Geology ReportsSearch

SEARCH · Geology Reports

Results for “Clear Waters”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 271 records · Page 15Linked to original sources

Indicators of streamflow alteration, habitat fragmentation, impervious cover, and water quality for Massachusetts stream basins

Massachusetts streams and stream basins have been subjected to a wide variety of human alterations since colonial times. These alterations include water withdrawals, treated wastewater discharges, construction of onsite septic systems and dams, forest clearing, and urbanization—all of which have the potential to affect streamflow regimes, water quality, and habitat integrity for fish and other aquatic biota. Indicators were developed to characterize these types of potential alteration for subbasins and groundwater contributing areas in Massachusetts. The potential alteration of streamflow by the combined effects of withdrawals and discharges was assessed under two water-use scenarios. Water-use scenario 1 incorporated publicly reported groundwater withdrawals and discharges, direct withdrawals from and discharges to streams, and estimated domestic-well withdrawals and septic-system discharges. Surface-water-reservoir withdrawals were excluded from this scenario. Water-use scenario 2 incorporated all the types of withdrawal and discharge included in scenario 1 as well as withdrawals from surface-water reservoirs—all on a long-term, mean annual basis. All withdrawal and discharge data were previously reported to the State for the 2000–2004 period, except domestic-well withdrawals and septic-system discharges, which were estimated for this study. The majority of the state’s subbasins and groundwater contributing areas were estimated to have relatively minor (less than 10 percent) alteration of streamflow under water-use scenario 1 (seasonally varying water use; no surface-water-reservoir withdrawals). However, about 12 percent of subbasins and groundwater contributing areas were estimated to have extensive alteration of streamflows (greater than 40 percent) in August; most of these basins were concentrated in the outer metropolitan Boston region. Potential surcharging of streamflow in August was most commonly indicated for main-stem river subbasins, although surcharging was also indicated for some smaller tributary subbasins. In the high-flow month of April, only 4.8 percent of subbasins and groundwater contributing areas had more than 10 percent potential flow alteration. A majority of the state’s subbasins and groundwater contributing areas were also indicated to have relatively minor alteration of streamflow under water-use scenario 2 (long-term average water use, including surface-water-reservoir withdrawals). Extensive alteration of mean annual flows was estimated for about 6 percent of the state’s subbasins and groundwater contributing areas. The majority of subbasins estimated to have extensive long-term flow alteration contained reservoirs that were specifically designed, constructed, and managed to supply drinking water to cities. Only a small number of subbasins and groundwater contributing areas (1 percent) were extensively surcharged on a long-term, mean annual basis. Because site-specific data concerning surface-water-reservoir storage dynamics and management practices are not available statewide, the seasonal effects of surface-water-reservoir withdrawals on downstream flows could not be assessed in this study. The impounded storage ratio (volume of impounded subbasin or groundwater-contributing-area storage divided by mean annual predevelopment outflow from the subbasin or contributing area, in units of days) indicates the potential for alteration of streamflow, sediment-transport, and temperature regimes by dams, independent of water use. Storage ratios were less than 1 day for 33 percent of the subbasins and groundwater contributing areas, greater than 1 month for about 40 percent of the cases, and greater than 1 year for 3.2 percent of the cases statewide. Dam density, an indicator of stream-habitat fragmentation by dams, averaged 1 dam for every 6.7 stream miles statewide. Many of these dams are not presently (2009) being managed. The highest dam densities were in portions of Worcester County and in the Plymouth-Carver region, respectively, reflecting the historical reliance of Massachusetts industry upon water power and agricultural water-management practices in southeastern Massachusetts. Impervious cover is a frequently used indicator of urban land use. About 33 percent of the state’s 1,429 subbasins and groundwater contributing areas are relatively undeveloped at the local scale, with a local impervious cover of less than 4 percent. About 18 percent of Massachusetts subbasins and contributing areas are highly developed, with a local impervious cover greater than 16 percent. The remaining 49 percent of subbasins and contributing areas have levels of urban development between these extremes (4 to 16 percent local impervious cover). Cumulative impervious cover, defined for the entire upstream area encompassed by each subbasin, shows a smaller range (0 to 55 percent) than local impervious cover. Both local and cumulative impervious cover were highest in metropolitan Boston and other urban centers. High elevated impervious-cover values were also found along major transportation corridors. The water-quality status of Massachusetts streams is assessed periodically by the Massachusetts Department of Environmental Protection pursuant to the requirements of the Federal Clean Water Act. Streams selected for assessment are commonly located in larger subbasins where some degree of impairment is expected. In the 72 percent of the state’s subbasins and groundwater contributing areas with assessed streams in 2002, more than 50 percent of the assessed stream miles were considered impaired. All of the assessed stream miles were considered impaired in 66 percent of the subbasins and groundwater contributing areas with assessed streams. Large streams, such as the main stems of rivers that make up most of the assessed stream miles, also are in many cases the receiving waters for treated wastewater discharges and for this reason may be more susceptible to water-quality impairments than smaller streams. Subbasins and contributing areas with large fractions of assessed stream miles that are listed as impaired are distributed across the state, but are more prevalent in eastern Massachusetts.

