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Evaluating groundwater quality influences from oil field operations and other anthropogenic activities in an urban setting, Santa Fe Springs, California

Groundwater quality is often affected by anthropogenic activities in urban settings. This study examines groundwater quality in and around the Santa Fe Springs Oil Field in Los Angeles County, California, where oil and gas production commonly intersects with high density industrial, commercial and residential land uses. Utilizing a combination of new and historical data, we evaluated potential pathways that would allow for oil field formation fluids to migrate into groundwater and whether mixing may have occurred based on the distribution of groundwater and oil field formation fluid tracers in samples. Samples were analyzed for a wide array of constituents including volatile organic compounds, light hydrocarbons, major ions, and various isotopic compositions. Despite evidence of oil field infrastructure providing potential pathways of migration via uncemented annular spaces, casing breaches and historical disposal of oil field formation water in surface ponds, the distribution and occurrence of stable isotopes of water, chloride, boron, and total dissolved solids do not indicate mixing of oil field formation water and groundwater. However, methane isotopic signatures and the presence of heavier alkanes suggest gas from oil-bearing formations have migrated from depth via oil field well infrastructure. Volatile organic compound detections were mainly from manufactured compounds unrelated to oil and gas production, with a relatively limited number of petroleum hydrocarbons also detected. Volatile organic compounds were generally found in wells tapping shallow, modern aged groundwater, indicating anthropogenic activities occurring at or near land surface as the source. Study results suggest that while oil field infrastructure provides migration pathways for oil field formation fluids to be introduced into groundwater, urban land uses not related to oil and gas production are the primary drivers of groundwater quality degradation.

California

Channel morphology and large wood control postfire debris-flow erosion and deposition

Runoff-generated debris flows are a known response to wildfire, and accurately predicting the volume of these debris flows is important for estimating the magnitude of downstream hazards. Prior data collection efforts have focused on debris-flow volume measurements at catchment outlets, but few studies have considered how erosion and deposition modulate the volume of sediment arriving at catchment outlets. This study takes advantage of a high-resolution dataset to document the factors that control the total debris-flow volume reaching the catchment outlet during a fatal postfire debris flow. Using pre- and post-event airborne lidar, satellite imagery and field mapping, we found that a postfire debris flow in the Black Hollow catchment in northern Colorado eroded 136,000 ± 30,000 m 3 and redeposited 27,000 ± 7,500 m 3 in the main channel. Most of the in-channel deposition (52% by volume) occurred where a confined channel reach transitioned to an unconfined channel reach downstream, allowing the flow to widen and deposit material. Wood jams played multiple roles in the debris-flow dynamics, both nucleating deposition (25% of the deposit volume was stored behind wood jams) and exacerbating erosion (50% of the total erosion occurred downstream from a wood dam break). The remaining deposition occurred due to spatial changes in channel slope as well as deposition observed at newly formed channel bars. Using these data in this study, we identified topographic and vegetation metrics that can be used (pre-event) to anticipate where deposition may occur in channels prior to a debris flow.

Colorado

Assessing nonpoint-source uranium pollution in an irrigated stream-aquifer system

Uranium (U) in rocks and soils of arid and semi-arid environments can be mobilized by irrigation and fertilization, posing environmental and health risks. Elevated U, along with selenium (Se) and nitrate (NO 3 ) co-constituents, necessitates careful monitoring and management. We developed a distributed-parameter numerical model to assess U pollution in an irrigated stream-aquifer system, applying it to a 552 km 2 region in Colorado's Lower Arkansas River Valley (LARV) over 14 years. A MODFLOW model, describing groundwater and stream flow, was coupled with an RT3D-OTIS model to portray reactive U transport. Calibration using the PESTPP-iES iterative ensemble smoother (iES) software indicated good agreement with observed U concentrations. The model revealed substantial and variable U levels across the LARV, highlighting potential hotspots and possible contributing factors, such as geological composition of the bedrock and near-surface shale and aquifer sediments derived from them, irrigation practices, and riparian landscape. U levels exceed the chronic standard (85th percentile = 30 μg/L, set by the US Environmental Protection Agency), which is the permissible regulatory threshold, in groundwater across 44 % of the region and along the river by an average factor of 2.9. Simulated average U concentrations in the non-riparian aquifer and river are 124 μg/L and 60 μg/L, respectively, compared with 112 μg/L and 62 μg/L for measured values. The average 85th percentile U concentration is 222 μg/L in the aquifer and 82 μg/L in the river. Average simulated U mass loading to the river is 0.17 kg/day per km, compared to an estimated 0.23 kg/day per km. Findings provide a baseline for comparing future simulated outcomes of alternative best management practices (BMPs) for U pollution mitigation and offer a methodology applicable to other irrigated regions.

