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Geochemical processes related to mined, milled, or natural metal deposits in a rapidly changing global environment

The demand for metals and raw materials, such as nickel and copper, has been projected to expand in the coming decades, driven by the global energy transition, the need for green technologies, and expanding infrastructure. Consequently, the increasing extraction and production of mining waste can have adverse impacts on surrounding environments and human health. The aim of this thematic collection is to fill critical knowledge gaps in the present-day cycles of metal(loid)s from source to larger sinks, and the effect of environmental management, anthropogenic development, and climate change. Altogether, the studies have been conducted in different natural settings around the world and comprise investigations in laterites, a soil-medicinal plant system, watersheds, and banded iron formations, among others. The geochemical applications in tracing mineralization, its secondary products, and/or potential impact on the immediate environment are highly diverse with applied tools ranging from isotope tracers to major and trace element systematics. Particularly the use of rare earth elements, their patterns and anomalies are methods employed by several studies in this collection. We summarize the findings to offer a potential future direction for the use of geochemical tracing techniques in resource exploration in the context of climate change and environmental challenges.

Geochemistry: Exploration, Environment, Analysis

Melt generation sources and conditions in the wake of a migrating slab window: Geochemistry and petrology of the million-year history of primitive volcanism at Clear Lake volcanic field, California

Clear Lake volcanic field (CLVF) is the northernmost and youngest (~2.2 Ma to 8 ka) of the volcanic centers distributed along the San Andreas transform fault in western California. The initial phase of CLVF volcanism (interval one) occurred between ~2.2 and 1.3 Ma and extends ~35 km southeast of Clear Lake, forming a semi-continuous upland plateau capped by lava flows, with isolated volcanic remnants on the periphery. This volcanism is broadly characterized by geochemically primitive compositions that reflect three source compositions and conditions of melt generation. (1) Partial melting of upwelling asthenospheric mantle lherzolite at moderate pressures (1.2–1.4 GPa) and temperatures (1297–1329 °C) produced high-CaO (9.8–11.3 wt %) basalts with high Al 2 O 3 (16.8–17.6 wt %), Mg#s (66–70), MgO (8–10 wt %), Ni (103–262 μg/g), and Cr (284–609 μg/g). These high-CaO basalts contain olivine (Fo 87–91 ) phenocrysts with Cr-spinel inclusions ± subordinate plagioclase and crop out only in the southern part of the CLVF. (2) Partial melting of depleted sub-continental lithospheric mantle harzburgite at variable pressures (0.7–1.5 GPa) and temperatures (1097–1299 °C) produced a compositional continuum of med-K 2 O, calc-alkaline, high-MgO basalts through high-MgO andesites with high Mg#s (67–77), MgO (8–14 wt %) and high Ni and Cr abundances (154–439 and 340–1124 μg/g, respectively). Mineral assemblages are olivine (Fo 88–93 ) with Cr-spinel inclusions ± subordinate clinopyroxene, orthopyroxene and plagioclase. Small (<2.5 cm) mantle harzburgite xenoliths and mantle olivine xenocrysts are also found in several of these samples. These high-MgO basalts through andesites represent the largest volume of primitive compositions and have erupted predominantly along the main, fault-controlled northwest-southeast trending axis of volcanism with peripheral outcrops to the north, west, and east. (3) Partial melting of the Gorda eclogite slab edge produced adakitic silicic slab melts with strong depletion in the heavy rare earth elements (Yb = 0.6 μg/g). Subsequent reaction of those melts with depleted ultramafic rocks during ascent imprinted the adakitic dacites with high Mg#s (65–78) and elevated Ni (117–210 μg/g) and Cr (191–283 μg/g). Phenocrysts of orthopyroxene (En 87–94 ) with spinel inclusions (Cr# = 80–88) and extremely Ni-rich (9483 μg/g) olivine cores (Fo 84–93 ) record those reactions. Small-volume outcrops of the adakites on the eastern periphery of the CLVF track the passing slab edge. The trio of melting sources recorded by early CLVF magmatism reflect the tectonically complex environment and the hot (1097–1329 °C), shallow (0.7–1.5 GPa) melting conditions for these primitive compositions and provide estimates of the heat delivered to the crust. Over time, this flux led to maturation of the CLVF magmatic system toward the more voluminous and silicic volcanism that characterizes the balance of its subsequent volcanic history and maintains the present-day anomalously high heat flow in the region. The current interval (interval four) of volcanic activity at CLVF is characterized by low-volume, fault-controlled eruptions of basaltic andesite and andesite suggestive of mantle magma and heat delivery to the crust, similar to interval one. This analogous activity provides motivation for the current study and begs the question of whether the system is undergoing thermal priming for renewed silicic volcanism.

