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A practical primer on geostatistics

Introduction The Challenge —Most geological phenomena are extraordinarily complex in their interrelationships and vast in their geographical extension. Ordinarily, engineers and geoscientists are faced with corporate or scientific requirements to properly prepare geological models with measurements involving a small fraction of the entire area or volume of interest. Exact description of a system such as an oil reservoir is neither feasible nor economically possible. The results are necessarily uncertain. Note that the uncertainty is not an intrinsic property of the systems; it is the result of incomplete knowledge by the observer. The Aim of Geostatistics —The main objective of geostatistics is the characterization of spatial systems that are incompletely known, systems that are common in geology. A key difference from classical statistics is that geostatistics uses the sampling location of every measurement. Unless the measurements show spatial correlation, the application of geostatistics is pointless. Ordinarily the need for additional knowledge goes beyond a few points, which explains the display of results graphically as fishnet plots, block diagrams, and maps. Geostatistical Methods —Geostatistics is a collection of numerical techniques for the characterization of spatial attributes using primarily two tools: probabilistic models, which are used for spatial data in a manner similar to the way in which time-series analysis characterizes temporal data, or pattern recognition techniques. The probabilistic models are used as a way to handle uncertainty in results away from sampling locations, making a radical departure from alternative approaches like inverse distance estimation methods. Differences with Time Series —On dealing with time-series analysis, users frequently concentrate their attention on extrapolations for making forecasts. Although users of geostatistics may be interested in extrapolation, the methods work at their best interpolating. This simple difference has significant methodological implications. Historical Remarks —As a discipline, geostatistics was firmly established in the 1960s by the French engineer Georges Matheron, who was interested in the appraisal of ore reserves in mining. Geostatistics did not develop overnight. Like other disciplines, it has built on previous results, many of which were formulated with different objectives in various fields. Pioneers —Seminal ideas conceptually related to what today we call geostatistics or spatial statistics are found in the work of several pioneers, including: 1940s: A.N. Kolmogorov in turbulent flow and N. Wiener in stochastic processing; 1950s: D. Krige in mining; 1960s: B. Mathern in forestry and L.S. Gandin in meteorology Calculations —Serious applications of geostatistics require the use of digital computers. Although for most geostatistical techniques rudimentary implementation from scratch is fairly straightforward, coding programs from scratch is recommended only as part of a practice that may help users to gain a better grasp of the formulations. Software —For professional work, the reader should employ software packages that have been thoroughly tested to handle any sampling scheme, that run as efficiently as possible, and that offer graphic capabilities for the analysis and display of results. This primer employs primarily the package Stanford Geomodeling Software (SGeMS) - recently developed at the Energy Resources Engineering Department at Stanford University - as a way to show how to obtain results practically. This applied side of the primer should not be interpreted as the notes being a manual for the use of SGeMS. The main objective of the primer is to help the reader gain an understanding of the fundamental concepts and tools in geostatistics. Organization of the Primer —The chapters of greatest importance are those covering kriging and simulation. All other materials are peripheral and are included for better comprehension of these main geostatistical modeling tools. The choice of kriging versus simulation is often a big puzzle to the uninitiated, let alone the different variants of both of them. Chapters 14, 18, and 19 are intended to shed light on those subjects. The critical aspect of assessing and modeling spatial correlation is covered in chapter 7. Chapters 2 and 3 review relevant concepts in classical statistics. Course Objectives —This course offers stochastic solutions to common problems in the characterization of complex geological systems. At the end of the course, participants should have: an understanding of the theoretical foundations of geostatistics; a good grasp of its possibilities and limitations; and reasonable familiarity with the SGeMS software, thus opening the possibility of practically applying geostatistics.

