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Spatial and temporal trends in nitrate concentrations in the eastern San Joaquin Valley regional aquifer and implications for fertilizer management

Ground-water withdrawals in the San Joaquin Valley totaled 64 million m 3 /day (19 million ac-ft) in 2000, supplying about 45% of agricultural irrigation demand and about 80% of municipal supply (Hutson et al., 2004). Most of the population and ground-water use are in the eastern San Joaquin Valley, where reliance on ground water is expected to increase as a result of rapid population growth and limited surface water supplies. Protection of ground-water quality for future use requires monitoring and understanding the mechanisms controlling the long-term quality of ground water in the regional aquifer system. Nitrate has been widely detected above background concentrations in ground water in the eastern San Joaquin Valley. Nitrate concentrations (reported as nitrogen in this paper) were above the MCL of 10 mg/L in 24% of domestic wells screened in the shallow part of the aquifer that were sampled during 1993–95 (Dubrovsky et al., 1998) and the Central Valley is one of the top three regions in the state in terms of the number of public drinking-water wells exceeding the MCL for nitrate (California State Water Resources Control Board, 2002). To assess spatial and temporal trends in nitrate concentrations in the eastern San Joaquin Valley and to evaluate the long-term effects of nitrogen fertilizer use on ground-water quality in this region, data were evaluated at multiple spatial scales. Data from regional-scale monitoring networks were used to map the regional occurrence of nitrate and to determine whether shallow ground water containing elevated nitrate is migrating to deeper parts of the aquifer system. At the local scale, mean ground-water ages from analysis of age-dating tracers were combined with concentrations of nitrate to reconstruct nitrate inputs in recharge through time and to compare with estimated nitrogen applications. Ground-water flow and transport simulations of a typical public-supply well screened from about 100 to 400 ft below the water table were used to evaluate long-term concentrations beneath agricultural areas under different nitrogen management scenarios.

California

A conceptual model of ground-water flow in the eastern Snake River Plain aquifer at the Idaho National Laboratory and vicinity with implications for contaminant transport

Ground-water flow in the west-central part of the eastern Snake River Plain aquifer is described in a conceptual model that will be used in numerical simulations to evaluate contaminant transport at the Idaho National Laboratory (INL) and vicinity. The model encompasses an area of 1,940 square miles (mi2) and includes most of the 890 mi2 of the INL. A 50-year history of waste disposal associated with research activities at the INL has resulted in measurable concentrations of waste contaminants in the aquifer. A thorough understanding of the fate and movement of these contaminants in the subsurface is needed by the U.S. Department of Energy to minimize the effect that contaminated ground water may have on the region and to plan effectively for remediation. Three hydrogeologic units were used to represent the complex stratigraphy of the aquifer in the model area. Collectively, these hydrogeologic units include at least 65 basalt-flow groups, 5 andesite-flow groups, and 61 sedimentary interbeds. Three rhyolite domes in the model area extend deep enough to penetrate the aquifer. The rhyolite domes are represented in the conceptual model as low permeability, vertical pluglike masses, and are not included as part of the three primary hydrogeologic units. Broad differences in lithology and large variations in hydraulic properties allowed the heterogeneous, anisotropic basalt-flow groups, andesite-flow groups, and sedimentary interbeds to be grouped into three hydrogeologic units that are conceptually homogeneous and anisotropic. Younger rocks, primarily thin, densely fractured basalt, compose hydrogeologic unit 1; younger rocks, primarily of massive, less densely fractured basalt, compose hydrogeologic unit 2; and intermediate-age rocks, primarily of slightly-to-moderately altered, fractured basalt, compose hydrogeologic unit 3. Differences in hydraulic properties among adjacent hydrogeologic units result in much of the large-scale heterogeneity and anisotropy of the aquifer in the model area, and differences in horizontal and vertical hydraulic conductivity in individual hydrogeologic units result in much of the small-scale heterogeneity and anisotropy of the aquifer in the model area. The inferred three-dimensional geometry of the aquifer in the model area is very irregular. Its thickness generally increases from north to south and from west to east and is greatest south of the INL. The interpreted distribution of older rocks that underlie the aquifer indicates large changes in saturated thickness across the model area. The boundaries of the model include physical and artificial boundaries, and ground-water flows across the boundaries may be temporally constant or variable and spatially uniform or nonuniform. Physical boundaries include the water-table boundary, base of the aquifer, and northwest mountain-front boundary. Artificial boundaries include the northeast boundary, southeast-flowline boundary, and southwest boundary. Water flows into the model area as (1) underflow (1,225 cubic feet per second (ft3/s)) from the regional aquifer (northeast boundary-constant and nonuniform), (2) underflow (695 ft3/s) from the tributary valleys and mountain fronts (northwest boundary-constant and nonuniform), (3) precipitation recharge (70 ft3/s) (constant and uniform), streamflow-infiltration recharge (95 ft3/s) (variable and nonuniform), wastewater return flows (6 ft3/s) (variable and nonuniform), and irrigation-infiltration recharge (24 ft3/s) (variable and nonuniform) across the water table (water-table boundary-variable and nonuniform), and (4) upward flow across the base of the aquifer (44 ft3/s) (uniform and constant). The southeast-flowline boundary is represented as a no-flow boundary. Water flows out of the model area as underflow (2,037 ft3/s) to the regional aquifer (southwest boundary-variable and nonuniform) and as ground-water withdrawals (45 ft3/s) (water table boundary-variable and nonuniform). Ground-water flow i

Scientific Investigations Report

Geology and water resources of Portage County, Wisconsin

Portage County has abundant resources of generally good quality water and, although water problems exist locally, depletion or general scarcity of water is not likely in the foreseeable future. The county receives annually about 31 inches of precipitation, of which about 21 inches is lost as evaportranspiration. The average annual water yield is about 10.6 inches and consists of about 10.3 inches of runoff to streams, about 0.2 inch of water which leaves the county as underflow, and about 0.1 inch of water which is used consumptively. The surface-water resources include 104 lakes, about 110 miles of streams that discharge about 600 cfs (cubic feet per second) to the Wisconsin, Waupaca, and Little Wolf Rivers, and the Wisconsin River which has an average flow of about 2.400 cfs. Extensive deposits of outwash sand and gravel, sandy till, and alluvium release annually about 460 cfs of ground water to the streams. The principal source of ground water is thick deposits of glacial drift that occur over all but the northwestern part of the county. Although as much as 100 feet of sandstone underlies the drift in the southern part, it is not an important aquifer. Impermeable crystalline rocks of Precambrian age underlie all the aquifers and limit the downward movement of water. The county has been divided into areas having similar geologic and hydrologic conditions. These areas are here named the "sand-plain province," the "drift province," and the "drift-crystalline-rock province." The sand-plain province and the eastern part of the drift province have the greatest potential for development of large ground-water supplies. Wells yielding 1,000 to 2,000 gpm (gallons per minute) can be developed in the sand-plain province and wells yielding about 500 gpm can be developed in the drift province. Nearly all the communities in the county have water resources adequate for future expansion. An exception to this is Junction City where only a limited supply of poor quality water is readily available. Additional supplies can be developed from ground water in the Mill Creek area or from the Wisconsin River. In the sand-plain and drift provinces, ground-water runoff is about 9 inches a year and surface runoff is about 1 inch a year and of short duration. In the drift-crystalline-rock province, however, ground-water runoff is about 2 inches a year and surface runoff is about 8 inches a year and varies greatly in rate of flow. Surface and ground water are closely interrelated throughout the county and constitute a single resource. Streams, lakes, and marshes are the visible part of the ground-water surface and ground water moves slowly and continuously toward these surface points of discharge. Pumping for irrigation has temporarily lowered water levels in the vicinity of wells but has not lowered regional water levels. Pumpage has intercepted and utilized some of the recharge that would have been rapidly discharged from the aquifer, but it has not materially depleted the flow of streams. The 1955-59 decline in water levels and lake stages is attributed to a deficiency in precipitation and not to the increased pumpage from irrigation wells. To prevent excessive declines in water levels, high-capacity wells should be adequately spaced about 2,500 feet between wells pumping 1,000 gpm for 90 days. In the Stevens Point area, heavy pumping of wells near the Plover River induces recharge to ground water and thus reduces local declines in the water level. The chemical quality of ground water is generally good, but, locally, hard water and undesirable amounts of iron require treatment.

