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Geophysical investigations in deep horizontal holes drilled ahead of tunnelling

Deep horizontal drill holes have been used since 1967 by the Defense Nuclear Agency as a primary exploration tool for siting nuclear events in tunnels at the Nevada Test Site. The U.S. Geological Survey had developed geophysical logging techniques for obtaining resistivity and velocity in these holes, and to date 33 horizontal drill holes in excess of 300 m in depth have been successfully logged. The deepest hole was drilled to a horizontal depth of 1125 m. The purposes of the logging measurements are to define clay zones, because of the unstable ground conditions such zones can present to tunnelling, and to define zones of partially saturated rock, because of the attenuating effects such zones have on the shock wave generated by the nuclear detonation. Excessive attenuation is undesirable because the shock wave is used as a tunnel closure mechanism to contain debris and other undesirable explosion products. Measurements are made by pumping resistivity, sonic and geophone probes down the drill string and out of the bit into the open hole. Clay zones are defined by the electrical resistivity technique based on empirical data relating the magnitude of the resistivity measurement to qualitative clay content. Rock exhibiting resistivity of less than 20 ??-m is considered potentially unstable, and resistivities less than 10 ??-m indicate appreciable amounts of clay are present in the rock. Partially saturated rock zones are defined by the measurement of the rock sound speed. Zones in the rock which exhibit velocities less than 2450 m/sec are considered of potential concern. ?? 1980.

International Journal of Rock Mechanics and Mining

Pb-Sr-Nd isotopes in surficial materials at the Pebble Porphyry Cu-Au-Mo Deposit, Southwestern Alaska: can the mineralizing fingerprint be detected through cover?

The Cretaceous Pebble porphyry Cu-Au-Mo deposit is covered by tundra and glacigenic sediments. Pb-Sr-Nd measurements were done on sediments and soils to establish baseline conditions prior to the onset of mining operations and contribute to the development of exploration methods for concealed base metal deposits of this type. Pebble rocks have a moderate range for 206 Pb/ 204 Pb = 18.574 to 18.874, 207 Pb/ 204 Pb = 15.484 to 15.526, and 208, Pb/ 204 Pb = 38.053 to 38.266. Mineralized granodiorite shows a modest spread in 87 Sr/ 86 Sr (0.704354–0.707621) and 143 Nd/ 144 Nd (0.512639–0.512750). Age-corrected (89 Ma) values for the granodiorite yield relatively unradiogenic Pb (e.g., 207 Pb/ 204 Pb <15.52), low values of 87 Sr/ 86 Sr, and positive values of ɛNd (1.00–4.52) that attest to a major contribution of mantle-derived source rocks. Pond sediments and soils have similar Pb isotope signatures and 87 Sr/ 86 Sr and 143 Nd/ 144 Nd values that resemble the mineralized granodiorites. Glacial events have obscured the recognition of isotope signatures of mineralized rocks in the sediments and soils. Baseline radiogenic isotope compositions, prior to the onset of mining operations, reflect natural erosion, transport and deposition of heterogeneous till sheets that included debris from barren rocks, mineralized granodiorite and sulfides from the Pebble deposit, and other country rocks that pre- and postdate the mineralization events. Isotopic variations suggest that natural weathering of the deposit is generally reflected in these surficial materials. The isotope data provide geochemical constraints to glimpse through the extensive cover and together with other geochemical observations provide a vector to concealed mineralized rocks genetically linked with the Pebble deposit.

Alaska

The lead-zinc veins of the chilete mining district in northern Peru

Lead-zinc-silver veins in the Chilete mining district in the Department of Cajamarca in northern Peru have been worked sporadically since the 17th century, but the greatest activity dates only from 1951. The ore deposits are in a thick section of andesitic volcanic rocks that overlie with marked unconformity a sequence of Cretaceous limestone, shale, and quartz-ite. The volcanic rocks form a gently north-dipping block of apparently simple structure. The Chilete deposits are quartz-sulfide veins consisting essentially of sphalerite, pyrite, and galena in a gangue of quartz and silici-fied and pyritized andesite. Wall rocks are calcitized, chloritized, pyrit-ized, and sericitized. The veins were formed by fissure filling, breccia filling, and replacement. Veins strike either northwest or east-northeast and dip steeply. They range from a few centimeters to 4 m in width and the longest has a strike length of about 1,700 m. The veins are eut by a number of post-mineral strike-slip faults of small displacement. Thicker sections of the principal northwest-striking vein, Murcielago, tend to occur where the strike swings slightly to the north. Vein intersections are not favorable loci for ore deposition, and several intersections seem to be dis-tinctly unfavorable. Ail the veins have roughly the same combined content of lead and zinc at ail levels, but the proportion of zinc to lead increases notably at the lowest levels of exploration, 200-250 m below the outerops. © 1955 Society of Economic Gelogists, Inc.

