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Invited perspectives: Integrating hydrologic information into the next generation of landslide early warning systems

Although rainfall-triggered landslides are initiated by subsurface hydro-mechanical processes related to the loading, weakening, and eventual failure of slope materials, most landslide early warning systems (LEWS) have relied solely on rainfall event information. In previous decades, several studies demonstrated the value of integrating proxies for subsurface hydrologic information to improve rainfall-based forecasting of shallow landslides. More recently, broader access to commercial sensors and telemetry for real-time data transmission has invigorated new research into hydrometeorological thresholds for LEWS. Given the increasing number of studies across the globe using hydrologic monitoring, mathematical modeling, or both in combination, it is now possible to make some insights into the advantages versus limitations of this approach. The extensive progress demonstrates the value of in situ hydrologic information for reducing both failed and false alarms, through the ability to characterize infiltration during, as well as the drainage and drying processes between major storm events. There are also some areas for caution surrounding the long-term sustainability of subsurface monitoring in landslide-prone terrain, as well as unresolved questions in hillslope hydrologic modeling, which relies heavily on the assumptions of diffuse flow and vertical infiltration but often ignores preferential flow and lateral drainage. Here, we share a collective perspective based on our previous collaborative work across Europe, North America, Africa, and Asia to discuss these challenges and provide some guidelines for integrating knowledge of hydrology and climate into the next generation of LEWS. We propose that the greatest opportunity for improvement is through a measure-and-model approach to develop an understanding of landslide hydro-climatology that accounts for local controls on subsurface storage dynamics. Additionally, new efforts focused on the subsurface hydrology are complementary to existing rainfall-based methods, so leveraging these with near-term precipitation forecasts is a priority for increasing lead times.

Alaska

Spatio-temporal modeling for assessing geoenergy resources: A workflow applied to gas in place variation in coal beds

The ability to estimate spatio-temporal changes in hydrocarbon reservoir properties and energy resources within pore volumes is essential for optimizing production, reservoir management, geologic energy storage, and safety in underground mining operations. In coal seams, predicting remaining methane gas-in-place (GIP) is critical for quantifying producible gas and improving mine safety and productivity through effective ventilation planning. Although such changes are commonly evaluated using physics-based numerical simulation models, these approaches often require extensive data, calibration effort, and time. This study presents a spatio-temporal geostatistical modeling approach that bridges the gap between purely spatial models and full numerical simulations. The method is applied to a case study of coal seam degasification in the Mary Lee coal group, Black Warrior Basin, Alabama, USA, to estimate GIP evolution over time within a selected mining district. The analysis uses published data from prior natural gas production history-matching of degasification using vertical wells. Empirical spatial and temporal statistics were calculated for reservoir pressure and water saturation, and spatio-temporal variogram models were fitted to experimental variograms. These models provided the structural basis for spatio-temporal kriging, integrated with spatial estimates of time-invariant parameters (porosity, density, and thickness) to estimate GIP. This approach enabled estimation of GIP changes over time, including periods without data. Boxplots of GIP estimates indicated systematic depletion and decreasing spatial variability, reflecting the impacts of degasification. Comparison with cumulative gas production from empirical well records showed approximately 85% agreement based on a relative similarity metric. Spatio-temporal GIP estimates were also used to estimate methane emissions to longwall ventilation systems and compared with reported emissions from the U.S. EPA Greenhouse Gas Reporting Program, showing similar distributions (≈80%) given data limitations. Overall, this integrated modeling approach provides time-dependent GIP estimates with broader implications for resource assessment applications.