Wisconsin

Geology and ground-water resources of Laramie County, Wyoming

Laramie County, an area of 2,709 square miles, is in the southeast corner of Wyoming. Rocks exposed there range in age from Precambrian to Recent. The most extensive aquifers in the county are the White River Formation of Oligocene age, which is as much as 500 feet thick and consists predominantly of siltstone ; the Arikaree Formation of Miocene age, which consists of as much as 450 feet of very fine grained to fine-grained sandstone; and the Ogallala Formation of Miocene and Pliocene age, which consists ,of as much as 330 feet of gravel, sand, silt, and some cobbles and boulders. These formations are capable of yielding large ,supplies of water locally. Terrace deposits of Quaternary age yield moderate .to large supplies of water in the southeastern and northeastern parts of the county. In the Federal well field, large yields of water from the White River Formation are obtained from gravel lenses. In the eastern part of the county near Pine Bluffs, large yields are obtained from openings in .the siltstone of the White River. Previous investigators reported that the large yields were obtained in areas where the formation is fractured and fissured. The authors of this report believe that .the large yields from siltstone in the White River Formation are from pipes, sometimes called natural tunnels, rather than from fractures ,or fissures. Little is known about the water-bearing properties of the pro-Tertiary aquifers in the county, but water derived from the pro-Tertiary formations would probably be of poor quality, except in the vicinity of the outcrop near the western edge of the county. Precipitation is the principal source of recharge to the ground-water reservoirs. About 5 percent of the annual precipitation, or about 108,400 acre-feet per year, is estimated to be recharged. Only a small amount of additional recharge is from streams. The general movement of ground water is eastward, and the average gradient of the water table is about 40 feet per mile. The total amount ,of ground water pumped from wells in Laramie County during 1964 is estimated to be 28,000 acre-feet; about 6,000 acre-feet was used for municipal and industrial supplies, about 17,000 acre-feet was used for irrigation in the Pine Bluffs-Carpenter area, and about 5,000 acre-feet was used for other purposes. The balance of the recharge (80,400 acre-feet) is estimated to be discharged by the following means: 20 percent by underflow, 20 percent by streamflow, and 60 percent by evapotranspiration. The coefficient of transmissibility of the Ogallala Formation, determined by averaging data from 28 pumping tests made in the Cheyenne municipal well field, is about 16,000 gallons per day per foot. However, this figure is an average of the more permeable zones, and the average coefficient of transmissibility of the Ogallala in the county is probably much less because of the heterogeneous character of the formation. A coefficient of transmissibility of 3,800 gallons per day per foot was calculated for the Ogallala, in the same vicinity that the pumping tests were made, by using a regional method of analysis. Although the average transmissibility of the Ogallala is considered to be low, large yields are obtained from gravel stringers and lenses in the formation. The maximum perennial yield from the Cheyenne well field is estimated to be about 1.6 billion gallons per year. Moderate to large yields of water can be obtained in the north-central part of the county where the saturated thickness of the Arikaree Formation, or combined Arikaree and Ogallala Formations, is 200 feet or more. Ground water has been developed throughout the county, but development has been intensive only in the Cheyenne municipal well fields near Cheyenne and Federal and in the Pine Bluffs lowland. The water level has been lowered as much as 40 feet in the Cheyenne well field and somewhat less in the Federal well field.

Wyoming

Geology, water-quality, hydrology, and geomechanics of the Cuyama Valley groundwater basin, California, 2008--12

