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Microgravity methods for characterization of groundwater-storage changes and aquifer properties in the karstic Madison aquifer in the Black Hills of South Dakota, 2009-12

A study of groundwater storage in the karstic Madison aquifer in the Black Hills of South Dakota using microgravity methods was conducted by the U.S. Geological Survey in cooperation with West Dakota Water Development District, South Dakota Department of Environment and Natural Resources, and Lawrence County. Microgravity measurements from 2009 to 2012 were used to investigate groundwater-storage changes and effective porosity in unconfined areas of the Madison aquifer. Time-lapse microgravity surveys that use portable high-sensitivity absolute and relative gravimeters indicated temporal-gravity changes as a result of changing groundwater mass. These extremely precise measurements of gravity required characterization and removal of internal instrumental and external environmental effects on gravity from the raw data. The corrected data allowed groundwater-storage volume to be quantified with an accuracy of about plus or minus 0.5 foot of water per unit area of aquifer. Quantification of groundwater-storage change, coupled with water-level data from observation wells located near the focus areas, also was used to calculate the effective porosity at specific altitudes directly beneath gravity stations. Gravity stations were established on bedrock outcrops in three separate focus areas for this study. The first area, the Spring Canyon focus area, is located to the south of Rapid City with one gravity station on the rim of Spring Canyon near the area where Spring Creek sinks into the Madison aquifer. The second area, the Doty focus area, is located on outcrops of the Madison Limestone and Minnelusa Formation to the northwest of Rapid City, and consists of nine gravity stations. The third area, the Limestone Plateau focus area, consists of a single gravity station in the northwestern Black Hills located on an outcrop of the Madison Limestone. An absolute-gravity station, used to tie relative-gravity survey data together, was established on a relatively impermeable bedrock outcrop to minimize groundwater-storage change at the reference location. Data from the three focus areas allow for interpretation of groundwater-storage characteristics using microgravity measurements. Gravity measurements, together with water-level data from an observation well located 2 miles from the Spring Canyon focus area and measured streamflow in Spring Creek, provided evidence that rapid groundwater-storage change, responding to changes in sinking streamflow over the recharge area of the aquifer, occurred in the Madison aquifer directly beneath the gravity station at Spring Canyon. This phenomenon likely was a result of groundwater movement through caverns, conduits, and fractures, which are common in karst aquifers. Spatially and temporally separated microgravity data for the Doty focus area indicated horizontal and vertical heterogeneity of effective porosity for the Madison aquifer. One such example of this was indicated by water-level measurements at an observation well and gravity measurements at four gravity stations in the southeastern part of the Doty area, which were used to estimate effective porosity values ranging from greater than 0 to 0.18. A decrease in groundwater storage determined by microgravity measurements during the spring recharge period for five upgradient stations in the Doty focus area indicated the possibility of rapid release and downgradient cascading of perched groundwater. Evidence for similar phenomena was documented for Wind Cave and Brooks Cave in the Black Hills. Absolute-gravity measurements at the Limestone Plateau focus area confirmed the relation between water levels in an observation well and changes in groundwater storage. Comparison of these gravity measurements with water levels in a nearby observation well resulted in an effective porosity estimate of 0.02 for the Madison aquifer beneath the gravity station.

South Dakota

Developing and implementing an International Macroseismic Scale (IMS) for earthquake engineering, earthquake science, and rapid damage assessment

