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USGS2005

Studies of the Chesapeake Bay impact structure - Introduction and discussion

The late Eocene Chesapeake Bay impact structure on the Atlantic margin of Virginia is the largest known impact crater in the United States, and it may be the Earth's best preserved example of a large impact crater that formed on a predominantly siliciclastic continental shelf. The 85-kilometer-wide (53-milewide) crater also coincides with a region of saline ground water. It has a profound influence on ground-water quality and flow in an area of urban growth. The USGS-NASA Langley corehole at Hampton , Va., is the first in a series of new coreholes being drilled in the crater, and it is the first corehole to penetrate the entire crater-fill section and uppermost crystalline basement rock. The Langley corehole is located in the southwestern part of the crater's annular trough. A comprehensive effort to understand the crater's materials, architecture, geologic history , and formative processes, as well as its influence on ground water, includes the drilling of coreholes accompanied by high-resolution seismic-reflection and seismic-refraction surveys, audio-magnetotelluric surveys, and related multidisciplinary research. The studies of the core presented in this volume provide detailed information on the outer part of the crater, including the crystalline basement , the overlying impact -modified and impact -generated sediments (physical geology, paleontology, shocked minerals, and crystalline ejecta), and the upper Eocene to Quaternary postimpact sedimentary section (stratigraphy, paleontology, and paleoenvironments). The USGS-NASA Langley corehole has a total depth below land surface of 635.1 meters (m; 2,083.8 feet (ft)). The deepest unit in the corehole is the Neoproterozoic Langley Granite. The top of this granite at 626.3 m (2,054.7 ft) depth is overlain by 390.6 m (1,281.6 ft) of impact -modified and impact -generated siliciclastic sediments. These crater-fill materials are preserved beneath a 235.6-m-thick (773.12-ft-thick) blanket of postimpact sediments. A high-resolution seismic-reflection and seismic-refraction profile that crosses the Langley drill site is tied to the core by borehole geophysical logs, and it reveals the details of extensional collapse structures in the western annular trough. Electrical cross sections based on audio-magnetotelluric (AMT) soundings image a nearly vertical zone of high resistivity at the outer margin of the annular trough, possibly indicating fresh ground water at that location, and they show impedance trends that match the curvature of the structure . They also image the subsurface contact between conductive sediments and resistive crystalline basement , showing that the depth to crystalline basement is relatively constant in the western part of the annular trough. Chemical and isotopic data indicate that saline ground water of the Virginia inland saltwater wedge or bulge is a mixture of freshwater and seawater, and evidence for a mixing zone at the crater's outer margin supports the concept of differential flushing of residual seawater to create the bulge. Ground-water brine in the central part of the crater was produced by evaporation, and brine production from the heat of the impact is at least theoretically possible.

Chesapeake Bay↗

USGS2011

Water-quality data for the Russian River Basin, Mendocino and Sonoma Counties, California, 2005-2010

Since 2003, the U.S. Geological Survey, in cooperation with the Sonoma County Water Agency, has been collecting chemical, microbiological, and isotopic data from surface-water and groundwater sites in Mendocino and Sonoma Counties, California. The investigation is being conducted to determine water-quality baseline conditions for the Russian River during the summer months and to characterize the water-quality in the area of the Sonoma County Water Agency's water-supply facility where Russian River water is diverted and treated by riverbank filtration. This report is a compilation of the hydrologic and water-quality data collected from 14 Russian River sites, 8 tributary sites, 1 gravel-terrace pit site, 14 groundwater wells, and a wastewater treatment plant between the city of Ukiah and the town of Duncans Mills for the period August 2005 through October 2010. Field measurements included discharge, barometric pressure, dissolved oxygen, pH, specific conductance, temperature, and turbidity. All samples were analyzed for nutrients, major ions, trace metals, total and dissolved organic carbon, organic wastewater compounds, standard bacterial indicators, and the stable isotopes of hydrogen and oxygen. Standard bacterial indicators included total coliform, Escherichia coli, enterococci, and Clostridium perfringens for the period 2005 through 2007, and total and fecal coliform, and enterococci for 2010. In addition, enrichment of enterococci was performed on all surface-water samples collected during summer 2006, for detection of the human-associated enterococcal surface protein in Enterococcus faecium to assess the presence of sewage effluent in the Russian River. Other analyses included organic wastewater compounds of bed sediment samples collected from four Russian River sites during 2005; carbon-13 isotopic values of the dissolved inorganic carbon for surface-water and groundwater samples collected during 2006; human-use pharmaceuticals on Russian River samples collected during 2007 and 2010; and the radiogenic isotopes tritium and carbon-14 for groundwater samples collected during 2008.

Data Series↗

USGS1974

Water resources inventory of Connecticut Part 5: lower Housatonic River basin

The 557 square miles of the lower Housatonic River basin in western Connecticut include the basins of two major tributaries, the Pomperaug and Naugatuck Rivers. Nearly all water is derived from precipitation, which averaged 47 inches per year during 1931-60, In this period an additional 570 billion gallons of water per year entered the basin in the main stem of the Housatonic River at Lake Lillinonah, and some water was imported by water-supply systems from outside the basin. Almost half the precipitation--21.6 inches--was lost from the basin by evapotranspiration. Except for small amounts exported, the remainder discharged as runoff and underflow into Long Island Sound. Variations in streamflow at 6 long-term continuous-record gaging stations are summarized in standardized graphs and tables that can be used to estimate streamflow characteristics at other sites. For example, mean flow and two low-flow characteristics, the 7-day annual minimum flow for 2-year and 10-year recurrence intervals, have been determined for many partial-record stations throughout the basin. Of the 37 principal lakes, ponds, and reservoirs in the basin, 6 have usable storage of more than 1 billion gallons. The “maximum safe draft rate” (described in: “Storage of Water in Lakes and Reservoirs”) of the largest of these, Thomaston Reservoir near Thomaston, is 75.6 million gallons per day for the 10-year and 20-year recurrence intervals of annual lowest mean flow. Floods have occurred during every month, at one time or another. The two greatest floods on the Naugatuck River in historical time occurred 2 months apart in 1955. The larger, in August, had a peak of 106,000 cfs (cubic feet per second) at Beacon Falls. Since then, the likelihood of major floods has been considerably reduced by a program of flood control in the basin. Water can be obtained from three aquifers under-lying the basin-stratified drift, till, and bedrock. Stratified drift covers about 16 percent of the basin, mostly in valleys and lowlands, and its saturated part generally ranges in thickness from 10 feet in small valleys to 200 feet in the Housatonic River valley. Its transmissivity ranges from 0 to 47,000 ft 2 /day (feet shared per day). Till, deposited directly by glacial ice, forms a widespread but discontinuous mantle over bedrock in most upland areas and extends beneath stratified drift in lowlands; it ranges in thickness from 0 to 200 feet. The median value of 31 published determinations of hydraulic conductivity of till in southern New England is 0.67 ft/day and ranges from 0.013 to 29 ft/day. Crystalline bedrock underlies most of the basin and is composed principally of granite, gneiss, and schist. Sedimentary volcanic bedrock underlies only the Pomperaug River basin. Regardless of rock type, water is obtained mostly from fractures. Streambed deposits are significant features of the hydrogeologic system because they affect the amount of water from streams and lakes that can be induced to infiltrate aquifers. Based on field tests, characteristic values of vertical hydraulic conductivity of streambed deposits are 0.40 ft/day for fine-grained deposits and 14 ft/day for gravelly deposits. Ground-water supplies generally range in yield from several millions of gallons per day from large well fields to 1 gpm (gallons per minute) from single wells. Large supplies, with yields of 100 gpm or more from individual wells, are most commonly obtained from stratified drift. Yields to be expected from screened wells tapping this aquifer can be calculated by use of a series of graphs in conjunction with estimates of transmissivity and aquifer thickness. The yields of 14 principal ground-water reservoirs are estimated from aquifer characteristics and also from the amount of water that can be obtained from aquifer storage, from interception or runoff, and from infiltration of streamflow at low-flow conditions, using a hypothetical well-field arrangement for each reservoir. It is assumed that induced infiltration is restricted to an amount equal to the 7-day annual minimum stream-flow for a 2-year recurrence interval. Yields range from 1.4 to 15 mgd (million gallons per day) during periods of no recharge, and from 2.0 to 17 mgd during recharge periods. Small to moderate water supplies can be obtained from any of the aquifers under suitable conditions. For example, data from 294 wells in the basin indicate that yields of a few gallons per minute can be obtained from bedrock at most sites. The likelihood of obtaining an adequate domestic supply is slightly greater in granite than in schist and also is greater where the overburden is stratified drift rather than till. Chemical analyses of precipitation samples collected monthly from five stations in the basin during a 9-month period in 1966 show that rainfall is acidic and that sulfate is the dominant anion, probably because of industrial fumes and smoke within and near the basin. Where unaffected by man’s activities, water in the basin is generally low in dissolved-solids concentration, is of the calcium magnesium bicarbonate type, and is soft to moderately hard. In general, streamflow is less mineralized than ground water, particularly when it consists largely of direct runoff. However, streamflow becomes more highly mineralized during low-flow conditions, when most of it consists of more highly mineralized water discharged from aquifers. The median value of dissolved-solids concentration of water at 22 stream sites was 51 mg/1 (milligrams per liter) during high flow, and 68 mg/1 during low flow within the study period. Iron and manganese occur naturally in objectionable concentrations in parts of the basin, particularly in streams draining swamps and in water from bedrock containing iron and manganese-bearing minerals. Man’s activities have degraded the quality of water in streams in much of the basin, except in the Pomperaug subbasin. In the Naugatuck River basin, the degradation in quality is shown by wide and erratic changes in dissolved-solids concentration, excessive amounts of certain trace elements, a low dissolved oxygen content, and abnormally high temperatures. Ground water is degraded principally by induced infiltration of stream water containing chemical wastes, by wastes stored on the ground and by effluents from septic tanks. Below its confluence with the Naugatuck River, much of the Housatonic River and adjoining marshes, wetlands, and aquifers contain salt water. Measurements of specific conductance during low-flow conditions in 1969 indicate that the dissolved-solids concentration of water in the estuary ranged from 210 mg/1 near Twomile Island to 20,000 mg/1 near Long Island Sound. The quantity and quality of water in the basin are satisfactory for a wide variety of uses, and, with suitable treatment, the water may be used for most purposes. In 1967, the total amount of water used in the basin was about 194 billion gallons. About 90 percent of this was used for industrial purposes, and 95 percent of the industrial water was obtained from surface-water sources. In the same year, 17 municipal and private water-supply systems supplied water of satisfactory quality to about three-fourths of the population.

