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Pesticide occurrence in shallow groundwater in three regions of agricultural land use: Baldwin County, the Wiregrass region, and the Tennessee River valley region of Alabama, 2009–20

As part of a cooperative investigation between the U.S. Geological Survey and the Alabama Department of Agriculture and Industries, a network of 22 groundwater wells were sampled from 2014 through 2020 for about 230 pesticide and pesticide degradate compounds. Wells were located in three regions of intensive agricultural land use in Alabama: Baldwin County, the Wiregrass region, and the Tennessee River valley region. Metolachlor sulfonic acid, a degradate of the herbicide metolachlor, was the most frequently detected compound, occurring in about 70 percent of the samples. Three other compounds, metolachlor, atrazine, and 2-chloro-4-isopropylamino-6-amino-s-triazine, were also detected in more than half of the samples. Metolachlor and its degradates accounted for 33 of the 50 greatest compound concentrations study-wide, including the maximum pesticide concentration across all compounds (62,500 nanograms per liter). The frequency and magnitude of detections of many specific pesticide compounds varied among the three regions, but all detected pesticide concentrations were well below the U.S. Environmental Protection Agency maximum contaminant levels and applicable human health benchmarks. Sample results were combined with results of previous (2009–13) sampling to provide a continuous time-series of data for 2009–20. More than half of the 289 pesticide compounds analyzed during 2009–20 were not detected in any samples. Only four compounds were detected at great enough frequency throughout the 10 sampling years to evaluate patterns of change through time. Metolachlor and its degradate, metolachlor sulfonic acid, were frequently detected in all regions. Atrazine and its degradate, 2-chloro-4-isopropylamino-6-amino-s-triazine, were also detected in wells from all regions, but the variability and magnitude of concentrations were greatest in the Tennessee River valley region. No apparent temporal pattern in concentrations was found.

Alabama

Summary of annual repeat magnetotelluric surveys of the Geysers geothermal field

As part of a multi-year project, funded by the California Energy Commission, annual magnetotelluric (MT) surveys have been collected at The Geysers geothermal field in northern California with the goal of measuring temporal changes within the steam field. The repeat surveys started in 2021 and repeated a 2017 survey (Peacock et al., 2020) with further extension to the southern part of the geothermal field. Temporal variations in the MT transfer functions are observed to be spatially coherent and compartmentalized. Mapping residual phase tensor ellipses demonstrates the direction of maximum change is often aligned with existing fracture orientations. Three dimensional inversion of the MT data, using the inversion results from previous years as the starting model, indicates that the steam reservoir has generally become more resistive over time (~10%), suggesting more steam in the field. A few pockets within the steam field have become more electrically conductive over time and are collocated with injection wells, suggesting either more fluid content in those zones, less steam, or more saline fluids.

California

Characterization of groundwater resources near the southeastern part of Puget Sound, Washington

More than 1 million people live within the active model area (AMA) in the southeastern part of the lowlands surrounding Puget Sound, or Puget Lowland, Washington, and groundwater is the source for approximately one-half of their public, domestic, and irrigation water demands. The 887-square-mile AMA, located in King and Pierce Counties, represents the area of analysis for the conceptual hydrogeologic framework and numerical groundwater-flow models within the study area and includes the Puyallup River and Chambers-Clover Creek watersheds. To assess the potential hydrologic and anthropogenic impacts to groundwater and the connected surface-water resources, conceptual and numerical groundwater-flow models of groundwater flow were developed by the U.S. Geological Survey Washington Water Science Center in close cooperation with 18 water-resource agencies and stakeholders. This multichapter volume documents the development of the conceptual and numerical groundwater-flow models of groundwater flow. Chapters A, B, and C provide an overall introduction to the multichapter volume (Chapter A), the conceptual hydrogeologic framework (Chapter B), and the groundwater budget (Chapter C). Chapters D and E describe numerical groundwater-flow model construction and calibration (Chapter D) and the numerical groundwater-flow model results (Chapter E). Collectively, these reports present a characterization and simulation tool for groundwater resources near the southeastern part of Puget Sound, Washington.