Alabama

Evaluating groundwater quality influences from oil field operations and other anthropogenic activities in an urban setting, Santa Fe Springs, California

Groundwater quality is often affected by anthropogenic activities in urban settings. This study examines groundwater quality in and around the Santa Fe Springs Oil Field in Los Angeles County, California, where oil and gas production commonly intersects with high density industrial, commercial and residential land uses. Utilizing a combination of new and historical data, we evaluated potential pathways that would allow for oil field formation fluids to migrate into groundwater and whether mixing may have occurred based on the distribution of groundwater and oil field formation fluid tracers in samples. Samples were analyzed for a wide array of constituents including volatile organic compounds, light hydrocarbons, major ions, and various isotopic compositions. Despite evidence of oil field infrastructure providing potential pathways of migration via uncemented annular spaces, casing breaches and historical disposal of oil field formation water in surface ponds, the distribution and occurrence of stable isotopes of water, chloride, boron, and total dissolved solids do not indicate mixing of oil field formation water and groundwater. However, methane isotopic signatures and the presence of heavier alkanes suggest gas from oil-bearing formations have migrated from depth via oil field well infrastructure. Volatile organic compound detections were mainly from manufactured compounds unrelated to oil and gas production, with a relatively limited number of petroleum hydrocarbons also detected. Volatile organic compounds were generally found in wells tapping shallow, modern aged groundwater, indicating anthropogenic activities occurring at or near land surface as the source. Study results suggest that while oil field infrastructure provides migration pathways for oil field formation fluids to be introduced into groundwater, urban land uses not related to oil and gas production are the primary drivers of groundwater quality degradation.

California

Assessing nonpoint-source uranium pollution in an irrigated stream-aquifer system

Uranium (U) in rocks and soils of arid and semi-arid environments can be mobilized by irrigation and fertilization, posing environmental and health risks. Elevated U, along with selenium (Se) and nitrate (NO 3 ) co-constituents, necessitates careful monitoring and management. We developed a distributed-parameter numerical model to assess U pollution in an irrigated stream-aquifer system, applying it to a 552 km 2 region in Colorado's Lower Arkansas River Valley (LARV) over 14 years. A MODFLOW model, describing groundwater and stream flow, was coupled with an RT3D-OTIS model to portray reactive U transport. Calibration using the PESTPP-iES iterative ensemble smoother (iES) software indicated good agreement with observed U concentrations. The model revealed substantial and variable U levels across the LARV, highlighting potential hotspots and possible contributing factors, such as geological composition of the bedrock and near-surface shale and aquifer sediments derived from them, irrigation practices, and riparian landscape. U levels exceed the chronic standard (85th percentile = 30 μg/L, set by the US Environmental Protection Agency), which is the permissible regulatory threshold, in groundwater across 44 % of the region and along the river by an average factor of 2.9. Simulated average U concentrations in the non-riparian aquifer and river are 124 μg/L and 60 μg/L, respectively, compared with 112 μg/L and 62 μg/L for measured values. The average 85th percentile U concentration is 222 μg/L in the aquifer and 82 μg/L in the river. Average simulated U mass loading to the river is 0.17 kg/day per km, compared to an estimated 0.23 kg/day per km. Findings provide a baseline for comparing future simulated outcomes of alternative best management practices (BMPs) for U pollution mitigation and offer a methodology applicable to other irrigated regions.

Colorado

U.S. Geological Survey Integrated Water Availability Assessment—2010–20

This professional paper is a multichapter report that assesses water availability in the United States for water years 2010–20. This work was conducted as part of the fulfillment of the mandates of Subtitle F of the Omnibus Public Land Management Act of 2009 (Public Law 111-11), also known as the SECURE Water Act. As such, this work examines the spatial and temporal distribution of water quantity and quality in surface water and groundwater, as related to human and ecosystem needs and as affected by human and natural influences. Chapter A introduces the National Integrated Water Availability Assessment and provides important background and definitions for how the report characterizes water availability and its components. Chapter A also presents the key findings of Chapters B–F and thus acts as a summary of the entire report. Chapter B is a national assessment of water supply, which is the quantity of water supplied through climatic inputs. Chapter C is a national assessment of water quality, which is the chemical and physical characteristics of water. Chapter D assesses water use including withdrawals and consumptive use in the conterminous United States. Chapter E presents an analysis of factors affecting future water availability under changing climate conditions. The National Integrated Water Availability Assessment culminates with Chapter F, which is an integrated assessment of water availability that considers the amount and quality of water coupled with the suitability of that water for specific uses. Together, these six chapters constitute the National Integrated Water Availability Assessment for water years 2010–20.