Colorado

Interplay between tectonics and submarine mass transport deposits in Cortes Basin: New high-resolution geophysics in the Outer California Borderland

The Outer California Borderland (OCB) is an active transform plate boundary offshore Southern California, where the relationship between faulting and submarine mass transport deposits (MTDs) remains poorly understood. Onshore paleoseismic data provide high-resolution earthquake records, whereas marine geophysical data capture longer-term histories. Offshore fault systems pose hazards to infrastructure and dense coastal populations, particularly when linked to submarine landslides. We present new high-resolution geophysical data set (cruise SR2303), including bathymetric and CHIRP sub-bottom data integrated with legacy seismic reflection data and chronostratigraphic constraints from ODP Site 1012 to examine Quaternary MTD recurrence and tectonic controls in the Cortes Basin, OCB. Bathymetry shows deformational features, including slide scarps and previously unmapped fault segments with evidence of Holocene activity. CHIRP profiles reveal 10 stacked MTDs in the East Cortes Basin and 8 in the West Cortes Basin, spanning ∼752 ka with an average recurrence of ∼83.6 ± 1 ka. Acoustic imaging shows 7 MTD intervals coinciding with fault offset increments and fault growth suggesting earthquake-triggered mass wasting. A strong association between MTD occurrences and sea-level extremes also supports glacio-eustatic contribution to slope failure. Stratigraphic correlations suggest quasi-synchronous MTDs across the eastern and western areas, likely triggered by larger eathquakes in the Quaternary. Although the identified MTDs occur relatively far from the Southern California coast, they still pose a potential tsunamigenic hazard requiring further assessment. Moreover, if linked to earthquakes along major strike-slip faults, for example, the Ferrelo fault, the MTDs may provide valuable proxies to constrain rupture scenarios and fault connectivity within the understudied OCB.

California

Rainfall thresholds for postfire debris-flow initiation vary with short-duration rainfall climatology

The size, frequency, and geographic scope of severe wildfires are expanding across the globe, including in the Western United States. Recently burned steeplands have an increased likelihood of debris flows, which pose hazards to downstream communities. The conditions for postfire debris-flow initiation are commonly expressed as rainfall intensity-duration thresholds, which can be estimated given sufficient observational history. However, the spread of wildfire across diverse climates poses a challenge for accurate threshold prediction in areas with limited observations. Studies of mass-movement processes in unburned areas indicate that thresholds vary with local climate, such that higher rainfall rates are required for initiation in climates characterized by frequent intense rainfall. Here, we use three independent methods to test whether initiation of postfire runoff-generated debris flows across the Western United States varies similarly with climate. Through the compilation of observed thresholds at various fires, analysis of the spatial density of observed debris flows, and quantification of feature importance at different spatial scales, we show that postfire debris-flow initiation thresholds vary systematically with short-duration rainfall-intensity climatology. The predictive power of climatological data sets that are readily available before a fire occurs offers a much-needed tool for hazard management in regions that are facing increased wildfire activity, have sparse observational history, and/or have limited resources for field-based hazard assessment. Furthermore, if the observed variation in thresholds reflects long-term adjustment of the landscape to local climate, rapid shifts in rainfall intensity related to climate change will likely induce spatially variable shifts in postfire debris-flow likelihood.

