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Sources and risk factors for nitrate, pathogens, and fecal contamination of private wells in rural southwestern Wisconsin, USA

Household well water can be degraded by contaminants from the land's surface, but private well owners lack means to protect the source water from neighboring disturbances. Rural residents of southwestern Wisconsin, USA, rely on private well water, and the combination of land use and fractured carbonate bedrock makes groundwater vulnerable to contamination. To identify the extent, sources, and risk factors of private well contamination, randomly selected wells sampled during two-day periods in fall (n = 301) and spring (n = 529) were analyzed for nitrate and indicator bacteria, and a subset (n = 138) was sampled across four seasonal events for analysis of pathogens and microbial source tracking markers by quantitative polymerase chain reaction. Risk factors representing land use, hydrology, geology, and well construction were analyzed for associations with contamination in multivariable models. The importance of risk factors varied by contaminant, illustrating the multifaceted nature of rural groundwater quality. Nitrate contamination was associated with agricultural land use, and wells with casings that extended below a shale aquitard accessed less contaminated water than those drawing water from above it. Human fecal microbes were detected in 64 wells (46%), and rainfall was the key risk factor for contamination, indicating that wastewater from septic systems was available to contaminate wells when transport conditions were favorable. Manure microbes from cattle/ruminants and pigs were detected in 33 and 13 wells, respectively, and concentrations increased with the hectarage of cultivated land near wells. Pathogen genes for viruses, bacteria, and protozoa were detected in 66 wells (48%), including more detections of zoonotic than human-specific pathogens, and human Bacteroides , an indicator of wastewater, was an equivocal predictor of pathogen presence in private wells. Characterizing important elements of the setting, like geology, and identifying sources and risk factors for contaminants can inform landscape-level policies to protect groundwater quality.

Wisconsin

Decoding the oxidative digestion mechanism for polystyrene nanoplastic detection in the Great Lakes using a customizable Raman spectral processing algorithm

Despite the concerns surging around nanoplastics (NPs) regarding their prevalence and bioavailability in freshwater systems, robust detection of NPs in complex environmental matrices is hindered by the lack of standardized sample pretreatment and a mechanistic understanding of oxidative digestion. Here, we systematically investigate the interaction between hydrogen peroxide (H 2 O 2 ) and polystyrene (PS) NPs during digestion in deionized (DI) water and four environmental matrices from in and around the Great Lakes Basin. To facilitate high-throughput analysis, we develop Pre_peak, a customizable Raman spectral processing algorithm that achieves >99% accuracy for both NP identification and interference rejection, allowing reliable NP quantification via pixel counting and systematic decoding of the oxidative digestion mechanisms. In DI water, varying H 2 O 2 doses from 0 to 30% has negligible effects on the recovery and Raman signal intensity of PS NPs over 24 hours of digestion. However, morphological changes and aggregation of PS NPs are observed when the H 2 O 2 dose exceeds 20%. Prolonged digestion further leads to progressive NP loss. In natural waters, the optimal dosage and digestion duration depend on matrix characteristics, including dissolved organic matter (DOM) and ion composition. This study provides mechanistic insights into NP–oxidant interactions and underscores the need for matrix-tailored digestion protocols to advance standardized NP detection in freshwater environments.

Great Lakes

Flood-Inundation Maps of the Current and Jacks Fork Rivers including the Ozark National Scenic Riverways, Southeast Missouri, 2023

Digital flood-inundation maps for a 131.8-mile reach of the Current River and a 44.6-mile reach of the Jacks Fork River, in southeast Missouri, were created by the U.S. Geological Survey (USGS) in cooperation with the Ozark Foothills Regional Planning Commission and the South Central Ozark Council of Governments. The maps also encompass the 134 miles of the Current and Jacks Fork Rivers within the Ozark National Scenic Riverways, which is the first national park area to protect a river system. The flood-inundation maps, which can be accessed through the USGS Flood Inundation Mapping Program website at https://water.usgs.gov/osw/flood_inundation/ , depict estimates of the areal extent and depth of flooding corresponding to selected water levels (hereafter referred to as “stages”) at eight reference USGS streamgages—five on the Current River (USGS station numbers 07064440, 07064533, 07066510, 07067000, and 07068000) and three on the Jacks Fork River (USGS station numbers 07065200, 07065495, and 07066000). Near-real-time stages at these streamgages may be obtained from the USGS National Water Information System at https://doi.org/10.5066/F7P55KJN or the National Weather Service National Water Prediction Service at http://water.noaa.gov/ , which also forecasts flood hydrographs at four of these sites (USGS station numbers 07067000, 07068000, 07065495, and 07066000). Flood profiles were computed for seven of the eight map reaches by means of two-dimensional hydraulic models and the remaining reach by a one-dimensional hydraulic model. The models were calibrated by using stage-streamflow relations or streamflow measurements at the USGS streamgages and from high-flow stage measurements from water-level loggers distributed throughout the reaches. The hydraulic models were used to compute water-surface profiles for flood stages at 1-foot intervals referenced to the streamgage datums. The profile stages ranged from the National Weather Service “action stage” or near bankfull, to a stage exceeding the highest recorded water level at each streamgage. The simulated water-surface profiles were then combined with a digital elevation model (derived from light detection and ranging data having a nonvegetated vertical accuracy of a maximum 10-centimeter root mean square error) to delineate the area flooded at each water level and the associated water depths. The availability of these maps, along with information regarding current stage from the USGS streamgage and forecasted high-flow stages from the National Weather Service, will provide emergency management personnel, resource managers, and residents with information that is critical for flood-response activities such as evacuations and road closures, as well as for postflood recovery efforts.

