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Geologic framework for the national assessment of carbon dioxide storage resources: Williston Basin, Central Montana Basins, and Montana Thrust Belt study areas

The 2007 Energy Independence and Security Act directs the U.S. Geological Survey (USGS) to conduct a national assessment of potential geologic storage resources for carbon dioxide (CO 2 ). The methodology used by the USGS for the national CO 2 assessment follows that of previous USGS work. This methodology is non-economic and is intended to be used at regional to sub-basinal scales. The Williston Basin of North Dakota, South Dakota, and Montana, along with the Central Montana Basins and Montana Thrust Belt study areas are adjacent and share similar geologic units. In general, the Williston Basin study area is a wide sedimentary basin, whereas the Central Montana Basins study area contains sedimentary rocks along topographic highs and flat plains, and the Montana Thrust Belt study area is more structurally complex. This report identifies and contains geologic descriptions of nine storage assessment units (SAUs) in Cambrian to Upper Cretaceous sedimentary rocks within the Williston Basin study area. The Central Montana Basins and Montana Thrust Belt study areas were also investigated for this report. Nevertheless, no SAUs in these study areas were assessed because they contained potential sources of underground drinking water; although sufficient geologic data were available, and suitable storage formations meeting our size, depth, reservoir quality, and regional seal guidelines were found. Ultimately, the report focuses on the characteristics, specified in the methodology, that influence the potential CO 2 storage resource in the SAUs. Specific descriptions of the SAU boundaries as well as their sealing and reservoir units are included. Properties for each SAU, such as depth to top, gross thickness, porosity, permeability, groundwater quality, and structural reservoir traps, are usually provided to illustrate geologic factors critical to the assessment. The geologic information herein was employed, as specified in the USGS methodology, to calculate a probabilistic distribution of potential storage resources in each SAU with these assessment outputs contained in a companion results report. Figures in this report show the study area boundaries along with the SAU extent and cell maps of well penetrations through sealing units into the top of the storage formations. The USGS does not necessarily know the location of all wells and cannot guarantee the full extent of drilling through specific formations in any given cell shown on the cell maps.

Montana, North Dakota, South Dakota

Ancient Martian aeolian processes and palaeomorphology reconstructed from the Stimson formation on the lower slope of Aeolis Mons, Gale crater, Mars

Reconstruction of the palaeoenvironmental context of Martian sedimentary rocks is central to studies of ancient Martian habitability and regional palaeoclimate history. This paper reports the analysis of a distinct aeolian deposit preserved in Gale crater, Mars, and evaluates its palaeomorphology, the processes responsible for its deposition, and its implications for Gale crater geological history and regional palaeoclimate. Whilst exploring the sedimentary succession cropping out on the northern flank of Aeolis Mons, Gale crater, the Mars Science Laboratory rover Curiosity encountered a decametre‐thick sandstone succession, named the Stimson formation, unconformably overlying lacustrine deposits of the Murray formation. The sandstone contains sand grains characterized by high roundness and sphericity, and cross‐bedding on the order of 1 m in thickness, separated by sub‐horizontal bounding surfaces traceable for tens of metres across outcrops. The cross‐beds are composed of uniform thickness cross‐laminations interpreted as wind‐ripple strata. Cross‐sets are separated by sub‐horizontal bounding surfaces traceable for tens of metres across outcrops that are interpreted as dune migration surfaces. Grain characteristics and presence of wind‐ripple strata indicate deposition of the Stimson formation by aeolian processes. The absence of features characteristic of damp or wet aeolian sediment accumulation indicate deposition in a dry aeolian system. Reconstruction of the palaeogeomorphology suggests that the Stimson dune field was composed largely of simple sinuous crescentic dunes with a height of ca 10 m, and wavelengths of ca 150 m, with local development of complex dunes. Analysis of cross‐strata dip‐azimuths indicates that the general dune migration direction and hence net sediment transport was towards the north‐east. The juxtaposition of a dry aeolian system unconformably above the lacustrine Murray formation represents starkly contrasting palaeoenvironmental and palaeoclimatic conditions. Stratigraphic relationships indicate that this transition records a significant break in time, with the Stimson formation being deposited after the Murray formation and stratigraphically higher Mount Sharp group rocks had been buried, lithified and subsequently eroded.

