Geology ReportsSearch

SEARCH · Geology Reports

Results for “Mine Water and the Environment”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 271 records · Page 15Linked to original sources

Geology of the Holocene surficial uranium deposit of the north fork of Flodelle Creek, northeastern Washington (USA)

The north fork of Flodelle Creek drainage basin in northeastern Washington contains the first surficial uranium deposit to be mined in the United States. The uranium was leached from granitic bedrock and fixed in organic-rich pond sediments. The distribution of these pond sediments and, therefore, the uranium has been strongly influenced by relict glacial topography, slope processes, and beaver activity. The north fork of Flodelle Creek drainage basin was covered by the Cordilleran ice sheet during the Fraser (late Wisconsin) glaciation. Till and outwash were deposited on the valley slopes and valley floor as ice receded. Outwash incision and melting of stagnant ice led to formation of a terrace and kames. Shortly after deglaciation, a small pond formed in the upper part of the valley when unconsolidated glacial sediment slumped off the valley slopes and restricted drainage. Fluvial processes dominated in the central and downstream parts of the valley for several thousand years after deglaciation, although drainage was partly restricted by kames. Beavers began to occupy and build dams on the wide outwash plains in the valley floor ∼5000 yr B.P. Beaver ponds in the central part of the basin subsequently filled with sediment and were abandoned, whereas downstream ponds remained relatively free of clastic input and are presently occupied by beavers. Ponds in the drainage basin have been sinks for fine-grained, organic-rich sediments. These organic-rich sediments provide a suitable geochemical environment for precipitation and adsorption of uranium leached from granitic bedrock into ground, spring, and surface waters. Processes of pond formation have thus been important in the development of surficial uranium deposits in the north fork of Flodelle Creek drainage basin and may have similar significance in other areas.

Washington

Arsenic and mercury contamination related to historical goldmining in the Sierra Nevada, California

Arsenic (As) is a naturally occurring constituent in low-sulphide gold-quartz vein deposits, the dominant deposit type for lode mines in the Sierra Nevada Foothills (SNFH) gold (Au) province of California. Concentrations of naturally occurring mercury (Hg) in the SNFH Au province are low, but extensive use and loss of elemental Hg during amalgamation processing of ore from lode and placer Au deposits led to widespread contamination of Hg in the Sierra Nevada foothills and downstream areas, such as the Sacramento–San Joaquin Delta and San Francisco Bay. This review paper provides an overview of As and Hg contamination related to historical Au mining in the Sierra Nevada of California. It summarizes the geology, mineralogy, and geochemistry of the Au deposits, and provides information on specific areas where detailed studies have been done in association with past, ongoing, and planned remediation activities related to the environmental As and Hg contamination. Arsenic is a naturally occurring constituent in low-sulphide Au-quartz vein deposits, the dominant deposit type for lode mines in the Sierra Nevada Foothills (SNFH) Au province ( Ashley 2002 ). Because of elevated concentrations of As in accessory iron-sulphide minerals including arsenopyrite (FeAsS) and arsenian pyrite (Fe(S,As) 2 ), As is commonly a contaminant of concern in lode Au mine waste, including waste rock and mill tailings. The principal pathways of human As exposure from mine waste include ingestion of soil or drinking water, and inhalation of dust in contaminated areas ( Mitchell 2014 ). Concentrations of naturally occurring Hg in the SNFH Au province are low, but extensive use and loss of elemental Hg during amalgamation processing of ore from lode and placer Au deposits ( Churchill 2000 ) led to widespread contamination of Hg in the Sierra Nevada foothills and downstream areas, such as the Sacramento–San Joaquin Delta and San Francisco Bay ( Alpers et al. 2005 a ). Conversion of Hg to monomethylmercury (MeHg) by sulphate-reducing and iron-reducing microbes facilitates its bioaccumulation ( Wiener et al. 2003 ). The human Hg exposure pathway of main concern is ingestion of MeHg from sport (non-commercial) fish, especially higher trophic levels such as bass species ( Davis et al. 2008 ). Wildlife exposure to MeHg is also a concern because of chronic and reproductive effects, for example in fish-eating and invertebrate-foraging birds (e.g. Wiener et al. 2003 ; Eagles-Smith et al. 2009 ; Ackerman et al. 2016 ).

California

Hydrology of Area 62, Northern Great Plains and Rocky Mountain Coal Provinces, New Mexico and Arizona