Executive Summary Macroseismic observations and analysis connect our collective seismological past with the present and the present to the future by facilitating hazard estimates and communicating the effects of ground shaking to a wide variety of audiences across the ages. Invaluable ground shaking and building damage information is gained through standardized, systematic approaches for assigning intensities and, importantly, sharing and archiving those assignments in a reproducible form. The applications for these assignments are far reaching. Traditional macroseismic surveys provide vital constraints on critical aspects of earthquakes and their effects on society, whereas internet-based macroseismic datasets are extremely valuable for real-time earthquake situational awareness, and they contribute to later engineering loss and risk analyses. These important applications of macroseismic observations would be helped by revisiting traditional macroseismic surveys for modern environments, standardizing internet-based collection strategies, and ensuring compatibility between traditional and internet-based approaches of macroseismic data collection. Even with best practices, we have identified several limitations with modern macroseismic data collection approaches, particularly from the U.S. Geological Survey's perspective. First, whereas crowdsourced, internet-based intensities such as “Did You Feel It?” are robust and definitive for lower intensities, they are poorly defined above intensity VII, where damage observations may require expert knowledge of each building’s structural system. Second, in the United States, we use the Modified Mercalli Intensity (MMI) Scale, which is consistent with—yet inferior to—the more recently developed European Macroseismic Scale (EMS–98; Grünthal and others, 1998). Similarly, New Zealand uses the New Zealand MMI Scale (Dowrick and others, 2008), which lacks detail on how to assign intensities above MMI VIII. The EMS–98 fundamentally advanced the science of macroseismic intensity assignment by requiring quantitative assessments at each location through consistent application on statistical ranges of well-defined damage grades to building-specific vulnerability classes. Lastly, the United States and New Zealand no longer have professionals dedicated to conducting traditional macroseismic field surveys, so a strategy is needed for allowing postearthquake building inspectors and insurance loss assessors to contribute to intensity assignments. The goals of our International Macroseismic Scale workshop were thus twofold. First, harmonize the MMI Scale with EMS–98 for the United States and New Zealand—which share several similar building types—by considering those structures and associated damage grades that are not well represented in the current EMS–98 building vulnerability class table. Second, begin to formalize the process of augmenting EMS–98 with new regional building classes and damage grades toward the development of a macroseismic scale that can be used globally, beyond the United States and New Zealand. Such an effort necessarily requires reviewing and expanding the original EMS–98 explanatory documents and consideration of any required revisions. We can build on the shoulders of giants in that a few of the original EMS–98 developers and experts participated in and were integral to our workshop. Their background and guidance were key in moving forward toward an international scale. We agreed that additional building vulnerability classes, damage grades, and written and pictorial descriptions are necessary and ideally accompanied by a detailed paper trail for other nations to follow. If we can improve the macroseismic assignment process in both nations, we can also aim to refine the process of collecting postearthquake impact data, a boon to many engineering and financial concerns. The benefits of a truly International Macroseismic Scale are considerable for both the engineering and seismology communities. A modern macroseismic scale requires more deliberate archival damage data collection, motivating more consistent and accessible postevent datasets that would have applications beyond the specific event. Applying field-collected building damage data toward macroseismic assignments would allow for increased coordination between engineering reconnaissance teams and local inspectors in collecting such data for official purposes. In addition, rapid and consistent intensity assignments globally would enable more accurate ShakeMaps—and thus improved earthquake engineering and geotechnical forensics, loss and risk estimates, and correlations between macroseismic intensity and ground motion parameters. A brief summary of the Powell Center IMS workshop was published by Wald and others (2023) in the magazine Eos. This Open-File Report describes the workshop, its discussions, and its outcomes in detail. In summarizing the workshop, we have added important background material and reflections for proper context.

Open-File Report

Quantification of sucralose in groundwater well drinking water by silylation derivatization and gas chromatography-mass spectrometry

Sucralose is an increasingly popular artificial sweetener and has been found in the environment in groundwater, surface water, and wastewater treatment plant effluent. Its chemical properties make it strongly recalcitrant in the environment and it has been used as a conservative tracer of human wastewater in recent years. Most current methods of sucralose analysis use high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) instrumentation. In this study, we describe an analytical method using silylation derivatization and gas chromatography mass spectrometry (GC-MS) for the quantification of sucralose in groundwater samples. This method employs a deuterium-labeled internal standard to account for reaction and sample processing imprecision. The deuterated internal standard as well as experiments using negative ion chemical ionization gas chromatography-mass spectrometry strongly indicate that sucralose is derivatized at all five hydroxyl positions with trimethyl silyl groups. A previously developed GC-MS method with derivatization of sucralose in environmental samples did not employ an internal standard for quantification. As such, this method represents a more robust methodological approach for sucralose quantification in environmental samples. The method detection limit based on a set of 15 method blanks was calculated to be 21.8 ng L −1 , which is competitive with most methods in the published literature and sufficient to detect sucralose in water with ∼0.1% wastewater contribution. The method was applied to 37 groundwater samples from drinking water wells in California's Central Valley, in which five samples (13.5%) were found to contain sucralose at concentrations greater than the 21.8 ng L −1 detection limit.