Massachusetts

Integrated assessment of chemical and biological recovery after diversion and treatment of acid mine drainage in a Rocky Mountain stream

Responses of stream ecosystems to gradual reductions in metal loading following remediation or restoration activities have been well documented in the literature. However, much less is known about how these systems respond to the immediate or more rapid elimination of metal inputs. Construction of a water treatment plant on the North Fork of Clear Creek (NFCC; CO, USA), a US Environmental Protection Agency Superfund site, captured, diverted, and treated the two major point-source inputs of acid mine drainage (AMD) and provided an opportunity to investigate immediate improvements in water quality. We conducted a 9-year study that included intensive within- and among-year monitoring of receiving-stream chemistry and benthic communities before and after construction of the treatment plant. Results showed a 64%–86% decrease in metal concentrations within months at the most contaminated sites. Benthic communities responded with increased abundance and diversity, but downstream stations remained impaired relative to reference conditions, with significantly lower taxonomic richness represented by a few dominant taxa (i.e., Baetis sp., Hydropsyche sp., Simulium sp., Orthocladiinae). Elevated metal concentrations from apparent residual sources, and relatively high conductivity from contributing major ions not removed during the treatment process, are likely limiting downstream recovery. Our study demonstrates that direct AMD treatment can rapidly improve water quality and benefit aquatic life, but effectiveness is limited, in part, to the extent that inputs of metals are captured and treated. Consideration should also be given to the effects of elevated major ion concentrations from the treated effluent not removed during the lime treatment process. Continued chemical and biological monitoring will be needed to quantify the NFCC recovery trajectory and to inform future remediation strategies.

Colorado

Detection of conduit-controlled ground-water flow in northwestern Puerto Rico using aerial photograph interpretation and geophysical methods

The development potential of ground-water resources in the karst limestone of northwestern Puerto Rico, in an area extending from the Río Camuy to Aguadilla, is uncertain as a result of limited knowledge of the location of areas where a high density of cavities (interconnected fractures, conduits, and other dissolution features) might suggest the occurrence of high water yields. The presence in northwestern Puerto Rico of numerous coastal submarine springs, cavernous porosity in some of the wells, and rivers with entrenched and underground paths, indicate that it is probable that water-bearing, subterranean interconnected cavities occur in the area between the Río Camuy and Aguadilla. The number of exploratory wells needed to determine the location of these conduits or zones of enhanced secondary porosity could be substantially reduced if more information were available about the location of these subterranean features, greatly reducing the drilling costs associated with a trial-and-error exploratory process. A 3-year study was conducted by the U.S. Geological Survey, in cooperation with the Puerto Rico Aqueduct and Sewer Authority, to detect the presence of cavities that might suggest the occurrence of conduit-controlled groundwater flow. Aerial photographs, geologic and topographic maps, and field reconnaissance were used to identify such linear terrain features as ridges, entrenched canyons, and fracture traces. Natural potential and gravity geophysical methods were also used. The following sites were selected for the aerial photograph interpretation and geophysical testing: Caimital Bajo uplands and former Ramey Air Force Base in Aguadilla; Quebrada de los Cedros between Aguadilla and Isabela; the University of Puerto Rico Agricultural Experiment Station, Otilio dairy farm, and Pozo Brujo in Isabela; the Monte Encantado area in Moca and Isabela; and the Rio Camuy cave system in Hatillo and Camuy. In general, the degree of success varied with site and the geophysical method used. At some sites such as Pozo Brujo, the University of Puerto Rico Agricultural Experiment Station, and Monte Encantado area, natural potential anomalies strongly suggest the existence of conduits with flowing water. At most sites, however, the results obtained did not clearly reveal the presence of subsurface cavities that might be associated with the occurrence of conduit-controlled ground-water flow. Sites such as the University of Puerto Rico Agricultural Experiment Station, Pozo Brujo, and Quebrada de los Cedros warrant a more detailed analysis, including a test well drilling phase to confirm the presence of suspected high-yield water-bearing zones.

Water-Resources Investigations Report

The Geysers-Clear Lake geothermal area, California - An updated geophysical perspective of heat sources

The Geysers-Clear Lake geothermal area encompasses a large dry-steam production area in The Geysers field and a documented high-temperature, high-pressure, water-dominated system in the area largely south of Clear Lake, which has not been developed. Both systems have been extensively studied with geophysical techniques, drilling, and geological mapping during the past 20 years. An updated view is presented of the geological/geophysical complexities of the crust in The Geysers-Clear Lake region in order to address key unanswered questions about the heat source and tectonics. Early geophysical interpretations used a gravity low centered in the area between Clear Lake and The Geysers to suggest that a large magma chamber existed at depths starting at about 7 km. This first-order assumption of a large magma chamber expressed in the gravity data was used as a guide in subsequent geophysical and geological interpretations. Drill-hole temperature evidence is strongly suggestive of a shallow, hot-intrusive body, but in this paper the complexities are documented of the geological and geophysical data sets that make it difficult to pinpoint the location of “magma” or hot, solidified intrusive material. Forward modeling, multidimensional inversions, and ideal body analysis of the gravity data, new electromagnetic sounding models, and arguments made from other geophysical data sets suggest that many of the geophysical anomalies have significant contributions from rock property and physical state variations in the upper 7 km and not from ”magma“ at greater depths. Regional tectonic and magmatic processes are analyzed to develop an updated scenario for pluton emplacement that differs substantially from earlier interpretations. In addition, a rationale is outlined for future exploration for geothermal resources in The Geysers-Clear Lake area.

