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USGS2010

Status and understanding of groundwater quality in the central-eastside San Joaquin Basin, 2006: California GAMA Priority Basin Project

Groundwater quality in the approximately 1,695-square-mile Central Eastside San Joaquin Basin (Central Eastside) study unit was investigated as part of the Priority Basin Project (PBP) of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001, and is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The GAMA Central Eastside study unit was designed to provide a spatially unbiased assessment of untreated-groundwater quality, as well as a statistically consistent basis for comparing water quality throughout California. During March through June 2006, samples were collected from 78 wells in Stanislaus and Merced Counties, 58 of which were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells), and 20 of which were sampled to evaluate changes in water chemistry along groundwater-flow paths (understanding wells). Water-quality data from the California Department of Public Health (CDPH) database also were used for the assessment. An assessment of the current status of the groundwater quality included collecting samples from wells for analysis of anthropogenic constituents such as volatile organic compounds (VOCs) and pesticides, as well as naturally occurring constituents such as major ions and trace elements. The assessment of status is intended to characterize the quality of untreated-groundwater resources within the primary aquifer system, not the treated drinking water delivered to consumers by water purveyors. The primary aquifer system (hereinafter, primary aquifer) is defined as that part of the aquifer corresponding to the perforation interval of wells listed in the CDPH database for the Central Eastside study unit. The quality of groundwater in shallower or deeper water-bearing zones may differ from that in the primary aquifer; shallower groundwater may be more vulnerable to surficial contamination. The primary aquifer is represented by the grid wells, of which 90 percent had depths to the tops of their perforations of about 80 to 330 feet and depths to bottom of about 100 to 670 feet. Relative-concentrations (sample concentration divided by benchmark concentration) were used as the primary metric for assessing the status of water quality for those constituents that have Federal and (or) California human health or aesthetic benchmarks. A relative-concentration greater than (>) 1.0 indicates a concentration above a benchmark, and less than or equal to (≤) 1.0 indicates a concentration equal to or below a benchmark. For organic and special interest constituents, relative-concentrations were classified as high (>1.0), moderate (≤1.0 and >0.1), or low (≤0.1). For inorganic constituents, relative-concentrations were classified as high (>1.0), moderate (≤1.0 and >0.5), or low (≤0.5). The threshold between low and moderate classifications was lower for organic and special interest constituents than for inorganic constituents because organic constituents generally are less prevalent and have smaller relative-concentrations than inorganic constituents. Grid-based and spatially-weighted approaches, the latter incorporating data from all CDPH wells, were used to evaluate the proportion of the primary aquifer (aquifer-scale proportions) with high, moderate, or low relative-concentrations. For individual constituents or classes of constituents, the aquifer-scale high proportion is the percentage of the area of the study unit having high relative-concentrations within the depth-zones of the primary aquifer. Aquifer-scale moderate and low proportions are defined similarly. Spatially-weighted aquifer-scale high proportions nearly always fell within the 90-percent confidence interval of grid-based aquifer-scale high proportions, indicating that the grid-based approach yielded statistically equivalent results to the spatially-weighted approach incorporating CDPH data. The status assessment for inorganic constituents showed that inorganic constituents (one or more) were high, relative to human-health benchmarks, in 18.0 percent of the primary aquifer, moderate in 44.0 percent, and low in 38.0 percent. Of inorganic constituents with human-health benchmarks, arsenic, vanadium, and nitrate were detected at high relative-concentrations in 15.6 percent, 3.6 percent, and 2.1 percent, respectively, of the primary aquifer. Of inorganic constituents with secondary maximum contaminant levels (SMCL), manganese, iron, and TDS were detected at high relative-concentrations in 4.5 percent, 2.2 percent, and 1.7 percent, respectively, of the primary aquifer. The status assessment for organic constituents showed that organic constituents (one or more) were high, relative to human-health benchmarks, in a smaller proportion of the primary aquifer (1.2 percent) than inorganic constituents (18.0 percent). Organic constituents had moderate relative-concentrations in 14.3 percent, and had low relative-concentrations or were not detected in 84.5 percent, of the primary aquifer. The proportion of the primary aquifer with high relative-concentrations of organic constituents reflected high proportions of the discontinued soil fumigant 1,2-dibromo-3-chlororopane (DBCP; 1.0 percent) and the solvent tetrachloroethene (PCE; 0.2 percent). Most of the organic and special interest constituents detected in groundwater in the Central Eastside study unit have human-health benchmarks. Of the 205 organic and special interest constituents analyzed for, 36 constituents were detected. Of these constituents, 32 were detected only at low relative-concentrations. Four constituents, chloroform, carbon tetrachloride, DBCP, and perchlorate, were detected at moderate relative-concentrations in grid wells. Nine organic and special-interest constituents were detected frequently (detected in greater than 10 percent of samples): the trihalomethanes chloroform, bromoform, bromodichloromethane, and dibromochloromethane; the solvent PCE; the herbicides atrazine, simazine, and metolachlor, and special-interest constituent perchlorate. An assessment of understanding of the groundwater quality included sampling of understanding wells, some of which were perforated in shallower or deeper portions of the aquifer system than the primary aquifer, and analysis of correlations of groundwater quality with land use, depth, age classification, and other potential explanatory factors. The understanding assessment indicated that the concentrations of many constituents were related to depth and groundwater age. However, concentrations of individual constituents or constituent classes also were sometimes related to geochemical conditions, lateral position in the flow system, or land use. High and moderate relative-concentrations of uranium, nitrate, and total dissolved solids (TDS) were detected in some wells where the tops of perforations are within the upper 200 feet of the aquifer system. In wells with the depth to the top of perforations below this depth, concentrations were low. A similar pattern occurred for the sum of herbicide concentrations. These vertical water-chemistry patterns are consistent with the hydrogeologic setting, in which return flows from agricultural and urban land use are the major source of recharge, and withdrawals for irrigation and urban supply are the major source of discharge, resulting in substantial vertical components of groundwater flow. The decrease in concentrations of many constituents with depth reflects in part that groundwater gets older with depth. Tritium, helium-isotopes, and carbon-14 data were used to classify the predominant age of groundwater samples into three categories: modern (water that has entered the aquifer in the last 50 years), pre-modern (water that entered the aquifer more than 50 years, up to tens of thousands of years, ago), and mixed (mixtures of waters with modern and pre-modern ages). Uranium, nitrate, and herbicide concentrations were significantly higher in groundwater having modern- and mixed-ages than pre-modern ages, indicating that these constituents may be affected by anthropogenic activities in the last 50 years. Other patterns in the distribution of nitrate, uranium, and TDS are evident. Isotopic and geochemical data are consistent with partial denitrification of nitrate in some reducing groundwaters in the western and deeper parts of the flow system. Uranium and TDS concentrations increase from east to west across the valley, along the direction of regional lateral groundwater flow. High and moderate relative-concentrations of arsenic can be attributed to reductive dissolution of manganese or iron oxides, or to desorption by high pH waters. Arsenic concentrations also increased with increasing depth and groundwater age. High to moderate relative-concentrations of vanadium primarily are related to high pH under oxic conditions. The frequency of detections of DBCP was greater in areas with orchard-vineyard land use >40 percent and at depths <200 feet. THMs and solvents were correlated positively with percent urban land use. Herbicide concentrations were correlated negatively with percent natural land use. Perchlorate concentrations were significantly greater in waters having modern and mixed ages than waters having pre-modern ages and were significantly and positively correlated with two land uses—percent orchard/vineyard land use and percent urban land use.

