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Watershed Models for Decision Support for Inflows to Potholes Reservoir, Washington

A set of watershed models for four basins (Crab Creek, Rocky Ford Creek, Rocky Coulee, and Lind Coulee), draining into Potholes Reservoir in east-central Washington, was developed as part of a decision support system to aid the U.S. Department of the Interior, Bureau of Reclamation, in managing water resources in east-central Washington State. The project is part of the U.S. Geological Survey and Bureau of Reclamation collaborative Watershed and River Systems Management Program. A conceptual model of hydrology is outlined for the study area that highlights the significant processes that are important to accurately simulate discharge under a wide range of conditions. The conceptual model identified the following factors as significant for accurate discharge simulations: (1) influence of frozen ground on peak discharge, (2) evaporation and ground-water flow as major pathways in the system, (3) channel losses, and (4) influence of irrigation practices on reducing or increasing discharge. The Modular Modeling System was used to create a watershed model for the four study basins by combining standard Precipitation Runoff Modeling System modules with modified modules from a previous study and newly modified modules. The model proved unreliable in simulating peak-flow discharge because the index used to track frozen ground conditions was not reliable. Mean monthly and mean annual discharges were more reliable when simulated. Data from seven USGS streamflow-gaging stations were used to compare with simulated discharge for model calibration and evaluation. Mean annual differences between simulated and observed discharge varied from 1.2 to 13.8 percent for all stations used in the comparisons except one station on a regional ground-water discharge stream. Two thirds of the mean monthly percent differences between the simulated mean and the observed mean discharge for these six stations were between -20 and 240 percent, or in absolute terms, between -0.8 and 11 cubic feet per second. A graphical user interface was developed for the user to easily run the model, make runoff forecasts, and evaluate the results. The models; however, are not reliable for managing short-term operations because of their demonstrated inability to match individual storm peaks and individual monthly discharge values. Short-term forecasting may be improved with real-time monitoring of the extent of frozen ground and the snow-water equivalent in the basin. Despite the models unreliability for short-term runoff forecasts, they are useful in providing long-term, time-series discharge data where no observed data exist.

Scientific Investigations Report

Hydrogeology and simulation of groundwater flow in fractured rock in the Newark basin, Rockland County, New York

Groundwater in the Newark basin aquifer flows primarily through discrete water-bearing zones parallel to the strike and dip of bedding, whereas flow perpendicular to the strike is restricted, thereby imparting anisotropy to the groundwater flow field. The finite-element model SUTRA was used to represent bedrock structure in the aquifer by spatially varying the orientation of the hydraulic conductivity tensor to reflect variations in the strike and dip of the bedding. Directions of maximum and medium hydraulic conductivity were oriented parallel to the bedding, and the direction of minimum hydraulic conductivity was oriented perpendicular to the bedding. Groundwater flow models were prepared to simulate local flow in the vicinity of the Spring Valley well field and regional flow through the Newark basin aquifer. The Newark basin contains sedimentary rocks deposited as alluvium during the Late Triassic and is one of a series of basins that developed when Mesozoic rifting of the super continent Pangea created the Atlantic Ocean. The westward-dipping basin is filled with interbedded facies of coarse-grained to fine-grained rocks that were intruded by diabase associated with Jurassic volcanism. The Newark basin aquifer is bounded to the north and east by the Palisades sill and to the west by the Ramapo Fault. Although the general dip of bedding is toward the fault, mapping of conglomerate beds indicates the rocks are folded into broad anticlines and synclines. An alternative, more uniform pattern of regional structure, based on interpolated strike and dip measurements from a number of sources, has also been proposed. Two groundwater flow models (A for the former type of bedrock structure and B for the latter type) were developed to represent these alternative depictions of bedrock structure. Transient simulations were calibrated to reproduce measured water-level recoveries in a 9.3 mi&sup2 area surrounding the Spring Valley well field during a 5-day aquifer test in 1992. The models represented a 330-ft thick rock mass divided vertically into 10 equally spaced layers and were calibrated through nonlinear regression. Results of model B best matched the observed water-level recoveries with an estimated hydraulic conductivity of 9.5 ft/day, specific storage of 7.6 x 10 -6 ft -1, and K max : K min anisotropy ratio (hydraulic conductivity parallel to bedding: perpendicular to bedding) of 72:1. Model error was 50 percent greater in model A because the assumed structure did not match the actual strike of bedding in this area. Steady-state simulations of regional flow through the 85.4-mi2 modeled extent of the Newark basin aquifer represented both the alluvial aquifer beneath the Mawah River and the fractured bedrock. The rock mass was divided into two aquifer units: an upper 500-ft thick unit divided into 10 equally spaced layers through which most groundwater is assumed to flow and a lower unit divided into 7 layers with increasing thickness. Models were calibrated through nonlinear regression to average water levels measured in 140 wells from August 2005 through April 2007. Water levels simulated using the two models were similar and generally matched those observed, and the average recharge rate estimated using both models was 19 inches/year for the simulated period. Estimated transmissivity parallel to the strike of bedding (1,100 ft&sup2/d) was uniform in two transmissivity (T) zones in model A, but in model B the transmissivity of a high T zone (1,600 ft&sup2/d), delineated on the basis of aquifer test data, was slightly greater than in a low T zone (1,300 ft&sup2/d). The K max : K min anisotropy was estimated to be 58:1 in model A and 410:1 in model B, so the proportion of flow perpendicular to bedding is less in model B than in model A. Distributions of groundwater age simulated with models A and B are similar and indicate that most shallow ground-water (225 ft below the bedrock surface) is 5 t