Professional Paper

Global variability of the composition and temperature at the 410-km discontinuity from receiver function analysis of dense arrays

Seismic boundaries caused by phase transitions between olivine polymorphs in Earth's mantle provide thermal and compositional markers that inform mantle dynamics. Seismic studies of the mantle transition zone often use either global averaging with sparse arrays or regional sampling from a single dense array. The intermediate approach of this study utilizes many densely spaced seismic arrays distributed around the globe. We systematically compute teleseismic P-to-S receiver functions for each seismic array and invert for the 1-D seismic velocity structure of the mantle transition zone beneath each array to facilitate a comparison between densely sampled regions. We stack 3,600 receiver functions on average at 67 arrays in total. The stack is used in a probabilistic inversion to estimate the mantle transition zone interface depths and velocities beneath each array. We focus on the 410-km discontinuity (410) because it is a prominent seismic interface that is clearly linked to a single mineral phase transition between olivine and wadsleyite. The depths and velocity contrasts of the 410 are mapped to temperatures and compositions using mineral physics constraints. The depth of the 410 ranges from ∼405–440 km, which is consistent with a ∼360 K temperature range in a dry mantle and a ∼260 K temperature range in a wet mantle (2 wt. % water). The Vs contrast across the 410 ranges from ∼2.5–8 %, which is consistent with ∼20–70 vol. % olivine composition in a dry mantle and ∼25–80 vol. % in a wet mantle. The bulk composition of the upper mantle near the 410-km discontinuity is typically considered to be well-mixed because there is no thermodynamic impediment to convection at the olivine to wadsleyite phase transition. However, the wide range of inferred olivine content from our study suggests that there are large lateral variations in the bulk composition of the upper mantle near the 410-km discontinuity.

Earth and Planetary Science Letters

Produced water geochemistry from hydraulically stimulated Niobrara Formation petroleum wells: Origin of salinity and temporal perspectives on treatment and reuse

Produced water (i.e., a mixture of returned injection fluids and geologic formation brines) represents the largest volumetric waste stream associated with petroleum production in the United States. As such, produced water has been the focus of intense study with emphasis on understanding the geologic origin of the fluids, environmental impacts of unintended or intentional release, disposal concerns, and their commodity (e.g., lithium) potential. However, produced water geochemistry from many active petroleum plays remain poorly constrained leading to knowledge gaps associated with the origin of brine salinity and parameters (e.g., radium levels) that can impact treatment, disposal, and possible reuse. Here we evaluate the major ion geochemistry, radium concentrations, and stable water isotope composition of ~120 produced water samples collected from 17 producing unconventional petroleum wells in Weld County, Colorado from the Late Cretaceous Niobrara Formation. This sample set encompasses eight produced water time series from four new wells across production days 0 to ~365 and from four established wells across production days ~1000 to ~1700. Additionally, produced water from nine other established Niobrara Formation wells were sampled at discrete time points ranging from day 458 to day 2256, as well as hydraulic fracturing input fluids. These results expand the available Niobrara Formation produced water geochemical data, previously limited to few wells sampled within the first year of production, allowing for the heterogeneity of major ions and radium to be evaluated. Furthermore, we explore the geochemical relationships between major ion ratios and stable water isotope composition to understand the origin of salinity in Niobrara Formation brines from the Denver-Julesburg Basin. These findings are discussed with perspective toward potential treatment and reuse of Niobrara produced water prior to disposal.

