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At least 289 records · Page 16Linked to original sources
USGS2014

Specific yield determined from a Thiem's Pumping‐Test

The specific yield of a water-bearing formation is defined as the ratio of (1) the volume of water, which after being saturated, it will yield by gravity to (2) its own volume (O. E. Meinzer, Outline of ground-water hydrology, U.S. Geol. Sur. Water-Supply Paper 494, p. 28, 1923). It is a measure of the quantity of water that a formation will yield when it is drained by lowering of the water-table. The determination of the specific yield is essential in many quantitative ground-water investigations. In 1931 a pumping-test was made in the Platte River Valley, in Nebraska, to determine by Thiem's method the permeability of the water-bearing sand and gravel that underlie the Valley. This test, which constitutes a part of a cooperative investigation by the Conservation and Survey Department of the University of Nebraska and the United States Geological Survey, was briefly described in the 1932 Transactions of the American Geophysical Union (p. 393). The well was pumped continuously for 48 hours, and measurements of the discharge were made every 30 minutes. During the period of pumping and after pumping stopped about 5,000 measurements were made of the depths to the water-surfaces in 80 observation-wells, which were located on lines radiating from the pumped well to distances up to 1,200 feet. Instrumental levels were run to the measuring points on each of the wells so that the altitudes of the water-surfaces could be determined for any time. From the data obtained in this test the average coefficient of permeability was computed to be about 700. In the present paper a method is presented for determining the specific yield of the water-bearing material from the data collected in this test, and the results of the computations are given. This method for determining specific yield was suggested by Meinzer (O. E. Meinzer, Outline of methods for estimating ground-water supplies, U.S. Geol. Sur. water-Supply Paper 638-c, p. 136, 1932).

Eos, Transactions, American Geophysical Union↗
USGS1973

Porphyry copper deposits in Puerto Rico and their relation to arc-trench tectonics

The study of porphyry copper deposits in islands arcs provides an opportunity to observe closely the direct relationship between tectonics and ore deposition, and to avoid such complications as multiple orogenies and contamination of magmas that are common to deposits on continental margins. Puerto Rico has proved to be an ideal laboratory to make these observations. In the west central part of the island 240 million tons of .7 to .8 percent copper ore has been proved up in three deposits (Lutjen, 1971). Although deep saprolite covers most of the mineralized area, two marginal deposits, Helecho and Sapo Alegre, are partly exposed by deep stream valleys. The U. S. Geological Survey, in cooperation with the Puerto Rico Department of Natural Resources is in the middle of a five year geologic and geochemical study of copper deposits in the island. Drill core was made available through the courtesy of Kennecott Copper Corporation, American Metals Climax Corporation and the Puerto Rico Mining Commission. I wish to acknowledge the help of the Puerto Rico Laboratory of Geology for the chemical work, and Richard Marvin and J. Thomas Nash of the USGS for geochronologic and fluid inclusion data, respectively. This report will briefly describe the porphyry copper deposits of Puerto Rico and their tectonic-chronologic position in the development of the Greater Antilles. By extrapolation from this data it will be suggested that these deposits and several others are related to a process of subduction zone deactivation.

Open-File Report↗
USGS2026

Development of a hydrologic flow model of the Zuñi Salt Lake and surrounding areas, west-central New Mexico