Missouri

Geophysical identification of potential groundwater – surface water interactions in the Bonita Peak Mining District, San Juan County, Colorado

This report includes the results and interpretation of geophysical investigations to aid in the location, identification, and conceptual site model (CSM) development of the near surface groundwater and surface water hydrology of the Upper Cement Creek and California Gulch of the Animas Rivers within the Bonita Peak Mining Districts (BPMD). Mine influenced water (MIW) from numerous mine adits within the BPMD has altered the geochemistry and ecology of these ground and surface waters. Many studies of varying scales have investigated the geology, hydrogeology, geochemistry, and aqueous chemistry of these adits and impacted areas. Field investigations using non-invasive geophysical methods were conducted in the summer of 2019 to aid in identifying potential groundwater inputs to these streams and further the CSM of the near surface within and along these streams. Two field deployments were completed in August and September of 2019. In August 2019, Phase 1 was completed using multifrequency electromagnetic induction (EMI) and thermal infrared imaging (TIR) to measure the bulk electrical conductivity, magnetic susceptibility, and the temperature response at known and suspected groundwater seeps into the Upper Cement Creek and California Gulch stretches of these alpine streams. Results and interpretation from Phase 1 were used to co-locate stretches of these streams for further detailed fiber optic distributed temperature system (FODTS) monitoring of the temperature dynamics for submeter identification of potential groundwater seeps during Phase 2. Phase 2 included additional EMI measurements, FODTS measurements, and repeated some Phase 1 measurements for improved data quality. All these data were used for the combined qualitative interpretation identifying seep locations. The data from both Phase 1 and Phase 2 are available in the USGS data release at: https://www.sciencebase.gov/catalog/item/5f18a30082cef313ed84879b. These data include detailed near-surface electrical conductivity and magnetic susceptibility mapping, discrete TIR imaging, and several kilometers of FODTS data. These data were georeferenced and used to identify potential groundwater seeps into these streams. The results indicate a complex near surface geophysical and hydrogeologic regime. Seeps are classified and spatially correlated to the EMI, TIR, and geochemical sampling results. This report is a thorough compilation of the geophysical field efforts in the summer of 2019, the data processing, and interpretations of these data. These data alone should not be used for final interpretations of the complex hydrogeology within these alpine systems. Rather, these data should be combined with other known data from various investigations to further refine the CSM and guide decisions for future investigations, watershed protective measures, and other site decisions. Geographical information system (GIS) layers of these results are available to project managers for such integration and combined interpretations.

Colorado

Tracking baseflow supply dynamics using SWOT data from small groundwater-dominated lakes

In situ surface-water monitoring strategies are biased towards larger perennial streams and lakes and are generally not designed to track mechanisms of baseflow supply contributed by the dynamic storage of aquifers. Additionally, small (< 1 km 2 ) groundwater-influenced lakes and wetlands globally have little in situ monitoring infrastructure. We explored the utility of remotely sensed Surface Water Ocean Topography Satellite (SWOT) data, collected from 2023 onward, to characterise the seasonal and multi-year water-level trends of groundwater flow-through kettle lakes distributed across the permeable sediments of eastern Massachusetts, USA. This analysis indicated that water levels for kettle lakes with areas down to approximately 0.05 km 2 are resolvable in the study area. Our examination of 17 kettle lakes found that SWOT water-surface elevation data closely tracked groundwater levels in adjacent monitoring wells where available, including the timing of seasonal patterns (highest levels generally in late spring), although there was some variation between years and there was a substantial lag in the timing of high water levels for a lake located downgradient from a 30-m-thick vadose zone. Furthermore, SWOT-observed water-level increases in kettle lakes tracked with baseflow increases in two adjacent groundwater-dominated streams, as would be expected from increased hydraulic gradients. Unlike spectral remote sensing, SWOT data are generally not affected by cloud cover, resulting in a potential for groundwater-dominated lakes to be sentinels of dynamic storage patterns, including identification of baseflow drought lags, which are currently ill-defined hydrological processes. SWOT monitoring of groundwater-influenced surface waters shows potential for augmenting existing monitoring wells and streamgages as continuous monitors of groundwater levels and baseflow supply in permeable terrain.

Massachusetts

Assessing future hydrologic extremes using an integrated hydrology and river operations model in the Russian River watershed

Study region The Russian River watershed, situated in coastal, northern California, experiences hydrologic extremes, including periodic droughts and flooding. Water managers are working to maintain sustainable water supplies and environmental flows, while mitigating flood risks. Study focus This paper introduces an integrated hydrology and river operations model for the Russian River watershed. This model is distinct from models in previous studies because it represents surface-groundwater interactions and uses climate forcings to estimate dynamic water use demands that are superimposed onto both reservoir operations and water supply constraints. The model was used to examine three historical (1990–2015) and eight future (2016–2099) water use and climate change scenarios. New hydrological insights for the region The direct connection between streams and aquifers facilitated both annual aquifer replenishment by high winter streamflows and streamflow depletion by groundwater wells (19 % of pumped groundwater in alluvial aquifers from stream leakage) during critical low flow periods. Simulated streamflow changes included 59 % longer and 54 % more severe streamflow droughts, 26 % lower seasonal low streamflows, and up to 125 % higher peak streamflows, averaged over future climate and water use scenarios, suggesting increased future flood and water availability risks. Results showed the importance of reservoir operations for mitigating the impacts of increased hydroclimatic volatility, despite a decrease in reservoir reliability at Lake Mendocino, suggesting that reservoir management may be used to decrease future risks.