California↗

USGS2015

Species richness and distributions of boreal waterbirds in relation to nesting and brood-rearing habitats

Identification of ecological factors that drive animal distributions allows us to understand why distributions vary temporally and spatially, and to develop models to predict future changes to populations–vital tools for effective wildlife management and conservation. For waterbird broods in the boreal forest, distributions are likely driven by factors affecting quality of nesting and brood-rearing habitats, and the influence of these factors may extend beyond singles species, affecting the entire waterbird community. We used occupancy models to assess factors influencing species richness of waterbird broods on 72 boreal lakes, along with brood distributions of 3 species of conservation concern: lesser scaup ( Aythya affinis ), white-winged scoters ( Melanitta fusca ), and horned grebe ( Podiceps auritus ). Factors examined included abundance of invertebrate foods (Amphipoda, Diptera, Gastropoda, Hemiptera, Odonata), physical lake attributes (lake area, emergent vegetation), water chemistry (nitrogen, phosphorus, chlorophyll a concentrations), and nesting habitats (water edge, non-forest cover). Of the 5 invertebrates, only amphipod density was related to richness and occupancy, consistently having a large and positive relationship. Despite this importance to waterbirds, amphipods were the most patchily distributed invertebrate, with 17% of the study lakes containing 70% of collected amphipods. Lake area was the only other covariate that strongly and positively influenced species richness and occupancy of scaup, scoters, and grebes. All 3 water chemistry covariates, which provided alternative measures of lake productivity, were positively related to species richness but had little effect on scaup, scoter, and grebe occupancy. Conversely, emergent vegetation was negatively related to richness, reflecting avoidance of overgrown lakes by broods. Finally, nesting habitats had no influence on richness and occupancy, indicating that, at a broad spatial scale, brood distributions are largely driven by the presence of quality brood-rearing lakes, not nesting habitats. Our findings are relevant to generating conservation plans or management goals; specifically, boreal lakes with abundant amphipods and surface areas >25 ha are important habitat for waterbird broods and merit conservation, especially given the patchy distribution of amphipods. Moreover, these high quality brood-rearing lakes are much rarer, and thus more constraining, than are quality nesting habitats, which are likely abundant in the boreal.

Alaska↗

USGS2007

Geochemical effects of induced stream-water and artificial recharge on the Equus Beds Aquifer, South-Central Kansas, 1995-2004