Economic Geology

The geology and mineral deposits of part of the western half of the Hailey 1 degree x 2 degrees quadrangle, Idaho

Rocks in the western half of the Hailey 1°x2° quadrangle of south-central Idaho include various units of the Atlanta lobe of the Idaho batholith (biotite granodiorite to two-mica granite) of Cretaceous age and plutons and dikes of Tertiary (Eocene to Miocene) age that intrude the batholith. Eocene plutonic rocks consist of a bimodal suite of anorogenic granite and tonalite-granodiorite and hypabyssal rhyolite and rhyodacite dikes. Rocks of the Eocene Challis Volcanics are scarce in the map area but are widespread to the east. Rhyolite ash flows of the Miocene Idavada Volcanics and basalt of the Snake River Plain crop out in the southern part of the area. Lacustrine rocks of probable Eocene to Holocene age are present in the vicinity of Anderson Ranch Reservoir. Quaternary basalts and gravels are widespread on the South Fork of the Boise River, and alluvial deposits are common along active drainages. Metasedimentary rocks of unknown age crop out on House Mountain, Chimney Peak, and on the ridges east of Anderson Ranch Reservoir. Older structures in the Idaho batholith include a major fault beneath House Mountain that may be a decollement for one of the large thrust sheets in eastern Idaho or part of an extensional core complex. The southern part of the Atlanta lobe of the Idaho batholith is cut by northeast-striking faults (parallel with the Trans-Challis fault system) that are related to Eocene extension and by northwest-oriented faults that formed during basin and range extension in the Miocene. The basin and range faults have prominent scarps typical of basin and range topography. The combination of northeast and northwest faults has broken the batholith into a series of rhomboid blocks. Some of these northeast and northwest faults are older structures that were reactivated in the Eocene or Miocene, as indicated by Ar 40 /Ar 39 dates on mineralized rock contained in some of the structures. The Idaho batholith and associated rocks in the map area host several hundred mines and prospects in 18 mining districts. The deposits range in age from Cretaceous to Eocene, and many were developed for precious metals. Most of the deposits are in quartz veins in shear zones in granitic rocks of the batholith. Several districts were actively being explored for low-grade, bulk-minable, precious-metal deposits in the late 1980s and early 1990s.

Idaho

The Glacier National Park: A popular guide to its geology and scenery

The Glacier National Park includes that part of the Front Range of the Rocky Mountains lying just south of the Canadian line, in Teton and Flathead counties, Mont. It is bounded on the west by Flathead River (locally called North Fork), on the south by the Middle Fork of Flathead River and the Great Northern Railway, and on the east by the Blackfeet Indian Reservation. Although this part of the Rocky Mountains has been known since Lewis and Clark crossed the continent in 1805-6, the region later made a park appears not to have been visited by white men until 1853, when Cut Bank Pass was crossed by A. W. Tinkham, one of the Government engineers engaged in exploring a route for the Pacific railroad. Tinkham, who was encamped in the Bitterroot Valley, was ordered to examine Marias Pass, but in traversing Middle Fork of Flathead River along the line of the present railroad he was evidently misled by the large size of the valley of Nyack Creek and ascended that instead of keeping to the right up the main stream. He reported the pass impracticable for railroad construction, and so this region dropped out of public attention for a long time. The next explorers to enter the region were a group of surveyors who, under the direction of American and British commissioners, established the international boundary line along the forty-ninth parallel from the Pacific coast to the main summit of the Rocky Mountains. This party reached the area now included in the park in the summer of 1861, and the stone monument shown in Plate I, B, which they erected on the Continental Divide west of Waterton Lake, still marks a point on the boundary between the United States and Canada. The land on the west side of the range formed a part of the public domain which, until the erection of the park, was open to settlement, but the land on the east originally belonged to the Blackfeet Indians and the white men had no rights upon it. About 1890 copper ore was found near the heads of Quartz and Mineral creeks, and a great boom for this region followed. Many prospectors drifted in, expecting to reap rich rewards from the discovery of mineral deposits and the general development of the region. Several of the main trails were built about this time, and considerable money was spent in prospecting, in opening mines, and in providing machinery to handle the large output of copper ore that was expected. The copper-bearing veins were found to extend through the range to the east side, but prospecting in that part of the mountains was not possible, for the land was included in the Indian reservation. This situation produced a growing discontent among the prospectors, who began to have a strong feeling that the Government should come to their relief by acquiring the coveted land and placing it at their disposal. The urgent demand of the prospectors and promoters was felt in Congress, and a bill was passed providing for the purchase from the Indians of this supposed mineral land for $1,500,000. In accordance with this act, a treaty with the Blackfeet Indians was signed at Browning, Mont., September 26, 1895, and approved by the Senate on June 10, 1896, by which the west line of the reservation was removed from the Continental Divide and was fixed along the eastern points of the spurs of the mountain range, as shown on the accompanying map, and the land so acquired was thrown open to mineral entry only. Under the stimulus of the new territory acquired, active prospecting was carried on for a time, but copper ore was found only in small quantities, and gradually the prospectors and miners drifted away to newer or more promising fields, and the region reverted to its original condition. For a long time it was visited only by hunters in search of big game and by summer visitors who, in order to escape the heat of the plains, were willing to undergo the privations and discomforts of the rude hotels then to be found in the region. Although these mountains had ceased to interest prospectors in search of mineral wealth, they still possessed a fascination for the lovers of natural scenery and almost everyone who visited the region was impressed with its alpine beauty. Again it was brought to the attention of Congress, which was urged to secure it for the use of the people by setting it aside as a national park. On May 11, 1910, President Taft signed the bill creating the Glacier National Park, and this most interesting and beautiful region thus became a permanent playground for the American people.

