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A crustal thermal model of the conterminous U.S. constrained by multiple data sets: A Monte-Carlo approach

The thermal structure of the continental crust plays a critical role in understanding its elastic and rheologic properties as well as its dynamic processes. Thermal parameter data sets on continental scales have been used to constrain the crustal thermal structure, including both the direct (e.g. temperature, heat flux and heat conductivity measured at the surface) and indirect (e.g. seismically derived Mohorovičić discontinuity (Moho) temperature, geomagnetically derived Curie depth) observations. In this study, we present a new continental scale crustal heat generation model with additional information from seismologically inferred crustal composition. Together with previous direct and indirect thermal parameter data sets in the conterminous United States, we use the new crustal heat generation model to construct a 3-D crustal temperature model under a newly developed Bayesian framework. Specifically, we first derive profiles of crustal heat generation based on an empirical geochemical relationship at 1683 locations where seismologically derived crustal composition information is available. Then for each of these locations, the average heat generation values in the upper, middle and lower crust are combined with other thermal parameters through a Markov Chain Monte-Carlo inversion for a conductive, vertically smooth temperature profile. The results, posterior distributions of temperature profiles, are used to generate a 3-D crustal thermal model with the uncertainties systematically assessed. The new temperature model overall exhibits similar patterns to that from the U.S. Geological Survey National Crustal Model, but also reduces possible biases and the model's dependence on a single thermal parameter.

conterminous United States

Geochemistry, petrography, and zircon U-Pb geochronology of Paleozoic metaigneous rocks in the Mount Veta area of east-central Alaska: implications for the evolution of the westernmost part of the Yukon-Tanana terrane

We report the results of new mapping, whole-rock major, minor, and trace-element geochemistry, and petrography for metaigneous rocks from the Mount Veta area in the westernmost part of the allochthonous Yukon–Tanana terrane (YTT) in east-central Alaska. These rocks include tonalitic mylonite gneiss and mafic metaigneous rocks from the Chicken metamorphic complex and the Nasina and Fortymile River assemblages. Whole-rock trace-element data from the tonalitic gneiss, whose igneous protolith was dated by SHRIMP U–Pb zircon geochronology at 332.6 ± 5.6 Ma, indicate derivation from tholeiitic arc basalt. Whole-rock analyses of the mafic rocks suggest that greenschist-facies rocks from the Chicken metamorphic complex, a mafic metavolcanic rock from the Nasina assemblage, and an amphibolite from the Fortymile River assemblage formed as island-arc tholeiite in a back-arc setting; another Nasina assemblage greenschist has MORB geochemical characteristics, and another mafic metaigneous rock from the Fortymile River assemblage has geochemical characteristics of calc-alkaline basalt. Our geochemical results imply derivation in an arc and back-arc spreading region within the allochthonous YTT crustal fragment, as previously proposed for correlative units in other parts of the terrane. We also describe the petrography and geochemistry of a newly discovered tectonic lens of Alpine-type metaharzburgite. The metaharzburgite is interpreted to be a sliver of lithospheric mantle from beneath the Seventymile ocean basin or from sub-continental mantle lithosphere of the allochthonous YTT or the western margin of Laurentia that was tectonically emplaced within crustal rocks during closure of the Seventymile ocean basin and subsequently displaced and fragmented by faults.

Alaska, British Columbia, Yukon

Vestiges of an Iapetan rift basin in the New Jersey Highlands: Implfications for the Neoproterozoic Laurentian margin