This report summarizes available hydrologic data for Area 62 and will aid leasing decisions, and the preparation and appraisal of environmental impact studies and mine-permit applications. Area 62 is located at the southern end of the Rocky Mountain Coal Province in parts of New Mexico and Arizona and includes approximately 9,500 square miles. Surface mining alters, at least temporarily, the environment; if the areas are unreclaimed, there can be long-term environmental consequences. The land-ownership pattern in Area 62 is complicated. The checkerboard pattern created by several types of ownership makes effective management of these lands difficult. The climate generally is semiarid with average annual precipitation ranging from 10 to 20 inches. Pinons, junipers, and grasslands cover most of the area, and much of it is used for grazing by livestock. Soils vary with landscape, differing from flood plains and hillslopes to mountain slopes. The major structural features of this area were largely developed during middle Tertiary time. The main structural features are the southern San Juan Basin and the Mogollon slope. Coal-bearing rocks are present in four Cretaceous rock units of the Mesaverde Group: the Gallup Sandstone, the Dileo Coal Member, and the Gibson Coal Member of the Crevasse Canyon Formation, and the Cleary Coal Member of the Menefee Formation. Area 62 is drained by Black Creek, the Puerco River, the Zuni River, Carrizo Wash-Largo Creek, and the Rio San Jose. Only at the headwaters of the Zuni River is the flow perennial. The streamflow-gaging station network consists of 25 stations operated for a variety of needs. Streamflow changes throughout the year with variation related directly to rainfall and snowmelt. Base flow in Area 62 is zero indicating no significant ground-water discharge. Mountainous areas contribute the highest mean annual runoff of 1.0 inch. Very few water-quality data are available for the surface-water stations. Of the nine surface-water stations that have water-quality data, only one has chemical analyses from more than 10 samples. Therefore, sufficient data to characterize the area in detail are not available. Suspended sediment data are available only for a few surface- water stations in the area. Erosion rates generally are less than 1 acre-foot per square mile per year. Greater erosion rates are found within the badland areas. Water levels are periodically measured at 21 selected wells in Area 62. These observation wells are located mostly along the Rio San Jose and northeast of Gallup, New Mexico. The recharge to ground-water aquifers generally coincide with areas of greater precipitation in the mountainous areas. Depth to water below land surface is generally less than 200 feet. Well yields of 100 gallons per minute are common in most of the area. Ground-water quality is variable both within each aquifer and between aquifers. Water quality generally is best near recharge areas. Historical and current data related to stream discharge, water quality, and suspended sediment are available from computer files in the U.S. Geological Survey's National Water Data Storage and Retrieval System (WATSTORE) and through the National Water Data Exchange (NAWDEX).

Open-File Report

Hydrology of Area 62, Northern Great Plains and Rocky Mountain Coal Provinces, New Mexico and Arizona

This report summarizes available hydrologic data for Area 62 and will aid leasing decisions, and the preparation and appraisal of environmental impact studies and mine-permit applications. Area 62 is located at the southern end of the Rocky Mountain Coal Province in parts of New Mexico and Arizona and includes approximately 9,500 square miles. Surface mining alters, at least temporarily, the environment; if the areas are unreclaimed, there can be long-term environmental consequences. The land-ownership pattern in Area 62 is complicated. The checkerboard pattern created by several types of ownership makes effective management of these lands difficult. The climate generally is semiarid with average annual precipitation ranging from 10 to 20 inches. Pinons, junipers, and grasslands cover most of the area, and much of it is used for grazing by livestock. Soils vary with landscape, differing from flood plains and hillslopes to mountain slopes. The major structural features of this area were largely developed during middle Tertiary time. The main structural features are the southern San Juan Basin and the Mogollon slope. Coal-bearing rocks are present in four Cretaceous rock units of the Mesaverde Group: the Gallup Sandstone, the Dileo Coal Member, and the Gibson Coal Member of the Crevasse Canyon Formation, and the Cleary Coal Member of the Menefee Formation. Area 62 is drained by Black Creek, the Puerco River, the Zuni River, Carrizo Wash-Largo Creek, and the Rio San Jose. Only at the headwaters of the Zuni River is the flow perennial. The streamflow-gaging station network consists of 25 stations operated for a variety of needs. Streamflow changes throughout the year with variation related directly to rainfall and snowmelt. Base flow in Area 62 is zero indicating no significant ground-water discharge. Mountainous areas contribute the highest mean annual runoff of 1.0 inch. Very few water-quality data are available for the surface-water stations. Of the nine surface-water stations that have water-quality data, only one has chemical analyses from more than 10 samples. Therefore, sufficient data to characterize the area in detail are not available. Suspended sediment data are available only for a few surface- water stations in the area. Erosion rates generally are less than 1 acre-foot per square mile per year. Greater erosion rates are found within the badland areas. Water levels are periodically measured at 21 selected wells in Area 62. These observation wells are located mostly along the Rio San Jose and northeast of Gallup, New Mexico. The recharge to ground-water aquifers generally coincide with areas of greater precipitation in the mountainous areas. Depth to water below land surface is generally less than 200 feet. Well yields of 100 gallons per minute are common in most of the area. Ground-water quality is variable both within each aquifer and between aquifers. Water quality generally is best near recharge areas. Historical and current data related to stream discharge, water quality, and suspended sediment are available from computer files in the U.S. Geological Survey's National Water Data Storage and Retrieval System (WATSTORE) and through the National Water Data Exchange (NAWDEX).

Water-Resources Investigations Report

A GIS-based vulnerability assessment of brine contamination to aquatic resources from oil and gas development in eastern Sheridan County, Montana

Water (brine) co-produced with oil in the Williston Basin is some of the most saline in the nation. The Prairie Pothole Region (PPR), characterized by glacial sediments and numerous wetlands, covers the northern and eastern portion of the Williston Basin. Sheridan County, Montana, lies within the PPR and has a documented history of brine contamination. Surface water and shallow groundwater in the PPR are saline and sulfate dominated while the deeper brines are much more saline and chloride dominated. A Contamination Index (CI), defined as the ratio of chloride concentration to specific conductance in a water sample, was developed by the Montana Bureau of Mines and Geology to delineate the magnitude of brine contamination in Sheridan County. Values > 0.035 indicate contamination. Recently, the U.S. Geological Survey completed a county level geographic information system (GIS)-based vulnerability assessment of brine contamination to aquatic resources in the PPR of the Williston Basin based on the age and density of oil wells, number of wetlands, and stream length per county. To validate and better define this assessment, a similar approach was applied in eastern Sheridan County at a greater level of detail (the 2.59 km 2 Public Land Survey System section grid) and included surficial geology. Vulnerability assessment scores were calculated for the 780 modeled sections and these scores were divided into ten equal interval bins representing similar probabilities of contamination. Two surface water and two groundwater samples were collected from the section with the greatest acreage of Federal land in each bin. Nineteen of the forty water samples, and at least one water sample from seven of the ten selected sections, had CI values indicating contamination. Additionally, CI values generally increased with increasing vulnerability assessment score, with a stronger correlation for groundwater samples (R 2 = 0.78) than surface water samples (R 2 = 0.53).