Scientific Investigations Report

Timescales of cumulate mobilization and mixing for the 1868 A.D. eruption of Mauna Loa, Island of Hawai‘i

The deadly 1868 A.D. eruption of Mauna Loa’s lower Southwest Rift Zone (Island of Hawai‘i) included a M7.9 earthquake and associated tsunami and landslides, demonstrating the severe hazards posed by Earth’s largest active subaerial volcano. To better understand the relationship between intense seismic activity, dike emplacement, magma storage, transport histories, and mobilization of olivine cumulates at Mauna Loa, we examine compositional zoning of olivine in the 1868 lava flows. Samples range from basalt (< 10% olivine) to picrite (30–40% olivine). The olivine cargo is heterogeneous (Fo 78.2–89.2 ; forsterite = [Mg/(Mg + Fe) × 100]) but dominated by ~ Fo 89 cores that lie above the Fe-Mg equilibrium field of host glasses. Crystal rims < Fo 80 are due to post-eruptive modification in slow cooling lava flows. Minor element compositions fall within the range of other Mauna Loa olivine erupted in the past 200 years. Olivine crystals exhibit both normal and complex Fo zoning patterns that yield timescales of diffusive re-equilibration that range from 3 to 258 days, with 72% of crystals recording 71 days or less. These timescales correspond to magmatic priming of the summit reservoir system ~ 2 months prior to the eruption and the M7.9 earthquake likely facilitated the transport of the crystal-rich summit-derived magmas downrift shortly prior to eruption. If the recently proposed faster Fe-Mg diffusion coefficient is used, timescales instead range from < 1 day to 25 days, with most recording 1 week or less. In this scenario, most of the olivine zoning would have to have been generated after the M7.9 earthquake perturbed the system.

Hawaii

Profiles of gamma-ray and magnetic data for aerial surveys over parts of the Western United States from longitude 108 to 126 degrees W. and from latitude 34 to 49 degrees N.

This CD-ROM contains images generated from geophysical data, software for displaying and analyzing the images and software for displaying and examining profile data from aerial surveys flown as part of the National Uranium Resource Evaluation (NURE) Program of the U.S. Department of Energy. The images included are of gamma-ray data (uranium, thorium, and potassium channels), Bouguer gravity data, isostatic residual gravity data, aeromagnetic anomalies, topography, and topography with bathymetry. This publication contains image data for the conterminous United States and profile data for the conterminous United States within the area longitude 108 to 126 degrees W. and latitude 34 to 49 degrees N. The profile data include apparent surface concentrations of potassium, uranium, and thorium, the residual magnetic field, and the height above the ground. The images on this CD-ROM include graytone and color images of each data set, color shaded-relief images of the potential-field and topographic data, and color composite images of the gamma-ray data. The image display and analysis software can register images with geographic and geologic overlays. The profile display software permits the user to view the profiles as well as obtain data listings and export ASCII versions of data for selected flight lines.

Data Series

Manipulation of the Symbiodiniaceae microbiome confers multigenerational impacts on symbioses and reproductive ecology of its Exaiptasia diaphana host