Geothermics

Water quality and macroinvertebrate communities of Emigration and Red Butte Creeks, Salt Lake County, Utah

Residential development in the canyons and foothills surrounding Salt Lake City, Utah, is growing at a rapid pace. Urban development typically degrades the water quality when formerly natural lands are developed. In Emigration Canyon, however, residential development is replacing land formerly used for grazing and recreation. It is not clear how this land use change has affected the water quality and biotic communities in this watershed. The water quality and macroinvertebrate communities of Emigration Creek and neighboring Red Butte Creek were examined by the U.S. Geological Survey (USGS) as part of the National Water-Quality Assessment Program (NAWQA) during summer 1999.

Utah

Knowledge and understanding of dissolved solids in the Rio Grande–San Acacia, New Mexico, to Fort Quitman, Texas, and plan for future studies and monitoring

Availability of water in the Rio Grande Basin has long been a primary concern for water-resource managers. The transport and delivery of water in the basin have been engineered by using reservoirs, irrigation canals and drains, and transmountain-water diversions to meet the agricultural, residential, and industrial demand. In contrast, despite the widespread recognition of critical water-quality problems, there have been minimal management efforts to improve water quality in the Rio Grande. Of greatest concern is salinization (concentration of dissolved solids approaching 1,000 mg/L), a water-quality problem that has been recognized and researched for more than 100 years because of the potential to limit both agricultural and municipal use. To address the issue of salinization, water-resource managers need to have a clear conceptual understanding of the sources of salinity and the factors that control storage and transport, identify critical knowledge gaps in this conceptual understanding, and develop a research plan to address these gaps and develop a salinity management program. In 2009, the U.S. Geological Survey (USGS) in cooperation with the U.S. Army Corps of Engineers (USACE), New Mexico Interstate Stream Commission (NMISC), and New Mexico Environment Department (NMED) initiated a project to summarize the current state of knowledge regarding the transport of dissolved solids in the Rio Grande between San Acacia, New Mexico, and Fort Quitman, Texas. The primary objective is to provide hydrologic information pertaining to the spatial and temporal variability present in the concentrations and loads of dissolved solids in the Rio Grande, the source-specific budget for the mass of dissolved solids transported along the Rio Grande, and the locations at which dissolved solids enter the Rio Grande. Dissolved-solids concentration data provide a good indicator of the general quality of surface water and provide information on the factors governing salinization within the Rio Grande study area. The pattern in dissolved-solids concentrations along the Rio Grande is one of increasing concentration with increasing distance downstream from Elephant Butte and Caballo Reservoirs. The concentration of dissolved solids in the Rio Grande doubles (approximately 500 to 1,000 mg/L) from below Elephant Butte Reservoir to El Paso and increases by more than a factor of 5 (approximately 500 to 3,200 mg/L) from below Elephant Butte Reservoir to Fort Quitman. Marked increases in the concentration of dissolved solids commonly coincide with contributions from agricultural drains, wastewater-treatment plants, regional groundwater, and upward-flowing saline groundwater. The greatest factor, from the surface-water system, in controlling dissolved solids in the Rio Grande is the amount of water that is being transported or stored. Annual variation in streamflow is influenced primarily by climate (precipitation and evaporation) and management of Elephant Butte and Caballo Reservoirs (water storage and release cycles). Seasonal variation in streamflow within the Rio Grande study area is generally categorized generally as irrigation (March–September) and nonirrigation (October–February) seasons; with streamflow in the Rio Grande is highest during the irrigation season and lowest during the nonirrigation season. Dissolved-solids loads during the irrigation season decrease between Leasburg and Fort Quitman primarily because of irrigation diversions and losses to the underlying alluvial aquifer. Conversely, dissolved-solids loads during the nonirrigation season increase between Caballo Dam and Fort Quitman primarily because of the inflow of dissolved solids from agricultural drains, wastewater-treatment plants, and groundwater with elevated concentrations of dissolved solids. Many studies have mass-balance budgets that account for the mass of dissolved solids transported along the Rio Grande. Results from mass-balance budgets developed for dissolved solids indicated that (1) the inflow of saline groundwater, inflow of regional groundwater, and chemical reactions between mineral phases are the primary sources controlling dissolved solids in the Rio Grande, and (2) groundwater pumping and mineral precipitation are causing a net storage of dissolved solids in the Leasburg to El Paso and El Paso to Fort Quitman reaches of the Rio Grande. Looking forward, multiple water-resource managers from State and local agencies in New Mexico and Texas and Federal agencies formed the Rio Grande Salinity Management Coalition with the goal to reduce the amount of dissolved solids that are transported and stored in the Rio Grande study area. The recommendations for additional monitoring to assist the coalition are as follows: -Monitoring: Couple water-quality and streamflow monitoring in the Rio Grande and agricultural drains; perform groundwater-seepage investigations in the Rio Grande and major agricultural drains; nonitor groundwater water-quality conditions in the Mesilla and Hueco Basins. -Focused Hydrogeology Studies at Inflow Sources: Map dissolved-solids concentrations in the Rio Grande and underlying alluvial aquifer; perform hydrogeologic characterization of subsurface areas containing unusually high concentrations of dissolved solids. -Modeling of Dissolved Solids: Develop models to simulate the transport and storage of dissolved solids in both surface-water and groundwater systems.

