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235 records · Page 12Linked to original sources
USGS1995

Evaluation of ground-water flow and hydrologic budget for Lake Five-O, a seepage lake in northwestern Florida

Temporal and spatial distributions of ground-water inflow to, and leakage from Lake Five-O, a softwater, seepage lake in northwestern Florida, were evaluated using hydrologic data and simulation models of the shallow ground-water system adjacent to the lake. The simulation models indicate that ground-water inflow to the lake and leakage from the lake to the ground-water system are the dominant components in the total inflow (precipitation plus ground-water inflow) and total outflow (evaporation plus leakage) budgets of Lake Five-O. Simlulated ground-water inflow and leakage were approximately 4 and 5 times larger than precipitation inputs and evaporative losses, respectively, during calendar years 1989-90. Exchanges of water between Lake Five-O and the ground-water system were consistently larger than atmospheric-lake exchanges. A consistent pattern of shallow ground-water inflow and deep leakage was also evident throughout the study period. The mean time of travel from ground-water that discharges at Lake Five-O (time from recharge at the water table to discharge at the lake) was estimated to be within a range of 3 to 6 years. Flow-path evaluations indicated that the intermediate confining unit probably has a negligible influence on the geochemistry of ground-water inflow to Lake Five-O. The hydrologic budgets and flow-path evaluations provide critical information for developing geochemical budgets for Lake Five-O and for improving the understanding of the relative importance of various processes that regulate the acid-neutralizing capacity of softwater seepage lakes in Florida.

Florida↗
USGS2025

Characterizing sedimentary organic carbon in a hydrothermal spreading center, the Escanaba Trough

Sediments in critical marine mineral environments are of wide importance due to their preservation of both marine minerals and organic carbon (OC) stocks. However, OC storage and cycling is often overlooked in mineral system studies. This work characterizes sedimentary OC within the Escanaba Trough, a hydrothermal sulfide system off the coast of northern California. By utilizing ROV-based push coring, we collected sediments near and far from high temperature, low temperature, and inactive vents. We applied a multipronged organic geochemical approach, measuring bulk sediment, OC fractions of varying labilities, and biomarkers to tease apart the storage, source, and cycling of OC within this complex system. In contrast to past work indicating a primarily terrestrial source to deeper, Pleistocene sediments, our results suggest a primarily marine source in surface sediments at least 50 m away from active venting. Near active venting, we see evidence of locally produced chemosynthetic OC in addition to the background marine source. This chemosynthetic OC appears to be rapidly remineralized and supports more complex deep-sea food webs compared to hemipelagic sites. Still, the greatest contribution of labile OC was observed at inactive vent sites, which we suggest is due to hydrothermal fluid alteration of more labile OC at actively venting sites. Depending on fluid temperature, hydrothermally altered OC is either preserved in the sediments as petroleum or migrated with fluid flow. Considering inactive sites are those most likely to be targeted by potential mining, we suggest additional studies could verify if these results apply at other sedimented seafloor massive sulfide systems.

California↗
USGS2025

Using peak geometry and shifts in the x-ray spectrum of carbon from electron probe microanalysis to determine thermal maturity of organic matter

During the burial of mudstones, the associated organic matter undergoes gradual thermal maturation, a key process that can influence the reactivity of organic matter during catagenesis, the formation of hydrocarbon deposits and the chemical weathering of mudstones. Conventional methods for assessing the thermal maturity of organic matter often fail to reflect the geochemical heterogeneity between individual organic phases in mudstone samples. Here, we report an alternative, non-destructive, surficial and micro-scale (analytical spot size of ~ 300 nm with about 4 μm diffusion depth for micrometre-size organic grains) method to evaluate the thermal maturity of organic matter in mudstones using the carbon K α X-ray spectrum measured by field emission-electron probe microanalyser (FE-EPMA). Using this method, we observed correlations between parameter values derived from FE-EPMA spectra, including the peak position, the peak area and the intra-sample heterogeneity of these measurements, and independently measured vitrinite/solid bitumen reflectance for a suite of mudstones, representing different age, geological context and burial depth. With the increased values in peak area and position, we identified an increase in the carbon mass fraction of organic matter and the mean nominal oxidation state of carbon approaching zero. These trends, which are consistent with aromatisation and graphitisation, provide the rationale for using FE-EPMA to estimate the thermal maturity of organic matter. To explore some of these trends in more detail, we employed time-of-flight secondary ionisation mass spectrometry, X-ray photoelectron spectroscopy and optical reflectance measurements on a subset of samples.