Open-File Report

Database of the United States Coal Pellet Collection of the U.S. Geological Survey Organic Petrology Laboratory

The Organic Petrology Laboratory (OPL) of the U.S. Geological Survey (USGS) Eastern Energy Resources Science Center in Reston, Virginia, contains several thousand processed coal sample materials that were loosely organized in laboratory drawers for the past several decades. The majority of these were prepared as 1-inch-diameter particulate coal pellets (more than 6,000 pellets; one sample usually was prepared as two pellets, although some samples were prepared in as many as four pellets), which were polished and used in reflected light petrographic studies. These samples represent the work of many scientists from the 1970s to the present, most notably Ron Stanton, who managed the OPL until 2001 (see Warwick and Ruppert, 2005, for a comprehensive bibliography of Ron Stanton's work). The purpose of the project described herein was to organize and catalog the U.S. part of the petrographic sample collection into a comprehensive database (available with this report as a Microsoft Excel file) and to compile and list published studies associated with the various sample sets. Through this work, the extent of the collection is publicly documented as a resource and sample library available to other scientists and researchers working in U.S. coal basins previously studied by organic petrologists affiliated with the USGS. Other researchers may obtain samples in the OPL collection on loan at the discretion of the USGS authors listed in this report and its associated Web page.

Open-File Report

Petrologic and isotopic data from the Cretaceous (Campanian) Blackhawk Formation and Star Point Sandstone (Mesaverde Group), Wasatch Plateau, Utah

The presence of discrete minerals associated with coal—whether (1) detrital or authigenic constituents of the coals or in thin mudstone or siltstone units interbedded with coals, or (2) authigenic phases that formed along cleats—might influence its utilization as an energy resource. The build-up of sintered ash deposits on the surfaces of heat exchangers in coal-fired power plants, due to the alteration of minerals during combustion of the coal, can seriously affect the functioning of the boiler and enhance corrosion of combustion equipment. In particular, the presence of sodium in coals has been considered a key factor in the fouling of boilers; however, other elements (such as calcium or magnesium) and the amount of discrete minerals burned with coal can also play a significant role in the inefficiency of and damage to boilers. Previous studies of the quality of coals in the Cretaceous (Campanian) Blackhawk Formation of the Wasatch Plateau, Utah, revealed that the sodium content of the coals varied across the region. To better understand the origin and distribution of sodium in these coals, petrologic studies were undertaken within a sedimentological framework to evaluate the timing and geochemical constraints on the emplacement of sodium-bearing minerals, particularly analcime, which previously had been identified in coals in the Blackhawk Formation. Further, the study was broadened to include not just coals in the Blackhawk Formation from various localities across the Wasatch Plateau, but also sandstones interbedded with the coals as well as sandstones in the underlying Star Point Sandstone. The alteration history of the sandstones in both formations was considered a key component of this study because it records the nature and timing of fluids passing through them and the associated precipitation of sodium-bearing minerals; thus, the alteration history could place constraints on the distribution and timing of sodium mineralization in the interbedded or overlying Blackhawk coals. Although some preliminary results were previously presented at scientific meetings, the petrologic and geochemical data have not been fully compiled and reported. The purpose of this report is to present the methods of data acquisition and the results of petrologic and isotopic analyses on coal and sandstone samples from the Blackhawk Formation as well as sandstones of the underlying Star Point Sandstone.

Utah

USGS compilation of geographic information system (GIS) data representing coal mines and coal-bearing areas in China

Geographic information system (GIS) information may facilitate energy studies, which in turn provide input for energy policy decisions. The U.S. Geological Survey (USGS) has compiled geographic information system (GIS) data representing the known coal mine locations and coal-mining areas of China as of 2001. These data are now available for download, and may be used in a GIS for a variety of energy resource and environmental studies of China. Province-scale maps were also created to display the point locations of coal mines and the coal-mining areas. In addition, coal-field outlines from a previously published map by Dai and others (2012) were also digitized and are available for download as a separate GIS data file, and shown in a nation-scale map of China. Chemical data for 332 coal samples from a previous USGS study of China and Taiwan (Tewalt and others, 2010) are included in a downloadable GIS point shapefile, and shown on a nation-scale map of China. A brief report summarizes the methodology used for creation of the shapefiles and the chemical analyses run on the samples.