Symbiodiniaceae-associated microbiota strongly influence cnidarian symbioses. We systematically reduced the bacterial and fungal communities associated with Symbiodiniaceae to study potential effects on the cnidarian holobiont Exaiptasia diaphana (Aiptasia). Clonal anemones were inoculated with xenic Breviolum minutum (SSB01) and microbiome-manipulated cultures after antibacterial or antifungal treatment. The asexual reproduction of pedal laceration allowed for three generations of clonal aposymbiotic Aiptasia to be utilised in this study, from the initial adult generation (G0), to the first (G1), and second (G2) generation. We inoculated small and large G1 Aiptasia with SSB01 algae and monitored onset of symbiosis, rate of algal proliferation, and holobiont characteristics. Sequencing the 16S and 18S rRNA gene regions identified significant differences in the bacterial and fungal communities of the G0 and G1 generations, alongside differences between the size classes of small and large G1 anemones. The microbiome of larger G1 individuals was distinct to the smaller G1 anemones, suggesting a microbiome maturation process. Control Breviolum minutum cultures exhibited a significantly greater proliferation rate in large G1 anemones when compared to antibacterial or antifungal treated cultures, whereas the opposite trend was documented in the small G1 anemones. Although no differences were observed between algal photochemical parameters, or the growth and polyp activity of G1 juveniles, we observed a significant influence in the production of G2 clones between treatments. Overall, we provide strong ecological implications of manipulating Symbiodiniaceae microbiome, not for the algae themselves, but for the maturation of the host Aiptasia, as well as for the cnidarian holobiont over multiple generations.

The ISME Journal

Hydrologic response of groundwater and streamflow to natural and anthropogenic drivers of change in headwaters of the upper Colorado River basin during recent wet (1982–1999) and drought (2000–2022) conditions

Study region: Headwaters of the upper Colorado River basin (UCOL), USA Study focus: Surface-water and groundwater numerical models incorporating water-use information were used to investigate changes in climate, water use, and simulated hydrologic responses of snow processes, evapotranspiration, groundwater, and streamflow during recent wet (1982–1999) and drought (2000–2022) periods in the headwater subregions of the upper Colorado River basin. New hydrologic insights for the region: Decreases in average streamflow between wet and drought periods ranged from 20 % in the Colorado River headwaters subregion to 23 % in the Gunnison River headwaters subregion. Like streamflow, average surface runoff was statistically less during the drought than the wet period, with decreases from 24–31 % in the headwaters. On a volume basis, runoff decreases were greater than streamflow decreases in both the Colorado River and Gunnison River headwaters. Although the amount of water-year groundwater discharge to streams remained nearly the same between the wet and drought periods, groundwater as a percentage of streamflow increased between the wet and drought periods, highlighting the importance of groundwater in sustaining streamflow during drought conditions. Multiple linear regression analyses revealed that snowmelt-only models were better than the best precipitation and temperature models at explaining streamflow variability from all headwater subregions for both the wet and drought periods.

Arizona, Colorado, New Mexico, Utah, Wyoming

Geologic map of the Greater Antilles and Virgin Islands

Introduction The geologic map of the Greater Antilles and Virgin Islands is a compilation of information from the literature, integrated to provide a seamless geologic map of the region. This map was prepared to serve as a base map for a mineral resource assessment of the region. Several small-scale regional geologic maps of the region have been prepared in the past. This report supersedes an earlier version of the geologic map of the Greater Antilles and the Virgin Islands that was released as U.S. Geological Survey (USGS) Open-File Report 2019–1036. For this report, the regional geologic overview shown on sheet 1 covers Cuba; the island of Hispaniola, which includes Haiti and Dominican Republic; Jamaica; the Cayman Islands; Puerto Rico; and the U.S. and British Virgin Islands. Sheet 2 shows the geology of Cuba and Cayman Islands, sheet 3 the geology of Jamaica, sheet 4 the geology of Hispaniola, and sheet 5 the geology of Puerto Rico and Virgin Islands. Accompanying the maps are three tables: table 1 lists the map units (in alphabetical order by map-unit label), their ages, and the countries or territories in which they can be found. These are listed in alphabetical order for ease in locating unit names from the symbols on the maps. Table 2 is a list of sources for the geologic map compilation of Puerto Rico. Table 3 shows formations in the Devil’s Race Course Group of Jamaica.