Geostandards and Geoanalytical Research↗
USGS2026

A review and synthesis of post-wildfire shifts in hydrologic processes and streamflow generation mechanisms

Critical water supply watersheds in the western United States (WUS) are impacted by wildfires, with potential negative effects on water quality and quantity. Scientific understanding is currently insufficient to deliver estimates of wildfire consequences for water quantity that are regionally accurate. Regional variability in the directionality and magnitude of post-wildfire shifts in streamflow generation fuels uncertainty in estimates of wildfire effects on water supply. In this work we provide a narrative review of wildfire effects on hydrologic processes and the resulting changes in streamflow generation mechanisms with a focus on the WUS, incorporating other global regions when pertinent. A conceptual model summary of wildfire effects on streamflow generation emphasizes: (1) precipitation seasonality, (2) synchrony of precipitation and potential evapotranspiration, (3) net shifts in interception, evaporation, and transpiration relative to total annual precipitation, (4) vegetation changes, including compensatory uptake and type conversion, (5) degree of overlap in rainfall rates and infiltration, (6) fire extent and severity, (7) burn scar positioning (e.g. in headwaters or proximal to watershed outlet), (8) scale-dependent groundwater leakage, (9) near-surface water storage reduction, and (10) soil to groundwater connectivity. Ongoing gaps and challenges include separating the influences of precipitation variability, water withdrawals, and post-fire land management; compound and overlapping disturbances; and lack of pre-fire data. Notable future opportunities include: harnessing ever-improving gridded and remotely sensed precipitation and fire-effects data; linking geophysical, isotopic tracer, and geochemical signatures to diagnose hydrologic changes; leveraging physically based and data-driven model advancements; and analyzing streamflow generation recovery trajectories across diverse watersheds.

western United States↗
USGS2026

Geologic map of pre-Middle Jurassic basement rocks beneath the Atlantic and Gulf Coastal Plains in Florida

Much of the southeastern United States, including all of Florida, is covered by flat-lying sedimentary strata of the Atlantic and Gulf Coastal Plains which have accumulated since Middle Jurassic time. The pre-Middle Jurassic rocks that underlie these coastal plains in Florida, here collectively referred to as “basement,” are known only from a relatively small number of boreholes. This scientific investigations map presents an interpretation of the basement geology in a 1:1,000,000-scale subsurface geologic map with supporting text, data, and figures. The subsurface mapping methodology integrates petrographic, geochronological, thermochronological, geochemical, and mineralogical analyses of drill cores and cuttings in the context of regional geophysical data. The pre-Middle Jurassic rocks of Florida consist of the Gondwanan (West African) Suwannee terrane which was accreted to Laurentia during the Alleghanian orogeny and subsequently intruded by Permian granites, superposed by early Mesozoic rift basins, and partially overlain by bimodal Jurassic volcanic rocks. The younger basement components, specifically the Southwest Florida volcanic province, North Florida tholeiites, early Mesozoic rift basins, and Alleghanian granitoids, have correlative and contemporaneous units throughout the Appalachian orogen. In contrast, Florida’s older basement rocks, including Paleozoic siliciclastic strata of the Suwannee basin, North Florida volcanic series, Osceola and Gaskin intrusive complexes, and the St. Lucie Metamorphic Complex, have neither surface exposures nor unequivocal correlates. Major structures include early Mesozoic normal faults and northwest-striking transfer zones such as the Jay fault. Many of these faults define the boundaries of subbasins within the South Georgia rift system. Top-of-basement structure contours show gentle arches and embayments that are also recognized in overlying coastal plain strata.

Florida↗
USGS2025

Projecting stream water quality using Weighted Regression on Time, Discharge, and Season (WRTDS): An example with drought conditions in the Delaware River Basin

