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At least 253 records · Page 14Linked to original sources

Mapping advanced argillic alteration at Cuprite, Nevada, using imaging spectroscopy

Mineral maps based on Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data were used to study late Miocene advanced argillic alteration at Cuprite, Nevada. Distributions of Fe-bearing minerals, clays, micas, sulfates, and carbonates were mapped using the Tetracorder spectral-shape matching system. The Al content of white micas increases toward altered areas and near intrusive rocks. Alunite composition varies from pure K to intimate mixtures of Na-K endmembers with subpixel occurrences of huangite, the Ca analogue of alunite. Intimately mixed Na-K alunite marks areas of relatively lower alteration temperature, whereas co-occurring Na-alunite and dickite may delineate relict hydrothermal conduits. The presence of dickite, halloysite, and well-ordered kaolinite, but absence of disordered kaolinite, is consistent with acidic conditions during hydrothermal alteration. Partial lichen cover on opal spectrally mimics chalcedony, limiting its detection to lichen-free areas. Pods of buddingtonite are remnants of initial quartz-adularia-smectite alteration. Thus, spectral maps provide a synoptic view of the surface mineralogy, and define a previously unrecognized early steam-heated hydrothermal event. Faulting and episodes of hydrothermal alteration at Cuprite were intimately linked to upper plate movements above the Silver Peak-Lone Mountain detachment and growth, collapse, and resurgence of the nearby Stonewall Mountain volcanic complex between 8 and 5 Ma. Isotopic dating indicates that hydrothermal activity started at least by 7.61 Ma and ended by about 6.2 Ma. Spectral and stable isotope data suggest that Cuprite is a late Miocene low-sulfidation adularia-sericite type hot spring deposit overprinted by late-stage, steam-heated advanced argillic alteration formed along the margin of the Stonewall Mountain caldera.

Nevada

Mineralogy and provenance of clays in miarolitic cavities of the Pikes Peak batholith, Colorado

Clay samples from 105 cavities within miarolitic granitic pegmatites throughout the Pikes Peak batholith, in Colorado, were analyzed by powder X-ray diffraction (XRD). Smectite (beidellite), illite, and kaolinite were found within the cavities. Calculation of crystallite-thickness distribution (CTD), mean thickness of the crystallites, and variance in crystallite thickness, as deduced from XRD patterns, allowed a determination of provenance and mode of formation for illite and smectite. Authigenic miarolitic-cavity illite and smectite show lognormal CTDs and larger mean thicknesses of crystallites than do their soil-derived counterparts; non-lognormal illite in a cavity results from mixing of cavity and soil illite. Analysis of mean thickness and thickness variance shows that crystal growth of illite is initiated by a nucleation event of short duration, followed by surface-controlled kinetics. Crystallization of the miarolitic cavity clays is presumed to occur by neoformation from hydrothermal fluids. The assessment of provenance allows a determination of regional and local distributions of clay minerals in miarolitic cavities within the Pikes Peak batholith.

Colorado

Biological effects of desert dust in respiratory epithelial cells and a murine model

As a result of the challenge of recent dust storms to public health, we tested the postulate that desert dust collected in the southwestern United States imparts a biological effect in respiratory epithelial cells and an animal model. Two samples of surface sediment were collected from separate dust sources in northeastern Arizona. Analysis of the PM 20 fraction demonstrated that the majority of both dust samples were quartz and clay minerals (total SiO 2 of 52 and 57%). Using respiratory epithelial and monocytic cell lines, the two desert dusts increased oxidant generation, measured by Amplex Red fluorescence, along with carbon black (a control particle), silica, and NIST 1649 (an ambient air pollution particle). Cell oxidant generation was greatest following exposures to silica and the desert dusts. Similarly, changes in RNA for superoxide dismutase-1, heme oxygenase-1, and cyclooxygenase-2 were also greatest after silica and the desert dusts supporting an oxidative stress after cell exposure. Silica, desert dusts, and the ambient air pollution particle NIST 1649 demonstrated a capacity to activate the p38 and ERK1/2 pathways and release pro-inflammatory mediators. Mice, instilled with the same particles, showed the greatest lavage concentrations of pro-inflammatory mediators, neutrophils, and lung injury following silica and desert dusts. We conclude that, comparable to other particles, desert dusts have a capacity to (1) influence oxidative stress and release of pro-inflammatory mediators in respiratory epithelial cells and (2) provoke an inflammatory injury in the lower respiratory tract of an animal model. The biological effects of desert dusts approximated those of silica.