Open-File Report

USGS compilation of geographic information system (GIS) data of coal mines and coal-bearing areas in Mongolia

Geographic information system (GIS) information may facilitate energy studies, which in turn provide input for energy policy decisions. The U.S. Geological Survey (USGS) has compiled GIS data representing coal mines, deposits (including those with and without coal mines), occurrences, areas, basins, and provinces of Mongolia as of 2009. These data are now available for download, and may be used in a GIS for a variety of energy resource and environmental studies of Mongolia. Chemical data for 37 coal samples from a previous USGS study of Mongolia (Tewalt and others, 2010) are included in a downloadable GIS point shapefile and shown on the map of Mongolia. A brief report summarizes the methodology used for creation of the shapefiles and the chemical analyses run on the samples.

Open-File Report

Coking coal of the United States—Modern and historical coking coal mining locations and chemical, rheological, petrographic, and other data from modern samples

Coking coal, or metallurgical coal, has been produced in the United States for nearly 200 years. Coking coal is primarily used in the production of coke for use in the steel industry, and for other uses (for example, foundries, blacksmithing, heating buildings, and brewing). Currently, U.S. coking coal is produced in Alabama, Arkansas, Pennsylvania, Virginia , and West Virginia. Historically, coking coal has also been produced in 15 other states (Alaska, Colorado, Georgia, Illinois, Indiana, Kentucky, Maryland, Montana, New Mexico, Ohio, Oklahoma, Tennessee, Utah, Washington, and Wyoming), but currently is not. Coals from the Appalachian, Arkoma, and Illinois basins are Pennsylvanian in age, while coals in Alaska, Colorado, Montana, New Mexico, Utah, Washington, and Wyoming range in age from Early Cretaceous through Eocene. This Open-File Report presents the geographic locations of current and historical coking coal deposits of the United States, with additional information about recent and historical mining and exploration activities. Chemical, rheological, petrographic, and other criteria for evaluating the coking potential of coals are discussed, and historical data for coking coals in the United States are presented. In addition, new coking coal samples from Alabama, Arkansas, Kentucky, and Oklahoma were collected and analyzed for this report, and the data are presented in multiple tables, including proximate and ultimate analyses; calorific value; sulfur forms; major-, minor-, and trace-element abundances; Free-Swelling Index; Gieseler Plastometer analyses; American Society for Testing and Materials (ASTM) dilatation; coal petrography; and predicted values of Coal Stability Factor and Coal Strength after Reaction with CO 2 (pCSF and pCSR, respectively). Data from previously analyzed coking coal samples in Kentucky, Pennsylvania, Virginia, and West Virginia were supplied by three companies, including results from all the tests listed above, plus oxidation, Hardgrove Grindability Index, and ash fusion (in a reducing environment) temperatures are also presented in tables in the report. Geographic Information System (GIS) data compiled for this project are available for download for public and private utilization and may be used to create maps for a variety of energy resource studies. These GIS data are in shapefile format, and metadata files are included describing all GIS processing. Additional geographic information about coking coal areas of the United States are also presented in tabular format in the report, including the following: names of coal basins, fields, regions, districts, and areas; coal beds or zones; geographic locations including States, counties, towns, rivers, mountains, etc.; stratigraphic hierarchy and age of the coal-bearing interval; coking characteristics including sulfur content, ash yield, volatile matter, moisture, calorific value, and Free-Swelling Index; coal rank; names of coal mines and coal-mining companies; current and past mining activity; and references for reports about the coal.

Open-File Report

Surface-mining modeling for USGS coal assessments

The value of national coal deposits is determined for the Solid Fuel Energy Resources Assessment and Research Project through economic evaluations using hypothetical mining models. Deposits near the surface are evaluated with the U.S. Geological Survey (USGS) surface-mining model, which is patterned after the standard mining techniques and infrastructures of commercial mining projects. The USGS surface-mining model uses these commercial mining project techniques as guides to develop a quantitative measurement to distinguish between potential recoverable resources and reserves by comparing total project cost and market value.

