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Groundwater hydrology, groundwater and surface-water interactions, water quality, and groundwater-flow simulations for the Wet Mountain Valley alluvial aquifer, Custer and Fremont Counties, Colorado, 2017–19

In 2017, the U.S. Geological Survey, in cooperation with the Upper Arkansas Water Conservancy District, began a study to provide a comprehensive analysis of the Wet Mountain Valley alluvial aquifer, Custer and Fremont Counties, Colorado. The study included collection of data pertaining to groundwater hydrology, groundwater and surface-water interactions, and water quality in the alluvial aquifer. In addition to providing foundational information on the hydrology of the alluvial aquifer, a numerical groundwater-flow model was developed to estimate the potential effects of additional storage of groundwater in the alluvial aquifer. Groundwater-level elevation data from 30 wells were used to estimate groundwater-flow directions in the alluvial aquifer, which were generally from the southwest to northeast, away from the Sangre de Cristo Mountains and towards perennial streams in the center of the valley. Although some seasonal variation was apparent in groundwater-level elevation records, no statistically significant seasonal trends were indicated. Statistically significant long-term trends were indicated in groundwater-level elevation records for 8 of the 30 wells, and of these wells with statistically significant trends, all but 1 indicated a negative trend of groundwater-level elevations. Spatial evaluation of wells with statistically significant negative groundwater-level elevation trends showed many are in areas of denser well drilling for domestic or other uses, indicating increasing groundwater use could potentially be causing groundwater-level elevation declines. There were instances of wells with no statistically significant groundwater-level elevation trends also located in areas of greater density of well completions. Additional investigations may be necessary to more fully characterize the processes responsible for negative groundwater-level elevation trends. Streamflow gain or loss calculations were completed for low flow in 2017–19 and for high flow in 2018 in nine reaches of streams within the study area. Stream reaches of the upper Texas Creek, upper Grape Creek, upper-middle Grape Creek, and Taylor Creek displayed consistent streamflow loss in each period from 2017 to 2019. These stream reaches represent long-term sources of recharge to the alluvial aquifer. Streamflow gain or loss varies through time in other stream reaches (lower Texas Creek, lower-middle Grape Creek, lower Grape Creek below Westcliffe, and lower Grape Creek above DeWeese Reservoir). The temporally variable behavior indicates these stream reaches may be sources of groundwater recharge or areas of groundwater discharge, likely depending on temporal dynamics between the elevation of the water table and the stream. Water-quality samples were collected from 10 groundwater wells and 10 stream sites during September through November 2019. All groundwater and stream samples were analyzed for major and trace elements and stable isotopes of water. A subset of groundwater samples was also analyzed for the environmental tracers sulfur hexafluoride, tritium, and noble gases. Comparison of water-quality results to U.S. Environmental Protection Agency drinking water-quality standards indicated no constituents exceeded primary standards for human health. Spatial evaluation of water quality indicated the concentrations of various constituents are likely controlled by groundwater and surface-water interactions and by spatial variability in bedrock geology underlying the alluvial aquifer. Specifically, streams shown to gain from groundwater had water chemistry constituent compositions similar to groundwater, whereas streams exiting the Sangre de Cristo Mountains tended to have compositions consistent with snowmelt. Groundwater geochemistry appeared to be partially controlled by oxidation-reduction processes and by proximity to igneous rocks in the Wet Mountains. Environmental tracers used to estimate groundwater age indicated all sampled groundwater contained tracers representing modern recharge (approximately less than 65 years old) but mixing of premodern recharge (approximately more than 65 years old) also occurs. Spatial evaluation of environmental tracers indicated large faults may be conduits for upwelling of older groundwater. No trends were observed in groundwater age with well depth, indicating all sampled wells are located within the zone of active groundwater flow. The presence of modern groundwater in wells with statistically significant negative groundwater-level elevation trends indicates groundwater storage depletions may be partially offset by capture of modern recharge. Repeated sampling of groundwater age would be necessary, however, to determine if any trends in groundwater age exist, which may indicate changing groundwater recharge, storage, or discharge. Additional investigations could also consider quantifying groundwater age in deeper wells to more fully define the depth of active groundwater flow. A numerical groundwater-flow model was developed to estimate components of the water budget, simulate groundwater and surface-water interactions, and evaluate the potential effects of aquifer storage and recovery. Simulated groundwater-level elevations from the calibrated groundwater-flow model are similar to the observed pattern of groundwater-level elevations with higher elevations in the western part of the study area along the Sangre de Cristo Mountains. Simulated water-budget components indicate most of the recharge to the alluvial aquifer is derived from streamflow losses, which is consistent with observations of losing streams along the mountain front. The largest groundwater discharge component of the alluvial aquifer was to streams in the center of the valley, where observations of stream gain or loss indicated the predominance of gaining conditions. Comparison of groundwater and surface-water interactions between the calibrated groundwater-flow model for 2000-19 (the base-case model) and a simulation including additional recharge, representing potential aquifer storage and recovery operations, indicated the additional recharge distributed throughout the area had minimal effects on streamflow in the nearby Grape Creek. An analysis of subregional groundwater budgets showed approximately 54 percent of the additional recharge flowed back to nearby Grape Creek, and the other 46 percent was distributed laterally into adjacent cells in the alluvial aquifer. The comparison of simulations and subregional water budget show the additional recharge did not substantially alter groundwater-level elevations or basin wide groundwater storage. Although the analysis of additional recharge provided in the numerical groundwater-flow model considers only one of many possible recharge scenarios, the model provides a useful tool that could be modified for various scenarios to understand potential effects of managed aquifer recharge.

