Geology ReportsSearch

SEARCH · Geology Reports

Results for “Mineralogy and Petrology”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 235 records · Page 13Linked to original sources

The Novarupta-Katmai eruption of 1912 - largest eruption of the twentieth century; centennial perspectives

The explosive outburst at Novarupta (Alaska) in June 1912 was the 20th century's most voluminous volcanic eruption. Marking its centennial, we illustrate and document the complex eruptive sequence, which was long misattributed to nearby Mount Katmai, and how its deposits have provided key insights about volcanic and magmatic processes. It was one of the few historical eruptions to produce a collapsed caldera, voluminous high-silica rhyolite, wide compositional zonation (51-78 percent SiO 2 ), banded pumice, welded tuff, and an aerosol/dust veil that depressed global temperature measurably. It emplaced a series of ash flows that filled what became the Valley of Ten Thousand Smokes, sustaining high-temperature metal-transporting fumaroles for a decade. Three explosive episodes spanned ~60 hours, depositing ~17 km 3 of fallout and 11±2 km 3 of ignimbrite, together representing ~13.5 km 3 of zoned magma. No observers were nearby and no aircraft were in Alaska, and so the eruption narrative was assembled from scattered villages and ship reports. Because volcanology was in its infancy and the early investigations (1915-23) were conducted under arduous expeditionary conditions, many provocative misapprehensions attended reports based on those studies. Fieldwork at Katmai was not resumed until 1953, but, since then, global advances in physical volcanology and chemical petrology have gone hand in hand with studies of the 1912 deposits, clarifying the sequence of events and processes and turning the eruption into one of the best studied in the world. To provide perspective on this century-long evolution, we describe the geologic and geographic setting of the eruption - in a remote, sparsely inhabited wilderness; we review the cultural and scientific contexts at the time of the eruption and early expeditions; and we compile a chronology of the many Katmai investigations since 1912. Products of the eruption are described in detail, including eight layers of regionwide fallout, nine packages of ash flows, and three lava domes that followed the explosive pyroclastic episodes. Changes in the proportions of coerupting rhyolite, dacite, and andesite pumice documented for the fallout and ash-flow successions, which are locally interbedded, permit close correlation of those synchronously emplaced sequences and their varied facies. Petrological correlation of the sequence of deposits near Novarupta with ash layers at Kodiak village, 170 km downwind, where three episodes of ashfall were recorded (to the hour), provides key constraints on timing of the eruptive events. Syneruptive collapse of a kilometer-deep caldera took place atop Mount Katmai, a stratovolcano centered 10 km east of the eruption site at Novarupta, owing to drainage of magma from beneath the Katmai edifice. Correlation of ~50 earthquakes recorded at distant seismic stations (including 14 shocks of magnitude 6.0 to 7.0) to fitful caldera collapse provides further constraints on eruption timing, because layers of nonjuvenile breccia and mud ejected from Mount Katmai during collapse pulses are intercalated with the pumice-fall layers from Novarupta. Structure of the Novarupta vent, a 2-km-wide depression backfilled by welded tuff and inferred to be funnel-shaped at depth, is described in detail, as is the 4-km-wide caldera at Mount Katmai. Discussions are also provided concerning: (1) the impact on global climate of the great mass of sulfur-poor but halogen-rich aerosol ejected into the atmosphere by the rhyolite-dominated eruption; (2) chemical and mineralogical effects of the fumarolic acid gases; and (3) the timing of several syneruptive landslide deposits sandwiched within the pumice-fall sequence. Secondary posteruption phenomena characterized include impounded lakes, ash-rich debris flows, phreatic craters on the ignimbrite sheet, responses of glaciers to the fallout blanket and to beheading by caldera collapse, growth of new glaciers inside the caldera, and gradual filling of the caldera lake. Structure, composition, and ages of the several andesite-dacite stratovolcanoes, closely clustered near Novarupta, all of which remain fumarolically and seismically active, are summarized. But among them only Mount Katmai extends compositionally to include basalt and rhyolite. The petrological affinities of 1912 magmas erupted at Novarupta with pre-1912 Katmai lavas are outlined, and various chemical, mineralogical, isotopic, and experimental data are assembled to construct a model of preeruptive magma storage beneath Mount Katmai. The monograph concludes by comparing the 1912 eruption with several other well-studied large explosive eruptions, 14 of them historical and 9 prehistoric. Finally, we retrospectively review the historical difficulties in understanding what had actually taken place at Katmai in 1912 and the century of progress in volcano science that has allowed most of it to be figured out.