Sedimentology

Influence of fracture anisotropy on ground water ages and chemistry, Valley and Ridge province, Pennsylvania

Model ground water ages based on chlorofluorocarbons (CFCs) and tritium/helium-3 (3H/3He) data were obtained from two arrays of nested piezometers located on the north limb of an anticline in fractured sedimentary rocks in the Valley and Ridge geologic province of Pennsylvania. The fracture geometry of the gently east plunging fold is very regular and consists predominately of south dipping to subhorizontal to north dipping bedding-plane parting and east striking, steeply dipping axial-plane spaced cleavage. In the area of the piezometer arrays, which trend north-south on the north limb of the fold, north dipping bedding-plane parting is a more dominant fracture set than is steeply south dipping axial-plane cleavage. The dating of ground water from the piezometer arrays reveals that ground water traveling along paths parallel to the dip direction of bedding-plane parting has younger 3H/3He and CFC model ages, or a greater component of young water, than does ground water traveling along paths opposite to the dip direction. In predominantly unmixed samples there is a strong positive correlation between age of the young fraction of water and dissolved sodium concentration. The travel times inferred from the model ages are significantly longer than those previously calculated by a ground water flow model, which assumed isotropically fractured layers parallel to topography. A revised model factors in the directional anisotropy to produce longer travel times. Ground water travel times in the watershed therefore appear to be more influenced by anisotropic fracture geometry than previously realized. This could have significant implications for ground water models in other areas underlain by similarly tilted or folded sedimentary rock, such as elsewhere in the Valley and Ridge or the early Mesozoic basins.

Pennsylvania

Mineralogy of selected sedimentary interbeds at or near the Idaho National Engineering Laboratory, Idaho

The U.S. Geological Survey (USGS) Project Office at the Idaho National Engineering Laboratory (INEL), in cooperation with the U.S. Department of Energy and Idaho State University, analyzed 66 samples from sedimentary interbed cores during a 38-month period beginning in October 1990 to determine bulk and clay mineralogy. These cores had been collected from 19 sites in the Big Lost River Basin, 2 sites in the Birch Creek Basin, and 1 site in the Mud Lake Basin, and were archived at the USGS lithologic core library at the INEL. Mineralogy data indicate that the core samples from the Big Lost River Basin have larger mean and median percentages of quartz, total feldspar, and total clay minerals, but smaller mean and median percentages of calcite than the core samples from the Birch Creek Basin. Core samples from the Mud Lake Basin have abundant quartz, total feldspar, calcite, and total clay minerals.

Open-File Report

Pleistocene Brawley and Ocotillo Formations: Evidence for initial strike-slip deformation along the San Felipe and San Jacinto fault zonez, Southern California

We examine the Pleistocene tectonic reorganization of the Pacific-North American plate boundary in the Salton Trough of southern California with an integrated approach that includes basin analysis, magnetostratigraphy, and geologic mapping of upper Pliocene to Pleistocene sedimentary rocks in the San Felipe Hills. These deposits preserve the earliest sedimentary record of movement on the San Felipe and San Jacinto fault zones that replaced and deactivated the late Cenozoic West Salton detachment fault. Sandstone and mudstone of the Brawley Formation accumulated between ???1.1 and ???0.6-0.5 Ma in a delta on the margin of an arid Pleistocene lake, which received sediment from alluvial fans of the Ocotillo Formation to the west-southwest. Our analysis indicates that the Ocotillo and Brawley formations prograded abruptly to the east-northeast across a former mud-dominated perennial lake (Borrego Formation) at ???1.1 Ma in response to initiation of the dextral-oblique San Felipe fault zone. The ???25-km-long San Felipe anticline initiated at about the same time and produced an intrabasinal basement-cored high within the San Felipe-Borrego basin that is recorded by progressive unconformities on its north and south limbs. A disconformity at the base of the Brawley Formation in the eastern San Felipe Hills probably records initiation and early blind slip at the southeast tip of the Clark strand of the San Jacinto fault zone. Our data are consistent with abrupt and nearly synchronous inception of the San Jacinto and San Felipe fault zones southwest of the southern San Andreas fault in the early Pleistocene during a pronounced southwestward broadening of the San Andreas fault zone. The current contractional geometry of the San Jacinto fault zone developed after ???0.5-0.6 Ma during a second, less significant change in structural style. ?? 2007 by The University of Chicago. All rights reserved.