The terminal Zuñi Salt Lake is in a maar in west-​central New Mexico and contains hypersaline water that has long been used by Native Americans for religious purposes and the collection of salt. The U.S. Geological Survey (USGS), in cooperation with the Zuni Tribe of the Zuni Reservation, New Mexico, and Bureau of Reclamation, developed the Zuñi Salt Lake hydrologic flow model to simulate the steady-state conditions of the lake and surrounding groundwater-flow system. The model is a tool that can be used to analyze the potential hydrologic responses to resource development in the region under different water-use scenarios, which can support negotiations that could help protect future use of the lake. The USGS modular hydrologic model, MODFLOW 6, was used to simulate the hydrologic system of the lake and surrounding areas. To define the layering of the model, a three-dimensional hydrogeologic framework was constructed, which included seven informal hydrogeologic units and the locations of faults that truncate and offset the units. Calibration of the model was performed using the iterative ensemble smoother included in a parameter estimation software suite (PEST++). The iterative ensemble smoother approach resulted in a posterior parameter ensemble of model realizations with parameter and simulated values that show similar success in matching observations. Groundwater flux to the Zuñi Salt Lake simulated by using the posterior parameter distribution ranged from 26 to 730 acre-feet per year with a mean, median, and standard deviation of 530, 570, and 170 acre-feet per year, respectively. The relative contribution of groundwater discharge to the lake was simulated using a particle-tracking model for MODFLOW (MODPATH) to be from, in order of decreasing contribution, the Mesaverde, Cenozoic, Mancos, and Dakota hydrogeologic units. Simulations of future conditions using the ensemble of models can provide an empirical estimate of forecast uncertainty without substantial additional analysis.

New Mexico↗
USGS2007

Influence of tectonic folding on rockfall susceptibility, American Fork Canyon, Utah, USA

We examine rockfall susceptibility of folded strata in the Sevier fold-thrust belt exposed in American Fork Canyon in north-central Utah. Large-scale geologic mapping, talus production data, rock-mass-quality measurements, and historical rockfall data indicate that rockfall susceptibility is correlated with limb dip and curvature of the folded, cliff-forming Mississippian limestones. On fold limbs, rockfall susceptibility increases as dip increases. This relation is controlled by several factors, including an increase in adverse dip conditions and apertures of discontinuities, and shearing by flexural slip during folding that has reduced the friction angles of discontinuities by smoothing surface asperities. Susceptibility is greater in fold hinge zones than on adjacent limbs primarily because there are greater numbers of discontinuities in hinge zones. We speculate that susceptibility increases in hinge zones as fold curvature becomes tighter.

Natural Hazards and Earth System Sciences↗
USGS1998

Assessment of peak discharge uncertainty in the American River basin, California

Flood-discharge data, current-meter and indirect measurements, and stage-discharge relations, the oldest of which dates to the early 1900's, were used to estimate the uncertainty about annual flood peaks in or near the American River Basin at 20 stream-gaging stations operated by the U.S. Geological Survey. The study estimates that, in the study area, most flood peaks that were determined from current-meter measurements have an uncertainty of about plus or minus 3 percent, whereas the peaks that were determined from indirect measurements have an uncertainty ranging from plus or minus 10 to plus or minus 70 percent. The study also determined that the stage-discharge relations that have been developed for most of the sites in the American River Basin are correct.

Open-File Report↗
USGS2010

Star crossings and stone monuments-Field astronomy by the Wheeler Survey in 1870s Colorado

The decade of the 1870s was a time of extensive exploration and surveying in the American West. The nation needed knowledge of the cultural features, topography, natural resources, and geology of this land to promote and aid the 'rapid development of an empire.' The need was particularly acute in the region that still was known in the early 1870s as Colorado Territory. There, cities and towns were springing up along the base of the Front Range, railroads were expanding, and in the mountains prospectors and miners were exploring the countryside seeking and extracting the region's abundant mineral resources. Also, recurring conflicts between the newcomers and Native Americans made it desirable to have accurate maps for military purposes. Four major government-sponsored scientific surveys formed the principal organized effort to provide critical knowledge of the land. Civilian scientists led three of these: John Wesley Powell ('Geographical and Topographical Survey of the Colorado River of the West'); Ferdinand V. Hayden ('Geological and Geographical Survey of the Territories'); and Clarence King ('Geological Exploration of the Fortieth Parallel'). Lt. George Montague Wheeler, a young graduate of West Point (Class of 1866) and a member of the U.S. Army Corps of Engineers, led the fourth and most ambitious project ('United States Geographical Surveys West of the One Hundredth Meridian').