Analytical Methods

Computer modelling for ecosystem service assessment

Computer models are simplified representations of the environment that allow biophysical, ecological, and/or socio-economic characteristics to be quantified and explored. Modelling approaches differ from mapping approaches (Chapter 5) as (i) they are not forcibly spatial (although many models do produce spatial outputs); (ii) they focus on understanding and quantifying the interactions between different components of social and/or environmental systems and (iii) by changing parameters within models, they are capable of exploring both alternative scenarios and internal model dynamics. When applied to the assessment of ecosystem services (ES), models are important tools which can quantify the relationships that underpin ES supply, demand and flows and, in some cases, produce maps representing these factors. Furthermore, as models can explore scenarios, trade-offs that result from different scenarios can be assessed. This chapter provides a broad overview of different types of models that have been applied to ES assessments and discusses, with examples, the ways that these models have the potential to be used in practice. In the context of ES, there are a number of ways of distinguishing between different types of models. Here, we distinguish between individual models focussing on single ES and modelling frameworks that can assess multiple ES within the framework of a single modelling tool.

Book chapter

Sources of glacial moisture in Mesoamerica

Paleoclimatic records from Mesoamerica document the interplay between Atlantic and Pacific sources of precipitation during the last glacial stage and Holocene. Today, and throughout much of the Holocene, the entire region receives its principal moisture in the summer from an interaction of easterly trade winds with the equatorial calms. Glacial records from sites east of 95?? W in Guatemala, Florida, northern Venezuela and Colombia record dry conditions before 12 ka, however. West of 95?? W, glacial conditions were moister than in the Holocene. For example, pollen and diatom data show that Lake Pa??tzcuaro in the central Mexican highlands was cool, deep and fresh during this time and fossil pinyon needles in packrat middens in Chihuahua, Sonora, Arizona, and Texas indicate cooler glacial climates with increased winter precipitation. Cold Gulf of Mexico sea-surface temperatures and reduced strength of the equatorial calms can explain arid full and late glacial environments east of 95?? W whereas an intensified pattern of winter, westerly air flow dominated hydrologic balances as far south as 20?? N. Overall cooler temperatures may have increased effective moisture levels during dry summer months in both areas. ?? 1997 INQUA/ Elsevier Science Ltd.

Quaternary International

Assessment of leachable elements in volcanic ashfall: A review and evaluation of a standardized protocol for ash hazard characterization

Volcanic ash presents a widespread and common hazard during and after eruptions. Complex interactions between solid ash surfaces and volcanic gases lead to the formation of soluble salts that may be mobilized in aqueous environments. A variety of stakeholders may be concerned about the effects of ash on human and animal health, drinking water supplies, crops, soils and surface runoff. As part of the immediate emergency response, rapid dissemination of information regarding potentially hazardous concentrations of soluble species is critical. However, substantial variability in the methods used to characterize leachable elements makes it challenging to compare datasets and eruption impacts. To address these challenges, the International Volcanic Health Hazard Network ( www.ivhhn.org ) organized a two-day workshop to define appropriate methods for hazard assessment. The outcome of this workshop was a ‘consensus protocol’ for analysis of volcanic ash samples for rapid assessment of hazards from leachable elements, which was subsequently ratified by leading volcanological organizations. The purpose of this protocol is to recommend clear, standard and reliable methods applicable to a range of purposes during eruption response, such as assessing impacts on drinking-water supplies and ingestion hazards to livestock, and also applicable to research purposes. Where possible, it is intended that the methods make use of commonly available equipment and require little training. To evaluate method transferability, an interlaboratory comparison exercise was organized among six laboratories worldwide. Each laboratory received a split of pristine ash, and independently analyzed it according to the protocol for a wide range of elements. Collated results indicate good repeatability and reproducibility for most elements, thus indicating that the development of this protocol is a useful step towards providing standardized and reliable methods for ash hazard characterization. In this article, we review recent ash leachate studies, report the outcomes of the comparison exercise and present a revised and updated protocol based on the experiences and recommendations of the exercise participants. The adoption of standardized methods will improve and facilitate the comparability of results among studies and enable the ongoing development of a global database of leachate information relevant for informing volcanic health hazards assessment.