California

Spatially referenced watershed models for the binational Red–Assiniboine River Basin: Bayesian vs frequentist comparison

Excess nutrient loading remains a leading cause of declining water quality in lakes, estuaries, and coastal waters worldwide, with global economic costs of US$200 billion – US$2 trillion annually from impacts on fisheries, tourism, freshwater resources, and water treatment. Our study focuses on total phosphorus (TP) in Lake Winnipeg and its binational Red-Assiniboine River Basin, where nutrient inputs have degraded water quality and increased cyanobacterial blooms. These changes pose ecological, public health, and economic risks. We applied a spatially referenced watershed model with a hybrid statistical-mechanistic structure partitioning annual nutrient loads into land-use export, land-to-water delivery, and in-reservoir decay. Bayesian and traditional frequentist model calibrations were compared. In the frequentist model, coefficients for agricultural inputs, forests /wetlands, stream channels, precipitation, and reservoir losses were statistically significant, whereas coefficient for wastewater was not. In contrast, all variables were successfully calibrated using the Bayesian approach. Model results delineate TP-export hotspots across the basin, showing that 54–62% of TP originates from the U.S., with agricultural sources ranging 62–72%—highlighting the importance of agriculture-focused Best Management Practices. Given the global relevance of nutrient-driven water-quality challenges, our results highlight Bayesian calibration for robust risk assessment and adaptive nutrient management.

Red–Assiniboine River Basin

Per- and polyfluoroalkyl substances in waters associated with oil and gas development in the Denver Basin

Use of per- and polyfluoroalkyl substances (PFAS) in the petroleum industry could be a cause for concern due to the large volumes of produced water (PW) generated during oil and gas extraction, the reuse of these wastes in water-stressed regions, and adverse health outcomes related to PFAS exposures. However, PW PFAS characterization is nearly absent in the literature, and hydraulic fracturing (HF) chemical disclosures often omit the identities of additives as proprietary. Here we evaluate PFAS in PW samples from three petroleum wells in the Denver Basin during their first year of production. Total concentrations of targeted PFAS (Σ 40 PFAS) were < 35 ng/L in PW samples, with short-chain PFAS like perfluorobutanoic acid persisting throughout the sampled duration. Analysis of freshwater inputs for hydraulic fracturing (Σ 40 PFAS ~ 113 ng/L) and mixed fracture fluid (Σ 40 PFAS ~ 69 ng/L) indicated much of the targeted PFAS content was derived from the input water, and not from HF additives, however samples subjected to oxidation indicated the presence of PFAS precursors that would not be detected by targeted analysis. This study highlights that while PFAS content is low in the studied PWs, the potential for redistribution of PFAS in the environment may be a consideration for reuse applications.

Colorado, Nebraska, Wyoming

Vulnerability assessment of groundwater influenced ecosystems in the Northeastern United States

Groundwater-influenced ecosystems (GIEs) are increasingly vulnerable due to groundwater extraction, land-use practices, and climate change. These ecosystems receive groundwater inflow as a portion of their baseflow or water budget, which can maintain water levels, water temperature, and chemistry necessary to sustain the biodiversity that they support. In some systems (e.g., springs, seeps, fens), this connection with groundwater is central to the system’s integrity and persistence. Groundwater management decisions for human use often do not consider the ecological effects of those actions on GIEs. This disparity can be attributed, in part, to a lack of information regarding the physical relationships these systems have with the surrounding landscape and climate, which may influence the environmental conditions and associated biodiversity. We estimate the vulnerability of areas predicted to be highly suitable for the presence of GIEs based on watershed (U.S. Geological Survey Hydrologic Unit Code 12 watersheds: 24–100 km 2 ) and pixel (30 m × 30 m pixels) resolution in the Atlantic Highlands and Mixed Wood Plains EPA Level II Ecoregions in the northeastern United States. We represent vulnerability with variables describing adaptive capacity (topographic wetness index, hydric soil, physiographic diversity), exposure (climatic niche), and sensitivity (aquatic barriers, proportion urbanized or agriculture). Vulnerability scores indicate that ~26% of GIEs were within 30 m of areas with moderate vulnerability. Within these GIEs, climate exposure is an important contributor to vulnerability of 40% of the areas, followed by land use (19%, agriculture or urbanized). There are few areas predicted to be suitable for GIEs that are also predicted to be highly vulnerable, and of those, climate exposure is the most important contributor to their vulnerability. Persistence of GIEs in the northeastern United States may be challenged as changes in the amount and timing of precipitation and increasing air temperatures attributed to climate change affect the groundwater that sustains these systems.