Connecticut↗

USGS2024

Physics to fish—Understanding the factors that create and sustain native fish habitat in the San Francisco Estuary

Executive Summary The Bureau of Reclamation (Reclamation) operates the Central Valley Project (CVP), one of the nation’s largest water projects. Reclamation has an ongoing need to improve the scientific basis for adaptive management of the CVP and, by extension, joint operations with California’s State Water Project. The U.S. Geological Survey (USGS) works cooperatively with the Bureau of Reclamation to provide scientific support for the management of Reclamation’s CVP project. Major habitat restoration efforts and a new water-diversion point are planned to benefit delta smelt ( Hypomesus transpacificus ) and other species of concern while ensuring the reliability of water supply. In addition, various flow actions and management activities have been identified as possible methods to increase populations of delta smelt and salmonid ( Oncorhynchus spp.) runs of concern. The overarching goal of this cooperative project was to provide Reclamation with the scientific information needed to evaluate the efficacy of ongoing and future adaptive management actions and to improve the scientific basis for more flexible CVP operations that would achieve water-supply reliability and fish protection. The research and monitoring described in this report comprises the period 2015–19 and focuses on management issues related to native fish species of concern, especially delta smelt. Conserving the delta smelt population while providing a reliable water supply is a primary management and policy issue in California. Our approach for this cooperative project is based on the “physics to fish” concept, the idea that high-quality habitat is generated and sustained by the interaction between physical processes and the landscape. These interactions create a template for chemical and biological processes that can change across a variety of spatial and temporal scales. Following this concept, this project (hereafter referred to as “the physics to fish project”) included monitoring and studies of water flows, sediments, water quality, and invertebrate and fish dynamics across a range of spatial and temporal scales and in regions relevant to resource managers tasked with managing water supplies and ecosystem health in the San Francisco Estuary. The intent of this approach was to document the habitat conditions, important processes, and interactions among them that create high-quality habitat for native fishes so that the likely effects of future management actions (for example, habitat restoration) can be objectively assessed at the local (site-specific), regional (within subregions of the estuary), and landscape (across the entire estuary and beyond) scales. Hydrodynamically, the upper estuary (landward of Carquinez Strait) is characterized by a fixed volume of tidally exchanged water (for example, tidal prism) that interacts with the existing channel network and bathymetry to create regions with differing hydrodynamics. Our results indicate that careful study of construction or reoperation of existing infrastructure to perform management actions can help (1) improve the accuracy of hydrodynamic models; (2) further understanding of ecological effects; and (3) enhance abilities to predict ecological outcomes. At the local scale, we developed a new concept called the Lagrangian to Eulerian (LE) ratio that can be used as a tool for understanding the importance of various hydrodynamic processes in specific channels or channel networks and for forecasting transport dynamics. Channels with LE ratios<1 in a channel network or in a dead-end slough are hydrodynamically able to develop an exchange zone between two parcels of water that may have different chemical and physical properties. In a dead-end channel, there is a landward region with long residence time (no-exchange zone) and a seaward region with short residence time (high-exchange zone) that are well mixed with seaward waters. At the transition (exchange zone) between the high and no-exchange regions, a gradient will form in water-quality constituents that differ in concentration between the landward and seaward waters. Turbidity affects fish habitat and has declined through time in the San Francisco Estuary. Average turbidity across the Sacramento–San Joaquin Delta (hereafter referred to as “the Delta”) is dependent on annual hydrology. In dry years, the region around Cache Slough (known regionally as the “Cache Slough Complex”) in the northern Delta is generally more turbid than Suisun Bay and the lower Sacramento River. When the Yolo By-Pass (known regionally as “Yolo Bypass”), a large flood bypass that runs parallel to the Sacramento River in the northern Delta, is not flooding and river flows are lower, sediment is usually transported into the Cache Slough Complex because flood tides dominate ebb tides, resulting in transport of suspended sediment from seaward areas of the upper estuary into the Cache Slough Complex. These hydrodynamic conditions also favor the formation of turbidity maximums (TMs) in the Cache Slough Complex. The TMs are areas of higher suspended-sediment concentration, providing higher-turbidity habitat favored by some fishes, including delta smelt, and they can also concentrate other constituents, including phytoplankton and organic carbon that can be important in food webs. Pelagic primary production by phytoplankton is the basis for Delta food webs supporting pelagic fishes such as delta smelt; however, phytoplankton abundance in the Delta has declined during recent decades. We examined how nutrients, hydrodynamics, and other factors affect phytoplankton blooms. Based on our results, we developed three new concepts of phytoplankton bloom formation in the Delta, each associated with a distinct set of hydrologic conditions. First, productivity cascades highlighted how local processes can contribute to phytoplankton blooms observed at the regional scale. Second, we observed phytoplankton blooms in the upper San Francisco Estuary that were associated with transport out of Yolo By-Pass (transport blooms). Third, we also documented a series of phytoplankton blooms that were in the confluence area at the landward edge of Suisun Bay. The conditions leading to creation of confluence phytoplankton blooms are not yet understood, but the confluence region connects the Cache Slough Complex with Suisun Marsh. Therefore, blooms in this area have the potential to spread to large areas of the Delta. At the landscape scale, the distribution of the invasive clams ( Potamocorbula amurensis and Corbicula fluminea , hereafter referred to as “ Corbicula ”) is driven by salinity. At smaller spatial scales, the distribution of either species is sensitive to multiple factors affecting survival and reproduction, complicating efforts to predict distribution and abundance without considering local-scale conditions across the area of interest. In the Cache Slough Complex, the area landward of the exchange zone in regions with LE ratio<1 were characterized by low abundances of Corbicula probably because recruits from seaward areas are not transported past the exchange zone and because there are no landward tributaries with adult Corbicula to provide an upstream source of recruits. Corbicula biomass was highest near or downstream from the exchange zone consistent with Corbicula grazing on phytoplankton produced in the exchange zone or transported from the no-exchange zone. The severity of Corbicula grazing could be reduced by manipulating the hydrodynamic characteristics of waterways; however, the beneficial and harmful effects on the organisms meant to benefit from increased phytoplankton production, including zooplankton and fish species of concern, should be thoroughly examined before manipulating hydrodynamic characteristics. The distribution of fishes at the landscape scale is generally driven by the position of the salinity field in the estuary. The physics to fish project compared distributions of fishes at Ryer Island, a tidal wetland in Suisun Bay and a region of variable salinity, with fish distributions at the Cache Slough Complex, a freshwater region. At Ryer Island, there was an absence of freshwater invasive species and an abundance of native species, such as Sacramento splittail ( Pogonichthys macrolepidotus ), tule perch ( Hysterocarpus traskii ), and Sacramento pikeminnow ( Ptychocheilus grandis ). The native species were almost exclusively captured in wetland and nearshore shallow-water habitat regardless of water-quality conditions. In the Cache Slough Complex, our regional scale objective was to elucidate how hydrodynamic-physical habitat interactions drive fish-community structure. Our studies showed that dendritic channel systems were better able to support native species, while intertidal habitats supported those species best able to exploit the transient character of the habitat. Habitats upstream from the exchange zone were especially important in supporting high numbers of native fishes relative to within or downstream from the exchange zone. Many of the native species were associated with tidal marsh in the no-exchange zone. More pelagic-oriented, mobile species, such as Striped Bass ( Morone saxatilis ), threadfin shad ( Dorosoma petenense ), and Sacramento pikeminnow, were more affected by water-quality conditions, such as turbidity. The physics to fish concept developed in this project provides a framework for designing individual projects and for considering the cumulative effects of multiple projects in a region, using the LE ratio as a guiding metric. The physics to fish concept may also provide a suitable framework for coordinating management actions. Tidal wetlands can function in several ways in the hydrodynamic framework. Relatively small tidal wetlands with short channel networks and with LE ratios>1 are not able to maintain a landward no-exchange zone or an exchange zone. This likely means that any contributions to pelagic food webs would be limited to resources derived from wetland vegetation, which can include dissolved and particulate organic matter (detritus) and populations of consumers that can increase in abundance based on those resources. The fate of the contributed production from these channels depends on the characteristics of the receiving waters seaward of the tidal wetland. If these channels join a large system such as Suisun Bay, then any contribution is likely to be rapidly dispersed in the larger volume; however, the channel junction might provide a focal point for consumers, such as fishes, to congregate and feed on material leaving the wetland on ebb tides before it is dispersed in the larger volume. Fishes might also access these resources by entering the wetland. The physics to fish project has established a foundation and several new concepts for understanding how habitat restoration can benefit native fish populations at the local and regional levels. Many of the ideas regarding habitat restoration and channel modifications outlined in this report could help guide management actions that could improve conditions for native fishes at little or no water cost beyond water already dedicated to other management actions. A complete list of products originating from this work is provided in appendix 1.