Journal of Volcanology and Geothermal Research

Pore characteristics of Wilcox Group Coal, U.S. Gulf Coast Region: Implications for the occurrence of coalbed gas

Pore characteristics of 27 subbituminous coal samples (16 mesh splits) from the Paleocene–Eocene Wilcox Group of north Louisiana (Ouachita and Caldwell Parishes) and south Texas (Zavala County) were examined in relation to desorbed gas content. Coal gas of the Wilcox Group is primarily biogenic in origin; thermogenic gas also may be present in some areas. On an as-received basis, desorbed gas contents range from 0.59 to 1.28 m 3 /t for Ouachita Parish samples, 0.37 to 5.19 m 3 /t for the Caldwell Parish samples, and 0.02 to 0.06 m 3 /t for the Zavala County samples. For Louisiana coal samples, micropore surface area and volume are correlated to the desorbed gas content of the Wilcox Group coal (correlations: r = 0.50 and 0.47, respectively), suggesting that micropore surface area and volume are important in terms of gas-holding capacity. Adsorption by micropores appears to be the primary form of gas storage for the Louisiana coal samples. Micropore surface area and volumes also are strongly correlated with the carbon/ash yield ratio (r = 0.97 and 0.94, respectively), indicating that gas sorption occurs primarily on organic matter. Mineral matter appears to reduce the sorption capacity of the coal. Micropore width decreases with depth (r = − 0.63), probably as the result of increasing pressure and coal rank with depth. For the Louisiana coal samples, mesopore surface area is negatively correlated with the carbon/ash yield ratio (r = − 0.70), suggesting that mesopores are preferentially associated with mineral matter. Average mesopore size is correlated with desorbed gas (r = 0.80) for the relatively shallow Ouachita Parish samples (average depth = 441 m, 1446 ft); these results suggest that the permeability of the Wilcox coal is greater in the shallow stratigraphic intervals compared to deeper intervals. Additionally, mesopore size decreases with depth (r = − 0.80). For Ouachita Parish coal samples, negative correlations of gas with mesopore surface area (r = − 0.74) and mesopore volume (r = − 0.56) strongly suggest that gas is not adsorbed in mesopores, and that free gas may be present in larger mesopores, macropores, or fractures of the Wilcox coal. Results also suggest that moisture in Ouachita Parish samples is present in mesopores; moisture in mesopores may have blocked gas adsorption. The low-gas south Texas samples (average depth = 313 m, 1026 ft) are markedly different from the Louisiana samples. Specifically, micropore surface area and micropore volume are negatively correlated with desorbed gas for the Texas samples (r =− 0.21 and − 0.36, respectively). Geologic or environmental conditions probably were not conducive to the generation or storage of microbial gas in the Zavala County coals. The geologic settings (i.e., salinity of formation water, groundwater recharge, permeability of coal) of each study area are important factors that need to be considered in relation to the potential for generation or storage of microbial gas. In south Texas, tectonic stress may have led to a reduction in permeability in the Wilcox Group coal, creating an unfavorable environment for the generation or preservation of microbial gas. The subbituminous rank of the Zavala coals is also too low for significant thermogenic gas generation to have occurred.

Arkansas, Louisiana, Mississippi, Texas

A microcomputer-based data acquisition and control system for the direct shear, ring shear, triaxial shear, and consolidation tests

This report is intended to provide internal documentation for the U.S. Geological Survey laboratory's automatic data acquisition system. The operating procedures for each type of test are designed to independently lead a first-time user through the various stages of using the computer to control the test. Continuing advances in computer technology and the availability of desktop microcomputers with a wide variety of peripheral equipment at a reasonable cost can create an efficient automated geotechnical testing environment. A geotechnical testing environment is shown in figure 1. Using an automatic data acquisition system, laboratory test data from a variety of sensors can be collected, and manually or automatically recorded on a magnetic device at the same apparent time. The responses of a test can be displayed graphically on a CRT in a matter of seconds, giving the investigator an opportunity to evaluate the test data, and to make timely, informed decisions on such matters as whether to continue testing, abandon a test, or modify procedures. Data can be retrieved and results reported in tabular form, or graphic plots, suitable for publication. Thermistors, thermocouples, load cells, pressure transducers, and linear variable differential transformers are typical sensors which are incorporated in automated systems. The geotechnical tests which are most practical to automate are the long-term tests which often require readings to be recorded outside normal work hours and on weekends. Automation applications include incremental load consolidation tests, constant-rate-of-strain consolidation tests, direct shear tests, ring shear tests, and triaxial shear tests.

