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USGS2026

Petrography and mineralogy of selected pre-Middle Jurassic basement rocks beneath the Atlantic and Gulf Coastal Plains in Florida

Florida is covered by flat-lying sedimentary strata of the Atlantic and Gulf Coastal Plains. These strata have accumulated since Middle Jurassic time. The pre-Middle Jurassic, or basement, rocks that underlie the Coastal Plain in Florida are known only from drill cores and cuttings recovered from a relatively small number of boreholes. This data report presents petrographic observations and the results of X-ray diffraction analyses of basement rocks from 18 boreholes across Florida in support of the identification, discrimination, and correlation of units for a subcrop geologic map of pre-Middle Jurassic rocks composing Florida’s sub-Coastal Plain geology.

Florida↗

USGS2025

Examining the role of elevated and sustained strain in dynamically triggering earthquakes on the Anza section of the San Jacinto fault

Microearthquakes can be dynamically triggered in southern California by remote earthquakes. However, directly connecting dynamic triggering mechanisms with observational data remains challenging. One proposed failure mechanism suggests that both the amplitude and duration of cyclic fatigue caused by the passing seismic wave contribute to triggering occurrence. Here, we measure dynamic strains recorded by borehole strainmeters in the Anza section of the San Jacinto fault zone from 710 earthquakes that occurred over 300 km away between 2008 and 2017 to systematically investigate the role of elevated and sustained strain in controlling dynamic triggering. We design a suite of tests to evaluate whether specific amplitude thresholds and durations of strain can predict dynamic triggering cases. We further test whether the peak dynamic strain (PDS) can predict triggering occurrence in combination with the strain amplitude and duration. Based on these tests, there is no strain amplitude–duration threshold that can distinguish triggering occurrence in Anza. Dynamic triggering is more likely to occur if a remote earthquake causes a PDS above 100 nanostrain, though many cases were triggered at smaller PDSs. The lack of clear correlation between triggering and characteristics of the dynamic strain field suggests that the tested features of the incoming waves do not determine triggering occurrence and local fault conditions and slip processes are more important in controlling dynamic triggering in Anza.

California↗

USGS2024

Estimating domestic self-supplied water use in Rhode Island, 2014–21

Water withdrawal from private groundwater wells is often unaccounted for in water planning studies, and water from private wells can be a source of exposure to environmental contaminants. The sizes of populations that depend on private wells for domestic water use and the amounts of water that are withdrawn from these wells are generally poorly represented in data collection efforts because of the challenges of locating, metering, or gathering withdrawal information from individual property owners. To address this problem, the U.S. Geological Survey, in cooperation with the Rhode Island Water Resources Board, estimated the volume of water withdrawn from domestic self-supply wells and the populations who use them for the State of Rhode Island at a 30-meter pixel spatial resolution and one-month temporal resolution between July 2014 and June 2021. The number of people reliant on domestic self-supply wells has increased in Rhode Island over the study period; however, the statewide estimate of total water withdrawal has not statistically increased. Withdrawals from private wells are largest in the inland areas of the western part of the State, and the towns of Scituate and Charlestown have the highest estimated withdrawals. Statewide monthly withdrawals ranged from 3.987 million gallons per day in March 2018 to 7.767 million gallons per day in September 2016. The median per capita domestic water use rate was 46.0 gallons per capita per day.

Rhode Island↗

USGS2026

Investigation of drivers and sources of potential harmful algal blooms in Lake Anna, Virginia, 2023-24