Arizona, California, Colorado, Nevada, New Mexico,

Produced water geochemistry from hydraulically stimulated Niobrara Formation petroleum wells: Origin of salinity and temporal perspectives on treatment and reuse

Produced water (i.e., a mixture of returned injection fluids and geologic formation brines) represents the largest volumetric waste stream associated with petroleum production in the United States. As such, produced water has been the focus of intense study with emphasis on understanding the geologic origin of the fluids, environmental impacts of unintended or intentional release, disposal concerns, and their commodity (e.g., lithium) potential. However, produced water geochemistry from many active petroleum plays remain poorly constrained leading to knowledge gaps associated with the origin of brine salinity and parameters (e.g., radium levels) that can impact treatment, disposal, and possible reuse. Here we evaluate the major ion geochemistry, radium concentrations, and stable water isotope composition of ~120 produced water samples collected from 17 producing unconventional petroleum wells in Weld County, Colorado from the Late Cretaceous Niobrara Formation. This sample set encompasses eight produced water time series from four new wells across production days 0 to ~365 and from four established wells across production days ~1000 to ~1700. Additionally, produced water from nine other established Niobrara Formation wells were sampled at discrete time points ranging from day 458 to day 2256, as well as hydraulic fracturing input fluids. These results expand the available Niobrara Formation produced water geochemical data, previously limited to few wells sampled within the first year of production, allowing for the heterogeneity of major ions and radium to be evaluated. Furthermore, we explore the geochemical relationships between major ion ratios and stable water isotope composition to understand the origin of salinity in Niobrara Formation brines from the Denver-Julesburg Basin. These findings are discussed with perspective toward potential treatment and reuse of Niobrara produced water prior to disposal.

Colorado, Nebraska, Wyoming

Intense alteration on early Mars revealed by high-aluminum rocks at Jezero Crater

The NASA Perseverance rover discovered light-toned float rocks scattered across the surface of Jezero crater that are particularly rich in alumina ( ~ 35 wt% Al 2 O 3 ) and depleted in other major elements (except silica). These unique float rocks have heterogeneous mineralogy ranging from kaolinite/halloysite-bearing in hydrated samples, to spinel-bearing in dehydrated samples also containing a dehydrated Al-rich phase. Here we describe SuperCam and Mastcam-Z observations of the float rocks, including the first in situ identification of kaolinite or halloysite on another planet, and dehydrated phases including spinel and apparent partially dehydroxylated kaolinite. The presence of spinel in these samples is likely detrital in origin, surviving kaolinitization, pointing to an ultramafic origin. However, the association of low hydration with increased Al 2 O 3 abundances suggests heating-induced dehydration which could have occurred during the lithification or impact excavation of these rocks. Given the orbital context of kaolinite-bearing megabreccia in the Jezero crater rim, we propose an origin for these rocks involving intense aqueous alteration of the parent material, followed by dehydration/lithification potentially through impact processes, and dispersion into Jezero crater through flood or impact-related processes.

Communications Earth & Environment

To heal or not to heal?: 2. The moment-recurrence time behavior of repeating earthquakes in the 2011 Prague, Oklahoma aftershock sequence is consistent with laboratory healing rates

The timing and failure conditions of an earthquake are governed by the interplay between fault reloading and restrengthening. The moment-recurrence time behavior of repeating earthquakes can give observational estimates of fault healing rates; however, it is difficult to link these observed healing rates to laboratory studies of frictional healing in part because of uncertainty in lithology. Here, we study the 2011 Prague earthquake sequence, which includes repeating earthquakes in the Arbuckle group and the granitic basement, and compare them to laboratory experiments on samples of the Arbuckle and Troy granite (representative of the basement rock) (Okamoto et al., 2025, https://doi.org/10.1029/2024JB030573 ). We find three spatially distinct groups of repeating earthquakes with different moment-recurrence behavior: (a) constant moment-recurrence time in the Arbuckle group, (b) scattered moment-recurrence time at the intersection of the foreshock-mainshock fault in the granitic basement, and (c) moment-predictable behavior outside of the foreshock-mainshock fault intersection also in the granitic basement. Our observation of stagnant healing for repeating sequences in the Arbuckle group is consistent with laboratory observations of low healing rates for moderately high pore fluid pressures in Arbuckle samples. For the moment-predictable group, the source radius that is required in order to match healing rates is consistent with source radius estimations when taking into account reasonable attenuation of the P- pulse width. Overall, we observe diverse healing behaviors in the seismic families that are consistent with laboratory healing rates, providing seismic evidence that contact-scale frictional mechanisms are relevant to large-scale earthquake dynamics.