Circular↗
USGS1994

What do maps show?

The purpose of the teaching package is to help students understand and use maps. The U.S. Geological Survey (USGS) has provided the package as a service to educators so that more Americans will learn to understand the world of information on maps. Everything in the package teaches and reinforces geographic skills that are required in your curriculum.

General Information Product↗
USGS2020

Diversity of diatoms, benthic macroinvertebrates, and fish varies in response to different environmental correlates in Arctic rivers across North America

Climate change poses a significant threat to Arctic freshwater biodiversity, but impacts depend upon the strength of organism response to climate‐related drivers. Currently, there is insufficient knowledge about Arctic freshwater biodiversity patterns to guide assessment, prediction, and management of biodiversity change. As part of the Circumpolar Biodiversity Monitoring Program's first freshwater assessment, we evaluated diversity of diatoms, benthic macroinvertebrates, and fish in North American Arctic rivers. Alpha diversity was assessed in relation to temperature, water chemistry, bedrock geology, and glaciation history to identify important environmental correlates. Biotic composition was compared among groups to evaluate response to environmental gradients. Macroinvertebrate α‐diversity declined strongly with increasing latitude from 48°N to 82°N, whereas diatom and fish diversity peaked around 70°N without a clear latitudinal decline. Macroinvertebrate diversity was significantly positively related to air temperature. Diatom diversity was related to bedrock geology and temperature, whereas fish diversity was related to glaciation history. Fish and macroinvertebrate assemblages differed between sites in western Canada, where invertebrate composition was more variable, and Alaska, where fish composition was more variable. In sites with both diatom and macroinvertebrate data, diatom composition was distinct in Alaska, where richness was highest in former glacial refugia. Macroinvertebrate composition was distinct in lowest‐latitude eastern and high‐latitude western Canadian sites where temperature was highest. Temperature, precipitation, geology, calcium, and substrate size were important environmental correlates for diatoms and macroinvertebrates, although the relative importance of each correlate differed. Diatom taxa were most strongly associated with water chemistry, whereas benthic invertebrate composition related most strongly to precipitation and temperature. This large‐scale study provides the most substantial integration and analysis of river diatom, macroinvertebrate, and fish data from the North American Arctic to date. Findings suggest that macroinvertebrates will show the strongest response to climate‐related shifts in temperature, whereas diatoms and fish are more likely to respond to climate‐induced shifts in nutrients and hydraulic connectivity. However, significant gaps in data coverage limited our ability to reliably evaluate spatial patterns and detect change. These gaps could be reduced by improving collaborative efforts between the U.S.A. and Canada to harmonise future monitoring.

Arctic↗
USGS2006

Geophysical studies of the Crump Geyser known geothermal resource area, Oregon, in 1975

