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Hydrologic effects of possible changes in water-supply withdrawals from, and effluent recharge to, the Kirkwood-Cohansey aquifer system, Winslow Township, Camden County, New Jersey

Winslow Township and the Camden County Municipal Utility Authority (CCMUA) developed a plan to shut down the Winslow sewage-treatment facility and associated effluent infiltration facility and transfer the effluent to the CCMUA sewage-treatment facility on the Delaware River in Camden, New Jersey. Winslow Township reduced groundwater withdrawals from the Kirkwood-Cohansey aquifer system to offset groundwater recharge lost with the cessation of effluent infiltration. The U.S. Geological Survey, in cooperation with Winslow Township and the CCMUA, collected data to evaluate conditions prior to cessation of effluent infiltration and installed two continuous-record streamflow-gaging stations. Streamflow measurements also were made at two low-flow partial-record sites, and groundwater levels were measured in 17 wells at high and low water-level periods (May and September 2010). A groundwater-flow model provides estimated changes in base flow of the Great Egg Harbor River under several groundwater-withdrawal and effluent infiltration scenarios. Water levels were measured in an observation well 480 feet (ft) from the infiltration lagoons during 1971–2010. A downward trend in water levels in the well prior to 1985 is attributed in part to increased impervious surfaces and groundwater withdrawals associated with development in the area that began in the early 1970s. From late 1985 to 2010, there was an upward trend in water levels in the well that is attributed to the construction of nearby effluent infiltration lagoons in 1985 and the increasing rate of effluent infiltration during the period. Recent and historical measurements made at the four surface-water sites were correlated with same-day discharges measured at three nearby index stations to estimate continuous low-flow record at the sites. Effects on base flow caused by reductions in groundwater withdrawals or the cessation of effluent infiltration in Winslow Township could not be ascertained from the available data with the statistical and analysis methods used. Groundwater discharge to streams (base flow) was simulated with a groundwater-flow model of the Great Egg Harbor and Mullica River Basins. Simulated monthly base flows using 2008–10 withdrawal rates and effluent recharge (Scenario 1) are generally about 1.5 million gallons per day (Mgal/d) greater than simulated base flows using 2003–07 withdrawal rates (Baseline Scenario) because of the 1.57 Mgal/d reduction in average withdrawals by Winslow Township from the Kirkwood-Cohansey aquifer system from 2003–07 to 2008–10. Simulated monthly base flows using 2008–10 withdrawals but without effluent infiltration (Scenario 2) are very similar to, but typically slightly lower than, Baseline Scenario base flows. Three hypothetical future distributions of groundwater withdrawals from existing Winslow Township wells are simulated, each without effluent infiltration and using the same groundwater withdrawal rate as Scenario 2, but with different hypothetical distributions of withdrawals among existing Winslow Township wells. The Scenario 3 and 4 base flows are greater than the Baseline Scenario base flows in all months, and the Scenario 5 base flows are less than the Baseline Scenario base flows in all months. The simulation results indicate that a reduction in average withdrawals from the Kirkwood-Cohansey aquifer system by 1.57 Mgal/d offsets the reduction of effluent infiltration by about the same rate, resulting in nearly unchanged base flows in the Great Egg Harbor River near Blue Anchor (01410820).

New Jersey

Water-level conditions in selected confined aquifers of the New Jersey and Delaware coastal plain, 2003

The Coastal Plain aquifers of New Jersey provide an important source of water for more than 2 million people. Steadily increasing withdrawals from the late 1800s to the early 1990s resulted in declining water levels and the formation of regional cones of depression. In addition to decreasing water supplies, declining water levels in the confined aquifers have led to reversals in natural hydraulic gradients that have, in some areas, induced the flow of saline water from surface-water bodies and adjacent aquifers to freshwater aquifers. In 1978, the U.S. Geological Survey began mapping the potentiometric surfaces of the major confined aquifers of New Jersey every 5 years in order to provide a regional assessment of ground-water conditions in multiple Coastal Plain aquifers concurrently. In 1988, mapping of selected potentiometric surfaces was extended into Delaware. During the fall of 2003, water levels measured in 967 wells in New Jersey, Pennsylvania, northeastern Delaware, and northwestern Maryland were used estimate the potentiometric surface of the principal confined aquifers in the Coastal Plain of New Jersey and five equivalent aquifers in Delaware. Potentiometric-surface maps and hydrogeologic sections were prepared for the confined Cohansey aquifer of Cape May County, the Rio Grande water-bearing zone, the Atlantic City 800-foot sand, the Vincentown aquifer, and the Englishtown aquifer system in New Jersey, as well as for the Piney Point aquifer, the Wenonah-Mount Laurel aquifer, and the Upper Potomac-Raritan-Magothy, the Middle and undifferentiated Potomac-Raritan-Magothy, and the Lower Potomac-Raritan-Magothy aquifers in New Jersey and their equivalents in Delaware. From 1998 to 2003, water levels in many Coastal Plain aquifers in New Jersey remained stable or had recovered, but in some areas, water levels continued to decline as a result of pumping. In the Cohansey aquifer in Cape May County, water levels near the center of the cone of depression underlying the southern part of the peninsula remained about the same as in 1998. To the south, recoveries up to 8 feet were observed in southern Lower Township as withdrawals had decreased since 1998. In the northern part of Cape May County, water levels had not changed substantially from historic conditions. In the Rio Grande water-bearing zone, water levels rose by as much as 13 ft at the Rio Grande well field; elsewhere across the aquifer, little change had occurred. In the Atlantic City 800-foot sand, water-level changes were greatest in southern Cape May County; at the Cape May desalination wells, water levels were as much as 32 ft lower in 2003 than in 1998. In contrast, water levels at the center of a regional cone of depression near Atlantic City rose by as much as 10 ft. Within the Piney Point aquifer water levels rose by 46 ft near Seaside Park. Similarly, water levels increased by more than 30 ft in and around the major cone of depression underlying Dover, Delaware. In the Vincentown aquifer, water levels stabilized or recovered by 2 ft to 6 ft from 1998 to 2003 in most of the wells measured; the exception is near Adelphia in Monmouth County, where water levels rose by as much as 18 ft. From 1998 to 2003, water levels near the center of a large cone of depression that extends from Monmouth to Ocean County recovered by as much as 20 ft in the Wenonah-Mount Laurel aquifer. Concurrently, ground-water levels within the Englishtown aquifer system declined by as much as 13 ft in the same area. Water levels across much of the Upper Potomac-Raritan-Magothy aquifer in the northern Coastal Plain remained about the same as 5 years previous, except in northern Ocean County where ground-water levels declined 10 ft to 33 ft. Water levels in the Middle Potomac-Raritan-Magothy aquifer declined from 5 to 9 ft along the border between Monmouth and Middlesex County. Elsewhere, across the northern part of the Coastal Plain, water levels stabilized within the Cretaceous-a

Delaware, New Jersey

Use of a ground-water flow model to delineate contributing areas to the Puchack Well Field, Pennsauken township and vicinity, Camden county, New Jersey

The New Jersey Department of Environmental Protection (NJDEP) Well Head Protection Program, developed in response to the 1986 Federal Safe Drinking Water Act Amendments, requires delineation of Well Head Protection Areas (WHPA's), commonly called contributing areas, for all public and non-community water-supply wells in New Jersey. Typically, WHPA's for public community water-supply wells in New Jersey are delineated using a two-dimensional ground-water flow model incorporating the regional hydraulic gradient; however, NJDEP guidelines allow for the use of a three-dimensional flow model to delineate contributing areas to wells in complex hydrogeologic settings. The Puchack well field in Pennsauken Township, Camden County, N.J., is an area of strong hydraulic connection between the Lower aquifer of the Potomac-Raritan-Magothy aquifer system and the Delaware River. Interactions among and within the public-supply well fields in the area are complex. To delineate the contributing area to the Puchack well field, the U.S. Geological Survey, in cooperation with the NJDEP, developed an 11-layer ground-water flow model of the Potomac-Raritan-Magothy aquifer system in the Pennsauken Township area to simulate flow in the vicinity of the well field. The model incorporates the interaction between the aquifer system and the Delaware River, and includes boundary flows from an existing regional model of the Camden area. Recharge used in the model ranged from 4.5 to 14 inches per year, and horizontal hydraulic conductivity ranged from 50 to 250 feet per day. Values of vertical hydraulic conductivity ranging from 0.001 to 0.5 feet per day were assigned to zones created on the basis of variations in hydrogeologic conditions observed in geophysical logs from wells. A steady-state simulation was used to calibrate the model to synoptic water-level data collected in March 1998. Near the Puchack well field, simulated heads generally were within 1 foot of the measured heads in both the Middle and Lower aquifers. Simulated water-level differences across the confining units at most of the nested wells were within ? 0.5 feet of the differences calculated from measured water levels. The existing flow model was modified to meet NJDEP guidelines for delineating contributing areas in complex hydrogeologic settings. These modifications included rediscretizing the model grid to a finer grid and preparing the water-use data set for use in the rediscretized model. The contributing area to the Puchack well field was delineated by means of particle tracking. An uncertainty analysis was conducted in which 36 model-input parameters were both increased and decreased until the resulting change in simulated heads exceeded the model-calibration criterion of ? 5 feet at any model cell. Porosity most affected the size and shape of the contributing area. The distribution of withdrawals at the Morris/Delair well field and variations in recharge affected both the size and shape of contributing area to the Puchack well field and the source of water to the Puchack wells. The results of the uncertainty analysis were combined to determine the 'aggregate' contributing area to the Puchack well field--a composite of areas on the land surface that contributed flow to the Puchack well field in less than 12 years in any uncertainty simulation. The shape of the aggregate contributing area was most similar to that associated with a reduction in porosity, which indirectly affected the size and shape of the contributing areas by changing travel time.

