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USGS2020

Hydrogeology and shallow groundwater quality in the tidal Anacostia River watershed, Washington, D.C.

Groundwater hydrology and geochemistry within the tidal Anacostia River watershed of Washington, D.C. are related to natural and human influences. The U.S. Geological Survey, in cooperation with the District Department of Energy & Environment, began investigating the hydrogeology and groundwater quality of the watershed in 2002. Lithologic coring, groundwater-level and tidal monitoring, and water-quality sampling have been conducted to improve understanding of the groundwater-flow system, geochemistry, water quality, and the likely interaction between groundwater and the tidal Anacostia River. The flow and interaction of shallow groundwater with the tidal Anacostia River and other area streams are affected by diversions, pumping, land reclamation, and other human activities in this highly urbanized watershed. The tidal Anacostia River watershed is underlain by a wedge of unconsolidated sediments that is part of the Atlantic Coastal Plain Physiographic Province. These sediments form a system of confined and unconfined aquifers. The coarse sediments of the Potomac Group sand-dominated lithofacies form the Patuxent aquifer. The Patuxent aquifer crops out and subcrops in the northwestern part of the study area, but is confined to the southeast by the overlying Potomac Group clay-dominated lithofacies. Overlying the Potomac Group is a series of interbedded sands and clays that form an unconfined surficial aquifer system. Regional correlation in the unconfined surficial aquifer system is complicated by local heterogeneity in aquifer sediments. Local perched and semi-confined conditions occur in some areas. Recharge of the confined Patuxent aquifer occurs primarily in the outcrop and subcrop area, although some recharge may also occur through overlying confining units. Recharge to the unconfined surficial aquifer system occurs through infiltration of precipitation and possible artificial recharge from structures such as underground water or sewer pipes. In the Patuxent aquifer, hydraulic gradients indicate downward movement in the outcrop area, whereas hydraulic heads beneath the Anacostia River are higher than land surface, indicating an upward hydraulic gradient. In the unconfined surficial aquifer system, groundwater generally flows from upland recharge areas towards discharge areas near the Anacostia River and its tributaries. Groundwater from the confined part of the Patuxent aquifer also may discharge to the Anacostia River in locations where the overlying clay-dominated lithofacies of the Potomac Group is absent as a result of past geologic and (or) alluvial processes. Geochemistry and groundwater quality are affected by hydrologic conditions as well as anthropogenic influences. Local variability in groundwater quality reflects local variability in hydrogeologic conditions and sources of chemicals. Groundwater ranges from anoxic and iron- or calcium-bicarbonate type, to oxic with elevated nitrate. The occurrence and distribution of pesticides, volatile organic compounds, and other selected chemical compounds in groundwater reflect the multitude of sources common to urban areas, as well as variable hydrogeologic and geochemical conditions that affect their fate and transport in the environment. Overall, concentrations of only a few of the over 200 chemical constituents included in laboratory analyses exceeded regulatory standards or guidance values. These include tetrachloroethene and arsenic, which were each detected one time in different wells. There were also several detections of iron and manganese that exceeded regulatory standards or guidance values that are associated with reducing conditions in aquifer sediments.

Washington, D.C.↗

USGS2005

Effects of urban land-use change on streamflow and water quality in Oakland County, Michigan, 1970-2003, as inferred from urban gradient and temporal analysis

Various adverse hydrologic effects on streams have been attributed to urban development and expanded impervious surface area, including increased high flows, decreased low flows, increased variability (commonly referred to as flashiness), nutrient enrichment, and increased dissolved solids concentrations. These effects are often observed through the use of urban-gradient studies, which compare hydrologic characteristics among watersheds with different levels of development. This technique is frequently applied when comparable prior data are not available for the watersheds of interest. During 1966 - 1970, and again during 2001 - 2003, the U.S. Geological Survey collected a series of low-flow water-chemistry samples. Streamflow-gaging stations were operated throughout the period from 1966- 2003 as part of ongoing monitoring operations. This study compares these two water-quality data sets; tests the streamflow data for trends in high flows, low flows, and flashiness; and correlates 2000 land use with water-quality and streamflow data collected during the 2001 - 2003 study. Despite substantial change in land use during 1980 - 2000, with urban land covers replacing open space, forest, and agriculture, little evidence is found in the time-series data of alteration of the daily streamflow characteristics or nutrient enrichment in the study watersheds. However, a distinct shift is observable in chloride concentrations. Strong positive correlations exist across the urban gradient between development and increased peak flows as well as between development and increased flashiness. Correlations of water-quality data to development metrics show strong positive correlations with increased dissolved solids and salt content, as well as increased concentrations of fecal indicator bacteria ( Eschericia coli ). This apparent contradiction may be caused by the differences in the changes measured in each analysis. The change-through-time approach describes change from a fixed starting point of approximately 1970; the gradient approach describes the cumulative effect of all change up to approximately 2000. These findings indicate that although urbanization in Oakland County results in most of the effects observed in the literature, as evidenced in the gradient approach, relatively few of the anticipated effects have been observed during the past three decades. This relative stability despite rapid land-cover change may be related to efforts to mitigate the effects of development and a general decrease in the density of new residential development. It may also be related to external factors such as climate variability and reduced atmospheric deposition of specific chemicals.