The U.S. Geological Survey (USGS) conducted geophysical studies in support of the resource appraisal of the Crump Geyser Known Geothermal Resource Area (KGRA). This area was designated as a KGRA by the USGS, and this designation became effective on December 24, 1970. The land classification standards for a KGRA were established by the Geothermal Steam Act of 1970 (Public Law 91-581). Federal lands so classified required competitive leasing for the development of geothermal resources. The author presented an administrative report of USGS geophysical studies entitled 'Geophysical background of the Crump Geyser area, Oregon, KGRA' to a USGS resource committee on June 17, 1975. This report, which essentially was a description of geophysical data and a preliminary interpretation without discussion of resource appraisal, is in Appendix 1. Reduction of sheets or plates in the original administrative report to page-size figures, which are listed and appended to the back of the text in Appendix 1, did not seem to significantly degrade legibility. Bold print in the text indicates where minor changes were made. A colored page-size index and tectonic map, which also show regional geology not shown in figure 2, was substituted for original figure 1. Detailed descriptions for the geologic units referenced in the text and shown on figures 1 and 2 were separately defined by Walker and Repenning (1965) and presumably were discussed in other reports to the committee. Heavy dashed lines on figures 1 and 2 indicate the approximate KGRA boundary. One of the principal results of the geophysical studies was to obtain a gravity map (Appendix 1, fig. 10; Plouff, and Conradi, 1975, pl. 9), which reflects the fault-bounded steepness of the west edge of sediments and locates the maximum thickness of valley sediments at about 10 kilometers south of Crump Geyser. Based on the indicated regional-gravity profile and density-contrast assumptions for the two-dimensional profile, the maximum sediment thickness was estimated at 820 meters. A three-dimensional gravity model would have yielded a greater thickness. Audiomagnotelluric measurements were not made as far south as the location of the gravity low, as determined in the field, due to a lack of communication at that time. A boat was borrowed to collect gravity measurements along the edge of Crump Lake, but the attempt was curtailed by harsh, snowy weather on May 21, 1975, which shortly followed days of hot temperature. Most of the geophysical data and illustrations in Appendix 1 have been published (Gregory and Martinez, 1975; Plouff, 1975; and Plouff and Conradi, 1975), and Donald Plouff (1986) discussed a gravity interpretation of Warner Valley at the Fall 1986 American Geophysical Union meeting in San Francisco. Further interpretation of possible subsurface geologic sources of geophysical anomalies was not discussed in Appendix 1. For example, how were apparent resistivity lows (Appendix 1, figs. 3-6) centered near Crump Geyser affected by a well and other manmade electrically conductive or magnetic objects? What is the geologic significance of the 15-milligal eastward decrease across Warner Valley? The explanation that the two-dimensional gravity model (Appendix 1, fig. 14) was based on an inverse iterative method suggested by Bott (1960) was not included. Inasmuch as there was no local subsurface rock density distribution information to further constrain the gravity model, the three-dimensional methodology suggested by Plouff (1976) was not attempted. Inasmuch as the associated publication by Plouff (1975), which released the gravity data, is difficult to obtain and not in digital format, that report is reproduced in Appendix 2. Two figures of the publication are appended to the back of the text. A later formula for the theoretical value of gravity for the given latitudes at sea level (International Association of Geodesy, 1971) should be used to re-compute gravity anomalies. To merge t

Open-File Report↗
USGS2017

Hydraulic and biological analysis of the passability of select fish species at the U.S. Geological Survey streamgaging weir at Blackwells Mills, New Jersey

Recent efforts to advance river connectivity for the Millstone River watershed in New Jersey have led to the evaluation of a low-flow gauging weir that spans the full width of the river. The methods and results of a desktop modelling exercise were used to evaluate the potential ability of three anadromous fish species ( Alosa sapidissima [American shad], Alosa pseudoharengus [alewife], and Alosa aestivalis [blueback herring]) to pass upstream over the U.S. Geological Survey Blackwells Mills streamgage (01402000) and weir on the Millstone River, New Jersey, at various streamflows, and to estimate the probability that the weir will be passable during the spring migratory season. Based on data from daily fishway counts downstream from the Blackwells Mills streamgage and weir between 1996 and 2014, the general migratory period was defined as April 14 to May 28. Recorded water levels and flow data were used to theoretically estimate water depths and velocities over the weir, as well as flow exceedances occurring during the migratory period. Results indicate that the weir is a potential depth barrier to fish passage when streamflows are below 200 cubic feet per second using a 1-body-depth criterion for American shad (the largest fish among the target species). Streamflows in that range occur on average 35 percent of the time during the migratory period. An increase of the depth criterion to 2 body depths causes the weir to become a possible barrier to passage when flows are below 400 cubic feet per second. Streamflows in that range occur on average 73 percent of the time during the migration season. Average cross-sectional velocities at several points along the weir do not seem to be limiting to the fish migration, but maximum theoretical velocities estimated without friction loss over the face of the weir could be potentially limiting.