Alaska;British Columbia;Washington;Yukon

Petrology of the 2016–2017 eruption of Bogoslof Island

The 2016–2017 eruption of Bogoslof primarily produced crystal-rich amphibole basalts. The dominant juvenile tephra were highly microlitic with diktytaxitic vesicles, and amphiboles had large reaction rims. Both observations support a magma history of slow ascent and/or shallow stalling prior to eruption. Plagioclase-amphibole-clinopyroxene mineralogy are also suggestive of shallow magma crystallization. Lavas were emplaced as shallow submarine lava domes and cryptodomes that produced 70 relatively short-lived and water-rich explosions over the course of the 9-month long eruption. The explosions ejected older trachyandesite lavas that were likely uplifted by cryptodome emplacement that began in December 2016 and continued for many months. Trachyte pumice, similar in composition to a 1796 lava dome, was entrained in basalts by the end of the eruption. The pumice appears to be a largely crystalline magma that was rejuvenated, entrained in the basalt, and heated to ~1000 ℃. The composition of trachytes require differentiation through stronger amphibole control than the apparent shallow crustal evolution implied for the basalt. This suggests that they are magmas derived from a mid-crustal zone of amphibole crystallization. Nearby arc-front volcanoes that notably lack amphibole have strikingly similar compositional trends. Trace element signatures of the Bogoslof basalts, however, suggest derivation from a mantle source with residual garnet and lower-degree melting than basalts from nearby arc-front volcanoes. The diversity of magmas erupted at Bogoslof thus provides an opportunity not only to probe rare backarc compositions from the Aleutian arc, but also to examine the apparent role of amphibole in generating evolved compositions more broadly in arc environments.

Alaska

ChemCam activities and discoveries during the nominal mission of the Mars Science Laboratory in Gale crater, Mars

At Gale crater, Mars, ChemCam acquired its first laser-induced breakdown spectroscopy (LIBS) target on Sol 13 of the landed portion of the mission (a Sol is a Mars day). Up to Sol 800, more than 188 000 LIBS spectra were acquired on more than 5800 points distributed over about 650 individual targets. We present a comprehensive review of ChemCam scientific accomplishments during that period, together with a focus on the lessons learned from the first use of LIBS in space. For data processing, we describe new tools that had to be developed to account for the uniqueness of Mars data. With regard to chemistry, we present a summary of the composition range measured on Mars for major-element oxides (SiO 2 , TiO 2 , Al 2 O 3 , FeO T , MgO, CaO, Na 2 O, K 2 O) based on various multivariate models, with associated precisions. ChemCam also observed H, and the non-metallic elements C, O, P, and S, which are usually difficult to quantify with LIBS. F and Cl are observed through their molecular lines. We discuss the most relevant LIBS lines for detection of minor and trace elements (Li, Rb, Sr, Ba, Cr, Mn, Ni, and Zn). These results were obtained thanks to comprehensive ground reference datasets, which are set to mimic the expected mineralogy and chemistry on Mars. With regard to the first use of LIBS in space, we analyze and quantify, often for the first time, each of the advantages of using stand-off LIBS in space: no sample preparation, analysis within its petrological context, dust removal, sub-millimeter scale investigation, multi-point analysis, the ability to carry out statistical surveys and whole-rock analyses, and rapid data acquisition. We conclude with a discussion of ChemCam performance to survey the geochemistry of Mars, and its valuable support of decisions about selecting where and whether to make observations with more time and resource-intensive tools in the rover's instrument suite. In the end, we present a bird's-eye view of the many scientific results: discovery of felsic Noachian crust, first observation of hydrated soil, discovery of manganese-rich coatings and fracture fills indicating strong oxidation potential in Mars' early atmosphere, characterization of soils by grain size, and wide scale mapping of sedimentary strata, conglomerates, and diagenetic materials.