Colorado

Streamflow, base flow, and ground-water recharge in the Housatonic River basin, western Massachusetts and parts of eastern New York and northwestern Connecticut

Streamflows for selected flow durations from 1 to 99 percent and the August median streamflows were estimated for 11 long-term streamflow-gaging stations in and near the study area. Estimates of streamflow and associated standard errors were determined for selected flow durations from 50 to 99 percent and the August median streamflows for 21 low-flow partial-record stations and for selected flow durations from 1 to 99 percent and the August median streamflows for two partial-record stations and seven short-term discontinued streamflow-gaging stations. Median streamflows per square mile for the 10-, 50-, and 90-percent flow durations and the August median streamflows were 3.90, 1.01, 0.185, and 0.248 cubic feet per second per square mile. Streamflows per square mile at selected flow-duration discharges between 1 and 99 percent at the 41 stations were related to basin characteristics to explain differences in streamflow characteristics. Basin characteristics included basin elevations, extent of stratified-drift deposits, land use, aspect, and underlying bedrock geology types. Most streamflow differences were positively correlated to basin elevation differences, most likely because precipitation increases with elevation, and to stratified-drift deposits, which allow more precipitation to recharge the ground water and to discharge later than do till and bedrock deposits. Mean base flow was computed from continuous records of daily mean discharge at 11 long-term streamflow-gaging stations in and near the study area. Mean annual base flow ranged from 13.4 to 24.5 inches per year. Minimum annual base flow ranged from 45 to 72 percent of mean annual rates at the 11 long-term stations, and the ratio of base flow to streamflow (base-flow index) ranged from 0.55 to 0.80. Base-flow durations between 1 and 99 percent were calculated from streamflow records at the 11 long-term streamflow-gaging stations. Base flow accounted for 45.5 to 85.0 percent of total annual streamflow at the 1- and 99-percent flow durations. Ground-water-recharge rates were computed from continuous records of daily mean discharge at 11 long-term streamflow-gaging stations in and near the study area. Mean annual ground-water-recharge rates ranged from 17.5 to 22.4 inches per year at 10 of the 11 long-term stations. Mean annual ground-water-recharge rates ranged from 2 to 7 inches per year higher than base flow. Minimum annual ground-water-recharge rates ranged from 48 to 72 percent of mean annual ground-water-recharge rates. Mean annual potential ground-water recharge was estimated from monthly climatological data collected at six climatological stations in and near the study area. Mean potential ground-water recharge ranged from about 17.9 to 28.9 inches per year, with a median value of 22.6 inches per year. This median value compares well to that calculated by use of streamflow records at the 11 streamflow-gaging stations (20.0 inches per year). Streamflows per square mile for the 10-, 50-, and 90-percent flow durations at stations in and near the study area were similar to those computed for other unregulated long-term continuous streamflow-gaging stations in central and eastern Massachusetts. Base-flow and ground-water-recharge rates in the study area compared closely to results from other studies in southeastern Massachusetts and Rhode Island, which were based on the same computational methods.

Connecticut, Massachusetts, New York

Assessment of channel morphology, hydraulics, and bedload transport along the Siletz River, western Oregon