Scientific Investigations Report

Total mercury and methylmercury in fish fillets, water, and bed sediments from selected streams in the Delaware River basin, New Jersey, New York, and Pennsylvania, 1998-2001

Within the Delaware River Basin, fish-tissue samples were analyzed for total mercury (tHg). Water and bed-sediment samples were analyzed for tHg and methylmercury (MeHg), and methylation efficiencies were calculated. This study was part of a National Mercury Pilot Program conducted by the U.S. Geological Survey (USGS). The Delaware River Basin was chosen because it is part of the USGS National Water-Quality Assessment Program that integrates physical, chemical, and biological sampling efforts to determine status and trends in surface-water and ground-water resources. Of the 35 sites in the study, 31 were sampled for fish. The species sampled at these sites include smallmouth bass (Micropterus dolomieu), the target species, and where smallmouth bass could not be collected, brown trout (Salmo trutta), chain pickerel (Esox niger), largemouth bass (Micropterus salmoides), and rock bass (Ambloplites rupestris). There were a total of 32 fish samples; 7 of these exceeded the 0.3 microgram per gram wet-weight mercury (Hg) concentration set for human health by the U.S. Environmental Protection Agency and 27 of these exceeded the U.S. Fish and Wildlife Service criteria of 0.1 microgram per gram wet weight for the protection of fish-eating birds and wildlife. Basinwide analysis of Hg in fish, water, and bed sediment showed tHg concentration in fillets correlated positively with population density, urban land cover, and impervious land surface. Negative correlations included wetland land cover, septic density, elevation, and latitude. Smallmouth bass from the urban sites had a higher median concentration of tHg than fish from agricultural, low intensity-agricultural, or forested sites. Concentrations of tHg and MeHg in water were higher in samples from the more urbanized areas of the basin and were positively correlated with urbanization and negatively correlated with forested land cover. Methylation efficiency of water was negatively correlated with urbanization. Bed-sediment patterns were similar to those observed in water. Concentrations of tHg were higher in samples from the urbanized areas. In the more forested areas, MeHg concentrations were higher than in other land-use areas. Concentrations of tHg in bed sediment were positively correlated with urbanization factors (population, urban land cover, and impervious land surface) and negatively correlated with forested land cover and elevation. Forested land cover and latitude were positively correlated with concentrations of MeHg. The methylation efficiency was higher in samples from the forested areas and was negatively correlated with urbanization. Analyses within land-use groups showed that tHg concentrations in fish fillets from the urban sites were positively correlated with forested land cover and wetland cover. Urbanization factors within the agricultural group were positively correlated with tHg in fish; concentrations of tHg in fish from sites in the low intensity-agricultural group were negatively correlated with urbanization factors. Within the agricultural land-use group, tHg concentrations in water were negatively correlated with septic density, and MeHg concentrations were negatively correlated with elevation. In the forested and low intensity-agricultural groups, MeHg in water was negatively correlated with forested and agricultural land cover. Methylation efficiency in water also was negatively correlated with forested land cover but positively correlated with agricultural land cover. Bed-sediment concentrations of tHg in the forested and low-agricultural groups were positively correlated with agricultural land cover and negatively correlated with forested land cover. Concentrations of MeHg in bed sediment were positively correlated with septic density and drainage area and negatively correlated with forested land cover. Methylation efficiency was negatively correlated with population density, agricultural land cover, and sulfate concentrations in water. An urbanization effect was observed in all three media—fish, water, and bed sediment. Different factors, basinwide and within land-use groups, showed a complex relation. Additional sampling within these land-use groups could help characterize interrelations of Hg in the environment to fish in the Delaware River Basin.

New Jersey, New York, Pennsylvania

Simulation of ground-water flow in the Potomac-Raritan-Magothy aquifer system, Pennsauken Township and vicinity, New Jersey

The Potomac-Raritan-Magothy aquifer system is one of the primary sources of potable water in the Coastal Plain of New Jersey, particularly in heavily developed areas along the Delaware River. In Pennsauken Township, Camden County, local drinking-water supplies from this aquifer system have been contaminated by hexavalent chromium at concentrations that exceed the New Jersey maximum contaminant level. In particular, ground water at the Puchack well field has been adversely affected to the point where, since 1984, water is no longer withdrawn from this well field for public supply. The area that contains the Puchack well field was added to the National Priorities List in 1998 as a Superfund site. The U.S. Geological Survey (USGS) conducted a reconnaissance study from 1996 to 1998 during which hydrogeologic and water-quality data were collected and a ground-water-flow model was developed to describe the conditions in the aquifer system in the Pennsauken Township area. The current investigation by the USGS, in cooperation with the U.S. Environmental Protection Agency (USEPA), is an extension of the previous study. Results of the current study can be applied to a Remedial Investigation and Feasibility Study conducted at the Puchack well field Superfund site. The USGS study collected additional data on the hydrogeology and water-quality in the area. These data were incorporated into a refined model of the ground-water-flow system in the Potomac-Raritan-Magothy aquifer system. A finite-difference model was developed to simulate ground-water flow and the advective transport of chromium-contaminated ground water in the aquifers of the Potomac-Raritan-Magothy aquifer system in the Pennsauken Township area. An 11-layer model was used to represent the complex hydrogeologic framework. The model was calibrated using steady-state water-level data from March 1998, April 1998, and April 2001. Water-level recovery during the shutdown of Puchack 1 during March to April 1998 was simulated to evaluate model performance in relation to changing stresses. The Delaware River contributes appreciable-flow to the ground-water system from areas where the Middle and Lower aquifers crop out beneath the river. A transient simulation of an aquifer test near the Delaware River was run to help characterize the hydraulic conductivity of the riverbed sediments represented in the model. Vertical flow across confining units between the aquifers is highly variable and is important in the movement of water and associated contaminants through the flow system. The model was imbedded within a regional model of the Potomac-Raritan-Magothy aquifer system in Camden County. In general, a simulation of baseline conditions, which can provide a representation on which simulations of various alternatives can be based for the feasibility study, incorporated average conditions from 1998 to 2000. Ground-water withdrawals within the model area during this period averaged about 14 Mgal/d. Regional ground-water flow is from recharge areas and from the Delaware River to downgradient pumped wells located just east of the model area in central Camden County. Simulation results show an important connection between the Intermediate sand and the Lower aquifer of the Potomac-Raritan-Magothy aquifer system in the vicinity of the chromium-contaminated area. The Delaware River contributes nearly 10 Mgal/d to the flow system, whereas recharge contributes about 6 Mgal/d. Ground-water withdrawals within the model area account for nearly 14 Mgal/d (mostly from the Lower aquifer of the Potomac-Raritan-Magothy aquifer system).