Journal of Analytical Atomic Spectrometry

Petrology of some lithic fragments from Luna 20

Microscopic and electron microprobe studies were made of polished thin sections of part of a 30-mg sample of 250–500 μm lunar soil returned by Luna 20 from a point between Mare Fecunditatis and Mare Crisium. Very fine-grained lithic (crystalline) rock fragments, composing about one fifth of the total sample, have mineralogical compositions equivalent to various types of gabbro, anorthositic gabbro, gabbroic anorthosite and troctolite, with minor basalt. The textures now observed in these fragments are in large part metamorphic. Twentyseven electron microprobe analyses of minerals from these fragments are presented, including olivine, plagioclase, pyroxene, spinel, nickel-iron and a Zr-Ti-REE mineral possibly similar to ‘phase B’ of Lovering and Wark (1971). Analyses of seven melt inclusions and twenty-eight defocused beam analyses of lithic fragments are also given. Some of the fragments contain ‘gas’ inclusions which, along with the fine grain size, are believed to indicate final crystallization under low pressure near surface conditions. The almost complete absence of granophyric material in this sample raises the question of whether or not there are at least two distinct magmas for the plagioclase-rich terrae rocks from which this soil sample was derived in part.

Geochimica et Cosmochimica Acta

Petrology and chemistry of the Green Acres gabbro complex near Winchester, Riverside County, California

The Cretaceous Green Acres layered igneous complex, northeast of Winchester, California, is composed of a suite of olivine- and hornblende-bearing gabbros in the Peninsular Ranges batholith within the Perris tectonic block. A consistent mineral assemblage is observed throughout the complex, but there is considerable textural and modal heterogeneity. Both preclude a consistent set of principles based on appearance and mineralogy on which to delineate map units. Distinct changes in the chemistry of olivine, pyroxene, and hornblende, however, serve to define discrete mappable units, and the complex has been divided into five geochemical map units on this basis. Limited whole-rock data show the Green Acres complex is chemically comparable to other Peninsular Ranges batholith gabbroic rocks, and rare earth element (REE) concentrations and patterns are typical of magmas generated in convergent margin settings. For the complex as a whole, olivine is Fo 80–35 , plagioclase is An 100–64 , clinopyroxene is Wo 49–41 En 48–38 Fs 18–6 and Wo 36–26 En 65–42 Fs 30–8 , and orthopyroxene is Wo 5–0 En 78–42 Fs 50–21 , where Fo is forsterite, An is anorthite, Wo is wollastonite, En is enstatite, and Fs is ferrosilite. The Mg/(Mg + ΣFe) atomic ratio in hornblende ranges from 0.84 to 0.50. Magmatic lineations and modal and textural layering are prevalent throughout the complex. Mineral chemistry does not change in any systematic way within and between layers in any map unit. Although the strike of layering varies, in any map unit at any given location it is the same in all units irrespective of intrusive order. Thin dikes, typically late-stage hornblende gabbro, commonly intrude parallel to layering. The strikes of magmatic lineations and modal layers are consistent with the populations of strikes of fabrics in the metamorphic basement as well as tectonic features in surrounding, postgabbro granitic rocks. These relations imply that the regional state of stress at the time of gabbro emplacement played a role in layer formation in conjunction with thermal and hydraulic pressure perturbations.

California

Fabric and its relation to sedimentologic and physical properties of near-surface sediment, Shelikof Strait and Alsek prodelta, Alaska

To investigate the possible relation between the fabric (microstructural arrangement of particles) of a fine-grained sedimentary deposit and the depositional and environmental processes of that deposit, the fabric of sediment samples from the sea floor of two different depositional settings, Shelikof Strait and the Alsek prodelta, Alaska, were studied by using scanning electron microscopy (SEM). Sediment of both areas is texturally similar, consisting of a muddy sand that grades to a mud with increasing water depth. Mineralogically, both areas are characterized by a clay-size fraction dominated by illite, chlorite, and rock flour. The dominant fabric of undisturbed sediment from both study areas consists of a sand- and coarse-silt-size agranular fraction surrounded by an open matrix of clay- and fine-silt-size platelets arranged in a combination of randomly oriented flocs and many single grain contacts. The similarity of the fabric of sediment from the two study areas suggests that the fabric is not controlled by the different depositional settings but rather by the dominant clay mineralogy and sediment texture. The most noticeable alteration of the original fabric of Shelikof Strait and Alsek prodelta sediment occurs as a result of high levels of consolidation and the shearing process.