Oklahoma

Potentially toxic elements in wild Agassiz’s desert tortoises: Tissue concentrations and association with disease

Background: Desert tortoise ( Gopherus agassizii ) populations have continued to decline due to infectious and other diseases, predation, and habitat alteration. The potential contribution of minerals and heavy metals to tortoise health and susceptibility to disease remains uncertain. Objective: The objective of this study was to evaluate the results of elemental analysis of trace minerals and macrominerals in scute keratin, kidney, and liver tissue from ill and dying desert tortoises salvaged for necropsy between 1993 and 2000. Methods: Salvaged tortoises were categorized by age (adult, juvenile), geographic location, and primary disease based on necropsy findings. A subset of tortoises that were injured or killed by vehicular trauma or predation but with no notable pathologic abnormalities were used as controls. A panel of 21 trace minerals and 6 macrominerals was analyzed in scute keratin, kidney, and liver tissue samples by inductively-coupled plasma spectrometry and atomic absorption spectrophotometry. Results: Necropsies were done on 46 tortoises, including 9 juveniles salvaged from 5 regions in the Colorado and Mojave deserts of California. Primary diseases were cutaneous dyskeratosis (n=9), infection/ inflammation (n=8), malnutrition (n=7), mycoplasmosis (n=5), and urolithiasis (n=3); 14 tortoises were classified as controls. Concentrations of elements differed significantly by tissue, age, desert region, and disease (P < 0.05). Tortoises with cutaneous dyskeratosis had significantly higher Se concentrations, primarily in keratin and liver, than tortoises with other diseases (P < 0.001). Juveniles were more likely than adults to have high Pb, Sn, and Zn levels (P < 0.05). All tortoises had detectable levels of more than one potentially toxic heavy metal, including As, Cd, Cr, Hg, Ni, Pb, Sn and V. Conclusions: Potentially toxic elements are frequently found in tissue from tortoises in desert regions of California, with significantly higher concentrations in diseased tortoises. Metal exposure from soils, mining, historic and ongoing military activities, and other human activities could increase susceptibility to disease in desert tortoises.

California

New paleomagnetic constraints on the eruption timing, stratigraphy, and post-emplacement deformation of the Picture Gorge Basalt within the Columbia River Basalt Group

The Picture Gorge Basalt (PGB) is part of the Miocene Columbia River Basalt Group (CRBG). The PGB, which outcrops in eastern Oregon, is considered coincident in time with the voluminous Grande Ronde Basalt. New radiometric ages have expanded the age‐range of the PGB, suggesting it began erupting prior to the Steens Basalt to its south and continued until after cessation of the Grande Ronde Basalt eruptions, an interval of 1.5 Ma. However, the existing paleomagnetism of the PGB implies this eruption timeline is an overestimate. To reconcile the radiometric and paleomagnetic timescales for the PGB, we conducted a paleomagnetic study on sections of the PGB to construct a detailed, high‐quality magnetostratigraphy. Our data indicate the stratigraphically lowest lava flows in the PGB are of reversed polarity, revealing a new paleomagnetic transition with the PGB and a reversed (R)–normal (N)–reversed (R) sequence. This suggests one of two timeline possibilities for PGB volcanism: (a) eruptions began and during through CRBG polarity chrons R0–N0–R1, penecontemporaneous with Steens Basalt, or (b) eruptions began and persisted during CRBG polarity chrons R1–N1–R2. Our work supports a longer interval of PGB volcanism than was suggested by previous paleomagnetic data but is at odds with the suggestion that PGB eruptions lasted through the entire main CRBG. We favor a scenario wherein PGB eruptions begin with R0 and continue into the R1 paleomagnetic interval. The paleomagnetic results also record a ∼18° vertical‐axis rotation of east‐central Oregon after ∼16 Ma with respect to stable North America.