To assess the water resources of the Cuyama Valley groundwater basin in Santa Barbara County, California, a series of cooperative studies were undertaken by the U.S. Geological Survey and the Santa Barbara County Water Agency. Between 2008 and 2012, geologic, water-quality, hydrologic and geomechanical data were collected from selected sites throughout the Cuyama Valley groundwater basin. Geologic data were collected from three multiple-well groundwater monitoring sites and included lithologic descriptions of the drill cuttings, borehole geophysical logs, temperature logs, as well as bulk density and sonic velocity measurements of whole-core samples. Generalized lithologic characterization from the monitoring sites indicated the water-bearing units in the subsurface consist of unconsolidated to partly consolidated sand, gravel, silt, clay, and occasional cobbles within alluvial fan and stream deposits. Analysis of geophysical logs indicated alternating layers of finer- and coarser-grained material that range from less than 1 foot to more than 20 feet thick. On the basis of the geologic data collected, the principal water-bearing units beneath the monitoring-well sites were found to be composed of younger alluvium of Holocene age, older alluvium of Pleistocene age, and the Tertiary-Quaternary Morales Formation. At all three sites, the contact between the recent fill and younger alluvium is approximately 20 feet below land surface. Water-quality samples were collected from 12 monitoring wells, 27 domestic and supply wells, 2 springs, and 4 surface-water sites and were analyzed for a variety of constituents that differed by site, but, in general, included trace elements; nutrients; dissolved organic carbon; major and minor ions; silica; total dissolved solids; alkalinity; total arsenic and iron; arsenic, chromium, and iron species; and isotopic tracers, including the stable isotopes of hydrogen and oxygen, activities of tritium, and carbon-14 abundance. Of the 39 wells sampled, concentrations of total dissolved solids and sulfate from 38 and 37 well samples, respectively, were greater than the U.S. Environmental Protection Agency’s secondary maximum contaminant levels. Concentrations greater than the maximum contaminant levels for nitrate were observed in five wells and were observed for arsenic in four wells. Differences in the stable-isotopic values of hydrogen and oxygen among groundwater samples indicated that water does not move freely between different formations or between different zones within the Cuyama Valley. Variations in isotopic composition indicated that recharge is derived from several different sources. The age of the groundwater, expressed as time since recharge, was between 600 and 38,000 years before present. Detectable concentrations of tritium indicated that younger water, recharged since the early 1950s, is present in parts of the groundwater basin. Hydrologic data were collected from 12 monitoring wells, 56 domestic and supply wells, 3 surface-water sites, and 4 rainfall-gaging stations. Rainfall in the valley averaged about 8 inches annually, whereas the mountains to the south received between 12 and 19 inches. Stream discharge records showed seasonal variability in surface-water flows ranging from no-flow to over 1,500 cubic feet per second. During periods when inflow to the valley exceeds outflow, there is potential recharge from stream losses to the groundwater system Water-level records included manual quarterly depth-to-water measurements collected from 68 wells, time-series data collected from 20 of those wells, and historic water levels from 16 wells. Hydrographs of the manual measurements showed declining water levels in 16 wells, mostly in the South-Main zone, and rising water levels in 14 wells, mostly in the Southern Ventucopa Uplands. Time-series hydrographs showed daily, seasonal, and longer-term effects associated with local pumping. Water-level data from the multiple-well monitoring sites indicated seasonal fluctuations as great as 80 feet and water-level differences between aquifers as great as 40 feet during peak pumping season. Hydrographs from the multiple-well groundwater monitoring sites showed vertical hydraulic gradients were upward during the winter months and downward during the irrigation season. Historic hydrographs showed water-level declines in the Southern-Main, Western Basin, Caliente Northern-Main, and Southern Sierra Madre zone ranging from 1 to 7 feet per year. Hydrographs of wells in the Southern Ventucopa Uplands zone showed several years with marked increases in water levels that corresponded to increased precipitation in the Cuyama Valley. Investigation of hydraulic properties included hydraulic conductivity and transmissivity estimated from aquifer tests performed on 63 wells. Estimates of horizontal hydraulic conductivity ranged from about 1.5 to 28 feet per day and decreased with depth. The median estimated hydraulic conductivity for the older alluvium was about five times that estimated for the Morales Formation. Estimates of transmissivity ranged from 560 to 163,400 gallons per day per foot and decreased with depth. The median estimated transmissivity for the younger alluvium was about three times that estimated for the older alluvium. Geomechanical analysis included land-surface elevation changes at five continuously operating global positioning systems (GPS) and land-subsidence detection at five interferometric synthetic aperture radar (InSAR) reference points. Analysis of data collected from continuously operating GPS stations showed the mountains to the south and west moved upward about 1 millimeter (mm) annually, whereas the station in the center of the Southern-Main zone moved downward more than 7 mm annually, indicating subsidence. It is likely that this subsidence is inelastic (permanent) deformation and indicates reduced storage capacity in the aquifer sediments. Analysis of InSAR data showed local and regional changes that appeared to be dependent, in part, on the time span of the interferogram, seasonal variations in pumping, and tectonic uplift. Long-term InSAR time series showed a total maximum detected subsidence rate of approximately 12 mm per year at one location and approximately 8 mm per year at a second location, while short-term InSAR time series showed maximum subsidence of about 15 mm at one location and localized maximum uplift of about 10 mm at another location.

California

Groundwater and surface-water resources in the Bureau of Land Management Moab Master Leasing Plan area and adjacent areas, Grand and San Juan Counties, Utah, and Mesa and Montrose Counties, Colorado

The Bureau of Land Management (BLM) Canyon Country District Office is preparing a leasing plan known as the Moab Master Leasing Plan (Moab MLP) for oil, gas, and potash mineral rights in an area encompassing 946,469 acres in southeastern Utah. The BLM has identified water resources as being potentially affected by oil, gas, and potash development and has requested that the U.S. Geological Survey prepare a summary of existing water-resources information for the Moab MLP area. This report includes a summary and synthesis of previous and ongoing investigations conducted in the Moab MLP and adjacent areas in Utah and Colorado from the early 1930s through the late 2000s. Eight principal aquifers and six confining units were identified within the study area. Permeability is a function of both the primary permeability from interstitial pore connectivity and secondary permeability created by karst features or faults and fractures. Vertical hydraulic connection generally is restricted to strongly folded and fractured zones, which are concentrated along steeply dipping monoclines and in narrow regions encompassing igneous and salt intrusive masses. Several studies have identified both an upper and lower aquifer system separated by the Pennsylvanian age Paradox Member of the Hermosa Formation evaporite, which is considered a confining unit and is present throughout large parts of the study area. Surface-water resources of the study area are dominated by the Colorado River. Several perennial and ephemeral or intermittent tributaries join the Colorado River as it flows from northeast to southwest across the study area. An annual spring snowmelt and runoff event dominates the hydrology of streams draining mountainous parts of the study area, and most perennial streams in the study area are snowmelt-dominated. A bimodal distribution is observed in hydrographs from some sites with a late-spring snowmelt-runoff peak followed by smaller peaks of shorter duration during the late summer. The large regional streams (Colorado, Green, and Dolores Rivers) integrate the regional hydrologic partitioning of a very large contributing area and, therefore, the hydrographs for these streams are much more smooth and consistent. Several streams throughout the study area are considered impaired and do not meet the standards set by the Environmental Protection Agency for specific designated-use classifications. Limited data are available to quantitatively estimate the large-scale regional groundwater budget for the study area. Previous studies have estimated groundwater budgets for areas in and adjacent to the current study area, namely Moab-Spanish Valley and parts of the Paradox Basin. Most groundwater recharge to the study area originates as infiltration of precipitation from upland areas and is further enhanced in areas covered with sandy soils or in areas where the bedrock is highly fractured. Additional groundwater recharge occurs as seepage from streams and irrigation water, and as subsurface inflow, both vertically between aquifers and as lateral movement into the study area. Groundwater discharge occurs as seepage to streams, evapotranspiration, to springs and seeps, well withdrawals; and as subsurface outflow, both vertically between aquifers and as lateral movement out of the study area across its defined boundaries. Groundwater use in the study area was determined using data from the Utah Division of Water Rights. Most wells in the study area are categorized as having multiple uses. Mean specific-conductance values for groundwater from wells and springs in the study area range from 101 to 220,000 microsiemens per centimeter at 25° C (μS/cm); most of the wells or springs have mean specific-conductance values of less than or equal to 1,000 μS/cm. Previously reported total dissolved-solids concentrations, specific conductances, and other groundwater-quality data for each of the principal aquifers indicate relative freshwater throughout the study area, except within the lower aquifer system and areas in contact with the Paradox Member of the Hermosa Formation evaporites. There is limited information on the resource availability of brines and saline groundwater in the study area. Total dissolved-solids concentrations typically are high (greater than 35,000 milligrams per liter) in groundwater from, or in contact with, the Paradox Member of the Hermosa Formation. Total dissolved-solids concentrations also are high in groundwater samples collected from the lower aquifer system. Because the Paradox Member of the Hermosa Formation is considered a barrier to vertical groundwater flow, most of the brine and saline groundwater resources are restricted to the lower aquifer system.

