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At least 235 records · Page 13Linked to original sources

USGS2011

Loch Vale watershed long-term ecological research and monitoring program quality assurance report, 2003-09

The Loch Vale watershed project is a long-term research and monitoring program located in Rocky Mountain National Park that addresses watershed-scale ecosystem processes, particularly as they respond to atmospheric deposition and climate variability. Measurements of precipitation depth, precipitation chemistry, discharge, and surface-water quality are made within the watershed and elsewhere in Rocky Mountain National Park. As data collected for the program are used by resource managers, scientists, policy makers, and students, it is important that all data collected in Loch Vale watershed meet high standards of quality. In this report, data quality was evaluated for precipitation, discharge, and surface-water chemistry measurements collected during 2003-09. Equipment upgrades were made at the Loch Vale National Atmospheric Deposition Program monitoring site to improve precipitation measurements and evaluate variability in precipitation depth and chemistry. Additional solar panels and batteries have been installed to improve the power supply, and data completeness, at the NADP site. As a result of equipment malfunction, discharge data for the Loch Outlet were estimated from October 18, 2005, to August 17, 2006. Quality-assurance results indicate that more than 98 percent of all surface-water chemistry measurements were accurate and precise. Records that did not meet quality criteria were removed from the database. Measurements of precipitation depth, precipitation chemistry, discharge, and surface-water quality were all sufficiently complete and consistent to support project data needs.

Colorado↗

USGS2005

Use of the Biotic Ligand Model to predict metal toxicity to aquatic biota in areas of differing geology

This work evaluates the use of the biotic ligand model (BLM), an aquatic toxicity model, to predict toxic effects of metals on aquatic biota in areas underlain by different rock types. The chemical composition of water, soil, and sediment is largely derived from the composition of the underlying rock. Geologic source materials control key attributes of water chemistry that affect metal toxicity to aquatic biota, including: 1) potentially toxic elements, 2) alkalinity, 3) total dissolved solids, and 4) soluble major elements, such as Ca and Mg, which contribute to water hardness. Miller (2002) compiled chemical data for water samples collected in watersheds underlain by ten different rock types, and in a mineralized area in western Colorado. He found that each rock type has a unique range of water chemistry. In this study, the ten rock types were grouped into two general categories, igneous and sedimentary. Water collected in watersheds underlain by sedimentary rock has higher mean pH, alkalinity, and calcium concentrations than water collected in watersheds underlain by igneous rock. Water collected in the mineralized area had elevated concentrations of calcium and sulfate in addition to other chemical constituents. Miller's water-chemistry data were used in the BLM (computer program) to determine copper and zinc toxicity to Daphnia magna. Modeling results show that waters from watersheds underlain by different rock types have characteristic ranges of predicted LC 50 values (a measurement of aquatic toxicity) for copper and zinc, with watersheds underlain by igneous rock having lower predicted LC 50 values than watersheds underlain by sedimentary rock. Lower predicted LC 50 values suggest that aquatic biota in watersheds underlain by igneous rock may be more vulnerable to copper and zinc inputs than aquatic biota in watersheds underlain by sedimentary rock. For both copper and zinc, there is a trend of increasing predicted LC 50 values with increasing dissolved organic carbon (DOC) concentrations. Predicted copper LC 50 values are extremely sensitive to DOC concentrations, whereas alkalinity appears to have an influence on zinc toxicity at alkalinities in excess of about 100 mg/L CaCO 3 . These findings show promise for coupling the BLM (computer program) with measured water-chemistry data to predict metal toxicity to aquatic biota in different geologic settings and under different scenarios. This approach may ultimately be a useful tool for mine-site planning, mitigation and remediation strategies, and ecological risk assessment.

Conference Paper↗

USGS2001

Processes regulating watershed chemical export during snowmelt, fraser experimental forest, Colorado

In the Central Rocky Mountains, snowfall dominates precipitation. Airborne contaminants retained in the snowpack can affect high elevation surface water chemistry during snowmelt. At the Fraser Experimental Forest (FEF), located west of the Continental Divide in Central Colorado, snowmelt dominates the annual hydrograph, and accounts for >95% of annual stream water discharge. During the winters of 1989-1993, we measured precipitation inputs, snowpack water equivalent (SWE) and ion content, and stream water chemistry every 7-10 days along a 3150-3500 m elevation gradient in the subalpine and alpine Lexen Creek watershed. The study objectives were to (1) quantify the distribution of SWE and snowpack chemical content with elevation and aspect, (2) quantify snowmelt rates, temperature of soil, snowpack, and air with elevation and aspect, and (3) use change in upstream-downstream water chemistry during snowmelt to better define alpine and subalpine flowpaths. The SWE increased with elevation (P < 0.001) and was greater on NE aspects (P < 0.05). Subalpine soils were unfrozen. Snowmelt occurred throughout winter at low elevation (3150 m), SE aspect stations. By snowpack peak water equivalent (PWE), the snowpack lost about a third (0.24 m) of its moisture. The subalpine snowpack had warm (> - 3??C) temperatures throughout winter which resulted in significant snowpack ion loss. By snowpack PWE in mid May, the snowpack had lost almost half the cumulative precipitation H+, NH4+, and SO42- inputs and a third of the NO3- input. Windborne soil particulate inputs late in winter increased snowpack base cation content. Variation in subalpine SWE and snowpack ion content with elevation and aspect, and wind redistribution of snowfall in the alpine resulted in large year-to-year differences in the timing and magnitude of SWE, PWE, and snowpack ion content. The alpine stream water ion concentrations changed little during snowmelt indicating meltwater passed quickly through surface porous soils and was well mixed before entering the stream. Conversely, subalpine stream water chemistry was diluted during snowmelt suggesting much melt water moved to the stream as shallow subsurface lateral flow. Published by Elsevier Science B.V.

