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At least 217 records · Page 12Linked to original sources

In situ measurements of post-fire debris flows in southern California: Comparisons of the timing and magnitude of 24 debris-flow events with rainfall and soil moisture conditions

Debris flows often occur in burned steeplands of southern California, sometimes causing property damage and loss of life. In an effort to better understand the hydrologic controls on post-fire debris-flow initiation, timing and magnitude, we measured the flow stage, rainfall, channel bed pore fluid pressure and hillslope soil-moisture accompanying 24 debris flows recorded in five different watersheds burned in the 2009 Station and Jesusita Fires (San Gabriel and Santa Ynez Mountains). The measurements show substantial differences in debris-flow dynamics between sites and between sequential events at the same site. Despite these differences, the timing and magnitude of all events were consistently associated with local peaks in short duration (< = 30 min) rainfall intensity. Overall, debris-flow stage was best cross-correlated with time series of 5-min rainfall intensity, and lagged the rainfall by an average of just 5 min. An index of debris-flow volume was also best correlated with short-duration rainfall intensity, but found to be poorly correlated with storm cumulative rainfall and hillslope soil water content. Post-event observations of erosion and slope stability modeling suggest that the debris flows initiated primarily by processes related to surface water runoff, rather than shallow landslides. By identifying the storm characteristics most closely associated with post-fire debris flows, these measurements provide valuable guidance for warning operations and important constraints for developing and testing models of post-fire debris flows. copyright. 2011 by the American Geophysical Union.

Journal of Geophysical Research F: Earth Surface

Triggering conditions, runout, and downstream impacts of debris flows following the 2021 Flag Fire, Arizona, USA

Debris flows pose a serious threat to communities in mountainous areas, particularly in the years following wildfire. These events have been widely studied in regions where post-wildfire debris flows have been historically frequent, such as southern California. However, the threat of post-wildfire debris flows is increasing in many regions where detailed data on debris-flow physical properties, volume, and runout potential are sparse, such as the Southwest United States (US) (Arizona and New Mexico). As the Southwest becomes more vulnerable to these hazards, there is an increasing need to better characterize the properties of post-wildfire debris flows in this region and to identify similarities and differences with nearby areas, particularly southern California, where there is a greater abundance of data. In this paper, we study the characteristics and downstream impacts of two post-wildfire debris flows that initiated following the 2021 Flag Fire in northern Arizona, US. We gathered data regarding soil hydraulic properties, rainfall characteristics, watershed response, and debris-flow initiation, runout, volume, grain size, and downstream impacts during the first two monsoon seasons following the containment of the Flag Fire. We also applied established debris-flow runout and volume models that were developed in southern California to our study watershed and compared the output with observations. In the first monsoon season following the fire, there were two post-wildfire debris flows, one of which resulted in damage to downstream infrastructure, and one major flood event. We found that, while more intense rainfall was observed to generate debris flows at our study site compared to southern California, burned watersheds in northern Arizona are still susceptible to debris flows during storms with low recurrence intervals in the first year following fire. During the second monsoon season, there were no major runoff events, despite more intense storms. This indicates that the temporal window for heightened debris-flow susceptibility at our study area was less than one year, due to the recovery of soil hydraulic properties and vegetation regrowth. We also found that the debris-flow properties at our study site, such as volume, mobility, and grain size distribution, may differ from those in other regions in the western US, including southern California, potentially due to regional differences in rainfall characteristics and sediment supply. Differences in rainfall characteristics and sediment supply may have also influenced the performance of the debris-flow runout and volume models, which overpredicted the observed runout distance by 400 m and predicted a volume more than 17 times greater than what was observed.

Arizona

Agricultural herbicide transport in a first-order intermittent stream, Nebraska, USA

The behavior of herbicides in surface waters is a function of many variables, including scale of the watershed, physical and chemical properties of the herbicide, physical and chemical properties of the soil, rainfall intensity, and time of year. In this study, the transport of 6 herbicides and 12 herbicide degradates was examined during the 2004 growing season in an intermediate-scale agricultural watershed (146 ha) that is drained by a first-order intermittent stream, and the mass load for each herbicide in the stream was estimated. The herbicide load during the first week of storm events after application ranged from 17% of annual load for trifluralin to 84% of annual load for acetochlor. The maximum weekly herbicide load in the stream was generally within the first 3 weeks after application for those compounds that were applied within the watershed during 2004, and later for herbicides not applied within the watershed during 2004 but still detected in the stream. The apparent dominant mode of herbicide transport in the stream-determined by analysis amongst herbicide and conservative ion concentrations at different points in the hydrograph and in base flow samples-was either overland runoff or shallow subsurface flow, depending on the elapsed time after application and type of herbicide. The load as a percentage of use (LAPU) for the parent compounds in this study was similar to literature values for those compounds applied by the farmer within the watershed, but smaller for those herbicides that had rainfall as their only source within the watershed.