California↗

USGS2011

Endocrine active chemicals, pharmaceuticals, and other chemicals of concern in surface water, wastewater-treatment plant effluent, and bed sediment, and biological characteristics in selected streams, Minnesota: Design, methods, and data, 2009

This report presents the study design, environmental data, and quality-assurance data for an integrated chemical and biological study of selected streams or lakes that receive wastewater-treatment plant effluent in Minnesota. This study was a cooperative effort of the U.S. Geological Survey, the Minnesota Pollution Control Agency, St. Cloud State University, the University of St. Thomas, and the University of Colorado. The objective of the study was to identify distribution patterns of endocrine active chemicals, pharmaceuticals, and other organic and inorganic chemicals of concern indicative of wastewater effluent, and to identify biological characteristics of estrogenicity and fish responses in the same streams. The U.S. Geological Survey collected and analyzed water, bed-sediment, and quality-assurance samples, and measured or recorded streamflow once at each sampling location from September through November 2009. Sampling locations included surface water and wastewater-treatment plant effluent. Twenty-five wastewater-treatment plants were selected to include continuous flow and periodic release facilities with differing processing steps (activated sludge or trickling filters) and plant design flows ranging from 0.002 to 10.9 cubic meters per second (0.04 to 251 million gallons per day) throughout Minnesota in varying land-use settings. Water samples were collected from the treated effluent of the 25 wastewater-treatment plants and at one point upstream from and one point downstream from wastewater-treatment plant effluent discharges. Bed-sediment samples also were collected at each of the stream or lake locations. Water samples were analyzed for major ions, nutrients, trace elements, pharmaceuticals, phytoestrogens and pharmaceuticals, alkylphenols and other neutral organic chemicals, carboxylic acids, and steroidal hormones. A subset (25 samples) of the bed-sediment samples were analyzed for carbon, wastewater-indicator chemicals, and steroidal hormones; the remaining samples were archived. Biological characteristics were determined by using an in-vitro bioassay to determine total estrogenicity in water samples and a caged fish study to determine characteristics of fish from experiments that exposed fish to wastewater effluent in 2009. St. Cloud State University deployed and processed caged fathead minnows at 13 stream sites during September 2009 for the caged fish study. Measured fish data included length, weight, body condition factor, and vitellogenin concentrations.

Minnesota↗

USGS2008

Hydrologic and water-quality characterization and modeling of the Onondaga Lake Basin, Onondaga County, New York

Onondaga Lake in Onondaga County, New York, has been identified as one of the Nation’s most contaminated lakes as a result of industrial and sanitary-sewer discharges and stormwater nonpoint sources, and has received priority cleanup status under the national Water Resources Development Act of 1990. A basin-scale precipitation-runoff model of the Onondaga Lake basin was identified as a desirable water-resources management tool to better understand the processes responsible for the generation of loads of sediment and nutrients that are transported to Onondaga Lake. During 2003–07, the U.S. Geological Survey (USGS) developed a model based on the computer program, Hydrological Simulation Program–FORTRAN (HSPF), which simulated overland flow to, and streamflow in, the major tributaries of Onondaga Lake, and loads of sediment, phosphorus, and nitrogen transported to the lake. The simulation period extends from October 1997 through September 2003. The Onondaga Lake basin was divided into 107 subbasins and within these subbasins, the land area was apportioned among 19 pervious and impervious land types on the basis of land use and land cover, hydrologic soil group (HSG), and aspect. Precipitation data were available from three sources as input to the model. The model simulated streamflow, water temperature, concentrations of dissolved oxygen, and concentrations and loads of sediment, orthophosphate, total phosphorus, nitrate, ammonia, and organic nitrogen in the four major tributaries to Onondaga Lake–Onondaga Creek, Harbor Brook, Ley Creek, and Ninemile Creek. Simulated flows were calibrated to data from nine USGS streamflow-monitoring sites; simulated nutrient concentrations and loads were calibrated to data collected at six of the nine streamflow-monitoring sites. Water-quality samples were collected, processed, and analyzed by personnel from the Onondaga County Department of Water Environment Protection. Several time series of flow, and sediment and nutrient loads were generated for known sources of these constituents, including the Tully Valley mudboils (flow and sediment), Otisco Lake (flow and nutrients), the Marcellus wastewater-treatment plant (flow and nutrients), and springs from carbonate bedrock (flow). Runoff from the impervious sewered areas of the City of Syracuse was adjusted for the quantity that was treatable at the county wastewater-treatment plant; the excess flows were routed to nearby streams through combined-sanitary-and-storm-sewer overflows. The mitigative effects that the Onondaga Reservoir and Otisco Lake were presumed to have on loads of sediment and particulate constituents were simulated by adjustment of parameter values that controlled sediment settling rates, deposition, and scour in the reservoir and lake. Graphical representations of observed and simulated data, and relevant statistics, were compared to assess model performance. Simulated daily and monthly streamflows were rated “very good” (within 10 percent of observed flows) at all calibration sites, except Onondaga Creek at Cardiff, which was rated “fair” (10–15 percent difference). Simulations of monthly average water temperatures were rated “very good” (within 7 percent of observed temperatures) at all sites. No observed data were available by which to directly assess the model’s simulation of suspended sediment loads. Available measured total suspended solids data provided an indirect means of comparison but, not surprisingly, yielded only “fair” to “poor” ratings (greater than 30 percent difference) for simulated monthly sediment loads at half the water-quality calibration sites. Simulations of monthly orthophosphate loads ranged from “very good” (within 15 percent of measured loads) at three sites to “poor” (greater than 35 percent difference) at one site; simulations of ammonia nitrogen loads ranged from “very good” at one site to “fair” (25–35 percent difference) at two sites. Simulations of monthly total phosphorus, nitrate, and organic nitrogen loads were generally rated “very good” at all calibration sites. Sources of uncertainty in model results were identified, including (1) errors in precipitation data, (2) limitations in model structure, (3) nonuniqueness of values for highly sensitive parameters, (4) errors or bias in data used to calibrate the different components of the model, (5) misclassification of land-use and land-cover data, (6) changes in land use during the simulation period, (7) unidentified sources or sinks of chemical loads and water-quality processes that varied over time, and (8) differences in scale between large calibrated subbasins and small subbasins to which calibrated parameter values were transferred. Uncertainty in simulations of water-quality constituents was compounded by uncertainty in the processes on which the water-quality simulations were based. Therefore, sediment simulations were affected by uncertainty in the simulation of hydrology, and nutrient simulations were affected by uncertainty in both the hydrologic and sediment processes, as well as, in simulations of water temperature and dissolved oxygen concentrations. The calibrated model can be used to simulate scenarios that represent planned or hypothetical development and implementation of best-management practices in the Onondaga Lake basin and to assess the effects that these changes and practices are likely to have on rural and urban nonpoint sources of pollution to Onondaga Lake. Model results also can be used as input to a hydrodynamic model of Onondaga Lake that is being developed by Onondaga County and to prioritize areas of the basin where mitigative measures to decrease sediment and nutrient loads could provide the greatest benefits to Onondaga Lake.