Journal of Hydrology↗

USGS2010

Hydrostratigraphy, soil/sediment chemistry, and water quality, Potomac-Raritan-Magothy aquifer system, Puchack Well Field Superfund site and vicinity, Pennsauken Township, Camden County, New Jersey, 1997-2001

Drinking-water supplies from the Potomac-Raritan-Magothy aquifer system at the Puchack well field in Pennsauken Township, Camden County, New Jersey, have been contaminated by hexavalent chromium-the most toxic and mobile form-at concentrations exceeding the New Jersey maximum contaminant level of 100 micrograms per liter. Also, scattered but widespread instances of volatile organic compounds (primarily trichloroethylene) at concentrations that exceed their respective maximum contaminant levels in the area's ground water have been reported. Because inorganic and organic contaminants are present in the ground water underlying the Puchack well field, no water from there has been withdrawn for public supply since 1998, when the U.S. Environmental Protection Agency (USEPA) added the area that contains the Puchack well field to the National Priorities List. As part of the USEPA's investigation of the Puchack Well Field Superfund site, the U.S. Geological Survey (USGS) conducted a study during 1997-2001 to (1) refine previous interpretations of the hydrostratigraphic framework, hydraulic gradients, and local directions of ground-water flow; (2) describe the chemistry of soils and saturated aquifer sediments; and (3) document the quality of ground water in the Potomac-Raritan-Magothy aquifer system in the area. The four major water-bearing units of the Potomac-Raritan-Magothy aquifer system-the Upper aquifer (mostly unsaturated in the study area), the Middle aquifer, the Intermediate Sand (a local but important unit), and the Lower aquifer-are separated by confining units. The confining units contain areas of cut and fill, resulting in permeable zones that permit water to pass through them. Pumping from the Puchack well field during the past 3 decades resulted in downward hydraulic gradients that moved contaminants into the Lower aquifer, in which the production wells are finished, and caused ground water to flow northeast, locally. A comparison of current (1997-2001) water levels near the site of the former pumping center with data from previous investigations indicates that, since pumping at the Puchack well field ceased, the dominant local ground-water flow direction is to the southeast, aligned with regional flow. Chromium concentrations were highest (8,010 micrograms per liter in 2000-01) in water from the Middle aquifer immediately downgradient from a possible source; the extent of this chromium plume is unknown but appears to be small. A second, unrelated, localized chromium plume also was identified in the Middle aquifer. The Intermediate Sand was found to contain an areally extensive plume of chromium-contaminated water, with concentrations up to 6,310 micrograms per liter in 2000-01, and another plume of about the same size, with concentrations up to 4,810 micrograms per liter in 2000-01, was identified in the Lower aquifer. The previous USGS investigation indicated the approximate extent of the combined plumes; the current delineation indicates that their locations have shifted slightly to the southeast since 1998. Concentrations of chromium in ground water decreased at some well locations by as much as 60 percent between sampling rounds in 1997-98 and 1999-2001. The decrease in chromium concentration at a given well could be the result of the chemical reduction of hexavalent chromium and precipitation of the resulting trivalent chromium, the sorption of hexavalent chromium to aquifer materials, or the physical movement of the plumes. Available data indicate that all three processes likely have affected concentrations. The distribution of hexavalent and total chromium in the soils and sediments of a possible source area indicates that some hexavalent chromium has undergone chemical reduction in the soils, but the degree to which this process takes place in the aquifer currently is not known. Nor is it known whether contaminated soils continue to contribute chromium to the aquifer system. Contamination by vola

Scientific Investigations Report↗

USGS2022

Aqueous geochemistry of waters and hydrogeology of alluvial deposits, Pinnacles National Park, California