Connecticut, Delaware, District of Columbia, Maine

Assessment of groundwater quantity and quality contributions to Lake Huron

Lake Huron, one of the five Great Lakes, borders the United States and Canada, with Michigan as the only U.S. State on its shoreline. Like other freshwater lakes, it faces water-quality challenges from nutrients and chemicals applied across its drainage basin. Although past studies focused on surface-water sources, groundwater contributions remain less understood. To address this gap, the U.S. Geological Survey, as part of the Cooperative Science and Monitoring Initiative, classified drainage basins to Lake Huron into eight hydrogeologic zones based on bedrock rock type and glacial sediment transmissivity. Utilizing existing data and empirical field data, we quantified groundwater discharge and identified areas of concern for loading of chloride and nitrate to Lake Huron. Groundwater contributions, including indirect and shoreline discharge, ranged from 5.8 to 11.5 inches annually, totaling 1.9 cubic miles and 0.09 cubic mile, respectively. Hydrogeologic zones with higher glacial sediment transmissivity yielded greater indirect groundwater discharge. Chloride levels above the U.S. Environmental Protection Agency’s 250-mg/L recommendation were mainly in the Saginaw lowlands, whereas nitrate above the 10-mg/L standard was rare—found in only 11 wells. Together, the analysis of where groundwater discharge is occurring in the Lake Huron Basin and the identification of areas with potential groundwater-quality concerns can help prioritize areas that are critical to protecting the long-term health of Lake Huron.

Michigan

Gaps in water quality modeling of hydrologic systems

This review assesses gaps in water quality modeling, emphasizing opportunities to improve next-generation models that are essential for managing water quality and are integral to meeting goals of scientific and management agencies. In particular, this paper identifies gaps in water quality modeling capabilities that, if addressed, could support assessments, projections, and evaluations of management alternatives to support ecosystem health and human beneficial use of water resources. It covers surface water and groundwater quality modeling, dealing with a broad suite of physical, biogeochemical, and anthropogenic drivers. Modeling capabilities for six constituents (or constituent categories) are explored: water temperature, salinity, nutrients, sediment, geogenic constituents, and contaminants of emerging concern. Each constituent was followed through the coupled atmospheric-hydrologic-human system, with prominent modeling gaps described for a diverse array of relevant inputs, processes, and human activities. Commonly identified modeling gaps primarily fall under three types: (1) model gaps, (2) data gaps, and (3) process understanding gaps. In addition to potential solutions for addressing specific individual modeling limitations, some broad approaches (e.g., enhanced data collection and compilation, machine learning, reduced-complexity modeling) are discussed as ways forward for tackling multiple gaps. This gap analysis establishes a framework of diverse approaches that may support improved process representation, scale, and accuracy of models for a wide range of water quality issues.

Water

Status and understanding of groundwater quality in the Mojave Basin Domestic-Supply Aquifer study unit, 2018—California GAMA Priority Basin Project

