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At least 271 records · Page 15Linked to original sources
USGS2006

A graphical modeling tool for evaluating nitrogen loading to and nitrate transport in ground water in the mid-Snake region, south-central Idaho

A flow and transport model was created with a graphical user interface to simplify the evaluation of nitrogen loading and nitrate transport in the mid-Snake region in south-central Idaho. This model and interface package, the Snake River Nitrate Scenario Simulator, uses the U.S. Geological Survey's MODFLOW 2000 and MOC3D models. The interface, which is enabled for use with geographic information systems (GIS), was created using ESRI's royalty-free MapObjects LT software. The interface lets users view initial nitrogen-loading conditions (representing conditions as of 1998), alter the nitrogen loading within selected zones by specifying a multiplication factor and applying it to the initial condition, run the flow and transport model, and view a graphical representation of the modeling results. The flow and transport model of the Snake River Nitrate Scenario Simulator was created by rediscretizing and recalibrating a clipped portion of an existing regional flow model. The new subregional model was recalibrated with newly available water-level data and spring and ground-water nitrate concentration data for the study area. An updated nitrogen input GIS layer controls the application of nitrogen to the flow and transport model. Users can alter the nitrogen application to the flow and transport model by altering the nitrogen load in predefined spatial zones contained within similar political, hydrologic, and size-constrained boundaries.

Scientific Investigations Report↗
USGS2007

Application of the Basin Characterization Model to Estimate In-Place Recharge and Runoff Potential in the Basin and Range Carbonate-Rock Aquifer System, White Pine County, Nevada, and Adjacent Areas in Nevada and Utah

A regional-scale water-balance model was used to estimate recharge and runoff potential and support U.S. Geological Survey efforts to develop a better understanding of water availability for the Basin and Range carbonate-rock aquifer system (BARCAS) study in White Pine County, Nevada, and adjacent areas in Nevada and Utah. The water-balance model, or Basin Characterization Model (BCM), was used to estimate regional ground-water recharge for the 13 hydrographic areas in the study area. The BCM calculates recharge by using a distributed-parameter, water-balance method and monthly climatic boundary conditions. The BCM requires geographic information system coverages of soil, geology, and topographic information with monthly time-varying climatic conditions of air temperature and precipitation. Potential evapotranspiration, snow accumulation, and snowmelt are distributed spatially with process models. When combined with surface properties of soil-water storage and saturated hydraulic conductivity of bedrock and alluvium, the potential water available for in-place recharge and runoff is calculated using monthly time steps using a grid scale of 866 feet (270 meters). The BCM was used with monthly climatic inputs from 1970 to 2004, and results were averaged to provide an estimate of the average annual recharge for the BARCAS study area. The model estimates 526,000 acre-feet of potential in-place recharge and approximately 398,000 acre-feet of potential runoff. Assuming 15 percent of the runoff becomes recharge, the model estimates average annual ground-water recharge for the BARCAS area of about 586,000 acre-feet. When precipitation is extrapolated to the long-term climatic record (1895-2006), average annual recharge is estimated to be 530,000 acre-feet, or about 9 percent less than the recharge estimated for 1970-2004.

Scientific Investigations Report↗
USGS2007

Evaluation of Approaches for Managing Nitrate Loading from On-Site Wastewater Systems near La Pine, Oregon

