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Major- and Trace-Element Concentrations in Rock Samples Collected in 2006 from the Taylor Mountains 1:250,000-scale Quadrangle, Alaska

Introduction The Kuskokwim mineral belt of Bundtzen and Miller (1997) forms an important metallogenic region in southwestern Alaska that has yielded more than 3.22 million ounces of gold and 400,000 ounces of silver. Precious-metal and related deposits in this region associated with Late Cretaceous to early Tertiary igneous complexes extend into the Taylor Mountains 1:250,000-scale quadrangle. The U.S. Geological Survey is in the process of conducting a mineral resource assessment of this region. This report presents analytical data collected during the third year of this multiyear study. A total of 138 rock geochemistry samples collected during the 2006 field season were analyzed using the ICP-AES/MS42, ICP-AES10, fire assay, and cold vapor atomic absorption methods described in more detail below. Analytical values are provided in percent (% or pct: 1 gram per 100 grams), parts per million (ppm: 1 gram per 1,000,000 grams), or parts per billion (ppb: 1 gram per 1,000,000,000 grams) as indicated in the column heading of the data table. Data are provided for download in Excel (*.xls), comma delimited (*.csv), dBase 4 (*.dbf) and as a point coverage in ArcInfo interchange (*.e00) formats available at http://pubs.usgs.gov/of/2007/1386/.

Open-File Report

Natural versus anthropogenic dispersion of metals to the environment in the Wulik River area, western Brooks Range, northern Alaska

Zinc-lead-silver mineral deposits in the Wulik River region, Alaska, contain an enormous accumulation of Zn. In addition to the giant deposits at Red Dog, at least nine other deposits are known. Natural weathering of these deposits has dispersed metals over a wide region over a long period of time (c. 10 000 years) through transport by stream and groundwater, stream sediments, formation of soils, and perhaps wind-blown atmospheric deposition from weathering of naturally enriched Pb-Zn surface deposits. Anthropogenic input also contributes metals to the environment. Mining of the Red Dog deposit, which began in 1989, produces fine-grained galena and sphalerite concentrates that are transported from the mine site by truck to a storage port facility. Wind-blown dispersion of concentrate dust along the road and around the port facility has been a source of local metal-rich surficial materials. Geochemical and mineralogical characteristics provide a means of distinguishing the natural versus anthropogenic metal sources. Soils over deposits have patterns of increasing metal contents with depth and proximity to the metal-bearing source, whereas ore concentrate dust is localized at the surface. The acidity produced by weathering of the sulphide deposits creates an environment in which elements such as Se and Mo are stable whereas Ca is not. Consequently, high Mo (up to 29 ppm) and Se (up to 17 ppm) and low Ca (<0.4%) concentrations characterize surficial materials near natural deposits. Acidic conditions also yield high Pb-Zn ratios (up to 70) because sphalerite is preferentially dissolved and Zn is mobilized during chemical weathering. In natural materials, secondary jarosite and anglesite are developed, and minor galena is etched and rounded due to a history of chemical and mechanical weathering. In contrast, dust-bearing samples have Pb/Zn ratios that are 0.4 or less, Ca contents are higher (0.2 to 3.6%), and Mo (<10 ppm) and Se (not detected) concentrations are low. Furthermore, galena and sphalerite grains are angular and secondary minerals are lacking. ?? 2007 AAG/Geological Society of London.

Geochemistry: Exploration, Environment, Analysis

The Alaskan Mineral Resource Assessment Program: Background information to accompany folio of geologic and mineral resource maps of the Tanacross quadrangle, Alaska

The Tanacross quadrangle, consisting of 17,400 km 2 (6,700 mi 2) in east-central Alaska, was investigated by an interdisciplinary research team for the purpose of assessing the mineral resource potential of the quadrangle. This report provides the background information for a folio of maps on the geology, geophysics, reconnaissance geochemistry, Landsat imagery, and mineral resource evaluation of the quadrangle. Revisions to the previously published geologic map of the Tanacross quadrangle, 18 new potassium-argon ages, and a comprehensive bibliography are also included.