Nebraska

Extent, patterns, and drivers of hypoxia in the world's streams and rivers

Hypoxia in coastal waters and lakes is widely recognized as a detrimental environmental issue, yet we lack a comparable understanding of hypoxia in rivers. We investigated controls on hypoxia using 118 million paired observations of dissolved oxygen (DO) concentration and water temperature in over 125,000 locations in rivers from 93 countries. We found hypoxia (DO < 2 mg L −1 ) in 12.6% of all river sites across 53 countries, but no consistent trend in prevalence since 1950. High-frequency data reveal a 3-h median duration of hypoxic events which are most likely to initiate at night. River attributes were better predictors of riverine hypoxia occurrence than watershed land cover, topography, and climate characteristics. Hypoxia was more likely to occur in warmer, smaller, and lower-gradient rivers, particularly those draining urban or wetland land cover. Our findings suggest that riverine hypoxia and the resulting impacts on ecosystems may be more pervasive than previously assumed.

Limnology and Oceanography - Letters

SedPods: a low-cost coral proxy for measuring net sedimentation

Sediment derived from impaired watersheds is a major stressor to adjacent coral reefs globally. To better understand stresses generated by specific processes and events, many coral reef scientists seek to collect physical samples of settling particles and obtain reproducible information about net rates of sediment accumulation on coral reefs. Yet, the tools most commonly used to gather this information, sediment tube traps, only provide information on the gross accumulation of sediment at a site, in that all particles are effectively trapped within the container, unlike what a coral surface experiences. To address the need for an improved measurement of net particle accumulation on coral surfaces, we propose using recoverable sediment pods (SedPods) that can be constructed from readily available materials for under US $20. These devices are inexpensive, easy to fabricate, and allow for capture of particles over a given time span. The particles can then be used for laboratory analysis and accurate calculation of net accumulation rates on a coral surface proxy. In an experiment in Hanalei Bay, HI, we found that net sediment accumulation on rectangular SedPods was an order of magnitude less than gross accumulation in nearby conventional tube traps.

Coral Reefs

A 17-year record of environmental tracers in spring discharge, Shenandoah National Park, Virginia, USA: use of climatic data and environmental conditions to interpret discharge, dissolved solutes, and tracer concentrations

A 17-year record (1995–2012) of a suite of environmental tracer concentrations in discharge from 34 springs located along the crest of the Blue Ridge Mountains in Shenandoah National Park (SNP), Virginia, USA, reveals patterns and trends that can be related to climatic and environmental conditions. These data include a 12-year time series of monthly sampling at five springs, with measurements of temperature, specific conductance, pH, and discharge recorded at 30-min intervals. The monthly measurements include age tracers (CFC-11, CFC-12, CFC-113, CFC-13, SF 6 , and SF 5 CF 3 ), dissolved gases (N 2 , O 2 , Ar, CO 2 , and CH 4 ), stable isotopes of water, and major and trace inorganic constituents. The chlorofluorocarbon (CFC) and sulfur hexafluoride (SF 6 ) concentrations (in pptv) in spring discharge closely follow the concurrent monthly measurements of their atmospheric mixing ratios measured at the Air Monitoring Station at Big Meadows, SNP, indicating waters 0–3 years in age. A 2-year (2001–2003) record of unsaturated zone air displayed seasonal deviations from North American Air of ±10 % for CFC-11 and CFC-113, with excess CFC-11 and CFC-113 in peak summer and depletion in peak winter. The pattern in unsaturated zone soil CFCs is a function of gas solubility in soil water and seasonal unsaturated zone temperatures. Using the increase in the SF 6 atmospheric mixing ratio, the apparent (piston flow) SF 6 age of the water varied seasonally between about 0 (modern) in January and up to 3 years in July–August. The SF 6 concentration and concentrations of dissolved solutes (SiO 2 , Ca 2+ , Mg 2+ , Na + , Cl − , and HCO 3 − ) in spring discharge demonstrate a fraction of recent recharge following large precipitation events. The output of solutes in the discharge of springs minus the input from atmospheric deposition per hectare of watershed area (mol ha −1 a −1 ) were approximately twofold greater in watersheds draining the regolith of Catoctin metabasalts than that of granitic gneisses and granitoid crystalline rocks. The stable isotopic composition of water in spring discharge broadly correlates with the Oceanic Niño Index. Below normal precipitation and enriched stable isotopic composition were observed during El Niño years.