Montana

Multiple applications of the U.S. EPA 1312 leach procedure to mine waste from the Animas watershed, SW Colorado

Eleven acid-sulphate and quartz-sericite-pyrite altered mine waste samples from the Animas River watershed in SW Colorado were subjected to a series of 5 to 6 successive leaches using the US EPA 1312 leach protocol to evaluate the transport of metals and loss of acidity from mine wastes as a function of time. Multi-acid digestion ICP-AES analyses, X-ray diffraction (XRD) mineral identification, total sulphur, and net acid potential (NAP) determinations were performed on the initial starting materials. Multiple leaching steps generally showed a ‘flushing' effect, whereby elements loosely bound, presumably as water-soluble salts, were removed. Aluminum, Cd, Fe, Mg, Mn, Sr, Zn, and S showed decreasing concentration trends, whereas Cu concentrations showed initially decreasing trends, followed by increasing trends in later steps. Concentrations of Zn in the first leach step were independent of whole-sample Zn content. Lead and Ba concentrations consistently increased with each step, indicating that anglesite (PbSO 4 ) and barite (BaSO 4 ), respectively, were dissolving in successive leach steps. Comparison of Fe content with NAP resulted in a modest correlation. However, using the S analyses and XRD identification of sulphide minerals to apportion S amongst enargite, barite, anglesite/galena, and sphalerite, and assigning the remaining S to pyrite, provided a useful correlation between estimated pyrite content and NAP. Whole-sample mass loss correlated well with NAP, but individual elements' behaviors varied between positive correlation (e.g. Al, Fe, Mg), no apparent correlation (Ca, Cd, Pb, Zn), and negative correlation (Cu). Comparison of the summed titrated acidities of the leachates with the whole-sample NAP values yielded an estimate of the fraction of NAP consumed, and led to an estimate of the time it would take to consume the sample acidity by weathering. We estimate, on the basis of these experiments, the acidity in the upper 30 cm would be consumed in 200–1000 years. In addition, calculations suggest that the acidity would be depleted before the complete store of the metals Cu-Cd-Zn in these mine wastes would be released to the environment.

Colorado

Selected elements and organic chemicals in bed sediment and fish tissue of the Tualatin River basin, Oregon, 1992-96

A variety of elements and organic compounds have entered the environment as a result of human activities. Such substances find their way to aquatic sediments from direct discharges to waterways, atmospheric emissions, and runoff. Some of these chemicals are known to harm fish or wildlife, either by direct toxicity, by reducing viability, or by limiting reproductive success. In aquatic systems, sediments become the eventual sink for most of these chemicals. Analyzing the sediments provides a first step in a chemical inventory that can lead to an assessment of potential biological impacts (Kennicutt and others, 1994). Many elements (iron, aluminum, calcium, and others) enter the environment from the natural weathering of rock. Additional amounts of elements have been contributed by human activities such as mining, metals production and processing, fossil fuel combustion, municipal waste incineration, and transportationrelated sources. The environmental presence of some elements, such as lead and mercury, is almost entirely due to human activity. Lead is often associated with the use of leaded gasoline and from the manufacture and disposal of lead storage batteries. Mercury was used historically in a variety of industrial processes and as a pesticide. Nriagu and Pacyna (1998) concluded that human activity is the “most important element in the global biogeochemical cycling of the trace metals.” The number of organic compounds in existence and their total production has more than tripled in the last century. Many of these compounds enter the environment directly as pesticides; others are inadvertently discharged. Some organic compounds have natural sources. Three general classes of organic compounds will be discussed: organochlorine compounds, polyaromatic hydrocarbons, and phthalates. Almost all organochlorine compounds are manmade. Many are pesticides that were used widely in the 1950s–60s (DDT and chlordanes, for example). Use of most organochlorine pesticides was restricted or banned in the United States in the 1970s–80s. Polychlorinated biphenyls (PCBs) are also organochlorine compounds; they were used for a variety of applications, but most commonly as insulators in electrical transformers and other equipment. In general, organochlorine compounds degrade very slowly in the environment and therefore, are routinely found in environmental samples, despite the fact that they are no longer used in the United States. They are hydrophobic that is they do not dissolve readily in water and, in aquatic systems, are almost exclusively associated with sediments or tissue. Because these compounds cause a variety of adverse health effects in wildlife, the U.S. Environmental Protection Agency (USEPA) has listed many as priority pollutants. Organochlorine compounds also have been implicated as endocrine disrupters— chemicals that can interfere with the normal function of hormones. Polyaromatic hydrocarbons (PAHs) are found in sediments throughout the world (Hites and others, 1980). Their presence is thought to be primarily anthropogenic. PAHs occur naturally in petroleum products and also are produced during combustion. They enter the environment from fuel spills, tar coatings, coal and other fossil fuel usage, road dust, and from the atmospheric deposition of combustion products (Prahl and others, 1984; Wakeham and others, 1980). Urban areas often have high concentrations of PAHs because of transportation-related sources (vehicle exhaust, paving materials, and releases of fuel or oil). Natural sources, such as forest fires, may contribute small amounts of PAHs. Several PAHs are known carcinogens (benzo[a]pyrene, for example); 16 are listed as USEPA priority pollutants. Phthalate compounds are often associated with urban areas. They are used in a wide variety of industrial applications and in inks, adhesives, resins, and as plasticizers (chemicals that increase the flexibility of plastics). In aquatic systems, phthalates are found mostly in sediments where they degrade very slowly. Phthalates are thought to be endocrine disrupters; Jobling and others (1995) found that some phthalates were weakly estrogenic. USEPA considers some phthalates to be possible carcinogens. This report describes the results of a reconnaissance survey of elements and organic compounds found in bed sediment and fish tissue in streams of the Tualatin River Basin. The basin is in northwestern Oregon to the west of the Portland metropolitan area (fig. 1). The Tualatin River flows for about 80 miles, draining an area of about 712 square miles, before it enters the Willamette River. Land use in the basin changes from mostly forested in the headwaters, to mixed forest and agriculture, to predominately urban. The basin supports a growing population of more than 350,000 people, most of whom live in lower parts of the basin. Water quality in the Tualatin River and its tributaries is expected to be affected by the increasing urbanization of the basin.