Colorado, Utah

Ground-water resources of Griggs and Steele Counties, North Dakota

Griggs and Steele Counties, in east-central North Dakota, are underlain by bedrock of Ordovician, Jurassic, and Cretaceous ages. The Fall River and Lakota Formations of Cretaceous age form the Dakota aquifer. The fractured upper part of the Pierre Formation (shale), also of Cretaceous age, forms another bedrock aquifer. The Dakota aquifer, which consists mainly of interbedded shale and sandstone units, may yield as much as 500 gallons per minute (32 liters per second) of sodium sulfate water to wells at selected locations. The Pierre aquifer yields from 1 to 10 gallons per minute (0.06 to 0.63 liters per second) of sodium bicarbonate or sodium sulfate water to wells. Four major glacial-drift aquifers are present in the study area. The Spiritwood aquifer system may supply as much as 1,500 gallons per minute (95 liters per second) of water to wells. Water samples contained dissolved-solids concentrations ranging from 244 to 9,800 milligrams per liter. The Galesburg aquifer will yield as much as 1,000 gallons per minute (63 liters per second) of water to wells. Water samples contained dissolved-solids concentrations ranging from 317 to 2,170 milligrams per liter. The McVille aquifer will yield as much as 500 gallons per minute (32 liters per second) to wells. Water samples contained dissolved-solids concentrations ranging from 449 to 2,200 milligrams per liter. The Elk Valley aquifer could yield 30 gallons per minute (2 liters per second) to wells. Water samples contained dissolved-solids concentrations ranging from 397 to 2,890 milligrams per liter. Six communities in the project area use ground-water supplies. Rural water districts are being developed in the two-county area that will provide dependable ground-water supplies for many farms and small municipalities. The Spiritwood aquifer system and the McVille and Galesburg aquifers are capable of supplying the water needs of these districts and could also provide water for irrigation.

North Dakota

Geohydrology and simulated response to ground-water pumpage in Carson Valley, a river-dominated basin in Douglas County, Nevada, and Alpine County, California

A numerical model was used to simulate the effect of development of the groundwater reservoir in Carson Valley on Carson River outflow, evapotranspiration, and groundwater levels and storage. The basin-fill groundwater reservoir consists of: (1) confined and unconfined sedimentary deposits of Quaternary age that underlie the valley floor, and (2) sedimentary deposits of Tertiary age that are exposed mainly on the east side of the valley. Water levels indicate the presence of two confined aquifer systems: one < 100 ft deep, and the other, generally deeper than 200 ft. The basin-fill reservoir is surrounded by bedrock that transmits recharge to the basin through weathered and fractured zones near the contact between bedrock and valley fill. Estimates were made of the distribution of hydraulic properties of aquifer materials, and of the components of inflow to and outflow from the basin-fill reservoir. Inflow components consisted of the following approximate quantities, in acre-ft/yr: (1) mainstem Carson River flow, 360,000; (2) direct precipitation, 70,000; (3) runoff from perennial and ephemeral streams, 24,000: and (4) subsurface inflow, 38,000. Approximate estimates of outflow components were, in acre-ft/yr; (1) mainstem Carson River flow, 291,000; (2) potential evapotranspiration, 200,000. Both inflow and outflow totaled about 490,000 acre-ft/yr. These flow volumes show that the hydrologic regimen of the basin is dominated by surface water flow of the Carson River. Steady-state and transient calibration of the model provided an unacceptable fit of observed versus simulated groundwater level fluctuations and storage, and surface water outflow from the valley. These values provide a reasonable balance for the simulated steady-state water budget. Simulations show that surface water flow is the ultimate source of about 75% of pumped water for six scenarios of possible future ground-water development. Model simulations indicate that changes from agricultural to urban land uses could decrease the loss of Carson River outflow to pumpage when streamflow is not used for flood irrigation in that area.

California, Nevada

Ground-water resources of the Wind River Indian Reservation, Wyoming

The area of this investigation is in the western part of the Wind River Basin and includes parts of the Absaroka, Washakie, Wind River, and Owl Creek Mountains. The purposes of the study were to determine the general hydrologic properties of the rocks in the area and the occurrence and quality c f the water in them. Structurally, the area is a downfolded basin surrounded by upfolded mountain ranges. Igneous and metamorphic rocks of Precambrian age are exposed in the mountains: folded sedimentary rocks representing all geologic periods, except the Silurian, crop out along the margins of the basin; and relatively flat-lying Tertiary rocks are at the surface in the central part of the basin. Surficial sand and gravel deposits of Quaternary age occur along streams and underlie numerous terraces throughout the basin. The potential yield and quality of water from most rocks in the area are poorly known, but estimates are possible, based on local well data and on data concerning similar rocks in nearby areas. Yields of more than 1,000 gpm are possible from the rocks comprising the Bighorn Dolomite (Ordovician), Darby Formation (Devonian), Madison Limestone (Mississippian), and Tensleep Sandstone (Pennsylvanian). Total dissolved solids in the water range from about 300 to 3,000 ppm. Yields of as much as several hundred gallons per minute are possible from the Nugget Sandstone (Jurassic? and Triassic?). Yields of 20 gpm or more are possible from the Crow Mountain Sandstone (Triassic) and Sundance Formation (Jurassic). Dissolved solids are generally high but are less than 1,000 ppm near outcrops in some locations. The Cloverly and Morrison (Cretaceous and Jurassic), Mesaverde (Cretaceous) and Lance(?) (Cretaceous) Formations may yield as much as several hundred gallons per minute, but most wells in Cretaceous rocks yield less than 20 gpm. Dissolved solids generally range from 1,000 to 5,000 ppm but may be higher. In some areas, water with less than 1,000 ppm dissolved solids may be available from the Cloverly and Morrison Formations. Tertiary rocks yield a few to several hundred gallons per minute and dissolved solids generally range from 1,000 to 5,000 ppm. Wells in the Wind River Formation (Eocene) yield about 1.-500 gpm of water having dissolved solids of about 200-5,000 ppm. Yields of a few to several hundred gallons per minute are available from alluvium (Quaternary). Dissolved solids range from about 200 to 5,000 ppm. Many parts of the Wind River Irrigation Project have become waterlogged. The relation of drainage problems to geology and the character and thickness of rocks in the irrigated areas are partly defined by sections drawn on the basis of test drilling. The drainage-problem areas are classified according to geologic similarities into five general groups: flood plains, terraces, underfit-stream valleys, slopes, and transitional areas. Drainage can be improved by open drains, buried drains, relief wells, and pumped wells or by pumping from sumps or drains. The methods that will be most successful depend on the local geologic and hydrologic conditions. In several areas, the most effective means of relieving the drainage problem would be to reduce the amount of infiltration of water by lining canals and ditches and by reducing irrigation water applications to the optimum. Water from underground storage in alluvium could supplement water from surface storage in some areas. A few thousand acre-feet of water per square mile are in storage in some of the alluvium. The use of both surface and underground storage would reduce the need for additional surface-storage facilities and also would alleviate drainage problems in the irrigated areas.

