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USGS2015

Chemical variations in Yellowknife Bay formation sedimentary rocks analyzed by ChemCam on board the Curiosity rover on Mars

The Yellowknife Bay formation represents a ~5 m thick stratigraphic section of lithified fluvial and lacustrine sediments analyzed by the Curiosity rover in Gale crater, Mars. Previous works have mainly focused on the mudstones that were drilled by the rover at two locations. The present study focuses on the sedimentary rocks stratigraphically above the mudstones by studying their chemical variations in parallel with rock textures. Results show that differences in composition correlate with textures and both manifest subtle but significant variations through the stratigraphic column. Though the chemistry of the sediments does not vary much in the lower part of the stratigraphy, the variations in alkali elements indicate variations in the source material and/or physical sorting, as shown by the identification of alkali feldspars. The sandstones contain similar relative proportions of hydrogen to the mudstones below, suggesting the presence of hydrous minerals that may have contributed to their cementation. Slight variations in magnesium correlate with changes in textures suggesting that diagenesis through cementation and dissolution modified the initial rock composition and texture simultaneously. The upper part of the stratigraphy (~1 m thick) displays rocks with different compositions suggesting a strong change in the depositional system. The presence of float rocks with similar compositions found along the rover traverse suggests that some of these outcrops extend further away in the nearby hummocky plains.

Journal of Geophysical Research E: Planets↗

USGS2006

Nature and origin of the hematite-bearing plains of Terra Meridiani based on analyses of orbital and Mars Exploration rover data sets

The ∼5 km of traverses and observations completed by the Opportunity rover from Endurance crater to the Fruitbasket outcrop show that the Meridiani plains consist of sulfate‐rich sedimentary rocks that are largely covered by poorly‐sorted basaltic aeolian sands and a lag of granule‐sized hematitic concretions. Orbital reflectance spectra obtained by Mars Express OMEGA over this region are dominated by pyroxene, plagioclase feldspar, crystalline hematite (i.e., concretions), and nano‐phase iron oxide dust signatures, consistent with Pancam and Mini‐TES observations. Mössbauer Spectrometer observations indicate more olivine than observed with the other instruments, consistent with preferential optical obscuration of olivine features in mixtures with pyroxene and dust. Orbital data covering bright plains located several kilometers to the south of the landing site expose a smaller areal abundance of hematite, more dust, and a larger areal extent of outcrop compared to plains proximal to the landing site. Low‐albedo, low‐thermal‐inertia, windswept plains located several hundred kilometers to the south of the landing site are predicted from OMEGA data to have more hematite and fine‐grained olivine grains exposed as compared to the landing site. Low calcium pyroxene dominates spectral signatures from the cratered highlands to the south of Opportunity. A regional‐scale model is presented for the formation of the plains explored by Opportunity, based on a rising ground water table late in the Noachian Era that trapped and altered local materials and aeolian basaltic sands. Cessation of this aqueous process led to dominance of aeolian processes and formation of the current configuration of the plains.

Journal of Geophysical Research E: Planets↗

USGS2012

Structural evidence for northeastward movement on the Chocolate Mountains Thrust, southeasternmost California

The Late Cretaceous Chocolate Mountains thrust of southeastern California and southwestern Arizona places a block of Proterozoic and Mesozoic continental crust over the late Mesozoic continental margin oceanic sedimentary and volcanic rocks of the regionally distinctive Orocopia Schist. The Chocolate Mountains thrust is interpreted as a thrust (burial, subduction) fault rather than a low-angle normal (exhumation, unroofing, uplift) fault. An important parameter required to understand the tectonic significance of the Chocolate Mountains and related thrusts is their sense of movement. The Chocolate Mountains thrust zone contains sparse to locally abundant mesoscopic asymmetric folds. Fabric relations, supported by regional geologic evidence, indicate that these folds are an integral part of and coeval with the thrust zone. On a lower hemisphere equal-area plot representing the orientation and sense of asymmetry of 80 thrust zone folds from 36 localities, spread over an area 60 by 10 km, Z folds plot northwest of and S folds plot southeast of a northeast-southwest striking vertical plane of overall monoclinic symmetry. The only sense of movement consistent with the collective asymmetry of the thrust zone folds is top to the northeast. Asymmetric microstructures studied at several localities also indicate top to the northeast movement. Paleomagnetic data suggest that the original sense of thrusting, prior to Neogene vertical axis tectonic rotation related to the San Andreas fault system, was northward. The essential point is that movement of the upper plate of the Chocolate Mountains thrust evidently was continentward. Continentward thrusting suggests a tectonic scenario in which an insular or peninsular microcontinental fragment collided with mainland southern California. The suture predicted by this model is elusive; but the Chocolate Mountains thrust and underlying Orocopia Schist themselves may represent the suture, at the present level of exposure. Alternative tectonic models involving subduction of the Orocopia Schist eastward beneath continental southern California circumvent the suture problem but are presently not supported by any direct structural evidence.