Colorado, Nebraska, Wyoming

System characterization report on the Environmental Mapping and Analysis Program (EnMAP)

This report addresses system characterization of the Environmental Mapping and Analysis Program hyperspectral sensor by the DLR (German Aerospace Center, ground segment project management), GFZ (Deutsches Geoforschungszentrum, science lead) and is part of a series of system characterization reports produced and delivered by the U.S. Geological Survey Earth Resources Observation and Science Cal/Val Center of Excellence. These reports present and detail the methodology and procedures for characterization; present technical and operational information about the EnMAP hyperspectral sensor; and provide a summary of test measurements, data retention practices, data analysis results, and conclusions. The Earth Resources Observation and Science Cal/Val Center of Excellence system characterization team completed data analyses to characterize the geometric (interior and exterior), and radiometric performances of the EnMAP hyperspectral sensor. Results of these analyses indicate that the Environmental Mapping and Analysis Program has a band-to-band geometric performance in the range of −0.135 to 0.15 pixel, geometric performance relative to the Operational Land Imager in the range of −27.716 meters (−0.92 pixel) to 32.892 meters (1.09 pixels) offset in comparison to Landsat 8 Operational Land Imager, offset of a radiometric comparison in the range of −0.012 to 0.020, slope of a radiometric comparison in the range of 0.947 to 1.031.

Open-File Report

Potentially toxic elements in wild Agassiz’s desert tortoises: Tissue concentrations and association with disease

Background: Desert tortoise ( Gopherus agassizii ) populations have continued to decline due to infectious and other diseases, predation, and habitat alteration. The potential contribution of minerals and heavy metals to tortoise health and susceptibility to disease remains uncertain. Objective: The objective of this study was to evaluate the results of elemental analysis of trace minerals and macrominerals in scute keratin, kidney, and liver tissue from ill and dying desert tortoises salvaged for necropsy between 1993 and 2000. Methods: Salvaged tortoises were categorized by age (adult, juvenile), geographic location, and primary disease based on necropsy findings. A subset of tortoises that were injured or killed by vehicular trauma or predation but with no notable pathologic abnormalities were used as controls. A panel of 21 trace minerals and 6 macrominerals was analyzed in scute keratin, kidney, and liver tissue samples by inductively-coupled plasma spectrometry and atomic absorption spectrophotometry. Results: Necropsies were done on 46 tortoises, including 9 juveniles salvaged from 5 regions in the Colorado and Mojave deserts of California. Primary diseases were cutaneous dyskeratosis (n=9), infection/ inflammation (n=8), malnutrition (n=7), mycoplasmosis (n=5), and urolithiasis (n=3); 14 tortoises were classified as controls. Concentrations of elements differed significantly by tissue, age, desert region, and disease (P < 0.05). Tortoises with cutaneous dyskeratosis had significantly higher Se concentrations, primarily in keratin and liver, than tortoises with other diseases (P < 0.001). Juveniles were more likely than adults to have high Pb, Sn, and Zn levels (P < 0.05). All tortoises had detectable levels of more than one potentially toxic heavy metal, including As, Cd, Cr, Hg, Ni, Pb, Sn and V. Conclusions: Potentially toxic elements are frequently found in tissue from tortoises in desert regions of California, with significantly higher concentrations in diseased tortoises. Metal exposure from soils, mining, historic and ongoing military activities, and other human activities could increase susceptibility to disease in desert tortoises.

California

Importance of fish in the diet of Adélie penguins across multiple life stages

Over recent decades, the Adélie penguin ( Pygoscelis adeliae ) population has grown across most of its range, the exception being the northern coast of the western Antarctic Peninsula (WAP). In the Ross Sea, the very large Cape Crozier colony grew to reach ~9% of the global population. Demographic factors driving the Cape Crozier trend have yet to be identified. However, low chick fledging mass - a negative influence in the northern WAP where the diet is mostly less-energy-dense krill - is not showing an effect in the Cape Crozier colony. Previously, we hypothesized that Cape Crozier fledglings, and post-breeding adults, must be finding sufficient higher-quality prey once free of the prey-depleted colony foraging area, with subsequent higher survival. Here we explore penguin diet within and outside the colony foraging area using stable isotope analysis (SIA) of feathers: those grown by post-breeding adults outside the foraging area, prior to moult, compared to those of near-fledged chicks raised on meals obtained within the foraging area. Second, we explore whether a major difference occurs between breeding and post-breeding diet of adults from a small, nearby colony (Cape Royds) that exploits a smaller, little-depleted preyscape. Finally, we compare the results to SIA analyses published by others to explore whether the pre-moult diet of Ross Island adults, mostly foraging within the north-eastern Ross Sea, compares with that of adults nesting in the southern WAP (Bellingshausen Sea coast). At the latter, populations are not decreasing, with diet containing an appreciable contribution of fish. The results confirmed that fish contributed greatly to chick diets at both Ross Island colonies (δ 15 N 10.6–11.4). Once adults were released from central-place foraging, SIA levels (δ 15 N 9.7–12.9) were similar to those of the southern WAP. Foraging on energy-dense fish in coastal Antarctic waters could be one reason Adélie penguins are among the most abundant and therefore most ecologically successful penguin species.