Artificial recharge of the Equus Beds aquifer is part of a strategy implemented by the city of Wichita, Kansas, to preserve future water supply and address declining water levels in the aquifer of as much as 30 feet caused by withdrawals for water supply and irrigation since the 1940s. Water-level declines represent a diminished water supply and also may accelerate migration of saltwater from the Burrton oil field to the northwest and the Arkansas River to the southwest into the freshwater of the Equus Beds aquifer. Artificial recharge, as a part of the Equus Beds Ground-Water Recharge Project, involves capturing flows larger than base flow from the Little Arkansas River and recharging the water to the Equus Beds aquifer by means of infiltration or injection. The geochemical effects on the Equus Beds aquifer of induced stream-water and artificial recharge at the Halstead and Sedgwick sites were determined through collection and analysis of hydrologic and water-quality data and the application of statistical, mixing, flow and solute-transport, and geochemical model simulations. Chloride and atrazine concentrations in the Little Arkansas River and arsenic concentrations in ground water at the Halstead recharge site frequently exceeded regulatory criteria. During 30 percent of the time from 1999 through 2004, continuous estimated chloride concentrations in the Little Arkansas River at Highway 50 near Halstead exceeded the Secondary Drinking-Water Regulation of 250 milligrams per liter established by the U.S. Environmental Protection Agency. Chloride concentrations in shallow monitoring wells located adjacent to the stream exceeded the drinking-water criterion five times from 1995 through 2004. Atrazine concentrations in water sampled from the Little Arkansas River had large variability and were at or near the drinking-water Maximum Contaminant Level of 3.0 micrograms per liter as an annual average established by the U.S. Environmental Protection Agency. Atrazine concentrations were much smaller than the drinking-water criterion and were detected at much smaller concentrations in shallow monitoring wells and diversion well water located adjacent to the stream probably because of sorption on aquifer sediment. Before and after artificial recharge, large, naturally occurring arsenic concentrations in the recharge water for the Halstead diversion well and recharge site exceeded the Maximum Contaminant Level of 10 micrograms per liter established by the U.S. Environmental Protection Agency for drinking water. Arsenic and iron concentrations decreased when water was recharged through recharge basins or a trench; however, chemical precipitation and potential biofouling eventually may decrease the artificial recharge efficiency through basins and trenches. At the Sedgwick site, chloride concentrations infrequently exceeded regulatory criteria. Large concentrations of atrazine were treated to decrease concentrations to less than regulatory criteria. Recharge of treated stream water through recharge basins avoids potentially large concentrations of arsenic and iron that exist at the Halstead diversion site. Results from a simple mixing model using chloride as a tracer indicated that the water chemistry in shallow monitoring well located adjacent to the Little Arkansas River was 80 percent of stream water, demonstrating effective recharge of the alluvial aquifer by the stream. Results also indicated that about 25 percent of the water chemistry of the diversion well water was from the shallow part of the aquifer. Additionally, diverting water through a diversion well located adjacent to the stream removed about 75 percent of the atrazine, probably through sorption to aquifer sediment, and decreased the need for additional water treatment to remove atrazine.

Kansas↗

USGS2009

Ground-Water Quality Data in the Santa Clara River Valley Study Unit, 2007: Results from the California GAMA Program

Ground-water quality in the approximately 460-square-mile Santa Clara River Valley study unit (SCRV) was investigated from April to June 2007 as part of the statewide Priority Basin project of the Ground-Water Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The study was designed to provide a spatially unbiased assessment of the quality of raw ground water used for public water supplies within SCRV, and to facilitate a statistically consistent basis for comparing water quality throughout California. Fifty-seven ground-water samples were collected from 53 wells in Ventura and Los Angeles Counties. Forty-two wells were selected using a randomized grid-based method to provide statistical representation of the study area (grid wells). Eleven wells (understanding wells) were selected to further evaluate water chemistry in particular parts of the study area, and four depth-dependent ground-water samples were collected from one of the eleven understanding wells to help understand the relation between water chemistry and depth. The ground-water samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, potential wastewater-indicator compounds, and pharmaceutical compounds), a constituent of special interest (perchlorate), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial constituents. Naturally occurring isotopes (tritium, carbon-13, carbon-14 [abundance], stable isotopes of hydrogen and oxygen in water, stable isotopes of nitrogen and oxygen in nitrate, chlorine-37, and bromine-81), and dissolved noble gases also were measured to help identify the source and age of the sampled ground water. Quality-control samples (blanks or replicates, or samples for matrix spikes) were collected from approximately 26 percent of the wells, and the analyses of these samples were used to evaluate the quality of the data for the ground-water samples. Assessment of the quality-control results showed that the quality of the environmental data was good, with low bias and low variability, and as a result, less than 0.1 percent of the analytes detected in ground-water samples were censored. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, and (or) blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is delivered (or, supplied) to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with regulatory and non-regulatory thresholds established by the U.S. Environmental Protection Agency (USEPA) and the California Department of Public Health (CDPH) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. Most constituents that were detected in ground-water samples were reported at concentrations below their established health-based thresholds. VOCs, pesticides and pesticide degradates, and potential wastewater-indicator compounds were detected in about 33 percent or less of the 42 SCRV grid wells. Concentrations of all detected organic constituents were below established health-based thresholds. Perchlorate was detected in approximately 12 percent of the SCRV grid wells; all concentrations reported were below the NL-CA threshold. Additional constituents, including major ions, trace elements, and nutrients were collected at 26 wells (16 grid wells and 10 understanding wells) of the 53 wells sampled f

Data Series↗

USGS1995

Hydrochemistry of aquifer systems and relation to regional flow patterns in Cretaceous and older rocks underlying Kansas, Nebraska, and parts of Arkansas, Colorado, Missouri, New Mexico, Oklahoma, South Dakota, Texas, and Wyoming

Aquifer systems in Cretaceous and older rocks of the Central Midwest are divided on the basis of hydrochemistry and ground-water flow patterns in the Plains subregion, the Western Interior Plains aquifer system contains sodium chloride type water with large concentrations of dissolved solids. Ion ratios suggest that the water was derived from seawater by concentration and by depletion of calcium and sulfate ions. In the overlying Western Interior Plains confining system, concentrations of depositional sea water and dissolution of extensive evaporite deposits have resulted in sodium chloride type water with large concentrations of dissolved solids and sodium. Overlying this confining system in the northwest part of the study area, the Great Plains aquifer system yields water that generally is less mineralized and more variable in water type than the underlying systems. Recharge of meteoric water, concentration of brackish water in which the rocks were deposited, and dissolution of underlying evaporite deposits have contributed to the observed water chemistry. The Great Plains confining system restricts the exchange of water between the underlying Great Plains aquifer system and the overlying unconfined aquifers. In the Ozark subregion, geological units equivalent to the Western Interior Plains aquifer system comprise the Ozark Plateaus aquifer system. Units of this aquifer system are exposed at the land surface, and fresh meteoric water moves rapidly through fractures and solution openings. Water chemistry in this system reflects primarily the dissolution of the predominately carbonate rocks.