California

Estimated hydrogeologic, spatial, and temporal distribution of self-supplied domestic groundwater withdrawals for aquifers of the Virginia Coastal Plain

Water use from private-domestic wells accounts for nearly 40 percent of total groundwater withdrawals in the Virginia Coastal Plain Physiographic Province (henceforth called the Virginia Coastal Plain). However, because self-supplied domestic water use generally falls below the Virginia Department of Environmental Quality (VDEQ) reporting and management threshold of 300,000 gallons per month, quantifying these withdrawals is challenging. This report builds upon the foundation of previous U.S. Geological Survey investigations by providing revised techniques to improve estimates of the aquifer source, spatial distribution, and monthly magnitude of these groundwater withdrawals. The aquifer sources of private-domestic wells in the Virginia Coastal Plain were estimated by cross-referencing 8,264 well records from the VDEQ and the Virginia Department of Health to a digital model of the Virginia Coastal Plain hydrogeologic framework. This analysis highlights the regional importance of the Yorktown-Eastover, Potomac, and surficial aquifers. Collectively, these three aquifers account for 80 percent of self-supplied domestic groundwater withdrawals. The population using self-supplied domestic water was estimated using census blocks, well-use ratios, building footprints, and land-use and land-cover data to produce a high-resolution, disaggregated, raster-based dataset. This approach improves upon previous models at the census-block or road-network scale by reducing the low-density spread of the self-supplied domestic population across undeveloped areas and concentrating the population and its corresponding water use in the areas where it is most likely to occur. Results show that an estimated 475,332 people comprise the 2020 self-supplied domestic population of the Virginia Coastal Plain, an increase of 5.7 percent since 2010, and the greatest concentrations of self-supplied domestic population surround large cities. Estimates could be further refined with the addition of current and complete spatial data on public water-system service areas. The quantity of water used by the self-supplied domestic population was estimated by modifying published state per-capita water-use coefficients with the corresponding monthly variability assessed from Virginia Coastal Plain public water-system withdrawal data. This analysis estimates an average increase of 12 percent from June through August and an average decrease of 8 percent from December through March from the baseline annual average of 80 gallons per day per capita, which generally matches similar studies in the eastern United States. The application of these revised methodologies for the estimation of private-domestic wells and the self-supplied domestic population improves understanding of domestic groundwater use in the Virginia Coastal Plain across hydrogeologic, spatial, and temporal scales. These revisions help better inform water-resource managers and decision makers and support higher resolution groundwater modeling. Furthermore, these methods are transferrable to other areas where self-supplied domestic water withdrawals are important to the overall water budget.

Virginia

Quality of groundwater used for domestic supply in the Gilroy-Hollister basin and surrounding areas, California, 2022

More than 2 million Californians rely on groundwater from domestic wells for drinking-water supply. This report summarizes a 2022 California Groundwater Ambient Monitoring and Assessment Priority Basin Project (GAMA-PBP) water-quality survey of 33 domestic and small-system drinking-water supply wells in the Gilroy-Hollister Valley groundwater basin and the surrounding areas, where more than 20,000 residents are estimated to utilize privately owned domestic wells. The study area includes the Llagas subbasin in the north, the North San Benito subbasin in the south, and the surrounding uplands. The study was focused on groundwater resources used for domestic drinking-water supply, which are mostly drawn from shallower parts of aquifer systems rather than those of groundwater resources used for public drinking-water supply in the same area. This assessment characterized the quality of ambient groundwater in the aquifer before filtration or treatment, rather than the quality of drinking water delivered to the tap. To provide context, the measured concentrations of constituents in groundwater were compared to Federal and California State regulatory and non-regulatory benchmarks for drinking-water quality. A grid-based method was used to estimate the areal proportions of groundwater resources used for domestic drinking wells that have water-quality constituents present at high concentrations (above the benchmark), moderate concentrations (between one-half of the benchmark and the benchmark for inorganic constituents, or between one-tenth of the benchmark and the benchmark for organic constituents), and low concentrations (less than one-half or one-tenth the benchmark for inorganic and organic constituents, respectively). This method provides statistically representative results at the study-area scale and permits comparisons to other GAMA-PBP study areas. In the study area, inorganic constituents in groundwater were greater than regulatory benchmarks (U.S. Environmental Protection Agency [EPA] or State of California maximum contaminant levels [MCLs]) for public drinking-water quality in 24 percent of domestic groundwater resources. The inorganic constituents present at concentrations greater than MCLs for drinking water were nitrate (as nitrogen), barium, chromium, and selenium. Total dissolved solids (TDS) or manganese were present at concentrations greater than the secondary maximum contaminant levels (SMCLs) that the State of California uses as aesthetic-based benchmarks in 48 percent of domestic groundwater resources. No volatile organic compounds or pesticide constituents were present at concentrations greater than regulatory benchmarks. Total coliform bacteria and enterococci were detected in 4 percent of domestic groundwater resources. Per- and polyfluoroalkyl substances (PFAS) were detected in 19 percent of domestic groundwater resources, and 10 percent had concentrations greater than recently enacted (April 2024) EPA MCLs. Physical and chemical factors from natural and anthropogenic sources that could affect the groundwater quality were evaluated using results from statistical testing of associations between constituent concentrations and potential explanatory variables. In this study, relevant physical factors include well construction characteristics, groundwater age, site proximity to groundwater recharge or discharge zones, and potential sources of contamination. Relevant chemical factors include the initial chemistry of the recharge water, the mineralogy of the aquifer sediments, and the subsequent shifts in chemistry as biologic and geologic reactions alter groundwater in the subsurface. Nitrate concentrations were correlated to agricultural land use, distance from the boundary of the Gilroy-Hollister Valley groundwater basin, and the proportion of modern (post-1950s) water captured by the well. Denitrification under anoxic redox conditions can mitigate some nitrate derived from fertilizer application. Total dissolved solids primarily were derived from water-rock interactions with soils and aquifer materials in the study area, but there were high concentrations where agricultural practices contributed additional TDS. Mineralogy of aquifer sediments and rocks also affect barium, selenium, boron, and chromium concentrations in the Gilroy-Hollister Valley groundwater basin. PFAS were positively correlated with urban land use and the proportion of modern water captured by the well.