Journal of Geophysical Research↗

USGS2022

Mars Science Laboratory CheMin data from the Glen Torridon region and the significance of lake-groundwater interactions in interpreting mineralogy and sedimentary history

The Glen Torridon (GT) region is positioned in terrains with strong clay mineral signatures, as inferred from orbital spectroscopy. The GT campaign confirmed orbital distinctions with in situ measurements by the Mars Science Laboratory rover, Curiosity , and the CheMin X-ray diffraction instrument with of some of the highest clay mineral abundances to date. Additionally, GT is unique because of distinct phase identifications for the first time by CheMin, including: (i) Fe-carbonates, and (ii) a novel peak in the XRD patterns of some GT samples, with an interplanar spacing of at 9.2 Å. Fe-carbonates have been previously suggested from other instruments onboard, but this is the first definitive reporting by CheMin of multiple samples with Fe-carbonate. This new phase has never been observed in Gale crater with the CheMin instrument and may be a new mineral for Mars, but discrete identification still remains enigmatic because no single phase on Earth is able to account the mineralogical, geochemical, and sedimentological constraints in the GT region. Here, we modeled XRD profiles and propose an interstratified clay mineral, specifically greenalite-minnesotaite (G-M), as a reasonable candidate. The coexistence of Fe-carbonate and Fe-rich clay minerals in the GT samples, supports a conceptual model of a lacustrine groundwater mixing environment in the ancient Gale crater lake. Groundwater interaction with percolating lake waters in the sediments is common in terrestrial lacustrine settings, and the diffusion of two distinct water bodies within the subsurface can create a geochemical gradient and unique mineral front in the sediments. Ultimately, the proximity to this mixing zone controlled the secondary minerals preserved in the Jura, Knockfarril Hill, and Glasgow members of the Mt. Sharp group exposed in GT.

Journal of Geophysical Research E: Planets↗

USGS2006

Overview of the Opportunity Mars Exploration Rover Mission to Meridiani Planum: Eagle Crater to Purgatory Ripple

The Mars Exploration Rover Opportunity touched down at Meridiani Planum in January 2004 and since then has been conducting observations with the Athena science payload. The rover has traversed more than 5 km, carrying out the first outcrop‐scale investigation of sedimentary rocks on Mars. The rocks of Meridiani Planum are sandstones formed by eolian and aqueous reworking of sand grains that are composed of mixed fine‐grained siliciclastics and sulfates. The siliciclastic fraction was produced by chemical alteration of a precursor basalt. The sulfates are dominantly Mg‐sulfates and also include Ca‐sulfates and jarosite. The stratigraphic section observed to date is dominated by eolian bedforms, with subaqueous current ripples exposed near the top of the section. After deposition, interaction with groundwater produced a range of diagenetic features, notably the hematite‐rich concretions known as “blueberries.” The bedrock at Meridiani is highly friable and has undergone substantial erosion by wind‐transported basaltic sand. This sand, along with concretions and concretion fragments eroded from the rock, makes up a soil cover that thinly and discontinuously buries the bedrock. The soil surface exhibits both ancient and active wind ripples that record past and present wind directions. Loose rocks on the soil surface are rare and include both impact ejecta and meteorites. While Opportunity's results show that liquid water was once present at Meridiani Planum below and occasionally at the surface, the environmental conditions recorded were dominantly arid, acidic, and oxidizing and would have posed some significant challenges to the origin of life.

Journal of Geophysical Research E: Planets↗

USGS2000

Sedimentary petrology of a declining reef ecosystem, Florida reef tract (U.S.A.)