Open-File Report

Introduction to the special issue of the Consortium of Organizations for Strong Motion Observation Systems (COSMOS) international guidelines for applying noninvasive geophysical techniques to characterize seismic site conditions

Knowledge about local seismic site conditions provides critical information to account for site effects that are commonly observed in strong motion recordings. Certainly, other wave propagation effects can influence these observations, which are attributable to variations in material properties of the paths traveled by the waves, as well as the characteristics of the seismic source. However, local geologic conditions, particularly, when under shear-wave excitation, are known to have a strong influence on the behavior of ground shaking in the frequency range that is expected to directly affect the built environment. Thus, shear waves traveling in the shallow subsurface—defined here as tens to hundreds of meters beneath the ground surface—are the main foci for application and research in the earthquake engineering community.

Journal of Seismology

Decoding paleomire conditions of Paleogene superhigh-organic-sulfur coals

Superhigh-organic‑sulfur (SHOS) coals (coals with organic sulfur content >4 wt%) are unique coal deposits found at a few notable locations in the world. Specific peat accumulation and preservation conditions must be met to form SHOS coals. Organic sulfur is a major constituent of such coals, and it may have various sources depending on the prevailing paleomire conditions. Understanding such paleomire conditions sheds light on the formation mechanisms of SHOS coals. This investigation decodes the paleomire conditions of the Paleogene SHOS coals from Meghalaya, India, using sulfur isotopic compositions ( δ 34 S) of organic sulfur ( δ 34 S OS ) and pyritic sulfur ( δ 34 S Py ) along with organic petrography, pyrite morphology and trace element ratios. Thirty coal samples were collected from the Jaintia Hills in the east, Khasi Hills in the middle, and Garo Hills in the west of Meghalaya. The organic sulfur content in the Garo, Khasi, and Jaintia coals varies from 1.0 to 3.3 wt%, 1.4 to 13.8 wt%, and 1.0 to 7.2 wt%, respectively. Further, after separation from pyritic sulfur and sulfate sulfur phases, the organic sulfur content ranges from 54.4 to 69.2%, 63.8 to 79.9%, and 59.3 to 73.8%, in the Garo, Khasi, and Jaintia Hills, respectively, suggesting the SHOS nature of these coal samples. The δ 34 S Py varies from −29.3 ‰ to +5.7 ‰, −21.3 ‰ to +27.3 ‰, and −12.1 ‰ to −4.3 ‰, in the Jaintia, Khasi, and Garo Hills, respectively, while the δ 34 S OS fluctuates from −4.6 ‰ to +3.7 ‰, −9.3 ‰ to +7.8 ‰, and − 9.0 ‰ to −5.0 ‰, respectively. The δ 34 S values of pyrite and organic sulfur (OS) in Jaintia coals are 34 S depleted compared to seawater sulfate (+22 ‰), leading to fractionations in the range of −51.3 ‰ to −16.3 ‰ (mean − 31.6 ‰) and − 26.6 ‰ to −18.3 ‰ (mean − 23.1 ‰) for pyritic and organic sulfur (OS), respectively. Pyrite in Khasi coals show a relatively heavier δ 34 S composition averaging at −20.5 ‰, whereas organic sulfur (OS) isotope compositions range from −31.3 ‰ to −14.2 ‰ with a mean of −22.6 ‰. Pyrite and OS in the Garo coals are depleted compared to seawater sulfate. Isotope variations in the Jaintia, Khasi, and Garo coals indicate microbial sulfate reduction (MSR) of seawater sulfate. Large isotopic fractionations between Eocene seawater sulfate and pyritic sulfur ( Δ 34 S SO4Eocene – pyrite = up to −51.3 ‰; mean − 31.6 ‰) in Jaintia coals indicate their possible formation in the water column/near the sediment-seawater interface (open system) and also hint toward dissimilatory sulfate reduction pathways that prevailed under anoxic redox conditions. However, mean values of Δ 34 S SO4Eocene – pyrite (−20.5 ‰) in the Khasi coals imply pyrite formation deeper in the sediments (more closed system) under dysoxic conditions. The dominance of OS over pyritic sulfur, framboidal pyrite, and its microcrystal size distributions in Jaintia coals may suggest syngenetic pyrite formation in open water reducing/anoxic conditions under paralic environments. Elevated Sr/Ba and U/Th values in these coals further confirm the anoxic conditions. Nevertheless, the presence of euhedral pyrite with the alleviated pyrite framboids in the Khasi coals and their complete absence in the Garo coals may suggest dysoxic-suboxic and suboxic-oxic depositional conditions, respectively. The isotopic signatures of the Garo coals suggest sulfur contribution from the parent paleobiota and MSR under a freshwater-oxic environment. Insignificant fractionations between δ 34 S Py and δ 34 S OS indicate limited iron and sulfate availability for additional sulfur cycling and disproportionation reactions, typical of oxic conditions. The absence of framboidal pyrite, elevated sulfate concentration, and mean Sr/Ba and U/Th values of 0.5 and 0.3, respectively, further suggest the freshwater peat deposition in the Garo Hills under limnotelmatic to telmatic freshwater conditions. Moreover, high inertinite content (I mmf = 9.77–33.16 vol%), possibly induced by atmospheric peat exposure, supports the interpretation of suboxic-oxic paleomire conditions in Garo Hills. Gradually decreasing mineral matter content from Jaintia (mean 13.6 vol%) to Garo coals (mean 7.4 vol%) additionally projects a transition from mesotrophic brackish to freshwater limnotelmatic environment, complementing the shift in the paleomire condition from eastern (Jaintia) to western (Garo) Meghalayan Hills.