Groundwater quality in the western part of the Mojave Desert in San Bernardino County, California, was investigated in 2018 as part of the California State Water Resources Control Board Groundwater Ambient Monitoring and Assessment Program Priority Basin Project. The Mojave Basin Domestic-Supply Aquifer study unit (MOBS) region was divided into two study areas—floodplain and regional—to assess differences between the two major aquifers used for drinking water supply in the area. This assessment characterized the quality of ambient groundwater and not the quality of treated drinking water. The study included three components: (1) a status assessment, which characterized the quality of groundwater resources used for domestic drinking-water supply in the floodplain and regional study areas; (2) a brief understanding assessment, which evaluated factors that could potentially affect the quality of groundwater used by domestic wells in the region; and (3) a comparative assessment between the groundwater resources used by domestic wells and public-supply wells in the two study areas. The domestic-well assessment was based on data collected by the U.S. Geological Survey from 48 domestic wells in January–May 2018. The public-supply assessment was based on data for samples from 322 public-supply wells in 2008–18, either collected by the U.S. Geological Survey or compiled from the California State Water Resources Control Boards Division of Drinking Water publicly available database. Concentrations of water-quality constituents in ambient groundwater were compared to regulatory and non-regulatory benchmarks typically used by the State of California and Federal agencies as health-based or aesthetic standards for public drinking water. Relative concentrations, defined as the measured concentration divided by the benchmark concentration, were classified as high (greater than 1.0), moderate (greater than 0.5 for inorganic constituents or 0.1 for organic and special-interest constituents, and not high), or low (concentrations lower than moderate). The floodplain and regional study areas were divided into 15 and 35 grid cells, respectively, and grid-based methods were used to compute the areal proportions of the two study areas with high, moderate, or low relative concentrations of individual constituents and classes of constituents. For the domestic-supply assessment, one or more inorganic constituents with health-based benchmarks were detected at high relative concentrations in 58 percent of the regional study area and 13 percent of the floodplain study area. The inorganic constituents with health-based benchmarks detected at high relative concentrations in the regional study area were arsenic, chromium and hexavalent chromium, fluoride, adjusted gross alpha particle activity, uranium, molybdenum, strontium, and nitrate; only arsenic was detected at high relative concentrations in the floodplain study area. One or more inorganic constituents with secondary maximum contaminant level benchmarks were detected at high concentrations in 15 and 6.7 percent of the regional and floodplain study areas, respectively. The constituents detected at high relative concentrations in the regional study area were total dissolved solids, chloride, sulfate, and iron; only total dissolved solids and sulfate were detected at high relative concentrations in the floodplain study area. Organic constituents were not detected at moderate or high relative concentrations in either the regional or floodplain study areas. Volatile organic compounds were detected at low relative concentrations in 21 and 27 percent of the regional and floodplain study areas, respectively, and pesticides were detected at low relative concentrations in 9.1 and 20 percent of the regional and floodplain study areas, respectively. The only individual organic constituent detected in more than 10 percent of either study area was the trihalomethane trichloromethane. Total coliform bacteria were detected in 15 and 27 percent of the grid wells in the regional and floodplain study areas, respectively. The greater prevalence of high relative concentrations of many inorganic constituents in the regional study area compared to the floodplain area likely indicates the greater diversity of geologic material at depth in aquifer material and generally finer-grained alluvium compared to the floodplain study area combined with generally older groundwater that has had more contact time with aquifer materials. In general, trace element concentrations (1) increased with increasing groundwater age, (2) increased with distance from recharge sources in the mountains, and (3) increased with closer proximity to some types of geological units. In general, groundwater from domestic wells in the floodplain study area is young, with most samples containing a component of modern groundwater based on tritium and unadjusted carbon-14 activities, whereas groundwater from domestic wells in the regional study area generally is old, with most samples having unadjusted carbon-14 ages of 5,000–40,000 years. Public-supply wells in MOBS generally were deeper than domestic wells and presumably are in contact with older, more weathered alluvium that may have more mobile trace elements, such as arsenic or uranium. However, only 26 percent of the public-supply regional study area had high relative concentrations of inorganic constituents, compared to 58 percent for the domestic regional study area. The percentages of the public-supply and domestic floodplain study areas with high relative concentrations of inorganic constituents were 11 and 13 percent, respectively. The ages of groundwater used by public-supply and domestic wells in each study area were similar, which was not expected given the greater depth of the public-supply wells. Three potential factors may contribute to these results: (1) greater spatial footprint of domestic well network, which may result in domestic wells pumping groundwater from fractured bedrock or mineralized areas not used by public-supply wells; (2) greater pumping rates in public-supply wells, resulting in more water being withdrawn from coarse-grained, heterogeneous alluvium than finer-grained layers, which may have higher concentrations of (or more mobile) inorganic constituents; and (3) a greater degree of well management with public-supply wells, which may include pausing use of or decommissioning wells if treating or blending water is not feasible to lower constituent concentrations.