This report presents the results of a study by the U.S. Geological Survey, done in cooperation with the Oregon Department of Environmental Quality and Deschutes County, to develop a better understanding of the effects of nitrogen from on-site wastewater disposal systems on the quality of ground water near La Pine in southern Deschutes County and northern Klamath County, Oregon. Simulation models were used to test the conceptual understanding of the system and were coupled with optimization methods to develop the Nitrate Loading Management Model, a decision-support tool that can be used to efficiently evaluate alternative approaches for managing nitrate loading from on-site wastewater systems. The conceptual model of the system is based on geologic, hydrologic, and geochemical data collected for this study, as well as previous hydrogeologic and water quality studies and field testing of on-site wastewater systems in the area by other agencies. On-site wastewater systems are the only significant source of anthropogenic nitrogen to shallow ground water in the study area. Between 1960 and 2005 estimated nitrate loading from on-site wastewater systems increased from 3,900 to 91,000 pounds of nitrogen per year. When all remaining lots are developed (in 2019 at current building rates), nitrate loading is projected to reach nearly 150,000 pounds of nitrogen per year. Low recharge rates (2-3 inches per year) and ground-water flow velocities generally have limited the extent of nitrate occurrence to discrete plumes within 20-30 feet of the water table; however, hydraulic-gradient and age data indicate that, given sufficient time and additional loading, nitrate will migrate to depths where many domestic wells currently obtain water. In 2000, nitrate concentrations greater than 4 milligrams nitrogen per liter (mg N/L) were detected in 10 percent of domestic wells sampled by Oregon Department of Environmental Quality. Numerical simulation models were constructed at transect (2.4 square miles) and study-area (247 square miles) scales to test the conceptual model and evaluate processes controlling nitrate concentrations in ground water and potential ground-water discharge of nitrate to streams. Simulation of water-quality conditions for a projected future build-out (base) scenario in which all existing lots are developed using conventional on-site wastewater systems indicates that, at equilibrium, average nitrate concentrations near the water table will exceed 10 mg N/L over areas totaling 9,400 acres. Other scenarios were simulated where future nitrate loading was reduced using advanced treatment on-site systems and a development transfer program. Seven other scenarios were simulated with total nitrate loading reductions ranging from 15 to 94 percent; simulated reductions in the area where average nitrate concentrations near the water table exceed 10 mg N/L range from 22 to 99 percent at equilibrium. Simulations also show that the ground-water system responds slowly to changes in nitrate loading due to low recharge rates and ground-water flow velocity. Consequently, reductions in nitrate loading will not immediately reduce average nitrate concentrations and the average concentration in the aquifer will continue to increase for 25-50 years depending on the level and timing of loading reduction. The capacity of the ground-water system to receive on-site wastewater system effluent, which is related to the density of homes, presence of upgradient residential development, ground-water recharge rate, ground-water flow velocity, and thickness of the oxic part of the aquifer, varies within the study area. Optimization capability was added to the study-area simulation model and the combined simulation-optimization model was used to evaluate alternative approaches to management of nitrate loading from on-site wastewater systems to the shallow alluvial aquifer. The Nitrate Loading Management Model (NLMM) was formulated to find the minimum red

Scientific Investigations Report↗
USGS1994

Hydrology and geochemistry of a surface coal mine in northwestern Colorado

The hydrology and geochemistry of a reclaimed coal mine in northwestern Colorado were monitored during water years 1988 and 1989. Some data also were collected in water years 1987 and 1990. This report describes (1) the sources of hydrologic recharge to and discharge from reclaimed spoil, (2) the relative contributions of recharge to the reclaimed spoil aquifer from identified source waters and the rate of water movement from those sources to the reclaimed spoil, and (3) the geochemical reactions that control water quality in reclaimed spoil. The study area was at a dip-slope coal mine encompassing about 7 square miles with land slopes of varying aspect. The area was instrumented and monitored at five sites; two sites had unmined and reclaimed- spoil areas adjacent to each other and three sites were unmined. The mined areas had been reclaimed. Instrumentation at the study sites included 1 climate station, 3 rain gages, 19 soil-water access tubes, 2 lysimeters, 18 wells completed in bedrock, 7 wells completed in reclaimed spoil, and 2 surface- water gaging stations. The results of the study indicate that the reclaimed spoil is recharged from surface recharge and underburden aquifers. Discharge, as measured by lysimeters, was about 3 inches per year and occurred during and after snowmelt. Hydraulic-head measurements indicated a potential for ground-water movement from deeper to shallower aquifers. Water levels rose in the reclaimed-spoil aquifer and spring discharge at the toe of the spoil slopes increased rapidly in response to snowmelt. Water chemistry, stable isotopes, geochemical models, and mass-balance calculations indicate that surface recharge and the underburden aquifers each contribute about 50 percent of the water to the reclaimed-spoil aquifers. Geochemical information indicates that pyrite oxidation and dissolution of carbonate and efflorescent sulfate minerals control the water chemistry of the reclaimed-spoil aquifer.