Scientific Investigations Report

Organic compounds and cadmium in the tributaries to the Elizabeth River in New Jersey, October 2008 to November 2008: Phase II of the New Jersey Toxics Reduction Workplan for New York-New Jersey Harbor

Samples of surface water and suspended sediment were collected from the two branches that make up the Elizabeth River in New Jersey - the West Branch and the Main Stem - from October to November 2008 to determine the concentrations of selected chlorinated organic and inorganic constituents. The sampling and analyses were conducted as part of Phase II of the New York-New Jersey Harbor Estuary Plan-Contaminant Assessment and Reduction Program (CARP), which is overseen by the New Jersey Department of Environmental Protection. Phase II of the New Jersey Workplan was conducted by the U.S. Geological Survey to define upstream tributary and point sources of contaminants in those rivers sampled during Phase I work, with special emphasis on the Passaic and Elizabeth Rivers. This portion of the Phase II study was conducted on the two branches of the Elizabeth River, which were previously sampled during July and August of 2003 at low-flow conditions. Samples were collected during 2008 from the West Branch and Main Stem of the Elizabeth River just upstream from their confluence at Hillside, N.J. Both tributaries were sampled once during low-flow discharge conditions and once during high-flow discharge conditions using the protocols and analytical methods that were used in the initial part of Phase II of the Workplan. Grab samples of streamwater also were collected at each site and were analyzed for cadmium, suspended sediment, and particulate organic carbon. The measured concentrations, along with available historical suspended-sediment and stream-discharge data were used to estimate average annual loads of suspended sediment and organic compounds in the two branches of the Elizabeth River. Total suspended-sediment loads for 1975 to 2000 were estimated using rating curves developed from historical U.S. Geological Survey suspended-sediment and discharge data, where available. Concentrations of suspended-sediment-bound polychlorinated biphenyls (PCBs) in the Main Stem and the West Branch of the Elizabeth River during low-flow conditions were 534 ng/g (nanograms per gram) and 1,120 ng/g, respectively, representing loads of 27 g/yr (grams per year) and 416 g/yr, respectively. These loads were estimated using contaminant concentrations during low flow, and the assumed 25-year average discharge, and 25-year average suspended-sediment concentration. Concentrations of suspended-sediment-bound PCBs in the Main Stem and the West Branch of the Elizabeth River during high-flow conditions were 3,530 ng/g and 623 ng/g, respectively, representing loads of 176 g/yr and 231 g/yr, respectively. These loads were estimated using contaminant concentrations during high-flow conditions, the assumed 25-year average discharge, and 25-year average suspended-sediment concentration. Concentrations of suspended-sediment-bound polychlorinated dibenzo-p-dioxins and polychlorinated dibenzo-p-difuran compounds (PCDD/PCDFs) during low-flow conditions were 2,880 pg/g (picograms per gram) and 5,910 pg/g in the Main Stem and West Branch, respectively, representing average annual loads of 0.14 g/yr and 2.2 g/yr, respectively. Concentrations of suspended-sediment-bound PCDD/PCDFs during high-flow conditions were 40,900 pg/g and 12,400 pg/g in the Main Stem and West Branch, respectively, representing average annual loads of 2.05 g/yr and 4.6 g/yr, respectively. Total toxic equivalency (TEQ) loads (sum of PCDD/PCDF and PCB TEQs) were 3.1 mg/yr (milligrams per year) (as 2, 3, 7, 8-TCDD) in the Main Stem and 28 mg/yr in the West Branch during low-flow conditions. Total TEQ loads (sum of PCDD/PCDFs and PCBs) were 27 mg/yr (as 2, 3, 7, 8-TCDD) in the Main Stem and 32 mg/yr in the West Branch during high-flow conditions. All of these load estimates, however, are directly related to the assumed annual discharge for the two branches. Long-term measurement of stream discharge and suspended-sediment concentrations would be needed to verify these loads. On the basis of the loads cal

Scientific Investigations Report

Hydrogeologic Framework in Three Drainage Basins in the New Jersey Pinelands, 2004-06

The U.S. Geological Survey, in cooperation with the New Jersey Pinelands Commission, began a multi-phase hydrologic investigation in 2004 to characterize the hydrologic system supporting the aquatic and wetland communities of the New Jersey Pinelands area (Pinelands). The Pinelands is an ecologically diverse area in the southern New Jersey Coastal Plain underlain by the Kirkwood-Cohansey aquifer system. The demand for ground water from this aquifer system is increasing as local development increases. To assess the effects of ground-water withdrawals on Pinelands stream and wetland water levels, three drainage basins were selected for detailed hydrologic assessments, including the Albertson Brook, McDonalds Branch and the Morses Mill Stream basins. Study areas were defined surrounding the three drainage basins to provide sub-regional hydrogeologic data for the ground-water flow modeling phase of this study. In the first phase of the hydrologic assessments, a database of hydrogeologic information and a hydrogeologic framework model for each of the three study areas were produced. These framework models, which illustrate typical hydrogeologic variations among different geographic subregions of the Pinelands, are the structural foundation for predictive ground-water flow models to be used in assessing the hydrologic effects of increased ground-water withdrawals. During 2004-05, a hydrogeologic database was compiled using existing and new geophysical and lithologic data including suites of geophysical logs collected at 7 locations during the drilling of 21 wells and one deep boring within the three study areas. In addition, 27 miles of ground-penetrating radar (GPR) surface geophysical data were collected and analyzed to determine the depth and extent of shallow clays in the general vicinity of the streams. On the basis of these data, the Kirkwood-Cohansey aquifer system was divided into 7 layers to construct a hydrogeologic framework model for each study area. These layers are defined by their predominant sediment textures as aquifers and leaky confining layers. The confining layer at the base of the Kirkwood-Cohansey aquifer system, depending on location, is defined as one of two distinct clays of the Kirkwood Formation. The framework models are described using hydrogeologic sections, maps of structure tops of layers, and thickness maps showing variations of sediment textures of the various model layers. The three framework models are similar in structure but unique to their respective study areas. The hydraulic conductivity of the Kirkwood-Cohansey aquifer system in the vicinity of the three study areas was determined from analysis of 16 slug tests and 136 well-performance tests. The mean values for hydraulic conductivity in the three study areas ranged from about 84 feet per day to 130 feet per day. With the exception of the basal confining layers, the variable and discontinuous nature of clay layers within the Kirkwood-Cohansey aquifer system was confirmed by the geophysical and lithologic records. Leaky confining layers and discontinuous clays are generally more common in the upper part of the aquifer system. Although the Kirkwood-Cohansey aquifer system generally has been considered a water-table aquifer in most areas, localized clays in the aquifer layers and the effectiveness of the leaky confining layers may act to impede the flow of ground water in varying amounts depending on the degree of confinement and the location, duration, and magnitude of the hydraulic stresses applied. Considerable variability exists in the different sediment textures. The extent to which this hydrogeologic variability can be characterized is constrained by the extent of the available data. Thus, the hydraulic properties of the modeled layers were estimated on the basis of available horizontal hydraulic conductivity data and the range of sediment textures estimated from geophysical and lithologic data.

Scientific Investigations Report

Relations of Water Quality to Streamflow, Season, and Land Use for Four Tributaries to the Toms River, Ocean County, New Jersey, 1994-99

The effects of nonpoint-source contamination on the water quality of four tributaries to the Toms River in Ocean County, New Jersey, have been investigated in a 5-year study by the U.S. Geological Survey (USGS), in cooperation with the New Jersey Department of Environmental Protection (NJDEP). The purpose of the study was to relate the extent of land development to loads of nutrients and other contaminants to these streams, and ultimately to Barnegat Bay. Volumetric streamflow (discharge) was measured at 6 monitoring sites during 37 stormflow and base-flow sampling events over a 5-year period (May 1994-September 1999). Concentrations and yields (area-normalized instantaneous load values) of nitrogen and phosphorus species, total suspended solids, and fecal coliform bacteria were quantified, and pH, dissolved oxygen, and stream stage were monitored during base-flow conditions and storms. Sufficient data were collected to allow for a statistical evaluation of differences in water quality among streams in subbasins with high, medium, and low levels of land development. Long Swamp Creek, in a highly developed subbasin (64.2 percent developed); Wrangle Brook, in a moderately developed subbasin (34.5 percent); Davenport Branch, in a slightly developed subbasin (22.8 percent); and Jakes Branch, in an undeveloped subbasin (0 percent) are the subbasins selected for this study. No point-source discharges are known to be present on these streams. Water samples were collected and analyzed by the NJDEP, and discharge measurements and data analysis were conducted by the USGS. Total nitrogen concentrations were lower in Davenport Branch than in Long Swamp Creek and Wrangle Brook during base flow and stormflow. Concentrations of total nitrogen and nitrate were highest in Wrangle Brook (as high as 3.0 mg/L and 1.6 mg/L, respectively) as a result of high concentrations of nitrate in samples collected during base flow; nitrate loading from ground-water discharge is much higher in Wrangle Brook than in any of the other streams, possibly as a result of an experimental wastewater-(secondary effluent) disposal site that was in operation during the 1980's. Ammonia concentrations were higher in samples from Long Swamp Creek than in those from the other two monitoring sites under all flow conditions, and ammonia yields were higher during stormflow than base flow at all monitoring sites. Concentrations and yields of fecal coliform bacteria and total suspended solids were higher during stormflow than during base flow at all monitoring sites. Concentrations and yields were significantly higher in Long Swamp Creek, a highly developed subbasin and Wrangle Brook, a moderately developed subbasin than in Davenport Branch, a slightly developed subbasin. Concentrations and yields of phosphate species, which also are strongly related to stormflow, were higher during stormflow in Long Swamp Creek than in the other subbasins. Base-flow separation techniques were used on hydrographs generated for storms to distinguish the fraction of discharge and constituent loading attributable to storm runoff (overland flow) from the fraction contributed by ground-water discharge. Precipitation records were used to determine the total annual volumes of ground-water discharge and runoff at each monitoring site. These volumes were used in conjunction with water-quality data to calculate total annual loads of each constituent at each monitoring site, separated into ground-water discharge and runoff fractions. It was determined that loads of ammonia, nitrate, organic nitrogen, total nitrogen, and orthophosphate in ground-water discharge were significantly higher in the moderately developed Wrangle Brook subbasin than in the highly developed Long Swamp Creek subbasin, and that no relation was apparent between the percent of land development and constituent loads from ground-water discharge. The loading of each constituent contributed by ground-water discharge is specific