Future water availability depends on understanding the responses of constituent concentrations to hydrologic change. Projecting future water quality remains a methodological challenge, particularly when using discrete observations with limited temporal resolution. This study introduces Weighted Regression on Time, Discharge, and Season for Projection (WRTDS-P), a novel, computationally efficient method that enables the projection of daily stream water quality under varying hydrologic conditions using commonly available discrete monitoring data. WRTDS-P model performance was validated using 39 sites in the Delaware River Basin (DRB) and four key constituents: specific conductance (SC), nitrate (NO 3 − ), magnesium (Mg 2+ ) and calcium (Ca 2+ ). Projections were tested against holdout data from the final 1 to 5 years of each time series, demonstrating robust predictive capability, with median Nash-Sutcliffe efficiencies of 0.67 for SC, 0.56 for NO 3 − , 0.65 for Ca 2+ , and 0.79 for Mg 2+ . Model uncertainty was correlated with indicators of hydrologic or geochemical mass-sinks, such as groundwater storage and adsorption in wetland soils. Drought scenario analyses for SC used ranges of reduced discharge including flows from the 1965 drought of record. Scenarios predicted widespread increases of SC, especially in southern DRB streams where baseline SC levels are already elevated. Fractional increases of SC were more uniformly distributed, indicating potential risk to sensitive ecosystems. Notably, drought-induced SC increases were positively correlated with interannual SC trends, indicating that hydrologic extremes could exacerbate ongoing salinization. This work provides a transferable and interpretable framework for projecting future water quality and assessing hydrologic risk to water resources and aquatic ecosystems.

Delaware, New Jersey, New York, Pennsylvania↗
USGS2025

Evidence of mineral alteration in a salt marsh subterranean estuary: Implications for carbon and trace element cycling

Subterranean estuaries (STE) in salt marshes are biogeochemically active zones where interactions between terrestrial groundwater and seawater drive complex cycling of carbon and trace elements, influenced by mineral dissolution. These systems, characterized by fine-grained organic-rich peat overlying permeable coastal aquifers, play a crucial role as a blue carbon sink, yet their geochemical dynamics remain poorly understood. We investigated dissolved trace elements, carbon, silica, and radium isotopes in a salt marsh STE (Sage Lot Pond, Waquoit Bay, MA) over seasonal and annual cycles. Our results reveal that groundwater and estuarine water circulation through marsh peat and aquifer sediments leads to enrichments of dissolved organic and inorganic carbon (DOC and DIC), Si, Ba, and Mn, with variable source/sink behavior of Fe and net removal of U. Submarine groundwater discharge dominated Ba fluxes, whereas pore water drainage from marsh peat acted as the main sink for U and source of Si. Fe cycling was variable, with terrestrial Fe largely removed as groundwater passed through the STE, consistent with Fe-sulfide and amorphous phase formation. Radium isotope ratios identified two distinct subsurface flow pathways, influenced by metal-oxide cycling and organic matter breakdown. Si production was decoupled from DIC, suggesting Si originates from mineral alteration, whereas DIC results from both mineral weathering and microbial respiration. Silicate mineral alteration, coupled with marsh pore water drainage, accounts for up to 16% of annual DIC exports (66 g C m −2 y −1 ), highlighting the importance of STEs in coastal carbon and trace element cycling, especially as marshes face environmental change.

Massachusetts↗
USGS2026

Deep subsurface organic-rich shale supports abundant, diverse, and novel fungi

As Earth’s principal reservoir of organic carbon and microbial biomass, the deep subsurface hosts microorganisms capable of mobilizing this once-sequestered carbon. Contrary to standard assumptions of eukaryotic scarcity, this study documents abundant fungal communities, ranging from 4.2 × 10 3 to 6.8 × 10 3 fungal cells mL −1 , across a methane-producing organic-rich shale 247–556 meters below the surface. Although fungal:bacterial cell ratios ranged from 1:7028 to 1:713, application of biomass conversion factors developed for oceanic systems yielded a median fungal:bacterial biomass ratio of 1:4.7. 16S rRNA gene amplicons revealed bacterial and archaeal communities mirroring those found in well-characterized extremophilic, carbon-degrading environments, while sequencing of 18S rRNA gene and ITS rRNA spacer amplicons collectively identified a eukaryotic hotspot with 689 fungal OTUs across six phyla. The dominant fungal classes, Agaricomycetes and Dothideomycetes, are well-established degraders of recalcitrant carbon compounds at the surface, suggesting they may similarly contribute to organic matter degradation and ecosystem maintenance in the subsurface. Cultivation and isolation efforts yielded 205 fungal strains, including 13 candidate novel taxa, underscoring the deep subsurface as an underexplored eukaryotic habitat. Stable carbon isotopes indicate methane is predominantly generated via microbial conversion of the fossil carbon, while water isotopes suggest in situ geochemical conditions have been relatively stable since the Late Pleistocene, with subglacial recharge as a plausible mechanism for microbial introduction. Collectively, these findings suggest that fungi are underrecognized contributors to organic matter transformation and functional diversity in the deep biosphere, revealing a critical gap in our understanding of deep subsurface ecosystem processes.