Oregon

Time-dependent accumulation of Cd, Co, Cu, Ni, and Zn in mayfly and caddisfly larvae in experimental streams: Metal sensitivity, uptake pathways, and mixture toxicity

Conceptual and quantitative models were developed to assess time-dependent processes in four sequential experimental stream studies that determined abundances of natural communities of mayfly and caddisfly larvae dosed with single metals (Cd, Co, Cu, Ni, Zn) or multiple metals (Cd+Zn, Co+Cu, Cu+Ni, Cu+Zn, Ni+Zn, Cd+Cu+Zn, Co+Cu+Ni, Cu+Ni+Zn). Metal mixtures contained environmentally relevant metal ratios found in mine drainage. Free metal ion concentrations, accumulation of metals by periphyton, and metal uptake by four families of aquatic insect larvae were either measured (Brachycentridae) or predicted (Ephemerellidae, Heptageniidae, Hydropsychidae) using equilibrium and biodynamic models. Toxicity functions, which included metal accumulations by larvae and metal potencies, were linked to abundances of the insect families. Model results indicated that mayflies accumulated more metal than caddisflies and the relative importance of metal uptake by larvae via dissolved or dietary pathways highly depended on metal uptake rate constants for each insect family and concentrations of metals in food and water. For solution compositions in the experimental streams, accumulations of Cd, Cu, and Zn in larvae occurred primarily through dietary uptake, whereas uptake of dissolved metal was more important for Co and Ni accumulations. Cd, Cu, and Ni were major contributors to toxicity in metal mixtures and for metal ratios examined. Our conceptual approach and quantitative results should aid in designing laboratory experiments and field studies that evaluate metal uptake pathways and metal mixture toxicity to aquatic biota.

Science of the Total Environment

Surprising abundance of Gallionella-related iron oxidizers in creek sediments at pH 4.4 or at high heavy metal concentrations

We identified and quantified abundant iron-oxidizing bacteria (FeOB) at three iron-rich, metal-contaminated creek sites with increasing sediment pH from extremely acidic (R1, pH 2.7), to moderately acidic (R2, pH 4.4), to slightly acidic (R3, pH 6.3) in a former uranium-mining district. The geochemical parameters showed little variations over the 1.5 year study period. The highest metal concentrations found in creek sediments always coincided with the lowest metal concentrations in creek water at the slightly acidic site R3. Sequential extractions of R3 sediment revealed large portions of heavy metals (Ni, Cu, Zn, Pb, U) bound to the iron oxide fraction. Light microscopy of glass slides exposed in creeks detected twisted stalks characteristic of microaerobic FeOB of the family Gallionellaceae at R3 but also at the acidic site R2. Sequences related to FeOB such as Gallionella ferruginea, Sideroxydans sp. CL21, Ferritrophicum radicicola, and Acidovorax sp. BrG1 were identified in the sediments. The highest fraction of clone sequences similar to the acidophilic “Ferrovum myxofaciens” was detected in R1. Quantitative PCR using primer sets specific for Gallionella spp., Sideroxydans spp., and “Ferrovum myxofaciens” revealed that ~72% (R2 sediment) and 37% (R3 sediment) of total bacterial 16S rRNA gene copies could be assigned to groups of FeOB with dominance of microaerobic Gallionella spp. at both sites. Gallionella spp. had similar and very high absolute and relative gene copy numbers in both sediment communities. Thus, Gallionella-like organisms appear to exhibit a greater acid and metal tolerance than shown before. Microaerobic FeOB from R3 creek sediment enriched in newly developed metal gradient tubes tolerated metal concentrations of 35 mM Co, 24 mM Ni, and 1.3 mM Cd, higher than those in sediments. Our results will extend the limited knowledge of FeOB at contaminated, moderately to slightly acidic environments.

Ronneburg

Selenium in ecosystems within the mountaintop coal mining and valley-fill region of southern West Virginia-assessment and ecosystem-scale modeling