Bulletin

Arsenic and mercury contamination related to historical goldmining in the Sierra Nevada, California

Arsenic (As) is a naturally occurring constituent in low-sulphide gold-quartz vein deposits, the dominant deposit type for lode mines in the Sierra Nevada Foothills (SNFH) gold (Au) province of California. Concentrations of naturally occurring mercury (Hg) in the SNFH Au province are low, but extensive use and loss of elemental Hg during amalgamation processing of ore from lode and placer Au deposits led to widespread contamination of Hg in the Sierra Nevada foothills and downstream areas, such as the Sacramento–San Joaquin Delta and San Francisco Bay. This review paper provides an overview of As and Hg contamination related to historical Au mining in the Sierra Nevada of California. It summarizes the geology, mineralogy, and geochemistry of the Au deposits, and provides information on specific areas where detailed studies have been done in association with past, ongoing, and planned remediation activities related to the environmental As and Hg contamination. Arsenic is a naturally occurring constituent in low-sulphide Au-quartz vein deposits, the dominant deposit type for lode mines in the Sierra Nevada Foothills (SNFH) Au province ( Ashley 2002 ). Because of elevated concentrations of As in accessory iron-sulphide minerals including arsenopyrite (FeAsS) and arsenian pyrite (Fe(S,As) 2 ), As is commonly a contaminant of concern in lode Au mine waste, including waste rock and mill tailings. The principal pathways of human As exposure from mine waste include ingestion of soil or drinking water, and inhalation of dust in contaminated areas ( Mitchell 2014 ). Concentrations of naturally occurring Hg in the SNFH Au province are low, but extensive use and loss of elemental Hg during amalgamation processing of ore from lode and placer Au deposits ( Churchill 2000 ) led to widespread contamination of Hg in the Sierra Nevada foothills and downstream areas, such as the Sacramento–San Joaquin Delta and San Francisco Bay ( Alpers et al. 2005 a ). Conversion of Hg to monomethylmercury (MeHg) by sulphate-reducing and iron-reducing microbes facilitates its bioaccumulation ( Wiener et al. 2003 ). The human Hg exposure pathway of main concern is ingestion of MeHg from sport (non-commercial) fish, especially higher trophic levels such as bass species ( Davis et al. 2008 ). Wildlife exposure to MeHg is also a concern because of chronic and reproductive effects, for example in fish-eating and invertebrate-foraging birds (e.g. Wiener et al. 2003 ; Eagles-Smith et al. 2009 ; Ackerman et al. 2016 ).

California

Hydrogeology of the Cliff House Sandstone in the San Juan structural basin, New Mexico, Colorado, Arizona, and Utah

This report is one in a series resulting from the U.S. Geological Survey's Regional Aquifer-System Analysis (RASA) study of the San Juan structural basin that began in October 1984. Previous reports in the series describe the hydrogeology of the Dakota Sandstone (Craigg and others, 1989), Point Lookout Sandstone (Craigg and others, 1990), Morrison Formation (Dam and others, 1990), Gallup Sandstone (Kernodle and others, 1989), and Menefee Formation (Levings and others, 1990) in the San Juan structural basin. The purposes of the RASA (Welder, 1986) are to: (1) Define and evaluate the aquifer system; (2) assess the effects of past, present, and potential ground-water use on aquifers and streams; and (3) determine the availability and quality of ground water. This report summarizes information on the geology and the occurrence and quality of water in the Cliff House Sandstone, one of the primary water-bearing units in the regional aquifer system. Data used in this report were collected during the study or were derived from existing records in the U.S. Geological Survey's computerized National Water Information System (NWIS) data base, the Petroleum Information Corporation's data base, and the Dwight's ENERGYDATA Inc. BRIN data base. Although all data available for the Cliff House Sandstone were considered in formulating the discussions in the text, not all those data could be plotted on the illustrations. The San Juan structural basin is in New Mexico, Colorado, Arizona, and Utah and has an area of about 21,600 square miles (fig. 1). The structural basin is about 140 miles wide and about 200 miles long. The study area is that part of the structural basin that contains rocks of Triassic or younger age and, therefore, is less extensive than the structural basin. Triassic through Tertiary sedimentary rocks are emphasized in this study because the major aquifers in the basin are present in these rocks. The study area is about 140 miles wide (about the same as the structural basin), 180 miles long, and has an area of about 19,400 square miles. Altitudes in the study area range from about 4,500 feet in San Juan County, Utah, to about 11,000 feet in Cibola County, New Mexico. Annual precipitation in the high mountainous areas along the north and east margins of the basin is as much as 45 inches, whereas annual precipitation in the lower altitude, central basin is generally less than 8 inches. Mean annual precipitation in the study area is about 12 inches. Data obtained from documents published by the U.S. Bureau of the Census, 1980 and 1985, were used to estimate the population of the study area. The population of the study area in 1970 was estimated to be about 134,000. The population rose to about 194,000 in 1980, 212,000 in 1982, 221,000 in 1984, and then fell to about 210,000 in 1985. The economy of the basin is supported by exploration and development of petroleum, natural gas, coal, and uranium resources; urban enterprise, farming and ranching; tourism; and recreation. The rise and fall in population were related to changes in the economic strength of the mining, petroleum, and natural-gas industries, and support services. Uranium mining and milling activities grew rapidly until the late 1970's when most uranium-mining activity ended in the study area. Likewise, the oil and gas industry prospered until about 1983 and then declined rapidly, also affecting many jobs in support industries.