New York↗

USGS2023

Data summary report: Unregulated contaminants monitoring project

The Drinking Water Protection Section of the Minnesota Department of Health conducted reconnaissance monitoring of selected public water systems in Minnesota. Funding was obtained primarily from the Environment and Natural Resources Trust Fund. Sampling was conducted in 2019 and 2021. Laboratory analysis of samples was conducted for a variety of different contaminants of emerging concern (CECs), including selected pharmaceuticals, pesticides, PFAS, wastewater indicators and other parameters chosen for the physical and land use setting surrounding the sampling points. Sampling site and parameter selection were designed with several goals, as follows: Characterize occurrence and distribution of selected CECs in settings where such chemicals are most likely to be present; Determine if any such occurrences represent a public health concern; Compare results from coupled source water and finished (i.e., treated) water samples at public water system sites where such sampling is feasible; Assess if results from geologically vulnerable (sensitive subject to rapid recharge) and geologically non-vulnerable settings differ significantly. 306 samples were collected as part of the study, from three networks of public water systems differentiated on the basis of source water type (i.e., surface water or groundwater) and land use environment (agricultural and wastewater influenced). This report provides a preliminary, qualitative evaluation of the results. Additionally, more rigorous research will be conducted on these water quality data to evaluate the below findings in more detail. High-level findings from this assessment include the following: Very few samples exceeded health-based guidance for CECs; o When this occurred, MDH staff conducted follow up sampling at the system and provided technical advice about managing the situation. Only a fraction of the CECs analyzed were detected; o Of the 522 different CECs analyzed in the water samples, 161 were detected in one or more samples; o Additionally, most detections were at low levels; Among the CEC classes included in the analytical work, pesticides and PFAS were generally detected at a greater frequency than other CECs; o See Executive Summary Figure 1. The ten most commonly detected individual compounds include: o Tribromomethane, or bromoform, (a disinfection by-product) (70% of sites where analyzed); o norgestrel (a pharmaceutical) (69% of sites where analyzed); o lithium (68% of sites where analyzed); o Metolachlor SA (52%), Deethylatrazine (49%), atrazine (45%), and deisopropylatrazine (31%) (pesticides); o PFBA (44%) and PFHxS (27%) (PFAS compounds); and o 5-methyl benzotriazole (29%) (a benzotriazole). Some CECs were detected more frequently in samples collected from surface waters than those collected from groundwater sources; CEC concentrations were generally higher in vulnerable settings compared to nonvulnerable settings; Whether CECs were detected more frequently in the source water or finished water varied by CEC class. For example, o Benzotriazoles and pharmaceuticals were more frequently detected in source water samples than finished water samples; and o Tribromomethane, or bromoform, a common disinfection by-product, was more frequently found in finished water samples than in source water samples. This work prompted a series of programmatic changes and innovations: A response framework was established for helping the program and public water systems manage detections of unregulated CECs in drinking water; Results were forwarded to the program within MDH responsible for developing healthbased guidance in order to nominate specific compounds found in drinking water but for which limited or no risk advice is available; MDH is seeking support from the Clean Water Council to support the establishment of permanent capacity within the Drinking Water Protection Section to continue sampling efforts of this type.

Minnesota↗

USGS1987

Results of a workshop concerning assessment of the functions of bottomland hardwoods

The U.S. Environmental Protection Agency (EPA) is authorized under Section 404 of the Clean Water Act (33 U.S.C. 1344) to participate in the regulation of the discharge of dredged or fill material into waters of the United States. This regulatory authority is exercised in partnership with the U.S. Army Corps of Engineers, which has responsibility for permit issuance, and in consultation with the U.S. Fish and Wildlife Service and the National Marine Fisheries Service. Through amendments to the original statute, a series of legal actions and court decisions, and the development of operating guidance among the responsible agencies, Section 404 has evolved into the primary mechanism afforded Federal authorities for the protection of wetlands. EPA recognizes the importance of wetlands in achieving the goals of the Clean Water Act, which are to protect and maintain the chemical, physical, and biological integrity of the Nation’s waters. EPA Administrator Lee Thomas has identified wetlands protection as among the highest of Agency priorities. EPA recognizes that bottomland hardwood (BLH) wetlands have vital and unique attributes that, if lost, would severely impact the physical, chemical, and biological integrity of the Nation's waters. As part of a broad program to better protect the Nation's wetlands, EPA has therefore identified bottomland hardwood wetlands as a priority resource requiring special attention on a national basis. Recognizing the importance of implementing an effective, nationally consistent, and scientifically defensible regulatory program, EPA, in October 1984, issued Interim Operating Guidance to its field personnel for implementing the Section 404 regulatory program in bottomland hardwood wetlands. With the goal of improving and finalizing that guidance, EPA is sponsoring a series of workshops designed to answer key questions concerning BLH wetlands, based on the best scientific and technical information currently available. The first two workshops were directed toward summarizing existing scientific and technical knowledge concerning the functions of BLH ecosystems, the characteristics that are important to each function, and the impact of various development activities on those characteristics. The first workshop, which was held in St. Francisville, Louisiana, in December, 1984, examined a wetland zonation concept as a framework for gaining a greater understanding of BLH structure and function. The workshop set out to determine whether characterization of BLH resources as a series of relatively distinct zones, defined by concomitant variation in hydrologic regime, soils, and vegetation, might provide the basis for a useful and scientifically sound regulatory framework. For examp1e, if certain zones are of particular importance to one or more wetland functions that the Clean Water Act was intended to protect, then the zonation concept might be useful from the perspective of how various activities should be regulated. Discussions during the first workshop, however, indicated that the zonation concept provides, at best, only an incomplete picture of the structure and function of BLH ecosystems. In many cases, BLH functions are not limited to or closely correlated with particular zones and, furthermore, many factors other than zone are important determinants of BLH functions. With these responses in mind, the second workshop, held at Lake Lanier, Georgia, in July, 1985, was designed to elicit information on two questions. First, if zones are not an adequate framework for understanding the functions of BLH systems, what characteristics (predictors) can be used to assess the extent to which a particular site performs these functions? And second, what are the impacts of various development activities that often occur in BLH ecosystems on those characteristics and thus on the functions themselves? At the second workshop, individual workgroups dealing with particular subject areas (e.g., hydrology, water quality, fisheries, wildlife, ecosystem processes, and cultural/recreational/economic resources) were able to identify site characteristics that are important determinants of the performance of various functions. For example, the Hydrology Workgroup identified flood storage as one of three major hydrologic functions that BLH ecosystems perform. The workgroup then identified the most important characteristic (e.g., surface area of the site, soil saturation, and others) that determine flood storage and the likely impact of several common activities (e.g., conversion to soybean production and levee construction) on these characteristics. Some of the workgroups also provided estimates of the aggregate impact of activities, acting through all of the characteristics, on certain functions. The workgroups also identified key characteristics that could be used to identify high-value wetlands for various functions. In addition, the workgroups pointed out a number of topics needing further examination and discussion. First, all of the workgroups identified the need to develop the technical basis and information sources to address the problem of cumulative impacts in the regulatory process. Second, most of the workgroups noted the important of contextual variables in assessing the function of a particular site. For example, the location of a BLH site in relationship to other tracts of habitat is an important variable for many wildlife species. Similarly, the extent to which a site retains or transforms contaminants is depended not only on the characteristics of the site, but also on its position in a watershed relative to contaminant inputs. And finally, several of the workgroups pointed out that assessing the impact of an activity on a function is not as simple as "adding up" the impact on individual characteristics, but may depend instead on complex interactions among characteristics. Addressing these questions, as summarized in the objectives and discussions that follow, was the focus of the third workshop, the results of which are described in this report.

Report↗

USGS1998

Factors affecting Escherichia coli concentrations at Lake Erie public bathing beaches

The environmental and water-quality factors that affect concentrations of Escherichia coli (E. coli) in water and sediment were investigated at three public bathing beachesEdgewater Park, Villa Angela, and Sims Parkin the Cleveland, Ohio metropolitan area. This study was done to aid in the determination of safe recreational use and to help water- resource managers assess more quickly and accurately the degradation of recreational water quality. Water and lake-bottom sediments were collected and ancillary environmental data were compiled for 41 days from May through September 1997. Water samples were analyzed for E. coli concentrations, suspended sediment concentrations, and turbidity. Lake- bottom sediment samples from the beach area were analyzed for E. coli concentrations and percent dry weight. Concentrations of E. coli were higher and more variable at Sims Park than at Villa Angela or Edgewater Park; concentrations were lowest at Edgewater Park. Time-series plots showed that short-term storage (less than one week) of E. coli in lake-bottom sediments may have occurred, although no evidence for long-term storage was found during the sampling period. E. coli concentrations in water were found to increase with increasing wave height, but the resuspension of E. coli from lake-bottom sediments by wave action could not be adequately assessed; higherwave heights were often associated with the discharge of sewage containing E. coli during or after a rainfall and wastewater-treatment plant overflow. Multiple linear regression (MLR) was used to develop models to predict recreational water quality at the in water. The related variables included turbidity, antecedent rainfall, antecedent weighted rainfall, volumes of wastewater-treatment plant overflows and metered outfalls (composed of storm-water runoff and combined-sewer overflows), a resuspension index, and wave heights. For the beaches in this study, wind speed, wind direction, water temperature, and the prswimmers were not included in the model because they were shown to be statistically unrelated to E. coli concentrations. From the several models developed, one model was chosen that accounted for 58 percent of the variability in E. coli concentrations. The chosen MLR model contained weighted categorical rainfall, beach-specific turbidity, wave height, and terms to correct for the different magnitudes of E. coli concentrations among the three beaches. For 1997, the MLR model predicted the recreational water quality as well as, and in some cases better than, antecedent E. coli concentrations (the current method). The MLR model improved the sensitivity of the prediction and the percentage of correct predictions over the current method; however, the MLR model predictions still erred to a similar degree as the current method with regard to false negatives. A false negative would allow swimming when, in fact, the bathing water standard was exceeded. More work needs to be done to validate the MLR model with data collected during other recreational seasons, especially during a season with a greater frequency and intensity of summer rains. Studies could focus on adding to the MLR model other environmental and water-quality variables that improve the predictive ability of the model. These variables might include concentrations of E. coli in deeper sediments outside the bathing area, the direction of lake currents, site-specific-rainfall amounts, time-of-day information on overflows and metered outfalls, concentrations of E. coli in treated wastewater-treatment plant effluents, and occurrences of sewage-line breaks. Rapid biological or chemical methods for determination of recreational water quality could also be used as variables in model refinements. Possible methods include the use of experimental rapid assay methods for determination of E. coli concentrations or other fecal indicators and the use of chemical tracers for fecal contamination, such as coprostanol (a degradation