California

Analyzing multi-year nitrate concentration evolution in Alabama aquatic systems using a machine learning model

Rising nitrate contamination in water systems poses significant risks to public health and ecosystem stability, necessitating advanced modeling to understand nitrate dynamics more accurately. This study applies the long short-term memory (LSTM) modeling to investigate the hydrologic and environmental factors influencing nitrate concentration dynamics in rivers and aquifers across the state of Alabama in the southeast of the United States. By integrating dynamic data such as streamflow and groundwater levels with static catchment attributes, the machine learning model identifies primary drivers of nitrate fluctuations, offering detailed insights into the complex interactions affecting multi-year nitrate concentrations in natural aquatic systems. In addition, a novel LSTM-based approach utilizes synthetic surface water nitrate data to predict groundwater nitrate levels, helping to address monitoring gaps in aquifers connected to these rivers. This method reveals potential correlations between surface water and groundwater nitrate dynamics, which is particularly meaningful given the lack of water quality observations in many aquifers. Field applications further show that, while the LSTM model effectively captures seasonal trends, limitations in representing extreme nitrate events suggest areas for further refinement. These findings contribute to data-driven water quality management, enhancing understanding of nitrate behavior in interconnected water systems.

Alabama

PFAS sampling activities in the U.S. Geological Survey national networks

Per- and polyfluoroalkyl substances (PFAS), frequently called “forever chemicals,” are used for a wide variety of industrial purposes and are often found in common household and industrial items such as firefighting foams, non-stick cookware, and water-resistant materials. The contamination of water, air, and soil by PFAS is a national and global issue due to their widespread occurrence in multiple applications and resistance to biodegradation and other traditional treatment processes. Research indicates that many PFAS can be emitted to the atmosphere and transported and deposited long distances from the source. The U.S. Geological Survey (USGS) Water Resources Mission Area received funding to implement a national-scale sampling effort to assess PFAS occurrence. To follow agency directives, the National Water Quality Network (NWQN) added PFAS sample monitoring for both surface water and groundwater, and also added PFAS monitoring to selected sites in the National Atmospheric Deposition Program (NADP).

General Information Product

James Buttle review: The characteristics of baseflow resilience across diverse ecohydrological terrains

The dynamic storage of aquifers is the portion of groundwater that can potentially drain to any given point along a stream to create baseflow. Baseflow typically occurs year-round in perennial streams, though the characteristics and stability of dynamic storage are often most important to instream processes during extended dry periods (without precipitation and snowmelt) when runoff and quickflows are minimised. The term ‘baseflow resilience’ is defined for this review as the tendency of baseflow in streams to maintain a consistent volume and water quality year to year while under stress from climate variability and extremes, along with anthropogenic stressors such as water withdrawals, land use change, and water quality degradation. ‘Baseflow resilience’ has, in part, a user-defined meaning spanning water supply and water quality variables of primary interest. Watershed characteristics that directly impact resilience can often produce non-intuitive feedbacks that enhance some attributes of baseflow while simultaneously impairing others. For example, permeable stream corridor geology creates strong stream-groundwater hydrologic connectivity, yet fast groundwater drainage via preferential high-permeability flowpaths can lead to streamflow not being sustained during extended dry periods. Also, shallow groundwater sources are generally more immediately vulnerable to extreme events, warming, salinization, transpiration, and precipitation drought, compared to deeper groundwater. Yet baseflow drought in streams influenced by deeper groundwater can lag precipitation drought by years, and contaminant legacies may propagate through deep groundwater flowpaths to receiving waters for decades to centuries. Finally, irrigation withdrawals can intercept groundwater that would have drained to streams, and the application of irrigation may leach contaminants from the soil zone by unnaturally raising water tables, yet irrigation return flows can sustain baseflow and groundwater-dependent habitats in semiarid areas. This review covers the concept of hydrologic resilience in the context of stream baseflow processes and summarises the common hydrogeological controls on, and multiscale stressors of, dynamic groundwater storage. Further, we present several quantitative metrics to assess a range of water supply to water quality baseflow characteristics using both broadly available and boutique data types, a subset of which are demonstrated using data from the Delaware River Basin, USA.