Michigan↗

USGS2002

Effects of wastewater and combined sewer overflows on water quality in the Blue River basin, Kansas City, Missouri and Kansas, July 1998-October 2000

Samples were collected from 16 base-flow events and a minimum of 10 stormflow events between July 1998 and October 2000 to characterize the effects of wastewater and combined sewer overflows on water quality in the Blue River Basin, Kansas City, Missouri and Kansas. Waterquality effects were determined by analysis of nutrients, chloride, chemical and biochemical oxygen demand, and suspended sediment samples from three streams (Blue River, Brush Creek, and Indian Creek) in the basin as well as the determination of a suite of compounds known to be indicative of wastewater including antioxidants, caffeine, detergent metabolites, antimicrobials, and selected over-the-counter and prescription pharmaceuticals. Constituent loads were determined for both hydrologic regimes and a measure of the relative water-quality impact of selected stream reaches on the Blue River and Brush Creek was developed. Genetic fingerprint patterns of Escherichia coli bacteria from selected stream samples were compared to a data base of knownsource patterns to determine possible sources of bacteria. Water quality in the basin was affected by wastewater during both base flows and stormflows; however, there were two distinct sources that contributed to these effects. In the Blue River and Indian Creek, the nearly continuous discharge of treated wastewater effluent was the primary source of nutrients, wastewater indicator compounds, and pharmaceutical compounds detected in stream samples. Wastewater inputs into Brush Creek were largely the result of intermittent stormflow events that triggered the overflow of combined storm and sanitary sewers, and the subsequent discharge of untreated wastewater into the creek. A portion of the sediment, organic matter, and associated constituents from these events were trapped by a series of impoundments constructed along Brush Creek where they likely continued to affect water quality during base flow. Concentrations and loads of most wastewater constituents in the Blue River and Indian Creek were significantly greater than in Brush Creek, especially during base flow. However, wastewater indicator compound concentrations were sometimes greater in some Brush Creek stormflow samples. Selected stream reaches along the mid-portion of Brush Creek showed higher effects relative to other sites, primarily because these sites were in impounded reaches with the greatest density of wastewater inputs, or had relatively small drainage areas.

Kansas, Missouri↗

USGS2009

Hydrochemical analysis of groundwater using multivariate statistical methods - The Volta region, Ghana

Q and R-mode multivariate statistical analyses were applied to groundwater chemical data from boreholes and wells in the northern section of the Volta region Ghana. The objective was to determine the processes that affect the hydrochemistry and the variation of these processes in space among the three main geological terrains: the Buem formation, Voltaian System and the Togo series that underlie the area. The analyses revealed three zones in the groundwater flow system: recharge, intermediate and discharge regions. All three zones are clearly different with respect to all the major chemical parameters, with concentrations increasing from the perceived recharge areas through the intermediate regions to the discharge areas. R-mode HCA and factor analysis (using varimax rotation and Kaiser Criterion) were then applied to determine the significant sources of variation in the hydrochemistry. This study finds that groundwater hydrochemistry in the area is controlled by the weathering of silicate and carbonate minerals, as well as the chemistry of infiltrating precipitation. This study finds that the ??D and ?? 18 O data from the area fall along the Global Meteoric Water Line (GMWL). An equation of regression derived for the relationship between ??D and ?? 18 O bears very close semblance to the equation which describes the GMWL. On the basis of this, groundwater in the study area is probably meteoric and fresh. The apparently low salinities and sodicities of the groundwater seem to support this interpretation. The suitability of groundwater for domestic and irrigation purposes is related to its source, which determines its constitution. A plot of the sodium adsorption ratio (SAR) and salinity (EC) data on a semilog axis, suggests that groundwater serves good irrigation quality in the area. Sixty percent (60%), 20% and 20% of the 67 data points used in this study fall within the medium salinity - low sodicity (C2-S1), low salinity -low sodicity (C1-S1) and high salinity - low sodicity (C3-S1) fields, which ascribe good irrigation quality to groundwater from this area. Salinities range from 28.1 to 1956 ??S/cm, whilst SAR values fall within the range 0-3. Extremely low sodicity waters of this kind, with salinities lower than 600 ??S/cm, have the tendency to affect the dispersive properties of irrigation soils when used for irrigation. About 50% of the groundwater in the study area fall within this category and need prior treatment before usage. ?? 2009 Korean Society of Civil Engineers and Springer-Verlag Berlin Heidelberg GmbH.