Journal of Geology

Late Neogene and Quaternary evolution of the northern Albemarle Embayment (mid-Atlantic continental margin, USA)

Seismic surveys in the eastern Albemarle Sound, adjacent tributaries and the inner continental shelf define the regional geologic framework and provide insight into the sedimentary evolution of the northern North Carolina coastal system. Litho- and chronostratigraphic data are derived from eight drill sites on the Outer Banks barrier islands, and the Mobil #1 well in eastern Albemarle Sound. Within the study area, parallel-bedded, gently dipping Miocene beds occur at 95 to > 160 m below sea level (m bsl), and are overlain by a southward-thickening Pliocene unit characterized by steeply inclined, southward-prograding beds. The lower Pliocene unit consists of three seismic sequences. The 55–60 m thick Quaternary section unconformably overlies the Pliocene unit, and consists of 18 seismic sequences exhibiting numerous incised channel-fill facies. Shallow stratigraphy (< 40 m bsl) is dominated by complex fill patterns within the incised paleo-Roanoke River valley. Radiocarbon and amino-acid racemization (AAR) ages indicate that the valley-fill is latest Pleistocene to Holocene in age. At least six distinct valley-fill units are identified in the seismic data. Cores in the valley-fill contain a 3–6 m thick basal fluvial channel deposit that is overlain by a 15 m thick unit of interlaminated muds and sands of brackish water origin that exhibit increasing marine influence upwards. Organic materials within the interlaminated deposits have ages of 13–11 cal. ka. The interlaminated deposits within the valley are overlain by several units that comprise shallow marine sediments (bay-mouth and shoreface environments) that consist of silty, fine- to medium-grained sands containing open neritic foraminifera, suggesting that this area lacked a fronting barrier island system and was an open embayment from ∼10 ka to ∼4.5 ka. Seismic data show that initial infilling of the paleo-Roanoke River valley occurred from the north and west during the late Pleistocene and early Holocene. Later infilling occurred from the south and east and is characterized by a large shoal body (Colington Island and Shoals) and adjacent inlet fill. Establishment of a continuous barrier island system across the bay-mouth resulted in deposition of the latest phase of valley-fill, characterized by estuarine organic-rich muds.

Albemarle Embayment

The Sedimentary Geochemistry and Paleoenvironments Project Phase 2 data release: An open data resource for the study of Earth's environmental history

Geochemical data from sedimentary rocks are the primary source of information regarding Earth's surface evolution through time, including its air and water envelopes and interactions with life and deep Earth processes. The Sedimentary Geochemistry and Paleoenvironments Project (SGP) is a scientific consortium centered around open data and community-driven development of cyberinfrastructure tools and resources for sedimentary geochemistry and Earth history. Here we describe the SGP Phase 2 data release, which focused on incorporating Paleoproterozoic and Mesoproterozoic (2500–1000 million years ago) data and better accommodating carbonate data. This data release was built through the involvement of >200 researchers worldwide in academia, government, and industry, and provides the largest available public data resource for our user community in the academic fields of geochemistry, sedimentology, tectonics, paleontology, Earth history, and paleoclimate, as well as the petroleum and minerals industries. The dataset now encompasses 126,006 samples and 4,132,371 geochemical analyses. In addition to direct entry by SGP Team Members, we have ingested and incorporated datasets from the Geoscience Australia OZCHEM database, the Alberta Geological Survey, and the Deep-Time Marine Sedimentary Element Database (DM-SED) compilation. This paper details sampling in the Phase 2 dataset with respect to age, geography, lithology, and other geological characteristics, documents access via our search website and API, discusses possible issues and/or biases in the dataset that could impact analyses, describes plans for governance and stewardship of data from Indigenous lands, and serves as the citable reference paper for the data release.

Chemical Geology

Significance of carbon dioxide density estimates for basin-scale storage resource assessments

The geologic carbon dioxide (CO 2 ) storage resource size is a function of the density of CO 2 in the subsurface. The pressure and temperature of the storage reservoir at depth affect the CO 2 density. Therefore, knowing these subsurface conditions allows for improved resource estimates of potential geologic CO 2 storage capacity. In 2012, the U.S. Geological Survey (USGS) completed an assessment of geologic CO 2 storage resources for large sedimentary basins in onshore and State waters areas of the U.S. Evaluating the subsurface conditions and CO 2 density in these basins was integral to the assessment. To better understand these conditions, investigations of pressure and temperature gradients, typically derived from borehole data and analog studies, were assembled at the basin scale. Based on the USGS assessment results and findings here, changes in subsurface pressure and temperature may yield density changes up to 40 percent, which may translate into significant changes in storage resource estimates.