Water-Resources Investigations Report↗
USGS1982

Evaluation of a predictive ground-water solute-transport model at the Idaho National Engineering Laboratory, Idaho

Aqueous chemical and radioactive wastes discharged to shallow ponds and to shallow or deep wells on the Idaho National Engineering Laboratory (INEL) since 1952 have affected the quality of the ground water in the underlying Snake River Plain aquifer. The aqueous wastes have created large and laterally dispersed concentration plumes within the aquifer. The waste plumes with the largest areal distribution are those of chloride, tritium, and with high specific conductance values. The data from eight wells drilled near the southern INEL boundary during the summer of 1980 were used to evaluate the accuracy of a predictive modeling study completed in 1973, and to simulate 1980 positions of chloride and tritium plumes. Data interpretation from the drilling program indicates that the hydrogeologic characteristics of the subsurface rocks have marked effects on the regional ground-water flow regimen and, therefore, the movement of aqueous wastes. As expected, the waste plumes projected by the computer model for 1980, extended somewhat further downgradient than indicated by well data due to conservative worst-case assumptions in the model input and inaccurate approximations of subsequent waste discharge and aquifer recharge conditions. (USGS)

Idaho↗
USGS1993

Hydrology and water quality of Powers Lake, southeastern Wisconsin

This report describes the hydrology and water quality of Powers Lake, a recreational lake in a densely populated area of southeastern Wisconsin, from October 16, 1986 - October 15, 1987. The hydrologic budget for the study period showed that direct precipitation on the lake and ground water were dominant sources of water entering the lake (37 and 36 percent, respectively) and that streamflow dominated the outflow. Surface runoff contributed 27 percent of the inflow-23 percent from Powers Lake inlet and 4 percent from shoreline drainage. Streamflow through Powers Lake outlet accounted for 62 percent of the outflow and evaporation accounted for 38 percent. Based on the streamflow from Powers Lake outlet, the lake's hydraulic residence time was 3.8 years. During the study period, precipitation was 27.16 inches or 4.08 inches below long-term (1951-80) average. The data were adjusted or normalized to represent an average year of precipitation and runoff to help evaluate the water quality of the lake for an average year. For an average year, precipitation dominated inflow (42 percent), followed by ground water (32 percent), Powers Lake inlet (21 percent), and shoreline drainage (5 percent). Streamflow through Powers Lake outlet accounted for 61 percent of an average year's outflow budget and the remaining 39 percent was evaporation. Based on an average year's streamflow from Powers Lake outlet, the lake's hydraulic residence time was 4.2 years. Phosphorus budgets were prepared for the study period and for an estimated normal year. The phosphorus budget for the study period showed that, of the total inputs (516 pounds), surface runoff contributed the largest amount; shoreline drainage contributed 44 percent, and Powers Lake inlet contributed 36 percent. Direct precipitation contributed 11 percent; ground water, 2 percent; and septic systems, 7 percent. Of the total outputs, 83 pounds (16 percent) was lost from the lake via the outlet; 433 pounds (84 percent) was lost to the sediments as the phosphorus that was attached to particles settled to the lake bottom. An estimated phosphorus budget for a normal year showed that of the total inputs (744 pounds), surface runoff contributed the largest amount; Powers Lake inlet contributed 45 percent and shoreline drainage contributed 35 percent. Precipitation contributed 9 percent; ground water, 1 percent; and septic systems, 10 percent. The health of the lake was evaluated using Carlson's Trophic State Index and Vollenweider's model. Carlson's Trophic State Index showed that Powers Lake was moderately enriched and in the mesotrophic range. Comparison of guidelines from Vollenweider's model showed that the total phosphorus input for the study period and for an estimated average year would not cause eutrophic conditions.