Petrologic evaluation of biogenic sediments collected shelf-wide along the Florida reef tract in 1989 revealed three principal components: coral, the calcareous green alga Halimeda, and mollusc. The dominant grain was dependent in part upon local morphology that controlled composition and vitality of the biota. Either Halimeda or mollusc grains prevailed in sands off the upper Keys. In the middle and lower Keys, Halimeda grains prevailed nearshore and coral grains offshore. Comparison with similar analyses of samples collected in 1952 and 1963 indicates that, over 37 years, the relative abundance of molluscan grains more than doubled in the upper Keys and that of particulate coral tripled in the middle Keys. These changes can be interpreted in the context of physical and biological events that affected Florida Keys reefs over that period of time. In the 1970s, outbreaks of extremely cold water killed even representatives of the hardiest coral species. In the 1980s, black-band and white-band diseases decimated the major reef-building acroporid corals, and the pivotal herbivore, Diadema antillarum, disappeared. Although Diadema is a major coral bioeroder, the sea urchin is also essential to healthy reef growth. The increase in coral debris in the middle Keys may be related to Hurricane Donna in 1960, but it is also consistent with the prediction of accelerated bioerosion by boring organisms in response to increased plankton productivity. Plankton productivity is stimulated by nutrients from Florida Bay and by well-documented eutrophication of nearshore environments. In the upper Keys, where reefs are somewhat removed from bay and nearshore influence, a relative decrease in coral debris over the 37 years may reflect proliferation of algae and algae-grazing molluscs as well as suppressed rates of bioerosion in the absence of Diadema. Human activities have substantially increased the natural flux of fixed nitrogen to coastal systems worldwide. Waters in the Florida Keys are no exception. Spatial and temporal trends in sediment constituents are compared to a previously published model that predicts the response of benthic biota to changes in nutrient supply. As adapted to interpret changes observed in reef-tract sediments, the model provides insights into the natural nutrient gradient along the Florida reef tract.

Journal of Coastal Research↗

USGS1999

Debris-flow origin for the Simud/Tiu deposit on Mars

A late Hesperian smooth plains deposit on Mars interpreted as a debris flow extends more than 2000 km from Hydraotes Chaos, through Simud and Tiu Valles, and into Chryse Planitia. The Simud/Tiu deposit widens out to >1000 km and embays streamlined landforms and knobs made up of sedimentary and perhaps volcanic deposits that were carved by earlier channeling activity. Morphologic features of the Simud/Tiu deposit observed in Viking and Pathfinder images are generally consistent with a debris-flow origin, but some of the deposit's salient features are not readily explained by catastrophic flooding or ice flow. Internal depressions appear to be bounded by linear scarps along flow margins where differential shearing may have occurred and in areas where flow spreading may have produced zones of extensional breakup and thinning within the flow. Possible flow lobes within the deposit may have formed by successive flow surges within the flow unit. The Pathfinder landing site is on the Simud/Tiu deposit, and the observations there are consistent with debris flow. The low, longitudinal ridges at the site may have formed by clast interactions as the flow ground to a halt. Imbricated, planar rocks on the ridges, such as in the Rock Garden, also may have been emplaced by debris or ice flow. However, stream energy calculations at Ares Vallis and channel geology indicate that flooding probably was incapable of emplacing the meter-size boulders observed at the Pathfinder site. Dewatering of pressurized zones in the debris flow or underlying material may be responsible for mud eruptions that formed a couple of patches of low pancakelike shields up to 5 km in diameter and for probable water flows that formed two small rille channels a few kilometers long. Local irregular grooves may be cracks that resulted from later desiccation and contraction of the flow material. The debris-flow unit apparently coalesced from outflows of water-fluidized debris originating from beneath chaotic and hummocky terrains within and along the margins of Simud and Tiu Valles. The deposit is onlapped from the north by another flow deposit originating from Acidalia Planitia. If the Simud/Tiu debris flow had entered a standing body of water, a turbidity current may have arisen from the debris flow and then backflowed over the debris flow to account for the Acidalia deposit.