Energy Procedia

A methodology to estimate CO2 and energy gas storage resources in depleted conventional gas reservoirs

Depleted hydrocarbon reservoirs are subsurface geological structures capable of sequestering vast quantities of carbon dioxide (CO 2 ) as well as storing other energy gases for later usage, such as natural gas, and potentially hydrogen (H 2 ). Here we outline a methodology to quantify multi-gas storage resources in depleted conventional gas reservoirs for usage in assessments by the United States Geological Survey (USGS) at the scale of sedimentary basins. The methodology consists first of quantifying accessible pore volume in a depleted reservoir for natural gas storage using up to three equations. Input data are derived from commonly reported or estimated reservoir parameters and natural gas production volumes, and equations may be combined in linear models to improve pore volume estimates. Storage estimates from these equations are tested and validated for 31 reservoirs in the Michigan Basin Province, USA that were previously converted to underground gas storage facilities and have known (federally reported) natural gas storage capacities. Secondly, natural gas storage capacities can be transformed via fluid substitution calculations to estimate the storage resources for non-native fluids, applied here for, CO 2 , H 2 , and methane-H 2 blends, accounting for molecule-specific deviations from ideal gas behavior at reservoir pressures and temperatures as well as differing storage efficiencies. Importantly, the storage of non-native fluids may not be appropriate in all depleted gas reservoir settings due to potential risks like leakage, in particular in the case of H 2 storage, requiring additional knowledge of caprock sealing capacity. Given this caveat, we demonstrate the fluid substitution method for natural gas reservoirs of the Northern Niagaran Reef and Southern Niagaran Reef USGS plays in the Michigan Basin Province, as these trends of Silurian pinnacle reefs are capped with tight-sealing evaporite facies. The deterministic equations outlined from this methodology can be incorporated into future probabilistic USGS gas storage assessments for CO 2 , H 2 , and natural gas resources in the United States.

Michigan

Archive of water gun subbottom data collected during USGS cruise SEAX 96004, New York Bight, 1 May - 9 June 1996

Beginning in 1995, the USGS, in cooperation with the U.S Army Corps of Engineers (USACE), New York District, began a program to generate reconnaissance maps of the sea floor offshore of the New York-New Jersey metropolitan area, one of the most populated coastal regions of the United States. The goal of this mapping program is to provide a regional synthesis of the sea-floor environment, including a description of sedimentary environments, sediment texture, seafloor morphology, and geologic history to aid in understanding the impacts of anthropogenic activities, such as ocean dumping. This mapping effort differs from previous studies of this area by obtaining digital, sidescan sonar images that cover 100 percent of the sea floor. This investigation was motivated by the need to develop an environmentally acceptable solution for the disposal of dredged material from the New York - New Jersey Port, by the need to identify potential sources of sand for renourishment of the southern shore of Long island, and by the opportunity to develop a better understanding of the transport and long-term fate of contaminants by investigations of the present distribution of materials discharged into the New York Bight over the last 100+ years (Schwab and others, 1997). Data collected in 1996, USGS cruise SEAX 96004, augments data collected in 1995 with sidescan sonar and seismic reflection data collected within the New York Bight Apex region. This report is an archive of the water gun seismic reflection data collected in 1996.

Open-File Report

Archive of water gun subbottom data collected during USGS cruise SEAX 95007 New York Bight, 7-25, May 1995

Beginning in 1995, the USGS, in cooperation with the U.S Army Corps of Engineers (USACE), New York District, began a program to generate reconnaissance maps of the sea floor offshore of the New York-New Jersey metropolitan area, one of the most populated coastal regions of the United States. The goal of this mapping program is to provide a regional synthesis of the sea-floor environment, including a description of sedimentary environments, sediment texture, seafloor morphology, and geologic history to aid in understanding the impacts of anthropogenic activities, such as ocean dumping. This mapping effort differs from previous studies of this area by obtaining digital, sidescan sonar images that cover 100 percent of the sea floor. This investigation was motivated by the need to develop an environmentally acceptable solution for the disposal of dredged material from the New York - New Jersey Port, by the need to identify potential sources of sand for renourishment of the southern shore of Long island, and by the opportunity to develop a better understanding of the transport and long-term fate of contaminants by investigations of the present distribution of materials discharged into the New York Bight over the last 100+ years (Schwab and others, 1997). Data collected in 1996, USGS cruise SEAX 96004, augments data collected in 1995 with sidescan sonar and seismic reflection data collected within the New York Bight Apex region. This report is an archive of the boomer seismic reflection data collected in 1996.