Inhalation Toxicology

Studies of pre-Selma Cretaceous core samples from the outcrop area in western Alabama

In 1954 four core holes were drilled in the pre-Selma Cretaceous strata of the Alabama Coastal Plain in order to get unweathered samples within a few miles of the outcrops. During the next few years several specialists studied the cores, and their reports are published as consecutive parts of this bulletin. Watson H. Monroe, who spent many years studying the Coastal Plain strata in Alabama and Mississippi, conceived and supervised the drilling and planned the later studies. His earlier published report (W. H. Monroe, 1955, Cores of pre-Selma Cretaceous rocks in the outcrop area in western Alabama: Gulf Coast Geol. Societies Trans., v. 5, p. 11-37) contains a brief description of the stratigraphy, together with logs and other information regarding the core holes, and he has provided the introductory chapter to this bulletin. Richard E. Bergenback studied the petrology of the cores, which included finding the distribution of grain sizes, determining the mineralogy of the grains and the matrix of the sediments, and having X-Ray identifications made of the clay minerals. Norman F. Sohl studied the mollusks and other large fossils obtained from the cores and compared them with other faunal suites collected in Alaban1a and Texas. Esther R. Applin studied the sparse microfauna, comparing it with faunas obtained from deep wells downdip in Georgia, Alabama, and Mississippi and with outcrop samples fron1 Texas, and has described a new species of Foraminifera. Estella B. Leopold and Helen M. Pakiser obtained a large pollen and spore assemblage by digesting carbonaceous layers of some of the cores in acid; this flora includes much new material, which is not described here. The Bergenback, Sohl, and Applin reports discuss the probable environment in which the sediments accumulated. Louis C. Conant, who spent several years studying and mapping these sediments, has written a summary chapter integrating some of the surface and subsurface information. Quarter-cuts of the cores belonging to the U.S. National Museum have been deposited on indefinite loan with the Alabama Geological Survey at University, Ala., and with the Shell Oil Co. at Jackson, Miss. They are available there for inspection and study.

Bulletin

Rare earth elements in coal and coal fly ash

The rare earth elements (REEs) are a group of 17 elements sharing similar chemical properties. They include yttrium (Y, atomic number 39), scandium (Sc, atomic number 21), and the 15 elements of the lanthanide series, atomic numbers 57 (lanthanum, La) to 71 (lutetium, Lu). Because promethium (Pm, atomic number 61) does not occur in the Earth’s crust and scandium typically has different geological occurrences from other REEs, they are not discussed further herein. REEs are, on average, more abundant than precious metals (for example, gold, silver, and platinum), but because of their unique geochemical properties, they do not commonly form economically viable ore deposits. Nevertheless, REEs are increasingly required for a range of modern applications in defense and renewable energy technologies and in commercial products, primarily as magnets, batteries, and catalysts. The United States currently (2018) produces REEs from a single mine in California, accounting for just 9 percent of global production, whereas 70 percent of global REE production comes from China. For these reasons, REEs are considered a critical resource, and the U.S. Geological Survey (USGS) has an interest in helping to identify new sources of REEs for domestic production. In 2017, coal use accounted for about 30 percent of the electric power generated in the United States. Fly ash, produced during the burning of coal, is a fine­-grained solid derived from noncombustible constituents of coal, such as clay minerals and quartz. When coal is burned, REEs are retained and enriched in the fly ash and, as a result, fly ash has long been considered a potential resource for REEs. The United States has the world’s largest coal reserves and, even though gas-­fired power generation has increased significantly in the last decade, the United States continues to produce vast quantities of fly ash, about half of which is beneficially reused, primarily in construction materials. The remainder is stored, mostly in landfills and impound­ments. Thus, annual fly ash production, combined with fly ash already in stor­age, constitutes a large potential resource. Research into how to utilize coal and coal fly ash as sources of REEs is ongo­ing. Viable recovery of REEs from coal and coal ash requires identification of coals and ashes with the highest REE concentrations and development of workable methods for REE extraction and recovery. Understanding how REEs occur within fly ash, described in this fact sheet, is one of the keys to developing possible methods for their recovery.