Journal of Geophysical Research E: Planets↗

USGS2012

Evolution of deep structure along the trans-Alaska crustal transect, Chugach Mountains and Copper River Basin, southern Alaska

One of the most important results of the Trans-Alaska Crustal Transect investigations is the discovery that more than one third of the North American plate in southern Alaska (Chugach Mountains and Copper River basin) consists of tectonically underplated oceanic lithosphere. In southern Alaska, exposed accreted tectonostratigraphic terranes, include, from south to north along the transect, the Prince William, Chugach, Peninsular, and Wrangellia terranes. Chief results from seismic refraction data include the following: (1) A sequence of layers of low and high velocity (5.7–7.8 km/s), more than 10 km thick, dips gently northward, with its top at the surface in the southernmost Chugach terrane and at more than 20-km depth beneath the southern Peninsular terrane. A high-velocity layer at the top of this sequence corresponds to metabasalt in the southernmost Chugach terrane. This sequence is interpreted to be tectonically underplated fragments of the Kula plate and its sedimentary overburden. (2) An intermediate-velocity layer (6.35–6.5 km/s) at 9-km depth beneath both the northern Chugach and southern Peninsular terranes appears to extend without offset across the deep projection of the suture between these two terranes, the Border Ranges fault system. (3) A crustal “root” between depths of 19 and 57 km beneath the northern Peninsular and Wrangellia terranes appears to extend without offset across the deep projection of the suture between these two terranes, the West Fork fault system. This crustal root also appears to abut the tectonically underplated sequence to the south. Unfortunately, in results 2 and 3 the apparent crosscutting and abutting relationships can not be unambiguously resolved. Three scenarios, A, B, and C, have been offered to explain the evolution of this structure. Scenarios A and B differ in interpretation of the depth extent of the northern Chugach and southern Peninsular terranes. In scenario A these terranes extend to only 9-km depth, where they rest on an unknown middle crust, interpreted as a deeper part of the Peninsular terrane. In this scenario, the northern Chugach and southern Peninsular terrenes moved landward as a tectonic wedge, during tectonic underplating in the latest Cretaceous or early Tertiary, and uplifted the upper crust of the Peninsular terrane to the north. In scenario B, the northern Chugach and southern Peninsular terranes extend to 20-km depth. In this scenario, they were compressed but not detached and displaced during accretion. Scenarios A, B, and C differ in interpretation of the deep crustal root that appears to abut the tectonically underplated sequence. Since the Peninsular and Wrangellia terranes were at or below sea level prior to the mid-Cretaceous, the root was probably emplaced in mid-Cretaceous or younger times. In scenario A the root is lower crust of North America that moved southward during tectonic underplating of the Kula plate. In scenario B the root is, in part, tectonically underplated rocks similar to the Kula plate sequence to the south. In scenario C the root is, in part, magmatically underplated rocks.

Journal of Geophysical Research↗

USGS2007

Earthquake-by-earthquake fold growth above the Puente Hills blind thrust fault, Los Angeles, California: Implications for fold kinematics and seismic hazard

Boreholes and high-resolution seismic reflection data collected across the forelimb growth triangle above the central segment of the Puente Hills thrust fault (PHT) beneath Los Angeles, California, provide a detailed record of incremental fold growth during large earthquakes on this major blind thrust fault. These data document fold growth within a discrete kink band that narrows upward from ???460 m at the base of the Quaternary section (200-250 m depth) to <150 m at 2.5 m depth, with most growth during the most recent folding event occurring within a zone only ???60 m wide. These observations, coupled with evidence from petroleum industry seismic reflection data, demonstrate that most (>82% at 250 m depth) folding and uplift occur within discrete kink bands, thereby enabling us to develop a paleoseismic history of the underlying blind thrust fault. The borehole data reveal that the youngest part of the growth triangle in the uppermost 20 m comprises three stratigraphically discrete growth intervals marked by southward thickening sedimentary strata that are separated by intervals in which sediments do not change thickness across the site. We interpret the intervals of growth as occurring after the formation of now-buried paleofold scarps during three large PHT earthquakes in the past 8 kyr. The intervening intervals of no growth record periods of structural quiescence and deposition at the regional, near-horizontal stream gradient at the study site. Minimum uplift in each of the scarp-forming events, which occurred at 0.2-2.2 ka (event Y), 3.0-6.3 ka (event X), and 6.6-8.1 ka (event W), ranged from ???1.1 to ???1.6 m, indicating minimum thrust displacements of ???2.5 to 4.5 m. Such large displacements are consistent with the occurrence of large-magnitude earthquakes (Mw > 7). Cumulative, minimum uplift in the past three events was 3.3 to 4.7 m, suggesting cumulative thrust displacement of ???7 to 10.5 m. These values yield a minimum Holocene slip rate for the PHT of ???0.9 to 1.6 mm/yr. The borehole and seismic reflection data demonstrate that dip within the kink band is acquired incrementally, such that older strata that have been deformed by more earthquakes dip more steeply than younger strata. Specifically, strata dip 0.4?? at 4 m depth, 0.7?? at 20 m depth, 8?? at 90 m, 16?? at 110 m, and 17?? at 200 m. Moreover, structural restorations of the borehole data show that the locus of active folding (the anticlinal active axial surface) does not extend to the surface in exactly the same location from earthquake to earthquake. Rather, that the axial surfaces migrate from earthquake to earthquake, reflecting a component of fold growth by kink band migration. The incremental acquisition of bed dip in the growth triangle may reflect some combination of fold growth by limb rotation in addition to kink band migration, possibly through a component of trishear or shear fault bend folding. Alternatively, the component of limb rotation may result from curved hinge fault bend folding, and/or the mechanical response of loosely consolidated granular sediments in the shallow subsurface to folding at depth. Copyright 2007 by the American Geophysical Union.