Water Supply Paper

Ground-water resources of southern New Castle County, Delaware

Southern New Castle County has a land area of 190 square miles in northcentral Delaware. It is predominantly a rural area with a population of about 9,500 people who are engaged chiefly in agriculture. By and large, the residents are dependent upon ground water as a source of potable water. This investigation was made to provide knowledge of the availability and quality of .the ground-water supply to aid future development. The climate, surface features, and geology of the area are favorable for the occurrence of ground water. Temperatures are generally mild and precipitation is normally abundant and fairly evenly distributed throughout the year. The topography of the area is relatively fiat and, hence, the streams have low gradients. The surface is underlain to a considerable depth by highly permeable unconsolidated sediments that range in age from Early Cretaceous to Recent. Nearly all the subsurface stratigraphic units yield some water to wells, but only four parts or combinations of these units are sufficiently permeable, to yield large supplies. These are, from oldest to youngest, the nonmarine Cretaceous sediments and the Magothy Formation, the Monmouth Group, the Rancocas Formation, and .the surficial terrace and valley-fill deposits. In the northern part of the area the nonmarine Cretaceous sediments and the Magothy Formation can be reached economically by wells. Yields in excess of 300 gpm (gallons per minute) have been obtained from wells screened in this aquifer, but the maximum productivity of the aquifer has not been .tested. The Monmouth Group is used as a source of water in the central part of the area, where some wells yield as much as 125 gpm. The Rancocas Formation is the principal aquifer in the southern part of the area. Yields of 200-400 gpm can be expected from this aquifer, owing to its uniformly coarse texture, particularly in the upper part of the formation. The terrace deposits compose the shallow watertable aquifer throughout the area. In places the water-table aquifer is connected hydraulically to each of .the other three aquifers. The yields of wells tapping this aquifer are generally small, because the saturated thickness of the aquifer is small. The aquifer does provide a convenient and economical source of water for domestic supplies, .and the quality o# the available water supply is generally satisfactory for most purposes. The use of water in the area was estimated to be about 1.77 million gallons per day in 1959. Rural uses amounted to about 75 percent of the total, and municipal and industrial uses accounted for .the remainder. Water for irrigation of crops constituted about half of the water pumped for rural use. The total use of ground water in the area is a mere fraction of the supply available. Each of the four major aquifers is capable of vastly increased production. Future development, however, will be .limited by the changes in the quality of the water resulting from the future pumping regime-and the expanded pattern of development. Salt-water encroachment will become a problem in the eastern part of the area if steps are not taken to avoid it.

Water Supply Paper

Preliminary results of hydrogeologic investigations in the valley of the Humboldt River near Winnemucca, Nevada

Most of the ground water of economic importance and nearly all the ground water closely associated with the flow o# the Humboldt River in the. 40-mile reach near Winnemucca, Nev., are in unconsolidated sedimentary deposits. These deposits range in age from Pliocene to Recent and range in character from coarse poorly sorted fanglomerate to lacustrine strata of clay, silt, sand, and gravel. The most permeable deposit consists of sand and gravel of Lake Lahontan age--the so-called medial gravel unit--which is underlain and overlain by fairly impermeable silt and clay also of Lake Lahontan age. The ultimate source of nearly all the water in the study area is precpitation within the drainage basin of the Humboldt River. Much of this water reaches the study, area as flow or underflow of the Humboldt River and as underflow from other valleys tributary to the study area. Little if any flow from the tributary streams in the study area usually reaches the Humboldt River. Most of the tributary streamflow within the study area evaporates or is transpired by vegetation, but a part percolates downward through unconsolidated deposits of the alluvial fans flanking the mountains and move downgradient as ground-water underflow toward the Humboldt River. Areas that contribute significant amounts of ground-water underflow to. the valley of the Humboldt River within the study area are (1) the valley of the Humboldt River upstream from the study area, (2) the Pole Creek-Rock Creek area, (3) Paradise Valley, and (4) Grass Valley and the northwestern slope of the Sonoma Range. The total average underflow from these areas in the period 1949-61 was about 14,000-19,000 acre-feet per year. Much of this underflow discharged into the Humboldt River within the study area and constituted a large part of the base flow of the river. Streamflow in the Humboldt River increases substantially in the early spring, principally because of runoff to the river in the reaches upstream from the study area. The resulting increase of the stage of the river causes the river to lose large amounts of water by infiltration to the ground-water reservoir in the study area. In addition, there is much recharge to the ground-water reservoir in the spring and early summer as a result of seepage losses from irrigation ditches and the downward percolation of some of the excess water applied for irrigation. The average net increase of ground water in storage in the deposits beneath and adjacent to the flood plain of the Humboldt River during the spring and early summer is about 10,000 acre-feet.

Nevada

Ground-water conditions and geologic reconnaissance of the Upper Sevier River basin, Utah

The upper Sevier River basin is in south-central Utah and includes an area of about 2,400 .square miles of high plateaus and valleys. It comprises the entire Sevier River drainage basin above Kingston, including the East Fork Sevier River and its tributaries. The basin was investigated to determine general ground-water conditions, the interrelation of ground water and surface water, the effects of increasing the pumping of ground water, and the amount of ground water in storage. The basin includes four main valleys - Panguitch Valley, Circle Valley, East Fork Valley, and Grass Valley - which are drained by the Sevier River, the East Fork Sevier River, and Otter Creek. The plateaus surrounding the valleys consist of sedimentary and igneous rocks that range in age from Triassic to Quaternary. The valley fill, which is predominantly alluvial gravel, sand, silt, and clay, has a maximum thickness of more than 800 feet. The four main valleys constitute separate ground-water basins. East Fork Valley basin is divided into Emery Valley, Johns Valley, and Antimony subbasins, and Grass Valley basin is divided into Koosharem and Angle subbasins. Ground water occurs under both artesian and water-table conditions in all the basins and subbasins except Johns Valley, Emery Valley, and Angle subbasins, where water is only under water-table conditions. The water is under artesian pressure in beds of gravel and sand confined by overlying beds of silt and clay in the downstream parts of Panguitch Valley basin, Circle Valley basin, and Antimony subbasin, and in most of Koosharem subbasin. Along the sides and upstream ends of these basins, water is usually under water-table conditions. About 1 million acre-feet of ground water that is readily available to wells is stored in the gravel and sand of the upper 200 feet of saturated valley fill. About 570,000 acre-feet is stored in Panguitch Valley basin, about 210,000 in Circle Valley basin, about 6,000 in Emery Valley subbasin, about 90,000 in Johns Valley subbasin, about 36,000 in Antimony subbasin, about 90,000 in Koosharem subbasin, and about 60,000 in Angle subbasin. Additional water, although it is not readily available to wells, is stored in beds of silt and clay. Some ground water also is available in the bedrock underlying and surrounding the basins, although the bedrock formations generally are poor aquifers. The principal source of recharge to the valley fill in the upper Sevier River basin is infiltration from streams, canals, and irrigated fields. Some ground water also miles into the valley till from the bedrock surrounding the basins. The basin contains about 300 wells, most of which are less than 4 inches in diameter, are less than 250 feet deep, and are used for domestic purposes and stock watering. More than half the wells are flowing wells in Koosharem subbasin. Approximately 82,000 acre-feet of ground water was discharged in 1962 from the valley till. Springs discharged about 33,000 acre-feet, wells about 3,000, and drains about 3,000; and evapotranspiration from phreatophyte areas about 43,000 acre-feet. Springs in bedrock discharged an additional 75,000 acre-feet. Most of the water discharged by springs, wells, and drains was used for irrigation. The ground water in the basin generally is of good chemical quality. The water is excellent for irrigation and stock but is not as desirable for most domestic and industrial uses because of its hardness. The dissolved-solids content of the ground water generally increases slightly from the upstream end of the individual ground-water basins to. the downstream end owing mostly to repeated use of the water for irrigation. Surface water and ground water in the upper Sevier River basin are inter- connected, and the base flows of streams are affected by changes in ground- water levels. Increased pumping of ground water would result in (1) an increase in the recharge to the aquifers from surface-water sources or (2) a decrease in the discharge from streams, springs, flowing wells, and areas of phreatophytes or (3) a combination of these. About 43,000 acre-feet of ground water is now discharged annually by evapotranspiration from phreatophyte areas, and perhaps one-third of this loss, or about 14,000 acre-feet, could be salvaged by eliminating wet areas and phreatophytes. The areas where water could be salvaged are at the downstream ends of Panguitch Valley basin, Circle Valley basin, and Antimony subbasin. Most of the 14,000 acre-feet 'of water could be pumped from large-diameter wells or developed by properly designed drains without greatly affecting stream- flow and with only moderate effect on 'spring discharge. If the wells were properly located, the pumping would lower water levels and dry up wet areas where phreatophytes grow. Conjunctive use of ground water and surface water would facilitate the more efficient use of all water resources in the basin