Greater Antilles, Virgin Islands

Hydrogeologic framework and considerations for drilling and grouting of closed-loop geothermal bores in the Erie-Ontario Lowlands and Allegheny Plateau of New York State

The hydrogeologic framework at closed-loop geothermal sites in the Erie-Ontario Lowlands and Allegheny Plateau of central and western New York is the result of the complex interaction of bedrock geology, glacial geology, and groundwater hydrology, and the occurrence of petroleum and gas. Considerations for closed-loop geothermal bore installation include the thickness and character of glacial deposits, bedrock solubility and depth to competent rock, karst development, the distribution of highly permeable zones and their hydraulic heads, and the presence of saline water, gas, and oil. The hydrogeology of the Erie-Ontario Lowlands and Allegheny Plateau poses challenges to closed-loop geothermal bore drilling and casing; managing drill cuttings, discharge water, and gas; and grouting. The potential to encounter severe challenges typically increases with bore depth. This report highlights hydrogeologic considerations for closed-loop geothermal bore installation in New York’s Erie-Ontario Lowlands and Allegheny Plateau to help guide the efficient and safe development of geothermal resources in the regions.

New York

Characterization and simulation of the quantity and quality of water in the Highland Lakes, Texas, 1983-92

The Highland Lakes, located in central Texas, are a series of seven reservoirs on the Colorado River (Lake Buchanan, Inks Lake, Lake Lyndon B. Johnson, Lake Marble Falls, Lake Travis, Lake Austin, and Town Lake). The reservoirs provide hydroelectric power for the area. In addition, Lake Austin and Town Lake also provide the public water supply for the Austin metropolitan area. Saline water released from Natural Dam Salt Lake during 1987&ndash;89 caused increased concern among water managers that high-salinity water entering the Highland Lakes could result in waterquality problems, necessitating additional treatment of the water. The maximum dissolved solids concentrations for the reservoirs after the saline inflow were about two to three times the average concentrations before the inflow. The maximum concentrations of chloride and sulfate after the inflow were about three to five times the average concentrations before the inflow. The concentrations of dissolved solids, chloride, and sulfate in Lake Buchanan, Inks Lake, Lake Lyndon B. Johnson, and Lake Marble Falls were less than the concentrations of the applicable water-quality standards by the end of 1990. Concentrations of these constituents in Lake Travis, Lake Austin, and Town Lake did not decrease to previous levels, which were less than the concentrations of the applicable waterquality standards, until the end of 1991. Constituent concentrations for Lake Buchanan and Inks Lake; for Lake Lyndon B. Johnson and Lake Marble Falls; and for Lake Travis, Lake Austin, and Town Lake were similar because of the relative storage capacities and location of tributary inflows. From the initial increase in constituent concentrations in Lake Buchanan (summer 1987) in response to the saline inflow, the high-salinity water passed through the entire Highland Lakes in about 3.5 years. A mathematical mass-balance model was used to simulate the input and movement of highsalinity water through the Highland Lakes and to estimate monthly mean concentrations of dissolved solids, chloride, and sulfate for wet, average, and dry hydrologic conditions. The simulated median monthly concentrations during the 10-year simulation period for each reservoir generally are larger for the average condition than for the wet condition and generally are larger for the dry condition than for the average condition. The simulated concentrations of dissolved solids, chloride, and sulfate decreased to levels less than the concentrations of the applicable water-quality standards in about 2 to 5 years after the saline water inflow of 1987&ndash;89 was simulated for the three hydrologic conditions. Results from the simulations indicate that saline inflows to the Highland Lakes similar to those of the releases from Natural Dam Salt Lake during 1987&ndash;89 are unlikely to cause large increases in future concentrations of dissolved solids, chloride, and sulfate in the Highland Lakes. The results also indicate that high-salinity water will continue to be diluted as it is transported downstream through the Highland Lakes, even during extended dry periods.