Virginia

Tree-ring based reconstructions of interannual to decadal scale precipitation variability for northeastern Utah since 1226 A.D.

Samples from 107 piñon pines ( Pinns edulis ) at four sites were used to develop a proxy record of annual (June to June) precipitation spanning the 1226 to 2001 AD interval for the Uinta Basin Watershed of northeastern Utah. The reconstruction reveals significant precipitation variability at interannual to decadal scales. Single-year dry events before the instrumental period tended to be more severe than those after 1900. In general, decadal scale dry events were longer and more severe prior to 1900. In particular, dry events in the late 13th, 16th, and 18th Centuries surpass the magnitude and duration of droughts seen in the Uinta Basin after 1900. The last four decades of the 20th Century also represent one of the wettest periods in the reconstruction. The proxy record indicates that the instrumental record (approximately 1900 to the Present) underestimates the potential frequency and severity of severe, sustained droughts in this area, while over representing the prominence of wet episodes. In the longer record, the empirical probability of any decadal scale drought exceeding the duration of the 1954 through 1964 drought is 94 percent, while the probability for any wet event exceeding the duration of the 1965 through 1999 wet spell is only 1 percent. Hence, estimates of future water availability in the Uinta Basin and forecasts for exports to the Colorado River, based on the 1961 to 1990 and 1971 to 2000 “normal” periods, may be overly optimistic.

Utah

Reducing sedimentation of depressional wetlands in agricultural landscapes

Depressional wetlands in agricultural landscapes are easily degraded by sediments and contaminants accumulated from their watersheds. Several best management practices can reduce transport of sediments into wetlands, including the establishment of vegetative buffers. We summarize the sources, transport dynamics, and effect of sediments, nutrients, and contaminants that threaten wetlands and the current knowledge of design and usefulness of grass buffers for protecting isolated wetlands. Buffer effectiveness is dependent on several factors, including vegetation structure, buffer width, attributes of the surrounding watershed (i.e., area, vegetative cover, slope and topography, soil type and structure, soil moisture, amount of herbicides and pesticides applied), and intensity and duration of rain events. To reduce dissolved contaminants from runoff, the water must infiltrate the soil where microbes or other processes can break down or sequester contaminants. But increasing infiltration also diminishes total water volume entering a wetland, which presents threats to wetland hydrology in semi-arid regions. Buffer effectiveness may be enhanced significantly by implementing other best management practices (e.g., conservation tillage, balancing input with nutrient requirements for livestock and crops, precision application of chemicals) in the surrounding watershed to diminish soil erosion and associated contaminant runoff. Buffers require regular maintenance to remove sediment build-up and replace damaged or over-mature vegetation. Further research is needed to establish guidelines for effective buffer width and structure, and such efforts should entail a coordinated, regional, multi-scale, multidisciplinary approach to evaluate buffer effectiveness and impacts. Direct measures in "real-world" systems and field validations of buffer-effectiveness models are crucial next steps in evaluating how grass buffers will impact the abiotic and biotic variables attributes that characterize small, isolated wetlands. ?? 2008 The Society of Wetland Scientists.

Wetlands

Water tracks enhance water flow above permafrost in upland Arctic Alaska hillslopes

Upland permafrost regions occupy approximately one third of the Arctic landscape. In upland regions, hydrologic fluxes are influenced by water tracks, curvilinear features on hillslopes that preferentially fill with and route water in response to snowmelt and rainfall when the soil above continuous permafrost thaws in the summer. As continued warming of the Arctic may alter hydrologic cycling leading to increased frequency of extreme hydrologic events like drought and flooding as well as modification of biogeochemical cycling, it is imperative to untangle the interplay between precipitation, runoff, and subsurface flow as water is routed from upland Arctic regions to the Arctic Ocean. This study quantifies how ground surface temperatures affect groundwater discharge from hillslopes with water tracks in the upland Arctic by employing a three-dimensional, physically based subsurface flow model with variable saturation and freeze and thaw capabilities that is calibrated to field measurements from the Upper Kuparuk River watershed on the North Slope of Alaska, USA. Model analysis indicates that higher ground surface temperatures along water track hillslopes promote increases in groundwater discharge where water tracks act as conduits for large recharge events and continue to discharge groundwater into the autumn after the adjacent hillslope has frozen. Simulating the conditions that distinguish water tracks from their hillslope watersheds changes subsurface water storage and ground thermal responses but does not alter the total magnitude of groundwater discharge outside of parameter uncertainty. These findings suggest that water tracks play a complex and critical role in hydrologic cycles of the upland Arctic.