Utah

Hydrogeologic and geochemical characterization of groundwater resources in Deep Creek Valley and adjacent areas, Juab and Tooele Counties, Utah, and Elko and White Pine Counties, Nevada

The water resources of Deep Creek Valley were assessed during 2012&ndash;13 with an emphasis on better understanding the groundwater flow system and groundwater budget. Surface-water resources are limited in Deep Creek Valley and are generally used for agriculture. Groundwater is the predominant water source for most other uses and to supplement irrigation. Most groundwater withdrawal in Deep Creek Valley occurs from the unconsolidated basin-fill deposits, in which conditions are generally unconfined near the mountain front and confined in the lower-altitude parts of the valley. Productive aquifers are also present in fractured bedrock that occurs along the valley margins and beneath the basin-fill deposits. The consolidated-rock and basin-fill aquifers are hydraulically connected in many areas with much of the recharge occurring in the consolidated-rock mountain blocks and most of the discharge occurring from the lower-altitude basin-fill deposits. Average annual recharge to the Deep Creek Valley hydrographic area was estimated to be between 19,000 and 29,000 acre-feet. Groundwater recharge occurs mostly from the infiltration of precipitation and snowmelt at high altitudes. Additional, but limited recharge occurs from the infiltration of runoff from precipitation near the mountain front, infiltration along stream channels, and possible subsurface inflow from adjacent hydrographic areas. Groundwater moves from areas of recharge to springs and streams in the mountains, and to evapotranspiration areas, springs, streams, and wells in the basins. Discharge may also occur as subsurface groundwater outflow to adjacent hydrographic areas. Average annual discharge from the Deep Creek Valley hydrographic area was estimated to be between 21,000 and 22,000 acre-feet, with the largest portion of discharge occurring as evapotranspiration. Groundwater samples were collected from 10 sites for geochemical analysis. Dissolved-solids concentrations ranged from 126 to 475 milligrams per liter, and none of the sites sampled during this study had dissolved-solids concentrations that exceeded the Environmental Protection Agency secondary standard for drinking water of 500 milligrams per liter. Tritium concentrations from 1.6 to 10.1 tritium units at 3 of the 10 sample sites indicate the presence of modern (less than 60 years old) groundwater, and apparent tritium/helium-3 ages calculated for these sites ranged from 7 to 29 years. The other seven sample sites had tritium concentrations less than or equal to 0.4 tritium units and are assumed to be pre-modern. Adjusted minimum radiocarbon ages of these seven pre-modern water samples ranged from 1,000 to 8,000 years with the ages of at least four of the samples being more than 3,000 years. Noble-gas recharge temperatures indicate that groundwater sampled along the valley axis recharged at both mountain and valley altitudes, providing evidence for both mountain-block and mountain-front recharge. Water-level altitude contours and groundwater ages indicate the potential for a long flow path from southwest to northeast between northern Spring and Deep Creek Valleys through Tippett Valley. Although information gathered during this study is insufficient to conclude whether or not groundwater travels along this interbasin flow path, dissolved sulfate and chloride data indicate that a small fraction of the lower altitude, northern Deep Creek Valley discharge may be sourced from these areas. Despite the uncertainty due to limited data collection points, a hydraulic connection between northern Spring Valley, Tippett Valley, and Deep Creek Valley appears likely, and potential regional effects resulting from future groundwater withdrawals in northern Spring Valley warrant ongoing monitoring of groundwater levels across this area.

Nevada, Utah

Distribution and variability of redox zones controlling spatial variability of arsenic in the Mississippi River Valley alluvial aquifer, southeastern Arkansas

Twenty one of 118 irrigation water wells in the shallow (25-30??m thick) Mississippi River Valley alluvial aquifer in the Bayou Bartholomew watershed, southeastern Arkansas had arsenic (As) concentrations (< 0.5 to 77????g/L) exceeding 10????g/L. Sediment and groundwater samples were collected and analyzed from the sites of the highest, median, and lowest concentrations of As in groundwater in the alluvial aquifers located at Jefferson County, Arkansas. A traditional five-step sequential extraction was performed to differentiate the exchangeable, carbonate, amorphous Fe and Mn oxide, organic, and hot HNO3-leachable fraction of As and other compounds in sediments. The Chao reagent (0.25??M hydroxylamine hydrochloride in 0.25??M HCl) removes amorphous Fe and Mn oxides and oxyhydroxides (present as coatings on grains and amorphous minerals) by reductive dissolution and is a measure of reducible Fe and Mn in sediments. The hot HNO3 extraction removes mostly crystalline metal oxides and all other labile forms of As. Significant total As (20%) is complexed with amorphous Fe and Mn oxides in sediments. Arsenic abundance is not significant in carbonates or organic matter. Significant (40-70????g/kg) exchangeable As is only present at shallow depth (0-1??m below ground surface). Arsenic is positively correlated to Fe extracted by Chao reagent (r = 0.83) and hot HNO3 (r = 0.85). Arsenic extracted by Chao reagent decreases significantly with depth as compared to As extracted by hot HNO3. Fe (II)/Fe (the ratio of Fe concentration in the extracts of Chao reagent and hot HNO3) is positively correlated (r = 0.76) to As extracted from Chao reagent. Although Fe (II)/Fe increases with depth, the relative abundance of reducible Fe decreases noticeably with depth. The amount of reducible Fe, as well as As complexed to amorphous Fe and Mn oxides and oxyhydroxides decreases with depth. Possible explanations for the decrease in reducible Fe and its complexed As with depth include historic flushing of As and Fe from hydrous ferric oxides (HFO) by microbially-mediated reductive dissolution and aging of HFO to crystalline phases. Hydrogeochemical data suggests that the groundwater in the area falls in the mildly reducing (suboxic) to relatively highly reducing (anoxic) zone, and points to reductive dissolution of HFO as the dominant As release mechanism. Spatial variability of gypsum solubility and simultaneous SO42- reduction with co-precipitation of As and sulfide is an important limiting process controlling the concentration of As in groundwater in the area. ?? 2008 Elsevier B.V. All rights reserved.