Arizona, Colorado, New Mexico, Utah

Hydrogeology of the Point Lookout Sandstone in the San Juan structural basin, New Mexico, Colorado, Arizona, and Utah

This report is one in a series resulting from the U.S. Geological Survey's Regional Aquifer-System Analysis (RASA) study of the San Juan structural basin that began in October 1984. Previous reports in the series describe the hydrogeology of the Dakota Sandstone (Craigg and others, 1989), Morrison Formation (Dam and others, 1990), Gallup Sandstone (Kernodle and others, 1989), Menefee Formation (Levings and others, 1990), and Cliff House Sandstone (Thorn and others, 1990), in the San Juan structural basin. The purposes of the RASA (Welder, 1986) are to: (1) Define and evaluate the aquifer system; (2) assess the effects of past, present, and potential ground-water use on aquifers and streams; and (3) determine the availability and quality of ground water. This report summarizes information on the geology and the occurrence and quality of water in the Point Lookout Sandstone, one of the primary water-bearing units in the regional aquifer system. Data used in this report were collected during the study or were derived from existing records in the U.S. Geological Survey's computerized National Water Information System (NWIS) data base, the Petroleum Information Corporation's database, and the Dwight's ENERGYDATA Inc. BRIN data base. Although all data available for the Point Lookout Sandstone were considered in formulating the discussions in the text, not all those data could be plotted on the illustrations. The San Juan structural basin is in New Mexico, Colorado, Arizona, and Utah and has an area of about 21,600 square miles (fig. 1). The structural basin is about 140 miles wide and about 200 miles long. The study area is that part of the structural basin that contains rocks of Triassic or younger age and, therefore, is less areally extensive than the structural basin. Triassic through Tertiary sedimentary rocks are emphasized in this study because the major aquifers in the basin are present in these rocks. The study area is about 140 miles wide (about the same as the structural basin), 180 miles long, and has an area of about 19,400 square miles. Altitudes in the study area range from about 4,500 feet in San Juan County, Utah, to about 11,000 feet in Cibola County, New Mexico. Annual precipitation in the high mountainous areas along the north and east margins of the basin is as much as 45 inches, whereas annual precipitation in the lower altitude, central basin is generally less than 8 inches. Mean annual precipitation in the study area is about 12 inches. Data obtained from documents published by the U.S. Bureau of the Census, 1980 and 1985, were used to estimate the population of the study area. The population of the study area in 1970 was estimated to be about 134,000. The population rose to about 194,000 in 1980, 212,000 in 1982, 221,000 in 1984, and then fell to about 210,000 in 1985. The economy of the basin is supported by exploration and development of petroleum, natural gas, coal, and uranium resources; urban enterprise, farming "and ranching; tourism; and recreation. The rise and fall in population were related to changes in the economic strength of the mining, petroleum, and natural-gas industries, and support services. Uranium mining and milling activities grew rapidly until the late 1970's when most uranium-mining activity ended in the study area. Likewise, the oil and gas industry prospered until about 1983 and then declined rapidly, also affecting many jobs in support industries.

Arizona, Colorado, New Mexico, Utah

Evolution of the Creede Caldera and its relation to mineralization in the Creede mining district, Colorado

At 25 Ma a major epithermal silver and base metal deposit formed in rhyolitic welded tuff near Creede, Colorado. Nearly 24000 metric tons of silver, appreciable lead, and small amounts of zinc, copper, and gold, have been produced from large, crustified veins under Bachelor and Bulldog Mountains north and northwest of Creede. Prior geologic, hydrologic, and stable-isotope studies showed that ore deposition was associated with the mixing and boiling of waters from diverse sources and suggester that a critical part of the ore-forming fluid may have originated within the ancient lake and sediments of the lacustrine Creede Formation that filled the Creede caldera. Two drill holes that sampled the heretofore hidden lower half of the Creede Formation are the focus of this book. The Creede caldera formed at 26.9 Ma within a high constructional plateau of silicic ashflows that covered and were sporadically interlayed with, intermediate lavas and lahars from large stratovolcanoes. The Creede caldera lake had an inflow evaporation balance that did not permit rapid filling to create a brim-full deep lake. Thus salts were evaporatively concentrated; but, with the exception of possible gypsum, no evaporite minerals preserved. Cool springs deposited travertine as mounds and contributed to limestone interlaminations within the sediment. The lake bottom was anoxic, and bacterial reduction of sulfate led to extreme sulfur isotopic fractionation in diagenetic pyrite. The caldera gradually resurged, converting the initial equant lake into an arcuate moat. Resurgent doming, alluvial fans, lacustrine sediments, ashfalls, and lava domes displaced water, lifted the lake so that it overlapped what later became the southern edge of the mineralized are, and eventually filled the basin. At 25.1 Ma an unseen pluton intruded beneath the northen part of the Creede district and created a convecting olume that drew in brine from the Creede caldera fill, meteotic water from highlands to the north, and possibly a fluid carrying radiogenic lead. These waters mixed and boiled as they approached the surface and moved southward, deposited a zoned epithermal deposit a few hundred meters below the paleosurface, and finally discharged into the top of the Creede Formation. The sulfide in the ores was the igneous derivation, but the sulfate was a mixture of biogenic sulfur from the Creede Formation, oxidized igneous sulfide, and thermochemically reduced and partially oxygen exchanged sulfate. The studies of the Creede caldera provide key observational and conceptual elements for the generalized model of the Creede ore deposit. The relation of the Creed ore deposit to a brine reservoir has broad significance because other brine accumulations (as in the Great Basin, the Green River Basin, or the playas of the Altiplano offer similar setting and exploration opportunities.