New Mexico;Texas

Selenium biotransformations into proteinaceous forms by foodweb organisms of selenium-laden drainage waters in California

Selenium contamination represents one of the few clear cases where environmental pollution has led to devastation of wildlife populations, most notably in agricultural drainage evaporation and power plant coal-fly ash receiving ponds. Complex biogeochemistry, in particular extensive biotransformations and foodchain transfer, governs Se ecotoxicology and toxicology, for which the mechanism(s) are still elusive. However, total waterborne Se concentration has been widely used as a criterion for regulating and mitigating Se risk in aquatic ecosystems, which does not account for Se biogeochemistry and its site-dependence. There is a need for more reliable indicator(s) that encompass Se ecotoxicity and/or toxicity. Selenomethionine warrants special attention since it simulates Se toxicosis of wildlife in laboratory feeding studies. While low in free selenomethionine, microphytes isolated from Se-laden agricultural evaporation ponds were abundant in proteinaceous selenomethionine. This prompted a more extensive survey of Se speciation in foodchain organisms including microphytes, macroinvertebrates, fish, and bird embryos residing mainly in the agricultural drainage systems of the San Joaquin Valley, California. Total Se in biomass, water-soluble fractions, and protein-rich fractions were measured along with GC-MS analysis of proteinaceous selenomethionine. In all foodchain organisms, water-soluble Se constituted the major fraction of total biomass Se, while proteinaceous Se was a substantial, if not dominant, fraction of the water-soluble Se. In turn, proteinaceous selenomethionine comprised an important fraction of proteinaceous Se. In terms of total biomass Se, an average 1400-fold of Se biomagnification from water to microphytes was observed while subsequent transfer from microphytes to macroinvertebrates exhibited an average of only 1.9-fold. The latter transfer was more consistent and greater in extent for proteinaceous Se and proteinaceous selenomethionine, which is consistent with their importance in foodchain transfer. Proteinaceous Se in the omnivorous carp (Cyprinus carpio) liver also demonstrated a relation to ovarian lesions, while deformed stilt (Himantopus mexicanus) embryo was more abundant in proteinaceous selenomethionine than were normal embryos. Although limited in the number of organisms surveyed, these findings provide an impetus for further field and laboratory feeding studies to substantiate the hypothesis that proteinaceous selenomethionine underlies Se ecotoxicity, which may in turn prove to be a reliable indicator of Se risk in aquatic ecosystems. Copyright ?? 2002 Elsevier Science B.V.

Aquatic Toxicology

Ground Water Atlas of the United States: Introduction and national summary

The Ground Water Atlas of the United States provides a summary of the most important information available for each principal aquifer, or rock unit that will yield usable quantities of water to wells, throughout the 50 States, Puerto Rico, and the U.S. Virgin Islands. The Atlas is an outgrowth of the Regional Aquifer-System Analysis (RASA) program of the U.S. Geological Survey (USGS), a program that investigated 24 of the most important aquifers and aquifer systems of the Nation and one in the Caribbean Islands (fig. 1). The objectives of the RASA program were to define the geologic and hydrologic frameworks of each aquifer system, to assess the geochemistry of the water in the system, to characterize the ground-water flow system, and to describe the effects of development on the flow system. Although the RASA studies did not cover the entire Nation, they compiled much of the data needed to make the National assessments of ground-water resources presented in the Ground Water Atlas of the United States. The Atlas, however, describes the location, extent, and geologic and hydrologic characteristics of all the important aquifers in the United States, including those not studied by the RASA program. The Atlas is written so that it can be understood by readers who are not hydrologists. Simple language is used to explain technical terms. The principles that control the presence, movement, and chemical quality of ground water in different climatic, topographic, and geologic settings are clearly illustrated. The Atlas is, therefore, useful as a teaching tool for introductory courses in hydrology or hydrogeology at the college level and as an overview of ground-water conditions for consultants who need information about an individual aquifer. It also serves as an introduction to regional and National ground-water resources for lawmakers, personnel of local, State, or Federal agencies, or anyone who needs to understand ground-water occurrence, movement, and quality. The purpose of the Ground Water Atlas of the United States is to summarize, in one publication with a common format, the most important ground-water information that has been collected over many years by the USGS, other Federal agencies, and State and local water management agencies. The purpose of this introductory chapter is to describe the content of the Atlas; to discuss the characteristics, use, and limitations of the maps and other types of illustrations used in the different chapters of the book; to summarize the locations of the principal aquifers on a Nationwide map; and to give an example of an aquifer in each principal hydrogeologic setting.