Journal of Contaminant Hydrology

Simulation of Ground-Water Flow in the Middle Rio Grande Basin Between Cochiti and San Acacia, New Mexico

This report describes a three-dimensional, finite difference, ground-water-flow model of the Santa Fe Group aquifer system within the Middle Rio Grande Basin between Cochiti and San Acacia, New Mexico. The aquifer system is composed of the Santa Fe Group of middle Tertiary to Quaternary age and post-Santa Fe Group valley and basin-fill deposits of Quaternary age. Population increases in the basin since the 1940's have caused dramatic increases in ground-water withdrawals from the aquifer system, resulting in large ground-water-level declines. Because the Rio Grande is hydraulically connected to the aquifer system, these ground-water withdrawals have also decreased flow in the Rio Grande. Concern about water resources in the basin led to the development of a research plan for the basin focused on the hydrologic interaction of ground water and surface water (McAda, D.P., 1996, Plan of study to quantify the hydrologic relation between the Rio Grande and the Santa Fe Group aquifer system near Albuquerque, central New Mexico: U.S. Geological Survey Water-Resources Investigations Report 96-4006, 58 p.). A multiyear research effort followed, funded and conducted by the U.S. Geological Survey and other agencies (Bartolino, J.R., and Cole, J.C., 2002, Ground-water resources of the Middle Rio Grande Basin, New Mexico: U.S. Geological Survey Circular 1222, 132 p.). The modeling work described in this report incorporates the results of much of this work and is the culmination of this multiyear study. The purpose of the model is (1) to integrate the components of the ground-water-flow system, including the hydrologic interaction between the surface-water systems in the basin, to better understand the geohydrology of the basin and (2) to provide a tool to help water managers plan for and administer the use of basin water resources. The aquifer system is represented by nine model layers extending from the water table to the pre-Santa Fe Group basement rocks, as much as 9,000 feet below the NGVD 29. The horizontal grid contains 156 rows and 80 columns, each spaced 3,281 feet (1 kilometer) apart. The model simulates predevelopment steady-state conditions and historical transient conditions from 1900 to March 2000 in 1 steady-state and 52 historical stress periods. Average annual conditions are simulated prior to 1990, and seasonal (winter and irrigation season) conditions are simulated from 1990 to March 2000. The model simulates mountain-front, tributary, and subsurface recharge; canal, irrigation, and septic-field seepage; and ground-water withdrawal as specified-flow boundaries. The model simulates the Rio Grande, riverside drains, Jemez River, Jemez Canyon Reservoir, Cochiti Lake, riparian evapotranspiration, and interior drains as head-dependent flow boundaries. Hydrologic properties representing the Santa Fe Group aquifer system in the ground-water-flow model are horizontal hydraulic conductivity, vertical hydraulic conductivity, specific storage, and specific yield. Variable horizontal anisotropy is applied to the model so that hydraulic conductivity in the north-south direction (along model columns) is greater than hydraulic conductivity in the east-west direction (along model rows) over much of the model. This pattern of horizontal anisotropy was simulated to reflect the generally north-south orientation of faulting over much of the modeled area. With variable horizontal anisotropy, horizontal hydraulic conductivities in the model range from 0.05 to 60 feet per day. Vertical hydraulic conductivity is specified in the model as a horizontal to vertical anisotropy ratio (calculated to be 150:1 in the model) multiplied by the horizontal hydraulic conductivity along rows. Specific storage was estimated to be 2 x 10-6 per foot in the model. Specific yield was estimated to be 0.2 (dimensionless). A ground-water-flow model is a tool that can integrate the complex interactions of hydrologic boundary conditions, aquifer materials

Water-Resources Investigations Report

Geology and ground water in Napa and Sonoma Valleys, Napa and Sonoma Counties, California

Napa and Sonoma Valleys are adjacent alluvium-filled valleys about 40 miles northeast of San Francisco. They occupy alined and structurally controlled depressions in the northern Coast Ranges physiographic province and drain south into San Pablo Bay. The valleys are surrounded and underlain by unconsolidated marine and continental sediments and volcanic rocks of Pliocene and Pleistocene age, which are water bearing in large part and together make up relatively extensive ground-water basins. Napa Valley, the eastern valley, is the larger and has a valley-floor area of about 85 square miles. Sonoma Valley has a valley-floor area of about 35 square miles; in addition, about 10 square miles is unreclaimed tidal marsh. The rock units of Napa and Sonoma Valleys are divided into four classes on the basis of their distribution and relative capacity to yield water: (a) Consolidated virtually non-water-bearing chiefly sedimentary (some metamorphic) rocks that range in age from Jurassic ( ?) to Pliocene; (b) marine shale and sand of the Petaluma formation (Pliocene) and the Merced formation (Pliocene and Pleistocene) that do not crop out within Napa or Sonoma Valleys but perhaps are penetrated by some deep wells drilled in Sonoma Valley; (c) Sonoma volcanics of Pliocene age, parts of which are non-water-bearing and parts of which locally yield large quantities of water; and (d) unconsolidated alluvial deposits mainly of Quaternary age. The deposits of classes (c) and (d) contain the most important aquifers in the area. Most of the water used in these valleys is pumped from wells in the younger and older alluvium in the Huichica and Glen Ellen formations. and in the Sonoma volcanics. The principal aquifers are the younger and older alluvium. but appreciable quantities of water are pumped locally from the Sonoma volcanics. The Huichica and Glen Ellen formations yield water in small quantities and at most places supply water only for limited domestic uses. The younger alluvium COIM3ists of interbedded deposits of unconsolidated gravel. sand, silt. and. locally, peat. These deposits underlie the flood plains and channels of the Napa River. Sonoma Creek, and their tributaries, low alluvial fans or plains graded to these streams. and the tidal marshlands. The older alluvium of Napa and Sonoma Valleys is composed of lenticular deposits of unconsolidated and poorly sorted clay, silt. sand. and gravel. Where exposed, claypan or hardpan soil is characteristically developed at the surface. The Huichica formation is composed of deformed continental beds consisting mostly of yellow silt with some interbedded lenses of silt and gravel, and silt and boulders. At the base are beds of redeposited volcanic material, silt, clay, and lenses of coarse gravel and boulders. The Glen Ellen fcrmation consists of alluvial clay, silt, sand, and gravel in clearly stratified but generally lenticular beds. The Sonoma volcanics constitute a thick and highly variate series of continental volcanic rocks, including andesite, basalt, and minor rhyolite flows and interbedded coarse- to fine-grained pyroclastic tuff and breccia, redeposited tuff and pumice, and diatomaceous mud, silt, and sand. A prominent body of rhyolite flows and tuff with some obsidian and perlitic glass, called the St. Helena rhyolite member, occurs in the upper part. Estimated ground-water pumpage for all uses in the year 1949-50 was about 5,600 acre-feet in Napa Valley and about 2,400 acre-feet in Sonoma Valley. Of this quantity the amounts pumped for irrigation were about 2,900 and 1,900 acre-feet, respectively. Water levels in wells in the central parts of the valleys range from a few feet above the land surface to about 50 feet below, with an average of about 25 feet. The quality of the water in most wells is satisfactory for domestic use and irrigation. Locally at the southern end of the valley some contamination of the native waters is caused by the movement of salty wate