Water-Resources Investigations Report↗

USGS1967

Ground water in the Eola-Amity Hills area, northern Willamette Valley, Oregon

The Eola-Amity Hills area ,comprises about 230 square miles on the west side of the Willamette Valley between Salem and McMinnville, Oreg. The area is largely rural, and agriculture is the principal occupation. Rocks ranging in age from Eocene to Recent underlie the area. The oldest rocks are a sequence more than 5,000 feet thick of marine-deposited shale and siltstone strata, with thin interbeds of sandstone that range in age from Eocene to middle Oligocene. They are widely exposed in and west of the Eola-Amity Hills and underlie younger sedimentary and volcanic rocks throughout the study area. In the Eola-Amity Hills and Red Hills of Dundee, the Columbia River Group, a series of eastward-dipping basaltic lava flows locally of Miocene age, and conformably overlies the marine sedimentary rocks. The Columbia River Group ranges in thickness from less than 1 foot to about 900 feet and has an average thickness of about 200 feet. The formation is exposed in the Eola-Amity Hills and Red Hills of Dundee and, at places, extends to the east beneath younger rocks. Overlying the Columbia River Group and marine sedimentary rocks are nonmarine sedimentary deposits that range in thickness from less than 1 foot, where they lap up (to an altitude of about 200 ft) on the flanks of the higher hills, to several hundred feet along the east margin of the study area. These deposits include the Troutdale Formation of Pliocene age, the Willamette Silt of late Pleistocene age, and alluvium of the Willamette River and its tributaries. The Troutdale Formation and the alluvium of the Willamette River contain the most productive aquifers in the Eola-Amity Hills area. These aquifers, which consist mainly of sand and gravel, generally yield moderate to large quantities of water to properly constructed wells. Basalt of the Columbia River Group yields small to moderate quantities of water to wells, and the marine sedimentary rocks and Willamette Silt generally yield small but adequate quantities of water for domestic and stock supplies. Ground water from the Columbia River Group and nonmarine sedimentary rocks is chemically suitable for irrigation and other uses, as is the water from shallow depths in the marine sedimentary rocks. However, water from depths of more than several hundred feet in the marine sedimentary rocks contains large amounts of chloride and other dissolved mineral constitutents that make it unsuitable for most uses. Samples from three fairly closely spaced wells obtaining water from depth zones of 50 to 77, 191 to 201, and about 2,000 feet contained 172, 1,160, and 26,000 ppm (parts per million) of chloride, respectively. About 6,100 acre-feet of ground water was pumped from wells and withdrawn from springs for various uses during 1964; of this amount about 4,800 acre-feet was used for irrigation. The total volume of ground water withdrawn and put to beneficial use each year is small compared with the amount that discharges naturally by evapotranspiration and through undeveloped seeps and springs. Much of the natural discharge could be intercepted and put to beneficial use by pumping from wells. Major problems affecting the development of ground water in the area include a) uneven areal distribution of permeable rocks, (b) undesirable chemical quality of the ground water locally in the marine sedimentary rocks, and (c) fine sand entering wells that tap the Troutdale Formation and thereby causing loss of well efficiency and costly wear on pumps and water-supply systems.

Water Supply Paper↗

USGS2006

Water-Quality Data, 1999-2005, and Ground-Water Level Data, 2004-2005, for McBaine Bottoms, Including the Eagle Bluffs Conservation Area, Columbia, Missouri

The U.S. Geological Survey, in cooperation with the city of Columbia, Missouri, and the Missouri Department of Conservation, collected ground-water quality data from June 1999 through August 2005, surface-water quality data from August 1999 through August 2003, and water-level data from February 2004 through August 2005 in McBaine Bottoms, southwest of Columbia. McBaine Bottoms, adjacent to the Missouri River, is the location of the municipal-supply well field for the city of Columbia, the city of Columbia wastewater-treatment wetlands, and the Missouri Department of Conservation Eagle Bluffs Conservation Area. This report presents water-quality data, which include water-quality analyses of samples collected from 36 water-quality sampling sites (31 were wells and 5 were surface-water sites), and ground-water level data, which include water-level measurements from more than 80 wells. Water samples were analyzed for physical properties, inorganic chemical constituents, nutrients, and dissolved iron. Selected samples were analyzed for trace elements, wastewater organic compounds, and pesticides. In samples from monitoring wells, chloride concentrations ranged from 2.41 to 259 mg/L (milligrams per liter), sodium concentrations ranged from 1.08 to 175 mg/L, and sulfate concentrations ranged from less than 0.2 to 271 mg/L (all concentrations were dissolved). Dissolved nitrite plus nitrate as nitrogen concentrations ranged from less than 0.05 to 0.46 mg/L. Total phosphorous concentrations ranged from less than 0.04 to 1.68 mg/L, dissolved phosphorous concentrations ranged from less than 0.04 to 1.50 mg/L, and dissolved orthophosphorous concentrations ranged from less than 0.01 to 1.83 mg/L. Dissolved iron concentrations ranged from less than 6 to 42,900 g/L (micrograms per liter). Dissolved arsenic concentrations in samples from two monitoring wells ranged from 11 to 37 g/L. In samples from surface-water sampling sites, chloride concentrations ranged from 8.67 to 289 mg/L, sodium concentrations ranged from 6.18 to 219 mg/L, and sulfate concentrations ranged from 33.4 to 119 mg/L. All of the minimum concentrations were detected in samples from Perche Creek. Dissolved nitrite plus nitrate as nitrogen concentrations ranged from less than 0.05 to 1.53 mg/L. Total phosphorous concentrations ranged from 0.07 to 3.06 mg/L, dissolved phosphorous concentrations ranged from less than 0.05 to 2.88 mg/L, and dissolved orthophosphorous concentrations ranged from less than 0.01 to 2.86 mg/L. Most of the maximum concentrations were detected in samples from the city outflow. More than 35 wastewater organic compounds and pesticides were detected in samples from the city outflow. However, most concentrations were estimated or their presence verified, but not quantified. Water levels in monitoring wells ranged from 548.54 to 576.55 ft (feet) above the National Geodetic Vertical Datum of 1929 (NGVD 29). The difference in water levels from February 2004 to August 2005 ranged from 0.13 ft to 10.97 ft.

Data Series↗

USGS2005

Occurrence of selected pharmaceutical and non-pharmaceutical compounds, and stable hydrogen and oxygen isotope ratios, in a riverbank filtration study, Platte River, Nebraska, 2001 to 2003, Volume 1

Although studied extensively in recent years in Europe, the occurrence of endocrine disrupters and other organic wastewater compounds in the environment in the United States is not well documented. To better understand the efficiency of riverbank filtration with respect to endocrine disrupting compounds and to evaluate the use of riverbank filtration as an effective means of drinking-water treatment, a study was conducted during 2001-2003 by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency and the City of Lincoln, at an established riverbank-filtration well field with horizontal collector wells and vertical wells. This study provides information that will be useful for (1) increased understanding of the processes and factors important in controlling the transport of endocrine disrupters, such as pesticides and pharmaceuticals during riverbank filtration, (2) better understanding of the physical and chemical processes that affect riverbank-filtration efficiency, and (3) managing the water resources of the eastern Platte River Basin. This report presents analytical methods and data collected during the study. Data are presented as generalized statistics and in figures showing temporal variations. Sites from which water-quality samples were collected for this study included wastewater sites (a cattle feedlot lagoon, a hog confinement lagoon, and wastewater-treatment plant effluent), surface-water sites (Platte River, Salt Creek, and Loup Power Canal), ground-water sites (one collector well and three vertical wells), and drinking-water sites (raw and finished). Field water-quality properties were measured in samples from these sites. Pharmaceutical compounds were detected often in the wastewater-treatment plant effluent. Surface and ground water showed low-level concentrations of pharmaceuticals. Finished drinking-water samples did not contain detectable concentrations of pharmaceuticals except for low levels of cotinine and caffeine. Antibiotics were found in some of the wastewater samples and twice in Salt Creek. Antibiotics were not detected in any samples from the Platte River or the well field. Surface-water samples were analyzed for total organic carbon and ground-water samples were analyzed for dissolved organic carbon. Samples from all sites were analyzed for major ions. Herbicides commonly detected in surface, ground, and drinking water included acetachlor, alachlor, atrazine, and metolachlor as well as degradates of these compounds. Most of the samples from wastewater sites were found to contain predominantly acetamide degradates. High concentrations of several organic wastewater indicator compounds were detected at the wastewater sites and in Salt Creek. Several organic wastewater indicator compounds were detected multiple times in samples from the Platte River. Bromoform, a by-product of disinfection in the treatment plant, was found in samples from the finished drinking water. Stable hydrogen isotope ratios show a range in seasonal variation of -73.6 per mill to -38.1 per mill relative to Vienna Standard Mean Ocean Water (VSMOW) reference water and -69.2 per mill to -46.5 per mill for surface water and ground water, respectively. Oxygen isotope ratios for surface-water samples varied between -9.86 per mill and -5.05 per mill. Stable oxygen isotope ratios of ground waters varied between -9.62 per mill and -5.81 per mill.

