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Late-Glacial paleoecology of the Middle Susitna Valley, Alaska: Environmental context for human dispersal

We present here the results of multi-proxy analyses (sediment geochemistry, diatoms, and pollen) from sediment cores collected at four lakes in the middle Susitna Valley, Alaska. These lakes form a transect from the tundra to the boreal forest. The retrieved cores span from ~12,000 cal yr BP to the present, with age control provided by radiometric dates and tephra deposits, some of which are newly identified. Results indicate that deglaciation occurred before 12,000 cal yr BP and that by that time, the lakes were deep, productive, and surrounded by shrub tundra. The lake with the highest sampling resolution indicates a brief climatic reversal ~11,500 cal yr BP with decreased diatom-inferred lake level and lowered lake productivity, and reduced shrub presence. During the early to middle Holocene, all of the sedimentary records provide evidence of climatic amelioration with tree expansion and productive lakes. A middle to late Holocene climatic deterioration with reduced trees and a shallower, less productive lake is also indicated. In addition, the prominent Watana tephra at ~4,000 cal yr BP likely reduced lake productivity and affected the vegetation. Even though the region was relatively productive soon after deglaciation, people did not occupy the region until ~11,000 cal yr BP, about 1000 years later, and then only sparsely. By the middle and late Holocene, the region was more densely populated and this shift in human occupancy presumably reflects changes in resource abundance, especially caribou. Whether the Watana ashfall influenced caribou abundance and thus people, is still under investigation, but given the tephra’s effect on vegetation and lake productivity, it seems likely.

Alaska

Atlas of microscopic images of biochar using reflected light microscopy in biochar characterization

Derived through the thermochemical conversion of biomass, biochar is a carbon-rich substance recognized for its significance in environmental applications and sustainable agriculture. As interest in its utilization continues to rise, it becomes crucial to comprehend how the source material and pyrolysis parameters influence the properties of biochar and, consequently, to research the suitability of various analytical methods for characterizing it. Despite the current utilization of numerous physical and chemical methods, the untapped potential of reflected light microscopy warrants further exploration. While a few recent studies suggest a correlation between certain microscopic characteristics and selected physical and chemical properties of biochar, the data are limited and difficult to compare. This is primarily due to variations in the types of original biomass used and lack of information about pyrolysis conditions. Moreover, because only a limited number of photographs taken under a reflected light microscope are publicly available to-date, it is difficult to evaluate morphological differences between various biochars and other organic materials such as inertinites from coal, charcoal, etc. To address limited availability of publicly available data, this “Atlas of Microscopic Images of Biochar” presents a collection of more than 300 images contributed by researchers from Poland, the United States, Canada, Australia, Brazil, and Denmark. These photomicrographs capture optical characteristics of a diverse array of biochar, demonstrating its unique morphological and structural features. This visual documentation can serve as a valuable resource for researchers, industry professionals, educators, and enthusiasts interested in investigating the complexities of biochar forms.

Indiana Journal of Earth Sciences

Evaluation of remote mapping techniques for earthquake-triggered landslide inventories in an urban subarctic environment: A case study of the 2018 Anchorage, Alaska Earthquake