A cooperative study between the National Park Service (NPS) and the U.S. Geological Survey (USGS) characterized groundwater quality and hydrogeology in parts of Pinnacles National Park. The water-quality investigation assessed the geochemistry of springs, wells, surface water, and precipitation and analyzed geochemistry of rock formations that affect the water chemistry through water-rock interaction. The hydrogeology investigation used geophysical and groundwater level data to characterize groundwater-flow processes in the alluvial deposits of Bear Valley and the Chalone Creek watershed. Analysis of aqueous geochemical parameters in water samples from perennial springs, water-supply wells, and surface waters was conducted for samples collected after the dry season (autumnal) and after the wet season (vernal) to assess changes in geochemistry due to changes in groundwater levels or flow resulting from precipitation. The chemistry of bulk precipitation collected during the wet season was also analyzed. Bedrock samples were analyzed for geochemical parameters to help constrain groundwater sources, flow paths, and weathering. The geochemical investigations show a correspondence between the source rock and the spring-water chemistry that can be attributed to the mineralogy of the source rock. The narrow range of strontium isotopes in water samples, sourced in geochemically and mineralogically disparate rocks, indicates that the bedrock groundwater is relatively old and has reached quasi-steady state with respect to weathering of susceptible minerals. Groundwater-level monitoring indicated that the water table is shallow—from 0 to 10 meters (m) below land surface. In southern Bear Valley and in the Chalone Creek alluvium, water levels rose and declined by several meters over each annual cycle of this study. In northern Bear Valley, water levels rose modestly over two wet seasons but declined during a third wet season. In Bear Valley, groundwater/surface-water interaction occurs along the perennial reach of Sandy Creek. Groundwater discharges to the upstream part of the reach, becomes surface water and is partly consumed by evapotranspiration, and infiltrates farther downstream. In the Chalone Creek alluvium, runoff-generated surface-water flow in intermittent stream reaches is a major component of groundwater recharge. After the onset of significant streamflow, creek water rapidly recharges groundwater until water levels rise to nearly the creek level. Groundwater levels generally remain high throughout the wet season, then gradually decline after the creek becomes dry.

California↗

USGS2007

Multivariate classification of small order watersheds in the Quabbin Reservoir Basin, Massachusetts

ABSTRACT: A multivariate approach was used to analyze hydrologic, geologic, geographic, and water-chemistry data from small order watersheds in the Quabbin Reservoir Basin in central Massachusetts. Eighty three small order watersheds were delineated and landscape attributes defining hydrologic, geologic, and geographic features of the watersheds were compiled from geographic information system data layers. Principal components analysis was used to evaluate 11 chemical constituents collected bi-weekly for 1 year at 15 surface-water stations in order to subdivide the basin into subbasins comprised of watersheds with similar water quality characteristics. Three principal components accounted for about 90 percent of the variance in water chemistry data. The principal components were defined as a biogeochemical variable related to wet. land density, an acid-neutralization variable, and a road-salt variable related to density of primary roads. Three subbasins were identified. Analysis of variance and multiple comparisons of means were used to identify significant differences in stream water chemistry and landscape attributes among subbasins. All stream water constituents were significantly different among subbasins. Multiple regression techniques were used to relate stream water chemistry to landscape attributes. Important differences in landscape attributes were related to wetlands, slope, and soil type.

Journal of the American Water Resources Associatio↗

USGS2023

Evaluation of potential stresses and hydrologic conditions driving water-level fluctuations in well ER-5-3-2, Frenchman Flat, southern Nevada