Fact Sheet

Gas, water, and oil production from the Wasatch Formation, Greater Natural Buttes Field, Uinta Basin, Utah

Gas, oil, and water production data were compiled from 38 wells with production commencing during the 1980s from the Wasatch Formation in the Greater Natural Buttes field, Uinta Basin, Utah. This study is one of a series of reports examining fluid production from tight gas reservoirs, which are characterized by low permeability, low porosity, and the presence of clay minerals in pore space. The general ranges of production rates after 2 years are 100-1,000 mscf/day for gas, 0.35-3.4 barrel per day for oil, and less than 1 barrel per day for water. The water:gas ratio ranges from 0.1 to10 barrel per million standard cubic feet, indicating that free water is produced along with water dissolved in gas in the reservoir. The oil:gas ratios are typical of a wet gas system. Neither gas nor water rates show dependence upon the number of perforations, although for low gas-flow rates there is some dependence upon the number of sandstone intervals that were perforated. Over a 5-year time span, gas and water may either increase or decrease in a given well, but the changes in production rate do not exhibit any dependence upon well proximity or well location.

Open-File Report

Gas, oil, and water production from Jonah, Pinedale, Greater Wamsutter, and Stagecoach Draw fields in the Greater Green River Basin, Wyoming

Gas, oil, and water production data were compiled from selected wells in four gas fields in rocks of Late Cretaceous age in southwestern Wyoming. This study is one of a series of reports examining fluid production from tight-gas reservoirs, which are characterized by low permeability, low porosity, and the presence of clay minerals in pore space. Production from each well is represented by two samples spaced five years apart, the first sample typically taken two years after commencement of production. For each producing interval, summary diagrams of oil versus gas and water versus gas production show fluid production rates, the change in rates during five years, the water-gas and oil-gas ratios, and the fluid type. These diagrams permit well-to-well and field-to-field comparisons. Fields producing water at low rates (water dissolved in gas in the reservoir) can be distinguished from fields producing water at moderate or high rates, and the water-gas ratios are quantified. The ranges of first-sample gas rates in Pinedale field and Jonah field are quite similar, and the average gas production rate for the second sample, taken five years later, is about one-half that of the first sample for both fields. Water rates are generally substantially higher in Pinedale than in Jonah, and water-gas ratios in Pinedale are roughly a factor of ten greater in Pinedale than in Jonah. Gas and water production rates from each field are fairly well grouped, indicating that Pinedale and Jonah fields are fairly cohesive gas-water systems. Pinedale field appears to be remarkably uniform in its flow behavior with time. Jonah field, which is internally faulted, exhibits a small spread in first-sample production rates. In the Greater Wamsutter field, gas production from the upper part of the Almond Formation is greater than from the main part of the Almond. Some wells in the main and the combined (upper and main parts) Almond show increases in water production with time, whereas increases in water production are rare in the upper part of the Almond, and a higher percentage of wells in the upper part of the Almond show water decreasing at the same rate as gas than in the main or combined parts of the Almond. In Stagecoach Draw field, the gas production rate after five years is about one-fourth that of the first sample, whereas in Pinedale, Jonah, and Greater Wamsutter fields, the production rate after five years is about one-half that of the first sample. The more rapid gas decline rate seems to be the outstanding feature distinguishing Stagecoach Draw field, which is characterized as a conventional field, from Pinedale, Jonah, and Greater Wamsutter fields, which are generally characterized as tight-gas accumulations. Oil-gas ratios are fairly consistent within Jonah, Pinedale, and Stagecoach Draw fields, suggesting similar chemical composition and pressure-temperature conditions within each field, and are less than the 20 bbl/mmcf upper limit for wet gas. However, oil-gas ratios vary considerably from one area to another in the Greater Wamsutter field, demonstrating a lack of commonality in either chemistry or pressure-temperature conditions among the six areas. In all wells in all four fields examined here, water production commences with gas production—there are no examples of wells with water-free production and no examples where water production commences after first-sample gas production. The fraction of records with water production higher in the second sample than in the first sample varies from field to field, with Pinedale field showing the lowest percentage of such cases and Jonah field showing the most. Most wells have water-gas ratios exceeding the amount that could exist dissolved in gas at reservoir pressure and temperature.