Indiana, Michigan, Ohio↗
USGS1976

Corwin Springs Known Geothermal Resources Area, Park County, Montana

The Corwin Springs Known Geothermal Resources Area (KGRA) is contiguous to Yellowstone National Park along a part of the northern boundary of the park near Gardiner, Park County, Mont. The area contains two known sites of hot-spring activity--LaDuke Spring, 2.8 km southeast of the small resort community of Corwin Springs, and Bear Creek Spring, 2.6 km east of Gardiner. LaDuke Spring issues from brecciated quartzite and has a flow rate of 380 1/min, a surface water temperature of 65°C, a silica-geothermometer temperature of 68.7°C, and a Na-K-Ca geothermometer temperature of 76.8°C. Bear Creek Spring issues from limestone and has a flow rate of 4 1/min, a surface water temperature of 32°C, a silica temperature of 46.7°C, and a Na-K-Ca temperature of 87.2°C. The springs, which are actively depositing travertine, are on or near the trace of the Gardiner fault-a high-angle reverse fault which forms the southwestern boundary of the Beartooth uplift. Features that make the Corwin Springs KGRA potentially significant include: (1) Proximity of the Corwin Springs area to significant Pliocene and Pleistocene volcanism in Yellowstone National Park and related geothermal activity, (2) existence of a large potential geothermal reservoir in the northern extension of the Sepulcher Mountain graben, (3) localization of thermal activity along the Gardiner fault in the Corwin Springs area, (4) occurrence of negative gravity anomaly centered over the northern end of the Sepulcher Mountain graben, (5) existence of negative magnetic anomaly in the Corwin Springs area, (6) location of the area within the Intermountain seismic belt, (7) evidence of recent tectonism in the area, as demonstrated by Pleistocene and Holocene faulting, and (8) observed surface temperatures and estimated geochemical temperatures of the two known hot springs (features which do not indicate high subsurface temperatures).

Montana↗
USGS2024

Dissolved arsenic concentrations in surface waters within the upper portions of the Klamath River Basin, Oregon and California

Arsenic toxicity is an environmental health problem. Levels of arsenic in surface waters at some locations in the Klamath River Basin in southern Oregon and northern California can exceed the U.S. Environmental Protection Agency (EPA) standard for drinking water. There are both anthropogenic and natural sources of arsenic. The Klamath River Basin consists primarily of volcanic deposits and contains an underground geothermal system with hot springs and warm water wells, all known natural sources of arsenic. Anthropogenic sources of arsenic are related to the agricultural use of herbicides, fungicides, and insecticides. Surface water arsenic levels can also be affected by fertilizer amendments, evaporative concentration, oxygen-level depletion, and various geochemical transformations that can increase arsenic mobilization. In this study by the U.S. Geological Survey and the Bureau of Reclamation, dissolved concentrations of arsenic, copper, and lead were measured in surface waters at 39 unique sites within the upper portions of the Klamath River Basin between 2018 and 2022. In every year, except 2022, sites were sampled four times between April and November. Surface-water arsenic concentrations varied up to four-orders of magnitude among sites. Median arsenic concentration was lowest at Cherry Creek (0.03 micrograms per liter [μg/L]) and highest at Wood Kimball Spring (36.7 μg/L), two sites located north of Upper Klamath Lake. The highest arsenic concentrations (17.4±4.9 μg/L, n =3) were found in drain sites (defined here as a waterbody returning used irrigation water) while the lowest arsenic concentrations were found in an artesian well (0.8 μg/L, n =1). The elevated arsenic concentrations of the drain sites suggest that arsenic might be concentrated or mobilized by agricultural activities, water re-use practices, and (or) by geochemical processes occurring around water stored in drains (that is, in the water column and across sediment water boundaries). A source of arsenic in drain water in the Klamath Strait Drain area includes water used for irrigation originating from Ady Canal. Other potential sources include groundwater, geothermal water, and local soils and sediments. Seasonal differences in surface-water arsenic concentrations were detected at 13 sites, 10 of which had higher arsenic concentrations in summer than in either spring or fall. The sites sampled around Upper Klamath Lake, the impounded rivers, one of the two canal sites, and 5 of the 14 river sites had higher surface-water arsenic concentrations in the summer than in either spring or fall. Surface-water arsenic concentrations from groundwater sources (that is, springs and in the artesian well) did not vary significantly among seasons (p-values greater than 0.1). Median surface-water concentrations of copper and lead ranged from 0.03 to 3.7 μg/L, and from 0.013 to 0.175 μg/L ( n =2–18), respectively. Dissolved concentrations of both metals were below acute toxicity endpoints reported by the EPA for freshwater animals. Surface-water arsenic concentrations varied independently from corresponding changes in surface-water lead or copper concentrations. However, arsenic concentrations measured in bed-sediment samples collected from a subset of sites located north of Upper Klamath Lake correlated strongly and significantly with the corresponding sedimentary lead concentrations ( p =0.015). Aqueous arsenic speciation measured in a subset of sites in 2019 and 2022 showed that all the arsenic existed as arsenic (V), the most oxidized arsenic species, and presumably, the least toxic. The highest proportions of arsenite (As(III)), the presumably most toxic arsenic species, relative to total arsenic concentrations were found at drain sites. Our assessment of dissolved arsenic concentrations in various surface-water bodies in the Upper Klamath River Basin reveals geographical areas of consistently low (below 2.1 μg/L), moderate (below 10 μg/L) and high (above 10 μg/L) surface-water arsenic concentrations. South of Upper Klamath Lake, surface-water arsenic concentrations were consistently higher than 20 μg/L at two drain sites located in an area of predominant agricultural land use with extensive water re-use practices. North of Upper Klamath Lake, surface-water arsenic concentrations greater than 20 μg/L were consistently measured at sites with limited nearby agricultural activities, suggesting a geogenic source. The consistently high arsenic levels from the Wood River at Jackson F. Kimball State Park, Fort Creek, and Crooked Creek, which are sites located at or near headwater spring sources, suggest a natural background source of arsenic. Water flowing downstream from this area could be a potential source of arsenic to Upper Klamath Lake and the Upper Klamath River.