Algal blooms in freshwater reservoirs are an increasing concern because of the risk to aquatic ecosystem health, recreational use, and water quality. Among the taxa that comprise an algal bloom, cyanobacteria are of particular concern due to the potential to produce toxic compounds which can cause acute and chronic illness in humans if ingested through contaminated water or shellfish. When toxins are above a toxin-specific threshold in the water column, the Commonwealth of Virginia categorizes the bloom as a harmful algal bloom (HAB), distinguishing it from an algal bloom without toxins present. Toxins are of particular concern in bodies of water which serve as major recreational areas, such as Lake Anna in central Virginia. Lake Anna is a 27 km-long and 47 km2 reservoir in central Virginia. Since the Commonwealth of Virginia revised the HAB monitoring framework in 2018, algal bloom advisories for potentially toxigenic blooms have been issued in the western, riverine zone of the reservoir. There were detections of microcystin and anatoxin production but no detections of cylindrospermopsin and saxitoxin production in Lake Anna; however, toxin concentrations were low, at values less than 0.65 µg/L. In 2023, the U.S. Geological Survey, in cooperation with Virginia Department of Environmental Quality, initiated a 19-month intensive and extensive study of western Lake Anna and its tributaries (North Anna River and Pamunkey Creek) to (1) characterize the algal community, biomass, and toxin production; (2) identify potential drivers leading to algal bloom initiation, persistence, and decline; and (3) assess the primary sources of the drivers contributing to algal blooms. Continuous and discrete monitoring of water quality within the lake, watershed inputs, meteorological conditions, and algal communities were monitored. Multiple modeling scenarios identified that the formation and persistence of algal blooms in Lake Anna are driven by interactions among chemical, macro- and micronutrient, and physical factors. Key drivers include total nitrogen, total phosphorus, water temperature, suspended sediment concentration, wind speed, copper, iron, molybdenum, nickel, sodium, and alkalinity. During this study, winter stormflow events delivered the highest loading of macro- and micronutrients from the tributaries to the lake. The lake is a sink for these nutrients in the water column or in the lake-bed sediments. During high-occupancy and recreation periods on the lake in the summer months, boating activity can promote internal loading by the resuspension of the lake-bed sediments, thereby increasing the nutrient availability for algal uptake. Thermal stratification and hypoxic conditions were observed, which can contribute to the passive release of nutrients into the water column, further facilitating algal bloom proliferation. These processes may create a positive feedback loop that supports the formation, persistence, and annual recurrence of algal blooms in the western region of Lake Anna. Continued water-quality monitoring of early warning indicators may improve the detection and forecasting of algal growth in the lake and help managers proactively manage water quality and algal growth.

EarthArXiv↗

USGS1997

Chemical evolution and estimated flow velocity of water in the Trinity Aquifer, south-central Texas

Three permeable zones with varying lithology and water chemistry compose the Trinity aquifer, a principal source of water in the 5,500- square-mile study area in south-central Texas. The upper permeable zone locally yields small quantities of water to wells and was not included in this study. The middle permeable zone primarily is composed of limestone with minor amounts of dolostone. Terrigenous sand and marine limestone, with minor amounts of dolostone, are the principal lithologic units in the lower permeable zone. Dissolved solids concentrations range from 329 to 1,820 milligrams per liter in water samples from the middle permeable zone and from 518 to 3,030 milligrams per liter in water samples from the lower permeable zone. Principal hydrochemical facies in the middle permeable zone are calcium magnesium bicarbonate and calcium magnesium sulfate. Hydrochemical facies in ground-water samples from the lower permeable zone vary. Tritium concentrations as large as 5.3 tritium units in the southeastern part of the study area are indicative of relatively recent recharge. Results of a geochemical mass balance simulation along a flowpath in the middle permeable zone indicate a mass transfer of 4.25 millimoles per liter of dolomite dissolved, 5.74 millimoles per liter of gypsum dissolved, 0.46 millimole per liter of sodium chloride dissolved, 8.07 millimoles per liter of calcite precipitated, and 0.67 millimole per liter of calcium-for-sodium cation exchange between solid and aqueous phases. These results support dedolomitization as a principal chemical process in the middle permeable zone of the Trinity aquifer. Results of a simulation along a flowpath in the lower permeable zone indicate a mass transfer of 0.41 millimole per liter of dolomite dissolved, 0.001 millimole per liter of gypsum dissolved, 9.58 millimoles per liter of sodium chloride dissolved, 1.09 millimoles per liter of calcite precipitated, and 1.11 millimoles per liter of sodium-forcalcium cation exchange between solid and aqueous phases. Lower permeable zone processes indicate sodium chloride dissolution, dedolomitization, and cation exchange. Ground-water-flow velocities determined from adjusted carbon-14 ages, calculated using NETPATH, for selected flowpaths in the middle and lower permeable zones were about 1.7 feet per year and less than about 4.4 feet per year, respectively.