Alaska

Turbidity on the shallow reef off Kaulana and Hakioawa watersheds, north coast of Kaho'olawe, Hawai'i: Measurements of turbidity and ancillary data on winds, waves, precipitation, and stream flow discharge, November 2005 to June 2008

The island of Kaho`olawe has particular cultural and religious significance for native Hawaiians. Once known as Kanaloa, the island was a center for native Hawaiian navigation. In the mid-20th century, the island was used as a bombing range by the U.S. Navy, and that practice, along with the foraging by feral goats, led to a near-complete decimation of vegetation. The loss of ground cover led to greatly increased erosion and run-off of sediment-laden water onto the island's adjacent coral reefs. Litigation in 1990 ended the U.S. Navy's use of the island as a bombing range, and in 1994 the island was transferred to the Kaho`olawe Island Reserve Commission (KIRC), http://kahoolawe.hawaii.gov/. As a result of the litigation, the U.S. Navy began a 10-year clean-up effort that was the foundation for the present restoration effort by KIRC (Slay, 2009). The restoration effort is centered on revegetating the island, reducing erosion, and limiting run-off onto adjacent reefs. Restoration efforts to mitigate sediment runoff to streams and gulches by restoring native vegetation and minimizing erosion have focused on two watersheds, Kaulana and Hakioawa, on the northeast and northwest sides of the island, respectively. Stream flow and sediment gages were installed by the U.S. Geological Survey Pacific Islands Water Science Center in each of the watersheds, and a weather station was established upland of the watersheds. For this study, turbidity monitors were installed on the insular shelf off the two watersheds to monitor the overall quality of reef waters and their changes in response to rain and stream flow discharge events.

Hawaii

Mitigating the effects of landscape development on streams in urbanizing watersheds

This collaborative study examined urbanization and impacts on area streams while using the best available sediment and erosion control (S&EC) practices in developing watersheds in Maryland, United States. During conversion of the agricultural and forested watersheds to urban land use, land surface topography was graded and vegetation was removed creating a high potential for sediment generation and release during storm events. The currently best available S&EC facilities were used during the development process to mitigate storm runoff water quality, quantity, and timing before entering area streams. Detailed Geographic Information System (GIS) maps were created to visualize changing land use and S&EC practices, five temporal collections of LiDAR (light detection and ranging) imagery were used to map the changing landscape topography, and streamflow, physical geomorphology, and habitat data were used to assess the ability of the S&EC facilities to protect receiving streams during development. Despite the use of the best available S&EC facilities, receiving streams experienced altered flow, geomorphology, and decreased biotic community health. These impacts on small streams during watershed development affect sediment and nutrient loads to larger downstream aquatic ecosystems such as the Chesapeake Bay.

Maryl

Using regression methods to estimate stream phosphorus loads at the Illinois River, Arkansas

The development of total maximum daily loads (TMDLs) requires evaluating existing constituent loads in streams. Accurate estimates of constituent loads are needed to calibrate watershed and reservoir models for TMDL development. The best approach to estimate constituent loads is high frequency sampling, particularly during storm events, and mass integration of constituents passing a point in a stream. Most often, resources are limited and discrete water quality samples are collected on fixed intervals and sometimes supplemented with directed sampling during storm events. When resources are limited, mass integration is not an accurate means to determine constituent loads and other load estimation techniques such as regression models are used. The objective of this work was to determine a minimum number of water-quality samples needed to provide constituent concentration data adequate to estimate constituent loads at a large stream. Twenty sets of water quality samples with and without supplemental storm samples were randomly selected at various fixed intervals from a database at the Illinois River, northwest Arkansas. The random sets were used to estimate total phosphorus (TP) loads using regression models. The regression-based annual TP loads were compared to the integrated annual TP load estimated using all the data. At a minimum, monthly sampling plus supplemental storm samples (six samples per year) was needed to produce a root mean square error of less than 15%. Water quality samples should be collected at least semi-monthly (every 15 days) in studies less than two years if seasonal time factors are to be used in the regression models. Annual TP loads estimated from independently collected discrete water quality samples further demonstrated the utility of using regression models to estimate annual TP loads in this stream system.