Well ER-5-3-2 is part of a well network designed to monitor long-term water levels and radionuclide concentrations downgradient from underground nuclear tests that occurred in Frenchman Flat, an area of the U.S. Department of Energy Nevada National Security Site in southern Nevada. Interpretation of monitoring records for well ER-5-3-2 was confounded by previously unexplained water-level fluctuations in the well hydrograph. This study integrated geologic, hydrologic, and water-chemistry data to evaluate potential stresses and hydrologic conditions that likely affected the well ER-5-3-2 hydrograph. Numerical groundwater models were applied to evaluate four model scenarios: (1) wellbore leakage without recharge, (2) wellbore leakage with recharge, (3) equilibration to vertical heterogeneities between shallow (low transmissivity) and deep (higher transmissivity) carbonate zones, and (4) equilibration to lateral heterogeneities in carbonate rocks. Meteoric recharge was not the cause of the 21-foot (ft) water-level rise in well ER-5-3-2 from 2001 to 2011 or the 4-ft decline from 2012 to 2016. Based on observed water-level fluctuations in nearby wells, the water-level rise and decline from recharge for these periods was less than 3 and 1 ft, respectively. The lateral-heterogeneity scenario is based on the assumption that the 21-ft water-level rise from 2001 to 2011 was a natural water-level reequilibration following the pumping-induced depressurization of a large volume of high transmissivity and low-storage carbonate rock that is surrounded by low transmissivity and high-storage carbonate rock. The lateral-heterogeneity scenario was discounted because simulated water levels cannot match the well ER-5-3-2 hydrograph. Underground nuclear testing and temperature effects were discounted based on hydraulic connections and water-temperature data. Wellbore-leakage scenarios are based on the assumption that the water-level rise was sustained from leakage rates required to cause a localized mounding in the carbonate system near well ER-5-3-2, where the carbonate transmissivity is 530 square feet per day. Even though simulated and measured water levels compare favorably for scenarios of wellbore leakage with and without recharge, large volumes (178–184 million gallons) of groundwater from volcanic rocks would be required to leak into the carbonate system, which is not supported by water-chemistry data. An alternative conceptualization of wellbore leakage is based on the assumption that the 21-ft water-level rise from 2001 to 2011 was sustained by the hydraulic disconnection of well ER-5-3-2 from the carbonate system. The disconnection occurred several months after a constant-rate test in well ER-5-3-2 when carbonate rocks were hydraulically disconnected from the well by either (1) the shifting of sloughed fill in the open hole or (2) the encrusting of carbonate precipitate in the well screen. The hydraulic disconnection effectively sealed the well and caused a 21-ft water-level rise from wellbore leakage during 2001–11. In this case, total wellbore leakage from 2001 to 2011 was about 50 gallons. The 4-ft water-level decline from 2012 to 2016 was conceptualized to have occurred from the slow breaking of the seal and reconnection of the well to the carbonate system. This alternative conceptualization of wellbore leakage was consistent with water-chemistry analyses because the computed wellbore leakage (50 gallons) was small relative to purged volumes (30,000–40,000 gallons) for sampling, and the water chemistry would not be expected to change. The shallow-deep carbonate scenario provided another explanation for the well ER-5-3-2 hydrograph. This scenario is based on the assumption that well-construction effects and vertical heterogeneity of the carbonate system explain the ER-5-3-2 water-level trend. Well-construction effects are attributed to a temporary clogging of the open interval below the well screen that was opened during pumping events, which affected the hydraulic connection of deep transmissive carbonate rocks to the wellbore. The 21-ft water-level rise from 2001 to 2011 was a natural equilibration to shallow, low-transmissivity carbonate rocks during a period when the lower open interval was clogged. The 4-ft decline from 2012 to 2016 represents equilibration between the shallow and deep intervals, because of a partial unclogging of the connection between the two intervals. The low water levels from 2016 to 2021 resulted from pumping for sampling and an unclogging of the open interval so that the low head in the deep carbonate dominated the water level. Despite potential well-construction effects, from either a wellbore leakage or shallow-deep carbonate scenario, samples collected from well ER-5-3-2 are representative of the carbonate system.

Nevada↗

USGS1999

Hydrogeology of the surficial aquifer in the vicinity of a former landfill, Naval Submarine Base Kings Bay, Camden County, Georgia

Neogene and Quaternary sediments constitute the surficial aquifer beneath the study area; in descending order from youngest to oldest these include-the Quaternary undifferentiated surficial sand and Satilla Formation; the Pliocene(?) Cypresshead Formation; and the middle Miocene Coosawhatchie Formation. Beneath the surficial aquifer, the upper Brunswick aquifer consists of part of the lower Miocene Marks Head Formation. The surficial aquifer is divided into three water-bearing zones on the basis of lithologic and geophysical properties of sediments, hydraulic-head differences between zones, and differences in ground-water chemistry. The shallowest zone-the water-table zone-consists of medium to fine sand and clayey sand and is present from land surface to a depth of about 77 feet. Below the water-table zone, the confined upper water-bearing zone consists of medium to very coarse sand and is present from a depth of about 110 to 132 feet. Beneath the upper water-bearing zone, the confined lower water-bearing zone consists of coarse sand and very fine gravel and is present from a depth of about 195 to 237 feet. Hydraulic separation is suggested by differences in water chemistry between the water-table zone and upper water-bearing zone. The sodium chloride type water in the water-table zone differs from the calcium bicarbonate type water in the upper water-bearing zone. Hydraulic separation also is indicated by hydraulic head differences of more than 6.5 feet between the water-table zone and the upper water-bearing zone. Continuous and synoptic water-level measurements in the water-table zone, from October 1995 to April 1997, indicate the presence of a water-table high beneath and adjacent to the former landfill-the surface of which varies about 5 feet with time because of recharge and discharge. Water-level data from clustered wells also suggest that restriction of vertical ground-water flow begins to occur at an altitude of about 5 to 10 feet below sea level (35 to 40 feet below land surface) in the water-table zone because of the increasing clay content of the Cypresshead Formation.

Georgia↗

USGS2018

Species‐ and habitat‐specific otolith chemistry patterns inform riverine fisheries management