KSCE Journal of Civil Engineering↗

USGS2011

Rocky Mountain snowpack physical and chemical data for selected sites, 2010

The Rocky Mountain Snowpack program established a network of snowpack-sampling sites in the Rocky Mountain region, from New Mexico to Montana, to monitor the chemical content of snow and to understand the effects of regional atmospheric deposition on freshwater systems. Scientists with the U.S. Geological Survey, in cooperation with the National Park Service; the U.S. Department of Agriculture Forest Service; the Colorado Department of Public Health and Environment; Teton County, Wyoming; and others, annually collected and analyzed snow-pack samples at 48 or more sites in the Rocky Mountain region during 1993-2010. Sixty-three snowpack-sampling sites were each sampled once in 2010, and those data are presented in this report. Data include acid-neutralization capacity, specific conductance, pH, hydrogen ion concentrations, dissolved concentrations of major constituents (calcium, magnesium, sodium, potassium, ammonium, chloride, sulfate, and nitrate), dissolved organic carbon concentrations, snow-water equivalent, snow depth, total mercury concentrations, and ionic charge balance. Quality-assurance data for field and laboratory blanks and field replicates for 2010 also are included.

Rocky Mountains↗

USGS2008

National, holistic, watershed-scale approach to understand the sources, transport, and fate of agricultural chemicals

This paper is an introduction to the following series of papers that report on in-depth investigations that have been conducted at five agricultural study areas across the United States in order to gain insights into how environmental processes and agricultural practices interact to determine the transport and fate of agricultural chemicals in the environment. These are the first study areas in an ongoing national study. The study areas were selected, based on the combination of cropping patterns and hydrologic setting, as representative of nationally important agricultural settings to form a basis for extrapolation to unstudied areas. The holistic, watershed-scale study design that involves multiple environmental compartments and that employs both field observations and simulation modeling is presented. This paper introduces the overall study design and presents an overview of the hydrology of the five study areas. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗

USGS2012

Quality of surface-water runoff in selected streams in the San Antonio segment of the Edwards aquifer recharge zone, Bexar County, Texas, 1997-2012

During 1997–2012, the U.S. Geological Survey, in cooperation with the San Antonio Water System, collected and analyzed water-quality constituents in surface-water runoff from five ephemeral stream sites near San Antonio in northern Bexar County, Texas. The data were collected to assess the quality of surface water that recharges the Edwards aquifer. Samples were collected from four stream basins that had small amounts of developed land at the onset of the study but were predicted to undergo substantial development over a period of several decades. Water-quality samples also were collected from a fifth stream basin located on land protected from development to provide reference data by representing undeveloped land cover. Water-quality data included pH, specific conductance, chemical oxygen demand, dissolved solids (filtered residue on evaporation in milligrams per liter, dried at 180 degrees Celsius), suspended solids, major ions, nutrients, trace metals, and pesticides. Trace metal concentration data were compared to the Texas Commission on Environmental Quality established surface water quality standards for human health protection (water and fish). Among all constituents in all samples for which criteria were available for comparison, only one sample had one constituent which exceeded the surface water criteria on one occasion. A single lead concentration (2.76 micrograms per liter) measured in a filtered water sample exceeded the surface water criteria of 1.15 micrograms per liter. The average number of pesticide detections per sample in stream basins undergoing development ranged from 1.8 to 6.0. In contrast, the average number of pesticide detections per sample in the reference stream basin was 0.6. Among all constituents examined in this study, pesticides, dissolved orthophosphate phosphorus, and dissolved total phosphorus demonstrated the largest differences between the four stream basins undergoing development and the reference stream basin with undeveloped land cover.