Arkansas

Quality of Wisconsin stormwater, 1989-94

Water-quality data were compiled from four urban stormwater monitoring projects conducted in Wisconsin between 1989 and 1994. These projects included monitoring in both storm-sewer pipes and urban streams. A total of 147 constitu ents were analyzed for in stormwater sampled from 10 storm-sewer pipes and four urban streams. Land uses represented by the storm-sewer watersheds included residential, commercial, industrial, and mixed. For about one-half the con stituents, at least 10 percent of the event mean con centrations exceeded the laboratory's minimum reporting limit. Detection frequencies were greater than 75 percent for many of the heavy metals and polycyclic aromatic hydrocarbons in both the storm sewer and stream samples, whereas detec tion frequencies were about 20 percent or greater for many of the pesticides in both types of sam ples. Stormwater concentrations for conventional constituents, such as suspended solids, chloride, total phosphorus, and fecal coliform bacteria were greater than minimum reporting limits almost 100 percent of the time. Concentrations of many of the constituents were high enough to say that stormwater in the storm sewers and urban streams might be contrib uting to the degradation of the streams. In this report, constituents defined as potential contami nants are those for which the laboratory minimum report limit was exceeded for at least 10 percent of the sampled storm events, and for which at least one event mean concentration exceeded an estab lished water-quality standard. Storm-sewer sam ples had event mean concentrations of lead, copper, zinc, cadmium, and silver that frequently exceeded Wisconsin's acute toxicity criteria for cold water fisheries. Wisconsin's human cancer criteria was exceeded almost 100 percent of the time for polycyclic aromatic hydrocarbons in stormwater samples from storm sewers and streams. Maximum concentrations of diazinon found in storm sewers exceeded recommended levels of diazinon. Storm-sewer samples also exceeded Wisconsin's ground-water enforcement standards for pesticides, PCB's, phthalates, and chloride. Defined by criteria in this report, poten tial contaminants included five metals (lead, zinc, copper, silver, and cadmium), nine polycyclic aro matic hydrocarbons, Bis(2-ethylhexyl)phthalate, four pesticides (DDT, atrazine, alachlor, and 2,4 D), suspended solids, chlorides, total phosphorus, BOD 5-day, and bacteria. Wisconsin stormwater quality was similar to stormwater quality monitored in other states. Nearly one-half of median concentrations of con stituents in Wisconsin stormwater were within 30 percent of the medians from other states. The clos est agreement was seen for biochemical oxygen demand, total phosphorus, and total recoverable zinc. Similarities in stormwater quality for the storm sewer and urban streams indicated the storm sewers were a major source of water to the streams during storm events. Concentrations of potential contaminants in urban streams increased dramati cally during storm events as compared to baseflow concentrations.

Wisconsin

Exploring the regional dynamics of U.S. irrigated agriculture from 2002 to 2017

The United States has a geographically mature and stable land use and land cover system including land used as irrigated cropland; however, changes in irrigation land use frequently occur related to various drivers. We applied a consistent methodology at a 250 m spatial resolution across the lower 48 states to map and estimate irrigation dynamics for four map eras (2002, 2007, 2012, and 2017) and over four 5-year mapping intervals. The resulting geospatial maps (called the Moderate Resolution Imaging Spectroradiometer (MODIS) Irrigated Agriculture Dataset or MIrAD-US) involved inputs from county-level irrigated statistics from the U.S. Department of Agriculture, National Agricultural Statistics Service, agricultural land cover from the U.S. Geological Survey National Land Cover Database, and an annual peak vegetation index derived from expedited MODIS satellite imagery. This study investigated regional and periodic patterns in the amount of change in irrigated agriculture and linked gains and losses to proximal causes and consequences. While there was a 7% overall increase in irrigated area from 2002 to 2017, we found surprising variability by region and by 5-year map interval. Irrigation land use dynamics affect the environment, water use, and crop yields. Regionally, we found that the watersheds with the largest irrigation gains (based on percent of area) included the Missouri, Upper Mississippi, and Lower Mississippi watersheds. Conversely, the California and the Texas–Gulf watersheds experienced fairly consistent irrigation losses during these mapping intervals. Various drivers for irrigation dynamics included regional climate fluctuations and drought events, demand for certain crops, government land or water policies, and economic incentives like crop pricing and land values. The MIrAD-US (Version 4) was assessed for accuracy using a variety of existing regionally based reference data. Accuracy ranged between 70% and 95%, depending on the region.