Scientific Investigations Report

Groundwater chemistry and water-level elevations in bedrock aquifers of the Piceance and Yellow Creek watersheds, Rio Blanco County, Colorado, 2013–16

The Piceance and Yellow Creek watersheds in Rio Blanco County, Colorado, are known to contain important energy resources (oil shale and natural gas) and mineral resources (nahcolite). The primary sources of fresh groundwater in the Piceance and Yellow Creek watersheds are bedrock aquifers in the Uinta and Green River Formations. The aquifers are divided into an upper and lower aquifer separated by a regionally extensive semiconfining layer. These aquifers provide water to streams and springs in the watersheds and are an important resource to people living and working in the area. Development of energy and mineral resources has the potential to affect the quality of groundwater in several ways. The Bureau of Land Management and the U.S. Geological Survey began groundwater monitoring in 2010 to characterize the groundwater quality and water-level elevations of shallow bedrock aquifers in the Piceance and Yellow Creek watersheds. The purpose of this report is to present ground-water chemistry and water-level elevations collected during 2013–16. Comparisons are made to data that were collected from the bedrock aquifers from 2010 to 2012 to identify the potential for changes in water quality and water-level elevations. Appreciable changes in water-level elevations and hydraulic gradient were observed in early April 2015 in two wells completed in the upper and lower aquifers. The hydraulic gradient between the two wells was consistently downward from the upper aquifer to the lower aquifer during 2010–15; however, in early April 2015, the gradient changed from downward to upward between the two aquifers. Overall, water-level elevations declined by about 14 and 11 feet in the upper and lower aquifers, respectively, from 2013 to 2016. Previously published data estimated groundwater ages at 1,200 years old in the upper aquifer and 9,600 years old in the lower aquifer. These groundwater ages indicate that ground-water was recharged over thousands of years. With such long periods of time for aquifer recharge, declines in water-level elevation over short time steps (a few months) have important implications for sustainable management of this resource. Solution mining activities or drilling for oil and natural gas in the area could be related to the changes observed in water-level elevations in these wells; however, further investigation would be needed to evaluate causation. Changes in major-ion chemistry were evaluated in the bedrock aquifer using time series plots of select major-ion data from 2010 to 2016. Major-ion chemistry was variable for a single well from 2010 to 2016 where alkalinity and sulfate were the most variable constituents. One possible explanation for the observed changes in major-ion chemistry may be that the sample depth for that well no longer represents the most appreciable flow in the borehole. On a larger scale, potential changes in flow within the borehole may indicate changes in the regional flow system. Methane and volatile organic compound concentrations were evaluated using a similar approach to that of major ions and had similar findings. Methane concentrations in wells sampled from 2010 to 2016 were generally constant. The only exception was observed at a single well where the range of methane concentrations was from 57.4 (2010) to 4.02 milligrams per liter (2013). This is the same well where changes in water-level elevation, hydraulic gradient, and major-ion chemistry were observed, providing multiple lines of evidence to indicate change in the bedrock aquifers. Sampling of a well located in an area with little energy development but where faults or fractures could provide a path for the migration of fluids indicate mixing of groundwater between the upper and lower aquifers.