Significant Findings Chinook salmon ( Oncorhynchus tshawytscha ) and Pacific lamprey ( Entosphenus tridentatus ) are native, anadromous fish species in the Siletz River Basin, western Oregon, that face many threats to their survival in freshwater and the ocean. The Confederated Tribes of Siletz Indians of Oregon seek to mitigate freshwater threats to Chinook salmon and Pacific lamprey, where possible, with habitat conservation and restoration efforts. This study was conducted to assist the Confederated Tribes of Siletz Indians of Oregon in documenting and understanding the hydrogeomorphic processes shaping present-day habitat conditions and assessing future habitat implications for Chinook salmon and Pacific lamprey along the main-stem Siletz River. As such, this study focused on understanding geomorphic processes and patterns of channel change, including lateral and vertical adjustments in channel position and changes in bed-material sediment (sands, gravels, and cobbles that mantle the channel bed), which collectively determine overall patterns of channel morphology and fluvial habitats. Objective One was to evaluate lateral changes in channel position, vertical changes in bed elevation, and longitudinal patterns in bed-material particle size along the Siletz River using detailed channel maps developed from aerial photographs collected from 1939 to 2016, long-term records of stage and discharge collected by the U.S. Geological Survey (USGS) near the City of Siletz, and sediment particle size data. Objective Two was to assess hydraulic conditions using one- and two-dimensional hydraulic models and transport capacity of bed-material sediment using bedload transport models and sediment particle size data for a range of discharge conditions. Objective Three was to identify potential burrowing habitat for lamprey larvae (PBH) along the Siletz River network and provide insights in local factors influencing PBH along the main-stem Siletz River. The overall findings are synthesized to describe habitat implications for Chinook salmon and Pacific lamprey under present-day and future conditions. Results of Objective One, an evaluation of changes in channel position and bed elevations and longitudinal patterns in bed-material particle size along the Siletz River, include the following From 1939 to 2016, channel planform and the mapped area of gravel bars did not change considerably along the 97.2-kilometers (km) of Siletz River between Elk Creek and Millport Slough, except for in short sections generally less than 1 km long. This inherent lateral channel stability results from the resistant bedrock and terraces that bound most of the channel and limit lateral changes in channel position. Intermittent sections along the study reach where the active channel widened at channel bends displayed noticeable planform changes and increases in mapped bar area. From water year (WY; a 12-month period from October 1 through September 30 and named for the year in which it ends) 1906 to 2021, changes in the stage-discharge relation interpreted as rising and lowering channel bed levels were observed at the USGS streamgage 14305500 (Siletz River at Siletz, OR) in response to floods (such as high flows in February 1996 and January 2002 that exceeded 0.1 and 0.667 annual exceedance probabilities [AEP] events, respectively). However, the rating curve representing the stage-discharge relation did not change in response to high-magnitude floods between 2007 and 2021. Along the approximately 54-km of the Siletz River between Moonshine Park and the Bulls Bag area, surficial particle distributions varied considerably between sampling sites in response to changes in channel width and gradient, sediment inputs from tributaries, and basin geology. Despite this variability, median particle sizes tended to decrease in size in the downstream direction over the 54 km. Results of Objective Two, an evaluation of hydraulic and bedload transport conditions along the Siletz River, include the following The most substantial increases in maximum and mean water velocity and bedload sediment transport capacity occurred at events between the 0.995 and 0.50 AEPs. Events of these magnitudes occur approximately every 1–2 years. Smaller events (0.995 AEP) are generally contained by the banks of the main channel, whereas larger events (0.50 AEP) generally spill over the banks and inundate high-elevation bar and low-elevation floodplain surfaces. Multiple smaller floods within a WY that exceed the 0.995 and 0.50 AEPs (such as in WY 1996) can transport as much or more bed-material sediment than a single, higher magnitude event (such as the maximum event recorded in WY 2000 with an estimated AEP of around 0.002). Bedload transport capacity generally exceeds sediment supply (greater than 2 millimeters [mm]) for most of the study area from Wildcat Creek to the City of Siletz as evidenced by substantial in-channel bedrock. Despite overall conditions of limited sediment supply, transport capacity still varies considerably within and between years with discharge magnitude and spatially in relation to local hydraulics imposed by bedrock, channel morphology, and human infrastructure (such as bridges). Results of Objective Three, an analysis of PBH for lamprey larvae, include the following About 28 percent of the Siletz River network meets the mean annual suspended sediment loads and channel slope criteria for PBH. Along the main-stem Siletz River, in-channel bedrock outcrops and high transport capacity are expected to further constrain PBH. Together, these results suggest that most of the Siletz River between Wildcat Creek and the City of Siletz has had only modest vertical and lateral change between the 1930s and 2010s because of the bedrock in and along the main channel and the river’s relatively high transport capacity relative to bed-material sediment supply. However, localized sections of the Siletz River where the active channel widens, particularly at channel bends, exhibited some change in channel planform and the locations and area of gravel bars. In the future, moderate increases in autumn-winter discharge may not result in substantial changes in coarse gravel bars along the Siletz River but may result in selective transport of finer bed-material sediment (gravel, sands, and silts) that provide spawning habitats for Chinook salmon and Pacific lamprey and burrowing habitats for lamprey larvae. Assuming no substantial changes in bed-material sediment supply, increased bedload transport capacity may cause frequent entrainment of lamprey larvae that are burrowed in coarse sand deposits, suspension and downstream transport of salmon eggs incubating in gravels, and reductions in the areas of spawning gravels for Chinook salmon and Pacific lamprey. Exact implications of current and future discharge conditions for these species along the Siletz River depends on many factors, including sediment supply, local hydraulics, and the timing of flood events relative to fish life stages.

Oregon

Geochemistry and thermometry of magnetite veins and replacements in iron ore deposits from the Iron Springs district, SW Utah, USA: Relation to magmatic and hydrothermal processes

Ore-genesis, texture, chemical compositions, and thermometry of magnetite were used to better evaluate the origins of iron ore deposits across the Iron Spring district, Utah. Trace element compositions, determined by LA-ICP-MS, were used to calculate temperatures based on X Mg numbers and characterize the trace element signatures of magmatic and hydrothermal magnetite. Magnetite occurs as coarser crystalline grains within veins, breccias, and cavities along with finer crystalline replacements. Magnetite is most commonly intergrown with apatite, phlogopite, and carbonate in veins, breccias, and cavities where apatite occurs separately from the other gangue minerals. The results using empirical trace element discrimination diagrams generally suggest that the magnetite is overall of hydrothermal origin regardless of textural variations or field relationships. The X Mg numbers of the magnetite in the magnetite-apatite ores, however, are suggestive of high temperature magmatic conditions; whereas those of vein, breccia, and replacement occurrences containing other gangue minerals are suggestive of lower temperature hydrothermal processes.