California, Oregon↗
USGS2025

Summary of selenium in the lower Gunnison River Basin, Colorado—Information and data gaps

The Cretaceous Mancos Shale is a geologic source of selenium in the lower Gunnison River Basin. Natural weathering processes and human activity mobilize selenium from the Mancos Shale and derived materials, and surface water, groundwater, and sediment all affect the transport of selenium from source areas to receiving streams and biota. Selenium accumulates through the aquatic food chain, and its toxic effects can result in invertebrate mortality and mortality, decreased reproduction, and deformities to fish and birds. The Bureau of Reclamation, in cooperation with the State of Colorado and Gunnison River Basin water users, is implementing a Selenium Management Program to reduce selenium concentrations in the lower Gunnison River Basin of Colorado. Goals of the Selenium Management Program are to (1) achieve compliance with the State of Colorado chronic aquatic-life standard for dissolved selenium (4.6 micrograms per liter) in the Gunnison River near Grand Junction, Colorado; (2) sufficiently improve water-quality conditions to assist in the recovery of endangered species in the Gunnison and Colorado Rivers by reducing selenium concentrations; and (3) support continued water uses in the basin. Many previous studies have contributed to the understanding of selenium in the environment; however, monitoring and research data gaps exist in the lower Gunnison River Basin. The purpose of this report is to summarize information regarding selenium in the lower Gunnison River Basin and describe strategies for scientific research and monitoring to potentially improve understanding of selenium sources; processes affecting the mobilization, transport, and fate of selenium; and the effects of selenium-mitigation projects in the lower Gunnison River Basin. Monitoring and research data gaps discussed in this report include geologic mapping and geochemical source characterization, long-term and ongoing monitoring of the surface-water and groundwater networks, developing and refining statistical models, characterizing selenium on suspended sediment, modeling selenium in the food web, evaluating best management practices, and more.