Scientific Investigations Report

Estimated ground-water availability in the Delaware River basin, 1997-2000

Ground-water availability using a watershed-based approach was estimated for the 147 watersheds that make up the Delaware River Basin. This study, conducted by the U.S. Geological Survey in cooperation with the Delaware River Basin Commission (DRBC), supports the DRBC's Water Resources Plan for the Delaware River Basin. Different procedures were used to estimate ground-water availability for the region underlain by fractured rocks in the upper part of the basin and for surficial aquifers in the region underlain by unconsolidated sediments in the lower part of the basin. The methodology is similar to that used for the Delaware River Basin Commission's Ground-Water Protected Area in Pennsylvania. For all watersheds, ground-water availability was equated to average annual base flow. Ground-water availability for the 109 watersheds underlain by fractured rocks in Delaware, New Jersey, New York, and Pennsylvania was based on lithology and physiographic province. Lithology was generalized by grouping 183 geologic units into 14 categories on the basis of rock type and physiographic province. Twenty-three index streamflow-gaging stations were selected to represent the 14 categories. A base-flow-recurrence analysis was used to determine the average annual 2-, 5-, 10-, 25-, and 50-year-recurrence intervals for each index station. A GIS analysis used lithology and base flow at the index stations to determine the average annual base flow for the 109 watersheds. Average annual base flow for these watersheds ranged from 0.313 to 0.915 million gallons per day per square mile for the 2-year-recurrence interval to 0.150 to 0.505 million gallons per day per square mile for the 50-year-recurrence interval. Ground-water availability for watersheds underlain by unconsolidated surficial aquifers was based on predominant surficial geology and land use, which were determined from statistical tests to be the most significant controlling factors of base flow. Twenty-one index streamflow-gaging stations were selected to represent the 13 categories of predominant surficial geology and land use for the 38 Coastal Plain watersheds. A base-flow-recurrence analysis was used to determine the average annual 2-, 5-, 10-, 25-, and 50-year-recurrence intervals for each group of predominant surficial geology and land use. Average annual base flow for these watersheds ranged from 0.465 to 1.169 million gallons per day per square mile for the 2-year-recurrence interval to 0.178 to 0.670 million gallons per day per square mile for the 50-year-recurrence interval. Estimated 2-, 5-, 10-, 25-, and 50-year annual base-flow-recurrence interval values for each watershed in the Delaware River Basin are considered to be the quantity of ground water available for each watershed over a range of climatic conditions. The recurrence intervals are considered to be relative indicators of climatic difference; the 2-year-recurrence value represents wetter years, and the 50-year-recurrence value represents drier years. The remaining available ground water in each watershed was determined by subtracting current (1997-2000) ground-water withdrawals and consumptive domestic use and adding water recharged by agricultural irrigation and land application of treated-sewage effluent. Ground-water use ranged from 0 to 60.8 percent of available ground water for the 2-year-recurrence interval; it exceeded 25 percent in four watersheds and 50 percent in two watersheds. Ground-water use ranged from 0 to 75.9 percent of available ground water for the 5-year-recurrence interval; it exceeded 25 percent in five watersheds and 50 percent in three watersheds. Ground-water use ranged from 0 to 84.5 percent of available ground water for the 10-year-recurrence interval; it exceeded 25 percent in seven watersheds and 50 percent in four watersheds. Ground-water use ranged from 0 to 103 percent of available ground water for the 25-year-recurrence interval; it exceeded 25 percent in nine watersheds, 5

Delaware, New Jersey, New York, Pennsylvania

Potentiometric surface maps and groundwater-level hydrographs for confined aquifers of the New Jersey Coastal Plain, 2018

The U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection (NJDEP), prepared potentiometric surface maps for 10 confined aquifers of the New Jersey Coastal Plain physiographic province based on water-level measurements collected during late 2018 and early 2019 from 951 wells in New Jersey and parts of Pennsylvania and Delaware. Maps were prepared for the confined Cohansey aquifer, Rio Grande water-bearing zone, Atlantic City 800-foot sand, Piney Point aquifer, Vincentown aquifer, Wenonah-Mount Laurel aquifer, Englishtown aquifer system, and the upper, middle, and lower aquifers of the Potomac-Raritan-Magothy aquifer system. Potentiometric surface maps indicate regional cones of depression in the following aquifers and the counties in which they are centered: Atlantic City 800-foot sand in Atlantic County, the Piney Point aquifer in Cumberland County, the Wenonah-Mount Laurel aquifer and Englishtown aquifer system in Monmouth and Ocean Counties, the Wenonah-Mount Laurel aquifer in Camden and Gloucester County, the upper aquifer of the Potomac-Raritan-Magothy aquifer system in Ocean County, and the upper, middle, and lower aquifers of the Potomac-Raritan-Magothy aquifer system in Camden County. Cones of depression with smaller areal extents were in the confined Cohansey aquifer, the Rio Grande water-bearing zone, the Atlantic City 800-foot sand centered in Cape May County, the Piney Point aquifer centered in Ocean County, the Wenonah-Mount Laurel aquifer in Salem and Burlington Counties, the Englishtown aquifer system in Camden County, the upper aquifer of the Potomac-Raritan-Magothy aquifer system in Monmouth County, and the middle aquifer of the Potomac-Raritan-Magothy aquifer system in Monmouth, Ocean, and Salem Counties. No cone of depression was interpreted in the Vincentown aquifer. Long-term hydrographs are presented for 75 wells spanning each of the 10 confined aquifers, and contain a mix of discrete water-level measurements and daily mean water levels based on continuously recorded 15-minute data. Changes of water levels during 2014–19, as indicated by the hydrographs, were compared with those of previous periods to assess any departures from historical data. During 2014–19, water levels were stable and fluctuated within similar ranges as previous periods in the following aquifers and locations: all wells in the confined Cohansey aquifer, the Rio Grande water-bearing zone, the Vincentown aquifer, the Englishtown aquifer system, the Piney Point aquifer wells in Burlington and Ocean Counties, six of eight wells in the Wenonah-Mount Laurel aquifer, all wells in the upper and lower aquifers of the Potomac-Raritan-Magothy aquifer system outside NJDEP Critical Areas, and all wells in the middle aquifer of the Potomac-Raritan-Magothy aquifer system except those within NJDEP Critical Area II. Increasing water levels in 2014–19, ongoing since historical periods, were indicated in the following aquifers and locations: Atlantic County wells in the Piney Point aquifer, all wells in the upper and lower aquifers of the Potomac-Raritan-Magothy aquifer system outside NJDEP Critical Areas, and all wells in the middle aquifer of the Potomac-Raritan-Magothy aquifer system within NJDEP Critical Area II. Water levels in the Atlantic City 800-foot sand also increased during 2014–19 in wells in Atlantic County and northern Cape May County closer to the center of the cone of depression in that aquifer, which is a response unique to this period and absent from previous periods. During 2013–19, continued decreasing water levels, ongoing since previous periods, were indicated by hydrographs of Atlantic City 800-foot sand wells in southern Cape May County, Piney Point aquifer wells in Cumberland County where the regional cone of depression is located, and two wells in the Wenonah-Mount Laurel aquifer—070478, which in 2014–19 departed from previous periods, and 330020, which continued a gradual decrease throughout its period of record.