Colorado

Water Resources Data, Florida, Water Year 2000, Volume 4. Northwest Florida

This report series for the 2000 water year for the state of Florida consists of records for continuous or daily discharge for 355 streams, periodic discharge for 17 streams, continuous or daily stage for 211 streams, periodic stage for 1 stream, peak stage and discharge for 37 streams; continuous or daily elevations for 16 lakes, and periodic elevations for 45 lakes; continuous ground-water levels for 393 wells, and periodic ground-water levels for 1,003 wells; quality-of-water for 124 surface-water sites and 244 wells. This volume (Volume 4, Northwest Florida) contains records of continuous or daily discharge for 54 streams, periodic discharge for 1 stream, continuous or daily stage for 15 streams, periodic stage for 1 stream, peak stage and discharge for 30 streams; continuous or daily elevations for 1 lake, periodic elevations for 1 lake; continuous ground-water levels for 2 wells, periodic ground-water levels for 0 wells; quality-of-water for 4 surface-water sites and 0 wells. These data represent the National Water Data System records collected by the U.S. Geological Survey and cooperating local, State, and Federal agencies in Florida.

Water Data Report

Water Resources Data, Florida, Water Year 2001, Volume 4. Northwest Florida

This report series for the 2001 water year for the state of Florida consists of records for continuous or daily discharge for 387 streams, periodic discharge for 14 streams, continuous or daily stage for 147 streams, periodic stage for 2 streams, peak stage and discharge for 8 streams, continuous or daily elevations for 14 lakes, periodic elevations for 47 lakes, continuous ground-water levels for 429 wells, periodic ground-water levels for 1,257 wells, and quality-of-water for 112 surface-water sites and 248 wells. This volume (Volume 4, Northwest Florida) contains records of continuous or daily discharge for 65 streams, periodic discharge for 1 stream, continuous or daily stage for 18 streams, periodic stage for 2 streams, peak stage and discharge for 0 streams, continuous or daily elevations for 1 lake, periodic elevations for 1 lake, continuous ground-water levels for 2 wells, periodic ground-water levels for 3 wells, and quality-of-water for 3 surface-water sites and 0 wells. These data represent the National Water Data System records collected by the U.S. Geological Survey and cooperating local, State, and Federal agencies in Florida.

Water Data Report

Water Resources Data, Florida, Water Year 2002, Volume 4. Northwest Florida

The U.S. Geological Survey (USGS), in cooperation with Federal, State, and local agencies, obtains a large amount of data on the water resources of the State of Florida each water year. These data, accumulated during many water years, constitute a valuable database that is used by water-resources managers, emergency-management officials, and many others to develop an improved understanding of water resources within the State. This report series for the 2002 water year for the state of Florida consists of records for continuous or daily discharge for 392 streams, periodic discharge for 15 streams, continuous or daily stage for 191 streams, periodic stage for 13 streams, peak stage and discharge for 33 streams, continuous or daily elevations for 14 lakes, periodic elevations for 49 lakes, continuous ground-water levels for 418 wells, periodic ground-water levels for 1,287 wells, and quality-of-water for 116 surface-water sites and 291 wells. This volume (Volume 4, Northwest Florida)contains records of continuous or daily discharge for 67 streams, periodic discharge for 1 stream, continuous or daily stage for 16 streams, periodic stage for 1 stream, peak stage and discharge for 29 streams, continuous or daily elevations for 1 lake, periodic elevations for 3 lakes, continuous ground-water levels for 2 wells, periodic ground-water levels for 3 wells, and quality-of-water for 5 surface-water sites and 0 wells. These data represent the National Water Data System records collected by the U.S. Geological Survey and cooperating local, State, and Federal agencies in Florida.