Wyoming

Examination of Libby, Montana, Fill Material for Background Levels of Amphibole from the Rainy Creek Complex Using Scanning Electron Microscopy and X-Ray Microanalysis

Natural background levels of Libby-type amphibole in the sediment of the Libby valley in Montana have not, up to this point, been determined. The purpose of this report is to provide the preliminary findings of a study designed by both the U.S. Geological Survey and the U.S. Environmental Protection Agency and performed by the U.S. Geological Survey. The study worked to constrain the natural background levels of fibrous amphiboles potentially derived from the nearby Rainy Creek Complex. The material selected for this study was sampled from three localities, two of which are active open-pit sand and gravel mines. Seventy samples were collected in total and examined using a scanning electron microscope equipped with an energy dispersive x-ray spectrometer. All samples contained varying amounts of feldspars, ilmenite, magnetite, quartz, clay minerals, pyroxene minerals, and non-fibrous amphiboles such as tremolite, actinolite, and magnesiohornblende. Of the 70 samples collected, only three had detectable levels of fibrous amphiboles compatible with those found in the rainy creek complex. The maximum concentration, identified here, of the amphiboles potentially from the Rainy Creek Complex is 0.083 percent by weight.

Open-File Report

Gas, oil, and water production from Grand Valley, Parachute, Rulison, and Mamm Creek fields in the Piceance Basin, Colorado

Gas, oil, and water production data for tight gas reservoirs were compiled from selected wells in western Colorado. These reservoir rocks—the relatively shallow Paleogene Wasatch G sandstone interval in the Parachute and Rulison fields and fluvial sandstones in the deeper Upper Cretaceous Mesaverde Group in the Grand Valley, Parachute, Rulison, and Mamm Creek fields—are characterized by low permeability, low porosity, and the presence of clay minerals in pore space. Production from each well is represented by two samples spaced five years apart, the first sample typically taken two years after production commenced, which was generally in the 1990s. For each producing interval, summary diagrams of oil-versus-gas and water-versus-gas production show fluid production rates, the change in rates during five years, the water-gas and oil-gas ratios, and the fluid type. These diagrams permit well-to-well and field-to-field comparisons. Fields producing water at low rates (water dissolved in gas in the reservoir) can be distinguished from fields producing water at moderate or high rates, and the water-gas ratios are quantified. Dry gas is produced from the Wasatch G interval and wet gas is produced from the Mesaverde Group. Production from the Wasatch G interval is also almost completely free of water, but water production commences with gas production in wells producing from the Mesaverde Group—all of these wells have water-gas ratios exceeding the amount that could exist dissolved in gas at reservoir temperature and pressure. The lack of produced water from the Wasatch G interval is attributed to expansion of the gas accumulation with uplift and erosion. The reported underpressure of the Wasatch G interval is here attributed to hydraulic connection to the atmosphere by outcrops in the Colorado River valley at an elevation lower than that of the gas fields. The amount of reduction of gas production over the five-year time span between the first and second samples is roughly one-half, with median values of second-sample to first-sample gas-production ratios ranging from 0.40 for Rulison-Mesaverde to 0.63 for Rulison-Wasatch G. Commencing with the first sample, the logarithm-of-production rate appears to decline linearly with time in many wells. However, water production is much more erratic as a function of time from an individual well and also from one well to the next within a field. Water production can either decrease or increase with time (from the first to the second sample). In this study, slightly more than half the wells producing from the Mesaverde Group show decreases in water production with time. Plots of water decline versus gas decline show little relation between the two, with only the wells in Rulison field displaying some tendency for water and gas to decline proportionately.