Journal of Geophysical Research B: Solid Earth↗

USGS2012

Tectonic setting of the Yukon-Koyukuk basin and its borderlands, western Alaska

The Yukon-Koyukuk basin of western Alaska is composed of an arcuate belt of Jurassic and Early Cretaceous subduction-related volcanic and plutonic rocks (Koyukuk terrane) flanked by deep subbasins filled with mid-Cretaceous terrigenous sedimentary rocks. The basin is bordered on three sides by metamorphosed Proterozoic and Paleozoic continental rocks (Seward, Arctic Alaska, and Ruby terranes) and is separated from the metamorphic borderlands by a narrow, highly tectonized belt of oceanic crust and mantle rocks (composite Angayucham-Tozitna terrane). The oceanic and mantle rocks, which dip inward beneath the basin and are thrust outward onto the borderlands, are divided into three separate thrust panels: (1) a structurally lowest panel (Slate Creek) composed of phyllite and metagraywacke of probable Devonian age, (2) a middle panel (Narvak) composed of imbricated basalt, chert, and gabbro of Devonian to Early Jurassic age, and (3) a structurally highest panel (Kanuti) composed of gabbro and peridotite of probable Middle and Late Jurassic age. The three thrust panels appear to represent a reversely stacked sequence that progresses from continental slope deposits in the lower panel to cumulus and mantle peridotites in the upper. Metamorphic mineral K-Ar ages from garnet amphibolite on the sole of the upper panel suggest that the upper panel was emplaced on the middle panel in the Middle to Late Jurassic. Subsequent accretion of all three panels to the continental rocks of the borderlands occurred in the latest Jurassic and Early Cretaceous, synchronous with arc volcanism within the basin. Arc volcanism waned and the accretionary phase ended in the middle of Early Cretaceous time. Uplift and erosion of the metamorphic borderlands and the obducted oceanic rocks began in late Early Cretaceous and was accompanied by the rapid filling of two flanking subbasins with turbiditic sediments. In the latest Early Cretaceous and early Late Cretaceous, shallow marine and nonmarine conglomerates were deposited around the margins of the basin, and a prograding delta was built out from the southeast margin of the basin across the turbiditic subbasins and the remnant volcanic arc. In the Late Cretaceous, western Alaska was subjected to strong east-west compression which severely deformed both the Yukon-Koyukuk basin and the borderlands. Several widespread magmatic episodes in the mid- and Late Cretaceous and in early Tertiary transgress the basin boundaries and stitch together the accreted arc and oceanic terranes and the continental borderlands.