Open-File Report

A summary of environmental geologic studies in the Georges Bank area, United States northeastern Atlantic Outer Continental Shelf, 1975-1977

The growing need for the United States to find and develop new energy resources has led to interest in the petroleum potential of frontier areas of the Atlantic Outer Continental Shelf (OCS) seaward of the eastern seaboard state boundaries. These submerged lands are under federal jurisdiction. The authority to lease tracts for resource development is vested with the Bureau of Land Management (BLM), of the Department of Interior, pursuant to the terms of the Outer Continental Shelf Lands Act of 1953 and the National Environmental Policy Act of 1969; the latter Act requires that the inevitable social and environmental effects of development be considered in leasing decisions. The Georges Bank region, part of the Continental Shelf off New England, is one of three designated Atlantic OCS target areas for petroleum exploration. It is also one of the world's most productive fishing grounds, and the nearby coastal states have high population densities, important fishing industries, and coastlines with extraordinary recreational and scenic value.

Georges Bank area

Characterization of Northern California petroleum by stable carbon isotopes

The purpose of this study is to characterize natural occurrences of petroleum at the surface and in the subsurface within northern California in order to define and map petroleum systems for U.S. Geological Survey energy resource assessments. Furthermore, the chemical characterization and mapping of natural petroleum occurrences could also be used to discriminate natural occurrences from accidental oil spills during the activities of extraction or transportation of petroleum. Samples include petroleum from exploratory well tests, producing fields, natural seeps, and oil-stained rocks, and condensates from gas wells. Most of the sample localities are in northern California but a few samples from central and southern California are included for comparison (table 1). Even though other analyses were performed, only stable carbon isotope (δ13C) data are presented here for brevity and because δ13C values are one of the most discriminating characteristics of California petroleum.

California

Studies of geology and hydrology in the Basin and Range Province, Southwestern United States, for isolation of high-level radioactive waste - Basis of characterization and evaluation