Utah

Critical Minerals in Ores (CMiO) database

Critical minerals are commodities essential to modern industrial and strategic technologies and are highly vulnerable to supply chain disruption. The Critical Minerals Mapping Initiative (CMMI) is a collaboration among the U.S. Geological Survey (USGS), the Geological Survey of Canada, and Geoscience Australia that aims to deepen global understanding of where critical minerals are located. A key output of this initiative is the Critical Minerals in Ores (CMiO) database that is advancing our collective understanding of critical minerals distributions. For instance, publicly available data on the concentrations of many critical minerals are sparse because these commodities can only be produced in small, yet essential, quantities compared to the primary commodities like copper and zinc. The CMiO database helps bridge this gap by offering high-quality, multielement geochemical data from a wide variety of critical mineral-bearing deposits around the world. Importantly, it uses a novel consensus deposit environment, group, and type classification scheme developed by the agencies that allows comparisons among ore deposits from different regions. The CMiO database contains geochemical data for more than 20,000 samples from more than 100 deposit types comprising 10 deposit environments.

Fact Sheet

Geochemical processes related to mined, milled, or natural metal deposits in a rapidly changing global environment

The demand for metals and raw materials, such as nickel and copper, has been projected to expand in the coming decades, driven by the global energy transition, the need for green technologies, and expanding infrastructure. Consequently, the increasing extraction and production of mining waste can have adverse impacts on surrounding environments and human health. The aim of this thematic collection is to fill critical knowledge gaps in the present-day cycles of metal(loid)s from source to larger sinks, and the effect of environmental management, anthropogenic development, and climate change. Altogether, the studies have been conducted in different natural settings around the world and comprise investigations in laterites, a soil-medicinal plant system, watersheds, and banded iron formations, among others. The geochemical applications in tracing mineralization, its secondary products, and/or potential impact on the immediate environment are highly diverse with applied tools ranging from isotope tracers to major and trace element systematics. Particularly the use of rare earth elements, their patterns and anomalies are methods employed by several studies in this collection. We summarize the findings to offer a potential future direction for the use of geochemical tracing techniques in resource exploration in the context of climate change and environmental challenges.

Geochemistry: Exploration, Environment, Analysis

Cotton farming pesticides affect ileal microbiota activity expressions of virulome but not resistome or metabolic pathways in a sedentary wild passerine

The increased use of agrochemicals to enhance crop production has had detrimental environmental effects including implication in the sharp decline of North American farmland-breeding birds. Here, using a combination of deep shotgun metatranscriptomics and pesticide exposure data, we sought to assess whether exposure to cotton ( Gossypium spp.) production had a differential effect on ileum multi-kingdom microbial activity, metabolism, anti-microbial resistance, and virulence factors of sedentary northern mockingbirds ( Mimus polyglottos ) sampled from two cotton-producing areas (16 birds in total) and one uncultivated area (7 birds) in Texas, USA. Both Shannon Index values (Adj. r 2 = 0.174, F (1,21) = 5.633, p = 0.027) and a Mantel test (Spearman ρ = 0.184, p = 0.013) supported a relationship between metabolically active microbiota Bray–Curtis dissimilarities and differences in pesticide mixtures among study areas. Virulence factor richness (Adj. r 2 = 0.182, F (1,21) = 5.890, p = 0.024), Shannon Index (Adj. r 2 = 0.231, F (1,21) = 7.612, p = 0.012), and load (sum of virulence factor abundances; Adj. r 2 = 0.160, F (1,21) = 5.194, p = 0.033) were related to total pesticide load (total quantity of pesticides). We found no pesticide effects on expression of either antimicrobial resistance genes or metabolic pathways.

Texas

Ultramafic float rocks at Jezero crater (Mars): Excavation of lower crustal rocks or mantle peridotites by impact cratering?

Based on observation and data from meteorites and in situ scientific missions, experiments as well as models, the Martian mantle is assumed to share some compositional and mineralogical affinity with the terrestrial mantle. However, there might be subtle differences like the Martian mantle being more ferroan. Yet, we do not have any direct analysis of a Martian mantle rock to confirm this assumption. NASA’s Perseverance rover found olivine-rich boulder-sized float rocks on the upper Jezero fan (Mars). These boulders have an ultramafic composition and their mineralogy is dominantly composed of Fo 73±3 olivine with high-Mg orthopyroxene, Cr-rich Ti-Fe oxides and minor plagioclase and high-Ca pyroxene. Microtextural and petrological analysis reveals that these minerals crystallized at equilibrium. In addition, these boulders are different from all the bedrocks analyzed by Perseverance along its traverse which are crustal igneous rocks and sediments. Comparing our data to Martian meteorites and available Mars bulk silicate models (BSM), we discuss that these boulders could represent primitive melts and/or lower crustal material, and we specifically hypothesize that they could be mantle peridotites. We propose that these putative mantle rocks could have been excavated by the succession of impacts from the shallow mantle or lower crust in the Isidis region where Jezero crater is located. These olivine-rich boulders could thereby constitute the first direct analysis of a Martian mantle rock.