Journal of Sedimentary Petrology

Petrology of the Vulcan Peak alpine-type peridotite, southwestern Oregon

The alpine-type peridotite in the area of Vulcan Peak, Oregon, is part of the larger Josephine ultramafic complex in the Klamath Mountains geologic province. Partially serpentinized, foliated harzburgite with 15 to 30 percent orthopyroxene makes up approximately 90 percent of the body. The remaining 10 percent is dunite that occurs in the harzburgite as concordant and discordant layers and as irregular bodies. In general, the peridotite at Vulcan Peak is similar in structure, texture, mineralogy, and chemistry to the peridotite at Burro Mountain, California. Structures, textures, and compositions of coexisting phases are consistent with high-temperature (1,000° to 1,200°C) deformation and recrystallization in the upper mantle, and tectonic emplacement into its present crustal position. Evidence to indicate whether the peridotite originated as a refractory residue during partial fusion processes that produced mafic melt or by crystallization from an ultramafic or picritic magma remains inconclusive; poikilitic clinopyroxene enclosing olivine in some dunites, and certain chromitite textures, may represent relict igneous features suggesting a magmatic stage in the history of the peridotite.

Oregon

Time and metamorphic petrology: Calcite to aragonite experiments

Although the equilibrium phase relations of many mineral systems are generally well established, the rates of transformations, particularly in polycrystalline rocks, are not. The results of experiments on the calcite to aragonite transformation in polycrystalline marble are different from those for earlier experiments on powdered and single-crystal calcite. The transformation in the polycrystalline samples occurs by different mechanisms, with a different temperature dependence, and at a markedly slower rate. This work demonstrates the importance of kinetic studies on fully dense polycrystalline aggregates for understanding mineralogic phase changes in nature. Extrapolation of these results to geological time scales suggests that transformation of calcite to aragonite does not occur in the absence of volatiles at temperatures below 200°C. Kinetic hindrance is likely to extend to higher temperatures in more complex transformations.

Science

The contributions and influence of two Americans, Henry S. Washington and Frank A. Perret, to the study of Italian volcanism with emphasis on volcanoes in the Naples area

A century ago, two Americans, Henry Stephens Washington and Frank Alvord Perret, made significant contributions to the geology, petrology, and volcanology of Italy, in particular to those volcanoes in the Naples area, Vesuvius, Campi Flegrei (Phlegraean Fields), and the Island of Ischia. Both were from the eastern United States, both were born in 1867, and both studied physics as undergraduates. However, each man followed a different scientific path and approach in his volcanological studies. Washington was classically trained and more interested in rock chemistry, mineralogy, and petrogenesis. Perret was a gifted inventor, worked in Edison's laboratory, established his own company, and was a keen observer of volcanic phenomena and processes; today he would be called a “physical volcanologist” Each man published classic works on Italian volcanoes, The Roman Comagmatic Region (Washington, 1906) and The Vesuvius Eruption of 1906 (Perret, 1924); both were published by the Carnegie Institution of Washington. However, both men had cosmopolitan tastes for other volcanoes, and they traveled widely and made significant contributions to the knowledge of other volcanic areas. The following two sections present, albeit briefly, their work, significance, and influence to Italian volcanism with emphasis on those volcanoes in the Naples area.

Naples

Factors controlling heavy-mineral variations on the South Texas outer continental shelf, Gulf of Mexico

Heavy-mineral distribution on the outer continental shelf off the southern coast of Texas shows regional variability induced by provenance and local variability reflecting genetic differences in sea-floor sediments. Q-mode factor analysis showed that three suites of heavy minerals are present. The southern ancestral Rio Grande delta sediments contain a distinct opaque-pyroxene-garnet suite, whereas the northern ancestral Brazes-Colorado delta sediments contain a tourmaline-green hornblende suite. An interdelta region contains a heavy mineral suite that is mixed owing to contributions from both ancestral deltas. Analysis of variance, correlation, and regression methods indicate that heavy-mineral variations in each sedimentary province have been significantly influenced by hydraulic fractionation by size, shape, and density, and by a selective chemical decomposition of unstable minerals. These factors have operated at varying degrees on the relict, palimpsest, and modern sediment populations of the sedimentary provinces since the end of Pleistocene time. The differential effects of these processes on the sediments have resulted in local variations that contribute to the total mineralogical variability. A comparison of the heavy mineral suites of the modern and relict Rio Grande delta sediments, which are derived from a common provenance, also shows mineral variations resulting from factors other than provenance.