The geologic and hydrologic factors in selected regions of the Basin and Range province were examined to identify prospective areas for further study that may provide isolation of high-level radioactive waste from the accessible environment. The six regions selected for study were characterized with respect to the following guidelines: (1) Potential repository media; (2) Quaternary tectonic conditions; (3) climatic change and geomorphic processes; (4) ground-water conditions; (5) ground-water quality; and (6) mineral and energy resources. The repository medium will function as the first natural barrier to radionuclide travel by virtue of associated slow ground-water velocity. The principal rock types considered as host media include granitic, intermediate, and mafic intrusive rocks; argillaceous rocks; salt and anhydrite; volcanic mudflow (laharic) breccias; some intrusive rhyolitic plugs and stocks; partially zeolitized tuff; and metamorphic rocks. In the unsaturated zone, the permeability and hydrologic properties of the rocks and the hydrologic setting are more important than the rock type. Media ideally should be permeable to provide drainage and should have a minimal water flux The ground-water flow path from a repository to the accessible environment needs to present major barriers to the transport of radionuclides. Factors considered in evaluating the ground-water conditions include ground-water traveltimes and quality, confining beds, and earth materials favorable for retardation of radionuclides. Ground-water velocities in the regions were calculated from estimated hydraulic properties of the rocks and gradients. Because site-specific data on hydraulic properties are not available, data from the literature were assembled and synthesized to obtain values for use in estimating ground-water velocities. Hydraulic conductivities for many rock types having granular and fracture permeability follow a log-normal distribution. Porosity for granular and very weathered crystalline rock tends to be normally distributed; porosity of fractured crystalline rock probably follows a log-normal distribution. The tectonic setting needs to prevent an increase in radionuclides to the accessible environment. Data on historic seismicity and heat flow, Quaternary faults, volcanism, and uplift were used to assess the tectonic conditions. Long-term late Cenozoic rates of vertical crustal movement in the Basin and Range province range from less than 2 meters per 104 years to greater than 20 meters per 104 years. Shortterm rates of vertical movement may be more than an order of magnitude greater, based on geodetic leveling. Changes in tectonic and climatic processes may potentially cause changes in hydrologic conditions and geomorphology that could affect the integrity of a deep, mined repository either adversely or beneficially. The transition from a full-glacial climate to the current interglacial condition has occurred within the past 15,000 years. Reconstructions of the last full-glacial climate indicate that, at that time, there was greater water availability for runoff and vegetation growth than there is now. Based on the increased water availability and depending on seasonal distribution of precipitation, on soil characteristics, on topography, and on other characteristics, ground-water recharge during the full-glacial climate is estimated to have been possibly 2 to 10 or more times the modern rate. During the full-glacial climate, more than 100 lakes occupied closed basins in the province. Any increase in ground-water recharge and refilling of Pleistocene lakes will tend to decrease the distance of ground-water flow and its time of travel. The unsaturated zone this zone is considered a potential host medium where the thickness is greater than 150 m will be decreased by these changes. In contrast, incision of streams and other geomorphic, tectonic, or climatically induced changes that lower the ground-water discharge level will tend to increase the thickness of the unsaturated zone. Aggradation in basinal troughs may either decrease or increase the thickness of the unsaturated zone. Aggradation in basins that causes the ground-water discharge level to rise will tend to decrease the thickness of unsaturated zone in the adjacent uplands; aggradation in basins where the ground-water discharge level remains the same or is lowered will increase the unsaturated thickness of basin fill. Records show that, throughout late Cenozoic time in the Basin and Range province, continued vertical crustal movements have tended to maintain mountain ranges and closed basins, whereas aggradation of the basins and erosion of the mountain ranges have tended to decrease the topographic relief. Maximum rates of denudation for small basins in areas climatically similar to the Basin and Range province are about 2 meters per 104 years. For sites unaffected by stream incision and scarp retreat, a conservative estimate of erosion affecting long-term changes in depth of burial would appear to be 2 meters per 104 years, or, equal to the long-term rate of vertical crustal movement where greater than 2 meters per 104 years. The response of the ground-water conditions to climatic and geomorphically induced boundary conditions is significant from the points of: (1) The potential maximum change in the ground-water flow system; (2) the time of response of the ground-water system; and (3) the present state of the ground-water system as a result of past changes. Effects of longterm climatic and tectonic changes on hydrologic and geomorphic conditions differ from area to area, and rates of change of geomorphic and hydrologic conditions may vary significantly. Therefore, sitespecific studies need to be made to assess the long-term integrity of deep, mined repositories.

Arizona, California, Idaho, Nevada, New Mexico, Te

Coal assessments and coal research in the Appalachian basin

Coal is one of our most important domestic energy resources, producing 37 percent of the Nation’s electricity in 2012. Coal mining within the Appalachian basin has been ongoing for three centuries and, cumulatively, the basin is the most productive coal region in the United States. In 2012, only the Powder River basin produced more coal than the Appalachian basin. Coal is the most important mined product within the basin, and research on the quality and quantity of the coal is one of the primary functions of the U.S. Geological Survey (USGS) and the State geological surveys of Alabama, Kentucky, Maryland, Ohio, Pennsylvania, Tennessee, Virginia, and West Virginia. The USGS and the State geological surveys historically have worked together on coal research and assessment projects to achieve mutually beneficial science goals. The 2000 USGS coal resource assessment of the Appalachian basin (Northern and Central Appalachian Basin Coal Regions Assessment Team, 2001, USGS Professional Paper 1625–C) was done in close collaboration with scientists of the State geological surveys of Kentucky, Maryland, Ohio, Pennsylvania, Virginia, and West Virginia. Five of the top-producing coal beds and coal zones within the basin were quantitatively assessed, and results show that ample coal resources remain. Coal quality, not coal quantity, is the principal driver for coal production and use within the basin and will be for the foreseeable future. Cumulative coalbed-methane (CBM) production within the Appalachian basin has been about 2.3 trillion cubic feet (TCF), and most of the production has come from Alabama and Virginia (Milici and Polyak, this volume, chap. G.2). Significant CBM resources occur throughout the coal-producing States in the Appalachian basin, and commercial production is possible in all. State geological surveys are concentrating on mapping and correlating coal beds and coal zones and studying CBM potential and production. Both State surveys and the USGS are researching the potential for carbon dioxide sequestration in unmined coal beds and other geologic reservoirs. In addition, the State geological surveys continue their long-term collaboration with the USGS and provide coal stratigraphic data to the National Coal Resources Data System (NCRDS).