Water Supply Paper

Reconnaissance of geology and ground water in the lower Grand River valley, South Dakota, with a section on Chemical quality of the ground water

The area described in this report is the flood plain of the Grand River and the bordering benchlands in Perkins and Corson Counties, S. Dak., from a point about 6 miles west of the town of Shadehill to the confluence of the Grand and Missouri Rivers near Mobridge. The exposed bedrock formations include the Pierre shale, the Fox Hills sandstone, and the Hell Creek formation of Late Cretaceous age, and-the Ludlow member of the Fort Union formation of Tertiary (Paleocene) age. Some stringers of the Cannonball formation probably interfinger with beds of the Ludlow member but none of the former was identified during the field investigations. The Pierre shale is exposed from the mouth of the Grand River to approximately the center of the area. Although a few wells in the area obtain water from this formation, it is not generally considered to be a source of supply. The Fox Hills sandstone, the Hell Creek formation, and the Ludlow member of the Fort Union formation are exposed successively upstream and, where saturated, yield small to moderate quantities of water to wells. Unconsolidated deposits of silt, sand, and gravel occur in several physiographic positions; they underlie the high benchland on both sides of the river, the poorly defined terraces along the river, and the flood plain throughout its entire length. Possibly all these unconsolidated deposits are water bearing; however, where the deposits on the benchland and in the terraces are dissected by streams, they probably contain little or no water. The average depth to ground water along the lower Grand River valley is about 17 feet. Probably, the flow of ground water in the bottom lands is nearly parallel to and slightly toward the surface stream. The measurements of the water level in observation wells for the period 1946-48 indicate that the fluctuations of the water table are small. The results of analyses of 13 samples of ground water from the alluvium and the Hell Creek formation show that the suitability of the ground water for use varies because of the considerable range in mineralization and composition. Dissolved solids ranged from 343 to 4,250 parts per million (ppm), hardness from 11 to 1,130 ppm, and percentage of sodium from 25 to 98. Concentrations of some of the individual constituents exceed standards of the United States Public Health Service. The water is moderately hard and contains undesirable amounts of iron and moderate to large amounts of dissolved solids. In general, the water quality ranges from excellent to unsuitable for irrigation use. The result of the mixing of the ground water with recharge water from Shadehill Reservoir cannot be predicted on the basis of available data. The geologic and hydrologic data in this report were obtained from earlier reports and from field observations during the period 1946-48. The report includes a geologic map and tabulated well records.

South Dakota

Chemical quality of the water in the Tucson basin, Arizona

The Tucson basin is a broad mountain-rimmed area of about 1,000 square miles in the Basin and Range physiographic province in southeastern Arizona. The altitude ranges from 2,000 feet in the basin to as much as 8,000 feat in the mountains. The major streams in the area are the Santa Cruz River and its principal tributaries--Cafiada del Oro, Rillito Creek, and Pantano Wash. The climate is semiarid, and the distribution and amount of precipitation vary greatly. The potential evapotranspiration is about four times the average annual precipitation. The streamflow is of excellent chemical quality, although most of the flow occurs during floods and generally has large concentrations of suspended sediment. Because of the erratic occurrence and quantity of streamflow and because of the lack of surface-water storage reservoirs, all the water for municipal, industrial, and agricultural uses is obtained from the many wells that tap the permeable sedimentary deposits, which constitute the principal aquifer in the Tucson basin. The aquifer consists of three sedimentary formations that range in age from middle Tertiary to Quaternary. The aquifer is as much as 2,000 feet thick and is composed mainly of sand, gravel, sandstone, and conglomerate. The upper part of the aquifer is more permeable than the lower part, and most wells obtain water at depths of less than 700 feet below the land surface. Most ground water contains less than 500 mg/l (milligrams per liter) of dissolved solids and is of suitable chemical quality for most uses. The water to depths of as much as 700 feet is a calcium sodium bicarbonate type, is hard to moderately hard, and contains less than 1.0 mg/l fluoride. Water at greater depth is a sodium bicarbonate type, is soft, and is of excellent chemical quality; however, water below about 1,0.00 feet may contain fluoride in excess of the maximum allowable limit of 1.4 mg/l for public supply. The ground water of poorest quality for public supply is at shallow depths along the major streams, in the Pantano Formation along the northeast margin of the basin, at depth in gypsiferous mudstone, and along a narrow zone that trends northwestward across the basin. Water from these hydrologic environ- may contain as much as 500 mg/1 dissolved solids an4 in places may contain more than 1,000 mg/1 dissolved solids. The anomalously large concentrations of calcium, bicarbonate, nitrate and sulfate in the ground water along the major streams, where the water table is from 25 to 150 feet below the land surface, are the result of near-surface phenomena. The large concentrations of these ions are derived from solution of relict salts, which were deposited in marshes along the streams prior to about 1900 by infiltrating surface water. In the narrow zone the trends northwestward across the basin, the large concentrations of calcium and sulfate are the result of the solution of limestone and gypsiferous mudstone in the sedimentary rocks in the headwaters area of Pantano Wash. The largest nitrate concentrations occur in the ground water along the Santa Cruz River; the nitrate probably is derived from irrigation return water, decayed vegetation from the marshes that occupied parts of the channel prior to 1900, and sewage effluent. Anomalously large concentrations of sodium, sulfate, chloride, and fluoride occur in ground water along the Santa Cruz River near the major faults that displace the older formations. These anomalously large concentrations probably are derived from the upward leakage of deep water that has reacted with the gypsiferous mudstone in the center of the basin and moved along the faults into the near-surface deposits. In the Tucson basin the water is divided into seven chemical types based on the relative amount of four major ions--calcium, sodium, bicarbonate, and sulfate---and the absolute amount of chloride. Most of the water is either a calcium sodium bicarbonate or a sodium bicarbonate type. Gr

Water Supply Paper