Water-Resources Investigations Report↗

USGS1989

Geochemical comparison of ground water in areas of New England, New York, and Pennsylvania

In New England, the ground-water geochemistry results mainly from the reaction of CO2-charged water with feldspar and other primary silicates. Water in the New England bedrock is more highly evolved geochemically than water in the drift, presumably as a result of its longer residence time. In the New York area, the geochemistry of water in both types of aquifers results mainly from carbonate-mineral dissolution. Water in most glacial drift and bedrock is saturated with respect to calcite. In some parts of New York, the dissolution of evaporite minerals has a marked effect on the water chemistry of the bedrock. In most of the Pennsylvania area, the geochemistry of water in both types of aquifers indicates that, although carbonate minerals are the principal reactants, their influence on water chemistry is less than in New York. In parts of Pennsylvania, chemical differences between ground water from drift and ground water from bedrock are attributed to a higher proportion of reactive minerals in the drift than in the local bedrock as a result of glacial transport. -from Author

Groundwater↗

USGS2007

Hydrologic landscapes on the Delmarva Peninsula - Part 2: Estimates of base-flow nitrogen load to Chesapeake Bay

ABSTRACT: The relation between landscape characteristics and water chemistry on the Delmarva Peninsula can be determined through a principal-component analysis of basin characteristics. Two basin types were defined by factor scores: (1) well-drained basins, characterized by combinations of a low percentage of forest cover, a low percentage of poorly drained soil, and elevated channel slope; and (2) poorly drained basins, characterized by a combinations of an elevated percentage of forest cover, an elevated percentage of poorly drained soil, and low channel slopes. Results from base-flow sampling of 29 basins during spring 1991 indicate that water chemistry of the two basin types differ significantly. Concentrations of calcium, magnesium, potassium, alkalinity, chloride, and nitrate are elevated in well-drained basins, and specific conductance is elevated. Concentrations of aluminum, dissolved organic carbon, sodium, and silica are elevated in poorly drained basins whereas specific conductance is low. The chemical patterns found in well-drained basins can be attributed to the application of agricultural chemicals, and those in poorly drained basins can be attributed to ground-water flowpaths. These results indicate that basin types determined by a quantitative analysis of basin characteristics can be related statistically to differences in base-flow chemistry, and that the observed statistical differences can be related to major processes that affect water chemistry.

Journal of the American Water Resources Associatio↗

USGS1998

Water-quality assessment of the Ozark Plateaus study unit, Arkansas, Kansas, Missouri, and Oklahoma- fish communities in streams of the Ozark Plateaus and their relations to selected environmental factors

Fish communities from 22 reaches at 18 stations in the Ozark Plateaus were sampled in 1993, 1994, and 1995. The 18 stations were chosen to represent selected combinations of major environmental factors (geology/physiographic area, land use, and basin size). Additional physical, chemical, and biological factors also were measured for each of the 22 reaches and the influence of these factors upon the fish communities was investigated. Fish community samples collected at the 22 reaches identified differences in these communities that can be attributed to differences in land use and related water-quality and habitat characteristics. Communities from agriculture reaches tended to have more species, increased relative abundance of stonerollers and members of the sucker family, and decreased relative abundance of members of the sunfish and darter families. Several groups of environmental factors (concentrations of nutrients, organic carbon, suspended sediment, and dissolved oxygen; measures related to ionic strength; measures related to riparian vegetation; measures related to substrate; and measures related to stream size) appear to be related to land-use differences and fish community differences. Three multivariate analysis techniques (two ordination techniques and a classification technique) yielded similar results when applied to the fish community data. Fish communities from reaches with more similar land use in their basins and with similar drainage areas generally were grouped closer together in the analysis. Water quality, substrate, stream morphology, and riparian measures appear to be affecting fish communities at these reaches. The relations between land use, stream size, and fish communities have implications for water quality assessments of Ozark streams. Compared to other parts of the United States, many fish species live in the Ozark Plateaus. At least 19 of these species are endemic to the Ozarks area. Many of these species are intolerant of habitat or water chemistry degradation. This characteristic makes fish a useful tool for assessing water-chemistry and other habitat conditions of streams. Several environmental factors can contribute to differences in fish communities. Elevated nutrient concentrations and greater canopy angles can increase periphyton production. Greater canopy angles can raise water temperatures and, if they reflect less woody vegetation along the banks of streams, can be associated with greater streambank erosion. Elevated suspended sediment concentrations and finer and more embedded substrates can reduce benthic macroinvertebrate populations, decrease spawning success of many fish species, and decrease protection of benthic fish from water velocities and predators.