Appalachian basin

Prospectivity mapping for geologic hydrogen

Geologic, or naturally occurring, hydrogen has the potential to become a new, low-carbon, primary energy resource. Often referred to as “white” or “gold” hydrogen, this gas occurs naturally in the Earth’s subsurface, similar to petroleum resources. However, unlike petroleum, which releases carbon dioxide when burned, burning hydrogen only produces water as a byproduct. Exploration for geologic hydrogen remains in an early stage and discoveries of high concentrations of subsurface hydrogen are still relatively rare. To facilitate research and exploration for this potential resource, this report presents the first publicly available prospectivity map of geologic hydrogen accumulations in the conterminous United States. Prospective regions are those regions in which all major components necessary for a hydrogen accumulation likely are present—a source of sufficient hydrogen generation, porous reservoirs for storage, and seals to prevent leakage. The midcontinent region of the United States and the central California coast are revealed as having high prospectivity. This analysis also identifies previously unrecognized prospective regions that may be favorable due to long distance lateral migration of subsurface hydrogen, such as the offshore eastern seaboard of the United States, and can provide a linkage between surface observations of hydrogen degassing and far-field source regions. The methodology developed to create this map is expandable and flexible and may be adapted to incorporate new concepts in the hydrogen system and for application to other regions of the world.

conterminous United States

Geologic cross section C-C' through the Appalachian basin from Erie County, north-central Ohio, to the Valley and Ridge province, Bedford County, south-central Pennsylvania

Geologic cross section C-C' is the third in a series of cross sections constructed by the U.S. Geological Survey (USGS) to document and improve understanding of the geologic framework and petroleum systems of the Appalachian basin. Cross section C-C' provides a regional view of the structural and stratigraphic framework of the Appalachian basin from north-central Ohio to the Valley and Ridge province in south-central Pennsylvania, a distance of approximately 260 miles (mi). This cross section is a companion to cross sections E-E' and D-D' that are located about 50 to 125 mi and 25 to 50 mi, respectively, to the southwest. Cross section C-C' contains much information that is useful for evaluating energy resources in the Appalachian basin. Although specific petroleum systems are not identified on the cross section, many of their key elements (such as source rocks, reservoir rocks, seals, and traps) can be inferred from lithologic units, unconformities, and geologic structures shown on the cross section. Other aspects of petroleum systems (such as the timing of petroleum generation and preferred migration pathways) may be evaluated by burial history, thermal history, and fluid flow models based on what is shown on the cross section. Cross section C-C' also provides a general framework (stratigraphic units and general rock types) for the coal-bearing section, although the cross section lacks the detail to illustrate key elements of coal systems (such as paleoclimate, coal quality, and coal rank). In addition, cross section C-C' may be used as a reconnaissance tool to identify plausible geologic structures and strata for the subsurface storage of liquid waste or for the sequestration of carbon dioxide.

Kentucky;Maryl;Ohio;Pennsylvania;Tennessee;Virgini

Geologic Cross Section I–I′ Through the Appalachian Basin from the Eastern Margin of the Illinois Basin, Jefferson County, Kentucky, to the Valley and Ridge Province, Scott County, Virginia