Nebraska↗

USGS2017

U.S. Geological Survey Karst Interest Group Proceedings, San Antonio, Texas, May 16–18, 2017

Introduction and Acknowledgments Karst aquifer systems are present throughout parts of the United States and some of its territories, and have developed in carbonate rocks (primarily limestone and dolomite) and evaporites (gypsum, anhydrite, and halite) that span an interval of time encompassing more than 550 million years. The depositional environments, diagenetic processes, post-depositional tectonic events, and geochemical weathering processes that form karst aquifers are varied and complex. These factors involve biological, chemical, and physical changes that when combined with the diverse climatic regimes in which karst development has taken place, result in the unique dual- or triple-porosity nature of karst aquifers. These complex hydrogeologic systems typically represent challenging and unique conditions to scientists attempting to study groundwater flow and contaminant transport in these terrains. The dissolution of carbonate rocks and the subsequent development of distinct and beautiful landscapes, caverns, and springs have resulted in the most exceptional karst areas being designated as national or state parks. Tens of thousands of similar areas in the United States have been developed into commercial caverns and known privately owned caves. Both public and private properties provide access for scientists to study the flow of groundwater in situ . Likewise, the range and complexity of landforms and groundwater flow systems associated with karst terrains are enormous, perhaps more than for any other aquifer type. Karst aquifers and landscapes that form in tropical areas, such as the cockpit karst along the north coast of Puerto Rico, differ greatly from karst landforms in more arid climates, such as the Edwards Plateau in west-central Texas or the Guadalupe Mountains near Carlsbad, New Mexico, where hypogenic processes have played a major role in speleogenesis. Many of these public and private lands also contain unique flora and fauna associated with these karst hydrogeologic systems. As a result, numerous federal, state, and local agencies have a strong interest in the study of karst terrains. Many of the major springs and aquifers in the United States have developed in carbonate rocks, such as the Floridan aquifer system in Florida and parts of Alabama, Georgia, and South Carolina; the Ozark Plateaus aquifer system in parts of Arkansas, Kansas, Missouri, and Oklahoma; and the Edwards-Trinity aquifer system in west-central Texas. These aquifers, and the springs that discharge from them, serve as major water-supply sources and form unique ecological habitats. Competition for the water resources of karst aquifers is common, and urban development and the lack of attenuation of contaminants in karst areas due to dissolution features that form direct pathways into karst aquifers can impact the ecosystem and water quality associated with these aquifers. The concept for developing a platform for interaction among scientists within the U.S. Geological Survey (USGS) working on karst-related studies evolved from the November 1999 National Groundwater Meeting of the USGS. As a result, the Karst Interest Group (KIG) was formed in 2000. The KIG is a loose-knit, grass-roots organization of USGS and non-USGS scientists and researchers devoted to fostering better communication among scientists working on, or interested in, karst science. The primary mission of the KIG is to encourage and support interdisciplinary collaboration and technology transfer among scientists working in karst areas. Additionally, the KIG encourages collaborative studies between the different mission areas of the USGS as well as with other federal and state agencies, and with researchers from academia and institutes. To accomplish its mission, the KIG has organized a series of workshops that have been held near nationally important karst areas. To date (2017) seven KIG workshops, including the workshop documented in this report, have been held. The workshops typically include oral and poster sessions on selected karst-related topics and research, as well as field trips to local karst areas. To increase non-USGS participation an effort was made for the workshops to be held at a university or institute beginning with the fourth workshop. Proceedings of the workshops are published by the USGS and are available online at the USGS publications warehouse https://pubs.er.usgs.gov/ by using the search term “karst interest group.” The first KIG workshop was held in St. Petersburg, Florida, in 2001, in the vicinity of the large springs and other karst features of the Floridan aquifer system. The second KIG workshop was held in 2002, in Shepherdstown, West Virginia, in proximity to the carbonate aquifers of the northern Shenandoah Valley, and highlighted an invited presentation on karst literature by the late Barry F. Beck of P.E. LaMoreaux and Associates. The third KIG workshop was held in 2005, in Rapid City, South Dakota, near evaporite karst features in limestones of the Madison Group in the Black Hills of South Dakota. The Rapid City KIG workshop included field trips to Wind Cave National Park and Jewel Cave National Monument, and featured a presentation by Thomas Casadevall, then USGS Central Region Director, on the status of Earth science at the USGS. The fourth KIG workshop in 2008 was hosted by the Hoffman Environmental Research Institute and Center for Cave and Karst Studies at Western Kentucky University in Bowling Green, Kentucky, near Mammoth Cave National Park and karst features of the Chester Upland and Pennyroyal Plateau. The workshop featured a late-night field trip into Mammoth Cave led by Rickard Toomey and Rick Olsen, National Park Service. The fifth KIG workshop in 2011 was a joint meeting of the USGS KIG and University of Arkansas HydroDays, hosted by the Department of Geosciences at the University of Arkansas in Fayetteville. The workshop featured an outstanding field trip to the unique karst terrain along the Buffalo National River in the southern Ozarks, and a keynote presentation on paleokarst in the United States was delivered by Art and Peggy Palmer. The sixth KIG workshop was hosted by the National Cave and Karst Research Institute (NCKRI) in 2014, in Carlsbad, New Mexico. George Veni, Director of the NCKRI, served as a co-chair of the workshop with Eve Kuniansky of the USGS. The workshop featured speaker Dr. Penelope Boston, Director of Cave and Karst Studies at New Mexico Tech, Socorro, and Academic Director at the NCKRI, who addressed the future of karst research. The field trip on evaporite karst of the lower Pecos Valley was led by Lewis Land (NCKRI karst hydrologist), and the field trip on the geology of Carlsbad Caverns National Park was led by George Veni. This current seventh KIG workshop is being held in San Antonio at the University of Texas at San Antonio (UTSA). This 2017 workshop is being hosted by the Department of Geological Sciences’ Student Geological Society (SGS), and student chapters of the American Association of Petroleum Geologists (AAPG) and Association of Engineering Geologists (AEG), with support by the UTSA Department of Geological Sciences and Center for Water Research. The UTSA student chapter presidents, Jose Silvestre (SGS), John Cooper (AAPG), and Tyler Mead (AEG) serve as co-chairs of the 2017 workshop with Eve Kuniansky of the USGS. The technical session committee is chaired by Eve Kuniansky, USGS, and includes Michael Bradley, Tom Byl, Rebecca Lambert, John Lane, and James Kaufmann, all USGS, and Patrick Tucci, retired USGS. The logistics committee includes Amy Clark, Yongli Gao, and Lance Lambert (Department Chair), UTSA Department of Geological Sciences; and Ryan Banta and Allan Clark, USGS, San Antonio, Texas. The field trip committee is chaired by Allan Clark and includes Amy Clark, Yongli Gao, and Keith Muehlestein, UTSA; Marcus Gary, Edwards Aquifer Authority and University of Texas at Austin; Ron Green, Southwest Research Institute; Geary Schindel, Edwards Aquifer Authority; and George Veni, NCKRI. Additionally, two organizations have assisted the UTSA student chapters in hosting the meeting by donating funds to the chapters: the Edwards Aquifer Authority, San Antonio, Texas, and the Barton Springs Edwards Aquifer Authority, Austin, Texas. Additionally, Yongli Gao, Center for Water Research and Department of Geological Sciences, UTSA, helped develop sessions on cave and karst research in China for this workshop. These proceedings could not have been accomplished without the assistance of Lawrence E. Spangler as co-editor who not only has subject matter expertise, but also serves as an editor with the USGS Science Publishing Network. We sincerely hope that this workshop continues to promote future collaboration among scientists of varied and diverse backgrounds, and improves our understanding of karst aquifer systems in the United States and its territories. The extended abstracts of USGS authors were peer reviewed and approved for publication by the USGS. Articles submitted by university researchers and other federal and state agencies did not go through the formal USGS peer review and approval process, and therefore may not adhere to USGS editorial standards or stratigraphic nomenclature. However, all articles had a minimum of two peer reviews and were edited for consistency of appearance in the proceedings. The use of trade, firm or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government. The USGS Water Availability and Use Science Program funded the publication costs of the proceedings.