Coal and associated waste rock are among environmental selenium (Se) sources that have the potential to affect reproduction in fish and aquatic birds. Ecosystems of southern West Virginia that are affected by drainage from mountaintop coal mines and valleys filled with waste rock in the Coal, Gauley, and Lower Guyandotte watersheds were assessed during 2010 and 2011. Sampling data from earlier studies in these watersheds (for example, Upper Mud River Reservoir) and other mining-affected watersheds also are included to assess additional hydrologic settings and food webs for comparison. Basin schematics give a comprehensive view of sampled species and Se concentration data specific to location and date. Food-web diagrams document the progression of Se trophic transfer across suspended particulate material, invertebrates, and fish for each site to serve as the basis for developing an ecosystem-scale model to predict Se exposure within the hydrologic conditions and food webs of southern West Virginia. This approach integrates a site-specific predator’s dietary exposure pathway into modeling to ensure an adequate link to Se toxicity and, thus, to species vulnerability. Site-specific fish abundance and richness data in streams documented various species of chub, shiner, dace, darters, bass, minnow, sunfish, sucker, catfish, and central stoneroller (Campostoma anomalum), mottled sculpin (Cottus bairdii), and least brook lamprey (Lampetra aepyptera). However, Se assessment species for streams, and hence, model species for streams, were limited to creek chub (Semotilus atromaculatus) and central stoneroller. Both of these species of fish are generally considered to have a high tolerance for environmental stress based on traditional comparative fish community assessment, with creek chub being present at all sites. Aquatic insects (mayfly, caddisfly, stonefly, dobsonfly, chironomid) were the main invertebrates sampled in streams. Collection of suspended particulate material acted as an integrator of organic-rich, fine-grained biomass present in streams. The base-case food web modeled for streams was suspended particulate material to aquatic insect to creek chub, with comparative modeling of a direct particulate-to-stoneroller food web. Model species for a reservoir setting were based on an earlier study of bluegill sunfish (Lepomis macrochirus), green sunfish (Lepomis cyanellus), and largemouth bass (Micropterus salmoides). Several reservoir food webs were considered based on a variety of invertebrates (insect, snail, clam). For stream and reservoir settings, predicted Se concentrations in exposure scenarios showed a high degree of correlation (r 2 = 0.91 for invertebrates and 0.75 for fish) with field observations of Se concentrations when modeling was initiated from suspended-particulate-material Se concentrations and model transfer parameters defined previously in the literature were used. These strong correlations validate the derived site-specific model and establish sufficient confidence that the predictions from the developed model can be quantitatively applied to the ecosystems in southern West Virginia. An application of modeling used a metric describing the partitioning of Se between particulate material and dissolved phases (K d ) to allow determination of a dissolved Se concentration that would be necessary to attain a site-specific Se fish body burden. The operationally defined K d quantifies the complex process of transformation at the base of a food web on a site-specific basis. The magnitude of this metric is known to vary with such factors as Se speciation, particulate-material type, and hydrology. This application (1) ties dissolved Se concentrations to fish tissue concentrations; (2) allows consideration of different choices for intervening site-specific exposure steps that set Se bioaccumulation, partitioning, and bioavailability; and (3) generates implications for management decisions that define protection through different regulatory pathways and guidelines. The range of model outcomes accounts for critical sources of variability and establishes whether site and food-web characterization were adequate to represent the dynamics of the system with certainty. This is especially true in terms of particulate-material phases at the base of the food web and utilization of K d in different hydrologic settings. For streams, a range of field-derived K d ds were applied to food-web exposure scenarios within a framework of locational and hydrologic variables (area of stream basin; stream gradient and discharge) that may affect the magnitude of K d . Overlaying even a coarse temporal scale that acknowledges variability in stream dissolved Se and Se speciation, such as through seasonal derivation of K d , can substantially narrow model uncertainty. Modeling that constrains the place and time of greatest ecosystem Se sensitivity within a specified food web gives insight into Se risk and identifies controlling management alternatives within a watershed or stream basin. If there is a range of hydrologic settings, specificity is needed to establish a hierarchy of in-stream and off-stream habitats for a watershed approach that takes into account Se-enriched water moving through different K d and food web environments. If there is a range of predator vulnerabilities (measured as a combination of food-web Se biodynamics and response in Se toxicity tests) within the site-specific community of fish species to be protected, then choice of fish species is critical to protection because it determines the food web and, hence, the magnitude of biotransfer through which Se is modeled. Whether creek chub is representative of the vulnerability to Se of all fish species encountered within the study-site ecosystems will require additional species-specific data and analysis. A range of site-specific scenarios illustrated here set model outcomes, but the final quantitative evaluation of alternatives and their implications will be those generated through choices and guidance formulated by state and other agencies in their decisionmaking processes. Proposed additions and refinements to the ecosystem-scale site-specific approach developed here include consideration of: measurement of temporally matched pairs of dissolved and suspended-particulate-material Se concentrations across a broader range of stream sites to expand the stream K d database and to test the representativeness of a suspended-particulate-material sample within a stream; characterization of different phases of particulate material across seasons to better define the base of the food web and connect to invertebrate feeding; refinement of model assumptions concerning dietary preferences and composition for fish to develop additional trophic transfer factors (TTFs) (for example, calculation of TTFinvertebrate composite for mixed diets); expansion of modeling of fish species and their food webs to include Se-vulnerable species; temporal characterization of a predator’s life cycle and habitat use as additional model layers to integrate with Se biodynamics in streams; investigation of the effect of stream gradient on K d based on a finer scale than presented here in terms of such variables as residence time, watershed dilution, and physical habitat attributes (for example, amount of ponding versus run or riffle within a stream); and linkage to discharge through use of stream gaging to record variability and enable model organization within water-year types and discharge seasons. Investigating the presence and variability of prey and predator species in demographically open systems such as streams also is key to model outcomes given the overall environmental stressors (for example, general landscape change, food-web disruption, recolonization potential) imposed on the composition of biological communities in coal mining and valley-fill affected watersheds

West Virginia

Petrography, geochemistry, and depositional setting of the San Pedro and Santo Tomas coal zones: Anomalous algae-rich coals in the middle part of the Claiborne Group (Eocene) of Webb County, Texas