Oregon

Importance of fish in the diet of Adélie penguins across multiple life stages

Over recent decades, the Adélie penguin ( Pygoscelis adeliae ) population has grown across most of its range, the exception being the northern coast of the western Antarctic Peninsula (WAP). In the Ross Sea, the very large Cape Crozier colony grew to reach ~9% of the global population. Demographic factors driving the Cape Crozier trend have yet to be identified. However, low chick fledging mass - a negative influence in the northern WAP where the diet is mostly less-energy-dense krill - is not showing an effect in the Cape Crozier colony. Previously, we hypothesized that Cape Crozier fledglings, and post-breeding adults, must be finding sufficient higher-quality prey once free of the prey-depleted colony foraging area, with subsequent higher survival. Here we explore penguin diet within and outside the colony foraging area using stable isotope analysis (SIA) of feathers: those grown by post-breeding adults outside the foraging area, prior to moult, compared to those of near-fledged chicks raised on meals obtained within the foraging area. Second, we explore whether a major difference occurs between breeding and post-breeding diet of adults from a small, nearby colony (Cape Royds) that exploits a smaller, little-depleted preyscape. Finally, we compare the results to SIA analyses published by others to explore whether the pre-moult diet of Ross Island adults, mostly foraging within the north-eastern Ross Sea, compares with that of adults nesting in the southern WAP (Bellingshausen Sea coast). At the latter, populations are not decreasing, with diet containing an appreciable contribution of fish. The results confirmed that fish contributed greatly to chick diets at both Ross Island colonies (δ 15 N 10.6–11.4). Once adults were released from central-place foraging, SIA levels (δ 15 N 9.7–12.9) were similar to those of the southern WAP. Foraging on energy-dense fish in coastal Antarctic waters could be one reason Adélie penguins are among the most abundant and therefore most ecologically successful penguin species.

Antarctic Science

Cajon Pass and the southern San Andreas Fault System: Earthquake cycle stress accumulation and present-day loading

With over a century since the last major rupture affecting the wider Los Angeles region, tectonic stress has steadily built along the southern San Andreas and San Jacinto fault systems, raising concerns of an imminent large earthquake. Cajon Pass, located at the junction of these faults, represents a critical site for potential through-going ruptures in Southern California. We constructed new 4D earthquake cycle simulations using a 1000-year paleoseismic rupture history of the San Andreas Fault System (SAFS) to assess spatial and temporal variations in stress. A semi-analytic Fourier transform model was used to compute stress from 3D dislocations in an elastic plate overlying a Maxwell viscoelastic half-space, assuming a complete coseismic reset of resolved shear stress on ruptured elements. Results show highest stress accumulation north of Cajon Pass (∼1.8 MPa/100 years) due to greater slip rates, and lower rates south of Cajon Pass (∼1.0–1.5 MPa/100 years). By 2025, Coulomb stress is estimated at 2.8 MPa on the Mojave South (MOS) segment, 1.8 MPa on the North San Bernardino (NSB1) segment and 3.6 MPa on the San Jacinto Bernardino (SJB) segment. Segments accumulate stresses with characteristic ranges of pre-event stress interpreted as failure thresholds: 1.2–2.7 MPa for MOS, 0.4–1.6 MPa for NSB1, and 1.2–2.9 MPa for SJB. When the stress disparity between segments SJB and MOS narrows, the faults appear to rupture jointly, suggesting that stress levels may control how Cajon Pass acts as an earthquake gate. These results may inform seismic hazard assessments by linking stress evolution to fault interactions.

California

Waning greenhouse gas emissions from U.S. Federal lease coal production by the mid-21st century

This study presents estimates of future years (2024–2051) United States Federal lease coal production and the resulting greenhouse gas (GHG) emissions from the combustion, transport, and mining of that fuel. Results from the coal production estimate indicate a decline in production from Federal leases; with known production of 240 million short tons (mtn) in 2023 and a projected decline to 34.0 mtn by 2051, which represents a reduction to 14.2% of the 2023 value. In parallel with this projection, total GHG emissions are estimated to decrease from 402.2 million metric tons of carbon dioxide equivalent (MMT CO 2 eq.) in 2024 to 55.0 MMT CO 2 eq. in 2051, a decline to 13.7% of 2024 emissions estimates. The reductions in coal production and emissions are mainly the result of planned coal combustion power plant closures, with major projected closures in 2037 and 2048. However, GHG emissions estimates for future years can be uncertain as they rely heavily on coal production estimates from operators' public business plans and other publicly available resources. Forward looking plans of this type are subject to significant changes if economic and political factors deviate from current information. Results suggest that average GHG emissions over the time series breakout to 95% end point combustion, 3.7% transportation combustion emissions, and 1.3% fugitive emissions, although there is uncertainty associated with these figures. Uncertainty stemming from production projections, sector distributions, and emissions factors on the future emissions estimates increases with time, ranging from −28% to +48% within the 2024–2051 timeframe.