Thin, discontinuous remnants of Neoproterozoic intracratonic rift-basin deposits of the Chestnut Hill Formation occur in the western New Jersey Highlands. These deposits form an important link between well-documented Iapetan rift-basins in both the northern and southern Appalachians. The close spatial relations of Chestnut Hill rocks to Paleozoic sedimentary rocks open the possibility that additional Iapetan rift-basins could be concealed beneath the rocks of the Valley and Ridge Province to the west indicating a much broader zone of rifting than has been previously proposed. The Chestnut Hill Formation is intermittently exposed along a 100 km-long band that extends northeast from Pennsylvania nearly to New York State. The lower part of the Chestnut Hill Formation is composed of interbedded lithic pebble- to boulder-conglomerate and feldspathic sandstone grading upward into interbedded phyllite, feldspathic and quartz sandstone, local paleosaprolite, quartz-pebble conglomerate, thin limestone lenses, volcanic, and volcaniclasic rocks, abundant bedded ironstone (hematite ore), and ultimately into diamictites that are interpreted as possible tilloids and containing rounded intra and extrabasinal clasts of the other lithologies. Extensive soft-sediment deformation, cross bedding, and clastic dikes are common in all but the lowest and upper facies. Banded hematite layers occur preferentially in fine-grained tuffs and tuffaceous sediments, but hematitization has affected most lithologies. Volcanic rocks consist of altered rhyolitic tuffs and lapilli tuffs that are interbedded with sediments. The Chestnut Hill Formation is interpreted to have been deposited in early alluvial, and later a complex of fluvial, lacustrine and deltaic environments. Provenance studies based upon petrographic and geochemical analysis of clastic rocks indicate that the sediments are predominantly immature and reflect derivation from local uplifted felsic basement sources in a rifted-margin tectonic setting. Low to moderate weathering of the source rocks is indicated by the geochemistry of most samples, as is the locally intense effect of hydrothermal alteration. Most occurrences of the Chestnut Hill Formation are associated with major faults that exhibit normal movement of apparent Neoproterozoic age. Rocks from the Morgan Hill fault near Easton, Pennsylvania display consistent normal shear sense and vary from low temperature S-C mylonites to breccia that contains deformed pieces of Chestnut Hill Formation. ?? 2004 Elsevier Ltd. All rights reserved.

Journal of Geodynamics

Sedimentological and geochemical perspectives on a marginal lake environment recorded in the Hartmann’s Valley and Karasburg members of the Murray formation, Gale crater, Mars

This study utilizes instruments from the Curiosity rover payload to develop an integrated paleoenvironmental and compositional reconstruction for the 65-m thick interval of stratigraphy comprising the Hartmann's Valley and Karasburg members of the Murray formation, Gale crater, Mars. The stratigraphy consists of cross-stratified sandstone (Facies 1), planar-laminated sandstone (Facies 2), and planar-laminated mudstone (Facies 3). Facies 1 is composed of sandstone showing truncated sets of concave-curvilinear laminae stacked into cosets. Sets are estimated to be meter-to sub-meter-scale, consistent with low-height dunes. Thin stratigraphic intervals of Facies 1 and stacking patterns with Facies 2 and 3 support a wet aeolian dune interpretation. Meter-thick packages of planar-laminated sandstone (Facies 2) are interpreted to represent interfingering dune-interdune strata. Facies 3 consists of meter-thick packages of planar-laminated mudstone interpreted to represent lacustrine deposition with persistent standing water. Integration of geochemistry with each facies reveals some compositional control based on the depositional process. Models for source rock composition from Alpha Particle X-Ray Spectrometer measurements show that facies derived from a basaltic source. Alteration indices and geochemical trends provide evidence that moderate chemical weathering occurred before compositional changes due to diagenesis. Differences in wt% FeO (T) and TiO 2 between facies are minimal, though trends point to sediment sorting in transport. Comparisons to terrestrial basaltic sedimentary systems indicate that the Hartmann's Valley and Karasburg facies reflect deposition in an environment where diverse subaqueous and subaerial facies persisted adjacent to a long-lived body of water.