Journal of Geophysical Research Solid Earth↗

USGS2001

Mars Global Surveyor Thermal Emission Spectrometer experiment: Investigation description and surface science results

The Thermal Emission Spectrometer (TES) investigation on Mars Global Surveyor (MGS) is aimed at determining (1) the composition of surface minerals, rocks, and ices; (2) the temperature and dynamics of the atmosphere; (3) the properties of the atmospheric aerosols and clouds; (4) the nature of the polar regions; and (5) the thermophysical properties of the surface materials. These objectives are met using an infrared (5.8- to 50-μm) interferometric spectrometer, along with broadband thermal (5.1- to 150-μm) and visible/near-IR (0.3- to 2.9-μm) radiometers. The MGS TES instrument weighs 14.47 kg, consumes 10.6 W when operating, and is 23.6×35.5×40.0 cm in size. The TES data are calibrated to a 1-σ precision of 2.5 −6 ×10 −8 W cm −2 sr −1 /cm −1 , 1.6×10 −6 W cm −2 sr −1 , and ∼0.5 K in the spectrometer, visible/near-IR bolometer, and IR bolometer, respectively. These instrument subsections are calibrated to an absolute accuracy of ∼4×10 −8 W cm −2 sr −1 /cm −1 (0.5 K at 280 K), 1–2%, and ∼1–2 K, respectively. Global mapping of surface mineralogy at a spatial resolution of 3 km has shown the following: (1) The mineralogic composition of dark regions varies from basaltic, primarily plagioclase feldspar and clinopyroxene, in the ancient, southern highlands to andesitic, dominated by plagioclase feldspar and volcanic glass, in the younger northern plains. (2) Aqueous mineralization has produced gray, crystalline hematite in limited regions under ambient or hydrothermal conditions; these deposits are interpreted to be in-place sedimentary rock formations and indicate that liquid water was stable near the surface for a long period of time. (3) There is no evidence for large-scale (tens of kilometers) occurrences of moderate-grained (>50-μm) carbonates exposed at the surface at a detection limit of ∼10%. (4) Unweathered volcanic minerals dominate the spectral properties of dark regions, and weathering products, such as clays, have not been observed anywhere above a detection limit of ∼10%; this lack of evidence for chemical weathering indicates a geologic history dominated by a cold, dry climate in which mechanical, rather than chemical, weathering was the significant form of erosion and sediment production. (5) There is no conclusive evidence for sulfate minerals at a detection limit of ∼15%. The polar region has been studied with the following major conclusions: (1) Condensed CO 2 has three distinct end-members, from fine-grained crystals to slab ice. (2) The growth and retreat of the polar caps observed by MGS is virtually the same as observed by Viking 12 Martian years ago. (3) Unique regions have been identified that appear to differ primarily in the grain size of CO 2 ; one south polar region appears to remain as black slab CO 2 ice throughout its sublimation. (4) Regional atmospheric dust is common in localized and regional dust storms around the margin and interior of the southern cap. Analysis of the thermophysical properties of the surface shows that (1) the spatial pattern of albedo has changed since Viking observations, (2) a unique cluster of surface materials with intermediate inertia and albedo occurs that is distinct from the previously identified low-inertia/bright and high-inertia/dark surfaces, and (3) localized patches of high-inertia material have been found in topographic lows and may have been formed by a unique set of aeolian, fluvial, or erosional processes or may be exposed bedrock.

Journal of Geophysical Research E: Planets↗

USGS1991

Fluid inclusions and preliminary studies of hydrothermal alteration in core hole PLTG-1, Platanares geothermal area, Honduras