New Jersey

Water-level conditions in the confined aquifers of the New Jersey Coastal Plain, 2013

The Coastal Plain aquifers of New Jersey provide an important source of water for more than 3.5 million people. In 2013, groundwater withdrawals from 10 confined aquifers of the New Jersey Coastal Plain totaled about 190 million gallons per day. Steadily increasing withdrawals from the late 1800s to the early 1990s resulted in declining water levels and the formation of regional cones of depression in many confined Coastal Plain aquifers. Starting in 1978, the U.S. Geological Survey (USGS) began mapping the potentiometric surfaces of the major confined Coastal Plain aquifers every 5 years to provide a regional assessment of groundwater conditions. In a study conducted by the USGS, in cooperation with the New Jersey Department of Environmental Protection, water levels in 10 confined aquifers of the New Jersey Coastal Plain were measured and evaluated to provide a regional overview of groundwater conditions during fall 2013. Water levels were measured in 987 wells in New Jersey, and parts of Pennsylvania and Delaware. Potentiometric-surface maps were prepared for, in ascending order of age, the confined Cohansey aquifer of Cape May County, Rio Grande water-bearing zone, Atlantic City 800-foot sand, Piney Point aquifer, Vincentown aquifer, Wenonah-Mount Laurel aquifer, Englishtown aquifer system, and the Upper, Middle, and Lower aquifers of the Potomac-Raritan-Magothy (PRM) aquifer system. Persistent, regionally extensive cones of depression were present in the potentiometric surfaces of the Englishtown aquifer system and Wenonah-Mount Laurel aquifer in Ocean and Monmouth Counties; Wenonah-Mount Laurel and Upper, Middle, and Lower PRM aquifers in Camden County; and Atlantic City 800-foot sand in Atlantic County. Changes in water levels from 2008 to 2013 were measured in many Coastal Plain aquifers in New Jersey. In some areas, water levels continued to decline as a result of pumping, but in other areas water levels continued to recover as a result of regulated decreases in groundwater withdrawals. Since 2008, in the confined Cohansey aquifer in Cape May County, water levels generally did not change; however, cones of depression in the potentiometric surface of the Piney Point aquifer in some areas of Cumberland County deepened by more than 20 feet (ft). In Critical Area 1, an area of restricted withdrawals, measured water levels in the Wenonah-Mount Laurel aquifer declined in parts of southern Monmouth County by more than 10 ft; however, rises in water levels of more than 10 ft were measured in parts of northern Ocean and Monmouth Counties. Since 2008, in Critical Area 2, also an area of restricted withdrawals, measured water levels in the Wenonah-Mount Laurel aquifer rose more than 20 ft in parts of western Burlington County and more than 20 ft in parts of western Camden County. Since 2008, in Critical Area 1, measured water levels in the Englishtown aquifer system declined in parts of eastern Ocean County by more than 10 ft and in southeastern Monmouth County by more than 20 ft; however, rises in water levels of more than 10 ft were measured in other parts of Ocean and Monmouth Counties. In general, since 2008 in Critical Area 2, in the Upper PRM aquifer, measured water levels continued to rise by 10 ft or more in central and western Burlington and central Camden Counties. In the Middle PRM aquifer in Critical Area 2, measured water levels rose in parts of central Camden County by 10 ft or more. However, measured water levels in the Lower PRM aquifer in Critical Area 2 were more than 10 ft lower in the center of the cone of depression in central Camden County, but measured water levels continued to rise updip from this area in Critical Area 2. Seasonal water-level fluctuations are presented in time-series hydrographs for 77 wells during 1978–2013. Analyses of long-term water-level changes for the period 2008–13 indicate downward water-level trends at 14 wells (18 percent), upward trends at 34 wells (44 percent), and no substantial change at 29 wells (38 percent). Downward trends were most often observed for wells screened in the Piney Point aquifer and the Atlantic City 800-foot sand. Upward water-level trends were most often measured for wells screened in the PRM aquifer system. Upward water-level trends also were measured for wells in the Englishtown aquifer system and the Wenonah-Mount Laurel aquifer in Critical Area 1 in some areas; however, downward trends and no substantial changes were measured in other areas.

New Jersey

Results from laboratory and field testing of nitrate measuring spectrophotometers

Five ultraviolet (UV) spectrophotometer nitrate analyzers were evaluated by the U.S. Geological Survey (USGS) Hydrologic Instrumentation Facility (HIF) during a two-phase evaluation. In Phase I, the TriOS ProPs (10-millimeter (mm) path length), Hach NITRATAX plus sc (5-mm path length), Satlantic Submersible UV Nitrate Analyzer (SUNA, 10-mm path length), and S::CAN Spectro::lyser (5-mm path length) were evaluated in the HIF Water-Quality Servicing Laboratory to determine the validity of the manufacturer's technical specifications for accuracy, limit of linearity (LOL), drift, and range of operating temperature. Accuracy specifications were met in the TriOS, Hach, and SUNA. The stock calibration of the S::CAN required two offset adjustments before the analyzer met the manufacturer's accuracy specification. Instrument drift was observed only in the S::CAN and was the result of leaching from the optical path insert seals. All tested models, except for the Hach, met their specified LOL in the laboratory testing. The Hach's range was found to be approximately 18 milligrams nitrogen per liter (mg-N/L) and not the manufacturer-specified 25 mg-N/L. Measurements by all of the tested analyzers showed signs of hysteresis in the operating temperature tests. Only the SUNA measurements demonstrated excessive noise and instability in temperatures above 20 degrees Celsius (°C). The SUNA analyzer was returned to the manufacturer at the completion of the Phase II field deployment evaluation for repair and recalibration, and the performance of the sensor improved significantly. In Phase II, the analyzers were deployed in field conditions at three diferent USGS sites. The measured nitrate concentrations were compared to discrete (reference) samples analyzed by the Direct UV method on a Shimadzu UV1800 bench top spectrophotometer, and by the National Environmental Methods Index (NEMI) method I-2548-11 at the USGS National Water Quality Laboratory. The first deployment at USGS site 0249620 on the East Pearl River in Hancock County, Mississippi, tested the ability of the TriOs ProPs (10-mm path length), Hach NITRATAX (5 mm), Satlantic SUNA (10 mm), and the S::CAN Spectro::lyser (5 mm) to accurately measure low-level (less than 2 mg-N/L) nitrate concentrations while observing the effect turbidity and colored dissolved organic matter (CDOM) would have on the analyzers' measurements. The second deployment at USGS site 01389005 Passaic River below Pompton River at Two Bridges, New Jersey, tested the analyzer's accuracy in mid-level (2-8 mg-N/L) nitrate concentrations. This site provided the means to test the analyzers' performance in two distinct matrices—the Passaic and the Pompton Rivers. In this deployment, three instruments tested in Phase I (TriOS, Hach, and SUNA) were deployed with the S::CAN Spectro::lyser (35 mm) already placed by the New Jersey Water Science Center (WSC). The third deployment at USGS site 05579610 Kickapoo Creek at 2100E Road near Bloomington, Illinois, tested the ability of the analyzers to measure high nitrate concentrations (greater than 8 mg-N/L) in turbid waters. For Kickapoo Creek, the HIF provided the TriOS (10 mm) and S::CAN (5 mm) from Phase I, and a SUNA V2 (5 mm) to be deployed adjacent to the Illinois WSC-owned Hach (2 mm). A total of 40 discrete samples were collected from the three deployment sites and analyzed. The nitrate concentration of the samples ranged from 0.3–22.2 mg-N/L. The average absolute difference between the TriOS measurements and discrete samples was 0.46 mg-N/L. For the combined data from the Hach 5-mm and 2-mm analyzers, the average absolute difference between the Hach samples and the discrete samples was 0.13 mg-N/L. For the SUNA and SUNA V2 combined data, the average absolute difference between the SUNA samples and the discrete samples was 0.66 mg-N/L. The average absolute difference between the S::CAN samples and the discrete samples was 0.63 mg-N/L.