Colorado

Engineering geology as applied to highway construction

A geologic study of the site for a relocated segment of State Highway 93 northwest of Denver Colo., was made by by the Engineering Geology Branch of the U.S. Geological Survey as a demonstration of the applicability of geologic mapping to problems of highway construction. The relocated segment provides access to the Rocky Flats plant of the Atomic Energy Commission. The geologic conditions along five miles of the relocation route were examined. In most places apparently well-indurated sandstones of the Upper Cretaceous Fox Hills sandstone and Laramie formation can be excavated without using explosives. The intersection of a six foot thick coal seam in the roadbed in one proposed cut was predicted and removal and replacement with more suitable subgrade material was recommended. Near Marshall the alignment crosses three northeast-trending normal faults which do not adversely affect the highway. Clay minerals with expanding properties are present in some of the claystones of the Laramie, and special measures must be taken to ensure that ground water will not seep into them and cause swelling beneath the roadbed. Late Tertiary or Early Quaternary gravel cap pediments along the mountain front. Ground water issuing from seeps and springs found at the contact between these gravels and the underlying bedrock should be intercepted and removed from beneath the roadbed.

Colorado

Regional appraisal of the Wilcox Group in Texas for subsurface storage of fluid wastes: Part 1: Geology

Sandy beds of the Wilcox Group in Texas are underlain and overlain by clays of the Midway and Claiborne Groups. The Wilcox is divided by a persistent shale wedge. Contrasting delta systems described as high-constructive and high-destructive exist in the divisions. Merged high constructive deltas characterize the lower, while the upper Wilcox was deposited as a high destructive system. Maximum sand development occurs downdip parallel to regional depositional strike in the delta facies. Further downdip, shales replace sands, and sediments are (abnormally high pressured) geopressured. The structure o5 the updip port[on is that of a stable shelf. Downdip, greatly thickened beds are cut by large faults. These faults and the resultant deposits are recognized as being the result of a previously unnamed phenomenon--here termed hydrothermal tectonism. This process is keyed to the thermal diagenesis of the clay mineral montmorillonite and resultant transfer of overburden pressure from the rock framework to the contained fluid.

Texas

Ground-water resources and geology of Colquitt County, Georgia

Limestone beds of Eocene, Oligocene, and lower Miocene age, called the principal artesian aquifer, are the chief source of ground water for Colquitt County. Because streams are small, undependable and relatively inaccessible to most users, ground water is the most important source for increased industrial and agricultural water use. Southeast of Moultrie the principal artesian aquifer is very productive, and has transmissivity in excess of 145,000 feet squared per day (13,500 meters squared per day). A structural or paleogeographic feature called the Suwannee strait traverses the county from near the southwest corner to the northeast corner. In this strait, limestone in the principal artesian aquifer is partly replaced by fine-grained clastic sediment, impairing transmissivity and making wells hard to construct. Transmissivity is much lower northwest of the strait than it is southeast, probably because of facies changes in the aquifer. In the belt of the hypothesized Ochlockonee fault, water containing greater-than-usual concentrations of dissolved solids is produced. This anomaly could be the result of the fault having acted as a conduit when the vertical hydraulic gradient was upward from a deeper aquifer, or be the result of the movement of ground water from a sulfate-rich source in the sediments of the Suwannee strait. In south-central Colquitt County, clay-capped permeable beds extending above potentiometric surfaces create conditions favorable for breathing wells. Predominantly clastic beds of Miocene age overlie the Suwannee Limestone. These beds have a transmissivity of about 2,280 feet squared per day (215 meters squared per day), but they are of comparatively little importance because larger yields can be obtained from the underlying principal artesian aquifer. Moreover, wells are difficult to construct in the poorly consolidated clastic sediments, and water from these shallow beds is likely to be depleted during droughts. The ground water is generally hard, but is otherwise of good quality. One exception is near the hypothesized Ochlockonee fault where water contains higher-than-usual concentrations of various ions, especially sulfate. Another exception occurs along the axis of the Suwannee strait where clay minerals in the channel facies may soften the water by ion exchange.