Texas

Probing the volcanic-plutonic connection and the genesis of crystal-rich rhyolite in a deeply dissected supervolcano in the Nevada Great Basin: Source of the late Eocene Caetano Tuff

Late Cenozoic faulting and large-magnitude extension in the Great Basin of the western USA has created locally deep windows into the upper crust, permitting direct study of volcanic and plutonic rocks within individual calderas. The Caetano caldera in north–central Nevada, formed during the mid-Tertiary ignimbrite flare-up, offers one of the best exposed and most complete records of caldera magmatism. Integrating whole-rock geochemistry, mineral chemistry, isotope geochemistry and geochronology with field studies and geologic mapping, we define the petrologic evolution of the magmatic system that sourced the >1100 km 3 Caetano Tuff. The intra-caldera Caetano Tuff is up to ∼5 km thick, composed of crystal-rich (30–45 vol. %), high-silica rhyolite, overlain by a smaller volume of comparably crystal-rich, low-silica rhyolite. It defies classification as either a monotonous intermediate or crystal-poor zoned rhyolite, as commonly ascribed to ignimbrite eruptions. Crystallization modeling based on the observed mineralogy and major and trace element geochemistry demonstrates that the compositional zonation can be explained by liquid–cumulate evolution in the Caetano Tuff magma chamber, with the more evolved lower Caetano Tuff consisting of extracted liquids that continued to crystallize and mix in the upper part of the chamber following segregation from a cumulate-rich, and more heterogeneous, source mush. The latter is represented in the caldera stratigraphy by the less evolved upper Caetano Tuff. Whole-rock major, trace and rare earth element geochemistry, modal mineralogy and mineral chemistry, O, Sr, Nd and Pb isotope geochemistry, sanidine Ar–Ar geochronology, and zircon U–Pb geochronology and trace element geochemistry provide robust evidence that the voluminous caldera intrusions (Carico Lake pluton and Redrock Canyon porphyry) are genetically equivalent to the least evolved Caetano Tuff and formed from magma that remained in the lower chamber after ignimbrite eruption and caldera collapse. Thus, the Caetano Tuff contradicts models for the mutually exclusive origins of voluminous volcanic and plutonic magmas in the upper crust. Crystal-scale O isotope data indicate that the Caetano Tuff is one of the most 18 O-enriched rhyolites in the Great Basin (δ 18 O magma = 10·2 ± 0·2‰), supporting anatexis of local metasedimentary basement crust. Metapelite xenoliths in the Carico Lake pluton and ubiquitous xenocrystic zircons in the Caetano Tuff provide constraints for the anatexis process; these data point to shallow (<15 km) dehydration melting of a protolith similar to the Proterozoic McCoy Creek Group siliciclastic sediments in eastern Nevada, projected beneath Caetano in fault-stacked shelf sediments that were thickened during Mesozoic crustal shortening. Mean zircon U–Pb ages for different stratigraphic levels of the intra-caldera Caetano Tuff are 34·2–34·5 Ma, 0·2–0·5 Myr older than the caldera sanidine 40 Ar/ 39 Ar age of 34·00 ± 0·03 Ma, documenting protracted duration of assembly and homogenization of isotopically diverse upper crustal melts, followed by crystallization and zonation to generate the Caetano Tuff magma chamber. Sanidine rims in the least evolved Caetano Tuff and in the Carico Lake pluton and Redrock Canyon porphyry have sharply zoned Ba domains that point to crystal growth during magmatic recharge events. The recharge magma is inferred to have been compositionally similar to the Caetano Tuff magma, with increased Ba resulting from remelting of Ba-rich sanidine cumulates. Mush reactivation to generate the Caetano Tuff eruption was sufficiently rapid to preserve compositional gradients in the intracaldera ignimbrite, calling into question models that predict homogeneity as a prerequisite for remobilizing crystal-rich ignimbrite magmas.