Earthquake-induced landslide inventories can be generated using field observations but doing so can be challenging if the affected landscape is large or inaccessible after an earthquake. Remote sensing data can be used to help overcome these limitations. The effectiveness of remotely sensed data to produce landslide inventories, however, is dependent on a variety of factors, such as the extent of coverage, timing, and data quality, as well as environmental factors such as atmospheric interference (e.g., clouds, water vapor) or snow and vegetation cover. With these challenges in mind, we use a combination of field observations and remote sensing data from multispectral, light detection and ranging (lidar), and synthetic aperture radar (SAR) sensors to produce a ground failure inventory for the urban areas affected by the 2018 magnitude (M w ) 7.1 Anchorage, Alaska earthquake. The earthquake occurred during late November at high latitude (∼61°N), and the lack of sunlight, persistent cloud cover, and snow cover that occurred after the earthquake made remote mapping challenging for this event. Despite these challenges, 43 landslides were manually mapped and classified using a combination of the datasets mentioned previously. Using this manually compiled inventory, we investigate the individual performance and reliability of three remote sensing techniques in this environment not typically hospitable to remotely sensed mapping. We found that differencing pre- and post-event normalized difference vegetation index maps and lidar worked best for identifying soil slumps and rapid soil flows, but not as well for small soil slides, soil block slides and rock falls. The SAR-based methods did not work well for identifying any landslide types because of high noise levels likely related to snow. Some landslides, especially those that resulted in minor surface displacement, were identifiable only from the field observations. This work highlights the importance of the rapid collection of field observations and provides guidance for future mappers on which techniques, or combination of techniques, will be most effective at remotely mapping landslides in a subarctic and urban environment.

Alaska

Soil property and class maps of the conterminous United States at 100-meter spatial resolution

With growing concern for the depletion of soil resources, conventional soil maps need to be updated and provided at finer and finer resolutions to be able to support spatially explicit human–landscape models. Three US soil point datasets—the National Cooperative Soil Survey Characterization Database, the National Soil Information System, and the Rapid Carbon Assessment dataset—were combined with a stack of over 200 environmental datasets and gSSURGO polygon maps to generate complete coverage gridded predictions at 100-m spatial resolution of six soil properties (percentage of organic C, total N, bulk density, pH, and percentage of sand and clay) and two US soil taxonomic classes (291 great groups [GGs] and 78 modified particle size classes [mPSCs]) for the conterminous United States. Models were built using parallelized random forest and gradient boosting algorithms as implemented in the ranger and xgboost packages for R. Soil property predictions were generated at seven standard soil depths (0, 5, 15, 30, 60, 100, and 200 cm). Prediction probability maps for US soil taxonomic classifications were also generated. Cross validation results indicated an out-of-bag classification accuracy of 60% for GGs and 66% for mPSCs; for soil properties, RMSE for leave-location-out cross-validation was 0.74 ( R 2 = 0.68), 17.8 wt% ( R 2 = 0.57), 12 wt% ( R 2 = 0.46), 3.63 wt% ( R 2 = 0.41), 0.2 g cm −3 ( R 2 = 0.42), and 0.27 wt% ( R 2 = 0.39) for pH, percent sand and clay, weight percentage of organic C, bulk density, and weight percentage of total N, respectively. Nine independent validation datasets were used to assess prediction accuracies for soil class models, and results ranged between 24 and 58% and between 24 and 93% for GG and mPSC prediction accuracies, respectively. Although mapping accuracies were variable and likely lower than gSSURGO in some areas, this modeling approach can enable easier integration of soil information with spatially explicit models compared with multicomponent map units.

Soil Science Society of America Journal

Overview of the Opportunity Mars Exploration Rover Mission to Meridiani Planum: Eagle Crater to Purgatory Ripple

The Mars Exploration Rover Opportunity touched down at Meridiani Planum in January 2004 and since then has been conducting observations with the Athena science payload. The rover has traversed more than 5 km, carrying out the first outcrop‐scale investigation of sedimentary rocks on Mars. The rocks of Meridiani Planum are sandstones formed by eolian and aqueous reworking of sand grains that are composed of mixed fine‐grained siliciclastics and sulfates. The siliciclastic fraction was produced by chemical alteration of a precursor basalt. The sulfates are dominantly Mg‐sulfates and also include Ca‐sulfates and jarosite. The stratigraphic section observed to date is dominated by eolian bedforms, with subaqueous current ripples exposed near the top of the section. After deposition, interaction with groundwater produced a range of diagenetic features, notably the hematite‐rich concretions known as “blueberries.” The bedrock at Meridiani is highly friable and has undergone substantial erosion by wind‐transported basaltic sand. This sand, along with concretions and concretion fragments eroded from the rock, makes up a soil cover that thinly and discontinuously buries the bedrock. The soil surface exhibits both ancient and active wind ripples that record past and present wind directions. Loose rocks on the soil surface are rare and include both impact ejecta and meteorites. While Opportunity's results show that liquid water was once present at Meridiani Planum below and occasionally at the surface, the environmental conditions recorded were dominantly arid, acidic, and oxidizing and would have posed some significant challenges to the origin of life.