International Journal of Coal Geology

Turbidite systems: State of the art and future directions

The study of turbidite systems covering a wide range of physical scales has led to confus ion regarding the use of certain key terms and hence a breakdown in communication between workers involved in turbidite research. There are three fundamentally different scales and types of observations derived from the study of outcrop data (ancient systems), high-resolution seismic reflection and side scan sonar data (modern systems), and multichannel seismic reflection data (modern and older buried systems). Despite the variability of scale the same terms are used to describe features that may have little in common. Consequently, turbidite system terminology has become imprecise and even misleading in some cases, thus providing impediments to developing useful predictive models for processes, depositional environments, and lateral and vertical distribution of sand bodies within turbidite systems. To address this concern, we review the principal elements critical to deepwater systems: slump scars, submarine canyons, channels, channel fill deposits, overbank deposits, and lobes and discuss some of their recognition criteria with each different type of data base. Local and regional tectonic setting, relative sea level variations, and bottom current activity are probably the main factors that control size, external geometry, internal stratal configuration, and facies characteristics of both modern and ancient turbidite systems. These factors ultimately control the timing and bounding characteristics between stages of growth of deepwater systems. If comparison of elements from different turbidite deposits using various data types is carried out at similar physical and temporal scales, predictive models eventually may be improved.

Reviews of Geophysics

A practical solution: The Anthropocene is a geological event, not a formal epoch

The Anthropocene has yet to be defined in a way that is functional both to the international geological community and to the broader fields of environmental and social sciences. Formally defining the Anthropocene as a chronostratigraphical series and geochronological epoch with a precise global start date would drastically reduce the Anthropocene’s utility across disciplines. Instead, we propose the Anthropocene be defined as a geological event, thereby facilitating a robust geological definition linked with a scholarly framework more useful to and congruent with the many disciplines engaging with human-environment interactions. Unlike formal epochal definitions, geological events can recognize the spatial and temporal heterogeneity and diverse social and environmental processes that interact to produce anthropogenic global environmental changes. Consequently, an Anthropocene Event would incorporate a far broader range of transformative human cultural practices and would be more readily applicable across academic fields than an Anthropocene Epoch, while still enabling a robust stratigraphic characterization.

Episodes

Conservation of marine birds of northern North America: Papers from the international symposium held at the Seattle Hyatt House, Seattle, Washington, 13-15 May 1975

The international symposium "Conservation of Marine Birds of Northern North America" was convened because of a growing awareness that not all was well with our marine birds. The symposium provided a forum for scientists, governmental administrators, conservationists, and laypeople to discuss the diverse topics and issues that we must all understand if we are to act both responsively and responsibly to assure that marine birds will not be lost through our neglect. The symposium was cosponsored by the Natural Resources Council of America, National Audubon Society, National Wildlife Federation, and the U.S. Department of the Interior, Fish and Wildlife Service; additional support was provided by the Canadian Wildlife Service, the International Association of Game, Fish, and Conservation Commissioners, the Pacific Seabird Group, the Sierra Club, the Smithsonian Institution, the Wildlife Management Institute, and the Wildlife Society. Persons interested and knowledgeable in the many and varied aspects of marine bird conservation were invited to participate in this symposium. There were 139 registered and several score of unregistered participants in attendance. Major topics treated were: (1) socioeconomic considerations and conservation of marine birds; (2) the marine environment of birds; (3) status of marine bird populations on land and sea; (4) the biology and ecology of marine birds in the North; (5) conflicts between the conservation of marine birds and uses of other resources; (6) programs and authorities related to the conservation of marine birds; and (7) conservation of marine birds in other lands.