Hydrologic Atlas

Water-quality characteristics, including sodium-adsorption ratios, for four sites in the Powder River drainage basin, Wyoming and Montana, water years 2001-2004

The U.S. Geological Survey, in cooperation with the Wyoming Department of Environmental Quality, monitors streams throughout the Powder River structural basin in Wyoming and parts of Montana for potential effects of coalbed natural gas development. Specific conductance and sodium-adsorption ratios may be larger in coalbed waters than in stream waters that may receive the discharge waters. Therefore, continuous water-quality instruments for specific conductance were installed and discrete water-quality samples were collected to characterize water quality during water years 2001-2004 at four sites in the Powder River drainage basin: Powder River at Sussex, Wyoming; Crazy Woman Creek near Arvada, Wyoming; Clear Creek near Arvada, Wyoming; and Powder River at Moorhead, Montana. During water years 2001-2004, the median specific conductance of 2,270 microsiemens per centimeter at 25 degrees Celsius (?S/cm) in discrete samples from the Powder River at Sussex, Wyoming, was larger than the median specific conductance of 1,930 ?S/cm in discrete samples collected downstream from the Powder River at Moorhead, Montana. The median specific conductance was smallest in discrete samples from Clear Creek (1,180 ?S/cm), which has a dilution effect on the specific conductance for the Powder River at Moorhead, Montana. The daily mean specific conductance from continuous water-quality instruments during the irrigation season showed the same spatial pattern as specific conductance values for the discrete samples. Dissolved sodium, sodium-adsorption ratios, and dissolved solids generally showed the same spatial pattern as specific conductance. The largest median sodium concentration (274 milligrams per liter) and the largest range of sodium-adsorption ratios (3.7 to 21) were measured in discrete samples from the Powder River at Sussex, Wyoming. Median concentrations of sodium and sodium-adsorption ratios were substantially smaller in Crazy Woman Creek and Clear Creek, which tend to decrease sodium concentrations and sodium-adsorption ratios at the Powder River at Moorhead, Montana. Dissolved-solids concentrations in discrete samples were closely correlated with specific conductance values; Pearson's correlation coefficients were 0.98 or greater for all four sites. Regression equations for discrete values of specific conductance and sodium-adsorption ratios were statistically significant (p-values <0.001) at all four sites. The strongest relation (R2=0.92) was at the Powder River at Sussex, Wyoming. Relations on Crazy Woman Creek (R2=0.91) and Clear Creek (R2=0.83) also were strong. The relation between specific conductance and sodium-adsorption ratios was weakest (R2=0.65) at the Powder River at Moorhead, Montana; however, the relation was still significant. These data indicate that values of specific conductance are useful for estimating sodium-adsorption ratios. A regression model called LOADEST was used to estimate dissolved-solids loads for the four sites. The average daily mean dissolved-solids loads varied among the sites during water year 2004. The largest average daily mean dissolved-solids load was calculated for the Powder River at Moorhead, Montana. Although the smallest concentrations of dissolved solids were in samples from Clear Creek, the smallest average daily mean dissolved-solids load was calculated for Crazy Woman Creek. The largest loads occurred during spring runoff, and the smallest loads occurred in late summer, when streamflows typically were smallest. Dissolved-solids loads may be smaller than average during water years 2001-2004 because of smaller than average streamflow as a result of drought conditions.

Scientific Investigations Report

Measurements of spectral optical properties and their relation to biogeochemical variables and processes in Crater Lake, Crater Lake National Park, OR

Spectral inherent optical properties (IOPs) have been measured at Crater Lake, OR, an extremely clear sub-alpine lake. Indeed Pure water IOPs are major contributors to the total IOPs, and thus to the color of the lake. Variations in the spatial distribution of IOPs were observed in June and September 2001, and reflect biogeochemical processes in the lake. Absorption by colored dissolved organic material increases with depth and between June and September in the upper 300 m. This pattern is consistent with a net release of dissolved organic materials from primary and secondary production through the summer and its photo-oxidation near the surface. Waters fed by a tributary near the lake's rim exhibited low levels of absorption by dissolved organic materials. Scattering is mostly dominated by organic particulate material, though inorganic material is found to enter the lake from the rim following a rain storm. Several similarities to oceanic oligotrophic regions are observed: (a) The Beam attenuation correlates well with particulate organic material (POM) and the relationship is similar to that observed in the open ocean. (b) The specific absorption of colored dissolved organic material has a value similar to that of open ocean humic material. (c) The distribution of chlorophyll with depth does not follow the distribution of particulate organic material due to photo-acclimation resulting in a subsurface pigment maximum located about 50 m below the POM maximum. ?? 2007 Springer Science+Business Media B.V.

Hydrobiologia

Reconstructing vegetation response to altered hydrology and its use for restoration, Arthur R. Marshall Loxahatchee National Wildlife Refuge, Florida

We present reconstructed hydrologic and vegetation trends of the last three centuries across the Arthur R. Marshall Loxahatchee National Wildlife Refuge, Florida in order to understand the effects of 20th century water management. We analyzed pollen assemblages from cores at marsh sites along three transects to document vegetation and infer hydroperiod and water depth both before and after human alteration of Everglades hydrology. In the northern and central part of the Refuge, late Holocene water levels were higher and hydroperiods longer than the last 100 years. Post-1950 was a time of several different water management strategies. Pollen assemblages indicate drier conditions post-1950 in the northern and central parts of the Refuge, whereas sites in the southern Refuge are wetter and vegetation turnover is higher. Throughout the Refuge, Sagittaria pollen declines with the onset of water management, and may indicate a loss of greater variation in hydroperiods across years and water depths between seasons. Paleoecological evidence provides clear estimates of the vegetation response to hydrologic change under specific hydrologic regimes.