New Jersey↗
USGS1979

Maps for America: Cartographic products of the U.S. Geological Survey and others

This book was first conceived as being devoted entirely to descriptions of the maps produced by the U.S. Geological Survey. As the project developed, however, it became clear that the story of maps is not complete unless it is properly set in the background of the American mapping effort as a whole. Extension of the scope of the book does not preclude placing emphasis on the Geological Survey mapping program, which is treated in full while other programs are treated only in sufficient detail to provide leads for exploring them elsewhere.

Report↗
USGS1987

Water-quality data-collection activities in Colorado and Ohio; Phase II, Evaluation of 1984 field and laboratory quality-assurance practices

Serious questions have been raised by Congress about the usefulness of water-quality data for addressing issues of regional and national scope and, especially, for characterizing the current quality of the Nation's streams and ground water. In response, the U.S. Geological Survey has undertaken a pilot study in Colorado and Ohio to (1) determine the characteristics of current (1984) water-quality data-collection activities of Federal, regional, State, and local agencies, and academic institutions; and (2) determine how well the data from these activities, collected for various purposes and using different procedures, can be used to improve our ability to answer major broad-scope questions, such as: A. What are (or were) natural or near-natural water-quality conditions? B. What are existing water-quality conditions? C. How has water quality changed, and how do the changes relate to human activities? Colorado and Ohio were chosen for the pilot study largely because they represent regions with different types of waterquality concerns and programs. The study has been divided into three phases, the objectives of which are: Phase I--Inventory water-quality data-collection programs, including costs, and identify those programs that met a set of broad criteria for producing data that are potentially appropriate for water-quality assessments of regional and national scope. Phase II--Evaluate the quality assurance of field and laboratory procedures used in producing the data from programs that met the broad criteria of Phase I. Phase III--Compile the qualifying data and evaluate the adequacy of this data base for addressing selected water-quality questions of regional and national scope. Water-quality data are collected by a large number of organizations for diverse purposes ranging from meeting statutory requirements to research on water chemistry. Combining these individual data bases is an appealing and potentially cost-effective way to attempt to develop a data base adequate for regional or national water-quality assessments. However, to combine data from diverse sources, field and laboratory procedures used to produce the data need to be equivalent and need to meet specific qualityassurance standards. It is these factors that are the focus of Phase II, which is described in this report. In the first phase of this study, an inventory was made of all public organizations and academic institutions that undertook water-quality data-collection activities in Colorado and Ohio in 1984. Water-quality programs identified in Phase I were tested against a set of broad screening criteria. A total of 44 waterquality programs in Colorado and 29 programs in Ohio passed the Phase-I screen and were examined in Phase II. These programs accounted for an estimated 165,000 analyses in Colorado and 76,300 analyses in Ohio for 20 selected constituents and properties. Although qualifying programs included both surface- and ground-water sampling, they emphasized surface waters and produced few groundwater analyses (3,660 for Colorado and 470 for Ohio). For Phase II, information about field and laboratory qualityassurance practices was provided by each organization and its supporting laboratories through questionnaires. This information was evaluated against a set of specific criteria for field and laboratory practices. The criteria were developed from guidelines published by public agencies and professional organizations such as the American Public Health Association, the U.Sc, Environmental Protection Agency, and the U.S. Geological Survey. Each of the eight criteria that comprise the Phase-II screen fall into one of two major categories--field practices or laboratory practices.