Alaska

Mineralogical maps showing the distribution of ore-related minerals in the minus-30-mesh, nonmagnetic heavy-mineral fraction of stream sediment, Healy Quadrangle, Alaska

A reconnaissance mineralogical and geochemical survey of stream sediments in the Healy quadrangle was conducted during 1980-1982 as part of the Alaskan Mineral Resource Assessment Program (AMRAP) of the United States Geological Survey (USGS). As a result of the various AMRAP investigations, a mineral resource evaluation of the quadrangle was published by Cox and others (1989). The Healy quadrangle comprises 6,700 mi 2 in southern Alaska and is located 60 mi south of Fairbanks and 120 mi north of Anchorage. The quadrangle is traversed by the central Alaska Range, which forms a glacially sculptured arcuate mountain wall with a maximum elevation of 12,339 ft (Mt. Deborah). The lowest elevation is about 1,000 ft along the Nenana River. Access to the sample sites was provided by helicopters, with the exception of a few sites that were accessible by automobile from the Denali and George Park highways.

Alaska

Summaries of data on and lists of references to metallic and selected nonmetallic mineral deposits in fifteen quadrangles in southwestern and west-central Alaska

These summaries of data on metallic and selected nonmetallic mineral occurrences and lists of selected references to them in Geological Survey, U.S. Bureau of Mines, and State of Alaska Division of Geological and Geophysical Surveys (and predecessor State and Territorial agencies) reports and maps released before Jan. 1, 1980, and in one abstract of a report presented orally at a scientific meeting, are designed to aid in library research on the mineral resources of 14 quadrangles in southwestern Alaska and the Saint Lawrence quadrangle in west—central Alaska. The references are selected in the sense that mainly statistical reports such as the annual Minerals Yearbook of the U.S. Bureau of Mines and many annual and biennial reports of the Alaska Division of Geological and Geophysical Surveys and its predecessor agencies are not included. Also not included are data on many claims about which little more than their locations is known (for example, localities 11 to 14 in MacKevett and Holloway, 1977 (OF 77-169D), p. 28). These omissions should not be interpreted as a judgement that the claims are not on valid mineral occurrences, but only that there are insufficient data to describe any mineral deposit that might be present. Geochemical anomalies determined by analyses of rock and stream—sediment samples in which no metallic mineral was identified are also omitted. Work now in progress should add greatly to the knowledge of mineral resources in several quadrangles on the Alaska Peninsula.

Alaska

40 Ar/ 39 Ar Dating of Zn-Pb-Ag Mineralization in the Northern Brooks Range, Alaska

The 40 Ar/ 39 Ar laser step-heating method potentially can be used to provide absolute ages for a number of formerly undatable, low-temperature ore deposits. This study demonstrates the use of this method by determining absolute ages for Zn-Pb-Ag sediment-hosted massive sulfide deposits and vein-breccia occurrences found throughout a 300-km-long, east-west-trending belt in the northern Brooks Range, Alaska. Massive sulfide deposits are hosted by Mississippian to Pennsylvanian(?) black carbonaceous shale, siliceous mudstone, and lesser chert and carbonate turbidites of the Kuna Formation (e.g., Red Dog, Anarraaq, Lik (Su), and Drenchwater). The vein-breccia occurrences (e.g., Husky, Story Creek, West Kivliktort Mountain, Vidlee, and Kady) are hosted by a deformed but only weakly metamorphosed package of Upper Devonian to Lower Mississippian mixed continental and marine clastic rocks (the Endicott Group) that stratigraphically underlie the Kuna Formation. The vein-breccias are mineralogically similar to, but not spatially associated with, known massive sulfide deposits. The region's largest shale-hosted massive sulfide deposit is Red Dog; it has reserves of 148 Mt grading 16.6 percent zinc, 4.5 percent lead, and 77 g of silver per tonne. Hydrothermally produced white mica in a whole-rock sample from a sulfide-bearing igneous sill within the Red Dog deposit yielded a plateau age of 314.5 Ma. The plateau age of this whole-rock sample records the time at which temperatures cooled below the argon closure temperature of the white mica and is interpreted to represent the minimum age limit for massive sulfide-related hydrothermal activity in the Red Dog deposit. Sulfide-bearing quartz veins at Drenchwater crosscut a hypabyssal intrusion with a maximum biotite age of 337.0 Ma. Despite relatively low sulfide deposition temperatures in the vein-breccia occurrences (162&deg;-251&deg;C), detrital white mica in sandstone immediately adjacent to large vein-breccia zones was partially to completely recrystallized. The 40 Ar/ 39 Ar age spectra and inverse isochron plots of the multicomponent whole-rock sandstone samples are more complex than those of single minerals. However, different minerals have different Ca/K and Cl/K ratios and closure temperatures, and these properties were used to identify portions of spectra dominated by argon release from specific minerals. 40 Ar/ 39 Ar laser step-heating analyses of Late Devonian sandstone whole rocks produced spectra that record a two-stage resetting history: a Carboniferous hydrothermal event first and later Mesozoic to Tertiary events, which are in agreement with geologic constraints. The 40 Ar/ 39 Ar ages and the similar mineralogy, lead isotope composition, and relative stratigraphic positions support the interpretation that the shale-hosted massive sulfide deposits and most vein-breccia occurrences are temporally and genetically related, and that they are different expressions of Carboniferous basinal dewatering.