Geologic cross section I‒I’ is the fourth in a series of cross sections constructed by the U.S. Geological Survey to document and improve understanding of the geologic framework and petroleum systems of the Appalachian basin. Cross section I‒I’ provides a regional view of the structural and stratigraphic framework of the Appalachian basin from the eastern margin of the Illinois basin in central Kentucky, across the Cincinnati arch (Lexington dome), to the Valley and Ridge province in southwestern Virginia, a distance of approximately 280 miles. This cross section is a companion to cross sections E‒E’ , D‒D’ , and C‒C’ that are located about 200 to 300 miles to the northeast. Cross section I‒I’ either updates or complements earlier geologic cross sections through the central Kentucky and southwestern Virginia part of the Appalachian basin. Although other published cross sections through parts of the basin show more structural and stratigraphic detail, these other cross sections are of more limited extent geographically and (or) stratigraphically. Cross section I‒I ’ contains much information that is useful for evaluating energy resources in the Appalachian basin. Many of the key elements of the Appalachian basin petroleum systems (such as source rocks, reservoir rocks, seals, and traps) can be inferred from lithologic units, unconformities, and geologic structures shown on the cross section. Other aspects of petroleum systems (such as the timing of petroleum generation and petroleum migration pathways) may be evaluated by burial history, thermal history, and fluid flow models on the basis of what is shown on the cross section. Cross section I‒I’ also provides a stratigraphic and structural framework for the Pennsylvanian coal-bearing section. In addition, geologists and engineers could use cross section I‒I’ as a reconnaissance tool to identify plausible geologic structures and strata for the subsurface storage of liquid waste or for the sequestration of carbon dioxide.

Kentucky, Pensylvania

Geologic cross section A–A′ through the Appalachian basin from the southern margin of the Ontario Lowlands province, Genesee County, western New York, to the Valley and Ridge province, Lycoming County, north-central Pennsylvania

Introduction Geologic cross section A–A′ is the fifth in a series of cross sections constructed by the U.S. Geological Survey (USGS) to document and improve understand­ing of the geologic framework and petroleum systems of the Appalachian basin. Cross section A–A′ provides a regional view of the structural and stratigraphic frame­work of the Appalachian basin from the southern mar­gin of the Ontario Lowlands province in western New York, across the Allegheny Plateau province of central New York and north-central Pennsylvania, to the Valley and Ridge province in north-central Pennsylvania, a dis­tance of approximately 176 miles. This cross section is a companion to cross sections E–E′, D–D′, C–C′ , and I–I′ that are located approximately 100 to 500 miles to the southwest. Cross section A–A′ complements earlier geologic or strati­graphic cross sections through the central New York and north-central Pennsylvania part of the Appalachian basin. Although some of these other cross sections show more structural and stratigraphic detail, they are of more limited extent geographically and stratigraphically. Cross section A–A′ contains much information that is useful for evaluating energy resources in the Appalachian basin. Although the Appalachian basin petroleum systems are not shown on the cross section, many of their key elements (such as source rocks, reservoir rocks, seals, and traps) can be inferred from lithologic units, unconformities, and geologic structures shown on the cross section. Important oil- and gas-bearing formations like the Oriskany Sandstone, Medina Group sandstones, Tuscarora Sandstone, and the Marcellus and Utica Shales are present on cross-section A–A′ .

New York, Pennsylvania

Cross section N–N' through the Valley and Ridge province of the southern Appalachian basin, from Greene County, west-central Alabama, to Bibb County, central Alabama

Introduction Geologic cross section N–N′ is the sixth in a series of geologic cross sections constructed by the U.S. Geological Survey to document and improve understanding of the geologic framework and petroleum systems of the Appalachian basin. Cross section N–N′ provides a regional view of the structural and stratigraphic framework of the Appalachian basin in the Valley and Ridge province in western and central Alabama; it spans approximately 69 miles (mi) (111 kilometers [km]). This geologic cross section is a companion to geologic cross sections E–E′ , D–D′ , C–C′ , I–I′ , and A–A′ that are located approximately 350 to 550 mi (563 to 885 km) to the northeast. Cross section N–N' complements earlier geologic cross sections through the Alabama part of the Appalachian basin. Although some of the other cross sections show more structural and stratigraphic detail, they are of more limited extent geographically and stratigraphically. Cross section N–N′ contains information that is useful for evaluating energy resources in the Appalachian basin. Although the Appalachian basin petroleum systems are not shown on the cross section, many of their key elements (such as source rocks, reservoir rocks, seals, and traps) can be inferred from lithologic units, unconformities, and geologic structures shown on the cross section. Other aspects of petroleum systems (such as the timing of petroleum generation and petroleum migration pathways) may be evaluated by burial history, thermal history, and fluid flow models based on what is shown on the cross section. In addition, cross section N–N′ may be used as a reconnaissance tool to identify plausible geologic structures and strata for the subsurface storage of liquid waste or for the sequestration of carbon dioxide.