New Jersey, New York

California State Waters Map Series — Offshore of Pacifica, California

In 2007, the California Ocean Protection Council initiated the California Seafloor Mapping Program (CSMP), designed to create a comprehensive seafloor map of high-resolution bathymetry, marine benthic habitats, and geology within the 3-nautical-mile limit of California&rsquo;s State Waters. The CSMP approach is to create highly detailed seafloor maps through collection, integration, interpretation, and visualization of swath sonar data, acoustic backscatter, seafloor video, seafloor photography, high-resolution seismic-reflection profiles, and bottom-sediment sampling data. The map products display seafloor morphology and character, identify potential marine benthic habitats, and illustrate both the surficial seafloor geology and shallow (to about 100 m) subsurface geology. The Offshore of Pacifica map area is located in northern California, on the Pacific coast of the San Francisco Peninsula about 10 kilometers south of the Golden Gate. The map area extends from Daly City, through Pacifica, to the small coastal community of Montara. Much of the coastal zone is managed by either the State of California or local governments, including Thornton Beach State Park, Mussel Rock Park, Pacifica State Beach, Gray Whale Cove State Beach, and Montara State Beach. The major structure in the transform boundary between the Pacific and North American tectonic plates, the northwest-striking San Andreas Fault, cuts through the map area, crossing the shoreline near Mussel Rock before continuing offshore. The epicenter of the great 1906 California earthquake is located on the offshore part of the San Andreas Fault Zone a few kilometers north of the map area. The map area is located at the northwest end of the Santa Cruz Mountains, much of which has been uplifted in the last 400,000 years. Southwest of the San Andreas Fault Zone, this uplift has resulted in a highly variable coastal morphology characterized by long, narrow beaches bounded by steep cliffs or marine terraces, small pocket beaches surrounded by rocky promontories, and steep, narrow coastal watersheds. Geologic units mapped along the coast include sedimentary, volcanic, and metamorphic rocks of the Franciscan Complex; Cretaceous granitic rocks; Tertiary sedimentary rocks; and Quaternary coastal marine terraces, deep-seated and shallow landslides, and beach and sand dune deposits, all of which contribute sediment to the coastal zone. In contrast to the more rural coastal zone to the south, the highly urbanized coastal zone north of Mussel Rock and the San Andreas Fault Zone is characterized by a narrow beach bounded by steep, 50- to 120-m-high cliffs made up of sand, silt, and clay of the Pliocene and Pleistocene Merced Formation, the source of numerous landslides. Two large landslides along &ldquo;Northridge bluff&rdquo; in 2003 and 2007 had estimated volumes of 305,800 to 382,300 m 3 and 120,800 m 3 , respectively. Coastal landslides also are an issue to the south between Mussel Rock and Mori Point, even as bluffs diminish in height and pocket beaches transition to a more continuous strand bounded by Quaternary-age dunes and low-lying marine terraces. Mori Point, a coastal promontory in Pacifica underlain by rocks of the Franciscan Complex, rises abruptly to a height of 90 m from the shoreline. Pocket beaches characterize the shoreline from Mori Point south to Shelter Cove, the largest of which, Pacifica State Beach, is at the mouth of San Pedro Creek. The coastal zone south of Pacifica, which stretches from Shelter Cove to Montara and includes Point San Pedro and Devils Slide, lies at the northwest end of San Pedro Mountain (underlain largely by early Tertiary sedimentary rocks) and Montara Mountain (underlain by Cretaceous granitic rocks). Elevations at Montara Mountain exceed 500 m just 4 km from the shoreline, and steep cliffs along the coast are as high as 275 m. This rugged terrain results in numerous rocky promontories, small pocket beaches, and large coastal landslides. Slope failures along Devils Slide are notorious for closing California Highway 1, creating such a large and persistent problem that the California Department of Transportation has bypassed this coastal section by tunneling through San Pedro Mountain; the tunnel was completed and the new section of highway opened in 2013. Coastal relief diminishes at Montara in the southernmost part of the map area, where the shoreline is bounded by 10- to 20-m-high marine terraces. Throughout the year, this part of the coast is exposed to the north Pacific swell, the southern swell, northwest wind waves, and local wind waves. The north Pacific swell dominates in winter months, having wave heights that range from 2 to 10 m at offshore buoys and wave periods that range from 10 to 25 s. During summer months, the largest waves come from the southern swell, generated by storms in the south Pacific and offshore of Central America. Characteristically, these swells have smaller wave heights (0.3&ndash;3 m) but similarly long wave periods (10&ndash;25 s). Local wind waves are most common from October to April, whereas northwest wind waves affect the coast throughout the year. These two wind-wave regimes typically have wave heights of 1 to 4 m and short wave periods (3&ndash;10 s). Unlike many other parts of the California coast where sediment is supplied primarily from river and (or) stream runoff, sediment supply to the offshore along this part of northern California is a complex mixture of (1) sand transported from the coast north of the Golden Gate, (2) sediment transported to the coast through the San Francisco Bay via the Golden Gate and then dispersed over the adjacent ebb-tide delta, and (3) varying volumes of sediment eroded from adjacent steep coastal bluffs caused by wave-induced landslides and other erosional events. Additionally, since the 1980s, coastal erosion south of the Golden Gate has increased substantially between Ocean Beach (on the west coast of San Francisco, about 5 km north of the map area) and Point San Pedro. The combined sediment load is transported southward along the coast by the generally north-to-south alongshore current, which develops in response to the energetic winter-wave climate associated with the north Pacific swell. Overall, beaches in the map area have a long-term erosional trend, except near Mussel Rock where a long-term accretionary trend may reflect increased sediment supply from landslides. Beach-front riprap armoring and retaining walls are used locally to protect the shoreline from seasonal storm waves, most notably between Mussel Rock and Mori Point. The continental shelf in the map area is about 40 km wide, with water depths at the shelf break that range from about 80 to 120 m. Within California&rsquo;s State Waters, the midshelf to inner shelf areas are characterized by a relatively flat, shallow (water depths of as much as 44 m) seafloor that dips gently (about 0.2&deg; to 0.3&deg;) westward. The seafloor is composed primarily of unconsolidated Holocene sediment (marine deposits), as well as some nearshore bedrock outcrops that consist primarily of rocks of the Tertiary Purisima Formation and also Cretaceous plutonic rocks (granite or granodiorite).