Journal of Geophysical Research Planets

Sulfate deposition in subsurface regolith in Gusev crater, Mars

Excavating into the shallow Martian subsurface has the potential to expose stratigraphic layers and mature regolith, which may hold a record of more ancient aqueous interactions than those expected under current Martian surface conditions. During the Spirit rover's exploration of Gusev crater, rover wheels were used to dig three trenches into the subsurface regolith down to 6-11 cm depth: Road Cut, the Big Hole, and The Boroughs. A high oxidation state of Fe and high concentrations of Mg, S, Cl, and Br were found in the subsurface regolith within the two trenches on the plains, between the Bonneville crater and the foot of Columbia Hills. Data analyses on the basis of geochemistry and mineralogy observations suggest the deposition of sulfate minerals within the subsurface regolith, mainly Mg-sulfates accompanied by minor Ca-sulfates and perhaps Fe-sulfates. An increase of Fe2O3, an excess of SiO2, and a minor decrease in the olivine proportion relative to surface materials are also inferred. Three hypotheses are proposed to explain the geochemical trends observed in trenches: (1) multiple episodes of acidic fluid infiltration, accompanied by in situ interaction with igneous minerals and salt deposition; (2) an open hydrologic system characterized by ion transportation in the fluid, subsequent evaporation of the fluid, and salt deposition; and (3) emplacement and mixing of impact ejecta of variable composition. While all three may have plausibly contributed to the current state of the subsurface regolith, the geochemical data are most consistent with ion transportation by fluids and salt deposition as a result of open-system hydrologic behavior. Although sulfates make up >20 wt.% of the regolith in the wall of The Boroughs trench, a higher hydrated sulfate than kieserite within The Boroughs or a greater abundance of sulfates elsewhere than is seen in The Boroughs wall regolith would be needed to hold the structural water indicated by the water-equivalent hydrogen concentration observed by the Gamma-Ray Spectrometer on Odyssey in the Gusev region.

Journal of Geophysical Research E: Planets

Mineral remains of early life on Earth? On Mars?

The oldest sedimentary rocks on Earth, the 3.8‐Ga Isua Iron‐Formation in southwestern Greenland, are metamorphosed past the point where organic‐walled fossils would remain. Acid residues and thin sections of these rocks reveal ferric microstructures that have filamentous, hollow rod, and spherical shapes not characteristic of crystalline minerals. Instead, they resemble ferric‐coated remains of bacteria. Modern so‐called iron bacteria were therefore studied to enhance a search image for oxide minerals precipitated by early bacteria. Iron bacteria become coated with ferrihydrite, a metastable mineral that converts to hematite, which is stable under high temperatures. If these unusual morphotypes are mineral remains of microfossils, then life must have evolved somewhat earlier than 3.8 Ga, and may have involved the interaction of sediments and molecular oxygen in water, with iron as a catalyst. Timing is constrained by the early in fall of planetary materials that would have heated the planet's surface. Because there are no earlier sedimentary rocks to study on Earth, it may be necessary to expand the search elsewhere in the solar system for clues to any biotic precursors or other types of early life. Evidence from Mars shows geophysical and geochemical differentiation at a very early stage, which makes it an important candidate for such a search if sedimentation is an important process in life's origins. Not only does Mars have iron oxide‐rich soils, but its oldest regions have river channels where surface water and sediment may have been carried, and seepage areas where groundwater may have discharged. Mars may have had an atmosphere and liquid water in the crucial time frame of 3.9–4.0 Ga. A study of morphologies of iron oxide minerals collected in the southern highlands during a Mars sample return mission may therefore help to fill in important gaps in the history of Earth's earliest biosphere.

Geomicrobiology Journal

Geochemical investigations of selected Eastern United States watersheds affected by acid deposition

The effects of acid deposition on surface waters in eastern United States watersheds having similar size, physiography, climate and land use are related to the composition of the underlying bedrock. Watersheds developed on greenstone, calcareous shale, sandstone, granite, and schist differ in their ability to neutralize acid deposition. Surface waters in watersheds developed on greenstone and calcareous shale are not discernably affected by acidification. Wastersheds developed on sand-stone have little capacity to neutralize acid rain; consequently, stream acidity is similar to that of precipitation. Watersheds developed on granite and schist are intermediate in their capacity to neutralize acid deposition. Bedrock composition appears to be the major property controlling surface-water chemistry in these systems; hydrologic flow paths and the nature of surficial materials and vegetation also influence chemical responses to acid deposition in watersheds.