Alabama, Colorado, Montana, North Dakota, Utah, Wy

Numerical modeling of Late Pleistocene to Holocene earthquake-induced progressive rock slope damage in the paraglacial Serpentine valley, Prince William Sound, Alaska

Landslides in deglaciating fjords pose a potential tsunami threat to nearby communities; however, processes contributing to long-term progressive rock damage and landslide conditioning remain poorly constrained in paraglacial settings. Here, we analyse the role of earthquake-induced rock mass damage over late Pleistocene to Holocene time scales, as a conditioning factor for modern landslides, using distinct element numerical modelling to assess spatial and temporal patterns of fracture propagation influenced by varying glacier thickness. Conceptualised numerical models were parameterised by in situ rock mass, glacial and topographic conditions in Serpentine valley, located in Prince William Sound, Alaska, where several large landslides are actively developing along the western valley wall. Results show that although rigid glacier buttressing reduces co-seismic rock mass damage, it does not suppress it completely, and damage occurs both above and below the glacier surface elevation. We demonstrate that topography, and especially steep slopes with topographic convexity, as well as preexisting damage of joint networks and faults inherited from tectonic and exhumation induced stresses, exert primary control on the location of new co-seismic damage. Simulations representing a simplified deglaciation sequence over the past 25 ka, with a series of 10 evenly spaced earthquakes, generated rock mass damage patterns that qualitatively match in situ landslide structural and kinematic observations at one instability in Serpentine valley. Our conceptual study helps clarify the role of repeated seismicity over glacial timescales as a long-term conditioning process for paraglacial rock slope failure, highlighting spatial and temporal patterns of progressive damage accumulation, with outcomes relevant for modern landslide hazard assessment.

Alaska

Groundwater flowpath characteristics drive variability in per- and polyfluoroalkyl substances (PFAS) loading across a stream-wetland system

Groundwater-dependent ecosystems in areas with industrial land use are at risk of exposure to a PFAS chemicals. We investigated one such system with several known PFAS source areas, where high and low permeability sediments (glacial) coupled with groundwater-lake and groundwater/surface-water interactions created complex ‘source to seep’ dynamics. Using heat-tracing and chemical methods, numerous preferential groundwater discharge zones were identified and sampled across the upper Quashnet River stream-wetland system in Mashpee, MA, USA, downgradient of Joint Base Cape Cod (JBCC). Surface-water and groundwater samples were analyzed for 40 PFAS compounds between March and October 2022. Samples were collected from groundwater seeps identified as preferential discharge points (PDPs), wells upgradient of the stream-wetland system, contributing flow-through kettle lakes, and along Quashnet River surface-waters. PFAS from sampled waters contained perfluorinated carboxylates (PFPea, PFHxA, PFNA), perfluorinated sulfonates (PFBS, PFPeS, PFHxS, PFOS), fluorotelomer sulfonates (6:2, 8:2 FtS), and perfluoroalkyl sulfonamides (PFOSA). Samples from PDPs and wells had measured PFAS concentrations ranging from non-detect to 4677 ng/L ng/L (mean = 418 ng/L, std. = 709 ng/L), and a range of deuterium excess values (3.2 to 15.9 per mil) indicative of varying degrees of groundwater-lake interaction prior to groundwater flowpath emergence at PDPs. Correlations ( p < 0.01) between deuterium excess, %PFAS precursors, and terminal PFAS compounds highlighted potential precursor transformations associated with lake-groundwater exchange along flowpaths sourcing PDPs. However, some seepages had higher total PFAS concentrations (>1000 ng/L) than upgradient kettle lakes despite showing lake (evaporative) isotopic signatures, indicating the potential for groundwater flowpath convergence at wetland discharge zones and the influence of lakebed PFAS precursor reactions. Results from these synoptic surveys address gaps in the existing PFAS literature by demonstrating the importance of subsurface fate and transport on PFAS compound concentrations and mass loading in preferential groundwater discharge zones.