Open-File Report

Updates to the regional groundwater-flow model of the New Jersey Coastal Plain, 1980–2013

A 21-layer three-dimensional transient groundwater-flow model of the New Jersey Coastal Plain was developed and calibrated by the U.S. Geological Survey (USGS) in cooperation with the New Jersey Department of Environmental Protection to simulate groundwater-flow conditions during 1980–2013, incorporating average annual groundwater withdrawals and average annual groundwater recharge. This model is the third version of the New Jersey Coastal Plain regional groundwater-flow model that was initially developed as part of the USGS Regional Aquifer System Analysis (RASA) program. The model simulates groundwater flow in 11 aquifers and 10 intervening confining units of the New Jersey Coastal Plain to provide a regional overview of groundwater conditions. Averaged groundwater withdrawal data for 1980 to 2013 were used in the model. The 11 aquifers in New Jersey are, from shallowest to deepest, the Holly Beach water-bearing zone and the confined Cohansey aquifer in Cape May County; the Rio Grande water-bearing zone; the Atlantic City 800-foot sand; the Piney Point, Vincentown, and Wenonah-Mount Laurel aquifers; the Englishtown aquifer system; and the upper, middle, and lower aquifers of the Potomac-Raritan-Magothy (PRM) aquifer system. The model was developed with the MODFLOW–2005 numerical code and the UCODE parameter estimation technique and calibrated using water-level and base-flow observations. A total of 3,453 water-level observations from 392 wells in New Jersey and 48 wells in Delaware from 1983 to 2013 were used in model calibration, which includes historical water-level trends for 29 wells in New Jersey during 1980–2013 presented in time-series hydrographs. In addition, derived observations also were included by calculating the vertical gradient at 33 pairs of nested observation wells in New Jersey, for a total of 210 observations. Changes in water levels over time were calculated for 134 wells in New Jersey and four wells in Delaware where water levels had varied substantially (approximately 10 ft) over the 30-year span of synoptic water-level measurements, for a total of 767 observations. A total of 1,485 base-flow observations in 47 surface-water basins in New Jersey from 1980 to 2013 were used in model calibration. Updates to the groundwater-flow model include the conversion to a fully three-dimensional model from the previous quasi-three-dimensional model. The new model will allow for potential future uses such as particle tracking or simulation of variable-density groundwater flow that could not be accomplished with earlier versions of the model. Spatially and temporally variable recharge estimated by using a soil-water balance model resulted in a spatially and temporally finer discretization. The Rio Grande water-bearing zone was added to the model as an aquifer layer to refine estimates of simulated flow in Atlantic and Cape May Counties, New Jersey. Hydrogeologic parameters were updated to include the confining units in New Jersey and corresponding hydrogeologic units in Delaware and eastern Maryland. The simulated water levels for the New Jersey Coastal Plain aquifers were compared to water-level measurements made during 1980–2013. The average residual for 4,243 water-level observations for New Jersey (simulated water levels minus measured water levels) is 1.5 feet. The simulated water-level contours for the confined aquifers for 2013 were compared to potentiometric surfaces produced from water levels measured during 2013. Simulated water levels generally matched the 2013 potentiometric surfaces of the confined aquifers in the areas of large withdrawals. Hydrographs of wells in the confined Coastal Plain aquifers of New Jersey show that simulated water levels generally match the magnitude and seasonal variation of the observed water levels. Hydrographs of base flow for the 47 streamgaging stations in New Jersey indicate that most of the simulated and estimated data match reasonably well. Groundwater withdrawals are an important resource for water supply, agricultural, industrial, and commercial needs in the New Jersey Coastal Plain. Groundwater withdrawals from the New Jersey Coastal Plain aquifers have resulted in persistent, regionally extensive cones of depression in the Englishtown aquifer system and Wenonah-Mount Laurel aquifer in Ocean and Monmouth Counties; Wenonah-Mount Laurel and upper, middle, and lower PRM aquifers in Camden County; and Atlantic City 800-foot sand in Atlantic County. Because hydrologic stresses and water-management needs change with time, periodic updates to the groundwater-flow model are required to provide current information about hydrologic conditions in the New Jersey Coastal Plain and to maintain its usefulness as a tool to manage water resources and develop water-resource strategies. The current updates will support the continued application of this model as a tool for evaluating the regional effects of changes in groundwater withdrawals and of current and potential future water-management strategies on groundwater levels in the New Jersey Coastal Plain.

New Jersey Coastal Plain

Naturally occurring contaminants in the Piedmont and Blue Ridge crystalline-rock aquifers and Piedmont Early Mesozoic basin siliciclastic-rock aquifers, eastern United States, 1994–2008

Groundwater quality and aquifer lithologies in the Piedmont and Blue Ridge Physiographic Provinces in the eastern United States vary widely as a result of complex geologic history. Bedrock composition (mineralogy) and geochemical conditions in the aquifer directly affect the occurrence (presence in rock and groundwater) and distribution (concentration and mobility) of potential naturally occurring contaminants, such as arsenic and radionuclides, in drinking water. To evaluate potential relations between aquifer lithology and the spatial distribution of naturally occurring contaminants, the crystalline-rock aquifers of the Piedmont and Blue Ridge Physiographic Provinces and the siliciclastic-rock aquifers of the Early Mesozoic basin of the Piedmont Physiographic Province were divided into 14 lithologic groups, each having from 1 to 16 lithochemical subgroups, based on primary rock type, mineralogy, and weathering potential. Groundwater-quality data collected by the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program from 1994 through 2008 from 346 wells and springs in various hydrogeologic and land-use settings from Georgia through New Jersey were compiled and analyzed for this study. Analyses for most constituents were for filtered samples, and, thus, the compiled data consist largely of dissolved concentrations. Concentrations were compared to criteria for protection of human health, such as U.S. Environmental Protection Agency (USEPA) drinking water maximum contaminant levels and secondary maximum contaminant levels or health-based screening levels developed by the USGS NAWQA Program in cooperation with the USEPA, the New Jersey Department of Environmental Protection, and Oregon Health & Science University. Correlations among constituent concentrations, pH, and oxidation-reduction (redox) conditions were used to infer geochemical controls on constituent mobility within the aquifers. Of the 23 trace-element constituents evaluated, arsenic, manganese, and zinc were detected in one or more water samples at concentrations greater than established human health-based criteria. Arsenic concentrations typically were less than 1 microgram per liter (µg/L) in most groundwater samples; however, concentrations of arsenic greater than 1 µg/L frequently were detected in groundwater from clastic lacustrine sedimentary rocks of the Early Mesozoic basin aquifers and from metamorphosed clastic sedimentary rocks of the Piedmont and Blue Ridge crystalline rock aquifers. Groundwater from these rock units had elevated pH compared to other rock units evaluated in this study. Of the nine samples for which arsenic concentration was greater than 10 µg/L, six were classified as oxic and three as anoxic, and seven had pH of 7.2 or greater. Manganese concentrations typically were less than 10 µg/L in most samples; however, 8.3 percent of samples from the Piedmont and Blue Ridge crystalline-rock aquifers and 3.0 percent of samples from the Early Mesozoic basin siliciclastic rock aquifers had manganese concentrations greater than the 300-µg/L health-based screening level. The positive correlation of manganese with iron and ammonia and the negative correlation of manganese with dissolved oxygen and nitrate are consistent with the reductive dissolution of manganese oxides in the aquifer. Zinc concentrations typically were less than 10 µg/L in the groundwater samples considered in the study, but 0.4 percent and 5.5 percent of the samples had concentrations greater than the health-based screening level of 2,000 µg/L and one-tenth of the health-based screening level, respectively. The mean rank concentration of zinc in groundwater from the quartz-rich sedimentary rock lithologic group was greater than that for other lithologic groups even after eliminating samples collected from wells constructed with galvanized casing. Approximately 90 percent of 275 groundwater samples had radon-222 concentrations that were greater than the proposed alternative maximum contaminant level of 300 picocuries per liter. In contrast, only 2.0 percent of 98 samples had combined radium (radium-226 plus radium-228) concentrations greater than the maximum contaminant level of 5.0 picocuries per liter, and 0.6 percent of 310 samples had uranium concentrations greater than the maximum contaminant level of 30 µg/L. Radon concentrations were highest in the Piedmont and Blue Ridge crystalline-rock aquifers, especially in granite, and elevated median concentrations were noted in the Piedmont Early Mesozoic basin aquifers, but without the extreme maximum concentrations found in the crystalline rocks (granites). Although the siliciclastic lithologies had a greater frequency of elevated uranium concentrations, radon and radium were commonly detected in water from both siliciclastic and crystalline lithologies. Uranium concentrations in groundwater from clastic sedimentary and clastic lacustrine/evaporite sedimentary lithologic groups within the Early Mesozoic basin aquifers, which had median concentrations of 3.6 and 3.1 µg/L, respectively, generally were higher than concentrations for other siliciclastic lithologic groups, which had median concentrations less than 1 µg/L. Although 89 percent of the 260 samples from crystalline-rock aquifers had uranium concentrations less than 1 µg/L, 0.8 percent had uranium concentrations greater than the 30-µg/L maximum contaminant level, and 6.5 percent had concentrations greater than 3 µg/L.