Journal of Geophysical Research E: Planets

Dynamics of the recovery of the western Lake Erie walleye (Stizostedion vitreum vitreum) stock

After its 1957 collapse under intensive fishing and environmental stresses, the walleye (Stizostedion vitreum vitreum) stock of western Lake Erie remained low throughout the 1960s. A moratorium on both sport and commercial fishing, resulting from the 1970 discovery of mercury concentrations in walleye flesh, provided an opportunity for the development of an international interagency management plan. The quota management plan developed depended on sequential projection of the fishable stock on the basis of estimated annual recruitment and reports of total withdrawals from the stock. The fishery reopened gradually and quota management (including allocation among jurisdictions) was implemented in 1976. The stock, which had been gradually increasing as a result of relatively strong year-classes produced in 1970, 1972, and 1974, responded well to limited exploitation and produced a record year-class in 1977. Quotas were exceeded in 1978-80, but the stock continued to improve to the extent that the recommended rate of exploitation was increased in 1980 and again in 1981. As the population expanded, growth began to decline; the decline became apparent in young-of-the-year in the early 1970s and in older walleyes in the late 1970s. This trend toward progressively slower growth, which continued in the 1977 and subsequent year-classes, was accompanied by an increase in length at sexual maturity and a decrease in the percentage of female walleyes reaching sexual maturity at age III. As a net result of these changes, the proportion of mature females in the stock (an index of stock fecundity) decreased slightly during the interval 1975-84, while the estimated biomass of the standing stock rose from 9 000 to nearly 26 000 t. Both sport and commercial catches increased markedly after 1980 in Lake Erie's central basin.

Canadian Journal of Fisheries and Aquatic Sciences

EXAFS study of mercury(II) sorption to Fe- and Al-(hydr)oxides - II. Effects of chloride and sulfate

Common complexing ligands such as chloride and sulfate can significantly impact the sorption of Hg(II) to particle surfaces in aqueous environmental systems. To examine the effects of these ligands on Hg(II) sorption to mineral sorbents, macroscopic Hg(II) uptake measurements were conducted at pH 6 and [Hg]i=0.5 mM on goethite (??-FeOOH), ??-alumina (??-Al2O3), and bayerite (??-Al(OH)3) in the presence of chloride or sulfate, and the sorption products were characterized by extended X-ray absorption fine structure (EXAFS) spectroscopy. The presence of chloride resulted in reduced uptake of Hg(II) on all three substrates over the Cl- concentration ([Cl-]) range 10-5 to 10-2 M, lowering Hg surface coverages on goethite, ??-alumina, and bayerite from 0.42 to 0.07 ??mol/m2, 0.06 to 0.006 ??mol/m2, and 0.55 to 0.39 ??mol/m2 ([Cl -]=10-5 to 10-3 M only), respectively. This reduction in Hg(II) uptake is primarily a result of the formation of stable, nonsorbing aqueous HgCl2 complexes in solution, limiting the amount of free Hg(II) available to sorb. At higher [Cl-] beam reduction of Hg(II) to Hg(I) was observed, resulting in the possible formation of aqueous Hg2Cl2 species and the precipitation of calomel, Hg 2Cl2(s). The presence of sulfate caused enhanced Hg(II) uptake over the sulfate concentration ([SO42-]) range 10-5 to 0.9 M, increasing Hg surface coverages on goethite, ??-alumina, and bayerite from 0.39 to 0.45 ??mol/m2, 0.11 to 0.38 ??mol/m2, and 0.36 to 3.33 ??mol/m2, respectively. This effect is likely due to the direct sorption or accumulation of sulfate ions at the substrate interface, effectively reducing the positive surface charge that electrostatically inhibits Hg(II) sorption. Spectroscopic evidence for ternary surface complexation was observed in isolated cases, specifically in the Hg-goethite-sulfate system at high [SO42-] and in the Hg-goethite-chloride system. ?? 2003 Elsevier Inc. All rights reserved.