Arkansas, Kansas, Missouri, Oklahoma↗

USGS2011

Geophysical logs and water-quality data collected for boreholes Kimama-1A and -1B, and a Kimama water supply well near Kimama, southern Idaho

In September 2010, a research consortium led by scientists from Utah State University began drilling the first of three continuously cored boreholes on the Snake River Plain in southern Idaho. The goals of this effort, the Snake River Scientific Drilling Project, are to study the interaction between the Earth's crust and mantle, to identify potential geothermal energy sources, and to track the evolution of the Yellowstone hotspot on the Snake River Plain. The first borehole, located near Kimama, Idaho, is about 50 miles southwest of the U.S. Department of Energy's Idaho National Laboratory. Because geohydrologic data are scarce for that area of the central Snake River Plain, the Kimama borehole, completed in January 2011, provided a unique opportunity to collect geophysical and water-chemistry data from the eastern Snake River Plain aquifer system, downgradient of the laboratory. Therefore, in conjunction with the Snake River Scientific Drilling Project, scientists from the U.S. Geological Survey's Idaho National Laboratory Project Office conducted geophysical logging and collected water samples at the Kimama site. Wireline geophysical logs were collected for the diverging borehole, Kimama-1A and -1B, from land surface to 976 and 2,498 feet below land surface (BLS), respectively. Water samples were collected from Kimama-1A at depths near 460 and 830 feet BLS, and from the Kimama Water Supply (KWS) well located about 75 feet away. Geophysical log data included a composite of natural gamma, neutron, gamma-gamma dual density, and gyroscopic analysis for boreholes Kimama-1A and -1B. Geophysical logs depicted eight sediment layers (excluding surficial sediment) ranging from 4 to 60 feet in thickness. About 155 individual basalt flows were identified, ranging from less than 3 feet to more than 175 feet in thickness (averaging 15 feet) for borehole Kimama-1B (0 to 2,498 feet BLS). Sediment and basalt contacts were selected based on geophysical traces and were confirmed with visual inspection of core photographs. Temperature logs from the water table surface (about 260 feet BLS) to the bottom of borehole Kimama-1B (2,498 feet BLS) were nearly isothermal, ranging from about 62 to 64 degrees Fahrenheit. Gyroscopic data revealed that borehole Kimama-1B begins to separate from borehole Kimama-1A near a depth of 676 feet BLS. Drillhole azimuth and horizontal deviation at total logged depth for boreholes Kimama-1A and -1B were 172.6 and 188.3 degrees and 25.9 and 82.0 feet, respectively. Water samples were collected and analyzed for common ions; selected trace elements; nutrients; isotopes of hydrogen, oxygen, and carbon; and selected radionuclides. One set of water samples was collected from the KWS well and the two other sample sets were collected from borehole Kimama-1A near 460 and 830 feet BLS. With one exception, data for all three zones sampled near Kimama generally indicated that the water chemistry was similar. The exception was found in the deepest zone in borehole Kimama-1A (830 feet BLS) where concentrations probably were affected by the drilling mud. A comparison of the inorganic, organic, and stable chemistry data between the KWS well and the 460-foot zone in borehole Kimama-1A indicated similar chemistry of the aquifer water, except for some variability with nitrate plus nitrite, orthophosphate, iron, zinc, and carbon-14. Radionuclide concentrations were either less than reporting levels or at background levels for the eastern Snake River Plain aquifer.

Idaho↗

USGS2016

Geochemistry and hydrology of perched groundwater springs: assessing elevated uranium concentrations at Pigeon Spring relative to nearby Pigeon Mine, Arizona (USA)

The processes that affect water chemistry as the water flows from recharge areas through breccia-pipe uranium deposits in the Grand Canyon region of the southwestern United States are not well understood. Pigeon Spring had elevated uranium in 1982 (44 μg/L), compared to other perched springs (2.7–18 μg/L), prior to mining operations at the nearby Pigeon Mine. Perched groundwater springs in an area around the Pigeon Mine were sampled between 2009 and 2015 and compared with material from the Pigeon Mine to better understand the geochemistry and hydrology of the area. Two general groups of perched groundwater springs were identified from this study; one group is characterized by calcium sulfate type water, low uranium activity ratio 234 U/ 238 U (UAR) values, and a mixture of water with some component of modern water, and the other group by calcium-magnesium sulfate type water, higher UAR values, and radiocarbon ages indicating recharge on the order of several thousand years ago. Multivariate statistical principal components analysis of Pigeon Mine and spring samples indicate Cu, Pb, As, Mn, and Cd concentrations distinguished mining-related leachates from perched groundwater springs. The groundwater potentiometric surface indicates that perched groundwater at Pigeon Mine would likely flow toward the northwest away from Pigeon Spring. The geochemical analysis of the water, sediment and rock samples collected from the Snake Gulch area indicate that the elevated uranium at Pigeon Spring is likely related to a natural source of uranium upgradient from the spring and not likely related to the Pigeon Mine.

Arizona↗

USGS1989

Porosity development in coastal carbonate aquifers

Geochemical mixing theory suggests that the mixing of seawater and calcite-saturated fresh ground water can result in a solution that is undersaturated with respect to calcite. Previous studies of the mixing of such waters in carbonate rocks along certain coastlines have indicated that this mixing effect may be responsible for significant amounts of calcite dissolution and porosity development. In this study, potential rates of porosity development by calcite dissolution are assessed by combining geochemical mixing theory with the hydrodynamics of fresh-water-salt-water mixing zones in a coupled reaction- transport model. Results from the reaction-path model PHREEQE are used with a variable-density ground-water flow and solute-transport model to simulate an idealized cross section of a coastal carbonate aquifer. Results of the simulations indicate that the dissolution process is sensitive to fresh-water chemistry, ground-water velocities, and sea-level movement. Dissolution potential was evaluated at three field sites, and evidence from those sites is in general agreement with the simulation results. Dissolution rates indicated by the model show that under the proper conditions this dissolution mechanism can produce significant increases in porosity over relatively short spans of geologic time (tens of thousands of years).