Wisconsin↗
USGS2005

Geological, hydrological, and biological issues related to the proposed development of a park at the confluence of the Los Angeles River and the Arroyo Seco, Los Angeles County, California

A new park is being considered for the confluence of the Los Angeles River and the Arroyo Seco in Los Angeles County, California. Components of the park development may include creation of a temporary lake on the Los Angeles River, removal of channel lining along part of the Arroyo Seco, restoration of native plants, creation of walking paths, and building of facilities such as a boat ramp and a visitor center. This report, prepared in cooperation with the Mountains Recreation and Conservancy Authority, delineates the geological, hydrological, and biological issues that may have an impact on the park development or result from development at the confluence, and identifies a set a tasks to help address these science issues. Geologic issues of concern relate to surface faulting, earthquake ground motions, liquefaction, landsliding, and induced seismicity. Hydrologic issues of concern relate to the hydraulics and water quality of both surface water and ground water. Biological issues of concern include colonization-extinction dynamics, wildlife corridors, wildlife reintroduction, non-native species, ecotoxicology, and restoration of local habitat and ecology. Potential tasks include (1) basic data collection and follow-up monitoring, and (2) statistical and probabilistic analyses and simulation modeling of the seismic, hydraulic, and ecological processes that may have the greatest impact on the park. The science issues and associated tasks delineated for the proposed confluence park will also have transfer value for river restoration in other urban settings.

Scientific Investigations Report↗
USGS1978

Quality and movement of ground water in Otter Creek - Dry Creek basin, Cortland County, New York

A steady increase in the chloride and nitrate content of water in a sand and gravel aquifer of glacial origin in the Cortland, N.Y., area prompted a study to obtain data on the extent and source of these constituents. Chloride concentration in the upper part of the aquifer increased generally from 2 mg/liter in 1930 to 20 mg/liter in 1976, and nitrate concentration (as nitrogen) in the upper part of the aquifer increased from 1 mg/liter in 1930 to an average of 4 mg/liter in 1976. Although the ground water is normally very hard, its quality generally meets State standards for source waters used for drinking. Road salting and farming seem to be the primary cause of chloride increases, although septic systems may be a major source locally. Farm-animal waste, sewage systems, and fertilizers are the major contributors of nitrate to ground water. Flow in the aquifer system in the Otter Creek-Dry Creek basin was simulated with a digital-computer model. The model was calibrated by comparing measured water levels in the aquifer with those determined by the model. The major sources of recharge are from precipitation and seepage from losing reaches of the streams. (Woodard-USGS)

New York↗
USGS1994

Evaluation of ground-water flow by particle tracking, Wright-Patterson Air Force Base, Ohio

The U.S. Geological Survey (USGS) and Wright-Patterson Air Force Base (WPAFB) began a Basewide Monitoring Program (BMP) in 1992. The purpose of the BMP was to establish a long-term ground-water and surface- water sampling network in order to (1) characterize current ground-water and surface-water quality; (2) describe water-quality changes as water enters, flows across, and exits Base boundaries; (3) conduct statistical analyses of water quality; and (4) estimate the effect of WPAFB on regional water quality. As part of the BMP, the USGS conducted ground-water particle-tracking analyses based on a ground-water-flow model produced during a previous USGS study. This report briefly describes the previous USGS study, the inherent assumptions of particle-tracking analyses, and information on the regional ground-water-flow field as inferred from particle pathlines. Pathlines for particles placed at the Base boundary and particles placed within identified Installation Restoration Program sites are described.

Ohio↗
USGS2003

Comparison of two methods for delineating land use near monitoring wells used for assessing quality of shallow ground water

Two methods were compared for delineating land use near shallow monitoring wells. These wells were used to assess the effects of agricultural cropland on the quality of recently recharged ground water in two sand and gravel aquifers located near land surface. The two methods for delineating land use near wells were (1) the sector method, which used potentiometric-surface maps to estimate average flow direction and a ground-water-flow model to estimate maximum length of contributing area to the monitoring well within an upgradient sector; and (2) the circle method, which used a 500- meter radius circle around the well based on a national empirical analysis. Land uses were compiled for 29 wells in each of two surficial aquifers in the Red River of the North Basin within the area defined by each method. Land use near each well was interpreted from orthorectified photographs and site inspection for both delineation methods. Land use near individual wells characterized by each method varied greatly, which can affect the results of statistical correlations between land use and water quality. Land use determined by the circle method related more closely to the land use for each entire study area. Land use determined by the sector method (within 200 meters from the wells) compared more favorably to ground-water quality based on nitrate concentrations. The maximum length of contributing areas to wells estimated in this study may be of value for other studies of unconsolidated sand and gravel aquifers with similar hydrogeological characteristics of permeability, water-table slopes, recharge, and depth to water. The additional effort required for estimating the model delineation of land use and land cover for the sector method must be weighed against the improved confidence in statistical correlation between land use and the quality of shallow ground water. Improved scientific confidence and understanding of relations between land use and quality of ground water may encourage more effective implementation of land and water management for protecting water quality