Texas↗

USGS2026

Decoding the oxidative digestion mechanism for polystyrene nanoplastic detection in the Great Lakes using a customizable Raman spectral processing algorithm

Despite the concerns surging around nanoplastics (NPs) regarding their prevalence and bioavailability in freshwater systems, robust detection of NPs in complex environmental matrices is hindered by the lack of standardized sample pretreatment and a mechanistic understanding of oxidative digestion. Here, we systematically investigate the interaction between hydrogen peroxide (H 2 O 2 ) and polystyrene (PS) NPs during digestion in deionized (DI) water and four environmental matrices from in and around the Great Lakes Basin. To facilitate high-throughput analysis, we develop Pre_peak, a customizable Raman spectral processing algorithm that achieves >99% accuracy for both NP identification and interference rejection, allowing reliable NP quantification via pixel counting and systematic decoding of the oxidative digestion mechanisms. In DI water, varying H 2 O 2 doses from 0 to 30% has negligible effects on the recovery and Raman signal intensity of PS NPs over 24 hours of digestion. However, morphological changes and aggregation of PS NPs are observed when the H 2 O 2 dose exceeds 20%. Prolonged digestion further leads to progressive NP loss. In natural waters, the optimal dosage and digestion duration depend on matrix characteristics, including dissolved organic matter (DOM) and ion composition. This study provides mechanistic insights into NP–oxidant interactions and underscores the need for matrix-tailored digestion protocols to advance standardized NP detection in freshwater environments.

Great Lakes↗

USGS1976

Detailed investigation of a coastal plain-Piedmont fault contact in northeastern Virginia

A trench across the Dumfries fault of the Stafford fault zone near Stafford, Virginia (see Mixon and Newell, 1976) exposed a high-angle reverse fault juxtaposing Paleozoic Quantico Slate and Cretaceous Potomac Group rocks. A system of subsidiary reverse faults and small scale normal faults disrupt the Coastal Plain strata adjacent to the main fault. Cross-cutting relations and stratigraphic details indicate that the subsidiary faults in the Cretaceous rocks document a history of episodic deformation, in part active during accumulation of the Coastal Plain strata. Slickensides and stereo net analysis of theorientation of subsidiary reverse faults, normal faults, and bedding indicate that, through time, faulting consistently included right lateral separation.

Virginia↗

USGS2024

Groundwater quality and groundwater levels in Dougherty County, Georgia, April 2020 through January 2023

The Upper Floridan aquifer is the uppermost reliable groundwater source in southwest Georgia. The aquifer lies on top of the Claiborne, Clayton, and Cretaceous aquifers, all of which exhibited water-level declines in the 1960s and 1970s. The U.S. Geological Survey has been working cooperatively with Albany Utilities to monitor groundwater quality and availability in these aquifers since 1977. Flow direction in the Upper Floridan aquifer is to the south and toward the Flint River. During the past 3 years, water levels varied above and below period-of-record median values. Water levels in the Upper Floridan aquifer were primarily above or at median levels during 2020 and 2021 and at or below median levels during 2022. Water levels in the Claiborne aquifer were above median levels, whereas water levels in the Clayton aquifer were at or below median levels, and in the Cretaceous aquifer system were close to median levels. During January 2021, eight wells were sampled for major ions, including nitrate plus nitrite as nitrogen (N). Nitrate plus nitrite as N concentrations ranged from 2.3 to 10.5 milligrams per liter (mg/L). During December 2021, seven wells were sampled for major ions, including nitrate plus nitrite as N. Nitrate plus nitrite as N concentrations ranged from 3.9 to 9.9 mg/L. During November 2022, eight wells were sampled for major ions, including nitrate plus nitrite as N. Nitrate plus nitrite as N concentrations ranged from 3.9 to 10.0 mg/L. Two wells were also sampled for per- and polyfluoroalkyl substances during November 2022.