Antarctic Science

The Europa Imaging System (EIS) investigation

The Europa Imaging System (EIS) consists of a Narrow-Angle Camera (NAC) and a Wide-Angle Camera (WAC) that are designed to work together to address high-priority science objectives regarding Europa’s geology, composition, and the nature of its ice shell. EIS accommodates variable geometry and illumination during rapid, low-altitude flybys with both framing and pushbroom imaging capability using rapid-readout, 8-megapixel (4k × 2k) detectors. Color observations are acquired using pushbroom imaging with up to six broadband filters. The data processing units (DPUs) perform digital time delay integration (TDI) to enhance signal-to-noise ratios and use readout strategies to measure and correct spacecraft jitter. The NAC has a 2.3° × 1.2° field of view (FOV) with a 10-μrad instantaneous FOV (IFOV), thus achieving 0.5-m pixel scale over a swath that is 2 km wide and several km long from a range of 50 km. The NAC is mounted on a 2-axis gimbal, ±30° cross- and along-track, that enables independent targeting and near-global (≥90%) mapping of Europa at ≤100-m pixel scale (to date, only ∼15% of Europa has been imaged at ≤900 m/pixel), as well as stereo imaging from as close as 50-km altitude to generate digital terrain models (DTMs) with ≤4-m ground sample distance (GSD) and ≤0.5-m vertical precision. The NAC will also perform observations at long range to search for potential erupting plumes, achieving 10-km pixel scale at a distance of one million kilometers. The WAC has a 48° × 24° FOV with a 218-μrad IFOV, achieving 11-m pixel scale at the center of a 44-km-wide swath from a range of 50 km, and generating DTMs with 32-m GSD and ≤4-m vertical precision. The WAC is designed to acquire three-line pushbroom stereo and color swaths along flyby ground-tracks.

Space Science Reviews

Water-quality assessment of south-central Texas: Occurrence and distribution of volatile organic compounds in surface water and ground water, 1983-94, and implications for future monitoring

The study area of the South-Central Texas study unit of the National Water-Quality Assessment Program comprises the Edwards aquifer in the San Antonio region and its catchment area. The first phase of the assessment includes evaluation of existing water-quality data for surface water and ground water, including volatile organic compounds, to determine the scope of planned monitoring. Most analyses of volatile organic compounds in surface water are from the National Pollutant Discharge Elimination System sites in San Antonio, Texas. Nine volatile organic compounds were detected at the six sites. The three compounds with the most detections at National Pollutant Discharge Elimination System sites are 1,2,4-trimethylbenzene, toluene, and xylene. Analysis of volatile organic compounds in ground water was limited to Edwards aquifer wells. Twenty-eight volatile organic compounds were detected in samples from 89 wells. The five most commonly detected compounds in samples from wells, in descending order, are tetrachloroethene, trichloroethene, bromoform, chloroform, and dibromochloromethane. Detections of volatile organic compounds in surface water and ground water within the South-Central Texas study area are limited to site-specific sources associated with development; therefore, planned monitoring for possible detections of volatile organic compounds as part of the National Water-Quality Assessment Program will emphasize areas of expanding population and development. Monitoring of volatile organic compounds is planned at National Pollutant Discharge Elimination System sites, at basic fixed surface-water sites, and in the ground-water study-unit surveys.