Journal of the Geological Society

Mars Science Laboratory CheMin data from the Glen Torridon region and the significance of lake-groundwater interactions in interpreting mineralogy and sedimentary history

The Glen Torridon (GT) region is positioned in terrains with strong clay mineral signatures, as inferred from orbital spectroscopy. The GT campaign confirmed orbital distinctions with in situ measurements by the Mars Science Laboratory rover, Curiosity , and the CheMin X-ray diffraction instrument with of some of the highest clay mineral abundances to date. Additionally, GT is unique because of distinct phase identifications for the first time by CheMin, including: (i) Fe-carbonates, and (ii) a novel peak in the XRD patterns of some GT samples, with an interplanar spacing of at 9.2 Å. Fe-carbonates have been previously suggested from other instruments onboard, but this is the first definitive reporting by CheMin of multiple samples with Fe-carbonate. This new phase has never been observed in Gale crater with the CheMin instrument and may be a new mineral for Mars, but discrete identification still remains enigmatic because no single phase on Earth is able to account the mineralogical, geochemical, and sedimentological constraints in the GT region. Here, we modeled XRD profiles and propose an interstratified clay mineral, specifically greenalite-minnesotaite (G-M), as a reasonable candidate. The coexistence of Fe-carbonate and Fe-rich clay minerals in the GT samples, supports a conceptual model of a lacustrine groundwater mixing environment in the ancient Gale crater lake. Groundwater interaction with percolating lake waters in the sediments is common in terrestrial lacustrine settings, and the diffusion of two distinct water bodies within the subsurface can create a geochemical gradient and unique mineral front in the sediments. Ultimately, the proximity to this mixing zone controlled the secondary minerals preserved in the Jura, Knockfarril Hill, and Glasgow members of the Mt. Sharp group exposed in GT.

Journal of Geophysical Research E: Planets

Submarine sliver in North Kona: A window into the early magmatic and growth history of Hualalai Volcano, Hawaii

Two manned submersible dives examined the Hualalai Northwest rift zone and an elongate ridge cresting at 3900 mbsl during a 2002 JAMSTEC cruise. The rift zone flank at dive site S690 (water depth 3412–2104 m) is draped by elongated and truncated pillow lavas. These olivine-rich tholeiitic lavas are compositionally indistinguishable from those examined further south along the bench, except that they span a wider range in dissolved sulfur content (200–1400 ppm). The elongate ridge investigated in dive S692, located at the base of the bench, is a package of distinct lithologic units containing volcaniclastic materials, glassy pillow breccias, and lava blocks; these units contain a range of compositions including tholeiitic basalt, transitional basalt, and hawaiite. The textures, compositions, and stratigraphic relationships of materials within the elongate ridge require that a variety of transport mechanisms juxtaposed materials from multiple eruptions into individual beds, compacted them into a coherent package of units, and brought the package to its present depth 10 km from the edge of the North Kona slump bench. Sulfur-rich hawaiite glasses at the base of the elongate ridge may represent the first extant representatives of juvenile alkalic volcanism at Hualalai. They are geochemically distinct from shield tholeiite and post-shield alkalic magmas, but may be related to transitional basalt by high-pressure crystal fractionation of clinopyroxene. Tholeiitic glasses that compose the majority of the exposed outcrop are similar to Mauna Kea tholeiites and other Hualalai tholeiites, but they differ from younger basalts in having greater incompatible element enrichments and higher CaO for a given MgO. These differences could arise from small extents of partial melting during the transition from alkalic to shield stage magmatism. Low sulfur contents of most of the volcaniclastic tholeiites point to early emergence of Hualalai above sea level relative to the development of the midslope slump bench.