Georgia↗

USGS2024

Analyzing spatial distributions and alignments of pitted cone features in Utopia Planitia on Mars

Martian geomorphology and surface features provide links to understanding past geologic processes such as fluid movement, local and regional tectonics, and feature formation mechanisms. Pitted cones are common features in the northern plains basins of Mars. They have been proposed to have formed from upwelling volatile-rich fluids, such as magma or water-sediment slurries. In this study, we map the spatial distributions of pitted cone features across the Utopia Planitia (UP) basin. Using the Average Nearest Neighbor technique, we find that pitted cone features appear to be clustered across the basin, occurring in a narrow band around the circumferential rim of UP. Additionally, we find that pitted cone features also appear to be aligned in chains that are sub-parallel with the basin margin. Parallel bands of cones generally follow elevation contours of the UP basin, which suggests elevation or a correlated factor plays a major role in pitted cone and cone chain formation. We propose that pitted cones and cone chains may be related to vertical fractures formed around the UP basin rim from subsidence of infilling basin material.

Icarus↗

USGS2025

Insights into widespread landsliding in southern Appalachia from Hurricane Helene

Between 23 and 27 September 2024, antecedent rain followed by Hurricane Helene produced one of the most damaging weather events in southern Appalachia history. The back-to-back storm events resulted in a maximum cumulative rainfall of 848 mm and hurricane-force wind gusts over 170 km/h in western North Carolina, eastern Tennessee, and southwestern Virginia. The resulting regional flooding, landslides, and tree blowdown caused over 100 fatalities, damaged or destroyed critical infrastructure and thousands of structures, and severed connectivity across the region. Over the next several weeks, a multi-agency landslide response produced a rapid hazard assessment and mapped 2217 landslides, 55% of which damaged infrastructure or property. Orographic uplift enhanced rainfall, resulting in concentrated landsliding along the ~250 km swath of the Blue Ridge escarpment in western North Carolina. Landslides initiated predominantly on windward-facing (southeast-facing) slopes, and localized clustering of initiation points indicated a strong influence of hillslope-scale meteorological and geomorphic factors. Many shallow landslides mobilized into larger, highly mobile, and damaging debris flows that graded into floods. Here, we put our preliminary observations in the context of historical storm-driven landslide events and open new avenues for investigating the nature and extent of landslides and their effects in southern Appalachia and similar environments.

Georgia, North Carolina, South Carolina, Tennessee↗

USGS2025

Hydrologic response of groundwater and streamflow to natural and anthropogenic drivers of change in headwaters of the upper Colorado River basin during recent wet (1982–1999) and drought (2000–2022) conditions

Study region: Headwaters of the upper Colorado River basin (UCOL), USA Study focus: Surface-water and groundwater numerical models incorporating water-use information were used to investigate changes in climate, water use, and simulated hydrologic responses of snow processes, evapotranspiration, groundwater, and streamflow during recent wet (1982–1999) and drought (2000–2022) periods in the headwater subregions of the upper Colorado River basin. New hydrologic insights for the region: Decreases in average streamflow between wet and drought periods ranged from 20 % in the Colorado River headwaters subregion to 23 % in the Gunnison River headwaters subregion. Like streamflow, average surface runoff was statistically less during the drought than the wet period, with decreases from 24–31 % in the headwaters. On a volume basis, runoff decreases were greater than streamflow decreases in both the Colorado River and Gunnison River headwaters. Although the amount of water-year groundwater discharge to streams remained nearly the same between the wet and drought periods, groundwater as a percentage of streamflow increased between the wet and drought periods, highlighting the importance of groundwater in sustaining streamflow during drought conditions. Multiple linear regression analyses revealed that snowmelt-only models were better than the best precipitation and temperature models at explaining streamflow variability from all headwater subregions for both the wet and drought periods.