Geology↗

USGS1982

Test well DO-CE 88 at Cambridge, Dorchester County, Maryland

Test well DO-CE 88 at Cambridge, Maryland, penetrated 3,299 feet of unconsolidated Quaternary, Tertiary and Cretaceous sediments and bottomed in quartz-monzonite gneiss. The well was drilled to provide data for a study of the aquifer system of the northern Atlantic Coastal Plain. Twenty-one core samples were collected. Six sand zones were tested for aquifer properties and sampled for ground-water chemistry. Point-water heads were measured at seven depths. Environmental heads (which ranged from -18.33 to +44.16 feet relative to sea level) indicate an upward component of flow. A temperature log showed a maximum temperature of 41.9 degrees Celsius and a mean temperature gradient of 0.00838 degrees Celsius per foot. The water analyses delineated the freshwater-saltwater transition zone between 2,650 and 3,100 feet. The ground water changes progressively downward from a sodium bicarbonate to a sodium chloride character. Clays in the analyzed core samples belong to the montmorillonite and kaolinite groups, and mean cation exchange capacity ranged from 8.3 to 38.9 milliequivalents per 100 grams. Vertical and horizontal hydraulic conductivities measured in cores ranged from 1.5 x 10-s to 1.3 feet per day and from 7.3 x 10-6 to 1.3 feet per day, respectively, but the most permeable sands were not cored. Porosity was 1.5 percent in the quartz monzonite bedrock and ranged from 22.4 to 41 percent in the overlying sediments. Transmissivities from aquifer tests ranged from 25 to 850 feet squared per day, horizontal hydraulic conductivities ranged from 2.5 to 85 feet squared per day, and intrinsic permeabilities ranged from 0.8 to 23 micrometers squared. Fossils identified in core samples include palynomorphs, dinoflagellates, and foraminifers.

Maryland↗

USGS2019

Evaluation of chemical and hydrologic processes in the eastern Snake River Plain Aquifer based on results from geochemical modeling, Idaho National Laboratory, eastern Idaho

Nuclear research activities at the U.S. Department of Energy (DOE) Idaho National Laboratory (INL) produced liquid and solid chemical and radiochemical wastes that were disposed to the subsurface resulting in detectable concentrations of some waste constituents in the eastern Snake River Plain (ESRP) aquifer. These waste constituents may affect the water quality of the aquifer and may pose risks to the eventual users of the aquifer water. To understand these risks to water quality the U.S. Geological Survey, in cooperation with the DOE, conducted geochemical mass-balance modeling of the ESRP aquifer to improve the understanding of chemical reactions, sources of recharge, mixing of water, and groundwater flow directions in the shallow (upper 250 feet) aquifer at the INL. Modeling was conducted using the water chemistry of 127 water samples collected from sites at and near the INL. Water samples were collected between 1952 and 2017 with most of the samples collected during the mid-1990s. Geochemistry and isotopic data used in geochemical modeling consisted of dissolved oxygen, carbon dioxide, major ions, silica, aluminum, iron, and the stable isotope ratios of hydrogen, oxygen, and carbon. Geochemical modeling results indicated that the primary chemical reactions in the aquifer were precipitation of calcite and dissolution of plagioclase (An 60 ) and basalt volcanic glass. Secondary minerals other than calcite included calcium montmorillonite and goethite. Reverse cation exchange, consisting of sodium exchanging for calcium on clay minerals, occurred near site facilities where large amounts of sodium were released to the ESRP aquifer in wastewater discharge. Reverse cation exchange acted to retard the movement of wastewater-derived sodium in the aquifer. Regional groundwater inflow was the primary source of recharge to the aquifer underlying the Northeast and Southeast INL Areas. Birch Creek (BC), the Big Lost River (BLR), and groundwater from BC valley provided recharge to the North INL Area, and the BLR and groundwater from BC and Little Lost River (LLR) valleys provided recharge to the Central INL Area. The BLR, groundwater from the BLR and LLR valleys and the Lost River Range, and precipitation provided recharge to the Northwest and Southwest INL Areas. The primary source of recharge west and southwest of the INL was groundwater inflow from BLR valley. Upwelling geothermal water was a small source of recharge at two wells. Aquifer recharge from surface water in the northern, central, and western parts of the INL indicated that the aquifer in these areas was a dynamic, open system, whereas the aquifer in the eastern part of the INL, which receives little recharge from surface water, was a relatively static and closed system. Sources of recharge identified from isotope ratios and geochemical modeling (major ion concentrations) were nearly identical for the North, Northeast, Southeast, and Central INL Areas, which indicated that both methods probably accurately identified the sources of recharge in these areas. Conversely, isotope ratios indicated that the BLR and groundwater from the LLR valley provided most recharge to the western parts of the Northwest and Southwest INL Areas, whereas geochemical modeling results indicated a smaller area of recharge from the BLR and groundwater from the LLR valley, a larger area of recharge from the Lost River Range, and recharge of groundwater from the BLR valley that extended to the west INL boundary. The results from geochemical modeling probably were more accurate because major ion concentrations, but not isotope ratios, were available to characterize groundwater from the BLR valley and the Lost River Range. Sources of recharge identified with a groundwater flow model (using particle tracking) and geochemical modeling were similar for the Northeast and Southeast INL Areas. However, differences between the models were that the geochemical model represented (1) recharge of groundwater from the Lost River Range in the western part of the INL, whereas the flow model did not, (2) recharge of groundwater from the BC and BLR valleys extending farther south and east, respectively, than the flow model, and (3) more recharge from the BLR in the Southwest INL Area than the flow model. Mixing of aquifer water beneath the INL included (1) mixing of regional groundwater and water from the BC valley in the Northeast and Southeast INL Areas and (2) mixing of surface water (primarily from the BLR) and groundwater across much of the North, Central, Northwest, and Southwest INL Areas. Localized recharge from precipitation mixed with groundwater in the Northwest and Southwest INL Areas, and localized upwelling geothermal water mixed with groundwater in the Central and Northeast INL Areas. Flow directions of regional groundwater were south in the eastern part of the INL and south-southwest at downgradient locations. Groundwater from the BC and LLR valleys initially flowed southeast before changing to south-southwest flow directions that paralleled regional groundwater, and groundwater from the BLR valley initially flowed south before changing to a southsouthwest direction. Wastewater-contaminated groundwater flowed south from the Idaho Nuclear Technology and Engineering Center (INTEC) infiltration ponds in a narrow plume, with the percentage of wastewater in groundwater decreasing due to dilution, dispersion, and (or) degradation from about 60‒80 percent wastewater 0.7‒0.8 mile (mi) south of the INTEC infiltration ponds to about 1.4 percent wastewater about 15.5 mi south of the INTEC infiltration ponds. Wastewater contaminated groundwater flowed southeast and then southwest from the Naval Reactors Facility industrial waste ditch, with the percentage of wastewater in groundwater decreasing from about 100 percent wastewater adjacent to the waste ditch to about 2 percent wastewater about 0.6 mi south of the waste ditch.