California

Wetter winters, drier summers: Quantifying the change in hydrological response around the Puget Sound area using the wflow_sbm hydrological model and CMIP6 projections

Climate change is expected to impact hydrological regimes worldwide, including the Pacific Northwest of the United States. This study investigates how climate change will affect river discharge in the Puget Sound region of the State of Washington, with a focus on King and Pierce Counties. We simulated river discharge under historical and future conditions using the physically based, spatially distributed wflow_sbm hydrological model, which was calibrated and validated against U.S. Geological Survey discharge records. Future forcing was based on an ensemble of six high-resolution CMIP6 climate models, which were bias corrected using empirical quantile mapping. The results indicate a decrease in summer discharges (5–10%) and an increase in winter discharges (5–10%) across the study region. The high discharges (90th percentile) are projected to increase in winter, and the low discharges are projected to decrease in summer, due to shifts in precipitation regimes, snowpack hydrology, and evapotranspiration. However, variability between individual CMIP6 models often exceeds the magnitude of ensemble mean changes, underscoring substantial uncertainty in climate projections and the importance of including multiple climate models in climate change analysis. Furthermore, model consensus increased with elevation, which could be the result of the higher elevation areas being driven by less diverse hydrological processes. These findings highlight potential challenges for regional water management, ecosystem health, and flood risk mitigation in the Puget Sound region under future climate conditions.

EarthArXiv

Escherichia coli monitoring and assessment in 2022 and 2023 after beach restoration at Lake St. Clair Metropark Beach, Macomb County, Michigan

Lake St. Clair Metropark Beach in Michigan has a history of closures because of elevated Escherichia coli ( E. coli ) concentrations in its recreational waters. To reduce closures, restoration projects were implemented in 2021 to deter waterfowl from congregating on the beach. In this study, the U.S. Geological Survey, in cooperation with the Michigan Department of the Environment, Great Lakes, and Energy and in collaboration with Huron-Clinton Metroparks and the Macomb County Health Department, monitored E. coli from 2022–23 in surface water, shallow groundwater, and sediment at Lake St. Clair Metropark Beach. Results were compared to data from a prerestoration (2018–19) study. A significant decrease in daily geometric mean E. coli concentrations in surface water was observed postrestoration, but the number of high concentration events increased. This resulted in more frequent beach closures postrestoration. Surface-sediment E. coli concentrations significantly decreased after restoration, and waterfowl populations generally decreased from 2021 to 2023, suggesting that the deterrence measures could be influencing E. coli concentrations in surface sediments and surface water. Groundwater E. coli concentrations were orders of magnitude higher than those in surface water and revealed no change correlated with restoration. Seepage measurements indicated that groundwater occasionally discharges into surface water, potentially providing a transport mechanism for E. coli to reach the lake. Continued monitoring and consideration of environmental factors could help to better understand the beach system.

Michigan

Mapping potential sensitivity to hydrogeomorphic change in the UMRS riverscape

In 2020 the U.S. Geological Survey (USGS), as part of the Upper Mississippi River Restoration (UMRR) Program, began a new project to characterize potential hydrogeomorphic change associated with hydrogeomorphic units (HGUs) and their catenae (units linked by their association with sediment sources and flow origins). The goal of the project was to develop a geographic information system (GIS) database of HGUs for the Upper Mississippi River System (UMRS) available to both scientists and river managers working on UMRR studies and HREP planning and design studies. The characterization was based on a hydrogeomorphic change hierarchical classification developed previously for the UMRS. The products were generated with automated techniques in a GIS using systemic datasets. Landforms were mapped from the 2015 UMRS topobathymetric dataset with geomorphon (shape-based) tools tailored for the large riverscape, valley bottom environments in the UMRS. A clustering analysis was applied to the resulting landforms to identify HGUs associated with zones of perennial low flows, bankfull flows, and overbank floodplains. Catenae were assembled based on the proximity of the units to the main channel, tributary mouths, and side channels from previously published aquatic areas (USACE, 2018) coupled with least-cost flowpath linkages between potential sediment origins and planform change units developed by Rogala, Fitzpatrick, and Henderson (2020). These GIS-based analyses were successful at identifying a range of HGUs using an automated technique with available data across the entire riverscape, with emphasis on those that have the potential for hydrogeomorphic change. Most of the resulting features are depositional, as expected in a large river system. However, this is the first attempt of linking tributary inputs, side channel erosion and levee breaches with their depositional counterparts. The approach was successfully piloted in Pools 8 and 10 in the Upper Impounded Reach and Pool 14 in the Lower Impounded Reach, with next steps for application in reaches of the unimpounded section and Illinois River. This report emphasizes results from Pool 10, which was the focus of most of our attention during the pilot phase.