Arizona, Colorado, New Mexico, Utah, Wyoming↗

USGS2026

Postglacial ecosystem development of a hydrothermal landscape in Yellowstone National Park

The Yellowstone geo-ecosystem has been the subject of much research, but the ecological history of the Yellowstone Plateau volcanic field and its iconic geyser basins is less known. In this investigation, paleoenvironmental analyses of sediment cores from lakes in Lower Geyser Basin were compared with regional records and paleoclimate model simulations to reconstruct the vegetation, wildfire, limnology, hydrothermal dynamics, and climate drivers since deglaciation, 15,000 to 14,000 years ago. Pollen data from Lower Geyser Basin lakes reveal the strong influence of infertile rhyolitic soils on vegetation history: an initial late-glacial steppe was replaced by lodgepole pine forest from 12.8 to 11.0 ka, with little change in forest composition or cover thereafter despite changing climate. This stability contrasts with the more dynamic vegetation response on nonrhyolite substrates in the Yellowstone region where nutrient and moisture availability is greater. Highest wildfire activity and low lake nutrient levels in Lower Geyser Basin occurred from 12 to 4 ka, when summers were substantially warmer and drier and fire-inducing vapor pressure deficits were 29 to 56% higher. The hydrothermal history, inferred from sedimentary arsenic and cesium abundances, was spatially and temporally variable but lake-forming hydrothermal events align with periods of abundant moisture. Thus, long-term changes in wildfire, limnology, and, to some extent, hydrothermal activity were governed by insolation-driven climate variations, whereas the vegetation response was muted and constrained by geologic processes. These findings suggest that warmer, drier conditions in the future could result in less hydrothermal activity yet little change in forest cover across the Yellowstone Plateau volcanic field despite more wildfires.

Idaho, Montana, Wyoming↗

USGS1976

A comparison of electronic particle counting and pipette techniques in routine mud analysis

Electronic particle counting and pipette size-analysis techniques are compared for their relative effectiveness in large-scale routine mud analysis. Optimum laboratory procedures for conducting electronic analyses with a Model TA Coulter Counter are presented. Comparative electronic and pipette analyses conducted on the same samples resulted in equivalent precision for both techniques. Results of electronic analyses consistently showed size distributions significantly coarser than those obtained by pipette analyses. The laboratory efficiency of the relatively rapid electronic technique is far superior to that of the pipette technique, although more extensive precautionary measures are required to maintain a high level of analytical accuracy and precision. The quality of electronic analyses largely depends upon the effectiveness of standardized operational procedures established within the laboratory.

Open-File Report↗

USGS2026

Simulation of the impacts of spring diversions on streamflow in the Strawberry Creek watershed, San Bernardino County, California, using an integrated hydrological model

The Strawberry Creek watershed, in the San Bernardino Mountains of southern California, features a group of natural springs known as Arrowhead Springs that have been augmented with diversions in the form of sub-horizontal borings and tunnels. Understanding the effects of these structures on streamflow through groundwater capture is crucial for managing surface-water resources in this watershed. In this study, we constructed the Strawberry Creek integrated hydrological model to increase this understanding. The Strawberry Creek integrated hydrological model is an integrated surface runoff and groundwater model, GSFLOW to simulate surface runoff and infiltration and groundwater flow. The model has 263 rows and 176 columns in each of its three layers. The model area includes the Strawberry Creek and four adjacent watersheds. The precipitation-runoff modeling system was calibrated using two streamflow gaging stations, and the groundwater and surface-water flow model was calibrated to the reported spring diversion discharge and a sparse number of groundwater-level measurements. The Strawberry Creek integrated hydrological model was run with and without diversions active, and simulated streamflow was compared, indicating that in the headwaters of Strawberry Creek, about 35 percent of the diversion flow was captured from base flow.