Texas

Solute transport and modeling of water quality in a small stream

An injection of chloride, sodium, and stable strontium was made at a constant rate for 3 hours into Uvas Creek, Santa Clara County, Calif., to determine the mass transport processes in a small stream. Five observation points were selected within a 610-metre reach of the stream below the injection site. Water samples were collected at the observation points during and immediately after the injection. A mathematical model of the stream was obtained by solving analytically and optimally the one-dimensional mass transport equation of the solutes in the stream. Comparison of field results with a simplified mathematical model indicates the dominance of convection in the behavior of sodium and chloride. The concentration of chloride and sodium can be closely simulated by the model. However, strontium cannot be well represented by the simplified model, which contains a first-order decay-type sink.

California

Geologic framework, hydrostratigraphy, and ichnology of the Blanco, Payton, and Rough Hollow 7.5-minute quadrangles, Blanco, Comal, Hays, and Kendall Counties, Texas

During 2023, the U.S. Geological Survey, in cooperation with the Edwards Aquifer Authority, revised an initial characterization completed during 2015–16 of the geologic framework, hydrostratigraphy, and ichnology of the Edwards and Trinity aquifers in the Blanco, Payton, and Rough Hollow 7.5-minute quadrangles in Blanco, Comal, Hays, and Kendall Counties, Texas. The purpose of this report is to present the updated geologic framework, hydrostratigraphy, and ichnology of the Trinity and Edwards Groups in those quadrangles. Rocks exposed in the study area are of the Lower Cretaceous Trinity Group and lower part of the Fort Terrett Formation of the Lower Cretaceous Edwards Group. The faulting and fracturing in the study area are part of the Balcones Fault Zone, an extensional system of faults active during the Paleocene to middle Eocene that generally trends southwest to northeast in south-central Texas. Hydrostratigraphically, the rocks exposed in the study area contain a section of the Edwards (Balcones Fault Zone) aquifer, upper zone of the Trinity aquifer, and middle zone of the Trinity aquifer. In the study area, the only hydrostratigraphic units of the Edwards (Balcones Fault Zone) aquifer remaining are (from top to bottom) VII and VIII, which cap several hills. The mapped hydrostratigraphic units of the upper zone of the Trinity aquifer are (from top to bottom) the cavernous, Camp Bullis, upper evaporite, fossiliferous, and lower evaporite. The mapped hydrostratigraphic units of the middle zone of the Trinity aquifer are (from top to bottom) the Bulverde, Little Blanco, Twin Sisters, Doeppenschmidt, Herff Falls (where present), Rust, Honey Creek, Hensell, and Cow Creek hydrostratigraphic units.

Texas

Preliminary geologic map of the Southern Santa Rosa Mountains and Borrego Badlands, San Diego County, Southern California

This investigation delineates the geologic framework of an area of 75 square kilometers (km 2 ) located west of the Salton Sea in southern California (fig. 1, on sheet 1). The study area encompasses the south flank of the Santa Rosa Mountains and the eastern part of the Borrego Badlands (sheet 1). In this study area, regionally important stratigraphic and structural elements collectively inform the late Cenozoic geologic evolution of the Anza-Borrego sector of the Salton Trough province. Critical stratigraphic and structural elements in the map area include the following: The well exposed sequence of late Cenozoic, nonmarine sedimentary rocks that filled the Anza-Borrego subbasin (fig. 1) of the Salton Trough; A tectonic boundary that—in the southern Santa Rosa Mountains—separates the sedimentary strata from underlying crystalline rocks of Peninsular Ranges type. This tectonic boundary, named the West Salton Detachment Fault System by Axen and Fletcher (1998), is projected to underlie all late Cenozoic sedimentary strata in the Anza-Borrego subbasin of the Salton Trough; A variety of transpressional, transtensional, and strike-slip structures that have deformed the late Cenozoic sedimentary strata and collectively guided syntectonic and posttectonic depositional events within the Anza-Borrego subbasin of the Salton Trough; and The southeasternmost surface expression of the Clark Fault, a major strand of the dextral San Jacinto Fault Zone. Geologic mapping and analysis for this investigation focused on clarifying geologic relations among these four stratigraphic and structural aspects in the map area.