Hawai'i

A geochemical study of oil in metalliferous veins, Idarado Mine, San Juan Mountains, Colorado

A tarry, benzene-soluble material is present in metal-rich veins in the Idarado mine, Ouray County, Colo., in an area not known to have petroleum resources. The material was compared chemically, spectometrically, and chromatographically with oils from four fields in the nearby Paradox basin. Each of these oil fields contains reservoir rocks equivalent to rock units known to extend beneath volcanic rocks near the mine. Carbon and sulfur isotope data and gas chromatographic data indicate a similarity between the oil from the nearby Sierra field and the oil from the mine. Thus, it seems both geologically and chemically possible that oil in the mine originated in Cretaceous sediments. Variations in the composition of oil from the mine and differences between the mine oil and Sierra oil, notably in the distributions of hydrocarbons, are attributed to bacterial degradation.

Colorado

Geochemical indicators of subsurface temperature: Part 1, basic assumptions

The chemical and isotopic compositions of hot-spring water and gas are used to estimate subsurface temperatures. The basic assumptions inherent in the methods are seldom stipulated. These assumptions include (1) a temperature-dependent reaction at depth, (2) a supply of the solid phase involved in the reaction to permit saturation of the constituent used for geothermometry, (3) water-rock equilibrium at depth, (4) negligible re-equilibration as the water flows to the surface, and (5) no dilution or mixing of hot and cold water. The first three assumptions are probably good for a few reactions that occur in many places. The last two assumptions probably are not valid for many hot-spring systems; information obtained is therefore for the shallower parts of those systems, or a limiting temperature (generally a minimum) is indicated.

Journal of Research of the U.S. Geological Survey

Trends and transformation of nutrients and pesticides in a Coastal Plain aquifer system, United States

Four local-scale sites in areas with similar corn (Zea mays L.) and soybean [Glycine max (L.) Merr.] agriculture were studied to determine the effects of different hydrogeologic settings of the Northern Atlantic Coastal Plain (NACP) on the transport of nutrients and pesticides in groundwater. Settings ranged from predominantly well-drained soils overlying thick, sandy surficial aquifers to predominantly poorly drained soils with complex aquifer stratigraphy and high organic matter content. Apparent age of groundwater, dissolved gases, N isotopes, major ions, selected pesticides and degradates, and geochemical environments in groundwater were studied. Agricultural chemicals were the source of most dissolved ions in groundwater. Specific conductance was strongly correlated with reconstructed nitrate (the sum of N in nitrate and N gas) (R 2 = 0.81, p < 0.0001), and is indicative of the relative degree of agricultural effects on groundwater. Trends in nitrate were primarily related to changes in manure and fertilizer use at the well-drained sites where aquifer conditions were consistently oxic. Nitrate was present in young groundwater but completely removed over time through denitrification at the poorly drained sites where there were variations in chemical input and in geochemical environment. Median concentrations of atrazine (6-chloro-N-ethyl-N'-(1- methylethyl)-1,3,5-triazine-2,4-diamine), metolachlor (2-chloro-N-(2-ethyl-6- methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide), and some of their common degradates were higher at well-drained sites than at poorly drained sites, with concentrations of degradates generally higher than those of the parent compounds at all sites. An increase in the percentage of deethylatrazine to total atrazine over time at one well-drained site may be related to changes in manure application. Copyright ?? 2010 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality

Insights from growing Globorotalia truncatulinoides and Globorotalia menardii in the laboratory

The vast majority of planktic foraminiferal culture studies have been carried out on spinose species of foraminifera, with relatively few studies on non-spinose species. We conducted a pilot study to test whether live specimens of the non-spinose planktic foraminifera, Globorotalia truncatulinoides and Globorotalia menardii , could be successfully harvested from offshore plankton tow samples in the Gulf of America (Gulf of Mexico) and kept alive in a laboratory at the US Geological Survey St. Petersburg Coastal and Marine Science Center. We collected several G. truncatulinoides specimens (n = 39) from the surface mixed-layer (0–80 meters) via vertical plankton tow in February 2020 during a sediment trap mooring recovery cruise. We collected G. menardii (n = 27) from the upper 200 meters of the water column on follow-up cruises in December 2021 and November 2022. The G. truncatulinoides specimens stayed alive in the laboratory for 8–76 days, and G. menardii for 7–29 days. All non-spinose foraminifera in this study showed a strong preference for eating marine snow aggregates from the plankton tow over Artemia nauplii. Using a combination of morphometric observations and geochemical analysis of the foraminiferal tests, we demonstrate that some specimens of both species grew new chambers while in culture, whereas other individuals added a calcite crust to the final whorl. The G. menardii were cultured in 87 Sr-labeled seawater, and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) was used to verify the presence of laboratory-grown calcite. Our results shed light on the feeding behavior and growth patterns in these two upper-ocean species of non-spinose foraminifera. This study demonstrates the feasibility of conducting laboratory culture experiments with G. truncatulinoides and G. menardii collected via plankton tow in the open ocean.