Journal of Petrology

Pore systems and organic petrology of cretaceous Mowry and Niobrara source-rock reservoirs, Powder River Basin, Wyoming, USA

The Powder River Basin (PRB) is a world-class oil province, in large part thanks to contributions from premier source rocks, Cretaceous Mowry and Niobrara shales. Both formations are also unconventional reservoirs. A critical aspect of evaluating production potential and finding sweet spots is the nature of the pore systems in these fine-grained source-rock reservoirs. Variation by stratigraphic interval is important for selecting optimum target zones for horizontal wells. Understanding variation in pore type, size, and connectivity and relationships with mineralogy and fabric help in determining prospectivity in different parts of the basin. Deciphering controls on pore-system development helps predict intervals and locations of optimum reservoir quality. Imaging of Niobrara and Mowry samples from a range of thermal maturities provided observations and data on pore systems, organic matter (OM) types and associations with mineralogy and fabric, wettability, and microporosity associated with both diagenetic and detrital clays. Imaging techniques included scanning electron microscopy, organic petrography and correlative scanning electron microscopy, and mapping of mineralogy through energy dispersive spectroscopy. Mean solid bitumen (BR o ) and vitrinite reflectance (VR o ) values indicate all samples are in the oil window with values ranging from 0.52 to 1.15%. Organic fluorescence is prominent in amorphous OM, solid bitumen and some vitrinite in the early oil window. The fluorescence is extinguished at higher thermal maturity. Carbonate pellets (in Niobrara) mainly contain migrated solid bitumen and residual live oil and little or no terrigenous OM (vitrinite and inertinite). However, terrigenous OM is common in siliceous/argillaceous laminae in both formations, where it occurs with amorphous OM, some of which has converted in situ to a solid bitumen petroleum residue. One key finding is the widespread presence of migrated OM at very early oil window maturity. Distribution of such OM and associated wettability alteration is fabric-controlled, at all levels of thermal maturity studied. Clay morphology and abundance and supporting rigid mineral grain framework strongly influence pore development, preservation, and connectivity in both formations. Carbonate content is a good proxy for reservoir quality in Niobrara intervals due to association of porous solid bitumen with calcareous fecal pellets. High recrystallized microquartz content is associated with the best reservoir intervals in the Mowry.

Wyoming

Geology of Saipan, Mariana Islands; Part 2, Petrology and soils

The rocks that comprise the volcanic formations of Saipan are of two principal types: dacites, which are characteristically glassy, and andesites, which are comparatively crystalline. The dacites consist primarily of silicic glass, oligoclase, and silica minerals (quartz, tridymite, cristobalite, chalcedony, and opal). Minor constituents in these rocks are green hornblende, biotite, magnetite, and hematite. The andesites are composed principally of labradorite, hypersthene, augite, and subcalcrc augite. Minor but also characteristic constituents of the andesites are quartz, tridymite, cristobalite, anorthoclase, and accessory magnetite, ilmenite, rutile, and apatite. Nine varieties of dacite and andesite are recognized on the basis of chemical composition, mineralogy, and texture. These are dacite, dacite vitrophyre, dacite perlite, hornblende-bearing dacite porphyry, augite-hypersthene andesite, quartz-bearing augite-hypersthene andesite, quartz-bearing augite-hypersthene andesite porphyry, augite andesite, and hypersthene andesite.

Professional Paper

Petrology of eucrites, howardites and mesosiderites

The eucrite and howardite calcium-rich achondrites and many mesosiderites are considered as a coherent meteorite assemblage, their silicates consisting essentially of calciumpoor monoclinic and orthorhombic pyroxenes and calcium-rich plagioclase feldspar. The achondrites can be grouped according to their brecciated structure as follows: eucrites—unbrecciated and monomict brecciated achondrites; howardites—polymict brecciated achondrites. Many mesosiderites contain brecciated structures; they are distinguished from the achondrites by their large metallic fraction. The structure and composition of rock fragments in the breccias indicate a complicated sequence of events including magmatic differentiation, brecciation, recrystallization and refragmentation, and ejection from the parent body. Detailed mineralogical and chemical data suggest that the magmatic differentiation proceeded primarily by the separation of pyroxene from an ultrabasic parent material that had a much lower alkali content than ordinary chondrites. Magmatic crystallization took place in environments ranging from extrusive to deep-seated intrusive. Polymict breccias contain fragments with a wide variety of magmatic and recrystallization textures, which suggests that the breccias were formed either in very large or repeated fragmentation events. Monomict breccias contain fragments with a small range of similar magmatic textures, which suggests that these breccias were formed by small or single events. Petrographic evidence suggests that many of the breccias are impact breccias. Either in their original magmatic crystallization sites or in the sites of breccia accumulation, most of these meteorites apparently had a near-surface location prior to ejection from the parent body. Evidence obtained from eucrites, howardites and mesosiderites forms an important part of our understanding of the early evolution of the surface regions of their parent body. Chemical and oxidation conditions were different from those presently found in the Earth's crust and upper mantle, but the necessary conditions may have been present in the early history of the Earth. A lunar origin for eucrites, howardites and mesosiderites is proposed, but an asteroidal origin can not be presently excluded.