Illinois, Indiana, Iowa, Minnesota, Missouri, Sout

Core microbiomes as a potential fingerprinting method of Western USA dust sources

Introduction: Changing frequency and intensity of dust emissions impacts ecosystems and human health. Dust carries microbes, nutrients, heavy metals, and other materials that may change environmental biogeochemistry at deposition sites. Identifying dust sources provides key information on where and when mitigation strategies should be employed. However, commonly used geochemical or isotopic tracers are often not capable of distinguishing between geographic regions. Methods: We explored whether soil bacterial communities may provide distinct fingerprints of dust sources in the western United States. We identified bacterial core communities of dust from ten locations monitored by the National Wind Erosion Research Network (NWERN) with varied land use (cropland, rangeland, and playa), and compared communities to location, soil, and regional characteristics. Samples were collected monthly from Modified Wilson and Cooke (MWAC) samplers, composited by season (spring, summer, and fall), and analyzed using 16S rRNA sequencing. Results: We found distinct bacterial core communities that reflected dust source characteristics. In order of importance, precipitation levels ( p = 0.0001), location ( p = 0.0001), soil texture ( p = 0.0001), seasonality ( p = 0.0001), and elevation (p = 0.0002) were correlated with bacterial community composition. Discussion: Distinct bacterial core communities were associated with site characteristics such as biocrusts, playas, and military base proximity. Our results suggest that the use of core microbiomes may offer a fingerprinting method to identify dust source regions.

Colorado, Nevada, New Mexico, North Dakota, Oklaho

On connecting hydro-social parameters to vegetation greenness differences in an evolving groundwater-dependent ecosystem

Understanding groundwater-dependent ecosystems (i.e., areas with a relatively shallow water table that plays a major role in supporting vegetation health) is key to sustaining water resources in the western United States. Groundwater-dependent ecosystems (GDEs) in Colorado have non-pristine temporal and spatial patterns, compared to agro-ecosystems, which make it difficult to quantify how these ecosystems are impacted by changes in water availability. The goal of this study is to examine how key hydrosocial parameters perturb GDE water use in time and in space. The temporal approach tests for the additive impacts of precipitation, surface water discharge, surface water mass balance as a surrogate for surface–groundwater exchange, and groundwater depth on the monthly Landsat normalized difference vegetation index (NDVI). The spatial approach tests for the additive impacts of river confluences, canal augmentation, development, perennial tributary confluences, and farmland modification on temporally integrated NDVI. Model results show a temporal trend (monthly, 1984–2019) is identifiable along segments of the Arkansas River at resolutions finer than 10 km. The temporal impacts of river discharge correlate with riparian water use sooner in time compared to precipitation, but this result is spatially variable and dependent on the covariates tested. Spatially, areal segments of the Arkansas River that have confluences with perennial streams have increased cumulative vegetation density. Quantifying temporal and spatial dependencies between the sources and effects of GDEs could aid in preventing the loss of a vulnerable ecosystem to increased water demand, changing climate, and evolving irrigation methodologies.

Colorado

Bathymetric contour maps, surface area and capacity tables, and bathymetric change maps for selected water-supply lakes in Missouri, 2022–23

Bathymetric data were collected at 13 water-supply lakes around the periphery of Missouri by the U.S. Geological Survey in cooperation with the Missouri Department of Natural Resources and various local agencies, as part of a multiyear effort to establish or update the surface area and capacity tables for the surveyed lakes. Surveys were carried out during the months of April and May in 2022 and 2023. All but two of the lakes had been surveyed previously by the U.S. Geological Survey, and the recent surveys were compared to the earlier surveys to document the changes in the bathymetric surface and capacity of the lake. Bathymetric data were collected using a high-resolution multibeam mapping system mounted on a boat. Supplemental depth data at three of the lakes were collected in shallow areas with an acoustic Doppler current profiler on a remote-controlled boat. Data points from the various sources were exported at a gridded data resolution appropriate to each lake, either 0.82 foot, 1.64 feet, or 3.28 feet. Data outside the multibeam survey extent and greater than the surveyed water-surface elevation were obtained from data collected using aerial light detection and ranging (lidar) point cloud data. A linear enforcement technique was used to add points to the dataset in areas of sparse data (the upper ends of coves where the water was shallow or aquatic vegetation precluded data acquisition) based on surrounding multibeam and upland data values. The various point datasets were used to produce a three-dimensional triangulated irregular network surface of the lake-bottom elevations for each lake. A surface area and capacity table was produced from the three-dimensional surface for each lake showing surface area and capacity at specified lake water-surface elevations. Various quality-assurance tests were conducted to ensure quality data were collected with the multibeam, including beam angle checks and patch tests. Additional quality-assurance tests were conducted on the gridded bathymetric data from the survey, the bathymetric surface created from the gridded data, and the contours created from the bathymetric survey.