Journal of Colloid and Interface Science

Management of ground water and evolving hydrogeologic studies in New Jersey : a heavily urbanized and industrialized state in the northeastern United States

New Jersey is the most densely populated and one of the most industrialized states in the United States. An abundance of freshwater and proximity to major northeastern metropolitan centers has facilitated this development. Pumpage of freshwater from all aquifers in the State in 1980 was 730 million gallons per day (2.76 million cubic meters per day). Management and efficient development of the ground-water resources of the State are the responsibility of the New Jersey Department of Environmental Protection. Laws have been enacted and updated by the State legislature to manage water allocation and to control the disposal of hazardous wastes. Present resource management is guided by the New Jersey Water-Supply Master Plan of 1981. Funding for management activities is partially derived from the sale of state-approved bonds. Effective planning and regional management require accurate and up-to-date hydrologic information and analyses. The U.S. Geological Survey, in cooperation with the New Jersey Geological Survey, is conducting three intensive ground-water studies involving the collection and interpretation of hydrologic data to meet the urgent water-management needs of New Jersey. These studies are part of a long-term cooperative program and are funded through the Water-Supply Bond Act of 1981. They began in 1983 and are scheduled to be completed in 1988. The project areas are situated in the New Jersey part of the Atlantic Coastal Plain in and near Atlantic City, Camden, and South River. They range in size from 400 to 1,200 mil (1,040 to 3,120 km2). The studies are designed to define the geology, hydrology, and geochemistry of the local ground-water systems. The results of these studies will enable the State to address more effectively major problems in these areas such as declining water levels, overpumping, saltwater intrusion, and ground-water contamination resulting from the improper disposal of hazardous wastes. Specific objectives of these studies by the U.S. Geological Survey are to (1) develop an accurate and up-to-date hydrogeologic data base, (2) design and implement a data-collection program and establish a computerized information management system, (3) refine the conceptualization of the ground-water flow system, and (4) define the geochemistry of the aquifer system by conducting a water-quality appraisal. The objectives are accomplished by standard hydrogeologic methods. Information concerning hydrogeologic framework, ground-water levels, water use, hydraulic characteristics, and water quality in the study areas is compiled from all available sources. Additional data needed are collected through well inventories, surface geophysical surveys, water-quality samplings, water-level measurements, and a well-drilling program. Interpretation of the flow system is based on the use of standard analytical techniques and digital flow modeling. Calibrated flow models will provide ground-water managers with a mechanism to develop and test regional water-supply strategies. Definition of the geochemistry of the aquifer system is accomplished through a variety of methods which depend on the problems and available data in the particular study area. The approach includes statistical analysis of water-quality data, reaction-path modeling, and determination of the movement of chemical constituents using analytical and numerical modeling techniques. A combined staff of 25 to 30 professionals and technicians from the New Jersey District office of the U.S. Geological Survey is committed to the three studies. The staff has specialists in geohydrology, numerical modeling, geochemistry, geophysics, and computer science. The findings of these studies will be published in data reports, interpretive reports, instructional manuals and journal articles.