Water Data Report

Water resources data, Florida, water year 2004, volume 4: northeast Florida

This report series for the 2004 water year for the state of Florida consists of records for continuous or daily discharge for 405 streams, periodic discharge for 12 streams, continuous or daily stage for 159 streams, periodic stage for 19 streams, peak stage and discharge for 30 streams, continuous or daily elevations for 14 lakes, periodic elevations for 23 lakes, continuous ground-water levels for 408 wells, periodic ground-water levels for 1,188 wells, and quality-of-water for 140 surface-water sites and 240 wells. This volume (Volume 4, Northwest Florida) contains records of continuous or daily discharge for 75 streams, periodic discharge for 2 streams, continuous or daily stage for 11 streams, periodic stage for 2 streams, peak stage and discharge for 22 streams, continuous or daily elevations for 1 lake, periodic elevations for 0 lakes, continuous ground-water levels for 3 wells, periodic ground-water levels for 0 wells, and quality-of-water for 3 surface-water sites and 0 wells. These data represent the National Water Data System records collected by the U.S. Geological Survey and cooperating local, State, and Federal agencies in Florida.

Water Data Report

Water resources data, Florida, water year 2005. Volume 4: Northwest Florida

This report series for the 2005 water year for the state of Florida consists of records for continuous or daily discharge for 429 streams, periodic discharge for 9 streams, continuous or daily stage for 218 streams, periodic stage for 5 streams, peak stage and discharge for 28 streams, continuous or daily elevations for 15 lakes, periodic elevations for 23 lakes, continuous ground-water levels for 401 wells, periodic ground-water levels for 1,098 wells, and quality-of-water for 211 surface-water sites and 208 wells. This volume (Volume 4, Northwest Florida) contains records of continuous or daily discharge for 76 streams, periodic discharge for 2 streams, continuous or daily stage for 14 streams, periodic stage for 0 streams, peak stage and discharge for 20 streams, continuous or daily elevations for 1 lake, periodic elevations for 0 lakes, continuous ground-water levels for 2 wells, periodic ground-water levels for 0 wells, and quality-of-water for 3 surface-water sites and 0 wells. These data represent the National Water Data System records collected by the U.S. Geological Survey and cooperating local, State, and Federal agencies in Florida.

Water Data Report

Water Resources Data for Florida, 1999, Volume 4: Northwest Florida

This report series for the 1999 water year for the State of Florida consists of records for continuous or daily discharge for 354 streams, periodic discharge for 17 streams, continuous or daily stage for 121 streams, periodic stage for 1 stream, peak stage and discharge for 38 streams; continuous or daily elevations for 21 lakes, and periodic elevations for 42 lakes; continuous ground-water levels for 408 wells, and periodic ground-water levels for 1,715 wells; quality-of-water for 131 surface-water sites and 198 wells. This volume (Volume 4, Northwest Florida) contains records of continuous or daily discharge for 54 streams, periodic discharge for 1 stream, continuous or daily stage for 15 streams, periodic stage for 1 stream, peak stage and discharge for 30 streams; continuous or daily elevations for 1 lake, periodic elevations for 1 lake; continuous ground-water levels for 1 well, periodic ground-water levels for 0 wells; and quality-of-water for 2 surface-water sites and 0 wells. These data represent the National Water Data System records collected by the U.S. Geological Survey and cooperating local, State, and Federal agencies in Florida.

Water Data Report

Water Resources Data: Hawaii and Other Pacific Areas, Water Year 1999. Volume 1. Hawaii

This report includes records on both surface and ground water in the State. Specifically, it contains: (1) Discharge records for 74 stream-gaging stations, 71 miscellaneous streamflow stations, and 88 crest-stage partial-record streamflow stations; (2) water-quality records for 6 streamflow-gaging stations, and 28 partial-record streamflow stations; (3) water-level records for 84 observation wells; (4) water-quality records for 122 observation wells; and (5) accumulated rainfall records for 40 rainfall stations. This series of annual reports for Hawaii began with the 1961 fiscal year (State of Hawaii) with a report that contained only data relating to the quantities of surface water. For the 1964 fiscal year, a similar report was introduced that contained only data relating to water quality. Beginning with the 1975 water year, the report format was changed to include, in one volume, data on quantities of surface water, quality of surface and ground water, and ground-water levels. Beginning with the 1993 water year, accumulated rainfall data were included in the report.