Florida

Movement of synthetic organic compounds in the food web after the introduction of invasive quagga mussels (Dreissena bugensis) in Lake Mead, Nevada and Arizona, USA

Introductions of dreissenid mussels in North America have been a significant concern over the last few decades. This study assessed the distribution of synthetic organic compounds (SOCs) in the food web of Lake Mead, Nevada/Arizona, USA and how this distribution was influenced by the introduction of invasive quagga mussels. A clear spatial gradient of SOC concentrations in water was observed between lake basins downstream of populated areas and more rural areas. Within the food web, trophic magnification factors (TMF) indicated statistically significant biomagnification for nine, and biodilution for two, of 22 SOCs examined. The highest value recorded was for PCB 118 (TMF, 5.14), and biomagnification of methyl triclosan (TMF, 3.85) was also apparent. Biodilution was observed for Tonalide® (0.06) and Galaxolide® (0.38). Total SOC concentration in quagga mussels was higher than in three pelagic fishes. Also, 19 of 20 SOC examined in Largemouth Bass ( Micropterus salmoides ) had substantially lower concentrations in 2013, when quagga mussels had become well established, than in 2007/08, soon after quagga mussels were introduced. Estimates of SOC concentrations in the water column and quagga mussels suggest that a considerable portion (~10.5%) of the SOC mass in the lake has shifted from the pelagic to the benthic environments due to quagga mussel growth. These observations suggest that benthic species, such as the endangered Razorback Sucker, may be experiencing increased risk of SOC exposure. In addition, stable isotope analysis (carbon and nitrogen) indicated a decrease in the nutritional value of zooplankton to consumers (e.g., Razorback Sucker larvae) since quagga mussels became established. These changes could affect Razorback Sucker larval survival and recruitment. Results from this study strongly suggest that the introduction of quagga mussels has greatly altered the dynamics of SOCs and other processes in the food web of Lake Mead.

Arizona, Nevada

Recent, widespread nitrate decreases may be linked to persistent dissolved organic carbon increases in headwater streams recovering from past acidic deposition

Long-term monitoring of water quality responses to natural and anthropogenic perturbation of watersheds informs policies for managing natural resources. Dissolved organic carbon (DOC) and nitrate (NO 3 − ) in streams draining forested landscapes provide valuable information on ecosystem function due to their biogeochemical reactivity and solubility in water. Here we evaluate a 20-year record (2001−2021) of biweekly stream-water samples ( n > 3000) and continuous discharge in three forested catchments in the Adirondack region of New York to investigate and interpret long-term trends in DOC and NO 3 − concentrations. Results from the intensively monitored catchments were compared with data from synoptic surveys of streams throughout the Adirondack region. A weighted regressions on time, discharge, and season (WRTDS) model, used to estimate daily flow-normalized concentrations, determined that DOC increased by ~30 to 50 % while NO 3 − decreased by ~50 to 70 % over the study period. The large amount of data from catchments with different soil properties permitted us to assess the relative effects of hydrology, season, and land cover factors on temporal trends in DOC and NO 3 − concentrations. We found weak evidence of climatic forcing of long-term increases in DOC, and instead contend that declining ionic strength in precipitation linked to declining anthropogenic acid deposition is driving DOC trends in stream waters. Nitrate concentrations were more variable but clearly decreased in recent years possibly related to declining N deposition. The recent increase in DOC:NO 3 − in all catchments indicates a major shift in stream stoichiometry that reflects changes in ecosystem functioning that may have important biogeochemical implications for terrestrial as well as aquatic ecosystems.

Science of the Total Environment

Per- and polyfluoroalkyl substances (PFAS) in drinking water in Southeast Los Angeles: Industrial legacy and environmental justice

Per - and polyfluoroalkyl substances (PFAS) are persistent chemicals of increasing concern to human health. PFAS contamination in water systems has been linked to a variety of sources including hydrocarbon fire suppression activities, industrial and military land uses, agricultural applications of biosolids, and consumer products. To assess PFAS in California tap water, we collected 60 water samples from inside homes in four different geographic regions, both urban and rural. We selected mostly small water systems with known history of industrial chemical or pesticide contamination and that served socioeconomically disadvantaged communities. Thirty percent of the tap water samples (18) had a detection of at least one of the 32 targeted PFAS and most detections (89 %) occurred in heavily industrialized Southeast Los Angeles (SELA). The residents of SELA are predominately Latino and low-income. Concentrations of perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) ranged from 6.8 to 13.6 ng/L and 9.4–17.8 ng/L, respectively in SELA and were higher than State (PFOA: 0.007 ng/L; PFOS: 1.0 ng/L) and national health-based goals (zero). To look for geographic patterns, we mapped potential sources of PFAS contamination, such as chrome plating facilities, airports, landfills, and refineries, located near the SELA water systems; consistent with the multiple potential sources in the area, no clear spatial associations were observed. The results indicate the importance of systematic testing of PFAS in tap water, continued development of PFAS regulatory standards and advisories for a greater number of compounds, improved drinking-water treatments to mitigate potential health threats to communities, especially in socioeconomically disadvantaged and industrialized areas.