Delaware River Basin

Hydrogeology and groundwater quality in the Snake River alluvial aquifer at Jackson Hole Airport, Wyoming, 2011–20

The Snake River alluvial aquifer underlying the Jackson Hole Airport (JHA) in northwest Wyoming is an important source of water used for domestic, commercial, and irrigation purposes by the airport and nearby residents. The U.S. Geological Survey, in response to previously identified water-quality concerns in the area, monitored and evaluated changes in hydrogeologic characteristics and groundwater-quality conditions of the alluvial aquifer during 2011–20. During that period, the Jackson Hole Airport made several changes that potentially improved water quality at and downgradient from the airport. Well, water level, and hydrogeologic data were collected from the alluvial aquifer to identify hydrogeologic characteristic and groundwater quality changes. Additionally, results of statistical tests were applied to water-quality results to evaluate trends in selected physical properties and constituent concentrations with time. The trends of those data show that water quality did improve overall during the study period compared to previously collected data. Presumably, these trends are in response to the changes in the aircraft deicing/anti-icing fluid (ADAF) formulation used by the JHA, the many JHA infrastructure improvements made during 2011–20, the degradation of existing ADAFs in subsurface soils and groundwater, or some combination of these possibilities.

Wyoming

Hydrogeology, karst, and groundwater availability of Monroe County, West Virginia

Monroe County is in southeastern West Virginia, encompassing an area of 474 square miles. The area consists of karst and siliciclastic aquifers of Ordovician, Silurian, Devonian, and Mississippian age and is in parts of two physiographic provinces: the Valley and Ridge Province to the east of Peters Mountain, and the Appalachian Plateau Province to the west of Peters Mountain. This study was developed in response to inquiries from the Monroe County Commission requesting assessment of the water resources of the county to better understand the quantity of the county’s groundwater resources, for both current [2023] and future demand, and to provide information to support protection and management of the county’s valuable groundwater resources. Various products were developed for this study that provide knowledge with respect to water availability and contamination susceptibility of the karst aquifers within the county. U.S. Geological Survey (USGS) geologists conducted extensive geologic mapping in support of the project, producing (1) a countywide bedrock geologic map, (2) a countywide hydrogeologic map, and (3) a light detection and ranging (lidar)-derived countywide digital elevation model and associated sinkhole map. A significant part of this work was to map in detail the Greenbrier Group at the formation level, which prior to this study had only partially been completed. The report also includes (4) a description of the lithologic units identified as part of the geologic mapping process. U.S. Geological Survey hydrologists completed several additional products for the hydrology part of the effort, including development of (1) a countywide potentiometric surface (water-table) map, (2) a countywide base-flow stream assessment, (3) countywide water-budget estimates, (4) well log surveys for 15 wells to better understand subsurface controls on groundwater flow within the study area, (5) two groundwater tracer tests to better refine the groundwater divide from the northern and southern parts of the karst aquifer in Monroe County; and finally, based on all available data collected for the study including the potentiometric surface map, geologic map, current [2023] and legacy fluorometric groundwater tracer tests, and base-flow stream assessments, (6) groundwater-basin delineations were reassessed for principal groundwater basins within the Greenbrier aquifer. In Monroe County, four principal hydrogeologic settings produce large yields of water for residential, agricultural, and other uses. The most relied upon water-bearing zone with respect to current [2023] public water supply is from springs along Peters Mountain. These springs are derived from intervals of fractured sandstone and resultant alluvial deposits. Groundwater flows downslope through these permeable alluvial deposits and discharges at the contact with less permeable strata, such as the Reedsville Shale. The second most relied upon water-bearing zone in Monroe County is within the karstic Greenbrier Group aquifer, in which the basal Hillsdale Limestone overlies the less permeable Maccrady Shale. This geologic contact between the Hillsdale Limestone and Maccrady Shale is not only targeted as a source of water for agricultural supply but also is targeted as a source of water for residential supply. The third most relied upon water-bearing zone is composed of shallow perched aquifers within the Greenbrier Group. The discontinuous nature of these perched aquifers makes mapping their extent impossible, but they are related to permeable geologic strata, such as karstified limestones with solutionally enhanced permeability that overlies less permeable shale or chert bedrock. During geologic mapping of the county, several of these perched aquifers were documented in the Pickaway, Union, and Alderson Limestones. A fourth zone consists of springs from Ordovician carbonates at the base of Peters Mountain, which are influenced by sinking streams as well as upwelling along faults. In terms of water quantity, the most sustainable springs are those having deeper-sourced flows. Public supplies are a principal source of water used for residential and commercial supply in the region, accounting for 0.49 million gallons per day (Mgal/d) of fresh-water withdrawals (0.14 Mgal/d of groundwater and 0.35 Mgal/d of surface water) for residential and commercial use and serving 6,645 individuals (49.2 percent of the population). An estimated 6,861 people, (50.8 percent of the population) primarily rely on private wells or other unregulated sources, such as springs, and withdraw 0.55 Mgal/d of groundwater for their residential use. Public water supply in the region is primarily (71.4 percent) derived from springs and augmented by stream withdrawals (backup sources mainly during low-flow periods), with the remaining portion (28.6 percent) derived from groundwater withdrawals from wells. For rural residents, however, 100 percent of their withdrawals are derived from groundwater (wells or springs).