Alabama;Delaware;Georgia;Maryl;New Jersey;North Ca

Hydrogeologic framework, ground-water quality, and simulation of ground-water flow at the Fair Lawn Well Field Superfund site, Bergen County, New Jersey

Production wells in the Westmoreland well field, Fair Lawn, Bergen County, New Jersey (the 'Fair Lawn well field Superfund site'), are contaminated with volatile organic compounds, particularly trichloroethylene, tetrachloroethylene, and 1,1,1-trichloroethane. In 1983, the U.S. Environmental Protection Agency (USEPA) placed the Westmoreland well field on its National Priority List of Superfund sites. In an effort to determine ground-water flow directions, contaminant-plume boundaries, and contributing areas to production wells in Fair Lawn, and to evaluate the effect of present pump-and-treat systems on flowpaths of contaminated ground water, the U.S. Geological Survey (USGS), in cooperation with the USEPA, developed a conceptual hydrogeologic framework and ground-water flow model of the study area. MODFLOW-2000, the USGS three-dimensional finite-difference model, was used to delineate contributing areas to production wells in Fair Lawn and to compute flowpaths of contaminated ground water from three potential contaminant sources to the Westmoreland well field. Straddle-packer tests were used to determine the hydrologic framework of, distribution of contaminants in, and hydrologic properties of water-bearing and confining units that make up the fractured-rock aquifer underlying the study area. The study area consists of about 15 square miles in and near Fair Lawn. The area is underlain by 6 to 100 feet of glacial deposits and alluvium that, in turn, are underlain by the Passaic Formation. In the study area, the Passaic Formation consists of brownish-red pebble conglomerate, medium- to coarse-grained feldspathic sandstone, and micaceous siltstone. The bedrock strata strike N. 9o E. and dip 6.5o to the northwest. The bedrock consists of alternating layers of densely fractured rocks and sparsely fractured rocks, forming a fractured-rock aquifer. Ground-water flow in the fractured-rock aquifer is anisotropic as a result of the interlayering of dipping water-bearing and confining units. Wells of similar depth aligned along the strike of the bedding intersect the same water-bearing units, but wells aligned along the dip of the bedding may intersect different water-bearing units. Consequently, wells aligned along strike are in greater hydraulic connection than wells aligned along dip. The Borough of Fair Lawn pumps approximately 770 million gallons per year from 13 production wells. Hydrographs from six observation wells ranging in depth from 162 to 505 feet in Fair Lawn show that water levels in much of the study area are affected by pumping. Straddle packers were used to isolate discrete intervals within six open-hole observation wells owned by the Fair Lawn Water Department. Transmissivity, water-quality, and static-water-level data were obtained from the isolated intervals. Measured transmissivity ranged from near 0 to 8,900 feet squared per day. The broad range in measured transmissivity is a result of the heterogeneity of the fractured-rock aquifer. Eight water-bearing units and eight confining units were identified in the study area on the basis of transmissivity. The water-bearing units range in thickness from 21 to 95 feet; the mean thickness is 50 feet. The confining units range in thickness from 22 to 248 feet; the mean thickness is 83 feet. Water-level and water-quality data indicate effective separation of water-bearing units by the confining units. Water-quality samples were collected from the six observation wells at 16 depth intervals isolated by the straddle packers in 2000 and 2001. Concentrations of volatile organic compounds generally were low in samples from four of the wells, but were higher in samples from a well in Fair Lawn Industrial Park and in a well in the Westmoreland well field. The digital ground-water flow model was used to simulate steady-state scenarios representing conditions in the study area in 1991 and 2000. These years were chosen because during the intervening period,

Scientific Investigations Report

High-water marks from Hurricane Sandy for coastal areas of Connecticut, Rhode Island, and Massachusetts, October 2012

Because coastal areas in Connecticut, Rhode Island, and Massachusetts were heavily affected by Hurricane Sandy in October 2012, the U.S. Geological Survey (USGS), under a mission agreement with the Federal Emergency Management Agency, collected storm tide high-water marks in those coastal areas. This effort was undertaken to better understand the areal extent and impact of storm tides resulting from strong storms. On October 27–29, 2012, Hurricane Sandy moved up the eastern coast of the United States after passing over the Bahamas. On October 29 at about 7:30 p.m. eastern daylight time, Hurricane Sandy made landfall its final time near Brigantine, New Jersey, with recorded wind speeds of about 80 miles per hour. The damages from Hurricane Sandy exceeded $50 billion in total, making it the second most costly Atlantic hurricane at that time, second only to Hurricane Katrina in 2005. Hurricane Sandy also resulted in 147 deaths, and about 650,000 homes and many businesses being damaged along the eastern coast of the United States. The severity of Hurricane Sandy’s effects resulted in presidential disaster declarations being declared in 10 States from Virginia to Massachusetts and the District of Columbia in the months following Hurricane Sandy; the list of States affected included Connecticut, Rhode Island, and Massachusetts. In response to the approach of Hurricane Sandy, the USGS deployed 60 temporary storm tide sensors and 2 temporary real-time rapid deployment gages to collect tide elevation data during the storm along the coastal areas of Connecticut, Rhode Island, and Massachusetts. This activity was done from Virginia to Maine before the storm. Following Hurricane Sandy, in October and November 2012, 371 storm tide high-water marks were identified and flagged in the coastal areas of Connecticut, Rhode Island, and Massachusetts. High-water marks near USGS temporary storm tide sensors, real-time rapid deployment gages, and streamgages affected by the tides as well as high-water marks on Block Island, R.I., and Martha’s Vineyard and Nantucket, Mass., were surveyed at the same time the high-water marks were identified and flagged in October and November 2012. The remaining high-water marks flagged during October and November 2012 were surveyed from December 2013 through June 2014 and in December 2016. Elevations of all high-water marks were referenced to the North American Vertical Datum of 1988 and horizontal coordinates to the North American Datum of 1983 using the Global Navigation Satellite System, survey-grade Digital Global Positioning System receivers, and total station surveying equipment. Of the 371 storm tide high-water marks flagged following Hurricane Sandy, only 364 high-water marks were surveyed; the remaining 7 could not be found or had been destroyed when locations were revisited to conduct surveys. The 157 high-water marks surveyed in Connecticut had elevations that ranged from 2.5 to 12.2 feet (ft) with an average elevation of 8.1 ft and a median elevation of 8.3 ft. The 76 high-water marks in Rhode Island had elevations that ranged from 3.6 to 16.2 ft and averaged 7.1 ft with a median of 6.6 ft. The 131 high-water marks in Massachusetts had elevations that ranged from 2.8 to 22.7 ft and averaged 7.3 ft with a median of 6.6 ft. Individual information on the location, type, accuracy, and elevation of the 371 high-water marks can be found in an accompanying USGS data release and at the USGS Flood Event Viewer website for Hurricane Sandy ( https://stn.wim.usgs.gov/fev/#Sandy ). The high-water marks along the coast line of Connecticut and eastern Massachusetts, including Nantucket, generally had higher storm tide elevations than the coast line of Rhode Island including Block Island and southern Massachusetts, including Martha’s Vineyard. The high-water mark elevations compare well with recorded peak-storm tide data at USGS temporary storm tide sensors and real-time rapid deployment gages deployed for Hurricane Sandy in Connecticut, Rhode Island, and Massachusetts. High-water mark data collected following Hurricane Sandy will be used by Federal, State, and local government agencies, nongovernmental organizations, universities, and the public for better understanding the areal extent and impact of the storm tides. Additionally, these data can be used for such activities as land-use planning, flood risk studies, flood resiliency studies, and coastal modeling. These data from this historic storm can be compared with other regional hurricanes and tropical storms for planning into the future.