Georgia

Use of imaging in the 0.46-2.36 [micrometers] spectral region for alteration mapping in the Cuprite mining district, Nevada

Color composites of Landsat MSS ratio images that display variations in the intensity of ferric-iron absorption bands are highly effective for mapping limonitic altered rocks, but ineffective for mapping nonlimonitic altered rocks. Analysis of 0.45-2.5 ?m field and laboratory spectra shows that iron-deficient opalites in the Cuprite mining district, Nevada, have an intense OH-absorption band near 2.2 ?m owing to their clay mineral and alunite contents and that this spectral feature is absent or weak in adjacent unaltered tuff and basalt. To evaluate the usefulness of this spectral feature for discriminating between altered and unaltered rocks, we generated color-ratio composite images from multispectral (0.46-2.36 ?m) aircraft data. The altered rocks in the district can be discriminated from unaltered rocks with few ambiguities; in addition, some effects of mineralogical zoning can be discriminated within the altered area. Only variations in amounts of limonite can be discerned in shorter wavelength aircraft data, Landsat MSS bands, and color aerial photographs.

Open-File Report

Analysis of borehole geophysical information across a uranium deposit in the Jackson Group, Karnes County, Texas

Borehole geophysical studies across a uranium deposit in the Jackson Group, South Texas, show the three geochemical environments often associated with uranium roll-type deposits: an altered (oxidized) zone, an ore zone, and an unaltered (reduced) zone. Mineralogic analysis of the total sulfides contained in the drill core shows only slight changes in the total sulfide content among the three geochemical regimes. However, induced polarization measurements on the core samples indicate that samples obtained from the reduced side of the ore zone are more electrically polarizable than those from the oxidized side of the ore zone, and therefore probably contain more pyrite. Analysis of the clay-size fraction in core samples indicates that montmorillonite is the dominant clay mineral. High resistivity values within the ore zone indicate the presence of calcite cement concentrations that are higher than those seen outside of the ore zone. Between-hole resistivity and induced polarization measurements show the presence of an extensive zone of calcite cement within the ore zone, and electrical polarizable material (such as pyrite) within and on the reduced side of the ore zone. A quantitative analysis of the between-hole resistivity data, using a layered-earth model, and a qualitative analysis of the between-hole induced polarization measurements showed that mineralogic variations among the three geochemical environments were more pronounced than were indicated by the geophysical and geologic well logs. Uranium exploration in the South Texas Coastal Plain area has focused chiefly in three geologic units: the Oakville Sandstone, the Catahoula Tuff, and the Jackson Group. The Oakville Sandstone and the Catahoula Tuff are of Miocene age, and the Jackson Group is of Eocene age (Eargle and others, 1971). Most of the uranium mineralization in these formations is low grade (often less than 0.02 percent U3O8) and occurs in shallow deposits that are found by concentrated exploratory drilling programs. The sporadic occurrence of these deposits makes it desirable to develop borehole geophysical techniques that will help to define the depositional environments of the uranium ore, which is characterized by geochemical changes near the uranium deposits. Geochemical changes are accompanied by changes in the physical characteristics of the rocks that can be detected with borehole geophysical tools. This study is concerned with a uranium deposit within the Jackson Group that is located just east of Karnes City, Tex. Five holes were drilled on this property to obtain borehole geophysical data and cores. The cores were analyzed for mineralogic and electrical properties. The borehole geophysical information at this property included induced polarization, resistivity, gamma-gamma density, neutron-neutron, gamma-ray, caliper, and single-point-resistance logs. Between-hole resistivity and induced polarization measurements were made between hole pairs across the ore deposit and off the ore deposit.