Geology and hydrology are drivers of water chemistry and thus important considerations for fish otolith chemistry research. However, other factors such as species and habitat identity may have predictive ability, enabling selection of appropriate elemental signatures prior to costly, perhaps unnecessary water/age‐0 fish sampling. The goal of this study was to develop a predictive methodology for using species and habitat identity to design efficient otolith chemistry studies. Duplicate water samples and age‐0 fish were collected from 61 sites in 4 Missouri River reservoirs for walleye Sander vitreus and one impoundment (Lake Sharpe, South Dakota) for other fishes (bluegill Lepomis macrochirus , black crappie Pomoxis nigromaculatus , gizzard shad Dorosoma cepedianum , largemouth bass Micropterus salmoides , smallmouth bass M. dolomieu , white bass Morone chrysops , white crappie P. annularis , and yellow perch Perca flavescens ). Water chemistry (barium:calcium [Ba:Ca], strontium:calcium [Sr:Ca]) was temporally stable, spatially variable, and highly correlated with otolith chemistry for all species except yellow perch. Classification accuracies based on bivariate Ba:Ca and Sr:Ca signatures were high (84% across species) yet varied between floodplain and main‐channel habitats in a species‐specific manner. Thus, to maximize the reliability of otolith chemistry, researchers can use species classifications presented herein to inform habitat selection (e.g., study reservoir‐oriented species such as white bass in main‐channel environments) and habitat‐based classifications to inform species selection (e.g., focus floodplain studies on littoral species such as largemouth bass). Overall, species and habitat identity are important considerations for efficient, effective otolith chemistry studies that inform and advance fisheries and aquatic resource management.

North Dakota, South Dakota↗

USGS1996

Ground-water and stream-water interaction in the Owl Creek basin, Wyoming

Understanding of the interaction of ground-water and surface-water resources is vital to water management when water availability is limited.Inflow of ground water is the primary source ofwater during stream base flow. The water chemistry of streams may substantially be affected by that inflow of ground water. This report is part of a study to examine ground-water and surface-water interaction in the Owl Creek Basin, Wyoming, completed by the U.S. Geological Survey incooperation with the Northern Arapaho Tribe and the Shoshone Tribe. During a low flow period between November\x1113 - 17, 1991, streamflowmeasurements and water-quality samples were collected at 16 selected sites along major streams and tributaries in the Owl Creek Basin,Wyoming. The data were used to identify stream reaches receiving ground-water inflow and to examine causes of changes in stream chemistry.Streamflow measurements, radon-222 activity load, and dissolved solids load were used to identified stream reaches receiving ground-water inflow.Streamflow measurements identified three stream reaches receiving ground-water inflow. Analysis of radon-222 activity load identified five stream reaches receiving ground-water inflow. Dissolvedsolids load identified six stream reaches receiving ground-water inflow. When these three methods were combined, stream reaches in two areas, theEmbar Area and the Thermopolis Anticline Area, were identified as receiving ground-water inflow.The Embar Area and the Thermopolis Anticline Area were then evaluated to determine the source of increased chemical load in stream water. Three potential sources were analyzed: tributary inflow, surficial geology, and anticlines. Two sources,tributary inflow and surficial geology, were related to changes in isotopic ratios and chemical load in the Embar Area. In two reaches in the Embar Area, isotopic ratios of 18O/16O, D/H, and 34S/32S indicated that tributary inflow affected stream-water chemistry. Increased chemical load of dissolved solids and dissolved sulfate in North Fork andSouth Fork Owl Creek appear to be related to the percentage of unconsolidated Quaternary deposits and of Cretaceous-Jurassic deposits in the drainage area. In the Thermopolis Anticline Area, changes in water chemistry in Owl Creek were not related to tributary inflow, surficial geology, or anticlines.The three tributaries that flow into Owl Creek in the Thermopolis Anticline Area did not substantially affect the isotopic ratios or contribute to the chemical load. Changes in the chemical load were not associated with changes in the surficial geologybetween the stream-water sampling sites. Water levels and chemical ratios indicate no ground-water inflow from the Thermopolis Anticline geothermal system to Owl Creek.

Water-Resources Investigations Report↗

USGS1980

Water-quality reconnaissance of the Middle and North Branch Park River watersheds, northeastern North Dakota

In order to design a network to monitor the effects of works of improvement in the Middle and North Branch Park River watersheds, and to determine the major factors controlling water-quality conditions in the watersheds, an evaluation of sediment transport, water chemistry, and biology was conducted during the spring and early summer of 1978. Major factors controlling water quality are geology, stream gradient, ground-water seepage, and the duration of streamflow. Sediment loads originate on the Pembina Escarpment. The coarse silt and sand parts of these loads are deposited on the Lake Agassiz Plain. Transport of sediment is lowered and flow duration is increased on the Middle Branch Park River due to the presence of small dams. Observations suggest that bedload transport is a significant process, particularly in the upstream reaches. However, no quantitative bedload data were collected. During periods of low flow, analyses of water from the rivers in both watersheds show downstream increases in sodium and chloride due to ground-water seepage or the unregulated flow of wells. Diversity of benthic invertebrates indicates water-quality conditions are better on the Middle Branch Park River than on the North Branch, and are better at upstream sites than at downstream sites. A program through which the Soil Conservation Service can monitor the effects of present and future works of improvement on the watersheds was designed. The monitoring program consists of intensive sampling at four locations for sediment and water chemistry during spring and early summer runoff events and by profiles of water chemistry during summer base runoff.