Minnesota, North Dakota↗
USGS1984

Hydrogeology of a low-level radioactive-waste disposal site near Sheffield, Illinois

The Sheffield low-level radioactive-waste facility is located on 20 acres of rolling terrain 3 miles southwest of Sheffield, Illinois. The shallow hydrogeologic system is composed of glacial sediments. Pennsylvania shale and mudstone bedrock isolate the regional aquifers below from the hydrogeologic system in the overlying glacial deposits. Pebbly sand underlies 67 percent of the site. Two ground-water flow paths were identified. The primary path conveys ground water from the site to the east through the pebbly-sand unit; a secondary path conveys ground water to the south and east through less permeable material. The pebbly-sand unit provides an underdrain that eliminates the risk of water rising into the trenches. Digital computer model results indicate that the pebbly-sand unit controls ground-water movement. Tritium found migrating in ground water in the southeast corner of the site travels approximately 25 feet per year. A group of water samples from wells which contained the highest tritium concentrations had specific conductivities, alkalinities, hardness, and chloride, sulfate, calcium, and magnesium contents higher than normal for local shallow ground water. (USGS)

Water-Resources Investigations Report↗
USGS2002

Ecological effects on streams from forest fertilization: Literature review and conceptual framework for future study in the western Cascades

Fertilization of forests with urea-nitrogen has been studied numerous times for its effects on water quality. Stream nitrogen concentrations following fertilization are typically elevated during winter, including peaks in the tens-of-thousands of parts per billion range, with summer concentrations often returning to background or near-background levels. Despite these increases, water-quality criteria for nitrogen have rarely been exceeded. However, such criteria are targeted at fish toxicity or human health and are not relevant to concentrations that could cause ecological disturbances. Studies of the responses of stream biota to fertilization have been rare and have targeted either immediate, toxicity-based responses or used methods insensitive to ongoing ecological processes. This report reviews water-quality studies following forest fertilizations, emphasizing Cascade streams in the Pacific Northwest and documented biological responses in those streams. A conceptual model predicting potential ecological response to fertilization, which includes effects on algal growth and primary production, is presented. In this model, applied fertilizer nitrogen reaching streams is mostly exported during winter. However, some nitrogen retained in soils or stream and riparian areas may become available to aquatic biota during spring and summer. Biological responses may be minimal in small streams nearest to application because of light limitation, but may be elevated downstream where light is sufficient to allow algal growth. Ultimately, algal response could be greatest in downstream reaches, although ambient nutrient concentrations remain low due to uptake and benthic nutrient recycling. Ground-water flow paths and hyporheic processing could be critical in determining the fate of applied nitrogen. A framework is provided for testing this response in the Little River watershed, a tributary to the North Umpqua River, Oregon, at basic and intensive levels of investigation.

Oregon↗
USGS1994

Description and application of capture zone delineation for a wellfield at Hilton Head Island, South Carolina