The Platanares geothermal area in western Honduras consists of more than 100 hot springs that issue from numerous hot-spring groups along the banks or within the streambed of the Quebrada de Agua Caliente (brook of hot water). Evaluation of this geothermal area included drilling a 650-m deep PLTG-1 drill hole which penetrated a surface mantling of stream terrace deposits, about 550 m of Tertiary andesitic lava flows, and Cretaceous to lower Tertiary sedimentary rocks in the lower 90 m of the drill core. Fractures and cavities in the drill core are partly to completely filled by hydrothermal minerals that include quartz, kaolinite, mixed-layer illite-smectite, barite, fluorite, chlorite, calcite, laumontite, biotite, hematite, marcasite, pyrite, arsenopyrite, stibnite, and sphalerite; the most common open-space fillings are calcite and quartz. Biotite from 138.9-m depth, dated at 37.41 Ma by replicate 40Ar/39 Ar analyses using a continuous laser system, is the earliest hydrothermal mineral deposited in the PLTG-1 drill core. This mid-Tertiary age indicates that at least some of the hydrothermal alteration encountered in the PLTG-1 drill core occurred in the distant past and is unrelated to the present geothermal system. Furthermore, homogenization temperatures (Th) and melting-point temperatures (Tm) for fluid inclusions in two of the later-formed hydrothermal minerals, calcite and barite, suggest that the temperatures and concentration of dissolved solids of the fluids present at the time these fluid inclusions formed were very different from the present temperatures and fluid chemistry measured in the drill hole. Liquid-rich secondary fluid inclusions in barite and caicite from drill hole PLTG-1 have Th values that range from about 20??C less than the present measured temperature curve at 590.1-m depth to as much as 90??C higher than the temperature curve at 46.75-m depth. Many of the barite Th measurements (ranging between 114?? and 265??C) plot above the reference surface boiling-point curve for pure water assuming hydrostatic conditions; however, the absence of evidence for boiling in the fluid inclusions indicates that at the time the minerals formed, the ground surface must have been at least 80 m higher than at present and underwent stream erosion to the current elevation. Near-surface mixed-layer illite-smectite is closely associated with barite and appears to have formed at about the same temperature range (about 120?? to 200??C) as the fluid-inclusion Th values for barite. Fluid-inclusion Th values for calcite range between about 136?? and 213??C. Several of the calcite Th values are significantly lower than the present measured temperature curve. The melting-point temperatures (Tm) of fluid-inclusion ice yield calculated salinities, ranging from near zero to as much as 5.4 wt. % NaCl equivalent, which suggest that much of the barite and calcite precipitated from fluids of significantly greater salinity than the present low salinity Platanares hot-spring water or water produced from the drill hole.

Journal of Volcanology and Geothermal Research↗

USGS2012

Remarkable isotopic and trace element trends in potassic through sodic Cretaceous plutons of the Yukon-Koyukuk Basin, Alaska, and the nature of the lithosphere beneath the Koyukuk terrane

During the period from 110 to 80 m.y. ago, a 450-km-long magmatic belt was active along the northern margin of Yukon-Koyukuk basin and on eastern Seward Peninsula. The plutons intruded Upper Jurassic(?) and Lower Cretaceous volcanic arc rocks and Cretaceous sedimentary rocks in Yukon-Koyukuk basin and Proterozoic and lower Paleozoic continental rocks in Seward Peninsula. Within Yukon-Koyukuk basin, the plutons vary in composition from calc-alkalic plutons on the east to potassic and ultrapotassic alkalic plutons on the west. Plutons within Yukon-Koyukuk basin were analyzed for trace element and isotopic compositions in order to discern their origin and the nature of the underling lithosphere. Farthest to the east, the calc-alkalic rocks of Indian Mountain pluton are largely tonalite and sodic granodiorite, and have low Rb (average 82 ppm), high Sr (>600 ppm), high chondrite-normalized (cn) Ce/Yb (16–37), low δ 18 O (+6.5 to +7.1), low initial 87 Sr/ 86 Sr (SIR) (0.704), and high initial 143 Nd/ 144 Nd (NIR) (0.5126). These rocks resemble those modelled elsewhere as partial melts and subsequent fractionates of basaltic or gabbroic metaigneous rocks, and may be products of melting in the deeper parts of the Late Jurassic(?) and Early Cretaceous volcanic arc. Farthest to the west, the two ultrapotassic bodies of Selawik and Inland Lake are high in Cs (up to 93 ppm), Rb (up to 997 ppm), Sr, Ba, Th, and light rare earth elements, have high (Ce/Yb)cn (30, 27), moderate to low δ 18 O (+8.4, +6.9), high SIR (0.712, 0.710), and moderate NIR (0.5121–0.5122). These rocks resemble rocks of Australia and elsewhere that were modelled as melts of continental mantle that had been previously enriched in large cations. This mantle may be Paleozoic or older. The farthest west alkalic pluton of Selawik Hills is largely monzonite, quartz monzonite, and granite; has moderate Rb (average 284 ppm), high Sr (>600 ppm), high (Ce/Yb)cn (15–25), moderate δ 18 O (+8.3 to +8.6), high SIR (0.708–0.712), and moderate NIR (0.5121–0.5122). These rocks may be the product of interaction of magma derived from old continental mantle and magma derived from old continental crust. Plutons between eastern and western extremes show completely gradational variations in the concentration of K and Rb and in the isotopic compositions of Sr, Nd, and O. These plutons probably originated either by melting in a mixed source composed of a Paleozoic or older continental section (mantle + crust) overlain by Mesozoic mafic arc rocks, or by mixing of ultrapotassic to potassic magmas from continental sources (mantle + crust), and tonalitic magmas from arc sources. We infer from these results that the northwest portion of Yukon-Koyukuk basin is underlain by a substantial continental basement of Paleozoic or greater age. This basement probably thins out to the east. There is no geochemical evidence for continental basement east of about longitude 157°, or along a belt of at least 50 km width flanking Ruby Geanticline as far to the southwest as about longitude 161°. These areas are probably underlain by oceanic and Mesozoic arc rocks.