Conterminous United States

Surface-water quality and suspended-sediment quantity and quality within the Big River Basin, southeastern Missouri, 2011-13

Missouri was the leading producer of lead in the United States&mdash;as well as the world&mdash;for more than a century. One of the lead sources is known as the Old Lead Belt, located in southeast Missouri. The primary ore mineral in the region is galena, which can be found both in surface deposits and underground as deep as 200 feet. More than 8.5 million tons of lead were produced from the Old Lead Belt before operations ceased in 1972. Although active lead mining has ended, the effects of mining activities still remain in the form of large mine waste piles on the landscape typically near tributaries and the main stem of the Big River, which drains the Old Lead Belt. Six large mine waste piles encompassing more than 2,800 acres, exist within the Big River Basin. These six mine waste piles have been an available source of trace element-rich suspended sediments transported by natural erosional processes downstream into the Big River. A study was performed by the U.S. Geological Survey in cooperation with U.S. Environmental Protection Agency, Region 7, to calculate and characterize suspended-sediment quantity and quality within the Big River basin after reclamation of the mine waste piles ended in 2012. Streamflow and suspended sediments were quantified and sampled at two locations along a 68-mile reach of the Big River between Bonne Terre and Byrnes Mill, Missouri. The results will help regulatory agencies, such as the U.S. Environmental Protection Agency and U.S. Fish and Wildlife Service, determine impaired reaches and ecosystems for remedial and restoration efforts. Continuous stream stage, water temperature, and turbidity, and discrete suspended-sediment concentration data were collected at the two sites between October 2011 and September 2013. Suspended-sediment samples were collected during various hydrologic conditions to develop a regression model between discrete suspended-sediment concentration and continuous turbidity. Suspended sediments collected during stormflow events were analyzed for concentrations of trace elements such as barium, cadmium, lead, and zinc within two sediment size fractions. Event loads and annual loads of suspended sediment and select trace elements in suspended sediments also were calculated. Suspended-sediment loads computed by the regression model increased downstream from about 201,000 tons at the upstream site to about 355,000 tons at the downstream site during the study period. Stormflow-event-based (hereinafter referred to as &ldquo;event-based&rdquo;) suspended-sediment loads ranged from 180 to 32,000 tons at the upstream sampling site and 390 to 53,000 tons at the downstream site along the Big River. Although only seven stormflow events at the upstream site and six at the downstream site were sampled, the event-based suspended-sediment loads accounted for nearly 30 percent of the total suspended-sediment loads computed at both sites, indicating most of the suspended sediment transported through the Big River occurs during higher streamflows. Sediment quality guidelines, known as the threshold effect concentration and the probable effect concentration, used to assess toxicity of trace-element concentrations in sediments were compared to the cadmium, lead, and zinc concentrations in suspended sediment samples collected during stormflow events. All concentrations of cadmium, lead, and zinc in event-based suspended sediment samples exceeded the threshold and probable effect concentrations. Lead and zinc concentrations in the sediment size fraction less than 0.063 millimeters also exceeded the toxic effect threshold, above which sediment is considered to be heavily polluted causing adverse effects on sediment-dwelling organisms. Concentrations of cadmium and zinc in event-based suspended sediment samples were notably higher in samples from the upstream site than samples from the downstream site, indicating the sources of sediments enriched in these trace elements decrease in the downstream area of the watershed. The reduction in concentration of cadmium and zinc could be from dissolution of the constituents during transport or possibly a decrease in downstream source material. The lead concentration exceedance of the probable effects concentration as well as the threshold effects concentration indicates that lead-rich suspended sediments in the fraction less than 0.063 millimeters are readily available within the Big River Basin for transport. These sediments remain in the system from historical mining, and as the reclamation of mine waste piles in the upstream area of the watershed reduce additional sediment loadings, these fine sediments may be continually released as the river scours the streambed and erodes stream banks causing the lead-rich suspended sediment to remain in a state of equilibrium. Barium concentrations in suspended-sediments were nearly twice as high in stormflow event samples collected at the downstream site as compared to samples from the upstream site. The source of barium in the Big River could be from Mineral Fork and Mill Creek, which flow through the historical barite (barium sulfate, also known as tiff) mining district in Washington County, and discharge into the Big River between the two study sites. Total trace-element loads and yields in suspended sediments were computed from the sampled events for each year in the study. The total barium loads in suspended sediments were higher for sampled events collected at the downstream site than the upstream site during both study years. Cadmium and zinc loads in suspended sediments were lower at the downstream site than the upstream site, although the decrease in total load was not substantial during the study period. Lead loads in suspended sediments were lower at the downstream site during the first study year, with a slightly higher load downstream in the second year though the increase from upstream to downstream was small. Event-based yields were higher at the upstream site, indicating that readily available sediment sources are closer to the upstream site where more mining affected areas are located. The estimates determined during large precipitation events indicate that large sources of suspended sediments with large concentrations of trace elements are still available for transport within the Big River.