Water Data Report

Water Resources Data Minnesota Water Year 1999

The Water Resources Division of the U.S. Geological Survey (USGS), in cooperation with State agencies, obtains a large amount of data pertaining to the water resources of Minnesota each water year. These data, accumulated during many years, constitute a valuable data base for developing an improved understanding of the water resources of the State. To make these data readily available to interested parties outside the USGS, the data are published annually in this report series entitled 'Water Resources Data - Minnesota.' Water-resources data for the 1999 water year (hereinafter 1999) for Minnesota consist of records of stage, discharge, and water quality of streams; and stage of lakes and reservoirs; and water quality of ground water. This volume contains discharge records for 103 stream-gaging stations; stage for 11 lakes and reservoirs; water quality for 13 stream-gaging stations; peak flow data for 87 high-flow partial-record stations; and 15 ground-water observation wells. These data represent a part of the National Water Data System collected by the USGS and cooperating State and Federal agencies in Minnesota.

Water Data Report

Water Resources Data--Nebraska, Water Year 2002

The Water Resources Discipline of the U.S. Geological Survey (USGS), in cooperation with State and local agencies, obtains a large amount of data pertaining to the water resources of Nebraska each water year. These data, accumulated during many water years, constitute a valuable data base for developing an improved understanding of the water resources of the State. To make these data readily available to interested parties outside the USGS, the data are published annually in this report series entitled ?Water Resources Data - Nebraska.' The Nebraska water resources data report for water year 2002 includes records of stage, discharge, and water quality of streams; stage and/or contents of lakes and reservoirs; and water levels and quality of ground water in wells. This report contains records of stream stage for 3 stations; stream discharge for 96 continuous and 5 crest-state gaging stations, and 3 miscellaneous and 55 low-flow sites; stream water quality for 23 gaging stations and 5 miscellaneous sites; water elevation and/or contents for 1 lake and 1 reservoir; ground-water levels for 43 observation wells; and ground-water quality for 115 wells. These data represent that part of the National Water Data System collected in and near Nebraska by the U.S. Geological Survey and cooperating local, state and Federal agencies.

Water Data Report

Water resources data for New Hampshire and Vermont, water year 2002

The Water Resources Division of the U.S. Geological Survey, in cooperation with State agencies, obtains a large amount of data pertaining to the water resources of New Hampshire and Vermont each water year. These data, accumulated during many water years, constitute a valuable data base for developing an improved understanding of the water resources of the States. To make these data readily available to interested parties outside the U.S. Geological Survey, the data are published annually in this report series entitled 'Water Resources Data-New Hampshire and Vermont.' This report series includes records of stage, discharge, and water quality of streams; contents of lakes and reservoirs; and water levels of ground-water wells. This volume contains records for water discharge at 84 gaging stations; stage records for 5 lakes; month end contents for 2 lakes and reservoirs; and water levels at 38 observation wells. Also included are data for 43 crest-stage partial record stations. Locations of these sites are shown in figures 1 and 2. Additional water data were collected at various sites not involved in the systematic data-collection program and are published under miscellaneous discharge measurements for gaging stations in New Hampshire and Vermont. The data in this report represent that part of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in New Hampshire and Vermont.

Water Data Report

Water resources data, Puerto Rico and the U.S. Virgin Islands, water year 2004

The Caribbean Water Science Center of the U.S. Geological Survey (USGS), in cooperation with local and Federal agencies obtains a large amount of data pertaining to the water resources of the Commonwealth of Puerto Rico and the Territory of the U.S. Virgin Islands each water year. These data, accumulated during many water years, constitute a valuable data base for developing an improved understanding of the water resources of the area. To make these data readily available to interested parties outside the U.S. Geological Survey, the data are published annually in this report series entitled 'Water Resources Data for Puerto Rico and the U.S. Virgin Islands.' This report includes records on both surface and ground water. Specifically, it contains: (1) discharge records for 89 streamflow-gaging stations, daily sediment records for 13 sediment stations, stage records for 18 reservoirs, and (2) water-quality records for 20 streamflow-gaging stations, and for 38 ungaged stream sites, 13 lake sites, 2 lagoons, and 1 bay, and (3) water-level records for 72 observation wells. Water-resources data for Puerto Rico for calendar years 1958-67 were released in a series of reports entitled 'Water Records of Puerto Rico.' Water-resources data for the U.S. Virgin Islands for the calendar years 1962-69 were released in a report entitled 'Water Records of U.S. Virgin Islands.' Included were records of streamflow, ground-water levels, and water-quality data for both surface and ground water. Beginning with the 1968 calendar year, surface-water records for Puerto Rico were released separately on an annual basis. Ground-water level records and water-quality data for surface and ground water were released in companion reports covering periods of several years. Data for the 1973-74 reports were published under separate covers. Water-resources data reports for 1975 to 2003 water years consist of one volume each and contain data for streamflow, water quality, and ground water.