Earth and Planetary Science Letters

Noble and base metal distribution and processes affecting ore tenors in the disrupted lower stratigraphy of the Stillwater Complex, USA

Exploration continues for contact-style Ni-Cu sulfide and chromitite-associated PGE mineralization in ultramafic rocks of the Stillwater Complex. At the Iron and Chrome Mountain areas, massive sulfides occur along the complex’s footwall contact and anomalous concentrations of PGE+Au are associated with the three lowermost chromitite seams. Southeast of Chrome Mountain, magmatic layering is highly disrupted by the presence of faults, magmatic breccias, serpentinized discordant dunites, pyroxenite pegmatoids, and disaggregated chromitite seams. The bulk rock chemistry, sulfide chemistry, and noble metal mineralogy of samples from this area were examined to determine the deportment of PGE and processes that led to enrichments in PGE, Au, Cu, Co and Ni. Results show that a sulfide liquid was the principal collector of PGE. If sulfide liquid was initially deposited with chromite, it was disaggregated or redistributed by subsequent melt or fluid infiltration, which may have resulted in the offset of peak PGE(+Cu, Ni) from peak Cr 2 O 3 concentrations, and upgraded PGE tenors. Upon cooling, PGE exsolved from sulfides to form discrete bismuth tellurides, arsenides, arsenic sulfides, antimonides, and alloys, commonly along the margins of sulfide globules. Calculated metal tenors are highest in the disseminated sulfides southwest of Chrome Mountain, whereas massive and net-textured sulfides near the Iron Mountain-Camp zone represent monosulfide solid solution cumulates. At progressively shallower levels, higher metal tenors combined with lower S/Se ratios are consistent with increasing R-factors from 100 to 100,000. Serpentinization and talc-tremolite alteration resulted in S loss through partial replacement of sulfides by secondary silicate+carbonate+magnetite+sulfide assemblages, further upgrading Ni-Cu-PGE tenors. The present work shows that processes responsible for the disruption of magmatic layering and post-magmatic fluid alteration along the intrusion’s lower contact led to noble and base metal enrichments.

Montana

Complex carbonate ore mineralogy in the Mountain Pass carbonatite rare earth element deposit, USA

Economic concentrations of rare earth element (REE) minerals are uncommon in the Earth’s crust, with most occurring in carbonatites. Unlike most igneous rocks composed of silicate minerals, carbonatites are dominated by carbonate minerals, some of which can incorporate significant light REEs (LREEs; La, Ce, Pr, Nd). Technological applications of REEs are numerous and they have been identified as some of the most critical mineral commodities to the global economy. The Mountain Pass carbonatite stock in the Mojave Desert of California is the most economically significant REE deposit in the USA and contains a few to tens of percent (by volume) of the carbonate REE ore mineral bastnäsite. Despite the economic significance of the Mountain Pass deposit, studies of its ore mineralogy are limited. Here we present new carbonate ore mineralogy data for a compositionally diverse suite of carbonatitic rocks from the Mountain Pass stock and related dikes. Whole-rock geochemical data are integrated with mineral-scale textural and chemical data obtained by scanning electron microscopy (SEM), electron probe microanalysis (EPMA), and microRaman spectroscopy. Our results document a complex spectrum of REE-bearing carbonate minerals and intermediate mixed-layer structures. Mineral species include bastnäsite [REE(CO 3 )F], hydroxylbastnäsite [REE(CO 3 )OH], parisite [Ca(REE) 2 (CO 3 ) 3 F 2 ], synchysite [Ca(REE)(CO 3 ) 2 F], röntgenite [Ca 2 (Ce,La) 3 (CO 3 ) 5 F 3 ], and sahamalite [(Mg,Fe 2+ )(REE) 2 (CO 3 ) 4 ]. Carbonate ore mineralogy is heterogeneous within and between samples, including at the intracrystal scale. Complexly zoned crystals exhibit as many as five to six different compositional domains and syntaxial intergrowths, commonly with the more Ca-rich varieties (parisite, synchysite) forming crystal rims that surround relict bastnäsite cores. We attribute the phenocryst variability to changes in the chemistry and temperature of primary carbonatite magmas and evolved/exsolved fluids. Cross-cutting vein textures of calcite, celestine and various REE carbonate minerals, interstitial bastnäsite crystallization, breccia blocks lined by fine-grained bastnäsite, and the presence of hydroxylbastnäsite and partially hydroxylated bastnäsite point to the role of secondary hydrothermal processes in REE mineralization. Fluorcarbonate mineral compositions demonstrate that La and Ce are more structurally abundant in bastnäsite, whereas the more Ca-rich species (parisite, synchysite) contain a greater proportion of REE heavier than Pr (Nd, Sm, Eu, Gd) and Y. Atomic ratios of Pr/(Nd + Pr) are likewise variable, with the highest average value for bastnäsite (0.25) compared to parisite (0.22) and sychysite (0.21). This finding has geometallurgical implications, given that current mining operations are focused on recovery of Nd and Pr for high field strength permanent magnets and the Nd/Pr ratios are a critical factor in ore processing and magnet manufacture.