California

Thermal springs in the Salmon River basin, central Idaho

The Salmon River basin drains approximately 13,000 square miles in central Idaho underlain by the Idaho batholith. Geologic units in the basin include igneous, sedimentary, and metamorphic rocks and granitic rocks predominate. Water from thermal springs ranges in temperature from 20.5 degrees to 94.0 degrees Celsius. The waters are slightly alkaline and are generally a sodium carbonate or bicarbonate type. Dissolved-solids concentrations are variable and range from 103 to 839 milligrams per liter. Estimated reservoir temperatures determined from the silicic acid-corrected silica, sodium-potassium-calcium, and sulfate-water isotope geothermometers range from 30 degrees to 184 degrees Celsius. Tritium concentrations in sampled thermal waters are near zero and indicate the waters are at least 100 years old and may be considerably older. Stable-isotope data indicate it is unlikely that a single area of recharge or a single hot-water reservoir supplies all hot springs in the basin. Thermal springs discharged at least 15,800 acre-feet of water in 1980. Associated convective heat flux is 27 million calories per second. (USGS)

Open-File Report

Geology of the Bighorn Mountains

This report is the result of studies made in the field during the seasons of 1901, 1902, 1903, 1904, and 1905. It relates to an area of about 9,000 square miles, situated mainly in the north-central portion of Wyoming and extending northward into Montana. Its location and general surroundings are shown on PL II. It covers the greater portion of the Bighorn uplift, together with an adjoining area of the Great Plains on the east. It also includes a small part of the Bighorn Basin and the eastern end of the Bridger Range. The report describes the various rocks, their structure, history, and mineral resources, including underground water, coal, gypsum, and various other products. It also contains information as to surface waters available for irrigation. Throughout the work assistance has been rendered by Mr. C. A. Fisher, who mapped portions of the area, measured numerous sections, collected fossils, and examined most of the crystalline rocks; and the author is indebted to Mr. Albert Johannsen for some of the petrographic descriptions. Previous observers have given but little information regarding the geology of the Bighorn Mountains, though Dr. F. V. Hayden ascertained the general relations of the uplift in his exploration of the Northwest, and Mr. George H. Eldridge, who crossed the range near Bald Mountain and southwest of Buffalo during the summer of 1893, described 0 some of the broader features of the geologic succession and structure in a remarkably comprehensive manner, considering how small an area he had the opportunity to examine. The Bighorn region is very thinly settled, there being no permanent habitations among the mountains, and it is but little visited by others than hunters, prospectors, and herders. There have recently been established two summer resorts in the mountains, and each year a larger number of persons visit the region. Unfortunately the mineral prospects have proved disappointing to the prospectors, and there appears to be but little promise that the area will become important on account of its mineral resources. In the Bridger uplift promising prospects of gold and copper have recently been discovered, which may prove of value. There are extensive, forests in the mountains, which are now included in a Government forest reserve, but their timber is not of great value. Much of the area below timber line contains an abundance of luxuriant grasses and other plants, which afford excellent pasturage for stock, and large herds of sheep and cattle are ranged in the region during the short summer season. Game is moderately abundant, and most of the streams contain large numbers of trout. The region is one of great interest geologically on account of its variety of sedimentary rocks, interesting structure, and remarkably instructive glacial features. The central area, with its high peaks, presents alpine scenery of notable character. Doubtless in the future the region will be extensively visited by tourists, hunters, and geologists.