Water Data Report

Predevelopment water-level map of the Santa Fe Group aquifer system in the middle Rio Grande basin between Cochiti Lake and San Acacia, New Mexico

Because of its increasing population and limited water resources, the Middle Rio Grande Basin between Cochiti Lake and San Acacia, New Mexico, has recently become the subject of intense study. In particular, the U.S. Geological Survey (USGS) in cooperation with the City of Albuquerque has constructed a series of ground-water-flow models of the Tertiary and Quaternary basin-fill deposits of the Santa Fe Group aquifer system (Kernodle and Scott, 1986; Kernodle and others, 1987; Kernodle and others, 1995; Kernodle, 1998; Tiedeman and others, 1998). The ground-water-flow system also has been the focus of hydrochemical studies and other efforts intended largely to help develop an improved flow model. Among the information critical to a thorough understanding of the ground-water-flow system are water-level data that indicate the directions of ground-water flow and the magnitudes of hydraulic gradients in the aquifer prior to perturbation by substantial ground-water withdrawals (under predevelopment conditions).

Water-Resources Investigations Report

Occurrence of selected radionuclides in ground water used for drinking water in the United States: A reconnaissance survey, 1998

The U.S. Geological Survey, in collaboration with the U.S. Environmental Protection Agency, the American Water Works Association, and the American Water Works Service Company, completed a targeted national reconnaissance survey of selected radionuclides in public ground-water supplies. Radionuclides analyzed included radium-224 (Ra-224), radium-226 (Ra-226), radium-228 (Ra-228), polonium-210 (Po-210) and lead-210 (Pb-210).This U.S. Geological Survey reconnaissance survey focused intentionally on areas with known or suspected elevated concentrations of radium in ground water to determine if Ra-224 was also present in the areas where other isotopes of radium had previously been detected and to determine the co-occurrence characteristics of the three radium isotopes (Ra-224, Ra-226, and Ra-228) in those areas. Ninety-nine raw-water samples (before water treatment) were collected once over a 6-month period in 1998 and 1999 from wells (94 of which are used for public drinking water) in 27 States and 8 physiographic provinces. Twenty-one of the 99 samples exceeded the current U.S. Environmental Protection Agency drinking-water maximum contaminant level of 5 picocuries per liter (pCi/L) for combined radium (Ra-226 + Ra-228). Concentrations of Ra-224 were reported to exceed 1 pCi/L in 30 percent of the samples collected, with a maximum concentration of 73.6 pCi/L measured in water from a nontransient, noncommunity, public-supply well in Maryland. Radium-224 concentrations generally were higher than those of the other isotopes of radium. About 5 percent of the samples contained concentrations of Ra-224 greater than 10 pCi/L, whereas only 2 percent exceeded 10 pCi/L for either Ra-226 or Ra-228. Concentrations of Ra-226 greater than 1 pCi/L were reported in 33 percent of the samples, with a maximum concentration of 16.9 pCi/L measured in water from a public-supply well in Iowa. Concentrations of Ra-228 greater than 1 pCi/L were reported in 22 samples, with a maximum concentration of 72.3 pCi/L measured in water from a non-transient, noncommunity, public-supply well in Maryland.Radium-224, which is a decay product of Ra-228 in the Th-232 decay series, was significantly correlated with Ra-228 (Spearman?s rank correlation coefficient ?r? equals 0.82) and to a lesser degree with Ra-226 (r equals 0.69), which is an isotope in the U-238 decay series. The rank correlation coefficient between Ra-226 and Ra-228 was 0.63. The high correlation between Ra-224 and Ra-228 concentrations and the corresponding isotopic ratios of the two (about 1:1 in 90 percent of the samples) indicates that the two radionuclides occur in approximately equal concentrations in most ground water sampled. Thus, Ra-228 can be considered as a reasonable proxy indicator for the occurrence of Ra-224 in ground water.The maximum concentration of Po-210 was 4.85 pCi/L and exceeded 1 pCi/L in only two samples. The maximum concentration of Pb-210 was 4.14 pCi/L, and about 10 percent of the samples exceeded 1 pCi/L. Areas with known, or suspected, elevated concentrations of polonium and lead were not targeted in this survey.Three major implications are drawn for future radionuclide monitoring on the basis of this information: (1) grossalpha particle analyses of ground water should be done within about 48-72 hours after collection to determine the presence of the short-lived, alpha-particle emitting isotopes, such as Ra-224, which was detected in elevated concentrations in many of the samples collected for this survey; (2) the isotope ratios of Ra-224 to Ra-228 in ground water are variable on a national scale, but the two radioisotopes generally occur in ratios near 1:1, therefore, the more commonly measured Ra-228 can be used as an indicator of Ra-224 occurrence for some general purposes other than compliance; and (3) the isotopic ratios of Ra-226 to Ra-228 were less than 3:2 in many samples. These ratios corroborate results of previous studies that have shown the presence of Ra-228.