Idaho↗

USGS2023

Determining three-dimensional hydrologic processes in the eastern Snake River Plain aquifer using geochemical mass-balance modeling, Idaho National Laboratory, eastern Idaho, with contributions by Treinen, K.C.

Waste constituents discharged to the eastern Snake River Plain aquifer at the U.S. Department of Energy (DOE) Idaho National Laboratory (INL) pose risks to the water quality of the aquifer. To understand these risks, the U.S. Geological Survey, in cooperation with the DOE, used geochemical mass-balance modeling to identify three-dimensional hydrologic processes in that portion of the aquifer underlying the southwestern part of the INL that affect the movement of groundwater and waste constituents. Modeling was performed using water chemistry of 74 water samples collected from 30 wells. Fifty-four of the water samples were collected from 11 wells equipped with multilevel monitoring systems with vertically discrete sampling zones that encompass the upper 750 feet of the aquifer. Water samples from these multilevel wells were collected during 2007‒13, a period when conditions in the aquifer were approximately steady-state because there was little or no recharge from the Big Lost River. The primary source of water in groundwater at the multilevel wells during 2007‒13 was the Big Lost River. Other sources of water include groundwater from the Little Lost River valley, precipitation, and wastewater. Horizontal groundwater-flow directions appear to be similar in both the shallow and deep parts of the aquifer, and surface-water sources of water in most deep groundwater shows that groundwater moves downward. Surface-water sources of water in deep groundwater noticeably decrease within and below the Matuyama flow and associated sedimentary interbeds, which indicates that these units are semi-impermeable and retard the downward movement of groundwater.

Idaho↗

USGS1996

Oxygen transport and pyrite oxidation in unsaturated coal-mine spoil

An understanding of the mechanisms of oxygen (0 2 ) transport in unsaturated mine spoil is necessary to design and implement effective measures to exclude 0 2 from pyritic materials and to control the formation of acidic mine drainage. Partial pressure of oxygen (Po 2 ) in pore gas, chemistry of pore water, and temperature were measured at different depths in unsaturated spoil at two reclaimed surface coal mines in Pennsylvania. At mine 1, where spoil was loose, blocky sandstone, Po 2 changed little with depth, decreasing from 21 volume percent (vol%) at the ground surface to a minimum of about 18 vol% at 10 m depth. At mine 2, where spoil was compacted, friable shale, Po 2 decreased to less than 2 vol% at depth of about 10 m. Although pore-water chemistry and temperature data indicate that acid-forming reactions were active at both mines, the pore-gas data indicate that mechanisms for 0 2 transport were different at each mine. A numerical model was developed to simulate 0 2 transport and pyrite oxidation in unsaturated mine spoil. The results of the numerical simulations indicate that differences in 0 2 transport at the two mines can be explained by differences in the air permeability of spoil. Po 2 changes little with depth if advective transport of 0 2 dominates as at mine 1, but decreases greatly with depth if diffusive transport of 0 2 dominates, as in mine 2. Model results also indicate that advective transport becomes significant if the air permeability of spoil is greater than 10 -9 m 2 , which is expected for blocky sandstone spoil. In the advective-dominant system, thermally-induced convective air flow, as a consequence of the exothermic oxidation of pyrite, supplies the 0 2 to maintain high Po 2 within the deep unsaturated zone.

Conference Paper↗

USGS2008

Pre- and post-eruptive investigations of gas and water samples from Mount St. Helens, Washington, 2002 to 2005

Samples of gas and water from thermal springs in Loowit and Step canyons and creeks that drain the crater at Mount St. Helens have been collected since October 2004 to monitor the flux of dissolved magmatic volatiles in the hydrologic system. The changing composition of the waters highlights a trend that began as early as 1994 and includes decreasing SO 4 and Cl concentrations and large increases in HCO 3 . Geochemical models indicate that mineral sources and sinks are not the main controls on the changing water chemistry, and carbon and helium isotopes indicate that their sources in the gases and waters have remained unchanged during this time. The present-day molar ratios of C, S, and Cl in the springs approximate ratios measured in plume emissions in August 2005 and provide supporting evidence that changes in water chemistry most likely reflect changes in the release rates of sulfur gases, HCl, and CO 2 from the magma and a varying degree of efficiency of gas scrubbing by the overlying water. Results from coupled chemical analyses and discharge measurements on the creeks yield an estimate of the dissolved flux of magmatic HCl, SO 2 , and CO 2 of around 5.2, 4.7, and 22 metric tons per day, respectively.