Texas↗

USGS2012

Contaminants in stream sediments from seven U.S. metropolitan areas: Data summary of a National Pilot Study

This report presents data collected as a part of a synoptic survey of stream sediment contaminants, associated watershed characteristics and invertebrate responses in laboratory sediment toxicity tests from 98 streams (sites) in seven metropolitan study areas across the continental United States. The report presents methods, data, and sediment-quality guidelines, including the derivation of a new sediment pyrethroid probable effects concentration, for the purposes of relating measured contaminants to land use and toxicity evaluation. The study evaluated sites that ranged in their degree of relative urbanization within the study areas of Atlanta, Boston, Dallas-Fort Worth, Denver, Milwaukee-Green Bay, Salt Lake City, and Seattle-Tacoma. In all, 108 chemical analytes quantified in the study are presented, by class and number of individual compounds, as follows: polyaromatic hydrocarbons (PAHs) (28), organochlorine pesticides (OCs) (18), polychlorinated biphenyls (Aroclors) (3), pyrethroid insecticides (14), fipronil compounds (4), priority trace and other major elements (41). The potential of these sediments to cause toxicity to sediment-dwelling invertebrates was evaluated using two standard sediment toxicity tests: a 28-day growth and survival toxicity test with the amphipod Hyalella azteca, and a 10-day growth and survival toxicity test with the midge Chironomus dilutus. Further, approximately 95 relevant watershed and reach-level characteristics were generated and are presented to aid in interpretation and explanation of contaminant and toxicity patterns. Interpretation of the findings of this study, including the relationships with urbanization and other factors, the relationship between sediment toxicity and sediment chemistry in the seven study areas, and the sources and occurrence of pyrethroid insecticides, are discussed in detail in a forthcoming series of journal articles.

Boston;Atlanta;Milwaukee;Green Bay;Dallas;Fort Wor↗

USGS2009

Rocky Mountain Snowpack Physical and Chemical Data for Selected Sites, 1993-2008

The Rocky Mountain Snowpack program established a network of snowpack-sampling sites in the Rocky Mountain region from New Mexico to Montana to monitor the chemical content of snow to help in the understanding of the effects of atmospheric deposition to this region. The U.S. Geological Survey, in cooperation with the National Park Service, the USDA Forest Service, Teton County in Wyoming, Rio Blanco County in Colorado, Pitkin County in Colorado, and others, collected and analyzed snowpack samples annually for 48 or more sites in the Rocky Mountain region during 1993-2008. Forty-eight of the 162 snow-sampling sites have been sampled annually since 1993. Data include acid-neutralization capacity, specific conductance, pH, hydrogen ion concentrations, dissolved concentrations of major constituents (calcium, magnesium, sodium, potassium, ammonium, chloride, sulfate, and nitrate), dissolved organic carbon concentrations, snow/ water equivalent, snow depth, stable sulfur isotope ratios, total mercury concentrations (beginning in 2001), and ionic charge balance. Quality-assurance data for field and laboratory blanks and field replicates for individual years (1993-2008) also are included.

Data Series↗

USGS2021

Survey of fish assemblages in the upper Neversink River and upper Rondout Creek, New York, 2017–19

Streams in the Catskill Mountains region of New York provide many important ecological and economic services, including recreational angling and serving as a drinking water supply to New York City. Many streams in this region were adversely affected by acid deposition during the late 20th century, impairing water quality and aquatic ecosystems. More recently, the level of acid deposition has declined while changes in climate have become more pronounced. As a result, biological and chemical data are needed to determine the current condition of stream ecosystems in the Catskill Mountains region. The U.S. Geological Survey, in cooperation with the Rondout Neversink Stream Program, surveyed fish communities and water chemistry annually between 2017 and 2019 at 23 sites in the upper Neversink River and upper Rondout Creek watersheds to compile a contemporary baseline dataset and assess potential biological recovery from reduced acidification. The resulting data indicated that brook trout ( Salvelinus fontinalis ) were present at every study site, although slimy sculpin ( Cottus cognatus ) was the most abundant species at most sites. Stream pH ranged from 4.8 to 7.0 across all sites and generally increased from upstream to downstream. Similarly, the number of species present and the ratio of brown trout ( Salmo trutta ) to brook trout increased at sites in each subwatershed from upstream to downstream.