Colorado

Surface-water quality in the Lycoming Creek watershed, north-central Pennsylvania, August 1–3, 2011

This report presents the methodology and results for a study of surface-water quality of the Lycoming Creek watershed in north-central Pennsylvania during August 1–3, 2011. The study was done in cooperation with the Williamsport Municipal Water Authority and the Pennsylvania Department of Environmental Protection. Samples of stream water were collected from 31 sites in an area of exploration and production of natural gas from the Marcellus Shale – 5 sites on the main stem of Lycoming Creek and 26 sites on tributary streams. The samples provide a snapshot of the base-flow water-quality conditions, which helps document the spatial variability in water-quality and could be useful for assessing future changes. The 272-square mile Lycoming Creek watershed is located within Lycoming, Tioga, and Sullivan Counties in north-central Pennsylvania. Lycoming Creek flows 37.5 miles to its confluence with the West Branch Susquehanna River in the city of Williamsport. A well field that supplies water for Williamsport captures some water that has infiltrated the streambed of Lycoming Creek. Because the stream provides a source of water to the well field, this study focused on the stream-water quality as it relates to drinking-water standards as opposed to aquatic life. Surface-water samples collected at 20 sites by the U.S. Geological Survey and 11 sites by the Pennsylvania Department of Environmental Protection were analyzed by each agency for a suite of constituents that included major ions, trace metals, nutrients, and radiochemicals. None of the analytical results failed to meet standards set by the U.S. Environmental Protection Agency as maximum contaminant levels for drinking water. Results of the sampling show the substantial spatial variability in base-flow water quality within the Lycoming Creek watershed caused by the interrelated effects of physiography, geology and land use. Dissolved-solids concentrations ranged from less than the laboratory reporting level of 12 milligrams per liter (mg/L) in Wolf Run, a pristine forested watershed, to 202 mg/L in Bottle Run, a watershed with more development near Williamsport. Concentrations of the major ions ranged over at least one order of magnitude; chloride had the largest range from 0.3 to 45.4 mg/L, with nine samples exceeding the natural background level of about 5 mg/L, most likely because of the application of deicing salt to roads. Trace constituents were even more variable, with concentrations for aluminum, cobalt, and manganese ranging over almost four orders of magnitude. Samples from Red Run and Dutchman Run, watersheds that experienced past coal mining activity, had concentrations of 11 metals that were significantly greater than in samples collected from other streams. Samples from Bottle Run, the tributary of Lycoming Creek nearest to Williamsport, contained elevated levels of chloride and boron, constituents associated with urban development.

Pennsylvania

Hydrogeology of the Pictured Cliffs Sandstone in the San Juan structural basin, New Mexico, Colorado, Arizona, and Utah

This report is one in a series resulting from the U.S. Geological Survey's Regional Aquifer System Analysis (RASA) study of the San Juan structural basin that began in October 1984. The purposes of the study (Welder, 1986) are to: (1) Define and evaluate the aquifer system; (2) assess the effects of past, present, and potential ground-water use on aquifers and streams, and (3) determine the availability and quality of ground water. Previous reports in this series describe the hydrogeology of the Dakota Sandstone (Craigg and others, 1989), Gallup Sandstone (Kernodle and others, 1989), Morrison Formation (Dam and others, 1990), Point Lookout Sandstone (Craigg and others, 1990), Kirtland Shale and Fruitland Formation (Kernodle and others, 1990), Menefee Formation (Levings and others, 1990), Cliff House Sandstone (Thorn and others, 1990), and Ojo Alamo Sandstone (Thorn and others, 1990) in the San Juan structural basin. This report summarizes information on the geology and the occurrence and quality of water in the Pictured Cliffs Sandstone, one of the primary water-bearing units in the regional aquifer system. Data used in this report were collected during the RASA study or derived from existing records in the U.S. Geological Survey's computerized National Water Information System (NWIS) data base, the Petroleum Information Corporation's data base, and the Dwight's ENERGYDATA Inc. BRIN database. Although all data available for the Pictured Cliffs Sandstone were considered in formulating the discussions in the text, not all those data could be plotted on the illustrations. The San Juan structural basin in New Mexico, Colorado, Arizona, and Utah has an area of about 21,600 square miles (fig. 1). The structural basin is about 140 miles wide and about 200 miles long. The study area is that part of the structural basin that contains rocks of Triassic and younger age; therefore, the study area is less extensive than the structural basin. Triassic through Tertiary sedimentary rocks are emphasized in this study because these units are the major aquifers in the basin. The study area is about 140 miles wide (about the same as the structural basin), 180 miles long, and has an area of about 19,400 square miles. Altitudes in the study area range from about 4,500 feet in southeastern Utah, to about 11,000 feet in the southeastern part of the basin. The area-weighted mean altitude is about 6,700 feet. Annual precipitation in the high mountainous areas along the north and east margins of the basin is as much as 45 inches, whereas annual precipitation in the lower altitude, central basin is generally less than 8 inches. Mean annual precipitation is about 12 inches. Data obtained from documents published by the U.S. Bureau of the Census (1980 and 1985) were used to calculate the population of the study area. The population in 1970 was calculated to be about 134,000. The population increased to about 194,000 in 1980,212,000 in 1982,221,000 in 1984, and then declined to about 210,000 in 1985. The economy of the basin is supported by exploration and development of natural gas, petroleum, coal, and uranium resources; urban enterprise; farming and ranching tourism, and recreation. The rise and fall in population were related to changes in the economic strength of the minerals, oil, and gas industries, and support services. Uranium-mining and -milling activities underwent rapid growth until the late 1970's when most uranium-mining activity came to an abrupt end. Likewise, the oil and gas industry prospered until about 1983 and then declined rapidly.