Alaska

Summary of references to mineral occurrences (other than mineral fuels and construction materials) in the Cordova Quadrangle, Alaska

This summary of references is designed to aid in library research on metallic and nonmetallic (other than mineral fuels and construction materials) mineral occurrences in the Cordova quadrangle, Alaska. References to most reports of the Geological Survey, U. S. Bureau of Mines, and State of Alaska Division of Geological and Geophysical Surveys and its predecessor agencies released before January 1, 1979, are included. Certain, mainly statistical, reports such as the annual Minerals Yearbook of the U.S. Bureau of Mines and the biennial and annual reports of the Alaska Division of Geological and Geophysical Surveys and its predecessor agencies are not included. Also not included are data on many prospects and claims about which little more than their locations is known (for example, many of those in Condon, 1965 (1-453) and some in MacKevett and Holloway, 1977 (OF-77-169A), p. 15). These omissions should not be interpreted as a judgement on my part that the prospects and claims are not valid mineral occurrences, but only that there are insufficient data to describe any mineral deposits that might be present. This report is divided into three parts: a section made up of summaries of references arranged alphabetically by occurrence name; a section that lists synonyms for names in the first section, claim names, and the names of operators and owners of mines and prospects; and a section that lists, by author, all references in the first section and in these introductory paragraphs.

Alaska

Geology and ore deposits in the Reid Inlet area, Glacier Bay, Alaska, with added notes on a mineralized zone near Lituya Bay

A gold-bearing area of about 7 1/2 square miles, first discovered by Mr. Joseph Ibach in 1924, exists near the head of Glacier Bay between Reid and Lamplugh glaciers. The dominant rock type in the area is granodiorite which is intruded into bedded rocks that may be of Paleozoic age. The bedded rocks consist of conglomerate, limestone, and black graphitic schist. A light-colored quartz diorite younger than the granodiorite crops out south of the mapped area. Most of the ore deposits are found in fissure type quartz veins. These occur in both the granodiorite and in the older bedded rocks. The mineralizing solutions which brought in the gold have altered the country rock for as much as a few tens of feet to each side of the fissures. Locally, this altered rock is gold-bearing, but in the places sampled the gold content was found to be too low to permit profitable mining. Most of the quartz veins tend to be lenticular, both horizontally and vertically, and the gold tends to be concentrated in discrete spots along the veins. These factors tend to make the ore spotty and its location unpredictable. This has given rise to the concept that the ore in the area has a tendency not to continue below the surface. Geologically there appears to be no reason to believe that gold mineralization is confined to surface outcrop. The Leroy and Rainbow properties are the only two that have yielded significant quantities of gold within the mapped area, but the veins on the Highland Chief and probably the Rambler claims appear to be of sufficient size and grade to be potential ore producers. The LeRoy mine is the largest in the area. The ore body consisted of a fissure type quartz vein averaging between 2 and 3 feet in width with a length of about 60 feet, but in 1954, all of the ore in the main vein had been mined out above the main working level. Ore probably amounting to several hundreds of tons was mined and milled from the Rainbow vein. The results of an investigation of a mineralized area near Lituya Bay is included in this report. The mineralized material consists of hydrothermally altered rock found in volcanic rocks believed to be of Mesozoic age. The gold content is too low to permit profitable mining, although it is possible that undiscovered spots exist in which the gold concentration is sufficiently high to be of economic significance.

Alaska