Missouri

Chloride concentrations, loads, and yields in four watersheds along Interstate 95, southeastern Connecticut, 2008-11: factors that affect peak chloride concentrations during winter storms

Chloride (Cl - ) concentrations and loads and other water chemistry characteristics were assessed to evaluate potential effects of road-deicer applications on streamwater quality in four watersheds along Interstate 95 (I&ndash;95) in southeastern Connecticut from November 1, 2008, through September 30, 2011. Streamflow and water quality were studied in the Four Mile River, Oil Mill Brook, Stony Brook, and Jordan Brook watersheds, where developed land ranged from 9 to 32 percent. Water-quality samples were collected and specific conductance was measured continuously at paired water-quality monitoring sites, upstream and downstream from I&ndash;95. Specific conductance values were related to Cl - concentrations to assist in determining the effects of road-deicing operations on the levels of Cl - in the streams. Streamflow and water-quality data were compared with weather data and with the timing, amount, and composition of deicers applied to State highways. Grab samples were collected during winter stormwater-runoff events, such as winter storms or periods of rain or warm temperatures in which melting takes place. Grab samples were also collected periodically during the spring and summer and during base-flow conditions. The estimated Cl - concentrations at the eight water-quality monitoring sites during winter storms peaked as high as 270 milligrams per liter (mg/L) and were well below the U.S. Environmental Protection Agency (EPA) recommended acute chloride toxicity criterion of 860 mg/L and the chronic 4-day average toxicity criterion of 230 mg/L. Cl - concentrations in streams, particularly at sites downstream from I&ndash;95, peaked during increased streamflow in the winter and early spring as a result of deicers applied to roads and washed off by stormwater or meltwater. Cl - concentrations during most of the nonwinter seasons decreased during increases in streamflow because storm runoff was more dilute than base flow. However, peaks in specific conductance and estimated chloride concentrations at streams in more urbanized watersheds corresponded to peaks in streamflow well after winter snow or ice events; these delayed peaks in Cl - concentration likely resulted from deicer residue that remained in melting snow piles and on roadsides and (or) that were flushed from soils and shallow groundwater, then discharged downstream. Estimated peak Cl - concentrations varied with the type of winter storm event and were highest during or after winter storms of frozen precipitation and rain, in which the rain or meltwater effectively washed off the deicers. Estimated peak Cl - concentrations correlated positively with the duration of deicer application but generally not with streamflow. Estimated peak Cl - concentrations during the winter season were highest during low streamflow at most sites. Chloride concentrations varied considerably in shallow groundwater as a result of land-use differences. Cl - concentrations were very high (as high as 800 mg/L) in shallow groundwater downstream from I&ndash;95 at the Four Mile River site. Chloride/bromide mass concentration ratios and the proximity of a former landfill and sewage lagoon upstream indicate a likely source of Cl - is landfill leachate and possibly sewage leachate. Cl - loads in streams generally were highest in the winter and early spring. The estimated daily Cl - yield for the four monitoring sites downstream from I&ndash;95 ranged from 0.0004 ton per day per square mile for one of the least developed watersheds to 0.052 ton per day per square mile for the watershed with the highest percentage of urban development and impervious area. The estimated median contribution of Cl - load from atmospheric deposition was small and ranged from 0.07 percent of Cl - load at the Jordan Brook watershed to 0.57 percent at the Oil Mill Brook watershed. The Cl - loads in streams (outputs) were compared with Cl - load inputs, which include atmospheric deposition and deicer applications; Cl - load inputs were slightly larger than the Cl - load outputs at most of the sites during most years but do not account for the Cl - load in groundwater leaving the watersheds. A multiple linear regression model was developed to describe the variability of the natural log of peak specific conductance, as well as estimated Cl - concentrations. Five significant variables best explained the variability in the natural log of the peak specific conductance after deicing events: (1) snow on ground before deicing event; (2) winter precipitation with rain; (3) specific conductance in base flow; (4) State-operated road lane miles divided by watershed area; and (5) amount of Cl - from deicers applied to State-operated roads per lane mile. In this report, winter precipitation is defined as any type of precipitation, including frozen precipitation and rain, that occurs during the active deicing season, typically November through March. Frozen precipitation is defined here as snow, sleet, freezing rain, or any winter precipitation except rain. The addition of a lane mile in both directions on I&ndash;95 would result in an estimate of approximately 2 to 11 percent increase in Cl - input from deicers applied to I&ndash;95 and other roads maintained by Connecticut Department of Transportation. The largest estimated increase in Cl - load was in the watersheds with the greatest number miles of I&ndash;95 corridor relative to the total lane miles maintained by Connecticut Department of Transportation. On the basis of these estimates and the estimated peak Cl - concentrations during the study period, it is unlikely that the increased use of deicers on the additional lanes would lead to Cl - concentrations that exceed the aquatic habitat criteria.