New Jersey

The saturated zone at Yucca Mountain: An overview of the characterization and assessment of the saturated zone as a barrier to potential radionuclide migration

The US Department of Energy is pursuing Yucca Mountain, Nevada, for the development of a geologic repository for the disposal of spent nuclear fuel and high-level radioactive waste, if the repository is able to meet applicable radiation protection standards established by the US Nuclear Regulatory Commission and the US Environmental Protection Agency (EPA). Effective performance of such a repository would rely on a number of natural and engineered barriers to isolate radioactive waste from the accessible environment. Groundwater beneath Yucca Mountain is the primary medium through which most radionuclides might move away from the potential repository. The saturated zone (SZ) system is expected to act as a natural barrier to this possible movement of radionuclides both by delaying their transport and by reducing their concentration before they reach the accessible environment. Information obtained from Yucca Mountain Site Characterization Project activities is used to estimate groundwater flow rates through the site-scale SZ flow and transport model area and to constrain general conceptual models of groundwater flow in the site-scale area. The site-scale conceptual model is a synthesis of what is known about flow and transport processes at the scale required for total system performance assessment of the site. This knowledge builds on and is consistent with knowledge that has accumulated at the regional scale but is more detailed because more data are available at the site-scale level. The mathematical basis of the site-scale model and the associated numerical approaches are designed to assist in quantifying the uncertainty in the permeability of rocks in the geologic framework model and to represent accurately the flow and transport processes included in the site-scale conceptual model. Confidence in the results of the mathematical model was obtained by comparing calculated to observed hydraulic heads, estimated to measured permeabilities, and lateral flow rates calculated by the site-scale model to those calculated by the regional-scale flow model. In addition, it was confirmed that the flow paths leaving the region of the potential repository are consistent with those inferred from gradients of measured head and those independently inferred from water-chemistry data. The general approach of the site-scale SZ flow and transport model analysis is to calculate unit breakthrough curves for radionuclides at the interface between the SZ and the biosphere using the three-dimensional site-scale SZ flow and transport model. Uncertainties are explicitly incorporated into the site-scale SZ flow and transport abstractions through key parameters and conceptual models. ?? 2002 Elsevier Science B.V. All rights reserved.

Journal of Contaminant Hydrology

Evaluating the effect of expert elicitation techniques on population status assessment in the face of large uncertainty

Population projection models are important tools for conservation and management. They are often used for population status assessments, for threat analyses, and to predict the consequences of conservation actions. Although conservation decisions should be informed by science, critical decisions are often made with very little information to support decision-making. Conversely, postponing decisions until better information is available may reduce the benefit of a conservation decision. When empirical data are limited or lacking, expert elicitation can be used to supplement existing data and inform model parameter estimates. The use of rigorous techniques for expert elicitation that account for uncertainty can improve the quality of the expert elicited values and therefore the accuracy of the projection models. One recurring challenge for summarizing expert elicited values is how to aggregate them. Here, we illustrate a process for population status assessment using a combination of expert elicitation and data from the ecological literature. We discuss the importance of considering various aggregation techniques, and illustrate this process using matrix population models for the wood turtle ( Glyptemys insculpta ) to assist U.S. Fish and Wildlife Service decision-makers with their Species Status Assessment. We compare estimates of population growth using data from the ecological literature and four alternative aggregation techniques for the expert-elicited values. The estimate of population growth rate based on estimates from the literature (λ mean = 0.952, 95% CI: 0.87–1.01) could not be used to unequivocally reject the hypotheses of a rapidly declining population nor the hypothesis of a stable, or even slightly growing population, whereas our results for the expert-elicited estimates supported the hypothesis that the wood turtle population will decline over time. Our results showed that the aggregation techniques used had an impact on model estimates, suggesting that the choice of techniques should be carefully considered. We discuss the benefits and limitations associated with each method and their relevance to the population status assessment. We note a difference in the temporal scope or inference between the literature-based estimates that provided insights about historical changes, whereas the expert-based estimates were forward looking. Therefore, conducting an expert-elicitation in addition to using parameter estimates from the literature improved our understanding of our species of interest.

Journal of Environmental Management