Colorado↗
USGS2025

Sources of water and salts for the Zuni Salt Lake in west-central New Mexico

The Zuni Salt Lake is located in a maar in west-central New Mexico and contains hypersaline water that has long been used by Native Americans for religious purposes and the collection of salt. There have been several investigations suggesting different sources for the water and salt to the lake. Springs, seeps, and ephemeral streamflow have all been observed to contribute freshwater to the lake, and brackish to hypersaline seeps have been documented along the banks of the lake. This report summarizes the findings of a study that characterizes the lake’s hydrology, its water and salinity sources, and the hydrogeologic conceptual model. Regional groundwater levels indicate that each of the aquifers in the area have the potential to discharge groundwater to the lake. There is also evidence of vertical groundwater flow pathways at the maar that were likely created by the igneous intrusion that fractured the intersecting aquifers. A detailed water budget was constructed from continuous lake stage, precipitation, and evaporation data to estimate the groundwater inflow to the Zuni Salt Lake. It was determined that groundwater inflow to the lake is 441 ±94 acre-feet per year, which composes as much as 77 percent of the total inflows. The high sodium and chloride concentrations measured in two hypersaline samples collected near the lake indicate that the majority of the dissolved solids entering the lake are from a hypersaline groundwater source. The geochemical and isotopic compositions measured in the lake and surrounding features support the interpretation that hypersaline groundwater is the primary source of salts to the lake, which is likely sourced from the older (and deeper) Permian units. The hypersaline groundwater samples collected during this investigation have a unique aqueous chemistry relative to each of the mapped aquifers, and variability in groundwater compositions is interpreted to result from differences in minerology and residence time.

New Mexico↗
USGS2025

The δ13C signature of dissolved organic and inorganic carbon reveals complex carbon transformations within a salt marsh

Coastal wetlands have high rates of atmospheric CO 2 uptake, which is subsequently respired back to the atmosphere, stored as organic matter within flooded, anoxic soils, or exported to the coastal ocean. Transformation of fixed carbon occurs through a variety of subsurface aerobic and anaerobic microbial processes, and results in a large inventory of dissolved carbon. Carbon source and the roles of aerobic respiration, sulfate reduction, and methane cycling were evaluated within salt marsh peat and the underlying sandy subterranean estuary. There is a large increase in dissolved inorganic carbon (DIC, 7,350 ± 3,900 μmol L −1 ), dissolved organic carbon (DOC, 1,040 ± 1,480 μmol L −1 ) and CH 4 (14.5 ± 33.3 μmol L −1 ) within the marsh porewaters compared to creek waters. Alkalinity production (5,730 ± 2,170 μeq L −1 ) and sulfate removal (1,810 ± 1,970 μmol L −1 ) indicate anaerobic respiration, however, relative contributions from the various decomposition pathways cannot be identified due to overlapping geochemical signatures. The δ 13 C of the DOC (−29.0 ± 3.7‰) and DIC (−11.2 ± 1.1‰) produced within the marsh differed from the bulk soil organic matter δ 13 C (−14.5 ± 0.2‰). We explore a variety of mechanisms that could result in co-occurring depleted δ 13 C-DOC and enriched δ 13 C-DIC compared to the bulk soil organic carbon pool and salt marsh vegetation, including selective mineralization, production of δ 13 C-depleted bacterial biomass, and methane-derived DOC. While important questions remain about carbon cycling pathways, we found evidence of a cryptic methane cycle. Alteration of the δ 13 C of carbon species complicates source attribution in solid and dissolved phases and careful consideration should be used when carbon is partitioned between in situ salt marsh production and external marine and terrestrial sources.

Massachusetts↗
USGS2024

Groundwater quality near the Placerita Oil Field, California, 2018

Groundwater-quality data and potential fluid-migration pathways near the Placerita Oil Field in Los Angeles County, California, were examined by the U.S. Geological Survey to determine if oil-field fluids (water and gas from oil-producing and non-producing zones) have mixed with groundwater resources. Six of the 13 new groundwater samples collected for this study contained petroleum hydrocarbons, thermogenic gas, inorganic chemical signatures, and (or) isotopic values consistent with potential mixing with fluids from hydrocarbon-bearing formations. For historical groundwater samples, benzene was the most detected petroleum hydrocarbon. The historical groundwater samples with a benzene concentration greater than 0.5 micrograms per liter were from environmental monitoring wells at industrial or commercial facilities unrelated to oil and gas development that, in many cases, have identified soil or groundwater contamination and were not typically analyzed for other constituents that could provide additional lines of evidence for potential mixing with oil-field fluids. Methane was not detected in any of the 12 historical samples with a reported measurement. Reviewing historical data revealed factors that could potentially adversely affect groundwater quality in the study area. These factors include modified hydraulic gradients caused by large volumes of water extracted from the main production area and reinjected downgradient into nonproducing zones, well-barrier failures in wells constructed in the northern part of the oil field before the 1970s, well-barrier failures in produced-water disposal wells downgradient from the main production area, and naturally occurring hydrocarbons at shallow intervals. The groundwater samples most geochemically similar to samples from hydrocarbon-bearing formations were in areas where hydrocarbons are naturally occurring at shallow intervals and where oil development is at shallow depths. Additional data for hydraulic heads, water quality, and formation temperatures at multiple depths in areas with large injection volumes and well-integrity issues are needed to evaluate whether those factors have contributed to mixing between fluids from oil-producing or injection formations and groundwater resources.