Geochimica et Cosmochimica Acta

Petrologic insights into rift zone magmatic interactions from the 2011 eruption of Kīlauea Volcano, Hawaiʻi

The high frequency of historical eruptions at Kīlauea Volcano presents an exceptional opportunity to address fundamental questions related to the transport, storage, and interaction of magmas within rift zones. The Nāpau Crater area on Kīlauea’s East Rift Zone (ERZ) experienced nine fissure eruptions within 50 years (1961–2011). Most of the magma intruded during these frequent eruptions remained stored within the rift zone, creating a potential magma mixing depot within the ERZ. The superbly monitored and sampled 2011 eruption (Puʻu ʻŌʻō episode 59) presents an extraordinary opportunity to evaluate magma mixing processes within the ERZ. Whole-rock, glass, and olivine compositions were determined, not only for lava from the 2011 eruption, but also for a new suite of Nāpau Crater area samples from the 1963, 1965, 1968, 1983, and 1997 eruptions, as well as the previously undocumented 1922 eruption. Whole-rock XRF data revealed two geochemically distinct magma batches for episode 59: one less evolved (∼6·6 wt % MgO, 0·46 wt % K2O) than the other (∼6·2 wt % MgO, 0·58 wt % K2O). Episode 59 lava is remarkably aphyric (∼0·1 vol. % phenocrysts), making use of mineralogy to identify parent magma affinities problematic. Linear compositional trends of whole-rock major and trace elements, and reversely zoned olivine crystals indicate episode 59 lavas underwent magma mixing. Least squares regression calculations and plots of major and trace element data, were used to evaluate whether the episode 59 samples are products of mixing summit-derived magma with residual magma from previous Nāpau Crater area eruptions. The regression results and trace element ratios are inconsistent with previously proposed mixing scenarios, but they do support mixing between summit-derived magma and residual magma from the 1983 and 1997 Nāpau Crater area eruptions. These magmas were stored in physically and chemically distinct pods at depths of 1·6–3·0 km prior to mixing with new magma intruded from the summit to produce the episode 59 lava. One pod contained a fractionated equivalent of 1983 lava, and the other a hybrid of compositions similar to 1983 and 1997 lavas. The petrology of episode 59 lava demonstrates that magmas from two previous eruptions (1983 and 1997) were available to mix with magma intruded from the summit region. This study clarifies the pre-eruptive history of the mixed episode 59 lava, and elucidates the evolution of the volcano's magmatic system in a region of frequent eruptions.

Hawaii

Origin and emplacement of the ultramafic rocks of the Emigrant Gap area, California

The ultramafic bodies of the Emigrant Gap area are part of a mafic complex within a large composite pluton of the northern Sierra Nevada. The pluton was magmatically emplaced and is surrounded by an aureole of hornblende-hornfels facies rocks. Inclusions of country rock in ultramafic rock are of pyroxene-hornfels facies and appear to have been partly melted. Gravity studies indicate that the ultramafic bodies have near-vertical contacts extending to depths of at least 1½ to 2½ km. The mafic complex shows rough concentric zoning of rock types: ultramafic bodies occur at the core; gabbro forms a discontinuous intermediate unit; and diorite, tonalite, and granodiorite occur at the margins. Within the ultramafic bodies, unserpentinized wehrlitic peridotite is dominant; dunite and olivine clinopyroxenite are present but greatly subordinate. The ultramafic rocks consist almost entirely of olivine (FO 80 ) and diopside (Ca 46 Mg 46 Fe 8 ); orthopyroxene, hornbolende, and plagioclase occur locally. The gabbro, diorite, tonalite, and granodiorite contain both ortho- and clinopyroxene. Both ultramafic and two-pyroxene-bearing rocks were emplaced nearly simultaneously, as partly crystallized magmas and magmatic crystal mushes that had similar temperature. In all the rocks the structures are dominantly magmatic and were produced by sorting and orientation of crystals by magmatic flow. Structures produced by post-consolidation deformation and replacement are minor and local. The structural and chemical relations within the mafic complex suggest that all the rocks are derived from a single gabbroic magma by crystal fractionation, with the ultramafic rocks formed by mechanical accumulation of early crystallized mafic minerals, and the two pyroxene-bearing granodiorite crystallized from a felsic differentiate. It is likely that flowage differentiation was the dominant process of crystal segregation. The Emigrant Gap mafic complex is similar in structure, rock texture, and mineralogy to zoned ultramafic complexes, such as those of south-eastern Alaska, and is very different from either stratiform or alpine-type bodies. Though unlike the Alaskan bodies in detail, it appears that this complex should be classed with the zoned complexes in any broad grouping of ultramafic occurrences.