Alaska↗

USGS1996

Long-term geochemical surveillance of fumaroles at Showa-Shinzan dome, Usu volcano, Japan

This study investigates 31 years of fumarole gas and condensate (trace elements) data from Showa-Shinzan, a dacitic dome-cryptodome complex that formed during the 1943-1945 eruption of Usu volcano. Forty-two gas samples were collected from the highest-temperature fumarole, named A-1, from 1954 (800??C) to 1985 (336??C), and from lower-temperature vents. Condensates were collected contemporaneously with the gas samples, and we reanalyzed ten of these samples, mostly from the A-1 vent, for 32 cations and three anions. Modeling using the thermochemical equilibrium program, SOLVGAS, shows that the gas samples are mild disequilibrium mixtures because they: (a) contain unequilibrated sedimentary CH4 and NH3; (b) have unequilibrated meteoric water; or (c) lost CO, either by air oxidation or by absorption by the sodium hydroxide sampling solution. SOLVGAS also enabled us to restore the samples by removing these disequilibrium effects, and to estimate their equilibrium oxygen fugacities and amounts of S2 and CH4. The restored compositions contain > 98% H2O with minor to trace amounts of CO2, H2, HCl, SO2, HF, H2S, CO, S2 and CH4. We used the restored gas and condensate data to test the hypotheses that these time-series compositional data from the dome's fumaroles provide: (1) sufficient major-gas data to analyze long-term degassing trends of the dome's magma-hydrothermal system without the influence of sampling or contamination effects; (2) independent oxygen fugacity-versus-temperature estimates of the Showa-Shinzan dacite; (3) the order of release of trace elements, especially metals, from magma; and (4) useful information for assessing volcanic hazards. The 1954-1985 restored A-1 gas compositions confirm the first hypothesis because they are sufficient to reveal three long-term degassing trends: (1) they became increasingly H2O-rich with time due to the progressive influx of meteoric water into the dome; (2) their C/S and S/Cl ratios decreased dramatically while their Cl/F ratios stayed roughly constant, indicating the progressive outgassing of less soluble components (F ??? Cl > S > C) from the magma reservoir; and (3) their H2O/H2, CO2/CO and H2S/SO2 ratios increased significantly in concert with equilibrium changes expected for the ??? 500??C temperature drop. When plotted against reciprocal temperature, the restored-gas log oxygen fugacities follow a tight linear trend from < NNO + 0.5 at > 800??C to NNO + 2.5 at ??? 400??C. This trend largely disproves the second hypothesis because the oxygen fugacities for the < 800??C restored gases can only be explained by mixing of hot magmatic gases with ??? 350??C steam from superheated meteoric water. But above 800??C this trend intersects the opposing linear trend for other Usu eruptive products, implying a log oxygen fugacity of -11.45 at 902??C for the Showa-Shinzan magma. The time-series trace-element data also disprove the third hypothesis because rock- and incrustation-particle contaminants in the condensates account for most of the trace-element variation. Nonetheless, highly volatile elements like B and As are relatively unaffected by this particle contamination, and they show similar time-series trends as Cl and F. Finally, except for infrequent sampling around the 1977 Usu eruption, the results generally confirm the fourth hypothesis, since the time-series trends for the major gases and selected trace elements indicate that, with time, the system cooled, degassed and was infiltrated by meteoric water, all of which are positive signs that volcanic activity declined over the 31-year history. This study also suggests that second boiling of shallow magma within and possibly beneath the cryptodome sustained magmatic degassing for at least 20 years after emplacement.

Journal of Volcanology and Geothermal Research↗