Wildlife Research Report

A new deglacial climate and sea-level record from 20 to 8 ka from IODP381 site M0080, Alkyonides Gulf, eastern Mediterranean

Records of relative sea-level rise for the last deglaciation are mostly limited to coral reef records and geophysical model estimates, but observational data from regions with temperate climates is sparse. We present a new relative climatic and regional sea-level rise record for glacial Termination 1 (Marine Isotope Stages [MIS] 2–1) based on ostracode paleoecology from the upper 8 m of the International Ocean Discovery Program (IODP) Site M0080 collected on Expedition 381, in the Gulf of Alkyonides, eastern Corinth basin of the Mediterranean Sea. Results show a series of major faunal transitions from lacustrine (Ponto-Caspian, Lake Corinth) glacial-age assemblages to fully marine (Mediterranean) interglacial assemblages between 20 and 8 ka. During glacial and early deglacial intervals, the Gulf of Alkyonides was characterized by non-marine lacustrine conditions with episodic sediment input from coastal, saline lake environments. Relatively stable lake shoreline conditions marked by the distinctive Tuberoloxoconcha sp. Existed from ∼17.5 to 15 ka. During the peak deglacial interval, the BØlling-AllerØd (B-A, ∼15–13.5 ka), rapid sea-level rise is indicated by a fully marine ostracode fauna colonization, which persisted from 13.5 to 7.5 ka (Late Pleistocene-Early to Middle Holocene).

Quaternary Science Reviews

Top-down targeted network analysis of critical mineral commodities applied to international geochemistry database

The global demand for critical mineral commodities is rapidly increasing, making domestic production an important factor in supporting the economy and national security. Large scale, publicly available geochemical databases allow for the application of data informatics methods to interrogate critical mineral commodities data for correlations in deposit formation and distribution, particularly for identifying enrichment of multiple critical mineral commodities at the same deposit. In this study, we applied network analysis to the Critical Minerals Mapping Initiative (CMMI) ore geochemistry (Critical Minerals in Ores, CMiO) database to identify the high concentration (defined as 10× bulk crustal abundance) co-occurrence of different critical mineral commodities across a mineral system hierarchy from deposit environments to individual deposits. Identifying patterns or unique outliers in enrichment in network communities will allow for the location of secondary critical mineral commodity resources from under-utilized deposits. We find trends in the enrichment of critical mineral commodities in network-communities between the elements praseodymium (Pr), neodymium (Nd), terbium (Tb), and dysprosium (Dy) across multiple CMiO database deposit environments and groups down to specific deposit types and sites. A separate trend in network community deposition is observed as well between iridium (Ir) and platinum (Pt) in deposit environments, groups, types, and sites. Network analysis focused on critical minerals in magmatic-hydrothermal deposits identified multiple deposit sites from different deposit types within the CMiO database with concentrations of Dy, Nd, Tb, Pr, Ir, and Pt that are at least ten times greater than the crustal average. This approach can be applied to any target element(s) or deposit(s) of interest, allowing broad investigation of co-enriched critical mineral commodities.

Journal of Geochemical Exploration

Paleontological analysis of a lacustrine carbonaceous uranium deposit at the Anderson mine, Date Creek basin, west-central Arizona (U.S.A.)