Washington↗

USGS2007

Ground-Water Quality of the Northern High Plains Aquifer, 1997, 2002-04

An assessment of ground-water quality in the northern High Plains aquifer was completed during 1997 and 2002-04. Ground-water samples were collected at 192 low-capacity, primarily domestic wells in four major hydrogeologic units of the northern High Plains aquifer-Ogallala Formation, Eastern Nebraska, Sand Hills, and Platte River Valley. Each well was sampled once, and water samples were analyzed for physical properties and concentrations of nitrogen and phosphorus compounds, pesticides and pesticide degradates, dissolved solids, major ions, trace elements, dissolved organic carbon (DOC), radon, and volatile organic compounds (VOCs). Tritium and microbiology were analyzed at selected sites. The results of this assessment were used to determine the current water-quality conditions in this subregion of the High Plains aquifer and to relate ground-water quality to natural and human factors affecting water quality. Water-quality analyses indicated that water samples rarely exceeded established U.S. Environmental Protection Agency public drinking-water standards for those constituents sampled; 13 of the constituents measured or analyzed exceeded their respective standards in at least one sample. The constituents that most often failed to meet drinking-water standards were dissolved solids (13 percent of samples exceeded the U.S. Environmental Protection Agency Secondary Drinking-Water Regulation) and arsenic (8 percent of samples exceeded the U.S. Environmental Protection Agency Maximum Contaminant Level). Nitrate, uranium, iron, and manganese concentrations were larger than drinking-water standards in 6 percent of the samples. Ground-water chemistry varied among hydrogeologic units. Wells sampled in the Platte River Valley and Eastern Nebraska units exceeded water-quality standards more often than the Ogallala Formation and Sand Hills units. Thirty-one percent of the samples collected in the Platte River Valley unit had nitrate concentrations greater than the standard, 22 percent exceeded the manganese standard, 19 percent exceeded the sulfate standard, 26 percent exceeded the uranium standard, and 38 percent exceeded the dissolved-solids standard. In addition, 78 percent of samples had at least one detectable pesticide and 22 percent of samples had at least one detectable VOC. In the Eastern Nebraska unit, 30 percent of the samples collected had dissolved-solids concentrations larger than the standard, 23 percent exceeded the iron standard, 13 percent exceeded the manganese standard, 10 percent exceeded the arsenic standard, 7 percent exceeded the sulfate standard, 7 percent exceeded the uranium standard, and 7 percent exceeded the selenium standard. No samples exceeded the nitrate standard. Thirty percent of samples had at least one detectable pesticide compound and 10 percent of samples had at least one detectable VOC. In contrast, the Sand Hills and Ogallala Formation units had fewer detections of anthropogenic compounds and drinking-water exceedances. In the Sand Hills unit, 15 percent of the samples exceeded the arsenic standard, 4 percent exceeded the nitrate standard, 4 percent exceeded the uranium standard, 4 percent exceeded the iron standard, and 4 percent exceeded the dissolved-solids standard. Fifteen percent of samples had at least one pesticide compound detected and 4 percent had at least one VOC detected. In the Ogallala Formation unit, 6 percent of water samples exceeded the arsenic standard, 4 percent exceeded the dissolved-solids standard, 3 percent exceeded the nitrate standard, 2 percent exceeded the manganese standard, 1 percent exceeded the iron standard, 1 percent exceeded the sulfate standard, and 1 percent exceeded the uranium standard. Eight percent of samples collected in the Ogallala Formation unit had at least one pesticide detected and 6 percent had at least one VOC detected. Differences in ground-water chemistry among the hydrogeologic units were attributed to variable depth to water, depth of the well screen below the water table, reduction-oxidation conditions, ground-water residence time, interactions with surface water, composition of aquifer sediments, extent of cropland, extent of irrigated land, and fertilizer application rates.

Scientific Investigations Report↗

USGS2000

Arsenic concentration and selected geochemical characteristics for ground water and aquifer materials in southeastern Michigan

Fifty-six private wells, 20 public wells and 38 monitoring wells in ten counties in southeastern Michigan were sampled to determine the concentration of naturally-occurring arsenic and specific geochemical parameters. The majority of ground water samples were analyzed for pH, dissolved oxygen, oxidation/reduction potential, specific conductance, major ions, dissolved and suspended organic carbon, and arsenic. Selected samples were analyzed for minor elements, nutrients, the isotope ratio of carbon and the concentration of tritium. The Mississippian Marshall Sandstone comprises a major aquifer in southeastern Michigan. To compare the lithology of the Marshall Aquifer to water chemistry, two new wells were drilled through the Marshall Sandstone to the underlying Coldwater Shale. Depth-specific bedrock and water samples were collected from these wells. For public and private drinking-water wells, the lowest concentration detected by USGS analysis was <1 microgram per liter and the highest was 220 micrograms per liter. Arsenic concentrations near or exceeding the current USEPA standard of 50 micrograms per liter occurred in ground water from each of the major aquifers in the study area. In the two newly-drilled wells, the lowest concentration detected by the USGS was <1 microgram per liter at about 350 ft below land surface and the highest concentration of 140 micrograms per liter was detected at around 50 ft below land surface. The data from this study may be used to indicate well characteristics and water chemistry factors that are related to arsenic in ground water in southeastern Michigan.

Michigan↗