Open-File Report↗

USGS2007

Urban-Related Environmental Variables and Their Relation with Patterns in Biological Community Structure in the Fountain Creek Basin, Colorado, 2003-2005

In 2003, the U.S. Geological Survey, in cooperation with Colorado Springs City Engineering, began a study to evaluate the influence of urbanization on stream ecosystems. To accomplish this task, invertebrate, fish, stream discharge, habitat, water-chemistry, and land-use data were collected from 13 sites in the Fountain Creek basin from 2003 to 2005. The Hydrologic Index Tool was used to calculate hydrologic indices known to be related to urbanization. Response of stream hydrology to urbanization was evident among hydrologic variables that described stormflow. These indices included one measurement of high-flow magnitude, two measurements of high-flow frequency, and one measurement of stream flashiness. Habitat and selected nonstormflow water chemistry were characterized at each site. Land-use data were converted to estimates of impervious surface cover and used as the measure of urbanization annually. Correlation analysis (Spearman?s rho) was used to identify a suite of nonredundant streamflow, habitat, and water-chemistry variables that were strongly associated (rho > 0.6) with impervious surface cover but not strongly related to elevation (rho < 0.60). An exploratory multivariate analysis (BIO-ENV, PRIMER ver 6.1, Plymouth, UK) was used to create subsets of eight urban-related environmental variables that described patterns in biological community structure. The strongest and most parsimonious subset of variables describing patterns in invertebrate community structure included high flood pulse count, lower bank capacity, and nutrients. Several other combinations of environmental variables resulted in competing subsets, but these subsets always included the three variables found in the most parsimonious list. This study found that patterns in invertebrate community structure from 2003 to 2005 in the Fountain Creek basin were associated with a variety of environmental characteristics influenced by urbanization. These patterns were explained by a combination of hydrologic, habitat, and water-chemistry variables. Fish community structure showed weaker links between urban-related environmental variables and biological patterns. A conceptual model was developed that showed the influence of urban-related environmental variables and their relation to fish and invertebrate assemblages. This model should prove helpful in guiding future studies on the impacts of urbanization on aquatic systems. Long-term monitoring efforts may be needed in other drainages along the Front Range of Colorado to link urban-related variables to aquatic communities in transition zone streams.

Scientific Investigations Report↗

USGS2013

Climate, not atmospheric deposition, drives the biogeochemical mass-balance of a mountain watershed

Watershed mass-balance methods are valuable tools for demonstrating impacts to water quality from atmospheric deposition and chemical weathering. Owen Bricker, a pioneer of the mass-balance method, began applying mass-balance modeling to small watersheds in the late 1960s and dedicated his career to expanding the literature and knowledge of complex watershed processes. We evaluated long-term trends in surface-water chemistry in the Loch Vale watershed, a 660-ha. alpine/subalpine catchment located in Rocky Mountain National Park, CO, USA. Many changes in surface-water chemistry correlated with multiple drivers, including summer or monthly temperature, snow water equivalent, and the runoff-to-precipitation ratio. Atmospheric deposition was not a significant causal agent for surface-water chemistry trends. We observed statistically significant increases in both concentrations and fluxes of weathering products including cations, SiO 2 , SO 4 2− , and ANC, and in inorganic N, with inorganic N being primarily of atmospheric origin. These changes are evident in the individual months June, July, and August, and also in the combined June, July, and August summer season. Increasingly warm summer temperatures are melting what was once permanent ice and this may release elements entrained in the ice, stimulate chemical weathering with enhanced moisture availability, and stimulate microbial nitrification. Weathering rates may also be enhanced by sustained water availability in high snowpack years. Rapid change in the flux of weathering products and inorganic N is the direct and indirect result of a changing climate from warming temperatures and thawing cryosphere.

Loch Vale Watershed, Rock Mountain National Park↗

USGS2010

Chemical Constituents in Groundwater from Multiple Zones in the Eastern Snake River Plain Aquifer at the Idaho National Laboratory, Idaho, 2005-08

From 2005 to 2008, the U.S. Geological Survey's Idaho National Laboratory (INL) Project office, in cooperation with the U.S. Department of Energy, collected water-quality samples from multiple water-bearing zones in the eastern Snake River Plain aquifer. Water samples were collected from six monitoring wells completed in about 350-700 feet of the upper part of the aquifer, and the samples were analyzed for major ions, selected trace elements, nutrients, selected radiochemical constituents, and selected stable isotopes. Each well was equipped with a multilevel monitoring system containing four to seven sampling ports that were each isolated by permanent packer systems. The sampling ports were installed in aquifer zones that were highly transmissive and that represented the water chemistry of the top four to five model layers of a steady-state and transient groundwater-flow model. The model's water chemistry and particle-tracking simulations are being used to better define movement of wastewater constituents in the aquifer. The results of the water chemistry analyses indicated that, in each of four separate wells, one zone of water differed markedly from the other zones in the well. In four wells, one zone to as many as five zones contained radiochemical constituents that originated from wastewater disposal at selected laboratory facilities. The multilevel sampling systems are defining the vertical distribution of wastewater constituents in the eastern Snake River Plain aquifer and the concentrations of wastewater constituents in deeper zones in wells Middle 2051, USGS 132, and USGS 103 support the concept of groundwater flow deepening in the southwestern part of the INL.