Two coal zones, the San Pedro and the overlying Santo Tomas, are present for nearly 35 km in outcrop, surface and underground mines, and shallow drill holes along the strike of the middle part of the Claiborne Group (Eocene) in Webb County, Texas. A sandstone-dominated interval of 25 to 35 m separates the two coal zones, which range up to 3 m in thickness. Each coal zone contains carbonaceous shales, thin (<0.75 m) impure coal beds, and thin (<0.85 m) but commercially significant nonbanded coal beds. The nonbanded coals are different from other Tertiary coals of the Gulf of Mexico Coastal Plain: unlike lignites that are typical of the older Wilcox Group (Paleocene-Eocene) and younger Jackson Group (Eocene), nonbanded coals of the Claiborne Group have high vitrinite-reflectance values (0.53 R max ) and high calorific yields (average 6670 kcal/kg or 12,000 Btu, dry basis). The coals are weakly agglomerating (free-swelling index is 1.5–2.0) and have an apparent rank of high-volatile bituminous. The coal-bearing portion of the middle Claiborne Group in the Rio Grande area represents a fining-upward transition from sandstone-dominated, marine-influenced, lower delta plain depositional environments to more inland, mudstone-rich, predominantly freshwater deltaic settings. Discontinuities within the San Pedro coal zone are attributed mainly to the influence of contemporaneous deposition of distributary mouth-bar sand bodies. The less variable nature of the Santo Tomas coal zone reflects its origin in the upper part of an interlobe basin that received only minor clastic influx. Petrographic attributes of the nonbanded coals indicate that they formed subaqueously in fresh to possibly brackish waters. A highly degraded groundmass composed of eugelinite is the main petrographic component (approximately 71%, mineral-matter-free basis). An enriched liptinite fraction (approximately 23%) probably accounts for unusually high calorific values. There is negligible inertinite. Petrographic study of polished blocks indicates that approximately 10 percent of the nonbanded coal from both coal zones is composed of green algae fructifications, which also occur in clastic rocks of the coal-bearing interval. Such algal material cannot be identified or quantified by conventional coal petrographic techniques that utilize particle pellets or by palynological analyses that include acid preparation.

International Journal of Coal Geology

The persistence of lead from past gasoline emissions and mining drainage in a large riparian system: Evidence from lead isotopes in the Sacramento River, California

Lead concentrations and isotope ratios measured in river water colloids and streambed sediment samples along 426 km of the Sacramento River, California reveal that the influence of lead from the historical mining of massive sulfide deposits in the West Shasta Cu-mining district (at the headwaters of the Sacramento River) is confined to a 60 km stretch of river immediately downstream of that mining region, whereas inputs from past leaded gasoline emissions and historical hydraulic Au-mining in the Sierra Nevadan foothills are the dominant lead sources in the remaining 370 km of the river. Binary mixing calculations suggest that more than 50% of the lead in the Sacramento River outside of the region of influence of the West Shasta Cu-mining district is derived from past depositions of leaded gasoline emissions. This predominance is the first direct documentation of the geographic extent of gasoline lead persistence throughout a large riparian system (>160,000 km 2 ) and corroborates previous observations based on samples taken at the mouth of the Sacramento River. In addition, new analyses of sediment samples from the hydraulic gold mines of the Sierra Nevada foothills confirm the present-day fluxes into the Sacramento River of contaminant metals derived from historical hydraulic Au-mining that occurred during the latter half of the 19th and early part of the 20th centuries. These fluxes occur predominantly during periods of elevated river discharge associated with heavy winter precipitation in northern California. In the broadest context, the study demonstrates the potential for altered precipitation patterns resulting from climate change to affect the mobility and transport of soil-bound contaminants in the surface environment.

Geochimica et Cosmochimica Acta

Environmental considerations related to mining of nonfuel minerals

Throughout most of human history, environmental stewardship during mining has not been a priority partly because of the lack of applicable laws and regulations and partly because of ignorance about the effects that mining can have on the environment. In the United States, the National Environmental Policy Act of 1969, in conjunction with related laws, codified a more modern approach to mining, including the responsibility for environmental stewardship, and provided a framework for incorporating environmental protection into mine planning. Today, similar frameworks are in place in the other developed countries of the world, and international mining companies generally follow similar procedures wherever they work in the world. The regulatory guidance has fostered an international effort among all stakeholders to identify best practices for environmental stewardship. The modern approach to mining using best practices involves the following: (a) establishment of a pre-mining baseline from which to monitor environmental effects during mining and help establish geologically reasonable closure goals; (b) identification of environmental risks related to mining through standardized approaches; and (c) formulation of an environmental closure plan before the start of mining. A key aspect of identifying the environmental risks and mitigating those risks is understanding how the risks vary from one deposit type to another—a concept that forms the basis for geoenvironmental mineral-deposit models. Accompanying the quest for best practices is the goal of making mining sustainable into the future. Sustainable mine development is generally considered to be development that meets the needs of the present generation without compromising the ability of future generations to meet their own needs. The concept extends beyond the availability of nonrenewable mineral commodities and includes the environmental and social effects of mine development. Global population growth, meanwhile, has decreased the percentage of inhabitable land available to support society’s material needs. Presently, the land area available to supply the mineral resources, energy resources, water, food, shelter, and waste disposal needs of all Earth’s inhabitants is estimated to be 135 square meters per person. Continued global population growth will only increase the challenges of sustainable mining. Current trends in mining are also expected to lead to new environmental challenges in the future, among which are mine-waste management issues related to mining larger deposits for lower ore grade; water-management issues related to both the mining of larger deposits and the changes in precipitation brought about by climate change; and greenhouse gas issues related to reducing the carbon footprint of larger, more energy-intensive mining operations.