Hydrologic Atlas

Ambient water quality in aquifers used for drinking-water supplies, Gem County, southwestern Idaho, 2015

In recent years, the rapid population growth in Gem County, Idaho, has been similar to other counties in southwestern Idaho, increasing about 54 percent from 1990 to 2015. Because the entire population of the study area depends on groundwater for drinking water supply (either from self-supplied domestic, community, or municipal-supply wells), this population growth, along with changes in land use (including potential petroleum exploration and development), indicated to the public and local officials the need to assess the quality of groundwater used for human consumption. To this end, the U.S. Geological Survey, in cooperation with Gem County and the Idaho Department of Environmental Quality, assessed the quality of groundwater from freshwater aquifers used for domestic supply in Gem County. A total of 47 domestic or municipal wells, 1 spring, and 2 surface-water sites on the Payette River were sampled during September 8–November 19, 2015. The sampled water was analyzed for a variety of constituents, including major ions, trace elements, nutrients, bacteria, radionuclides, dissolved gasses, stable isotopes of water and methane, and either volatile organic compounds (VOCs) or pesticides. To better understand analytical results, a conceptual hydrogeologic framework was developed in which three hydrogeologic units were described: Quaternary-Tertiary deposits (QTd), Tertiary Idaho Group rocks (Tig), and Tertiary-Cretaceous igneous rocks (TKi). Water levels were measured in 30 wells during sampling, and a groundwater-level altitude map was constructed for the QTd and Tig units showing groundwater flow toward the Emmett Valley and Payette River. Analytical results indicate that groundwater in Gem County is generally of good quality. Samples collected from two wells contained water with fluoride concentrations greater than the U.S. Environmental Protection Agency (EPA) Maximum Contaminant Level (MCL) of 4 milligrams per liter (mg/L), six wells contained arsenic at concentrations greater than the EPA MCL of 10 micrograms per liter, and a sample from one well exceeded the MCL of 15 picocuries per liter for alpha particles. Although previous samples collected from some wells in Gem County contained nitrate concentrations greater than the MCL of 10 mg/L, the largest concentration detected in the current study was 5.2 mg/L. Total coliform bacteria was detected in four groundwater samples. Three volatile organic compounds (VOCs) were detected in samples collected from five wells, and five compounds of the triazine class of herbicides were detected in samples from five wells; no concentrations were greater than applicable EPA MCLs. Methane was detected in samples from 36 wells, with the concentration in 1 well large enough to be considered an explosion hazard by U.S. Office of Surface Mining guidelines. Stable isotope signatures of methane in six samples suggest that naturally occurring methane in Gem County is probably of both thermogenic and biogenic origin.

Idaho

Geology and mineral resources of central Antioquia Department (Zone IIA), Colombia

This report summarizes the geology of an area of some 6000 square kilometers in the northern part of the Central Cordillera of the Colombian Andes. The area, in north-central Department of Antioquia, was mapped between 1964 and 1968 as part of the Inventario Minero Nacional (IMN) project. Mineral resources are summarized within a larger area, designated as subzone ILK of IMN Zone If, which comprises almost 22,000 sq. kin, including the area mapped geologically by IMN and additional areas mapped by other agencies. The oldest formation is a micaceous paragneiss of early Paleozoic or possibly late Precambrian age. A thick geosynclinal sedimentary series accumulated during the Paleozoic Era and became regionally metamorphosed to greenschist (locally amphibolite) facies during the Permian or early Triassic; these schists and gneisses are designated collectively as the Valdivia Group. The Permian(?) orogenic episode included intrusion of concordant syntectonic plutons, mostly of tonalitic composition. Rocks of unequivocal Triassic or Jurassic age are not recognized. The Cretaceous is well represented by both igneous and sedimentary assemblages. Eugeosynclinal alpine ophiolites comprising submarine basalt flows and numerous intrusions of gabbro and serpentinite are prominent in the Lower Cretaceous, together with flysch composed of marine shale and lesser sandstone and conglomerate. The Upper Cretaceous is represented along the west border of the mapped area by submarine basalt flows and pyroclastic rocks, locally Interbedded with fine-grained clastic sedimentary beds, and lenses of dark laminated chert, at least part of which is radiolarian. The Late Cretaceous was marked by an orogenic event that profoundly folded and faulted all rocks and in the Central Cordillera caused low-grade metamorphism, the overprint of which is hardly observable in pre-Cretaceous rocks elsewhere. The Late Cretaceous orogeny culminated with discordant intrusion of the epizonal tonalitic Antioquian batholith. Displacement along the great Romeral wrench fault may have begun in the Cretaceous. Plutonism continued into the Cenozoic, exemplified by the hornblende-diorite Sabanalarga pluton. Intermontane basins were filled with molasse derived from the erosion of adjacent highlands; Tertiary sedimentation in marshy areas included organic carboniferous matter subsequently converted to lignite or subbituminous coal. The Sabanalarga fault system originated in the Late Tertiary; intermittent displacement continued on the older wrench faults such as the Romeral. Epeirogenic uplift, which probably began in the Pliocene and continued through the Pleistocene and Holocene, brought on renewed erosion which has sculptured the mountains into their present form. Mineral resources in subzone IIA are varied but not of outstanding importance. Gold and silver mining, significant in past centuries, is minor today. Ferruginous laterite on serpentinite once considered as a potential source of iron ore is not economically exploitable. IMN has explored nickeliferous laterite at the extreme northwest corner of subzone IIA; this is a potential resource, exploitable only after exhaustion of the larger and richer nickel laterite deposit at Cerro Matoso, farther to the north and outside the boundaries of Zone If. Known deposits of mercury, chromium, manganese, and copper are small, with limited economic potential. Nonmetallic resources include raw materials for cement, including portland cement. Saprolite clay is widely used in making common red brick and tile, still a dominant construction material in all but the most modern multistory buildings. Aggregate materials are varied and abundant. Kaolin of good quality near La Union is important as a ceramic raw mineral filler. Tertiary subbituminous coal beds are an important energy resource in western subzone IIA, and have a good potential for greater development. Deposits of sodic feldspar, talc, decorative stone, and silica a