California

Puhimau thermal area: a window into the upper east rift zone of Kilauea Volcano, Hawaii?

We report the results of two soil CO 2 efflux surveys by the closed chamber circulation method at the Puhimau thermal area in the upper East Rift Zone (ERZ) of Kilauea volcano, Hawaii. The surveys were undertaken in 1996 and 1998 to constrain how much CO 2 might be reaching the ERZ after degassing beneath the summit caldera and whether the Puhimau thermal area might be a significant contributor to the overall CO 2 budget of Kilauea. The area was revisited in 2001 to determine the effects of surface disturbance on efflux values by the collar emplacement technique utilized in the earlier surveys. Utilizing a cutoff value of 50 g m −2 d −1 for the surrounding forest background efflux, the CO 2 emission rates for the anomaly at Puhimau thermal area were 27 t d −1 in 1996 and 17 t d −1 in 1998. Water vapor was removed before analysis in all cases in order to obtain CO 2 values on a dry air basis and mitigate the effect of water vapor dilution on the measurements. It is clear that Puhimau thermal area is not a significant contributor to Kilauea's CO 2 output and that most of Kilauea's CO 2 (8500 t d −1 ) is degassed at the summit, leaving only magma with its remaining stored volatiles, such as SO 2 , for injection down the ERZ. Because of the low CO 2 emission rate and the presence of a shallow water table in the upper ERZ that effectively scrubs SO 2 and other acid gases, Puhimau thermal area currently does not appear to be generally well suited for observing temporal changes in degassing at Kilauea.

Hawaii

Precipitation and runoff simulations of select perennial and ephemeral watersheds in the middle Carson River basin, Eagle, Dayton, and Churchill Valleys, west-central Nevada

The effect that land use may have on streamflow in the Carson River, and ultimately its impact on downstream users can be evaluated by simulating precipitation-runoff processes and estimating groundwater inflow in the middle Carson River in west-central Nevada. To address these concerns, the U.S. Geological Survey, in cooperation with the Bureau of Reclamation, began a study in 2008 to evaluate groundwater flow in the Carson River basin extending from Eagle Valley to Churchill Valley, called the middle Carson River basin in this report. This report documents the development and calibration of 12 watershed models and presents model results and the estimated mean annual water budgets for the modeled watersheds. This part of the larger middle Carson River study will provide estimates of runoff tributary to the Carson River and the potential for groundwater inflow (defined here as that component of recharge derived from percolation of excess water from the soil zone to the groundwater reservoir). The model used for the study was the U.S. Geological Survey's Precipitation-Runoff Modeling System, a physically based, distributed-parameter model designed to simulate precipitation and snowmelt runoff as well as snowpack accumulation and snowmelt processes. Models were developed for 2 perennial watersheds in Eagle Valley having gaged daily mean runoff, Ash Canyon Creek and Clear Creek, and for 10 ephemeral watersheds in the Dayton Valley and Churchill Valley hydrologic areas. Model calibration was constrained by daily mean runoff for the 2 perennial watersheds and for the 10 ephemeral watersheds by limited indirect runoff estimates and by mean annual runoff estimates derived from empirical methods. The models were further constrained by limited climate data adjusted for altitude differences using annual precipitation volumes estimated in a previous study. The calibration periods were water years 1980-2007 for Ash Canyon Creek, and water years 1991-2007 for Clear Creek. To allow for water budget comparisons to the ephemeral models, the two perennial models were then run from 1980 to 2007, the time period constrained somewhat by the later record for the high-altitude climate station used in the simulation. The daily mean values of precipitation, runoff, evapotranspiration, and groundwater inflow simulated from the watershed models were summed to provide mean annual rates and volumes derived from each year of the simulation. Mean annual bias for the calibration period for Ash Canyon Creek and Clear Creek watersheds was within 6 and 3 percent, and relative errors were about 18 and -2 percent, respectively. For the 1980-2007 period of record, mean recharge efficiency and runoff efficiency (percentage of precipitation as groundwater inflow and runoff) averaged 7 and 39 percent, respectively, for Ash Canyon Creek, and 8 and 31 percent, respectively, for Clear Creek. For this same period, groundwater inflow volumes averaged about 500 acre-feet for Ash Canyon and 1,200 acre-feet for Clear Creek. The simulation period for the ephemeral watersheds ranged from water years 1978 to 2007. Mean annual simulated precipitation ranged from 6 to 11 inches. Estimates of recharge efficiency for the ephemeral watersheds ranged from 3 percent for Eureka Canyon to 7 percent for Eldorado Canyon. Runoff efficiency ranged from 7 percent for Eureka Canyon and 15 percent at Brunswick Canyon. For the 1978-2007 period, mean annual groundwater inflow volumes ranged from about 40 acre-feet for Eureka Canyon to just under 5,000 acre-feet for Churchill Canyon watershed. Watershed model results indicate significant interannual variability in the volumes of groundwater inflow caused by climate variations. For most of the modeled watersheds, little to no groundwater inflow was simulated for years with less than 8 inches of precipitation, unless those years were preceded by abnormally high precipitation years with significant subsurface storage carryover.