California↗

USGS2024

Assessment of the interconnection between Tampa Bay and the Floridan aquifer system: Historical groundwater data compilation and analysis, 1976–2022

The U.S. Geological Survey used existing data collected after the last major navigational channel modification in the mid-1980s to investigate groundwater levels and chloride concentrations in wells in the Floridan aquifer system and other aquifers beneath and near Tampa Bay. Tampa Bay is located on the west-central coast of Florida and provides access for commercial shipping. In 2021, the U.S. Army Corps of Engineers began to investigate alternatives to improve the efficiency of the deep-draft navigation channels within Tampa Bay, reduce costs, improve safety, and analyze the implications of modifying navigational channels. The Floridan aquifer system underlies Tampa Bay and is the primary source of public water supply in the region. Modifications to the channels have the potential to expose the Floridan aquifer system to the saltwater in Tampa Bay, with the potential to increase salinity in wells in the region. Other factors affecting the groundwater levels and the location of the freshwater/saltwater interface were also examined, including changes in sea level, groundwater extraction, and variations in climate. Groundwater levels and well-construction reports were used to identify whether different aquifer units are well-connected. Twelve wells had available data before and after the last major channel modifications, which took place in the 1980s, with six datasets of chloride concentration available in areas along the northern and eastern coastline of Tampa Bay, which is nearest to historical dredging activities. Of these six, Kendall’s τ and p -values indicated increasing trends in chloride concentration for three datasets (TR 11-2, TR 10-2, 51), no trend in chloride concentration for two datasets (TR 9-3, 50), and a decreasing trend in chloride concentration for one dataset (TR 9-1). The upward trends in chloride concentration observed for TR 10-2 and 51 are likely the result of changes in local groundwater withdrawals. Well TR 11-2 had a gradual increasing trend in chloride concentration, fresh groundwater throughout the period of record, and a 3- to 4-foot increase in hydraulic head during the period of record, possibly caused by the construction and control of the Tampa Bypass Canal, resulting in changes to the regional potentiometric surface.

Florida↗

USGS2026

Decadal trends and occurrence of geogenic constituents and mixtures in groundwater across the continental United States

Worldwide, about 50% of the population is served by groundwater-sourced drinking water. Numerous groundwater quality assessments have found that geogenic constituents are among the most common contaminants in drinking-water aquifers. Documenting changing groundwater quality is a crucial aspect of water availability assessments. We assess trends and occurrence of geogenic constituent concentrations in groundwater across the continental United States using 3 decades of data from the U.S. Geological Survey’s National Water Quality Network. Thousands of groundwater wells were grouped into agricultural, urban, or domestic supply network types. Although most networks and constituents had no statistically significant change in concentration, many had increasing concentration trends, elevated concentrations, or both. Lithium, sodium, radium, sulfate, and uranium had increasing trends in more than 10% of the study networks. Urban and domestic well networks had increasing lithium and sodium trends more often than agricultural networks. Manganese most commonly increased in domestic well networks; uranium more commonly increased in agricultural and urban networks. Elevated concentration mixtures were widespread, and mixture complexities appeared to increase over time. Our results indicate that more than 2.3 million domestic-well users may be affected by elevated concentrations of one or more geogenic constituents.

continental United States↗

USGS2025

Assessing legacy nitrogen in groundwater using numerical models of the Long Island aquifer system, New York