Open-File Report

Geology of the lead-silver deposits of the Clark Fork district, Bonner County, Idaho

This report gives the results of a reinvestigation of the lead-silver deposits of the Clark Fork district, Bonner County, Idaho, which since the late twenties have been the most important producers of lead-silver ore in northern Idaho outside of the Coeur d'Alene district, their production up to the end of 1941 having been more than $1,200,000. The deposits closely resemble those in the Coeur d'Alene district. They are fillings and replacements along minor low-angle thrust and high-angle reverse faults, which genetically are related to the Hope fault, a great transverse earth fracture, which provides the same sort of structural background for this district that the famous Osburn fault does for the Coeur d'Alene district. The deposits are contained in the Wallace and Striped Peak formations, members of the pre-Cambrian Belt series, and are closely associated with faulting and igneous activity that is probably of early Tertiary age. The mineralization has not been so extensive as in the Coeur d'Alene district, but the deposits, though comparatively small, are rich. Much of the ore is in compact seams and lenses a few inches thick, but stringers of ore and subordinate fractures along which grains of sulfide are disseminated extend across zones that are commonly 2 to 4 feet and exceptionally as much as 8 feet in width. The ore is mainly sulfide ore of the Coeur d'Alene type, consisting dominantly of galena, which is accompanied by lesser quantities of siderite, quartz, and sphalerite and by still smaller quantities of pyrite, arsenopyrite, tetrahedrite, and calcite. Some of the deposits, however, have been substantially enriched by the addition of hypogene silver and antimony minerals, so that much of the ore being mined has a higher silver content than any of that in the Coeur d'Alene district. The hypogene minerals include lead sulfantimonites and sulfarsenites, copper-lead sulfantimonites, and ruby silver. These minerals are absent from only one of the mines, and in one of the mines they form the bulk of the ore that is now being taken out. The high silver content of some of the ore is due in part to the presence of pyrargyrite (3Ag2S.SbS:4). The deposits apparently were formed at moderate depths and at moderate temperatures. It is believed that the ore will persist to depths appreciably greater than those yet reached in mining. The district has not yet been adequately explored, and undiscovered ore bodies may remain hidden beneath glacial and other surface debris.

Idaho

Investigations needed to stimulate the development of Jordan's mineral resources

The level of living that any society can attain is a direct function of the use it makes of all kinds of raw materials (soil, water, metals, nonmetals, etc.), all kinds of energy (both animate and inanimate), and all kinds of human ingenuity; and is an inverse function of the size of the population that must share the collective product. The relation between raw materials, energy and ingenuity is such that use of a large amount of one may offset the need for large amounts of others. The most vital raw materials are water, soil, and construction materials, for these are needed in large quantities and are hard to import. Metals, chemicals, and inanimate energy are necessary for industrialization. The more of these minerals a nation possess, the better, but not nation can hope to be self-sufficient in all of the m and therefore must trade for some essential materials. Jordan’s natural resources have been little explored. The grantitc-metamorphic terrane in the southeastern part of the Kingdom could contain deposits of tungsten, rare earths, feldspar, mica, fluorite etc. and the sedimentary terrane over much of the rest of the county is favorable for the occurrence of oil. Even if none of these minerals is found, however, Jordan’s other mineral resource, if fully explored and developed in the light of modern technology, will support a far higher level of living than her people now enjoy. Very likely she can increase her rainfall by about 10 percent by cloud seeding, and she undeveloped supplies in both surface and ground water that are sufficient to nearly double her usable water supply. Even if she does not have oil or have it in large quantities, she can buy it cheaply from neighboring counties, and in addition has undeveloped sources of hydroelectric power, large reserves of bituminous limestone, large reserves of nuclear power as uranium in phosphate rock, and can use solar and wind power for special purposes. Her large supplies of construction, fertilizer, and other chemical raw materials will not only satisfy her own needs, but will yield both raw materials and some manufactured products for export. And she has valuable resource of touristic interest in the form of incomparable scenery, antiquities, and holy places, which, if properly advertised, could well become her largest single source of foreign currency. Revenues obtained from this source and from the export of agricultural products, nonmetallic minerals, and mineral products should support foreign oil purchase of oil, machinery, and other products not mined or produced internally. Full development of Jordan’s economic potential will take years to achieve and involves many complex activities. One of the most essential is one that can be pressed in the early years, namely the gathering of facts and basic data concerning the character, extent, and distribution of her resources, and the uses that can be made of them. Without each fundamental data or the understanding of their meaning or the ways to use and apply them, costly developmental projects and similar efforts to raise the level of living are likely to have limited success at best. Basic data and mineral resources are best gathered and published by permanent government agencies, for private organizations and individual cannot afford to take the risks involved in gathering data that may not have an immediate economic return; and even if private parties do collect such data they are not likely to make them general available. Of the activities needed in the field of mineral resources, some are already underway as the established function of government agencies. No bureau however, seems to have responsibility for making geologic maps and for gathering data on such things as steam flow, composition and properties of minerals and rocks, or for investigating the uses to which Jordan’s minerals might be put. To satisfy these needs, a Geological Survey and a Bureau of Mineral Industries should be formed and placed in operation as quickly as possible. The task of collecting and interpreting basic data or mineral resources must be done largely by Jordanians, for only in this way will Jordan acquire the technical competence needed to use the information. Few Jordanians have enough training or experience to work independently in these fields now, however, so help from outside technicians would be necessary over an initial training period of several years. But the number of outside technicians should never exceed the number of Jordanian technicians, and for this reason, neither organization could have a staff of more than a few people during the early years of operation.