Journal of Foraminiferal Research

Porphyry-type metallization and alteration at La Florida de Nacozari, Sonora, Mexico

Pervasive secondary biotite-rich mineral assemblages, characteristic of potassic alteration found in the cores of most commercial porphyry copper systems, are associated spatially with a conspicuous color and a geochemical anomaly at La Florida de Nacozari, Sonora. These composite biotite-magnetite assemblages, with or without actinolite, quartz, rutile, sphene, chalcopyrite, and pyrite assemblages, are primarily the result of early dispersed biotitic (EDB) alteration of andesite. The bulk of the near-surface copper in the area, however, was introduced later by the veins that cut the EDB-altered andesite. These late veins are distinguished by a quartz-calcite-chlorite&plusmn;laumontite&plusmn;chalcopyrite assemblage, and the chalcopyrite in these veins may reflect upward remobilization of deep EDB copper by fluids associated with the emplacement of nearby coarse-grained granite. Fluid-inclusion relations in the late veins suggest that their fluids were nonboiling and relatively dilute.

Sonora

Use of machine-processable field notes in a wilderness mapping project (Granite Fiords area), southeastern Alaska

For reconnaissance geologic mapping and mineral resource evaluation of the Granite Fiords wilderness study area, we developed and used a system of machine-processable field notes. Preprinted field forms standardize notes and serve as checklists that insure collection of all available data. The use of this system cut in half the time required to record data at an outcrop. The system consists of three related but different types of preprinted field sheets, a key to abbreviations and codes, and a set of written instructions. The field sheets include a station sheet for basic outcrop data, a specimen sheet for rock samples, and a geochemical sheet for materials to be chemically analyzed. Data on the field sheets are keypunched on standard IBM cards, then arranged in subfiles and retrieved by using a card sorter. Our system is designed specifically for a region of granitic and metamorphic rocks but is easily modified for use in different geologic terranes. We offer four guidelines for developing a system of machine-processable field notes: (1) Time and money spent to develop the system must be worth its anticipated benefits. (2) The system should be as flexible as possible. (3) It is necessary to tailor the system to a particular geologic terrane or project objective. (4) The system should be as simple and self-explanatory as possible.

Alaska

Dissolution of fluorapatite by Pseudomonas fluorescens P35 resulting in fluorine release

Chemical weathering of fluorine-bearing minerals is widely accepted as the main mechanism for the release of fluorine (F) to groundwater. Here, we propose a potential mechanism of F release via microbial dissolution of fluorapatite (Ca 5 (PO 4 ) 3 F), which has been neglected previously. Batch culture experiments were conducted at 30°C with a phosphate-solubilizing bacteria strain, Pseudomonas fluorescens P35, and rock phosphates as the sole source of phosphate for microbial growth in parallel with abiotic controls. Rock phosphates consisted of 55–91% of fluorapatite and 5–10% of dolomite before microbial dissolution as indicated by X-ray diffraction (XRD). Mineral composition and morphology changed after microbial dissolution characterized by the disappearance of dolomite and the development of etched cavities on rock phosphate surfaces. The pH of media used was approximately 7.4 at the beginning and increased gradually to 7.7 in abiotic controls; with the inoculum, the pH decreased to acidic values of 3.7–3.8 after 27 h. Phosphate, calcium, and fluoride were released from the rock phosphate to the acidified medium. At 42 h, the concentration of F reached 8.1–10.3 mg L −1 . The elevated F concentration was two times higher than the F levels in groundwater in regions diagnosed with fluorosis, and was toxic to the bacteria, as demonstrated by a precipitous decrease in live cells. Geochemical modeling demonstrated that the oxidation of glucose (the carbon source for microbial growth in the medium) to gluconic acid could decrease the pH to 3.7–3.8 and result in the dissolution of fluorapatite and dolomite. Dolomite and fluorapatite remained unsaturated, while concentrations of dissolved phosphorus (P), calcium (Ca), and F increased throughout the time course Fluorite reached saturation [saturation index (SI) 0.22–0.42] after 42 h in rock phosphate–amended biotic systems. However, fluorite was not detected in XRD patterns of the final residue from microcosms. Given that phosphate-solubilizing bacteria are ubiquitous in soil and groundwater ecosystems, they could play an important role in fluorapatite dissolution and the release of F to groundwater.