California↗
USGS2025

Reservoir thermal energy storage pre-assessment for the United States

Storing thermal energy underground for later use in electricity production or direct-use heating/cooling is a promising, viable, and economical green energy option. Reservoir thermal energy storage (RTES) is one such option, which stores energy in underutilized permeable strata with low ambient groundwater flow rates and more geochemically evolved (e.g. brackish/saline) waters relative to overlying principal aquifer systems. The U.S. Geological Survey has begun assessing RTES potential nationally by focusing on five generalized geologic regions (Basin and Range, Coastal Plain, Illinois Basin, Michigan Basin, Pacific Northwest) across the United States. Hydrogeologic reservoir models are developed for the following eight metropolitan area cities within those regions to evaluate RTES performance across different climates and subsurface conditions: Albuquerque, New Mexico; Charleston, South Carolina; Chicago and Decatur, Illinois; Lansing, Michigan; Memphis, Tennessee; Phoenix, Arizona; and Portland, Oregon. Evaluated metrics include estimated required well spacing, thermal storage capacity, and thermal recovery efficiency through time. Also considered for each reservoir are potential complicating factors, including reservoir depth, thermally driven free convection, and groundwater salinity. This work focuses on direct-use cooling because the need for cooling modern office buildings greatly exceeds that for heating in most parts of the country (Falta and others, 2016); however, the evaluated metrics are also relevant to heating and electricity applications. Results indicate that favorable RTES conditions exist in each region, with the Coastal Plain and Basin and Range being especially favorable for thermal storage capacity, while the Pacific Northwest and Michigan Basin excel at energy recovery for the evaluated cooling application. The results underscore the utility of developing maps of thermal storage capacity, subsurface temperature models, and volumetric estimates of thermal storage capacity to serve as key RTES resource classification standards. Overall, this pre-assessment provides a basic understanding of RTES potential in several cities and geologic regions throughout the country and will aid ongoing thermal energy storage assessment efforts.

Arizona, Illinois, Michigan, New Mexico, Oregon, S↗
USGS2026

Shallow differentiation of primitive arc magmas at the Jurassic Emigrant Gap mafic complex, Sierra Nevada, California

The Emigrant Gap composite pluton exposes ultramafic to silicic intrusive rocks that preserve the chemical evolution of primitive mafic arc magmas and their open-system interactions in the upper crust during mid-Jurassic growth of the Sierra Nevada batholith (California). We present field and petrographic observations and mineral and whole-rock chemistry of the ~35-km 2 ultramafic to dioritic Emigrant Gap mafic complex and an adjacent penecontemporaneous ~90-km 2 granodiorite that together make up the composite pluton. In the Emigrant Gap mafic complex, four roughly central masses of dunite, wehrlite, and olivine clinopyroxenite are surrounded by weakly layered gabbronorite and non-layered diorite. The ultramafic rocks are cumulates formed from near-liquidus minerals of primitive arc magmas that accumulated in steep feeder zones with substantial modification by melt–mush reaction as primitive liquids repeatedly transited the mush-filled conduits. The dominant gabbronoritic rocks are the variably accumulative products of more advanced crystallization–differentiation of arc tholeiitic basalts and basaltic andesites. The adjacent granodiorite intrusion originated separately and preserves field and geochemical evidence for assimilation of metasedimentary rocks. Open-system hybridization between the gabbronoritic mushes and the granodioritic magma produced an intervening body of two-pyroxene diorite. We infer that the ultramafic rocks and gabbronorite of the Emigrant Gap mafic complex crystallized from near-primitive arc basaltic to basaltic andesitic magmas at ~0.15–0.3 GPa, with estimated f O 2 of ≥FMQ +1 and dissolved H 2 O concentrations of only ~0.5–2 wt %. Notably, the Emigrant Gap composite pluton is distinct from other Mesozoic plutons in the Sierra Nevada batholith because of (1) its abundance of mafic and ultramafic rocks that crystallized from relatively primitive mafic melts and (2) the low inferred H 2 O concentrations of its parental magmas, indicated by a near absence of igneous amphibole and by the intermediate rather than calcic compositions of plagioclase. A Jurassic regional extension event probably accounts for the formation of relatively dry primitive arc magmas, as well as for their ascending to the upper crust.