Montana, Wyoming

Spatially referenced statistical assessment of dissolved-solids load sources and transport in streams of the Upper Colorado River Basin

The Upper Colorado River Basin (UCRB) discharges more than 6 million tons of dissolved solids annually, about 40 to 45 percent of which are attributed to agricultural activities. The U.S. Department of the Interior estimates economic damages related to salinity in excess of $330 million annually in the Colorado River Basin. Salinity in the UCRB, as measured by dissolved-solids load and concentration, has been studied extensively during the past century. Over this period, a solid conceptual understanding of the sources and transport mechanisms of dissolved solids in the basin has been developed. This conceptual understanding was incorporated into the U.S. Geological Survey Spatially Referenced Regressions on Watershed Attributes (SPARROW) surface-water quality model to examine statistically the dissolved-solids supply and transport within the UCRB. Geologic and agricultural sources of dissolved solids in the UCRB were defined and represented in the model. On the basis of climatic and hydrologic conditions along with data availability, water year 1991 was selected for examination with SPARROW. Dissolved-solids loads for 218 monitoring sites were used to calibrate a dissolved-solids SPARROW model for the UCRB. The calibrated model generally captures the transport mechanisms that deliver dissolved solids to streams of the UCRB as evidenced by R2 and yield R2 values of 0.98 and 0.71, respectively. Model prediction error is approximated at 51 percent. Model results indicate that of the seven geologic source groups, the high-yield sedimentary Mesozoic rocks have the largest yield of dissolved solids, about 41.9 tons per square mile (tons/mi2). Irrigated sedimentary-clastic Mesozoic lands have an estimated yield of 1,180 tons/mi2, and irrigated sedimentary-clastic Tertiary lands have an estimated yield of 662 tons/mi2. Coefficients estimated for the seven landscape transport characteristics seem to agree well with the conceptual understanding of the role they play in the delivery of dissolved solids to streams in the UCRB. Predictions of dissolved-solids loads were generated for more than 10,000 stream reaches of the stream network defined in the UCRB. From these estimates, the downstream accumulation of dissolved solids, including natural and agricultural components, were examined in selected rivers. Contributions from each of the 11 dissolved-solids sources were also examined at select locations in the Grand, Green, and San Juan Divisions of the UCRB. At the downstream boundary of the UCRB, the Colorado River at Lees Ferry, Arizona, monitoring site, the dissolved-solids contribution of irrigated agricultural lands and natural sources were about 45 and 57 percent, respectively. Finally, model predictions, including the contributions of natural and agricultural sources for selected locations in the UCRB, were compared with results from two previous studies.

Arizona, Colorado, Idaho, New Mexico, Utah, Wyomin

Hydrogeology of the stratified-drift aquifers in the Cayuta Creek and Catatonk Creek valleys in parts of Tompkins, Schuyler, Chemung, and Tioga Counties, New York

The surficial deposits, areal extent of aquifers, and the water-table configurations of the stratified-drift aquifer systems in the Cayuta Creek and Catatonk Creek valleys and their large tributary valleys in Tompkins, Schuyler, Chemung, and Tioga Counties, New York were mapped in 2009, in cooperation with the New York State Department of Environmental Conservation. Well and test-boring records, surficial deposit maps, Light Detection and Ranging (LIDAR) data, soils maps, and horizontal-to-vertical ambient-noise seismic surveys were used to map the extent of the aquifers, construct geologic sections, and determine the depth to bedrock (thickness of valley-fill deposits) at selected locations. Geologic materials in the study area include sedimentary bedrock, unstratified drift (till), stratified drift (glaciolacustrine and glaciofluvial deposits), and recent alluvium. Stratified drift consisting of glaciofluvial sand and gravel is the major component of the valley fill in this study area. The deposits are present in sufficient amounts in most places to form extensive unconfined aquifers throughout the study area and, in some places, confined aquifers. Stratified drift consisting of glaciolacustrine fine sand, silt, and clay are present locally in valleys underlying the surficial sand and gravel deposits in the southern part of the Catatonk Creek valley. These unconfined and confined aquifers are the source of water for most residents, farms, and businesses in the valleys. A generalized depiction of the water table in the unconfined aquifer was constructed using water-level measurements made from the 1950s through 2010, as well as LIDAR data that were used to determine the altitudes of perennial streams at 10-foot contour intervals and water surfaces of ponds and wetlands that are hydraulically connected to the unconfined aquifer. The configuration of the water-table contours indicate that the general direction of groundwater flow within Cayuta Creek and Catatonk Creek stratified-drift aquifers is predominantly from the valley walls toward the main streams in the valleys. The groundwater discharges from the aquifer system to the main-stem streams in the valleys. Locally, the direction of groundwater flow is radially away from groundwater mounds that have formed beneath upland tributaries that typically lose water where they flow on alluvial fans in the valleys. In some places, groundwater that would normally flow toward streams is intercepted by pumping wells.