California

Rare earth element-mineralized carbonatite in the Bear Lodge Alkaline Complex, USA—Ore genesis implications from fluid inclusion characterization

Rare earth element (REE) resources of the Bear Lodge Alkaline Complex, Wyoming, are hosted in variably leached carbonatite spatially related to diatreme breccia pipes. We investigated the genesis of REE and lesser-known gold resources through fluid inclusion analysis of carbonatite, fluorite breccia, and smoky quartz vein samples. Physicochemical characteristics of inclusion-trapped fluids were evaluated using petrography, microthermometry, Raman spectroscopy, decrepitate mound analysis, energy-dispersive spectroscopy, laser ablation inductively coupled plasma mass spectrometry, and noble gas isotope analysis. Microthermometry results reveal three fluid types that affected carbonatite dikes within deeper zones that escaped near-surface, ore-grade REE enrichment: (1) high-temperature (330–432°C) magmatic fluid captured in fine-grained calcite; (2) REE-enriched alkali bicarbonate-sulfate brine; and (3) low-temperature (117–182°C) diluted magmatic or meteoric water. Multiphase brine-like inclusions contain burbankite, nahcolite, strontianite, celestine and alkali sulfate daughter crystals, linking them to early burbankite mineralization. Peripheral smoky quartz and fluorite occurrences at Smith Ridge, 1.5 km from the central carbonatite dike swarm, contain primary inclusions that are Cl-poor and rich in Na-HCO 3 -SO 4 , similar to secondary and pseudosecondary inclusions in carbonatites. Helium isotopes reveal a MORB-like source for carbonatite samples and an older crust signature at Smith Ridge, consistent with the proximal ridge-top exposures of Archean granite. Results from this fluid inclusion study coupled with previous studies of carbonatite mineral paragenesis, show that light REEs (LREEs) were not mobilized great distances. Instead, burbankite crystallized within carbonatite from alkali bicarbonate fluids. With sodium retained in early burbankite, outward-emanating fluids enriched in potassium relative to sodium (higher K:Na) resulted in potassium–ferric iron metasomatism of silicate host rocks. This alkali fractionation was accompanied by fractionation of LREEs and heavy REEs (HREEs), with LREEs dominating the central carbonatite resources. In contrast, areas of peripheral REE mineralization at Bear Lodge are commonly characterized by higher HREE:LREE ratios. The K:Na ratio of associated fenites or alteration assemblages could be indicative of early crystallized burbankite in carbonatites and REE fractionation processes potentially leading to areas of concentrated HREEs with greater supply vulnerabilities.

South Dakota, Wyoming

To heal or not to heal?: 2. The moment-recurrence time behavior of repeating earthquakes in the 2011 Prague, Oklahoma aftershock sequence is consistent with laboratory healing rates

The timing and failure conditions of an earthquake are governed by the interplay between fault reloading and restrengthening. The moment-recurrence time behavior of repeating earthquakes can give observational estimates of fault healing rates; however, it is difficult to link these observed healing rates to laboratory studies of frictional healing in part because of uncertainty in lithology. Here, we study the 2011 Prague earthquake sequence, which includes repeating earthquakes in the Arbuckle group and the granitic basement, and compare them to laboratory experiments on samples of the Arbuckle and Troy granite (representative of the basement rock) (Okamoto et al., 2025, https://doi.org/10.1029/2024JB030573 ). We find three spatially distinct groups of repeating earthquakes with different moment-recurrence behavior: (a) constant moment-recurrence time in the Arbuckle group, (b) scattered moment-recurrence time at the intersection of the foreshock-mainshock fault in the granitic basement, and (c) moment-predictable behavior outside of the foreshock-mainshock fault intersection also in the granitic basement. Our observation of stagnant healing for repeating sequences in the Arbuckle group is consistent with laboratory observations of low healing rates for moderately high pore fluid pressures in Arbuckle samples. For the moment-predictable group, the source radius that is required in order to match healing rates is consistent with source radius estimations when taking into account reasonable attenuation of the P- pulse width. Overall, we observe diverse healing behaviors in the seismic families that are consistent with laboratory healing rates, providing seismic evidence that contact-scale frictional mechanisms are relevant to large-scale earthquake dynamics.