Open-File Report

Texture, clay mineralogy, trace metals, and age of cored sediments from the North Atlantic Outer Continental Shelf

The concentration of 9 trace metals in sediment cores collected from the Continental Shelf off the northeastern United States are generally uniform with sediment depth and are low compared to average crustal abundances. No evidence for the accumulation of anthropogenic metals was found in these samples. The sediment texture on Georges Bank is predominantly sand at essentially all sediment depths and at all locations. A larger concentration of silts and clays was found at some locations west of Great South Channel. The major clay mineral group in these sediments is illite with moderate amounts of chlorite and small amounts of kaolinite. 14 C ages on total organic matter in sediments have given the first evidence that the area of fine—grained sediment south of Martha's Vineyard is a modern deposit. This area may be the only sink for fine sediments and sediment—related contaminants on the Continental Shelf exclusive of the Gulf of Maine. 14 C ages on total organic matter in glacial till recovered south of Nantucket Island tentatively suggest the presence of Late Wisconsin ice at this location. Confirmation requires analysis of detrital coal in these samples.

North Atlantic Outer Continental Shelf

Clay mineralogy of Devonian shales in the Appalachian Basin

A study of the clay mineralogy of the Devonian black shales of the Appalachian basin was undertaken to help predict areas for potential gas resources. More than 2,100 samples from 84 drill holes representing 11 shale units were analyzed for clay mineralogy or whole—rock mineralogy or both. Approximately 1,300 samples were from drill cores and about 800 samples were from drill cuttings. Illite (2M) recrystallized during diagenesis is more or less uniformly present throughout all shale units. Chlorite formed during low grade metamorphism is least abundant in the younger units and more abundant in the older units. Illite—smectite mixed—layer clay, which supplied the material for the formation of chlorite, is most abundant in the younger units and least abundant in the older units. Illite—chlorite mixed—layer clay occurs as a trace in all shale units. Kaolinite, the only unaltered detrital clay mineral, occurs in about 25 to 30 percent of the samples. The source of the kaolinite appears to have been to the east and northeast of the basin of deposition. The color of the shale units is primarily due to the organic content; however, those shales that contain calcite are darker than those that do not for equal amounts of organic carbon.

Appalachian Basin

Core OL-92 from Owens Lake, southeast California

The drilling project at Owens Lake commenced in April, 1991. This Open-File Report represents an effort to make available to other researchers our preliminary data collected during the first year of study following completion of the core-drilling phase. Nineteen data collections and preliminary interpretations are presented in the following sections. They are the work of fifteen first-authors and their numerous co-authors. Broadly, their topics include a field log of the core (1 contribution), sedimentological analyses (1), clay- mineral identification (1), geochemical analyses (5), dating and age estimates of the cored sediments (4), and identifications of fossil materials (7).

California

Approximate land-surface subsidence in Fort Bend County, Texas, 1943-87 and 1973-87

Land-surface subsidence resulting from the lowering of water levels that accompany ground-water development in areas of the Texas Gulf Coast has been described in numerous reports, newspapers, and magazines since the 1950s. Gabrysch and Bonnet (1975), Gabrysch (1984), and Gabrysch and Coplin (1990) presented subsidence maps of the Houston-Galveston region, including Fort Bend County, for a number of time periods. Most of the subsidence has been in the Houston area. This report, prepared in cooperation with the Fort Bend Subsidence District and the Harris-Galveston Coastal Subsidence District, presents contour maps of land-surface subsidence in Fort Bend County that occurred during 1943-87 and 1973-87. Fort Bend County is underlain by a thick section of unconsolidated lenticular deposits of sand and clay. The deposits include the principal aquifers in the county – the Evangeline aquifer and the overlying Chicot aquifer. Within these aquifers, the interbedded sands and clays are saturated with water almost to the land surface. The sand layers generally are connected laterally, but the clays retard the vertical movement of water, creating confined (artesian) conditions within the aquifer. The sands are fine to medium grained, and the combined layers yield large quantities of water. The clays are principally montmorillonite, the most compressible of the clay minerals.

Texas