West Virginia

Geology of an area near Brentwood, Williamson County, Tennessee

The lithology and geologic structure of an area near Brentwood, Williamson County, Tennessee, were studied to define the potential aquifers and confining units of the ground-water flow system. Four formations were identified. They are, in descending order, the Bigby-Cannon Limestone, the Hermitage Formation, the Carters Limestone, and the Lebanon Limestone. The Bigby-Cannon Limestone and the Carters Limestone are potential aquifers. The Hermitage Formation and the Lebanon Limestone are confining units. The Bigby-Cannon Limestone and the Hermitage Formation have been affected by recent erosion. Any variation of the Carters Limestone is controlled by pre-Carters erosion of the top of the Lebanon Limestone. The thickness of the Carters Limestone ranges from 65 to 79 feet. Structurally, the area reflects the regional northwest dip. A small scale anti-cline-syncline pair also is evident. This feature is not a result of erosion and also occurs in the T-3 bentonite bed in the Carters Limestone.

Tennessee

A 10-year continuous daily simulation of chloride flux from a suburban watershed in Fairfax County, Virginia, USA

Increasing levels of chloride in surface water are associated with detrimental effects on water quality, aquatic ecosystems, infrastructure, and human health. Numerous mass-balance studies have inferred watershed transport processes by interpreting chloride inputs and outputs, but few represent internal dynamics explicitly. We constructed a coupled water/chloride mass balance model to gain insights into storage, residence time, and transport processes in a 10-km 2 urban watershed. The model, which operates over a 10-year period at a daily time scale, represents storage in a dynamic soil-moisture reservoir, quick-flow runoff from storm events, and slow-flow runoff that sustains streamflow in dry weather. The calibrated model accurately represented (a)the observed transition from a streamflow enrichment regime in cold months to a dilution regime in warmer months, (b) the observed tendency for late-summer concentrations to be higher after winters with heavy snowfall, and (c) a period-of-record downward trend in chloride concentration likely associated with a downward trend in annual snowfall. Estimated chloride inputs averaged 195 metric tons per year, while the average output was 270 metric tons per year. In contrast, estimated storage was only 107 metric tons. The estimated mean residence time in groundwater was 1.27 years. This short residence time indicates that efforts to reduce inputs will manifest as decreased concentrations in streamflow on a management-relevant time scale of several years. The coupled mass balance model yielded insights into internal watershed dynamics that would not be possible from simple input/output analysis; such models can be useful tools for gaining insight into small watershed hydrology and pollutant transport.

Virginia

Groundwater quality near an oil field in a stream-dominated recharge setting, California, USA

Alluvial valley aquifers are important sources of water supply in many areas but effects of co-located oil and gas development on these resources have not been widely reported, especially in settings where recharge is dominated by stream infiltration. Interpreting the presence of geochemical indicators in the context of hydrology, geology, and other factors provides a more complete understanding of the relations between groundwater and sources of oil-field fluids and aids in identifying risks associated with oil and gas development. Groundwater and Salinas River water samples were collected in an alluvial valley near the San Ardo Oil Field in Monterey County, California and analyzed for a wide range of dissolved chemical, gas, and isotopic constituents to determine if oil-field fluids (water and gas from oil-producing and non-producing zones) have mixed with fresh groundwater used for supply. Hydraulic gradients, age-dating tracers, and other geochemical indicators show that recharge from the Salinas River has the potential to dilute oil-field fluids that might migrate or seep into the aquifer. Groundwater and Salinas River water collected downgradient of the San Ardo Oil Field showed little or no evidence of mixing with oil-field fluids. Some samples within the oil field contained trace amounts of hydrocarbons or elevated temperatures, indicating that any potential effects from oil-field activities are minor or have been diluted by recharge from the Salinas River. The two samples with the most geochemical evidence of potential mixing with oil-field fluids (SP-18 and GW-17) were collected west of or along the Los Lobos fault, where naturally occurring hydrocarbons are near the land surface. Those samples are also near active or inactive oil-field wells, and so anthropogenic activities and pathways cannot be ruled out as a cause of trace detections of hydrocarbons and elevated temperatures in the aquifer.

California

Geohydrology of the Cross-Florida Barge Canal area, with special reference to the Ocala vicinity