Nitrogen transported along groundwater flow paths in coastal aquifers can contribute substantially to nitrogen loading into surface water receptors, particularly in hydrologic systems dominated by groundwater discharge. Nitrogen entrained in the aquifer is a function of land use and associated nitrogen sources at the time of groundwater recharge, which may differ considerably from present-day sources. Legacy nitrogen can result in substantial discrepancies between observed present-day nitrogen loading to surface water receptors and loading estimated from present-day sources. Additionally, legacy nitrogen can continue to discharge into surface waters after nitrogen mitigation actions have been undertaken. Here, we use a numerical modeling framework to compare three methods of estimating time-varying historical nitrogen loads to four water bodies (receptors) on eastern Long Island, New York. The methods span a range of data requirements and process complexity, from instantaneous receptor loads calculated from steady-state groundwater contributing areas, to transient loads estimated by explicitly simulating legacy groundwater nitrogen transport over a century with large changes in nitrogen sources and hydrologic conditions. The effects of legacy nitrogen on estimated receptor loads varied temporally and spatially within the study area. Depending on antecedent nitrogen inputs and hydrologic conditions, historical annual nitrogen loads estimated from transient simulations accounting for legacy nitrogen can be quite similar (<10% difference) or substantially different (±100%) from those estimated from simpler instantaneous methods. Continued input of present-day nitrogen sources using methods that account for legacy nitrogen results in asymptotic increases in receptor nitrogen loads over time, indicating that simulated present-day receptor nitrogen loads are not in equilibrium with present-day inputs. For these receptors in disequilibrium, models simulating transient groundwater nitrogen transport could be used to account for legacy nitrogen lag times to help resource managers evaluate the potential effectiveness of proposed nitrogen mitigation actions.

EarthArXiv↗

USGS1993

Ground-water quality near an inactive landfill and sludge-spreading area, Tallahassee, Florida

Ground-water quality of a 120-acre area encompassing an inactive landfill southwest of Tallahassee, Florida, was assessed by installing and sampling 21 monitoring wells. Sludge from a municipal sewage-treatment plant was also applied to the land surface near the landfill site. Water samples were collected from the 21 monitoring wells from June 1987 through September 1990 and analyzed for concentrations of major ions, nitrogen species, trace metals, field measurements, and more than 140 organic constituents. Water quality in the Upper Floridan aquifer at the study site was compared to background water quality in other areas of Leon County. Ground-water quality of the study site was evaluated by the location of wells sampled in relation to the landfill and the sludge-spreading areas. Results of nonparametric statistical analysis indicated that potassium and nitrite plus nitrate as nitrogen concentrations in water samples from wells completed in the Upper Floridan aquifer at the study site were significantly different at the 5 percent probability level from those in samples from background wells completed in this aquifer in Leon County. Median potassium concentrations were 0.4 mg/L (milligrams per liter) in water from wells at the study site and 0.7 mg/L in water from background wells in Leon County. Median nitrite plus nitrate concentrations were 6.48 mg/L in water samples from wells at the study site and 0.51 mg/L in water samples from background wells. Graphical comparison of the water quality characteristics in water from six categories of wells; upgradient, landfill, adjacent to the landfill, downgradient onsite, downgradient offsite, and background Leon County, indicated that sodium, bicarbonate, sulfate, iron, manganese, and dissolved solids concentrations and specific conductance values were highest within the landfill. Upgradient and downgradient well categories include wells in areas affected by sludge spreading. Localized reducing conditions were indicated in a downgradient area by median iron concentrations of 930 and 30 ug/L (micrograms per liter) in samples from wells only 5 feet apart. Nitrite plus nitrate concentrations were lowest in water from wells in the landfill compared to water from the other categories. Concentrations of most trace elements and organic compounds were mostly below detection limits, although State maximum contaminant levels of 1 ug/L for benzene and vinyl chloride and 3 ug/L for tetrachloroethene were exceeded in 14 samples. Concentrations of sodium, potassium, chloride, sulfate, nitrite plus nitrate, total organic and ammonia nitrogen, and ammonia nitrogen in ground water were statistically analyzed in areas affected by sludge-spreading and other areas. Only nitrite plus nitrate and chloride concentrations were significantly different between the two areas. Median nitrite plus nitrate and chloride concentrations in sludge-spreading areas were 6.9 mg/L and 2.9 mg/L, respectively, compared to 1.1 mg/L and 1.8 mg/L in other areas.

Florida↗