New York↗

USGS2005

Sediment studies in the Assabet River, central Massachusetts, 2003

From its headwaters in Westborough, Massachusetts, to its confluence with the Sudbury River, the 53-kilometer-long Assabet River passes through a series of small towns and mixed land-use areas. Along the way, wastewater-treatment plants release nutrient-rich effluents that contribute to the eutrophic state of this waterway. This condition is most obvious where the river is impounded by a series of dams that have sequestered large amounts of sediment and support rooted and floating macrophytes and epiphytic algae. The water in parts of these impoundments may also have low concentrations of dissolved oxygen, another symptom of eutrophication. All of the impoundments had relatively shallow maximum water depths, which ranged from approximately 2.4 to 3.4 meters, and all had extensive shallow areas. Sediment volumes estimated for the six impoundments ranged from approximately 380 cubic meters in the Aluminum City impoundment to 580,000 cubic meters in the Ben Smith impoundment. The other impoundments had sediment volumes of 120,000 cubic meters (Powdermill), 67,000 cubic meters (Gleasondale), 55,000 cubic meters (Hudson), and 42,000 cubic meters (Allen Street). The principal objective of this study was the determination of sediment volume, extent, and chemistry, in particular, the characterization of toxic inorganic and organic chemicals in the sediments. To determine the bulk-sediment chemical-constituent concentrations, more than one hundred sediment cores were collected in pairs from the six impoundments. One core from each pair was sampled for inorganic constituents and the other for organic constituents. Most of the cores analyzed for inorganics were sectioned to provide information on the vertical distribution of analytes; a subset of the cores analyzed for organics was also sectioned. Approximately 200 samples were analyzed for inorganic constituents and 100 for organics; more than 10 percent were quality-control replicate or blank samples. Maximum bulk-sediment phosphorus concentrations in surface samples from the impoundments increased along a downstream gradient, with the exception of samples from the last impoundment, where the concentrations decreased. In addition, the highest phosphorus concentrations were generally in the surface samples; this finding may prove helpful if surface dredging is selected as a means to control phosphorus release from sediments. There is no known relation, however, between bulk-sediment concentration of phosphorus and the concentrations of phosphorus available to biota. Potentially toxic metals, including arsenic, cadmium, chromium, copper, nickel, lead, and zinc were frequently measured at concentrations that exceeded U.S. Environmental Protection Agency sediment-quality guidelines for the protection of aquatic life and that occasionally exceeded Massachusetts Department of Environmental Protection guidelines governing landfill disposal (reuse). Due to the effects of matrix interference and sample dilution on laboratory analyses, neither pesticides nor volatile organic compounds were detected at any sites. However, samples collected in other studies from nearby streams indicated the possibility that pesticides might have been detected in the impoundments if not for these analytical problems. Although polychlorinated biphenyl concentrations, as individual Aroclors, generally exceeded published U.S. Environmental Protection Agency guideline concentrations for potential effects on aquatic life, the U.S. Environmental Protection Agency guideline concentrations for human contact or the Massachusetts guidelines for landfill reuse were rarely exceeded. Concentrations of polycyclic aromatic hydrocarbons, both individually and total, frequently were greater than guideline concentrations. Concentrations of total extractable petroleum hydrocarbons did not exceed Massachusetts guideline concentrations in any samples. When the sediment analytes from surface samples are considered togethe