Professional Paper

Conceptual models of the formation of acid-rock drainage at road cuts in Tennessee

Pyrite and other minerals containing sulfur and trace metals occur in several rock formations throughout Middle and East Tennessee. Pyrite (FeS2) weathers in the presence of oxygen and water to form iron hydroxides and sulfuric acid. The weathering and interaction of the acid on the rocks and other minerals at road cuts can result in drainage with low pH (< 4) and high concentrations of trace metals. Acid-rock drainage can cause environmental problems and damage transportation infrastructure. The formation and remediation of acid-drainage from roads cuts has not been researched as thoroughly as acid-mine drainage. The U.S Geological Survey, in cooperation with the Tennessee Department of Transportation, is conducting an investigation to better understand the geologic, hydrologic, and biogeochemical factors that control acid formation at road cuts. Road cuts with the potential for acid-rock drainage were identifed and evaluated in Middle and East Tennessee. The pyrite-bearing formations evaluated were the Chattanooga Shale (Devonian black shale), the Fentress Formation (coal-bearing), and the Precambrian Anakeesta Formation and similar Precambrian rocks. Conceptual models of the formation and transport of acid-rock drainage (ARD) from road cuts were developed based on the results of a literature review, site reconnaissance, and the initial rock and water sampling. The formation of ARD requires a combination of hydrologic, geochemical, and microbial interactions which affect drainage from the site, acidity of the water, and trace metal concentrations. The basic modes of ARD formation from road cuts are; 1 - seeps and springs from pyrite-bearing formations and 2 - runoff over the face of a road cut in a pyrite-bearing formation. Depending on site conditions at road cuts, the basic modes of ARD formation can be altered and the additional modes of ARD formation are; 3 - runoff over and through piles of pyrite-bearing material, either from construction or breakdown material weathered from shale, and 4 - the deposition of secondary-sulfate minerals can store trace metals and, during rainfall, result in increased acidity and higher concentrations of trace metals in storm runoff. Understanding the factors that control ARD formation and transport are key to addressing the problems associated with the movement of ARD from the road cuts to the environment. The investigation will provide the Tennessee Department of Transportation with a regional characterization of ARD and provide insights into the geochemical and biochemical attributes for the control and remediation of ARD from road cuts.

Tennessee

National water summary 1987: Hydrologic events and water supply and use

Water use in the United States, as measured by freshwater withdrawals in 1985, averaged 338,000 Mgal/d (million gallons per day), which is enough water to cover the 48 conterminous States to a depth of about 2.4 inches. Only 92,300 Mgal/d, or 27.3 percent of the water withdrawn, was consumptive use and thus lost to immediate further use; the remainder of the withdrawals (72.7 percent) was return flow available for reuse a number of times as the water flowed to the sea. The 1985 freshwater withdrawals were much less than the average 30 inches of precipitation that falls on the conterminous States each year; consumptive use accounted for only 7 percent of the estimated annual runoff of 1,230,000 Mgal/d. Nonetheless, as the State summaries on water supply and use clearly show, water is not always available when and where it is needed. Balancing water demands with available water supplies constitutes one of the major resource allocation issues that will face the United States in the coming decade. Of the 1985 freshwater withdrawals, 78.3 percent (265,000 Mgal/d) came from surface-water sources (streams and lakes), and 21.7 percent (73,300 Mgal/d) came from ground water. Surface water provided drinking water for about 47 percent of the Nation's total population. It was the source of 59.9 percent of the Nation's public-supply systems. For self-supplied withdrawals, surface water accounted for 1.6 percent of the domestic and commercial uses; 64.0 percent of the industrial and mining use; 99.4 percent of the thermoelectric generation withdrawals, mainly for cooling water; and 65.6 percent of the agricultural withdrawals. Eight States accounted for 43 percent of the surface-water use; California, Colorado, and Idaho used surface water primarily for irrigation, and Dlinois, Michigan, Ohio, Pennsylvania, and Texas used surface-water primarily for cooling condensers or reactors in thermoelectric plants. Ground water provided drinking water for 53 percent of the Nation's total population and nearly all the rural population. It was the source of 40.1 percent of the public-supply systems withdrawals. For self-supplied withdrawals, ground water accounted for 11.3 percent of the domestic and commercial use, 17.3 percent of the industrial and mining withdrawals, less than 1 percent of the thermoelectric generation withdrawals, and 34.4 percent of the agricultural withdrawals (irrigation and livestock). Eight States Arizona, Arkansas, California, Florida, Idaho, Kansas, Nebraska, and Texas accounted for 66 percent of the ground water used. In each of those States, as in many other States, irrigation was the major use of ground water. Each offstream-use category described in the State summaries public supply, domestic and commercial, industrial and mining, thermoelectric power, and agriculture (irrigation and livestock) followed its own geographic pattern as described below. Consumptive use of water effectively removes the water from immediate further use downstream of the withdrawal point. Of the total amount of consumptive water use in 1985, agricultural use accounted for about 82.5 percent. More than one-half (53 percent) of irrigation water is consumptively used by evapotranspiration or is incorporated into the crop. This is a good indication of the effect that irrigated agriculture can have in a river basin where irrigation is a major activity. The availability of return flows for reuse depends largely on where the water reenters the system. If the return flows are discharged to a stream, they usually can be reused; if they are discharged to a saltwater estuary, they are effectively lost to further use because of water-quality degradation just as if the water had been consumptively used. Similarly, water that recharges a highly transmissive aquifer can be available for reuse either through pumpage from a well or as discharge to a local stream. Thus, much of the water withdrawn for different uses can and does become available for further use although the quality might degrade with each additional use. The allocation and the management of water resources are the responsibilities of the individual States and water institutions within the States. These institutions are evolving in response to the challenges of water management problems. As the individual State summaries indicate, recent State legislation deals with facilitating water transfers within the States as a means of reducing imbalances between water supplies and use, with emphasizing water conservation in times of drought and at places where groundwater depletion is a problem of long standing, and with reducing threats to public health and the environment from water pollution. Most of the State summaries indicate the expectation that water use will continue to increase in the future and that water contamination will continue to be a major water concern. Both issues will require increasingly intensive water management in the future. Whether the water resources under management are considered to be fully appropriated or over appropriated, as in some Western States, or whether the resource could support additional development, as is the situation in most States, improved water-use information will play a key role in future water management efforts.