Oklahoma

Reduction of red bed sedimentary rocks in connection with energy metal ore formation: A case study from the Sinbad seep, Mesa County, Colorado

The Paradox Basin’s Sinbad seep is a modern analog for ancient bleaching of red bed sediments by introduced alkaline, reducing brines. This bleaching, involving reductive alteration of former red beds, is essential ground preparation that enables the altered rocks to trap Cu, U, and V from later oxidized fluids, forming ore deposits. Study of Sinbad thus offers insights into these metallic mineralization processes in the Paradox and other sedimentary basins. The Sinbad seep occurs where shallow groundwater interacts with organic-rich petroleum source rocks, flows up a fault, and discharges into Salt Creek. Ratios of Na/Cl, Na/Br, and Cl/Br, plus high sulfate concentrations, indicate that the salinity of the seep water originated from dissolution of halite and gypsum during topographically driven flow of meteoric water across a diapir of the Pennsylvanian Paradox Formation, rather than from deep basinal brines. In contact with the organic-rich shales of the Paradox, these SO 4 -rich waters become reduced through bacterial reduction, producing H 2 S. The waters react with red beds of the Permian Cutler Formation, causing pervasive bleaching. The bleaching at Sinbad is characterized by iron-conservative reduction of ferric iron in diagenetic hematite and detrital ilmenite and magnetite to Fe sulfides. The ferrous iron is retained in these sulfides likely as sorbed Fe. Associated alteration includes precipitation of quartz and feldspar overgrowths, partial dissolution of detrital quartz and feldspar caused by pressure solution, formation of clay and authigenic rutile, and precipitation of carbonate and gypsum. The Fe sulfides rapidly degenerate to a mixture of jarosite and iron oxides on weathering at the surface. Among the major-oxide elements and most trace elements, there is no statistical difference between unbleached and bleached samples. The exceptions are uranium and sulfur, which are somewhat greater in bleached samples. Fission track radiography illuminates that uranium is preferentially concentrated in iron oxide cements, iron sorbed into detrital clasts, and finely disseminated iron oxide in illite cement in bleached samples. A leaching experiment suggests that uranium may be more easily available for mobilization from rocks that have undergone bleaching alteration, making them potential U sources. In addition, bleached rocks form effective traps for U, V, and some Cu mineralization.

Colorado

SUTRA— A code for simulation of saturated-unsaturated, variable-density groundwater flow with solute or energy transport—Documentation of the version 4.0 enhancements—Freeze-thaw capability, saturation and relative-permeability relations, spatially varying properties, and enhanced budget and velocity outputs

Version 4.0 of the Saturated-Unsaturated Transport (SUTRA) software code provides the capability to simulate the freezing and thawing of groundwater during energy transport simulations under saturated and unsaturated conditions. In addition to the types of hydrogeologic processes that SUTRA has been able to simulate in the past, this version can be used to study the effects of the freeze-thaw process on the flow and energy dynamics of hydrogeologic systems. The freeze-thaw simulation capability accounts for the latent heat of fusion and allows thermal property values to vary with changing total-water saturation, liquid-water saturation, and ice saturation. It allows the effective permeability of the porous medium to change as a result of freezing and thawing. This version also provides several user-selectable relations for the dependence of total-water saturation on fluid pressure, the dependence of liquid-water saturation on temperature during freezing and thawing, and the dependence of relative permeability on liquid saturation, as well as three user-selectable formulae for defining the bulk thermal conductivity of a mixture of solid grains, liquid water, ice, and air. For unsaturated simulations without freezing, the selectable total-water saturation relations eliminate the need for the user to program these and their associated relative-permeability functions, as had been required in previous SUTRA versions. Optional nonlinear dependence of fluid density on temperature, which covers the range from supercooled (about −50 degrees Celsius) to superheated (about 400 degrees Celsius), is also provided. Additionally, this version makes it possible to spatially vary parameters that, in previous versions of SUTRA, were required to be spatially uniform: solid-matrix properties, adsorption parameters, and parameters for production of solute mass or energy. Spatial variation is also allowed for the newly included freeze-thaw process parameters. Additional enhancements provide (1) output of water-mass and energy budgets that include values of all component terms in the governing balance equations, and (2) output of Darcy velocities (fluid fluxes), in addition to the velocity output provided by previous SUTRA versions. These enhanced outputs allow fuller interpretation of simulation results, especially for freeze-thaw phenomena. The set of processes simulated by this version of SUTRA are useful for studying a wide range of hydrogeologic system types, conditions, and questions. For cryohydrogeologic simulations, however, this version of the code is limited in that (1) it does not simulate thermomechanical effects of freeze-thaw, (2) pressure changes due to water density change during freezing are neglected, (3) ice saturation cannot exceed the initial porosity of the simulated medium, and (4) cryosuction, the migration of liquid water toward freezing fronts, is neglected. Furthermore, this version does not account for air flow or for water vaporization and sublimation under unsaturated conditions.