Missouri

Prioritizing US Geological Survey science on salinization and salinity in candidate and selected priority river basins

The US Geological Survey (USGS) is selecting and prioritizing basins, known as Integrated Water Science basins, for monitoring and intensive study. Previous efforts to aid in this selection process include a scientifically defensible and quantitative assessment of basins facing human-caused water resource challenges (Van Metre et al. in Environmental Monitoring and Assessment , 192(7), 458 2020). In the present work, we explore this ranking process based on water quality considerations, specifically salinity and salinization. We selected top candidate basins to study salinity and salinization issues in 18 hydrologic regions that include 163 candidate basins. Our prioritization is based on quantitative assessment of sources of salinity, drivers of change, and receptors that must respond to those sources and drivers. Source terms represented in the prioritization include geology, depth to brackish groundwater, stream conductivity, chloride in precipitation, urban and agricultural land use, application of road salt as a deicer, and irrigation. Drivers represented in prioritization include changes in chemical weathering as a result of changes in rainwater chemistry. Receptors include measures of water stress, measurements of stream ecological health, and socioeconomic factors. In addition, we present research activities for the USGS on salinity and salinization that can be pursued in these basins including assessment of sources, pathways, and loadings; predicting and understanding changes in sources, peaks, and trends; understanding the components of salinity and mobilization of contaminants; understanding the relationship between salinization and changing ecosystems; and developing knowledge on the causes and distribution of groundwater salinity, brackish water resources, and challenges related to desalination.

Enviornmental Monitoring and Assessment

Extremophile hotspots linked to containerized industrial waste dumping in a deep-sea basin

Decaying barrels on the seafloor linked to DDT contamination have raised concerns about the public health implications of decades old industrial waste dumped off the coast of Los Angeles. To explore their contents, we collected sediment cores perpendicular to five deep-sea barrels. The concentration of DDT and its breakdown products were highly elevated relative to control sites yet did not vary with distance from the barrels, suggesting that they were not associated with the contamination. Sediment cores collected through white halos surrounding three barrels were enriched in calcite and had elevated pH. The associated microbial communities were low diversity and dominated by alkalophilic bacteria with metagenome-assembled genomes adapted to high pH. A solid concretion sampled between a white halo and barrel was composed of brucite, a magnesium hydroxide mineral that forms at high pH. Based on these findings, we postulate that leakage of containerized alkaline waste triggered the formation of mineral concretions that are slowly dissolving and raising the pH of the surrounding sediment pore water. This selects for taxa adapted to extreme alkalinity and drives the precipitation of “anthropogenic” carbonates forming white halos, which serve as a visual identifier of barrels that contained alkaline waste. Remarkably, containerized alkaline waste discarded >50 years ago represents a persistent pollutant creating localized mineral formations and microbial communities that resemble those observed at some hydrothermal systems. These formations were observed at one-third of the visually identified barrels in the San Pedro Basin and have unforeseen, long-term consequences for benthic communities in the region.

California

Status and understanding of groundwater quality in the San Joaquin Valley Kern County subbasin domestic-supply aquifer study unit, 2022—California GAMA Priority Basin Project