The Cross-Florida Barge Canal route commences at Palatka on the St. Johns River, about 75 miles upstream from the Atlantic Ocean, and extends 110 miles southwestward across Peninsular Florida into deep water in the Gulf of Mexico near Yankeetown. The canal will be equipped with five locks, each 600 feet long and 84 feet wide, and the channel will be a minimum of 12 feet deep and 150 feet wide. From near Ocala northeastward, the canal channel will replace much of the natural channel of the Oklawaha River, and will be excavated into beds of the so-called shallow sand aquifer of Miocene age and younger, which overlies limestone of the Floridan aquifer. Westward from Ocala, most of the canal will be excavated below the potentiometric surface into limestone and dolomite of the Floridan aquifer. Water levels of Rodman, Eureka, and Inglis Pools will be controlled by dams and spillways with the limited exchange of water between the pools and the aquifers. The water levels in the Summit Pools will fluctuate with the natural changes in the ground-water level of the Floridan aquifer, although the stage of the pool will be controlled partly by the stage held in the Eureka Pool. A dynamic inflow-outflow relationship will exist between the Summit Pool and the Floridan aquifer. The Floridan aquifer in the canal area is 1,000 to 1,200 feet thick and consists of limestone and dolomite of middle Eocene Miocene age, including from older to younger, the Lake City, Avon Park, and Ocala limestones plus permeable sandy, dolomitic limestone in the lower part of the Hawthorn Formation. It is possible that most of the flow to the two major springs in the area occurs in the upper 100 feet or so of the aquifer in the Ocala Limestone. The aquifer is underlain by the Oldsmar limestone of early Eocene age and is overlain by sand, clayey sand, clay and shell beds of Miocene through Holocene age, in thickness from a few feet to 300 feet. The permeable beds overlying the Floridan aquifer constitute the shallow aquifer, while the poorly permeable ones act as confining beds where the Floridan aquifer is under artesian conditions. A north-south line drawn separating the head of Silver Springs on the west from the Oklawaha River on the east marks the approximate western limit of a continuous blanket of materials of Miocene-Pliocene(?) age covering the rocks of the Floridan aquifer. East of the line, much of the aquifer is under artesian conditions, particularly in the Oklawaha River valley, although in some areas east of the valley, direct recharge through thick permeable Miocene-Pliocene(?) sands occurs. West of the line, only scattered remnants of a once continuous Miocene-Pliocene(?) cover remain. Lack of the cover is a result of erosion on the crest and flank of the Ocala Uplift, a broad northwest-southeast trending anticlinal upwarp, the axis of which is crossed by the canal route in the Dunnellon area. Over most of this area the Floridan aquifer is unconfined and receives direct recharge through a cover of a few tens of feet of sand and clayey sand of Quaternary age. Tensional stresses during the structural evolution of the Ocala Uplift produced an intersecting system of fractures and normal faults in rocks of the Floridan aquifer. The fractures and faults are important controls for orientation of solution channels and, therefore, for development of ground-water circulation patterns. When the system surface streams, which once drained the Barge Canal area, eroded the poorly permeable Miocene-Pliocene(?) cover from the flanks of the Ocala Uplift, surface runoff was reduced and precipitation began to directly infiltrate the underlying limestones. Now only principal streams remain, such as the Oklawaha and Withlacoochee Rivers and a few short tributaries, while one of the most highly developed subsurface drainage systems in the world has evolved in cavernous limestone of the Floridan aquifer. Two of the larger freshwater springs in the world now discharge from the Floridan aquifer in the canal area. Silver Springs near Ocala discharges an average 531 mgd (million gallons per day) down the 4-mile long Silver River, which flows on poorly permeable beds to the Oklawaha River. Rainbow Springs near Dunnellon discharges on average 468 mgd from numerous orifices in the bed of the 5-mile-long Rainbow River, which flows into the Withlacoochee River. The heads of the springs have migrated to their present positions partly because of a tendency of ground-water levels to decline as permeability in the aquifer is increased due to removal of limestone by solution, and because of mechanical erosion of the limestone in the vicinity of the spring heads. Also, points of principal spring discharges have shifted in the past due to changes in ground-water levels in response to changes in sea level. The subsurface drainage system is continuing to evolve today, as evidenced in part by frequent occurrence of new sinkholes and by the presence of significant amounts of calcium bicarbonate in the spring waters. Rodman Pool, at the east end of the canal, is separated from the Floridan aquifer by poorly permeable materials. The pool's operating water level will be only a few feet above the potentiometric surface at the downstream end, and at or slightly below the potentiometric surface at the upstream end. Little exchange of water between the Rodman Pool and the Floridan aquifer is expected. Eureka Pool, just upstream from Rodman Pool, will also be separated from the Floridan aquifer by poorly permeable beds. However, the stage of the pool will be about 15 feet higher than the natural potentiometric surface at the pool's downstream end, and some seepage into the Floridan aquifer is anticipated through faults and leaky parts of the poorly permeable beds, with a consequent rise in ground-water levels in areas adjacent to the lower end of the pool. Possibilities for particulate contamination of the aquifer will tend to be minimized because of the filtering capacity of the materials through which water must pass to reach the aquifer, although the natural filter will not preclude movement into the aquifer of contaminants which might become dissolved in the pool waters. No significant interchange of water between the pool and the aquifer is expected at the upstream end of the Eureka Pool. Present construction plans indicate an operating stage for Eureka Pool which will range between 38 and 40 feet above mean sea level, although it is possible to dredge the pool deep enough to permit a range in stage of 36 to 40 feet. A backwater effect extending up Silver River from the Eureka Pool is expected to regulate the stage at the head of Silver Springs between 39 and 44 feet above mean sea level if the pool ranges between 36 and 40 feet. If Eureka Pool ranges only between 38 and 40 feet, the range of stage at the head of the springs should be about 41 to 44 feet above mean sea level. From Inglis Lock west, the canal will have direct connection with the Gulf, and canal stage will fluctuate with the Gulf tide. Since the canal stage will be slightly lower than the adjacent ground-water levels along much of the reach, there will be some ground-water inflow to the canal. No significant changes in the existing ground-water regime are expected in the vicinity of Inglis Pool, the first step up in the canal east of the Gulf. Existing ground-water and surface-water levels in the area will not change appreciable, and the natural stage and flow of Rainbow Springs, which will flow by way of Rainbow River into Inglis Pool, should not be affected by canal operations. A possible adverse effect of the canal on the Inglis Pool area could result if sea water is locked up from the Gulf through Inglis Lock. However, the high step of 25 feet at the lock, flushing action of continuous flow from Inglis Pool to the lower reaches of the Withlacoochee River, and use of possible preventive locking procedures should minimize the problem. The potential for adverse effects on the ground-water regime is greatest in the area of the Summit Pool. Through most of the length of the pool, the canal channel will be excavated into limestone of the Floridan aquifer to depths of 12 to 27 feet below the potentiometric surface. Changes that will take place in the ground-water flow system in the Silver Springs drainage area, once the canal is completed, were estimated by flow-net analysis. Variation in aquifer transmissivity was determined by calculating transmissivity in 25 different flow cells surrounding Silver Springs. Transmissivity in the 25 cells averages about 15,600,000 gpd/ft [2,090,000 ft2/day (feet squared)], but transmissivity in the six cells through which the Summit Pool passes ranges from 9,000,000 to 44,000,000 gpd/ft (1,210,000 to 5,900,000 ft2/day). Transmissivity was used to compute static stage of the Summit Pool under given ground-water level conditions. Had the canal existed in May 1968 and had the stage of Eureka Pool been held at 36 feet at the time, the static stage in Summit Pool would have been about 42.1 feet above mean sea level. Thus, a conceptual model of the changes in the potentiometric surface wrought by the finished canal was drawn, and zones of ground-water inflow and outflow were delineated. Most outflow from the Summit Pool to the aquifer should be limited to one 4-mile-long zone along the north side of the pool, about 5 miles south of Silver Springs. It is estimated that a water volume equivalent to about 8 percent of the daily flow of Silver Springs will enter the Summit Pool each day from the southern one-third of the Silver Springs drainage area. A like amount will reenter the aquifer at the main zone of outflow and move toward Silver Springs at an estimated average velocity of about 200 feet per day, if something close to the natural static stage of the pool is maintained by return pumpage of the lockage losses. At a velocity of 200 feet per day, water from the Summit Pool would discharge at Silver Springs about 140 days later. However, any estimate of velocity in the highly cavernous limestone aquifer in the area should be used with caution, because difficult to measure changes in porosity and thickness of major zones of flow may cause large variations in velocity. If all lockage losses are returned to the Summit Pool by pumping from Eureka Pool, no net loss from the Silver Springs drainage area, except for some evaporation from the water surface in the canal and possible leakage around locks, will result from canal operations. The zone of outflow from the Summit Pool to the aquifer will be in a natural potentiometric trough, and the zone of inflow will be in a potentiometric ridge area. The equilibrium water level in the pool will tend to be about 1 foot higher than the altitude of the lowest level in the pre-canal potentiometric trough, and about 2 feet lower than the highest level on the pre-canal potentiometric ridge. West of the Silver Springs drainage area just east of Dunnellon Lock, in the area of a local potentiometric high, the water level in the Summit Pool is expected to be about 15 feet below the natural potentiometric surface. In most areas 2 to 3 miles away from the Summit Pool, effects of the canal on the natural potentiometric surface should be slight. The stage of the Summit Pool, judging from the 36-year record for ground-water level changes and the anticipated indirect effect of the controlled stage in Eureka Pool, should have a maximum of about 10.5 feet with a maximum water level of about 51.5 feet above mean sea level and a minimum of about 41.0 feet above mean sea level. Of particular importance in the Summit Pool is an implementation of well planned construction and operational procedures designed to minimize risks of ground-water contamination.