Nevada

Ground-water resources and geology of northern and central Johnson County, Wyoming

Northern and central Johnson County, Wyo., is an area of about 2,600 square miles that lies principally in the western part of the Powder River structural basin but also includes the east flank of the Bighorn Mountains. Sedimentary rocks exposed range in age from Cambrian to Recent and have an average total thickness of about 16,000 feet. Igneous and metamorphic rocks of Precambrian age crop out in the Bighorn Mountains. Rocks of pre-Tertiary age, exposed on the flanks and in the foothills of the Bighorns, dip steeply eastward and lie at great depth in the Powder River basin. The rest of the project area is underlain by a thick sequence of interbedded sandstone, siltstone, and shale of Paleocene and Eocene age. Owing to the regional structure, most aquifers in Johnson County contain water under artesian pressure. The Madison Limestone had not been tapped for water in Johnson County at the time of the present investigation (1963), but several wells in eastern Big Horn and Washakie Counties, on the west flank of the Bighorn Mountains, reportedly have flows ranging from 1,100 to 2,800 gallons per minute. Comparable yields can probably be obtained from the Madison in Johnson County in those areas where the limestone is fractured or cavernous. The Tensleep Sandstone reportedly yields 600 gallons per minute to a pumped irrigation well near its outcrop in the southwestern part of the project area. Several flowing wells tap the formation on the west flank of the Bighorn Mountains. The Madison Limestone and the Tensleep Sandstone have limited potential as sources of water because they can be developed economically only in a narrow band paralleling the Bighorn Mountain front in the southwestern part of the project area. Overlying the Tensleep Sandstone is about 6,000 feet of shale, siltstone, and fine-grained sandstone that, with a few exceptions, normally yields only small quantities of water to wells. The Cloverly Formation and the Newcastle Sandstone may yield moderate quantities of water to wells; but, in some areas, properly constructed wells tapping both formations might yield large quantities of water. The Shannon Sandstone Member of the Cody Shale will probably yield only small quantities of water to Wells, but it is the best potential source of ground water in the stratigraphic interval between the Newcastle and Parkman Sandstones. The Parkman Sandstone and the Lance Formation yield water to relatively shallow wells principally in the southwestern part of the project area. The Fort Union Formation yields adequate supplies of water for stock and domestic use from relatively shallow wells near its outcrop almost everywhere in the county. A few deep wells tap the Fort Union along the Powder River valley in the northeastern part of Johnson County. Some of these wells flow, but their flows rarely exceed 10 gallons per minute; larger yields could be undoubtedly be obtained by pumping. The Wasatch Formation is the principal source of ground water in Johnson County. It yields adequate supplies to many relatively shallow stock and domestic wells, some of which flow, but much larger yields probably would require pumping lifts that are prohibitive for most purposes. The Kingsbury Conglomerate and Moncrief Members of the Wasatch Formation, though, may yield moderate quantities of water in some places. Alluvial deposits underlying the valleys of the Powder River and Crazy Woman, Clear, and Piney Creeks are potential sources of moderate to large supplies of water in the Powder River drainage basin. The permeability of these deposits decreases with distance from the Bighorn Mountain front, so that largest yields can probably be obtained along the upper reaches of these streams. Most ground water utilized in the project area is for domestic and stock supplies and is obtained from drilled wells and from springs. Water for irrigation is obtained almost entirely by diverting flows of perennial streams. The discharge of wel

Water Supply Paper

Controls on water quality below a reclaimed surface coal mine, southeastern Montana

Coal mining and reclamation can have a profound influence on hydrogeologic systems, with clear consequences for groundwater quality, yet their long-term influence on downgradient water quality over time following reclamation is less well documented. Geochemical trends were evaluated in water quality downgradient of a fully reclaimed landscape at the former Big Sky Mine in the Rosebud Creek watershed (southeastern Montana, USA), over a 3-year period (2020–2022), including bond release in 2022. Within 6 km downgradient from the reclaimed area, sulfate concentrations decreased from approximately 3500 to 1800 mg l −1 within the Miller Coulee alluvial aquifer. Major ions, δ 34 S SO4 values, and residence time tracers suggest that the observed decreases in sulfate concentration result from a combination of dilution by mixed-age inflows and incomplete transit of the high salinity plume from the mine boundary. Both bedrock and alluvial aquifers of the Rosebud Creek corridor contained contributions of millennia-old regional groundwater, which may serve to mitigate mine-derived high salinity waters. Rosebud Creek, which traverses the outflow zone of Miller Coulee in the study area, exhibited high sulfate concentrations during low flows and consistent downgradient increases in sulfate concentration. The possibility of plume dynamics in Miller Coulee suggests that the greatest water quality impacts may not yet have reached Rosebud Creek.

Montana