Geomicrobiology Journal

Reevaluating the age of the Walden Creek Group and the kinematic evolution of the western Blue Ridge, southern Appalachians

An integrated synthesis of existing datasets (detailed geologic mapping, geochronologic, paleontologic, geophysical) with new paleontologic and geochemical investigations of rocks previously interpreted as part of the Neoproterozoic Walden Creek Group in southeastern Tennessee suggest a necessary reevaluation of the kinematics and structural architecture of the Blue Ridge Foothills. The western Blue Ridge of Tennessee, North Carolina, and Georgia is composed of numerous northwest-directed early and late Paleozoic thrust sheets, which record pronounced variation in stratigraphic/structural architecture and timing of metamorphism. The detailed spatial, temporal, and kinematic relationships of these rocks have remained controversial. Two fault blocks that are structurally isolated between the Great Smoky and Miller Cove-Greenbrier thrust sheets, here designated the Maggies Mill and Citico thrust sheets, contain Late Ordovician-Devonian conodonts and stable isotope chemostratigraphic signatures consistent with a mid-Paleozoic age. Geochemical and paleontological analyses of Walden Creek Group rocks northwest and southeast of these two thrust sheets, however, are more consistent with a Late Neoproterozoic (550&ndash;545 Ma) depositional age. Consequently, the structural juxtaposition of mid-Paleozoic rocks within a demonstrably Neoproterozoic-Cambrian succession between the Great Smoky and Miller Cove-Greenbrier thrust sheets suggests that a simple foreland-propagating thrust sequence model is not applicable in the Blue Ridge Foothills. We propose that these younger rocks were deposited landward of the Ocoee Supergroup, and were subsequently plucked from the Great Smoky fault footwall as a horse, and breached through the Great Smoky thrust sheet during Alleghanian emplacement of that structure.

North Carolina, Tennessee

Paleomagnetism of the Miocene intrusive suite of Kidd Creek: Timing of deformation in the Cascade arc, southern Washington

Paleomagnetic study of the intrusive suite of Kidd Creek in the southern Washington Cascades (23 sites in dikes and sills) was undertaken to help determine if these rocks are comagmatic and whether they postdate regional folding of the volcanic arc. Fission track and 40 Ar- 39 Ar age determinations indicate an age of ∼12.7 Ma (middle Miocene) for these rocks. The similarity of normal-polarity characteristic directions for most samples corroborate the available geochemical data indicating that these rocks are most likely comagmatic. Reversed-polarity directions for samples from four sites, however, show that emplacement of Kidd Creek intrusions spanned at least one reversal of the geomagnetic field. The paleomagnetic directions for the dikes and sills fail a fold test at the 99% confidence level indicating that the Kidd Creek rocks postdate regional folding. The mean in situ direction also indicates that the Kidd Creek and older rocks have been rotated 22°±6° clockwise about a vertical or near-vertical axis from the expected Miocene direction. Compression and regional folding of the Cascade arc in southern Washington therefore had ended by ∼12 Ma prior to the onset of deformation resulting in rotation of these rocks.

Journal of Geophysical Research B: Solid Earth