Florida

Spatial differences in soil nutrients along a hydrographic gradient on floodplains in Dongting Lake

The spatial heterogeneity of soil nutrients is crucial for the water bird and whole floodplain wetland ecosystem in large lakes, and it is influenced by the dramatic water level changes and sedimentation progress in West Dongting Lake (WDL). Soil samples were collected at various soil depths along the Yuan River and Li River that feed into WDL. The concentrations of soil total organic carbon (TOC), total nitrogen (TN), total phosphorus (TP), and soil grain size were tested. The stoichiometric ratios of C, N, P, and the mean value of soil grain size ( Mz ) were calculated. The differences of soil TOC, TN, TP and the stoichiometric ratio at different sites and soil depths were compared. Linear regression was used to explore the relationships of Mz and nutrient concentrations, and relationships between TOC, TN, and TP. Redundancy analysis was used to explore the relationship between soil nutrients, heavy metal concentrations, and plant community diversity. The results showed that the distributions of soil TOC, TN, and TP concentrations differed across regions in west Dongting Lake along the Yuan and Li Rivers. Total organic carbon concentration differed at different sedimentation depths. Soil grain size showed negative effect with soil TOC, TN, and TP concentrations in this region. Plant community diversity correlated positively with soil TOC and negatively with Hg. West Dongting Lake was N limited despite the high wet deposition of N. It could potentially be attributed to the insufficient presence of aerobic environments for microbes during intermittent flooding of the floodplain, coupled with feeble mineralization. This study can provide valuable insights for the conservation of water bird habitats and wetland ecosystems.

West Dongting Lake