Techniques and Methods

Seasonal migrations and other movements

In the past 25 years new information has been obtained on the migrations and movements of mountain sheep (bighorn [Ovis canadensis], thinhorn [Ovis dalli]). This chapter provides a comprehensive overview of mountain sheep migration and other movements across their broad distribution in western North America. Across the range of mountain sheep, migrations and other seasonal movements define a complex movement portfolio that relates to and supports all aspects of mountain sheep ecology. Bighorn and thinhorn species have examples of migratory behaviors that span the continuum between annual residents and long-distance migrants. Migratory behaviors can be characterized as low- or high-elevation residents; elevational migrations and other variants; and geographic migrants. Native populations that have been extant on the landscape without notable human intervention have greater migratory propensity and more diverse migratory portfolios due to the maintenance of migration through cultural learning and social transmission. Restored and augmented populations, where the population-level knowledge of migration has been lost or greatly reduced, are largely nonmigratory, although translocations show some ability to restore short-distance elevational migrations. Seasonal spring and fall migrations are less common in desert bighorn sheep (O. canadensis spp.) or bighorn sheep living in canyon or prairie breaks landscapes. Mineral lick visitation is important and common across the range of mountain sheep. Managing for migratory diversity can help to sustain migratory behavior in the face of climate change and other anthropogenic pressures, which can limit landscape connectivity between seasonal ranges or alter the spatiotemporal dynamics of regional phenology with cascading effects to other biotic and abiotic interactions such as the need to balance forage and predation risk or the spatial refugia with increased temperatures.

Book chapter

Utilizing downhole datasets for modelling the aeromagnetic signature of the Iron Creek Co-Cu deposit in the Idaho Cobalt Belt

The Idaho Cobalt Belt in east-central Idaho is host to some of the largest domestic Co resources, including the informal Iron Creek deposit. The two main ore zones of this deposit, the Iron Creek and the Ruby, are hosted in greenschist-grade interbedded argillite/siltstone and quartz-rich units of the Mesoproterozoic Apple Creek Formation of Lemhi Group. The primary ore mineral is cobalt-bearing pyrite, which occurs with pyrrhotite, chalcopyrite, and magnetite. This study integrates mineralogical and core-scale geophysical measurements with regional-scale aeromagnetic surveys. The high magnetite content within the Ruby zone produces elevated magnetic susceptibility, but the relatively limited spatial footprint of the ore zone would produce a small-scale anomaly that may be overlooked in regional surveys. The low magnetite content in the Iron Creek zone results in low magnetic susceptibility, creating a relatively low amplitude geophysical response. By characterizing the magnetic properties and mineralogy of these ore zones, this study enhances the interpretation of aeromagnetic data, enabling the identification of small or faint anomalies as potential Co targets. These findings improve can improve exploration strategies, both within the Idaho Cobalt Belt as well as for similar deposit types globally.

Idaho

Enhancing mineral systems exploration through geochronology, thermochronology, and isotope analysis: USGS Geochron and USGS Isotope databases

A mineral systems approach to mineral exploration provides a comprehensive framework for understanding ore deposit formation by examining the geodynamic, magmatic, hydrothermal, and sedimentary processes responsible for mineralization, alteration, and remobilization of economic mineral deposits. Temporal and thermal constraints on ore genesis are crucial for refining mineral system models and guiding predictive exploration strategies. Geochronology and thermochronology offer invaluable insights into the timing and thermal evolution of ore-forming processes, whereas isotopic analyses provide critical information on the source and geochemical history of ore-forming fluids. Combining these methodologies have proven highly effective for mineral exploration in regions like Australia, however, their combined application has been limited in the United States. To apply these tools to mineral systems-based exploration, the U.S. Geological Survey (USGS) has developed two products: (1) The USGS Geochron Database, and (2) the USGS Isotope Database. These databases provide centralized repositories of geo/thermochronological dates and data (Geochron Database) and both radiogenic and stable isotope data (Isotope Database) generated by the USGS and partners over the past decades. Integrating these datasets together and with traditional exploration approaches provides the mineral exploration community with powerful tools for determining the temporal and thermal histories of ore systems and identifying metallogenic source provinces.

Continental United States

Seismic techniques and suggested instrumentation to monitor volcanoes

Introduction Changes in the pressure or location of magma can stress or break surrounding rocks and trigger flow of nearby waters and gases, causing seismic signals, such as discrete earthquakes and tremor. These phenomena are types of seismic unrest that commonly precede eruption and can be used to forecast volcanic activity. Mass movements at the surface, including avalanches, debris flows, and lahars, may also generate seismic signals that are specifically addressed in chapter H , this volume (Thelen and others, 2024). Our focus in this chapter is to determine the levels of instrumentation recommended to produce high-quality, well-constrained seismic observations important for early warning of impending eruptions, detecting changes in ongoing eruptions, and characterizing other hazardous volcanic events. There are emerging techniques and new types of instrumentation, such as distributed acoustic sensing or rotational seismometers, that we do not consider here. These types of instrumentation show promise for monitoring but still require maturation before being considered more generally in volcano monitoring. Most of the capabilities mentioned below are universal for all types of volcanic systems, although some are best applied to stratovolcanoes with an apical single vent. In some settings, such as calderas or shield volcanoes, we must broaden coverage to include multiple possible storage regions or vent locations. As an example, Thelen (2014) discretized the long rift zones of shield volcanoes in Hawaiʻi as a set of evenly spaced “vents.” In this construct, each vent comes with recommendations, and several thousand network configurations were simulated to assess the effect on network quality levels and to determine the most efficient network design. The same process could be applied in a caldera setting or a volcanic field, where an evenly spaced grid of potential vents is considered. Localized recommendations for each unique system are beyond the scope of this report and left up to local experts to assess based on the conditions, restrictions, and requirements of each volcano.

Scientific Investigations Report