Texas

Groundwater flowpath characteristics drive variability in per- and polyfluoroalkyl substances (PFAS) loading across a stream-wetland system

Groundwater-dependent ecosystems in areas with industrial land use are at risk of exposure to a PFAS chemicals. We investigated one such system with several known PFAS source areas, where high and low permeability sediments (glacial) coupled with groundwater-lake and groundwater/surface-water interactions created complex ‘source to seep’ dynamics. Using heat-tracing and chemical methods, numerous preferential groundwater discharge zones were identified and sampled across the upper Quashnet River stream-wetland system in Mashpee, MA, USA, downgradient of Joint Base Cape Cod (JBCC). Surface-water and groundwater samples were analyzed for 40 PFAS compounds between March and October 2022. Samples were collected from groundwater seeps identified as preferential discharge points (PDPs), wells upgradient of the stream-wetland system, contributing flow-through kettle lakes, and along Quashnet River surface-waters. PFAS from sampled waters contained perfluorinated carboxylates (PFPea, PFHxA, PFNA), perfluorinated sulfonates (PFBS, PFPeS, PFHxS, PFOS), fluorotelomer sulfonates (6:2, 8:2 FtS), and perfluoroalkyl sulfonamides (PFOSA). Samples from PDPs and wells had measured PFAS concentrations ranging from non-detect to 4677 ng/L ng/L (mean = 418 ng/L, std. = 709 ng/L), and a range of deuterium excess values (3.2 to 15.9 per mil) indicative of varying degrees of groundwater-lake interaction prior to groundwater flowpath emergence at PDPs. Correlations ( p < 0.01) between deuterium excess, %PFAS precursors, and terminal PFAS compounds highlighted potential precursor transformations associated with lake-groundwater exchange along flowpaths sourcing PDPs. However, some seepages had higher total PFAS concentrations (>1000 ng/L) than upgradient kettle lakes despite showing lake (evaporative) isotopic signatures, indicating the potential for groundwater flowpath convergence at wetland discharge zones and the influence of lakebed PFAS precursor reactions. Results from these synoptic surveys address gaps in the existing PFAS literature by demonstrating the importance of subsurface fate and transport on PFAS compound concentrations and mass loading in preferential groundwater discharge zones.

Massachusetts

Repeated coral bleaching events have eroded reef accretion potential in the Florida Keys

Coral bleaching is now the primary driver of coral-reef degradation globally, threatening the persistence of coral-reef functions and the invaluable ecosystem services they support. The Florida Keys have been impacted by four severe, regional-scale coral-bleaching events, which occurred in 1997–1998, 2005, 2014–2015, and 2023. Our aim in this study was to quantify the effects of those thermal-stress events on the persistence of coral-reef structures. We leveraged long-term coral-reef monitoring data to quantify the impacts of coral bleaching on coral cover, carbonate production, and reef-accretion potential throughout the Florida Keys from 1996–2024. Our study indicates that coral bleaching drove significant declines of reef-building corals, which successively diminished regional-scale reef-accretion potential (from 1.65 ± 0.33 mm y -1 in 1996) and culminated with a regional-scale transition to net reef erosion (-0.12 ± 0.08 mm y -1 ) following the 2023 event. Coral bleaching was the primary driver of declining reef-building capacity, with the cumulative impacts of the four coral-bleaching events accounting for >75% of total declines since 1996. The 1997–1998 event alone drove ~50% of overall declines, largely due to losses of the shallow-water ecosystem engineer, Acropora palmata . More moderate impacts of thermal stress on regional reef-accretion potential in 2005 (6%) and 2014–2015 (9%) could lend some support to the hypothesis that the remaining corals were more thermally tolerant; however, the unprecedented thermal stress event in 2023 caused widespread coral-bleaching and bleaching-related mortality, and caused an additional 12% of the total decline in reef-accretion potential. Stony-coral tissue loss disease accounted for an additional 6% of the decline, with the remaining 19% unexplained. Coral bleaching has already dramatically reshaped the structure and function of coral reefs in the Florida Keys over the last three decades. With the high likelihood that thermal stress will accelerate moving forward, the persistence of Florida’s essential coral-reef functions and services is uncertain.