Scientific Investigations Report↗

USGS2014

U.S. Geological Survey Karst Interest Group Proceedings, Carlsbad, New Mexico, April 29-May 2, 2014

Karst aquifer systems are present throughout parts of the United States and some of its territories, and have developed in carbonate rocks (primarily limestone and dolomite) that span an interval of time encompassing more than 550 million years. The depositional environments, diagenetic processes, post-depositional tectonic events, and geochemical weathering processes that form karst aquifers are varied and complex, and involve biological, chemical, and physical changes. These factors, combined with the diverse climatic regimes under which karst development in these rocks has taken place, result in the unique dual- or triple-porosity nature of karst aquifers. These complex hydrogeologic systems typically represent challenging and unique conditions to scientists attempting to study groundwater flow and contaminant transport in these terrains. The dissolution of carbonate rocks and the subsequent development of distinct and beautiful landscapes, caverns, and springs has resulted in the most exceptional karst areas of the United States being designated as national or state parks; commercial caverns and known privately owned caves number in the tens of thousands. Both public and private properties provide access for scientists to study the flow of groundwater in situ. Likewise, the range and complexity of landforms and groundwater flow systems associated with karst terrains are enormous, perhaps more than for any other aquifer type. Karst aquifers and landscapes that form in tropical areas, such as the cockpit karst along the north coast of Puerto Rico, differ greatly from karst landforms in more arid climates, such as the Edwards Plateau in west-central Texas or the Guadalupe Mountains near Carlsbad, New Mexico, where hypogenic processes have played a major role in speleogenesis. Many of these public and private lands also contain unique flora and fauna associated with these karst hydrogeologic systems. As a result, numerous federal, state, and local agencies have a strong interest in the study of karst terrains. Many of the major springs and aquifers in the United States have developed in carbonate rocks, such as the Floridan aquifer system in Florida and parts of Alabama, Georgia, and South Carolina; the Ozark Plateaus aquifer system in parts of Arkansas, Kansas, Missouri, and Oklahoma; and the Edwards-Trinity aquifer system in west-central Texas. These aquifers, and the springs that discharge from them, serve as major water-supply sources and as unique ecological habitats. Competition for the water resources of karst aquifers is common, and urban development and the lack of attenuation of contaminants in karst areas can impact the ecosystem and water quality of these aquifers. The concept for developing a platform for interaction among scientists within the U.S. Geological Survey (USGS) working on karst-related studies evolved from the November 1999 National Ground-Water Meeting of the USGS. As a result, the Karst Interest Group (KIG) was formed in 2000. The KIG is a loose-knit, grass-roots organization of USGS and non-USGS scientists and researchers devoted to fostering better communication among scientists working on, or interested in, karst science. The primary mission of the KIG is to encourage and support interdisciplinary collaboration and technology transfer among scientists working in karst areas. Additionally, the KIG encourages collaborative studies between the different mission areas of the USGS as well as other federal and state agencies, and with researchers from academia and institutes. The KIG also encourages younger scientists by participation of students in the poster and oral sessions. To accomplish its mission, the KIG has organized a series of workshops that are held near nationally important karst areas. To date (2014) six KIG workshops, including the workshop documented in this report, have been held. The workshops typically include oral and poster sessions on selected karst-related topics and research, as well as field trips to local karst features. Proceedings of the workshops are published by the USGS and are available online at http://water.usgs.gov/ogw/karst/kig . The first KIG workshop was held in St. Petersburg, Florida, February 13–16, 2001, in the vicinity of the large springs and other karst features of the Floridan aquifer system. The second KIG workshop was held August 20–22, 2002, in Shepherdstown, West Virginia, in proximity to the carbonate aquifers of the northern Shenandoah Valley and highlighted an invited presentation on karst literature by the late Barry F. Beck of P.E. LaMoreaux and Associates. The third KIG workshop was held September 12–15, 2005, in Rapid City, South Dakota, nearby to karst features in evaporites and limestones of the Madison Group in the Black Hills of South Dakota, including Wind Cave National Park and Jewel Cave National Monument. The workshop also included a featured presentation by Thomas Casadevall, Central Region Director, USGS, on the status of earth science at the USGS and evening trips to Jewel Cave led by Mike Wiles, National Park Service (NPS) and Wind Cave led by Rod Horrocks, NPS. The fourth KIG workshop was held May 27–29, 2008, and hosted by the Hoffman Environmental Research Institute and Center for Cave and Karst Studies at Western Kentucky University in Bowling Green, Kentucky, near Mammoth Cave National Park and karst features of the Chester Upland and Pennyroyal Plateau. The workshop featured a late-night field trip into Mammoth Cave with Rickard Toomey and Rick Olsen, NPS. The fifth workshop was held April 26–29, 2011, and was a joint meeting of the USGS KIG and University of Arkansas HydroDays, hosted by the Department of Geosciences at the University of Arkansas in Fayetteville. The workshop featured an outstanding field trip to the unique karst terrain along the Buffalo National River of the southern Ozarks and a keynote presentation on paleokarst in the United States by Art and Peggy Palmer. This sixth and current 2014 KIG workshop is hosted by the National Cave and Karst Research Institute (NCKRI) in Carlsbad, New Mexico, with Director of NCKRI, George Veni, serving as co-chair of the workshop with Eve Kuniansky, USGS. The session planning committee for this sixth workshop includes Van Brahana, USGS retired and University of Arkansas Professor Emeritus; Tom Byl, USGS and Tennessee State University; Zelda Bailey, former Director of NCKRI and retired Director, National Institute of Standards and Technology, Boulder Laboratory, Colorado; Patrick Tucci, USGS retired; and Mike Bradley, Allan Clark, Geoff Delin, Daniel Doctor, James Kaufmann, Eve Kuniansky, Randy Orndorff, Larry Spangler, and Dave Weary of the USGS. The karst hydrology field trip on Thursday will be led by Lewis Land (NCKRI karst hydrologist) and the optional Friday field trip on the geology of Carlsbad Caverns National Park will be led by George Veni. The keynote speaker is Dr. Penelope Boston, Director of Cave and Karst Studies at New Mexico Tech, Socorro, and Academic Director at NCKRI, who will address the future of karst research. Additionally, there is a featured presentation “Irish karst and its management,” by Caoimhe Hickey, The Geological Survey of Ireland, preceding a panel discussion on “Collaboration During Times of Limited Resources.” The extended abstracts of USGS authors were peer reviewed and approved for publication by the U.S. Geological Survey. Articles submitted by university researchers and other federal and state agencies did not go through the formal USGS peer review and approval process, and therefore may not adhere to our editorial standards or stratigraphic nomenclature and is not research conducted or data collected by the USGS. However, all articles had at a minimum of two peer reviews, and all articles were edited for consistency of appearance in the published Proceedings. The use of trade, firm or product names in any article is for descriptive purposes only and does not imply endorsement by the U.S. Government. The USGS, Office of Groundwater, provides technical support for the Karst Interest Group website and public availability of the Proceedings from these workshops, and the USGS Groundwater Resources Program funds the publication costs. Finally, the cover illustration is the work of Ann Tihansky, USGS, used since the first KIG workshop in 2000.

Scientific Investigations Report↗

USGS2008

Algal and water-quality data for Rapid Creek and Canyon Lake near Rapid City, South Dakota, 2007

This report summarizes the results of algae and water-quality sampling on Rapid Creek and Canyon Lake during May and September 2007. The overall purpose of the study was to determine the algal community composition of Rapid Creek and Canyon Lake in relation to organisms that are known producers of unwanted tastes and odors in drinking-water supplies. Algal assemblage structure (phytoplankton and periphyton) was examined at 16 sites on Rapid Creek and Canyon Lake during May and September 2007, and actinomycetes bacteria were sampled at the Rapid City water treatment plant intake in May 2007, to determine if taste-and-odor producing organisms were present. During the May 2007 sampling, 3 Rapid Creek sites and 4 Canyon Lake sites were quantitatively sampled for phytoplankton in the water column, 7 Rapid Creek sites were quantitatively sampled for attached periphyton, and 4 lake and retention pond sites were qualitatively sampled for periphyton. Five Rapid Creek sites were sampled for geosmin and 2-methylisoborneol, two common taste-and-odor causing compounds known to affect water supplies. During the September 2007 sampling, 4 Rapid Creek sites were quantitatively sampled for attached periphyton, and 3 Canyon Lake sites were qualitatively sampled for periphyton. Water temperature, dissolved oxygen, pH, and specific conductance were measured during each sampling event. Methods of collection and sample analysis are presented for the various types of biological and chemical constituent samples. Diatoms comprised 91-100 percent of the total algal biovolume in periphyton samples collected during May and September. Cyanobacteria (also called blue-green algae) were detected in 7 of the 11 quantitative periphyton samples and ranged from 0.01 to 2.0 percent of the total biovolume. Cyanobacteria were present in 3 of the 7 phytoplankton samples collected in May, but the relative biovolumes were small (0.01-0.2 percent). Six of seven qualitative samples collected from Canyon Lake and retention ponds during May and September also contained cyanobacteria. Geosmin and 2-methylisoborneol concentrations were less than detection limits (0.005 ug/L) in all five of the Rapid Creek samples collected in May. Actinomycetes bacteria were present at the water treatment plant intake in May 2007, at a concentration of 6 colonies per milliliter. During this study, no taste-and-odor problems with the drinking water within the study area were reported. However, the presence of cyanobacterial taxa known to contain taste-and-odor producing strains (such as Leptolyngbya, Phormidium, and Anabaena) indicates the potential for taste-and-odor problems under certain physical and chemical conditions.