Connecticut

Large streamflow differences between forested and urbanized watersheds in the energy-limited eastern United States: The role of evapotranspiration and impervious surfaces

Urban forests and other green infrastructures have been viewed as part of the “Nature-based Solutions” (NbS) to mitigate emerging urban environmental change. This study focuses on the role of evapotranspiration (ET) in regulating water balances of small watersheds in the eastern United States. We compared streamflow and ET patterns at daily, monthly and annual scales and linked these hydrological variables to the physical properties of 11 paired watersheds dominated by forests (FW) or urban (UW) land covers. The annual precipitation ranged from 1028 mm to 1683 mm and potential ET (PET) from 815 mm to 1450 mm. The mean annual flow/precipitation (Q/P) ratios were 0.26 ± 0.13 and 0.41 ± 0.1 for FW and UW, respectively. Overall, UW had lower annual ET (772 mm in UW vs. 947 mm in FW), but higher mean annual and (∼58% higher), monthly water yield (17%–186% higher), and peakflow rates (up to 100 times higher) than FW. The streamflow differences between FW and UW were most pronounced during the growing season and early winter (June-November). The mean Q/P ratios for 30 large hurricane events (2016–2021) were 0.12 ± 0.11 and 0.38 ± 0.23 for FW and UW, respectively. The flow rates in the dormant season (around December-May) in UW were similar or lower than FW. We developed conceptual models to explain the seasonal and storm event streamflow differences using background climate (PET), ET, and land surface characteristics. Urban NbS designs should factor in strategies that maximize ET while minimizing impervious surfaces enhancing watershed “sponge” and “pump” functions.

eastern United States

Opportunities and challenges for precipitation forcing data in post-wildfire hydrologic modeling applications

The frequency and extent of wildfires have increased in recent decades with immediate and cascading effects on water availability in many regions of the world. Precipitation is used as primary input to hydrologic models and is a critical driver of post-wildfire hydrologic hazards including debris flows, flash floods, water-quality effects, and reservoir sedimentation. These models are valuable tools for understanding the hydrologic response to wildfire but require accurate precipitation data at suitable spatial and temporal resolutions. Wildfires often occur in data-sparse, headwater catchments in complex terrain, and post-wildfire hydrologic effects are particularly sensitive to high-intensity, short-duration precipitation events, which are highly variable and difficult to measure or estimate. Therefore, the assessment and prediction of wildfire-induced changes to watershed hydrology, including the associated effects on ecosystems and communities, are complicated by uncertainty in precipitation data. When direct measurements of precipitation are not available, datasets of indirect measurements or estimates are often used. Choosing the most appropriate precipitation dataset can be difficult as different datasets have unique trade-offs in terms of spatial and temporal accuracy, resolution, and completeness. Here, we outline the challenges and opportunities associated with different precipitation datasets as they apply to post-wildfire hydrologic models and modeling objectives. We highlight the need for expanded precipitation gage deployment in wildfire-prone areas and discuss potential opportunities for future research and the integration of precipitation data from disparate sources into a common hydrologic modeling framework.

WIREs Water