Water-Resources Investigations Report

Hydrogeology of the Tully Lakes area in southern Onondaga and northern Cortland Counties, New York

Water levels in a series of kettlehole lakes and ponds known as the Tully Lakes respond to seasonal water-level changes in the surrounding aquifer but often differ from ground-water levels in the aquifer because the lakebed sediments are poorly permeable and inhibit the exchange of water. Three sets of ground-water-level measurements were made from the spring recharge period of 2000 through the fall of that year. Seasonal ground-water-level declines ranged from 1.5 to 8 feet. Average annual water-level fluctuations in the three western lakes ranged from 2.5 to 6 feet, whereas those in the two eastern lakes were only about 1.5 feet because these lakes have natural outlets. The ground-water divide between the St. Lawrence and Susquehanna River Basins did not coincide with the surface-water divide and the ground-water divide moved southerly in response to lower water levels in the aquifer during the summer and fall.

New York

Hydrogeology and water chemistry of Montezuma Well in Montezuma Castle National Monument and surrounding area, Arizona

Increasing population and associated residential and commercial development have greatly increased water use and consumption in the Verde Valley near Montezuma Well, a unit of Montezuma Castle National Monument in central Arizona. Flow from Montezuma Well and water levels in eight wells that are measured annually do not indicate that the ground-water system has been affected by development. Additional data are needed to develop an adequate ground-water monitoring program so that future effects of development can be detected. Monitoring the ground-water system would detect changes in discharge from the Montezuma Well or changes in the ground-water system that might indicate a potential change of flow to the well. Water samples were collected, and field measurements of specific conductance, pH, temperature, and dissolved oxygen were made throughout the pond at Montezuma Well during an exploration in May 1991. The exploration included two fissures in the bottom of the pond that were filled with sand. The sand in the fissures was kept in suspension by water entering the pond. Water chemistry indicates that the ground water from the area is a mixed combination of calcium, magnesium, sodium, and bicarbonate type water. The analyses for 18O/16O and 2H/1H show that the water from the wells and springs in the area, including Montezuma Well, has been exposed to similar environmental conditions and could have had similar flow paths. The MODFLOW finite-difference ground-water model was used to develop an uncalibrated interpretive model to study possible mechanisms for discharge of water at Montezuma Well. The study presents the hypothesis that ground water in the Supai Formation is the source of discharge to Montezuma Well because of the differences between the surface elevation of the pond at Montezuma Well and the stage in the adjacent Wet Beaver Creek. A series of simulations shows that upward flow from the Supai Formation is a possible mechanism for discharge to Montezuma Well, and that a geologic structure in the Supai Formation could play a role in the upward movement of water to Montezuma Well. The mechanism for inflow from the Verde Formation is not understood; however, this study concludes that the Verde Formation, Supai Formation, and other underlying rock units are probably the sources of water to Montezuma Well.

Water-Resources Investigations Report