Scientific Investigations Report↗

USGS2002

Delineation of the Troy Bedrock Valley and particle-tracking analysis of ground-water flow underlying Belvidere, Illinois

The U.S. Geological Survey, U.S. Environmental Protection Agency, and Illinois Environmental Protection Agency began a study of the hydrogeology, flow system, and distribution of contaminants in the aquifers underlying Belvidere, Ill., and vicinity in 1992. As part of the study, the ancestral Troy Bedrock Valley, located about 1.5 miles west of Belvidere, was identified as an important part of the ground-water-flow system. In the deepest parts of the valley, the basal Glenwood confining unit may be absent; thick deposits of sand and gravel that infill part of the valley may directly overlie the sandstone St. Peter aquifer, a regionally important source of water for public supply. With few deep wells open to the St. Peter aquifer present in the valley to provide necessary geologic information, tritium and other water-chemistry data were collected from eight wells to possibly delineate areas where the confining unit may be absent; the data also provide baseline water-quality information for an area expecting changes in land use and increases in water withdrawal. Also as part of the study, particle-tracking analysis was done using an available flow model to (1) identify possible discharge locations of ground water and contaminants and (2) delineate areas contributing recharge to the Belvidere municipal wells. This report presents and interprets water-chemistry data collected during December 2000 and presents results of particle-tracking analysis. Ground water in samples from two of four wells open to the St. Peter aquifer appears to have recharged after 1954, suggesting that the Glenwood confining unit may be absent near the wells. Other hydrogeologic and water-chemistry data, however, were inconclusive or contradictory. Concentrations of iron, manganese, and lead exceeded maximum contaminant levels in five or less samples, but materials associated with the water-distribution systems appear to contribute to the elevated concentrations above natural levels. Particle-tracking analysis indicates that most ground-water flow beneath possible contaminant-source areas discharges from the glacial drift aquifer to the Kishwaukee River. Most of the source areas are in or near Belvidere and are within 1,500 feet of the river. The analysis also indicates the possibility that in parts of the study area, some ground water does not discharge to the river, but flows beneath the Kishwaukee River in the underlying carbonate Galena-Platteville aquifer. Ground water that discharges to the one municipal well open to the glacial drift aquifer is estimated to travel over 1 mile in less than 25 years. Simulated residence (travel) times of ground water from the base of the glacial drift aquifer to the six municipal wells open, in part, to the Galena-Platteville aquifer, are estimated at less than about 40 years. Because fractures in this aquifer are unaccounted for in the flow model, actual areas contributing recharge are likely larger and travel times faster than those simulated for most of the municipal wells. Tritium data indicate that, in general, travel times from the land surface to the deepest parts of the Galena-Platteville aquifer are less than 46 years. Methyl tertiary-butyl ether data indicate that travel times to the upper part of the aquifer may be less than 16 years. The water-quality-based estimates of travel time generally are consistent with the estimates from particle-tracking analysis.

Illinois↗

USGS2011

Groundwater chemistry near an impoundment for produced water, Powder River Basin, Wyoming, USA

The Powder River Basin is one of the largest producers of coal-bed natural gas (CBNG) in the United States. An important environmental concern in the Basin is the fate of the large amounts of groundwater extracted during CBNG production. Most of this produced water is disposed of in unlined surface impoundments. A 6-year study of groundwater flow and water chemistry at one impoundment, Skewed Reservoir, has produced the most detailed data set for any impoundment in the Basin. Data were collected from a network of 21 observation wells and three suction lysimeters. A groundwater mound formed atop bedrock within initially unsaturated, unconsolidated deposits underlying the reservoir. Heterogeneity in physical and chemical properties of sediments resulted in complex groundwater flow paths and highly variable groundwater chemistry. Sulfate, bicarbonate, sodium, and magnesium were the dominant ions in all areas, but substantial variability existed in relative concentrations; pH varied from less than 3 to more than 9, and total dissolved solids concentrations ranged from less than 5000 to greater than 100,000 mg/L. Selenium was a useful tracer of reservoir water; selenium concentrations exceeded 300 μg/L in samples obtained from 18 of the 24 sampling points. Groundwater travel time from the reservoir to a nearby alluvial aquifer (a linear distance of 177 m) was calculated at 474 days on the basis of selenium concentrations. The produced water is not the primary source of solutes in the groundwater. Naturally occurring salts and minerals within the unsaturated zone, dissolved and mobilized by infiltrating impoundment water, account for most of the solute mass in groundwater. Gypsum dissolution, cation-exchange, and pyrite oxidation appear to be important reactions. The complex geochemistry and groundwater flow paths at the study site underscore the difficulty in assessing effects of surface impoundments on water resources within the Powder River Basin.