California

Organic petrology and geochemistry of mudrocks from the lacustrine Lucaogou Formation, Santanghu Basin, northwest China: Application to lake basin evolution

Exploration for tight oil in the frontier Santanghu Basin of northwest China has resulted in recent commercial discoveries sourced from the lacustrine Upper Permian Lucaogou Formation, already considered a “world class source rock” in the Junggar Basin to the west. Here we apply an integrated analytical program to carbonate-dominated mudrocks from the Lucaogou Formation in Santanghu Basin to document the nature of organic matter (OM) in the context of an evolving lake system. The organic-rich samples (TOC 2.8–11.4 wt%; n = 10) were widely spaced from an ~ 200 m cored section, interpreted from textural and mineralogical evidence to document transition from a lower under-filled to an overlying balanced-filled lake. Organic matter is dominated by moderate to strongly fluorescent amorphous material with Type I geochemical signature (HI values 510–755; n = 10) occurring in a continuum from lamellar stringers, 10–20 μm thick, some ≥ 1 mm in length (possible microbial mat; preserved only in lower under-filled section) to finely-disseminated amorphous groundmass intimately intermixed with mineral matrix. Biomarkers for methanotrophs and photosynthetic cyanobacteria indicate a complex microbial consortium. A unicellular prasinophyte green alga(?), similar to Tasmanites in marine rocks, is present as discrete flattened discs 50–100 μm in diameter. Type III OM including vitrinite (some fluorescent) and inertinite also is abundant. Solid bitumen, indicating local kerogen conversion, fills voids and occurs throughout the cored section. Vitrinite reflectance values are 0.47–0.58%, consistent with strong OM fluorescence but may be “suppressed”. Other proxies, e.g., biomarker parameters, indicate the Lucaogou Formation is in the early oil window at this location. On average, slightly more amorphous OM and telalginite are present in the lower section, consistent with a shallow, stratified, saline environment with low sediment dilution. More inertinite is present in the upper section, indicating greater terrestrial influx and consistent with higher quartz and plagioclase content (dominantly authigenic chalcedony and albite). Laminated mudstones in the upper section indicate anoxia prevented bioturbation from benthic grazing, also indicating stratified water column conditions. A decrease upsection in authigenic dolomite with reciprocal increase of ankerite/siderite is consistent with decreasing salinity, as is an overall decrease in gammacerane index values. These observations suggest evolution from a shallow, stratified evaporative (saline) setting to a deeper, stratified freshwater basin with higher water input during Lucaogou deposition. The evolution from an under-filled to balance-filled lake in Santanghu Basin is similar to Lucaogou deposition in Junggar Basin, suggesting similar tectonic and climatic controls. Paleoclimate interpretations from other researchers in this area suggested an evolution from semi-arid to humid conditions during the Roadian; we interpret that the evolution from an under-filled to balanced-filled lake seen in our data is in response to climate change, and may represent increased groundwater delivery to the Santanghu Basin.

International Journal of Coal Geology

A chemical study of serpentinization — Burro Mountain, California

Serpentinized dunites and harzburgites from the Burro Mountain peridotite show no change in the ratio of iron and magnesia to silica when compared with the same ratio for the unserpentinized equivalents. The mineral assemblage resulting from serpentinization consists of lizardite-chrysotile, brucite, and magnetite and is determined by the original bulk composition of the peridotite. The chemical and mineralogical data indicate that serpentinization proceeded under isochemical conditions except for the introduction of water into the peridotite. Expansion accompanies serpentinization because the serpentine products occupy a greater volume than the peridotite protolith. Tectonic emplacement of the Burro Mountain peridotite was facilitated by serpentinization and the attendant expansion.

California