Connecticut, Massachusetts, Rhode Island

Hydrologic assessment of the Edwin B. Forsythe National Wildlife Refuge

The Edwin B. Forsythe National Wildlife Refuge (hereafter Forsythe refuge or the refuge) is situated along the central New Jersey coast and provides a mixture of freshwater and saltwater habitats for numerous bird, wildlife, and plant species. Little data and information were previously available regarding the freshwater dynamics that support the refuge’s ecosystems. In cooperation with the U.S. Fish and Wildlife Service, the U.S. Geological Survey conducted an assessment of the hydrologic resources and processes in the refuge and surrounding areas to provide baseline information for evaluating restoration projects and future changes in the hydrologic system associated with climate change and other anthropogenic stressors. During spring 2015, water levels were measured at groundwater and surface-water sites in and near the Forsythe refuge. These water-level measurements, along with surface-water elevations obtained from digital elevation models, were used to construct water-table-elevation and depth-to-water maps of the refuge and surrounding areas. Water-table elevations in the refuge ranged from sea level to approximately 65 feet above sea level; in most of the refuge, the water-table elevation was within 3 feet of sea level. The water-table-elevation map indicates that the direction of shallow groundwater flow at the regional scale is generally from west to east (much of it from the northwest to the southeast), and groundwater moves downgradient from the uplands toward major groundwater discharge areas consisting of coastal streams and wetlands. The depth to water is estimated to be less than 2 feet for approximately 86 percent of the refuge, which coincides closely with the percentage of wetland area in the refuge. Depth to water in excess of 20 feet below land surface is limited to higher elevation areas of the refuge. Streamflow data collected at continuous-record streamgages and partial-record stations within the Mullica-Toms Basin were summarized. Hydrograph separation of streamflow data for eight streamgages (2004–13) reveals that base flow accounts for 68–94 percent of streamflow in basins upstream from the refuge. The high base-flow inputs underscore the importance of groundwater as a source of freshwater that supports both the streams that flow into the refuge and the hydroecology of the contributing basins. Mean annual flow typically ranged from 1.7 to 2.1 cubic feet per second per square mile at the streamgages (2004–13) and between 1.2 and 2.3 cubic feet per second per square mile at the partial-record stations (1965–2015) but was notably greater or lower than these ranges at several stations. Mean annual water budgets were estimated for multiple regions of the refuge for 2004–13 using data compiled from nearby meteorological stations and groundwater flows derived from previously calibrated groundwater-flow models. Precipitation, groundwater recharge, and evapotranspiration were estimated from available data; direct runoff was calculated as the residual component of the water balance. Groundwater recharge rates were greatest in the upland-dominated areas of the refuge with estimates of 14.4 to 18.9 inches per year, which are equivalent to 30 to 40 percent of precipitation. Groundwater recharge rates were nearly zero in the central coastal areas because these areas are major groundwater discharge zones, the water table is near land surface, the subsurface is close to saturation and cannot accept much recharge, and much of the area is underlain by thick marsh deposits likely with low permeability. Estimates of evapotranspiration varied from about 26 inches per year in the upland-dominated areas to more than 35 inches per year in the coastal wetlands, equivalent to 55–79 percent of mean annual precipitation, indicating that it is a major component of the hydrodynamics of the Forsythe refuge. On the basis of output from previously calibrated groundwater-flow models, nearly all of the groundwater exiting the surficial aquifer system in the central coastal areas of the refuge is discharged to wetlands, which highlights the importance of groundwater discharge in supporting the ecosystems of the Forsythe refuge. In the central coastal areas, horizontal flow contributes more than 90 percent of the groundwater flow to the surficial system, indicating that the upbasin areas are a substantial source of water that ultimately discharges to streams and wetlands in the refuge.

New Jersey

A comparison of synthetic flowpaths derived from light detection and ranging topobathymetric data and National Hydrography Dataset High Resolution Flowlines

Bathymetric and topobathymetric light detection and ranging (lidar) digital elevation models created for the Delaware River were provided to the National Geospatial Program and used to evaluate synthetic flowpath extraction from bathymetric/topobathymetric lidar survey data as a data source for improving the density, distribution, and connectivity of the National Hydrography Dataset High Resolution Flowline Network. As the surface-water component of The National Map, the National Hydrography Dataset maintains the Nation’s drainage network flow information and geometries for surface-water features used in hydrologic, hydraulic, and other science and engineering disciplines. The regional lidar survey for the Delaware River between Hancock, New York, and Trenton, New Jersey, was collected for the U.S. Geological Survey using the Experimental Advanced Airborne Research Lidar sensor system and processed by the Coastal National Elevation Database Applications Program. Using 1 percent of the maximum flow accumulation value for the surveyed Delaware River corridor as the flow accumulation threshold for grid cells at 1-, 5-, and 10-meter resolution created 223 to 283 kilometers of synthetic flowpaths potentially representing the river channel thalweg, which is the deepest point in a riverbed cross-section. There was potential for improving the High Resolution National Hydrography Dataset (HR NHD) Flowline network in places where the Delaware River channel, depicted as an Artificial Path in the HR NHD, is offset from the extracted synthetic river flowpath which sometimes appeared better positioned than the Artificial Path to represent the river thalweg. For the same area, using 0.05 percent of the maximum flow accumulation at the 1-, 5-, and 10-meter resolutions extracted 744 to 1,317 kilometers of synthetic flowpaths, with extracted synthetic flowpaths representing the main river channel and additional synthetic flowpaths representing tributaries or streams adjacent to the main channel. Overlaying these results with the HR NHDFlowline Network indicates that some of the additional synthetic flowpaths are connected to or extend HR NHD stream/river feature types. Some disconnected or isolated synthetic flowpaths not included in stream/river feature types were validated in orthoimagery and U.S. Topo Maps and provide examples of how extracted synthetic flowpaths could be used to delineate new stream/river features. Other additional extracted synthetic flowpaths depict linear features such as canals, tree lines, roads, or linear topographic depressions. For some river reaches where obstructions to flow or where low-relief topographic or bathymetric surfaces alter the flow direction, the software tool used to develop the flow direction grid did not calculate a primary flowpath for the river channel. Based on the results of this analysis, site conditions for the Delaware River corridor did not affect the quality of lidar bathymetric survey data. However, depending on the resolution of the lidar bathymetric digital elevation models (BDEMs), site conditions do have different effects on results for extracted synthetic flowpaths. We found that synthetic flowpaths extracted from 1-meter resolution lidar DEMs had more varied flow directions around in-channel landforms that obstructed flow than synthetic flowpaths extracted from 5- or 10-meter resolution lidar DEMs. As a result the 1-meter resolution DEM created some isolated or discontinuous synthetic flowpath segments where the 5- and 10-meter DEMs developed more continuous flowpaths. In this case the river bed upstream from the in-channel obstruction is shallower than the river bed downstream. Under these conditions the 1-meter resolution DEM provided synthetic flowpaths delineating a potential river thalweg. In this same area, the software solution modified (virtually raised) the river bed in the 5- and 10-meter resolution DEMs and flattened the bathymetric surface to create a continuous downstream flow direction, which caused trellis-patterned synthetic flowpaths to form. Under different site conditions and converse to the above development of synthetic flowpaths at different resolutions, at an abandoned river flood plain (terrace) with low relief that is adjacent to the river channel, the flow direction grid for the 1-meter resolution DEM developed continuous synthetic flowpath corresponding to a HR NHD Flowline network stream/river feature that connected to the main river channel but the larger resolution DEMs created isolated or disconnected synthetic flowpaths. A project to continue an evaluation of benefits of or issues caused by extracting synthetic flowpaths to enhance the HR NHD could include a study to assess the potential for merging surface-water flowpaths extracted from lidar topobathymetry and 3D Elevation Program digital elevation models. The merged DEM approach to synthetic flowpath extraction could extend the HR NHDFlowline network and enhance flow accumulations that might develop better flow direction grids in low-relief areas. Because of the confined lateral extent of the Delaware River, the lidar DEMs were not used to create catchments or watersheds; however, the merged DEM approach could also be tested as a resource for enhancing HR NHD catchments and watersheds. This lidar DEM synthetic flowpath extraction project supports the National Geospatial Program efforts to collect and produce high-quality lidar data to provide 3-dimensional representations of natural feature and aligns with the National Spatial Data Infrastructure to improve utilization of geospatial data. The results also can be useful for understanding strategies that can help maintain quality data in the HR NHD programs. KEYWORDS: bathymetric, digital elevation model, extracted synthetic flowpath, lidar, High Resolution National Hydrography Dataset, topobathymetric

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