Massachusetts

Structural evolution and slip rate variations through time of the Puente-Hills blind-thrust fault beneath Los Angeles: Implications for seismic hazard and folding kinematics

Using seismic reflection profiles, historical well logging data, and luminescence and radiocarbon ages, we determine a Pleistocene-Holocene slip history for the central, Santa Fe Springs segment of the Puente Hills blind-thrust fault (PHT), a major seismogenic fault situated beneath the urbanized Los Angeles metropolitan region. We analyze the geometry of correlative stratigraphic units in the forelimb and backlimb of the overlying growth-fold, the Santa Fe Springs anticline, and determine the uplift of seven age-correlative markers. Uplift measurements are converted to thrust displacements on the underlying PHT using a structural method laid out by Don et al. (2022, https://doi.org/10.1785/0120220048 ) that accounts for the geometry of the fault. These data indicate that deep thrust displacement on the PHT is partially consumed updip in the creation of a hanging-wall fault-bend fold, with forelimb growth strata recording <80% of the slip documented within the backlimb. Chronological data from growth strata yield age constraints for folding and faulting on the underlying PHT, providing a detailed incremental slip history derived from both the forelimb and backlimb folding for seven discrete growth horizons, spanning the past 1.4 million years. The resulting six incremental slip rates demonstrate that fault slip has varied through time from the middle Pleistocene to the Holocene. Moreover, these results reveal synchronous acceleration of both the central, Santa Fe Springs and western, Los Angeles segments of the fault system since late Pleistocene time (after 200 ka) and slip rates of greater than 2 mm/yr on the downdip, backlimb, fault-ramp below the anticline.

California

The use of fluorite geochemistry and machine learning to identify critical mineral systems

Fluorite (CaF 2 ) is a potential pathfinder to critical mineral and rare earth element (REE) deposits but its application has been limited to a narrow range of mineralization types. I show that fluorite is a robust recorder of mineralization fertility by applying statistical and machine-learning methods to a new global fluorite geochemical database. Distinct median rare earth and trace element patterns are observed among deposit types and genetic environments. Fluorite associated with carbonatites and REE deposits are relatively enriched in Sr and have minimal Eu anomalies. These characteristics define new bivariate discrimination diagrams that correctly identify 78% of carbonatite-related fluorite and 88% of fluorite from REE deposits. Random forest classifiers were developed for a wide range of mineralization types and genetic settings. Trained solely on rare earth element patterns, these models achieve accuracies of 77–79%. Higher classification accuracies (up to 88–96%) are obtained when including elements such as Sr, highlighting the significance of trace elements for optimal fluorite classification. The recognition of diagnostic fluorite compositional fingerprints, particularly in REE-fertile systems, underscores its potential as a pathfinder and indicator for critical mineral exploration in F-bearing environments.

Mineralium Deposita

Repeated coral bleaching events have eroded reef accretion potential in the Florida Keys

Coral bleaching is now the primary driver of coral-reef degradation globally, threatening the persistence of coral-reef functions and the invaluable ecosystem services they support. The Florida Keys have been impacted by four severe, regional-scale coral-bleaching events, which occurred in 1997–1998, 2005, 2014–2015, and 2023. Our aim in this study was to quantify the effects of those thermal-stress events on the persistence of coral-reef structures. We leveraged long-term coral-reef monitoring data to quantify the impacts of coral bleaching on coral cover, carbonate production, and reef-accretion potential throughout the Florida Keys from 1996–2024. Our study indicates that coral bleaching drove significant declines of reef-building corals, which successively diminished regional-scale reef-accretion potential (from 1.65 ± 0.33 mm y -1 in 1996) and culminated with a regional-scale transition to net reef erosion (-0.12 ± 0.08 mm y -1 ) following the 2023 event. Coral bleaching was the primary driver of declining reef-building capacity, with the cumulative impacts of the four coral-bleaching events accounting for >75% of total declines since 1996. The 1997–1998 event alone drove ~50% of overall declines, largely due to losses of the shallow-water ecosystem engineer, Acropora palmata . More moderate impacts of thermal stress on regional reef-accretion potential in 2005 (6%) and 2014–2015 (9%) could lend some support to the hypothesis that the remaining corals were more thermally tolerant; however, the unprecedented thermal stress event in 2023 caused widespread coral-bleaching and bleaching-related mortality, and caused an additional 12% of the total decline in reef-accretion potential. Stony-coral tissue loss disease accounted for an additional 6% of the decline, with the remaining 19% unexplained. Coral bleaching has already dramatically reshaped the structure and function of coral reefs in the Florida Keys over the last three decades. With the high likelihood that thermal stress will accelerate moving forward, the persistence of Florida’s essential coral-reef functions and services is uncertain.

Florida