South Dakota↗

USGS2015

Hydrogeologic data and water-quality data from a thick unsaturated zone at a proposed wastewater-treatment facility site, Yucca Valley, San Bernardino County, California, 2008-11

The Hi-Desert Water District, in the community of Yucca Valley, California, is considering constructing a wastewater-treatment facility and using the reclaimed water to recharge the aquifer system through surface spreading. The Hi-Desert Water District is concerned with possible effects of this recharge on water quality in the underlying groundwater system; therefore, an unsaturated-zone monitoring site was constructed by the U.S. Geological Survey (USGS) to characterize the unsaturated zone, monitor a pilot-scale recharge test, and, ultimately, to monitor the flow of reclaimed water to the water table once the treatment facility is constructed. In June and July 2008, a borehole (YVUZ-5) was drilled by the USGS through the unsaturated zone in the vicinity of the proposed wastewater-treatment facility site by using an overburden drilling method. In addition to a variety of unsaturated-zone instrumentation, an observation well screened near the water table was installed in the borehole. The drilling procedures, lithologic and geophysical data, construction details, physical properties of unsaturated alluvial deposits, and instrumentation installed in YVUZ-5 are described in this report. Core material was analyzed for bulk-density, porosity, effective porosity, volumetric water content, residual water content, saturation, effective saturation, matric-potential, and saturated hydraulic conductivity. Concentrations of soluble anions, including bromide, chloride, fluoride, sulfate, nitrate, nitrite, phosphate, and orthophosphate, in unsaturated-zone sediment and dissolved in unsaturated-zone water were determined by analyzing water extracted from drill-cutting material. A 0.1-acre pilot-scale infiltration pond was constructed in the vicinity of YVUZ-5. Water was applied to the pond over a period of about 8 months and allowed to infiltrate into the underlying unsaturated zone. Data were collected on chemical and isotopic composition of the groundwater, unsaturated-zone water, and infiltration pond water before, during, and after infiltration of water from the constructed pond. Selected drill cuttings and core samples collected during drilling were analyzed for the presence or absence of denitrifying and nitrate-reducing bacteria. Water levels in the observation well ranged from about 367 to 370 feet below land surface during the period of the study. Measured saturated hydraulic conductivity of core material ranged from 2.1 to 11.0 feet per day. Average vertical infiltration rates in the pilot-scale infiltration pond ranged from 0.7 to 2.4 feet per day. Both denitrifying and nitrate-reducing bacteria were present in drill cutting material in most probable numbers ranging from below detection limits to 2,400,000 for denitrifying and to 93,000 for nitrate-reducing bacteria.

California↗

USGS2008

Selected Water- and Sediment-Quality, Aquatic Biology, and Mine-Waste Data from the Ely Copper Mine Superfund Site, Vershire, VT, 1998-2007

The data contained in this report are a compilation of selected water- and sediment-quality, aquatic biology, and mine-waste data collected at the Ely Copper Mine Superfund site in Vershire, VT, from August 1998 through May 2007. The Ely Copper Mine Superfund site is in eastern, central Vermont (fig. 1) within the Vermont Copper Belt (Hammarstrom and others, 2001). The Ely Copper Mine site was placed on the U.S. Environmental Protection Agency (USEPA) National Priorities List in 2001. Previous investigations conducted at the site documented that the mine is contributing metals and highly acidic waters to local streams (Hammarstrom and others, 2001; Holmes and others, 2002; Piatak and others, 2003, 2004, and 2006). The U.S. Geological Survey (USGS), in cooperation with the USEPA, compiled selected data from previous investigations into uniform datasets that will be used to help characterize the extent of contamination at the mine. The data may be used to determine the magnitude of biological impacts from the contamination and in the development of remediation activities. This report contains analytical data for samples collected from 98 stream locations, 6 pond locations, 21 surface-water seeps, and 29 mine-waste locations. The 98 stream locations are within 3 streams and their tributaries. Ely Brook flows directly through the Ely Copper Mine then into Schoolhouse Brook (fig. 2), which joins the Ompompanoosuc River (fig. 1). The six pond locations are along Ely Brook Tributary 2 (fig. 2). The surface-water seeps and mine-waste locations are near the headwaters of Ely Brook (fig. 2 and fig. 3). The datasets 'Site_Directory' and 'Coordinates' contain specific information about each of the sample locations including stream name, number of meters from the mouth of stream, geographic coordinates, types of samples collected (matrix of sample), and the figure on which the sample location is depicted. Data have been collected at the Ely Copper Mine Superfund site by the USEPA, the Vermont Department of Environmental Conservation (VTDEC), and the USGS. Data also have been collected on behalf of USEPA by the following agencies: Arthur D. Little Incorporated (ADL), U.S. Army Cold Region Research and Engineering Laboratory (CRREL), URS Corporation (URS), USEPA, and USGS. These data provide information about the aquatic communities and their habitats, including chemical analyses of surface water, pore water, sediments, and fish tissue; assessments of macroinvertebrate and fish assemblages; physical characteristics of sediments; and chemical analyses of soil and soil leachate collected in and around the piles of mine waste.

Data Series↗

USGS2015

2013 Survey of Iowa groundwater and evaluation of public well vulnerability classifications for contaminants of emerging concern

Studies in Iowa have long documented the vulnerability of wells with less than 50 feet (15 meters) of confining materials above the source aquifer to contamination from nitrate and various pesticides. Recent studies in Wisconsin have documented the occurrence of viruses in untreated groundwater, even in wells considered to have little vulnerability to contamination from near-surface activities. In addition, sensitive methods have become available for analyses of pharmaceuticals and pesticides. This study represents the first comprehensive examination of contaminants of emerging concern in Iowa’s groundwater conducted to date, and one of the first conducted in the United States. Raw groundwater samples were collected from 66 public supply wells during the spring of 2013, when the state was recovering from drought conditions. Samples were analyzed for 206 chemical and biological parameters; including 20 general water-quality parameters and major ions, 19 metals, 5 nutrients, 10 virus groups, 3 species of pathogenic bacteria, 5 microbial indicators, 108 pharmaceuticals, 35 pesticides and pesticide degradates, and tritium. The wells chosen for this study represent a diverse range of ages, depths, confining material thicknesses, pumping rates, and land use settings. The most commonly detected contaminant group was pesticide compounds, which were present in 41% of the samples. As many as 6 pesticide compounds were found together in a sample, most of which were chloroacetanilide degradates. While none of the measured concentrations of pesticide compounds exceeded current benchmark levels, several of these compounds are listed on the U.S. Environmental Protection Agency’s Contaminant Candidate List and could be subject to drinking water standards in the future. Despite heavy use in the past decade, glyphosate was not detected, and its metabolite, aminomethylphosphonic acid, was only detected in two of 60 wells tested (3%) at the detection limit of 0.02 μg/L. Pharmaceutical compounds were detected in 35% of 63 samples. Of the 14 pharmaceuticals detected, six had reported concentrations above the method reporting limit, with the maximum reported concentration of 826 ng/L for acetaminophen. Diphenhydramine was the only pharmaceutical to have two detections above the reporting limit, at 24.5 and 145 ng/L. Eight pharmaceuticals had confirmed detections at concentrations below the method reporting limit. Caffeine was the most frequently detected pharmaceutical compound (25%), followed by the caffeine metabolite, 1,7- dimethylxanthine (16%). Microorganisms were detected in 21% of the wells using quantitative polymerase chain reaction methodologies. The most frequently detected microorganism was the pepper mild mottle virus (PMMV), a plant pathogen found in human waste. PMMV was detected in 17% of samples at concentrations ranging from 0.4 to 6.38 gene copies per liter. GII norovirus, human polyomavirus, bovine polyomavirus, and Campylobacter were also detected, while adenovirus, enterovirus, GI norovirus, swine hepatitis E, Salmonella, and enterohemmorhagic E. coli were not detected. No correlations were found between viruses or pathogenic bacteria and microbial indicators. Wells with less than 50 feet (15 meters) of confining material were shown to have greater incidence of surface-related contaminants; however, significant relationships (p<0.05) between confining layer thickness and contaminants were only found for nitrate and herbicides.

Iowa↗