Florida

Bottom-up characterization of geologic methane emissions in the San Juan Basin in the southwestern USA

Methane is a potent greenhouse gas that plays an important role in atmospheric chemistry and global warming. The current global methane budget has large uncertainties, and a better understanding of the budget would help to guide strategies for reducing anthropogenic emissions to fight climate change. Natural geologic methane emissions are a particularly poorly constrained source, with top-down estimates from 14 C in ice cores suggesting much lower geologic emissions than bottom-up scaling of direct flux measurements. Our study aims to contribute to resolving this discrepancy through improved bottom-up characterization of geologic methane seepage in the San Juan Basin in southwestern Colorado and northwestern New Mexico, USA. We performed 983 new flux chamber measurements in this basin during summer 2022 and winter 2023 field campaigns. Our results, in combination with prior measurements, suggest that natural seepage in the San Juan Basin only occurs on or near the Fruitland coal outcrop. Specifically, our new measurements confirm previous measurements of seepage along the northwestern exposure of the Fruitland outcrop in Colorado (a known hydrodynamic overpressure region) and for the first time, identified seepage locations along the southernmost Fruitland outcrop exposure in New Mexico, in association with a coal cleat and a fault. Overall, seepage along the Fruitland coal outcrop is heterogeneously distributed, with both positive and negative (interpreted as microbial soil sink) methane fluxes. Features that are hypothesized to be predictive of seepage (e.g., faults) were not associated with positive methane fluxes in areas outside of the Fruitland outcrop. Our best estimate for total geologic methane seepage in the San Juan Basin from spatial interpolation and statistical upscaling is approximately 0.14 Tg CH 4 /yr, with a range from 0.029 to 0.48 Tg CH 4 /yr. This best-estimate value is lower than a previous bottom-up estimate from a gridded seepage inventory, but higher than a previous top-down estimate.

Colorado, New Mexico

Submarine groundwater discharge creates cold‐water refugia that can mitigate exposure of heat stress in nearshore corals

Coral reef mortality around the world is accelerating due to human activities and rising sea temperatures that cause bleaching, which is expected to become more frequent. Our ability to predict which corals will be most resilient, however, remains limited due to insufficient information characterizing nearshore temperature and habitat conditions. In this study, we examine how submarine groundwater discharge (SGD) reduces nearshore water temperatures and exposure of corals to heat stress, complementing the understanding that SGD can adversely affect coral when it contains elevated nutrient concentrations. Data from fixed nearshore sensors and vertical depth profiles along ~100 km of the western shoreline of the Island of Hawai’i from 2003 to 2014 demonstrate that submarine groundwater discharge (SGD) can reduce nearshore water temperatures by 1 °C–5°C and create estuarine-like conditions with salinities as low as 20 PSU, where the prevalent coral species, Pocillopora meandrina, Porites lobata , and Montipora capitata , thrive. Time-series temperature records reveal that exposure to high ambient ocean temperatures, which are known to initiate bleaching events, are reduced up to 5%–46% of the time. Coral health surveys indicated coral bleaching in response to moderately high annual temperatures in 2010 and 2011, with more colonies affected farther from cold, SGD-fed waters. Synthesis of these results, along with coral response data following the more extreme marine heat wave of 2014–2015, demonstrates lower coral loss and greater coral recovery near groundwater seeps, particularly those with higher flux and influence on reducing nearshore water temperatures. Our results demonstrate that SGD may therefore provide a beneficial ecosystem service and enhance coral reef resilience, particularly where human-related nutrient additions to groundwater can be mitigated. The implications of our findings are relevant across tropical coasts where groundwater inputs can be substantial, such as the Caribbean and Indo-Pacific, and contribute to improving our understanding of coral sensitivity to gradients in temperature and nutrient stress. Improved management of groundwater resources could thus be vital to local–regional strategies for mitigating future heat stress.