Water Supply Paper

Characterization of arsenic species in microbial mats from an inactive gold mine

Filamentous cyanobacterial mats and Fe oxyhydroxide-rich bacterial mats collected near an inactive gold mine in California are enriched in arsenic (As) approximately 1000-fold relative to the waters in contact with them. The predominant organism in the cyanobacterial mat could not be identified using morphological characteristics, but the unique morphology of the sheath-forming β protobacterium Leptothrix ochracea was used to identify this species in Fe oxyhydroxide mat samples from several sites near the gold mine. Leptothrix sheaths commonly exceed 10 μm in length and have an average diameter of 1 μm . The Fe-oxyhydroxide mats are dominated by L. ochracea sheaths, but use of fluorescently tagged genetic stains reveals the presence of sheathless bacteria that presumably also promote the formation of Fe oxyhydroxide. X-ray absorption fine structure (XAFS) spectroscopy was used to identify As species in these microbial mats. Mat-associated As is predominantly As(V), even when As(III) is the primary dissolved species in contact with the mats. The species of As(V) associated with the cyanobacterial mat could not be conclusively identified; however, it is not associated with Fe oxyhydroxide or other minerals, based on comparison to XAFS spectra of As adsorbed to various substrates. In addition, the cyanobacterial mat XAFS spectrum is different from that of aqueous As(V), suggesting that As(V) in the mat lacks some or all of the coordinating water molecules present in aqueous solution. We hypothesize that As is associated with the exopolysaccharide (EPS) matrix secreted by the cyanobacteria. In Leptothrix -dominated Fe-oxyhydroxide bacterial mats, XAFS analysis clearly indicates that As(V) is associated with the Fe oxyhydroxide as an adsorbed and/or coprecipitated complex.

California

Zinc isotope investigation of surface and pore waters in a mountain watershed impacted by acid rock drainage

The pollution of natural waters with metals derived from the oxidation of sulfide minerals like pyrite is a global environmental problem. However, the metal loading pathways and transport mechanisms associated with acid rock drainage reactions are often difficult to characterize using bulk chemical data alone. In this study, we evaluated the use of zinc (Zn) isotopes to complement traditional geochemical tools in the investigation of contaminated waters at the former Waldorf mining site in the Rocky Mountains, Colorado, U.S.A. Geochemical signatures and statistical analysis helped in identifying two primary metal loading pathways at the Waldorf site. The first was characterized by a circumneutral pH, high alkalinity, and high Zn/Cd ratios. The second was characterized by acidic pHs and low Zn/Cd ratios. Zinc isotope signatures in surface water samples collected across the site were remarkably similar (the δ 66 Zn, relative to JMC 3-0749-L, for most samples ranged from 0.20 to 0.30‰ ± 0.09‰ 2σ). This probably suggests that the ultimate source of Zn is consistent across the Waldorf site, regardless of the metal loading pathway. The δ 66 Zn of pore water samples collected within a nearby metal-impacted wetland area, however, were more variable, ranging from 0.20 to 0.80‰ ± 0.09‰ 2σ. Here the Zn isotopes seemed to reflect differences in groundwater flow pathways. However, a host of secondary processes might also have impacted Zn isotopes, including adsorption of Zn onto soil components, complexation of Zn with dissolved organic matter, uptake of Zn into plants, and the precipitation of Zn during the formation of reduced sulfur species. Zinc isotope analysis proved useful in this study; however, the utility of this isotopic tool would improve considerably with the addition of a comprehensive experimental foundation for interpreting the complex isotopic relationships found in soil pore waters.

Colorado

Hydrothermal vents and methane seeps: Rethinking the sphere of influence

Although initially viewed as oases within a barren deep ocean, hydrothermal vent and methane seep communities are now recognized to interact with surrounding ecosystems on the sea floor and in the water column, and to affect global geochemical cycles. The importance of understanding these interactions is growing as the potential rises for disturbance from oil and gas extraction, seabed mining and bottom trawling. Here we synthesize current knowledge of the nature, extent and time and space scales of vent and seep interactions with background systems. We document an expanded footprint beyond the site of local venting or seepage with respect to elemental cycling and energy flux, habitat use, trophic interactions, and connectivity. Heat and energy are released, global biogeochemical and elemental cycles are modified, and particulates are transported widely in plumes. Hard and biotic substrates produced at vents and seeps are used by &ldquo;benthic background&rdquo; fauna for attachment substrata, shelter, and access to food via grazing or through position in the current, while particulates and fluid fluxes modify planktonic microbial communities. Chemosynthetic production provides nutrition to a host of benthic and planktonic heterotrophic background species through multiple horizontal and vertical transfer pathways assisted by flow, gamete release, animal movements, and succession, but these pathways remain poorly known. Shared species, genera and families indicate that ecological and evolutionary connectivity exists among vents, seeps, organic falls and background communities in the deep sea; the genetic linkages with inactive vents and seeps and background assemblages however, are practically unstudied. The waning of venting or seepage activity generates major transitions in space and time that create links to surrounding ecosystems, often with identifiable ecotones or successional stages. The nature of all these interactions is dependent on water depth, as well as regional oceanography and biodiversity. Many ecosystem services are associated with the interactions and transitions between chemosynthetic and background ecosystems, for example carbon cycling and sequestration, fisheries production, and a host of non-market and cultural services. The quantification of the sphere of influence of vents and seeps could be beneficial to better management of deep-sea environments in the face of growing industrialization.

Frontiers in Marine Science