Alabama

Hydrogeologic framework and estimates of ground-water volumes in Tertiary and upper Cretaceous hydrogeologic units in the Powder River basin, Wyoming

The Powder River Basin in Wyoming and Montana is an important source of energy resources for the United States. Coalbed methane gas is contained in Tertiary and upper Cretaceous hydrogeologic units in the Powder River Basin. This gas is released when water pressure in coalbeds is lowered, usually by pumping ground water. Issues related to disposal and uses of by-product water from coalbed methane production have developed, in part, due to uncertainties in hydrologic properties. One hydrologic property of primary interest is the amount of water contained in Tertiary and upper Cretaceous hydrogeologic units in the Powder River Basin. The U.S. Geological Survey, in cooperation with the Bureau of Land Management, conducted a study to describe the hydrogeologic framework and to estimate ground-water volumes in different facies of Tertiary and upper Cretaceous hydrogeologic units in the Powder River Basin in Wyoming. A geographic information system was used to compile and utilize hydrogeologic maps, to describe the hydrogeologic framework, and to estimate the volume of ground water in Tertiary and upper Cretaceous hydrogeologic units in the Powder River structural basin in Wyoming. Maps of the altitudes of potentiometric surfaces, altitudes of the tops and bottoms of hydrogeologic units, thicknesses of hydrogeologic units, percent sand of hydrogeologic units, and outcrop boundaries for the following hydrogeologic units were used: Tongue River-Wasatch aquifer, Lebo confining unit, Tullock aquifer, Upper Hell Creek confining unit, and the Fox Hills-Lower Hell Creek aquifer. Literature porosity values of 30 percent for sand and 35 percent for non-sand facies were used to calculate the volume of total ground water in each hydrogeologic unit. Literature specific yield values of 26 percent for sand and 10 percent for non-sand facies, and literature specific storage values of 0.0001 ft-1 (1/foot) for sand facies and 0.00001 ft-1 for non-sand facies, were used to calculate a second volume of ground water for each hydrogeologic unit. Significant figure considerations limited estimates of ground-water volumes to two significant digits. A total ground-water volume of 2.0x1014 ft3 (cubic feet) was calculated using porosity values, and a total ground-water volume of 3.6x1013 ft3 was calculated using specific yield and specific storage values. These results are consistent with retention properties, which would have some of the total water being retained in the sediments. Sensitivity analysis shows that the estimates of ground-water volume are most sensitive to porosity. The estimates also are sensitive to confined thickness and saturated thickness. Better spatial information for hydrogeologic units could help refine the ground-water volume estimates.

Scientific Investigations Report

Development of hydrocarbon gas standards for stable isotopic composition (δ13C and δ2H)

A suite of gas standards was developed to serve as international secondary reference materials (RMs) for the determination of the compound-specific carbon-13/carbon-12 ( δ 13 C) and hydrogen-2/hydrogen-1 ( δ 2 H) values of hydrocarbon gases. This report provides background information on the project, the methods used to produce and analyze the gases, as well as the data analysis and recommended stable isotopic values. Additionally, samples of older hydrocarbon gas RMs no longer available were analyzed along with the new RMs to allow for traceability to historical data. These secondary RMs are intended for interlaboratory standardization and traceability to primary RMs. The gaseous RMs are currently (at time of publication) available for purchase from the U.S. Geological Survey Energy Resources Program.

Scientific Investigations Report