Hawaii

Sedimentological and geochemical characterization of lacustrine deposits of the Babouri-Figuil basin, northern Cameroon: Implications for source rocks distribution and petroleum exploration

The West and Central African Rift System (WCARS) refers to the series of Cretaceous rift basins where commercial hydrocarbon accumulations have been discovered. Some of the WCARS frontier basins are currently being investigated to increase our understanding of these basins in light of new commercial discoveries. The present study was performed in the Babouri-Figuil Basin (BFB), which is genetically related to the WCARS and constitutes an area of interest in terms of petroleum prospecting, where the distribution of petroleum source rocks and potential targets for petroleum exploration across the entire basin is poorly understood. For the current study, an integrated facies analysis along with organic and inorganic geochemical techniques were applied to the basin's Cretaceous deposits with the aim of reconstructing the paleodepositional environment, assessing factors that triggered the input of organic matter, and providing a spatial overview of the organic matter accumulation in the basin based on outcrop samples. An alluvial fan-lacustrine-braided river system is inferred from the facies analysis of the stratigraphic sequence consisting of conglomerate, sandstone, siltstone, limestone, marlstone, and claystone. Bulk analysis of organic matter reveals that black shale and massive claystone are the main prospective petroleum source rocks in the basin. Inorganic geochemical analyses reveal the influence of anoxic conditions, moderate to high primary productivity, and low terrigenous inputs in organic matter enrichment. The formations rich in organic matter are predominantly concentrated in the western and eastern parts of the basin which may represent areas with depressions, characterized by high accommodation space. In terms of the regional context of the WCARS rift basins, typical hydrocarbon exploration in the BFB may target basal-conglomerate, sandstone beds situated directly above or/and interbedded with the Lower Cretaceous source rocks, and the Upper Cretaceous sandstone beds. Basement rocks (granite, granodiorite, and gneisses) and oil shale deposits may represent potential unconventional hydrocarbon exploration. The current integrated study provides an insight that should guide future hydrocarbon exploration campaigns in the basin.

Babouri-Figuil basin

A benchmark dataset and workflow for landslide susceptibility zonation

Landslide susceptibility shows the spatial likelihood of landslide occurrence in a specific geographical area and is a relevant tool for mitigating the impact of landslides worldwide. As such, it is the subject of countless scientific studies. Many methods exist for generating a susceptibility map, mostly falling under the definition of statistical or machine learning. These models try to solve a classification problem: given a collection of spatial variables, and their combination associated with landslide presence or absence, a model should be trained, tested to reproduce the target outcome, and eventually applied to unseen data. Contrary to many fields of science that use machine learning for specific tasks, no reference data exist to assess the performance of a given method for landslide susceptibility. Here, we propose a benchmark dataset consisting of 7360 slope units encompassing an area of about 4,100 km 2 "> 4,100 km 2 in Central Italy. Using the dataset, we tried to answer two open questions in landslide research: (1) what effect does the human variability have in creating susceptibility models; (2) how can we develop a reproducible workflow for allowing meaningful model comparisons within the landslide susceptibility research community. With these questions in mind, we released a preliminary version of the dataset, along with a “call for collaboration,” aimed at collecting different calculations using the proposed data, and leaving the freedom of implementation to the respondents. Contributions were different in many respects, including classification methods, use of predictors, implementation of training/validation, and performance assessment. That feedback suggested refining the initial dataset, and constraining the implementation workflow. This resulted in a final benchmark dataset and landslide susceptibility maps obtained with many classification methods. Values of area under the receiver operating characteristic curve obtained with the final benchmark dataset were rather similar, as an effect of constraints on training, cross–validation, and use of data. Brier score results show larger variability, instead, ascribed to different model predictive abilities. Correlation plots show similarities between results of different methods applied by the same group, ascribed to a residual implementation dependence. We stress that the experiment did not intend to select the “best” method but only to establish a first benchmark dataset and workflow, that may be useful as a standard reference for calculations by other scholars. The experiment, to our knowledge, is the first of its kind for landslide susceptibility modeling. The data and workflow presented here comparatively assess the performance of independent methods for landslide susceptibility and we suggest the benchmark approach as a best practice for quantitative research in geosciences.

Earth-Science Reviews