at some sites suggests potential slip surfaces enhancing probability of landslides. The origin of clay-rich horizons appears to be (1) fractures in granodiorite that facilitate water flow and leaching, accelerating mineral dissolution during early weathering stages, and (2) smectite-rich buried soils under permeable colluvium likely deposited by a prior mass wasting event. Where clay-rich layers occur beneath more-permeable horizons, rapid infiltration then absorption of water in clay-rich subsoil horizons causes decreased shear strength and increased landslide susceptibility.

Puerto Rico

Ductile and brittle Rio Grande Rift deformation in Oligocene granite records a two-stage rift history in southern Colorado

The timing and nature of early deformation in the Rio Grande Rift remains poorly constrained. We present evidence for the earliest structural signature of rift extension in the Sangre de Cristo Range, southern Colorado, based on new geologic mapping, structural analysis, rock magnetic data, and thermochronology. These analyses focus on the ~30.0 Ma granite of Chokecherry Canyon, which hosts discrete low-angle mylonitic shear zones and a distributed, gently SW-dipping protomylonitic fabric. Incremental stretching axes, stretching lineations, and Kmax magnetic lineations plunge gently WSW. Quartz microstructures and crystallographic orientations indicate dominantly coaxial strain in the protomylonite and general shear in the discrete shear zones. Quartz c-axis opening-angle thermometry suggests deformation at ~420–540°C. Thermal modeling of ⁴⁰Ar/³⁹Ar K-feldspar data indicates rapid post magmatic cooling below the brittle–plastic transition, supporting shear-zone formation immediately after emplacement. Slow cooling from ~20–13 Ma was followed by renewed rapid cooling at ~13 Ma, interpreted as the onset of extensional exhumation along the Sangre de Cristo Fault System. These results show that extension in the northern Rio Grande Rift was active by ~30 Ma, earlier than previously recognized. We propose a two-stage model for northern Rio Grande Rift evolution: Stage I (30–23 Ma) records ENE–WSW extension localized in low-angle mylonitic shear zones associated with mid-crustal intrusions; Stage II (≤18 Ma) reflects brittle high-angle normal faulting, focused exhumation, and rift narrowing. Stage I magmatism and deformation along the western range front likely established crustal weaknesses that guided later fault development.

Colorado