Ground-water capture zone boundaries for individual pumped wells in a confined aquffer were delineated by using groundwater models. Both analytical and numerical (semi-analytical) models that more accurately represent the $round-water-flow system were used. All models delineated 2-dimensional boundaries (capture zones) that represent the areal extent of groundwater contribution to a pumped well. The resultant capture zones were evaluated on the basis of the ability of each model to realistically rapresent the part of the ground-water-flow system that contributed water to the pumped wells. Analytical models used were based on a fixed radius approach, and induded; an arbitrary radius model, a calculated fixed radius model based on the volumetric-flow equation with a time-of-travel criterion, and a calculated fixed radius model derived from modification of the Theis model with a drawdown criterion. Numerical models used induded the 2-dimensional, finite-difference models RESSQC and MWCAP. The arbitrary radius and Theis analytical models delineated capture zone boundaries that compared least favorably with capture zones delineated using the volumetric-flow analytical model and both numerical models. The numerical models produced more hydrologically reasonable capture zones (that were oriented parallel to the regional flow direction) than the volumetric-flow equation. The RESSQC numerical model computed more hydrologically realistic capture zones than the MWCAP numerical model by accounting for changes in the shape of capture zones caused by multiple-well interference. The capture zone boundaries generated by using both analytical and numerical models indicated that the curnmtly used 100-foot radius of protection around a wellhead in South Carolina is an underestimate of the extent of ground-water capture for pumped wetis in this particular wellfield in the Upper Floridan aquifer. The arbitrary fixed radius of 100 feet was shown to underestimate the upgradient contribution of ground-water flow to a pumped well.

South Carolina↗
USGS1998

Optimization of ground-water withdrawal in the lower Fox River communities, Wisconsin

Pumping from closely spaced wells in the Central Brown County area and the Fox Cities area near the north shore of Lake Winnebago has resulted in the formation of deep cones of depression in the vicinity of the two pumping centers. Water-level measurements indicate there has been a steady decline in water levels in the vicinity of these two pumping centers for the past 50 years. This report describes the use of ground-water optimization modeling to efficiently allocate the ground-water resources in the Lower Fox River Valley. A 3-dimensional ground-water flow model was used along with optimization techniques to determine the optimal withdrawal rates for a variety of management alternatives. The simulations were conducted separately for the Central Brown County area and the Fox Cities area. For all simulations, the objective of the optimization was to maximize total ground-water withdrawals. The results indicate that ground water can supply nearly all of the projected 2030 demand for Central Brown County municipalities if all of the wells are managed (including the city of Green Bay), 8 new wells are installed, and the water-levels are allowed to decline to 100 ft below the bottom of the confining unit. Ground water can supply nearly all of the projected 2030 demand for the Fox Cities if the municipalities in Central Brown County convert to surface water; if Central Brown County municipalities follow the optimized strategy described above, there will be a considerable shortfall of available ground water for the Fox Cities communities. Relaxing the water-level constraint in a few wells, however, would likely result in increased availability of water. In all cases examined, optimization alternatives result in a rebound of the steady-state water levels due to projected 2030 withdrawal rates to levels at or near the bottom of the confining unit, resulting in increased well capacity. Because the simulations are steady-state, if all of the conditions of the model remain the same these withdrawal rates would be sustainable in perpetuity.

Wisconsin↗
USGS1996

Hydrogeologic setting and simulation of pesticide fate and transport in the unsaturated zone of a regolith-mantled, carbonate-rock terrain near Newville, Pennsylvania