The Tertiary sedimentary sequence of the Date Creek basin area of Arizona is composed principally of intertonguing alluvial-fan and lacustrine deposits. The lacustrine rocks contain large intermediate- to, locally, high-grade uranium deposits that form one of the largest uranium resources in the United States (an estimated 670,000 tons of U 3 O 8 at an average grade of 0.023% is indicated by drilling to date). At the Anderson mine, about 50,000 tons of U 3 O 8 occurs in lacustrine carbonaceous siltstones and mudstones (using a cutoff grade of 0.01%). The Anderson mine constitutes a new class of ore deposit, a lacustrine carbonaceous uranium deposit. Floral and faunal remains at the Anderson mine played a critical role in creating and documenting conditions necessary for uranium mineralization. Organic-rich, uraniferous rocks at the Anderson mine contain plant remains and ostracodes having remarkably detailed preservation of internal features because of infilling by opaline silica. This preservation suggests that the alkaline lake waters in the mine area contained high concentrations of dissolved silica and that silicification occurred rapidly, before compaction or cementation of the enclosing sediment. Uranium coprecipitated with the silica. Thinly laminated, dark-colored, siliceous beds contain centric diatoms preserved with carbonaceous material suggesting that lake waters at the mine were locally deep and anoxic. These alkaline, silica-charged waters and a stagnant, anoxic environment in parts of the lake were necessary conditions for the precipitation of large amounts of uranium in the lake-bottom sediments. Sediments at the Anderson mine contain plant remains and pollen that were derived from diverse vegetative zones suggesting about 1500 m of relief in the area at the time of deposition. The pollen suggests that the valley floor was semiarid and subtropical, whereas nearby mountains supported temperate deciduous forests.

Nevada

Maps of the Arctic Alaska boundary area as defined by the U.S. Arctic Research and Policy Act—Including geospatial characteristics of select marine and terrestrial features

This pamphlet presents a series of general reference maps showing relevant geospatial features of the U.S. Arctic boundary as defined by the U.S. Congress since 1984. The first generation of the U.S. Arctic Research and Policy Act (ARPA) boundary maps was originally formatted and published in 2009 by a private firm contracted with the National Science Foundation and the U.S. Arctic Research Commission. Recognizing the steadily increasing relevance of Arctic issues to national and global affairs that requires more functional projections and online tools, the U.S. Geological Survey (USGS) Alaska Regional Office and the National Geospatial Technical Operations Center developed this updated series of ARPA boundary maps. Map sheet 1 shows the ARPA boundary as it relates to Alaska and marine features of the Bering Sea. Map sheet 2 shows the ARPA boundary from a circumpolar perspective. Map sheet 3 shows the national boundary of the U.S. 200-nautical-mile Exclusive Economic Zone through the Bering, Chukchi, and Beaufort Seas, facilitating Arctic domain awareness and more consistent territorial assessments of the U.S. Arctic. Map sheet 4 shows, in poster-size detail, the ARPA boundary as it relates to terrestrial features of Arctic Alaska north of the Yukon and Kuskokwim Rivers. Map sheet 5 shows, in poster-size detail, the ARPA boundary as it relates to marine and terrestrial features of the Aleutian Islands. These new maps collectively illustrate several value-added attributes, including updated bathymetry and shoreline refinements, demographic information, international borders and offshore territorial claims, Alaska conservation areas, Alaska land cover, Alaska terrestrial shaded relief, annual sea ice maximum extent, annual circumpolar 10-degree-Celsius isotherm, location of active volcanoes, and updated geospatial information. The static PDF-file maps offer value as standalone products but are intended for use with a potential interactive website that can be sourced by annual data updates, allowing users to access the various map layers in a dynamic up-to-date environment.

Alaska

Occurrence, temporal variation, and estrogenic burden of five parabens in sewage sludge collected across the United States

Five parabens used as preservatives in pharmaceuticals and personal care products (PPCPs) were measured in sewage sludges collected at 14 U.S. wastewater treatment plants (WWTPs) located in nine states. Detected concentration ranges (ng/g, dry weight) and frequencies were as follows: methyl paraben (15.9 to 203.0; 100%), propyl paraben (0.5 to 7.7; 100%), ethyl paraben (< 0.6 to 2.6; 63%), butyl paraben (< 0.4 to 4.3; 42%) and benzyl paraben (< 0.4 to 3.3; 26%). The estrogenicity inherent to the sum of parabens detected in sewage sludge (ranging from 10.1 to 500.1 pg/kg 17 β- estradiol equivalents) was insignificant when compared to the 10 6 -times higher value calculated for natural estrogens reported in the literature to occur in sewage sludge. Temporal monitoring at one WWTP provided insights into temporal and seasonal variations in paraben concentrations. This is the first report on the occurrence of five parabens in sewage sludges from across the U.S., and internationally, the first on temporal variations of paraben levels in sewage sludge. Study results will help to inform the risk assessment of sewage sludge destined for land application (biosolids).

Arizona, Indiana, Florida, Maryland, Montana, New