Colorado, Ohio↗
USGS2025

Airborne geophysical efforts for critical mineral systems mapping in the southern Midcontinent, USA

The increasing global demand for critical minerals to support energy and technological advancement has accelerated exploration and research efforts for these essential resources. Since 2019, the United States Geological Survey (USGS) Earth Mapping Resources Initiative (EMRI) has worked to modernize geologic mapping of the Nation to better understand its critical mineral resources. To further this initiative, the USGS has flown a series of high-resolution airborne magnetic and radiometric surveys over large areas of the southern Midcontinent. The surveys cover known critical mineral deposits and areas with the potential to host additional critical minerals based on the presence of one or more overlapping mineral systems. One aspect of EMRI emphasizes close collaboration between the USGS and the Association of American State Geologists, as well as other government and industry partners to leverage geophysical, geological, and geochemical expertise on both regional and local scales. The EMRI high-resolution airborne survey data provide new insights into the geophysical framework of the southern Midcontinent and its critical mineral endowment. Additionally, discoveries made from the data have directed new studies for critical mineral exploration.

southern Midcontinent↗
USGS1952

Preliminary report on ground water in the Michaud Flats Project, Power County, Idaho

The Michaud Flats Project area, as here described, includes about 65 square miles in central Power County, south of the Snake River in the southeastern Snake River Plain of Idaho. The principal town and commercial center of the area is American Falls. The immediate purpose of work in the area by the U.S. Geological Survey was to investigate the possibility of developing substantial quantities of ground water for irrigating high and outlying lands in the proposed Michaud Flats Project area of the U.S. Bureau of Reclamation. Initial findings are sufficiently favorable to warrant comprehensive further investigation. Advanced study would assist proper utilization of ground-water resources and would aid ultimate evaluation of total water resources available in the area. About 10,000 acres of low-lying lands in the Michaud Flats project could be irrigated with water from the Snake River under a low-line distribution system involving a maximum pumping lift of about 200 feet above the river. An additional larger area of high and outlying lands is suitable for irrigation with water pumped from wells. If sufficient ground water is economically available, the expense of constructing and operating a costly highline distribution system for surface water could be saved. Reconnaissance of the ground-water geology of the area disclosed surface outcrops of late Cenozoic sedimentary, pyroclastic, and volcanic rocks. Well logs and test borings show that similar materials are present beneath the land surface in the zone of saturation. Ground water occurs under perched, unconfined, and confined (artesian) conditions, but the aquifers have not been adequately explored. Existing irrigation wells, 300 feet or less in depth, yield several hundred to 1,400 gallons of water a minute, with pumping drawdowns of 6 to 50 feet, and perhaps more. A few wells have been pumped out at rates of less than 800 gallons a minute. Scientific well-construction and development methods would lead to more efficient well performance. A generalized water-table contour map of the area shows that the principal general direction of ground-water movement is toward the west and northwest. The southwestern part of the American Falls Reservoir, and a segment of the Snake River below the dam, may be perched above the water table. Ground water appears to move beneath this segment of the river to the Snake River Plain on the northwest side. So far as is known, recharge to the ground-water reservoir is chiefly from local sources and from the runoff from the mountain area southeast of the project. Seepage losses from surface water spread for irrigation would contribute a substantial amount of new recharge to the ground water, but the amount of such recharge might be less than the depletion of ground water by pumping. Therefore, with ground-water irrigation a part of the project, return flow to the American Falls Reservoir might be less than it is in the existing regimen. Ground-water pumping where the ground water is not tributary to the reservoir might not deplete the reservoir appreciably, but would reduce the net supply of water available west of Neeley. Evidence indicates that at least moderate supplies of ground water can be obtained in low-lying areas southwest and northeast of American Falls, but the safe perennial yields of the aquifers cannot now be estimated. The ground-water potential in high and outlying lands is not known. It is unlikely that this potential is sufficient to supply all high and outlying lands, but the supply may be adequate for a substantial part of these lands. Thorough investigation appears to be warranted.