The quality of water accessed by domestic wells (here referred to as domestic groundwater resources) in the San Joaquin Valley Kern County subbasin (basin number 5-022.14) was assessed as part of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project (GAMA-PBP), in cooperation with the California State Water Resources Control Board. Kern County is at the southern end of the San Joaquin Valley in California, and about 30,000 residents are estimated to use privately owned domestic wells for drinking water. Domestic wells typically draw from shallower parts of the aquifer system than public-supply wells and can be more vulnerable to effects from surface activities. Kern County is host to a highly productive agricultural industry, with Bakersfield as the main urban center. The Kern River runs through Bakersfield from the southern Sierra Nevada and intersects the Kern Water Bank, one of the largest groundwater banking operations in California, at the Kern River Intertie. The section of the Kern River running through the Kern Water Bank is dry most years. Kern County also encompasses some of the most productive oil and gas basins in California, with extensive underground and surface disposal of oil-field wastewater. This study was based on data collected from 33 sites sampled by the U.S. Geological Survey for the GAMA-PBP in 2022. To provide context for the water quality assessment, measured concentrations were compared to regulatory and non-regulatory health-based and aesthetic benchmarks. A grid-based method was used to estimate the proportions of the groundwater resources used for domestic-supply wells that have water-quality constituents below (low relative concentration), approaching (moderate relative concentration), or above (high relative concentration) benchmark concentrations. At least one measured constituent with a regulatory benchmark was categorized as having a high relative concentration in 72 percent of the aquifer area used for domestic groundwater resources. Inorganic constituents were detected at high concentrations in 45 percent of the domestic groundwater resources, and the constituents detected above regulatory benchmarks were arsenic, nitrate, and uranium. At least one organic constituent was detected at high concentrations in 41 percent of the domestic groundwater resources, and the constituents exceeding regulatory benchmarks were the fumigants 1,2,3-trichloropropane (1,2,3-TCP), 1,2-dibromo-3-chloropropane (dibromochloropropane [DBCP]), 1,2-dibromoethane (EDB), and the per-and polyfluoroalkyl substance (PFAS) perfluorooctanesulfonate. The disinfection by-product chloroform, the fumigant 1,2-dichloropropane, the herbicides atrazine and hexazinone, and the herbicide degradates 2-chloro-6-ethylamino-4-amino-s-triazine, 2-chloro-4,6-diamino-s-triazine, 4-hydroxychlorothalonil, and metolachlor sulfonic acid were detected in more than 10 percent of domestic groundwater resources, but concentrations did not exceed regulatory benchmarks. Land use, groundwater age (fraction of modern water and mean age), and geochemical environment (oxic or anoxic conditions, pH, alkalinity) were associated with the distribution of high relative concentrations of inorganic and organic constituents. Young, oxygenated water is recharged along the Kern River and adjacent recharge ponds, or as irrigation water in the agricultural areas. High concentrations of nitrate and volatile organic compounds occurred in the oxic water in urban and agricultural areas. The fumigants 1,2,3-TCP, DBCP, and EDB were reported throughout the agricultural areas, whereas chloroform, tetrachloroethene, and PFAS were associated with urban land use. High uranium concentrations were associated with young, modern groundwater in agricultural areas with low pH and high bicarbonate. Total dissolved solids increased with distance from the Kern River, as the contributions of fresh, oxic water decreased. High concentrations of arsenic were present in older anoxic or alkaline groundwater away from areas of recharge. Overall, groundwater age, redox conditions, and the source of recharge as a result of different land uses contribute to large aquifer-scale portions of domestic groundwater resources that exceed health-based benchmarks for nitrate, uranium, and fumigant concentrations.

California

Groundwater structures fish growth and production across a riverscape

Landscapes are composed of habitat patches and conditions that vary across space and time. While habitat variability and complexity can support important ecological processes and ecosystem services, the dynamic nature of habitats can also constrain organismal growth and production as optimal conditions are fleeting. In riverine ecosystems, groundwater discharge to streams stabilises water temperature and flow regimes, thus mediating how habitat complexity is expressed. Yet, how stable habitats structure growth and production within the broader landscape matrix is not well understood. In this study, we explored the effects of groundwater on spatiotemporal variation in growth and production for juvenile Yellowstone cutthroat trout ( Oncorhynchus virginalis bouvieri ) across the upper Snake River catchment, Wyoming, USA. We combined machine learning techniques and remotely sensed landscape data to estimate groundwater availability across the river network, which we linked to stream temperature regimes and conspecific density. We then used Bayesian hierarchical models to quantify the effects of temperature, density and groundwater on spatiotemporal variation in fish growth and production in 52 focal reaches. Finally, we predicted body size trajectories and trends in total production continuously over both space and time to understand the effect of groundwater at the riverscape scale. Groundwater discharged to streams where topography changes abruptly in valley-bottom areas underlain by coarse glacial deposits. Groundwater stabilised temperature regimes and was associated with high trout densities. Temperature and density, in turn, interacted to influence growth rates: growth increased strongly with temperature, but this effect was reduced when density was high. Accordingly, variation in groundwater availability among stream reaches diversified growth and production regimes. In reaches with low groundwater availability, growth and production declined over time from summer maxima. In contrast, in reaches with high groundwater availability, temporal trends in growth and production were hump-shaped—peaking in autumn—and mean production was greater. At the riverscape scale, temporal asynchrony in growth rates generated convergent spatial variation in growth capacity, but—when combined with density—led to the formation of distinct hotspots of production. Our results demonstrate how groundwater, an important driver of aquatic ecosystem heterogeneity, structures trout growth and production across space and time. Importantly, rare, but stable habitats may disproportionately affect ecological processes and serve as key sources of population diversity at larger spatial scales.

Wyoming