New York

Measurement of unsaturated hydraulic properties and evaluation of property-transfer models for deep sedimentary interbeds, Idaho National Laboratory, Idaho

Operations at the Idaho National Laboratory (INL) have the potential to contaminate the underlying Eastern Snake River Plain (ESRP) aquifer. Methods to quantitatively characterize unsaturated flow and recharge to the ESRP aquifer are needed to inform water-resources management decisions at INL. In particular, hydraulic properties are needed to parameterize distributed hydrologic models of unsaturated flow and transport at INL, but these properties are often difficult and costly to obtain for large areas. The unsaturated zone overlying the ESRP aquifer consists of alternating sequences of thick fractured volcanic rocks that can rapidly transmit water flow and thinner sedimentary interbeds that transmit water much more slowly. Consequently, the sedimentary interbeds are of considerable interest because they primarily restrict the vertical movement of water through the unsaturated zone. Previous efforts by the U.S. Geological Survey (USGS) have included extensive laboratory characterization of the sedimentary interbeds and regression analyses to develop property-transfer models, which relate readily available physical properties of the sedimentary interbeds (bulk density, median particle diameter, and uniformity coefficient) to water retention and unsaturated hydraulic conductivity curves. During 2013&ndash;14, the USGS, in cooperation with the U.S. Department of Energy, focused on further characterization of the sedimentary interbeds below the future site of the proposed Remote Handled Low-Level Waste (RHLLW) facility, which is intended for the long-term storage of low-level radioactive waste. Twelve core samples from the sedimentary interbeds from a borehole near the proposed facility were collected for laboratory analysis of hydraulic properties, which also allowed further testing of the property-transfer modeling approach. For each core sample, the steady-state centrifuge method was used to measure relations between matric potential, saturation, and conductivity. These laboratory measurements were compared to water-retention and unsaturated hydraulic conductivity parameters estimated using the established property-transfer models. For each core sample obtained, the agreement between measured and estimated hydraulic parameters was evaluated quantitatively using the Pearson correlation coefficient (r). The highest correlation is for saturated hydraulic conductivity ( K sat ) with an r value of 0.922. The saturated water content (q sat ) also exhibits a strong linear correlation with an r value of 0.892. The curve shape parameter (&lambda;) has a value of 0.731, whereas the curve scaling parameter (y o ) has the lowest r value of 0.528. The r values demonstrate that model predictions correspond well to the laboratory measured properties for most parameters, which supports the value of extending this approach for quantifying unsaturated hydraulic properties at various sites throughout INL.

Idaho

Geologic map of MTM -15027, -20027, -25027, and -25032 quadrangles, Margaritifer Terra region of Mars

Mars Transverse Mercator (MTM) quadrangles &minus;15027, &minus;20027, &minus;25027, and &minus;25032 (lat 12.5&deg;&minus;28&deg; S., long 330&deg;&minus;335&deg; E. and lat 22.5&deg;&minus;28&deg; S., long 324.5&deg;&minus;330&deg; E.) in southwestern Margaritifer Terra include diverse erosional landforms, sedimentary deposits, and tectonic structures that record a long geologic and geomorphic history. The northeastern regional slope of the pre-Noachian crustal dichotomy (as expressed along the Chryse trough) and structures of the informally named Middle Noachian or older Holden and Ladon impact basins dominate the topography of the map area. A series of mesoscale outflow channels, Uzboi, Ladon, and Morava Valles, integrated these formerly enclosed basins by overflow and incision around the Noachian/Hesperian transition, although some flooding may have occurred earlier. The area includes excellent examples of Late Noachian to Hesperian valley networks, dissected crater rims, alluvial fans, deltas, and light-toned layered deposits, particularly in Holden and Eberswalde craters. Structural forms include Tharsis-radial grabens, Hesperian wrinkle ridges, floor-fractured impact craters, and severely disrupted chaotic terrains. These well-preserved landforms and sedimentary deposits represent multiple erosional epochs and discrete flooding events, which provide significant insight into the geomorphic processes and climate change on early Mars.

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