Physical and chemical data were collected from May 1991 through April 1993 at a 4.5 hectare field site in Cumberland County, Pa., about 5 kilometers southeast of Newville. These data were used to define the hydrogeologic setting of a field site representative of the intensively farmed carbonate valleys of southeastern and south-central Pennsylvania. The environmental processing of commonly used pesticides (herbicides, fungicides, and insecticides) in the unsaturated zone was simulated with a process- oriented digital model to evaluate the environmental fate and transport of pesticides to ground water. Site data and modelling results provide a basis for a discussion of water-quality implications of agricultural best-management practices. The carbonate valleys of Pennsylvania comprise regolith-mantled carbonate-rock terrains that consist of broad undulating upland areas dissected by mostly dry valleys and widely spaced spring-fed creeks. The upland areas are farmed and exhibit possess a doline karst topography with many closed depressions, sinkholes, and bedrock outcrops. Unsaturated materials at the field site consist of an almost continuous soil cover composed of fine-grained residuum underlain by an intermediate vadose zone composed of karstified limestone. Soils are absent on scattered bedrock outcrops and are more than 12 meters thick in other areas of the site. The soil profile stores appreciable quantities of water with a volumetric average of about 36 percent water at field capacity. Organic carbon content of soil materials is about 1.7 percent in the Ap-horizon and from 0.1 to 0.3 percent throughout the full thickness of the B- and C-horizons. Atrazine, metolachlor, simazine, and the atrazine soil metabolites deethylatrazine and deisopropylatrazine were detected at concentrations above 0.05 mg/L in just the upper 0.6 meters of soil materials. However, detectable concentrations of atrazine, simazine, and atrazine soil metabolites were measured in water samples from lysimeters installed in soil materials at depths of 1.2, 2.1, and 3.7 meters and from monitor wells completed in the saturated zone to depths of 122 meters. Data collected from the field site were used to configure a pesticide screening model based on the pesticide version of the leaching estimation and chemistry model (LEACHP) developed by Wagenet and Hutson (1987). Model simulations show that most field-applied pesticides volatilize to the atmosphere, accumulate in soils, degrade in the subsurface environment, or leach to ground water. Model results were used to rank the leaching potentials of 66 pesticides. Eighteen of 32 herbicides, 4 of 9 fungicides, and 10 of 25 insecticides have moderate to large potential for leaching to ground water. A review of available pesticide monitoring data suggests that many compounds given moderate or high leaching potentials have not been tested for in ground water and the presence of pesticides in Pennsylvania's ground water may be underreported. Monitoring data do not exist for more than two-thirds of the pesticide compounds currently used in agricultural, carbonate areas of Pennsylvania. Knowledge of processes that govern fate and transport of pesticides is needed to facilitate development of effective pesticide best-management practices. In addition to comprehensive monitoring for pesticides and pesticide degradation products in ground water downgradient of areas of pesticide use, improved (1) characterization of unsaturated flow and transport through regolith mantled carbonate rocks, (2) estimates of pesticide degradation rates, (3) understanding of soil-property controls on pesticide movement, and (4) management models developed from process-oriented research would aid in understanding the processes.

Water-Resources Investigations Report↗
USGS2008

Distribution and migration of ordnance-related compounds and oxygen and hydrogen stable isotopes in ground water near Snake Pond, Sandwich, Massachusetts

Explosive compounds, such as RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine) and HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine), and the propellant compound perchlorate are present in ground water near Snake Pond, a ground-water flow-through glacial kettle pond in the glacial sand and gravel aquifer on western Cape Cod near Camp Edwards on the Massachusetts Military Reservation. The contaminants originate from the J-3 Range ordnance training and testing area. Ground-water samples were collected at 10 sites near the pond to determine the paths of the contaminants as they underflow or completely or partially discharge into the pond. Water-quality profiles were developed for sites on opposite ends of a 200-foot-long intermittent island near the northern, upgradient end of the pond by collecting water samples from two temporary drive-point borings. RDX was detected at both locations between 60 and 90 feet below the pond level. The highest RDX concentration was 0.99 micrograms per liter. Perchlorate was detected at only one location on the island, between 95 and 100 feet below the pond level at a concentration of 0.61 micrograms per liter. Profiles of oxygen and hydrogen stable isotopes were developed for seven sites spaced 300 to 600 feet apart along the southern, downgradient shore of the pond. A transition from heavier to lighter oxygen and hydrogen isotopes was observed at an altitude of about -50 feet. This transition most likely is the boundary between evaporation-affected pond water that is seeping into the aquifer and ground water that has passed beneath the pond. RDX was not detected in the ground-water samples collected south of the pond. Perchlorate was detected only in one sample from a shallow depth in one boring. The results of these analyses indicate that the J-3 Range plume contains low concentrations of RDX and perchlorate (less than 1 microgram per liter) as it passes beneath the northern end of Snake Pond. Results of ground-water-flow modeling indicate that ground water containing these low levels of RDX and perchlorate discharges into the pond south of the island. If the contaminated ground water should travel as far as the southern shore of the pond, it would be overlain near the shore by a zone of pond water seeping into the aquifer that is about 100 feet thick.