Open-File Report↗
USGS2020

Karst geology of the Upper Midwest, USA

Karst in the Upper Midwest occurs within a thick sequence of mixed carbonate and siliciclastic Cambrian through Pennsylvanian sedimentary rocks, with a minor occurrence of karst in Proterozoic sandstone. Deposition of the sediments occurred on a marine epeiric ramp that spanned much of the North American continent through most of the Paleozoic. The Upper Midwest region experienced dramatic changes in sea level over geologic time, resulting in the observed sequence of interbedded carbonate and clastic rocks. The greatest degree of karst development occurs within (1) the Lower Ordovician Prairie du Chien Group below the Sauk-Tippecanoe (Knox) unconformity, (2) the Upper Ordovician Galena Group, (3) the Middle and Upper Devonian Wapsipinicon and Cedar Valley Groups, and (4) the Middle Mississippian Mammoth Cave Group and correlative formations. Uplift and exposure of the rocks likely occurred in the Permian, with some later deposition of Cretaceous terrestrial sediments atop the marine strata. Nearly all the Cenozoic sedimentary units were removed by ice sheets during the Pleistocene; however, pockets of Cretaceous sediments persist on the margins of the Driftless Area, a region of the Upper Mississippi River Valley that remained largely free of ice during the last ice age.

Book chapter↗
USGS2006

New digital data base helps to map North America

A new effort is underway to compile an upgraded digital magnetic anomaly data base and map for the North American continent by 2002. This program is a joint effort by the Geological Survey of Canada (GSC), the U.S. Geological Survey (USGS), and Consejo de Recursos Minerales de Mexico (CRM). An integrated, readily accessible, modern digital data base of magnetic anomaly data spanning North America will be a powerful tool for evaluating the structure, geologic processes, and tectonic evolution of the continent, and may also be used to help resolve societal and scientific issues that span national boundaries. Maps derived from the digital data base will provide a view of continentalscale trends not available in individual data sets, help link widely separated areas of out-crop, and unify disparate geologic studies.

Eos Science News↗
USGS2005

A universal surface complexation framework for modeling proton binding onto bacterial surfaces in geologic settings

Adsorption onto bacterial cell walls can significantly affect the speciation and mobility of aqueous metal cations in many geologic settings. However, a unified thermodynamic framework for describing bacterial adsorption reactions does not exist. This problem originates from the numerous approaches that have been chosen for modeling bacterial surface protonation reactions. In this study, we compile all currently available potentiometric titration datasets for individual bacterial species, bacterial consortia, and bacterial cell wall components. Using a consistent, four discrete site, non-electrostatic surface complexation model, we determine total functional group site densities for all suitable datasets, and present an averaged set of 'universal' thermodynamic proton binding and site density parameters for modeling bacterial adsorption reactions in geologic systems. Modeling results demonstrate that the total concentrations of proton-active functional group sites for the 36 bacterial species and consortia tested are remarkably similar, averaging 3.2 ?? 1.0 (1??) ?? 10-4 moles/wet gram. Examination of the uncertainties involved in the development of proton-binding modeling parameters suggests that ignoring factors such as bacterial species, ionic strength, temperature, and growth conditions introduces relatively small error compared to the unavoidable uncertainty associated with the determination of cell abundances in realistic geologic systems. Hence, we propose that reasonable estimates of the extent of bacterial cell wall deprotonation can be made using averaged thermodynamic modeling parameters from all of the experiments that are considered in this study, regardless of bacterial species used, ionic strength, temperature, or growth condition of the experiment. The average site densities for the four discrete sites are 1.1 ?? 0.7 ?? 10-4, 9.1 ?? 3.8 ?? 10-5, 5.3 ?? 2.1 ?? 10-5, and 6.6 ?? 3.0 ?? 10-5 moles/wet gram bacteria for the sites with pKa values of 3.1, 4.7, 6.6, and 9.0, respectively. It is our hope that this thermodynamic framework for modeling bacteria-proton binding reactions will also provide the basis for the development of an internally consistent set of bacteria-metal binding constants. 'Universal' constants for bacteria-metal binding reactions can then be used in conjunction with equilibrium constants for other important metal adsorption and complexation reactions to calculate the overall distribution of metals in realistic geologic systems.

American Journal of Science↗