California

Use of a numerical groundwater-flow model and projected climate scenarios to simulate the effects of future climate conditions on base flow for reach 1 of the Washita River alluvial aquifer and Foss Reservoir storage, western Oklahoma

To better understand the relation between climate variability and future groundwater resources in reach 1 of the Washita River alluvial aquifer and Foss Reservoir in western Oklahoma, the U.S. Geological Survey, in cooperation with the Bureau of Reclamation, used a previously published numerical groundwater-flow model and climate-model data to investigate changes in base flow and reservoir storage by evaluating three scenarios. The three projected climate scenarios were (1) a central-tendency scenario, (2) a warmer/drier scenario, and (3) a less-warm/wetter scenario. To estimate future base flow and groundwater availability in western Oklahoma, specifically in reach 1 of the Washita River alluvial aquifer, downscaled climate-model data from 231 Coupled Model Intercomparison Project phase 5 (CMIP5) projections coupled with a previously published numerical groundwater-flow model were used to compare the effects of different climate scenarios on the aquifer. Changes in base flow and groundwater-level elevations during a 30-year baseline scenario (1985–2014) and the three 30-year projected climate scenarios (2050–79) under central-tendency, warmer/drier, and less-warm/wetter climatic conditions were assessed by using the calibrated model. In the simulations, the amount of base flow and reservoir storage declined in the central-tendency and warmer/drier scenarios compared to the amount of base flow and reservoir storage under historical climatic conditions (baseline scenario). Mean annual change in reservoir storage decreased from the baseline scenario the most in the warmer/drier scenario, followed by the central-tendency scenario, but increased in the less-warm/wetter scenario compared to the baseline scenario. At the end of the simulation period (2079), the largest magnitude differences in groundwater-level elevations in all three projected climate scenarios relative to the baseline scenario occurred upstream from Foss Reservoir. Results from incorporating downscaled climate projections into localized numerical groundwater-flow models can highlight potential future changes in and implications for groundwater resources and availability.

Oklahoma

New paleomagnetic constraints on the eruption timing, stratigraphy, and post-emplacement deformation of the Picture Gorge Basalt within the Columbia River Basalt Group

The Picture Gorge Basalt (PGB) is part of the Miocene Columbia River Basalt Group (CRBG). The PGB, which outcrops in eastern Oregon, is considered coincident in time with the voluminous Grande Ronde Basalt. New radiometric ages have expanded the age‐range of the PGB, suggesting it began erupting prior to the Steens Basalt to its south and continued until after cessation of the Grande Ronde Basalt eruptions, an interval of 1.5 Ma. However, the existing paleomagnetism of the PGB implies this eruption timeline is an overestimate. To reconcile the radiometric and paleomagnetic timescales for the PGB, we conducted a paleomagnetic study on sections of the PGB to construct a detailed, high‐quality magnetostratigraphy. Our data indicate the stratigraphically lowest lava flows in the PGB are of reversed polarity, revealing a new paleomagnetic transition with the PGB and a reversed (R)–normal (N)–reversed (R) sequence. This suggests one of two timeline possibilities for PGB volcanism: (a) eruptions began and during through CRBG polarity chrons R0–N0–R1, penecontemporaneous with Steens Basalt, or (b) eruptions began and persisted during CRBG polarity chrons R1–N1–R2. Our work supports a longer interval of PGB volcanism than was suggested by previous paleomagnetic data but is at odds with the suggestion that PGB eruptions lasted through the entire main CRBG. We favor a scenario wherein PGB eruptions begin with R0 and continue into the R1 paleomagnetic interval. The paleomagnetic results also record a ∼18° vertical‐axis rotation of east‐central Oregon after ∼16 Ma with respect to stable North America.

Oregon