Massachusetts↗
USGS1979

Water-level predictions for Indian Wells Valley ground-water basin, California, 1978

Ground-water pumpage in Indian Wells Valley, virtually a closed basin in the Mojave Desert of southern California, has increased gradually since 1945 and presently exceeds the long-term mean annual recharge (perennial supply). In order to aid in the understanding and management of the ground-water basin, a digital ground-water model was constructed by the U.S. Geological Survey. Since the original development of this model, conditions in the basin, including areal distribution and rates of ground-water pumpage, have changed. The results of the present simulation for the period 1969-76 constitute a second verification of the original model. Calculated heads for 1976 agree well with the observed heads, indicating a good calibration of the original model. A predictive simulation for the period 1977-2020 used pumpage values increasing from about 15,500 acre-feet per year to about 26,000 acre-feet per year. The pumpage used in this report reflects a slightly slower growth rate and a more concentrated pattern of development than that investigated when the model was originally developed. The effects of this pattern of pumpage are reflected in the water levels simulated by the model. Predicted drawdowns for 1983 are less extensive but locally more severe than those predicted earlier. The reversal of the hydraulic gradient between China Lake playa and the city of Ridgecrest, as produced by these drawdowns by the year 2020, suggests that the water-quality effects of such drawdowns should be investigated, as this could result in inferior water from the China Lake playa area flowing southward into areas of withdrawal.

California↗
USGS2004

Simulation of regional ground-water flow in the Upper Deschutes Basin, Oregon

This report describes a numerical model that simulates regional ground-water flow in the upper Deschutes Basin of central Oregon. Ground water and surface water are intimately connected in the upper Deschutes Basin and most of the flow of the Deschutes River is supplied by ground water. Because of this connection, ground-water pumping and reduction of artificial recharge by lining leaking irrigation canals can reduce the amount of ground water discharging to streams and, consequently, streamflow. The model described in this report is intended to help water-management agencies and the public evaluate how the regional ground-water system and streamflow will respond to ground-water pumping, canal lining, drought, and other stresses. Ground-water flow is simulated in the model by the finite-difference method using MODFLOW and MODFLOWP. The finite-difference grid consists of 8 layers, 127 rows, and 87 columns. All major streams and most principal tributaries in the upper Deschutes Basin are included. Ground-water recharge from precipitation was estimated using a daily water-balance approach. Artificial recharge from leaking irrigation canals and on-farm losses was estimated from diversion and delivery records, seepage studies, and crop data. Ground-water pumpage for irrigation and public water supplies, and evapotranspiration are also included in the model. The model was calibrated to mean annual (1993-95) steady-state conditions using parameter-estimation techniques employing nonlinear regression. Fourteen hydraulic-conductivity parameters and two vertical conductance parameters were determined using nonlinear regression. Final parameter values are all within expected ranges. The general shape and slope of the simulated water-table surface and overall hydraulic-head distribution match the geometry determined from field measurements. The fitted standard deviation for hydraulic head is about 76 feet. The general magnitude and distribution of ground-water discharge to streams is also well simulated throughout the model. Ground-water discharge to streams in the area of the confluence of the Deschutes, Crooked, and Metolius Rivers is closely matched. The model was also calibrated to transient conditions from 1978 to 1997 using traditional trial-and-error methods. Climatic cycles during this period provided an excellent regional hydrologic signal for calibration. Climate-driven water-level fluctuations are simulated with reasonable accuracy over most of the model area. The timing and magnitude of simulated water-level fluctuations caused by annual pulses of recharge from precipitation match those observed reasonably well, given the limitations of the time discretization in the model. Water-level fluctuations caused by annual canal leakage are simulated very well over most of the area where such fluctuations occur. The transient model also simulates the volumetric distribution and temporal variations in ground-water discharge reasonably well. The match between simulated and measured volume of and variations in ground-water discharge is, however, somewhat dependent on geographic scale. The rates of and variations in ground-water discharge are matched best at regional scales. Example simulations were made to demonstrate the utility of the model for evaluating the effects of ground-water pumping or canal lining. Pumping simulations show that pumped water comes largely from aquifer storage when pumping begins, but as the water table stabilizes, the pumping increasingly diminishes the discharge to streams and, hence, streamflow. The time it takes for pumping to affect streamflow varies spatially depending, in general, on the location of pumping relative to the discharge areas. Canal-lining simulations show similar effects.

Water-Resources Investigations Report↗