California↗
USGS2025

Relating systematic molecular and textural properties of graptolite pyrolyzed via gold tube hydrous pyrolysis: Implications for thermal proxies in lower Paleozoic marine shales

A series of gold tube pyrolysis experiments (72 h, 300–550 °C, 50 MPa) conducted on a graptolite-rich lower Paleozoic marine shale generated pyrolysis residues for a comprehensive evaluation of the molecular and structural variability of three types of graptolite periderm. Organic petrology, Raman spectroscopy, and field emission scanning electron microscopy (FE-SEM) with energy dispersive spectroscopy (EDS) were combined to evaluate the thermal evolution process. The three types of graptolite periderm, namely granular, non-granular, and nodular graptolite, were analyzed by Raman spectroscopy wherein point measurements were obtained after the maceral was identified and the location verified by organic petrology. Distinct thermal evolution pathways among non-granular, granular, and nodular graptolite periderms were recorded. The evolution patterns of the Raman parameters, particularly D1 and G bands, highlight the differences in geochemical composition of the graptolite periderm types and the alteration of molecular structure with increasing thermal maturity. Raman parameters D1 (position of the D1 peak), G-FWHM (full width at half maximum of the G peak), and ratios D1-FWHM/G-FWHM (full width at half maximum of the D1 peak ratioed to G-FWHM) and A D1 /A G (ratio of D1 and G peak intensities) showed effectiveness in assessing thermal maturity. Bireflectance with increasing gold tube pyrolysis temperature followed a hierarchy: non-granular > granular > nodular, reflecting different molecular alignment intensities. Qualitative FE-SEM evaluation showed that fine-grained mineral inclusions (primarily Fe-sulfide as determined via EDS) were associated with the graptolite populations, with granular graptolite containing greater amounts of coarser-grained (e.g., ∼300–1400 nm) mineral inclusions relative to non-granular and nodular graptolite, which contain finer-grained (e.g., ∼100–200 nm) inclusions difficult to resolve with optical microscopy. These findings are investigated to highlight the mechanisms that drive organic matter evolution within graptolite during thermal maturation, as well as to explore some of the limitations of using spectroscopic parameters as thermal maturity proxies.

International Journal of Coal Geology↗
USGS2024

Indications of preferential groundwater seepage feeding northern peatland pools

Groundwater seepage from underlying permeable glacial sedimentary structures, such as eskers, has been hypothesized to directly feed pools in northern peat bogs. These hypotheses directly contradict classical peat bog models for ombrogenous systems, wherein meteoric water is the sole water input to these systems. Variations in the underlying mineral sediment in contact with the peat imply that unrecognized hydrogeologic connectivity may exist with pools in northern peat bogs, particularly where high permeability materials are in contact with the peat. Seepage dynamics originating from these structural variations were investigated using a suite of thermal and hydrogeophysical methods deployed around pools in a peat bog of northeastern Maine, USA. Thermal characterization methods mapped anomalies that were confirmed as matrix seepage or preferential flow pathways (PFPs). Geochemical methods were employed at identified thermal anomalies to confirm upwelling of solute-rich groundwater. Conduits around pools were associated with surficial terminations of suspected peat pipes, based on the inference of pathways extending down into the peat, that focus flow through PFPs in the peat matrix. Discharge also occurred through the peat matrix adjacent to suspected pipe structures and matrix seepage rates were quantified using analysis of diurnal temperature signals recorded at multiple depths. Seepage rates, with a maximum of nearly 0.4 m/d, were measured at localized points around pools. Periods of synchronized temperatures paired with highly muted diurnal temperature signals, recorded in diurnal temperature with depth data, were interpreted qualitatively as activation of strong upward discharge rates through suspected peat pipes. These time periods correlated strongly with local precipitation events around the peatland. Ground-penetrating radar surveys revealed discontinuities in the low permeability glacio-marine clay at the mineral sediment-peat interface, interpreted to be regional glacial esker deposits, which were located beneath and around pools. Heat tracing, specific conductance contrasts, seepage rates, and trace metal concentrations all imply groundwater seepage originating from underlying permeable glacial esker deposits and directly sourcing pools. Preferential groundwater inputs into northern peat bogs may play a key role in developing and maintaining pool systems, with enhanced solute transport impacting peatland ecology, water resources, and carbon cycling.

Maine↗