Wyoming↗

USGS2007

Ground-water quality data in the Monterey Bay and Salinas Valley Basins, California, 2005— Results from the California GAMA program

Ground-water quality in the approximately 1,000-square-mile Monterey Bay and Salinas Valley study unit was investigated from July through October 2005 as part of the California Ground-Water Ambient Monitoring and Assessment (GAMA) program. The study was designed to provide a spatially unbiased assessment of raw ground-water quality, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 94 public-supply wells and 3 monitoring wells in Monterey, Santa Cruz, and San Luis Obispo Counties. Ninety-one of the public-supply wells sampled were selected to provide a spatially distributed, randomized monitoring network for statistical representation of the study area. Six wells were sampled to evaluate changes in water chemistry: three wells along a ground-water flow path were sampled to evaluate lateral changes, and three wells at discrete depths from land surface were sampled to evaluate changes in water chemistry with depth from land surface. The ground-water samples were analyzed for volatile organic compounds (VOCs), pesticides, pesticide degradates, nutrients, major and minor ions, trace elements, radioactivity, microbial indicators, and dissolved noble gases (the last in collaboration with Lawrence Livermore National Laboratory). Naturally occurring isotopes (tritium, carbon-14, helium-4, and the isotopic composition of oxygen and hydrogen) also were measured to help identify the source and age of the sampled ground water. In total, 270 constituents and water-quality indicators were investigated for this study. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, and (or) blended with other waters to maintain water quality. In addition, regulatory thresholds apply to treated water that is served to the consumer, not to raw ground water. In this study, only six constituents, alpha radioactivity, N-nitrosodimethylamine, 1,2,3-trichloropropane, nitrate, radon-222, and coliform bacteria were detected at concentrations higher than health-based regulatory thresholds. Six constituents, including total dissolved solids, hexavalent chromium, iron, manganese, molybdenum, and sulfate were detected at concentrations above levels set for aesthetic concerns. One-third of the randomized wells sampled for the Monterey Bay and Salinas Valley GAMA study had at least a single detection of a VOC or gasoline additive. Twenty-eight of the 88 VOCs and gasoline additives investigated were found in ground-water samples; however, detected concentrations were one-third to one-sixty-thousandth of their respective regulatory thresholds. Compounds detected in 10 percent or more of the wells sampled include chloroform, a compound resulting from the chlorination of water, and tetrachloroethylene (PCE), a common solvent. Pesticides and pesticide degradates also were detected in one-third of the ground-water samples collected; however, detected concentrations were one-thirtieth to one-fourteen-thousandth of their respective regulatory thresholds. Ten of the 122 pesticides and pesticide degradates investigated were found in ground-water samples. Compounds detected in 10 percent or more of the wells sampled include the herbicide simazine, and the pesticide degradate deethylatrazine. Ground-water samples had a median total dissolved solids (TDS) concentration of 467 milligrams per liter (mg/L), and 16 of the 34 samples had TDS concentrations above the recommended secondary maximum contaminant level (SMCL-a threshold established for aesthetic qualities: taste, odor, and color) of 500 mg/L, while four samples had concentrations above the upper SMCL of 1,000 mg/L. Concentrations of nitrate plus nitrite ranged from 0.04 to 37.8 mg/L (as nitrogen), and two samples had concentrations above the health-based threshold for nitrate of 10 mg/L (as nitrogen). The median sulfate concentration

California↗

USGS2015

Chemical constituents in groundwater from multiple zones in the eastern Snake River Plain aquifer, Idaho National Laboratory, Idaho, 2009-13

From 2009 to 2013, the U.S. Geological Survey’s (USGS) Idaho National Laboratory (INL) Project office, in cooperation with the U.S. Department of Energy, collected water-quality samples from multiple water-bearing zones in the eastern Snake River Plain aquifer. Water samples were collected from 11 monitoring wells completed in about 250–750 feet of the upper part of the aquifer, and samples were analyzed for selected major ions, trace elements, nutrients, radiochemical constituents, and stable isotopes. Each well was equipped with a multilevel monitoring system containing four to seven sampling ports that were each isolated by permanent packer systems. The sampling ports were installed in aquifer zones that were highly transmissive and that represented the water chemistry of the top three to five model layers of a steady-state and transient groundwater‑flow model. The groundwater-flow model and water chemistry are being used to better define movement of wastewater constituents in the aquifer. The water-chemistry composition of all sampled zones for the five new multilevel wells is calcium plus magnesium bicarbonate. One of the zones in well USGS 131A has a slightly different chemistry from the rest of the zones and wells and the difference is attributed to more wastewater influence from the Idaho Nuclear Technology and Engineering Center. One well, USGS 135, was not influenced by wastewater disposal and consisted of mostly older water in all of its zones. Tritium concentrations in relation to basaltic flow units indicate the presence of wastewater influence in multiple basalt flow groups; however, tritium is most abundant in the South Late Matuyama flow group in the southern boundary wells. The concentrations of wastewater constituents in deep zones in wells Middle 2051, USGS 132, USGS 105, and USGS 103 support the concept of groundwater flow deepening in the southwestern corner of the INL, as indicated by the INL groundwater-flow model.

Idaho↗