Open-File Report

Geochemistry of trace elements in coals from the Zhuji Mine, Huainan Coalfield, Anhui, China

The abundances of nine major elements and thirty-eight trace elements in 520 samples of low sulfur coals from the Zhuji Mine, Huainan Coalfield, Anhui, China, were determined. Samples were mainly collected from 10 minable coal seams of 29 boreholes during exploration. The B content in coals shows that the influence of brackish water decreased toward the top of coal seams; marine transgression and regression occurred frequently in the Lower Shihezi Formation. A wide range of elemental abundances is found. Weighted means of Na, K, Fe, P, Be, B, Co, Ni, Cr, Se, Sb, Ba, and Bi abundances in Zhuji coals are higher, and the remainder elements are either lower or equal to the average values of elements in coals of northern China. Compared to the Chinese coals, the Zhuji coals are higher in Na, K, Be, B, Cr, Co, Se, Sn, Sb, and Bi, but lower in Ti, P, Li, V and Zn. The Zhuji coals are lower only in S, P, V and Zn than average U.S. and world coals. Potassium, Mg, Ca, Mn, Sr, As, Se, Sb and light rare earth elements (LREE) had a tendency to be enriched in thicker coal seams, whereas Fe, Ti, P, V, Co, Ni, Y, Mo, Pb and heavy rare earth elements (HREE) were inclined to concentrate in thinner coal seams. The enrichment of some elements in the Shanxi or Upper Shihezi Formations is related to their depositional environments. The elements are classified into three groups based on their stratigraphic distributions from coal seams 3 to 11-2, and the characteristics of each group are discussed. Lateral distributions of selected elements are also investigated. The correlation coefficients of elemental abundances with ash content show that the elements may be classified into four groups related to modes of occurrence of these elements. ?? 2009 Elsevier B.V. All rights reserved.

International Journal of Coal Geology

Regional geochemical studies in the Patagonia Mountains, Santa Cruz County, Arizona

The Patagonia Mountains in southern Arizona contain the deeply buried porphyry copper system at Red Mountain as well as a number of other base- and precious-metal mines and prospects. The range contains complex Basin and Range geology with units ranging in age from Precambrian to Holocene. Rock types present include igneous intrusive and extrusive units as well as sedimentary and metamorphic units, most of which have been tectonically disturbed. A total of 264 stream-sediment samples were collected and analyzed for 32 elements. Geochemical maps for Sb, Ag, Pb, Te, B, Mn, Au, Zn, Cu (total), Cu (cold-extractable), and Mo, as well as for Cu (cold-extractable)/Cu (total) and Fe/Mn, are presented. Anomaly patterns for these elements generally occur over the Red Mountain deposit and (or) along a north-northwest trend parallel to the major Harshaw Creek Fault. Much of the entire area sampled contains widespread anomalies for Pb, Te, and Cu; the other elements are only locally anomalous. Various plots of ratios of Cu (cold-extractable) to Cu (total) did not produce any new information not readily apparent on either one of the two copper maps. A plot of ratios of Fe to Mn delineated many areas of pyrite mineralization. Several of these areas may represent the pyritic halos around deeply buried porphyry copper systems. The best ore guide for the Red Mountain porphyry system is the coincidence of positive anomalies of Mo, Pb, and Te and a negative anomaly of Mn. Other areas with anomalies of the same suite of elements are present within the Patagonia Mountains. It is concluded that geochemical sampling, even in a highly contaminated area, can be useful in delineating major geologic features, such as porphyry copper belts and major faults. Multielement geochemical surveys on a regional scale can effectively locate large, deeply buried, zoned mineral systems such as that at Red Mountain. Plots of element ratios, where adequately understood, can provide geochemical information not readily discernible from plots of single elements alone.

Arizona

Sulfur isotope study of the "B" limestone and Galena fissure ore deposits of the U.S. mine, Bingham mining district, Utah

The delta S 34 values for 261 sulfide concentrates from the "B" limestone replacement and Galena fissure deposits of the U. S. mine range from +3.8 to --8.0 permil; the mean is +0.56 permil. The data indicate that (1) sulfides of the "B" limestone ore deposits are depleted in S 34 by 0.4 to 0.7 permil relative to those of the Galena fissure ore deposits; (2) sulfides of both deposits exhibit a primary fractionation trend characterized by increasing S 34 depletion in the sequence pyrite, sphalerite, tetrahedrite, and galena; (3) delta values for coexisting sulfide pairs of the "B" limestone deposit increase with increasing altitude; (4) sulfides of both deposits are increasingly depleted in S 34 with increasing altitude; (5) the paragenetic order of sulfide deposition is accompanied by an apparent depletion of S 34 that is independent of mineral species; and (6) pyrite disseminated in wall rocks is depleted in S 34 relative to pyrite from adjacent ore deposits. The similarity of delta S 34 values and isotopic trends to those of the central porphyry-type deposit at Bingham (Field, 1966) suggests that the hydrothermal deposits of the district were formed by fluids that originated from a common source during one episode of sequential mineralization. Gross isotopic differences between the deposits, consistent differences between coexisting sulfides, and systematic variations of delta values are attributed to temperature effects imposed upon sulfide exchange equilibria; isotopic temperatures suggest a lateral gradient between the "B" limestone and adjacent Galena fissure deposits and a possible vertical gradient within the "B" limestone deposit. The vertical zonation of delta S 34 values and trends related to pyrite physical occurrence and sulfide paragenesis are provisionally attributed to a pH-Eh control. Although the apparent trends are imperfectly resolved because of textural complexities, the marked depletion of S 34 in pyrite disseminated in country rocks warrants additional study as a potential exploration method.

Utah