Scientific Investigations Report↗

USGS1963

Geology and ground-water resources of Hays County, Texas

The Edwards limestone of Early Cretaceous age is the chief aquifer for San Marcos Springs and about 160 other springs and wells in Hays County, along the Balcones fault zone in South-central Texas. Hays County is underlain by a basement of Paleozoic rocks; and in the southeastern part of the county the Hosston and Sligo formations of Early Cretaceous age, correlative with the Coahuila series of Mexico, have been encountered in the subsurface. Rocks exposed in the county are principally Cretaceous and Quaternary sedimentary units, which are assigned to the Trinity, Fredericksburg, and Washita groups in the Comanche series; the Eagle Ford shale, Austin chalk, Taylor marl, and Navarro group in the Gulf series: and the Leona formation and equivalent rocks in the Pleistocene series. Recent alluvium and colluvium locally overlie the older rocks. In addition to the Edwards limestone in the Fredericksburg group, waterbearing rock units in Hays County include the Pearsall formation (Travis Peak of outcrop areas) and the Glen Rose limestone in the Trinity group, the Austin chalk and Taylor marl, and the Quaternary rocks. The surface slope and regional dip are toward the southeast. Several normal strike faults have displaced the Cretaceous rocks downward to the southeast, the aggregate displacement being about 1,700 feet within the county. The boundaries of the Edwards limestone ground-water reservoir are formed by major faults which are the major controls of movement of water. Much of the water discharged at San Marcos Springs is derived from influent seepage from streams and infiltration from precipitation in recharge areas southwest of Hays County. The average underground inflow from Comal County through the Edwards limestone reservoir is estimated as 70,000 acre-feet per year for the period 1934-47. The discharge of San Marcos Springs, averaging about 55 million gallons a day during 1955, greatly exceeds local ground-water recharge within Hays County. Depth to water, direction of movement of water, subsurface location of aquifers, and quality of water in Hays County have been determined from records of 519 wells and springs, drillers' logs of 49 wells, periodic water-level measurements in about 70 wells, and chemical analyses of water samples from 238 wells and springs. Ground water from wells in the Pearsall formation generally contains less than 500 parts per million of dissolved solids. Water from the Glen Rose limestone in some places contains more than 500 parts per million of sulfate and more than 1,000 parts per million of dissolved solids; locally it is high in nitrate also. Except in the southeastern part of the county, water from the Edwards limestone is commonly very hard but is otherwise of good quality for most uses. Analyses of two water samples from the Austin chalk indicate a high content of bicarbonate. Water from the Taylor marl and from Quaternary sediments generally is hard, and locally it contains excessive nitrate. Most wells in Hays County are used for domestic and stock supplies. About 20 wells, most of them in the Edwards limestone, yield water in relatively large amounts for industrial use, irrigation, or public supplies.

Water Supply Paper↗

USGS1994

Characterization of ecological risks at the Milltown Reservoir-Clark Fork River Sediments Superfund Site, Montana

A comprehensive field and laboratory approach to the ecological risk assessment for the Milltown Reservoir-Clark Fork River Sediments Site, a Superfund site in the Rocky Mountains of Montana, has been described in the preceding reports of this series. The risk assessment addresses concerns over the ecological impacts of upstream releases of mining wastes to fisheries of the upper Clark Fork River (CFR) and the benthic and terrestrial habitats further downstream in Milltown Reservoir. The risk characterization component of the process integrated results from a triad of information sources: (a) chemistry studies of environmental media to identify and quantify exposures of terrestrial and aquatic organisms to site-related contaminants; (b) ecological or population studies of terrestrial vegetation, birds, benthic communities, and fish; and (c) in situ and laboratory toxicity studies with terrestrial and aquatic invertebrates and plants, small mammals, amphibians, and fish exposed to contaminated surface water, sediments, wetland soils, and food sources. Trophic transfer studies were performed on waterfowl, mammals, and predatory birds using field measurement data on metals concentrations in environmental media and lower trophic food sources. Studies with sediment exposures were incorporated into the Sediment Quality Triad approach to evaluate risks to benthic ecology. Overall results of the wetland and terrestrial studies suggested that acute adverse biological effects were largely absent from the wetland; however, adverse effects to reproductive, growth, and physiological end points of various terrestrial and aquatic species were related to metals exposures in more highly contaminated depositional areas. Feeding studies with contaminated diet collected from the upper CFR indicated that trout are at high risk from elevated metals concentrations in surface water, sediment, and aquatic invertebrates. Integration of chemical analyses with toxicological and ecological evaluations of metal effects on the wetland and fishery has provided an important foundation for environmental decisions at this site.

Montana↗

USGS2006

Water-Quality Data for the Lower Russian River Basin, Sonoma County, California, 2003-2004

In 2003, the U.S. Geological Survey, in cooperation with the Sonoma County Water Agency, began a study to determine the chemical, microbiological, and isotopic composition of the surface water and ground water in selected areas of the Lower Russian River Basin, Sonoma County, California. This report is a compilation of the hydrologic and water-quality data collected from 10 Russian River sites, 1 gravel-terrace pit site, 12 ground-water sites, 11 tributary sites including Mark West Creek, and 2 estuary sites between the city of Healdsburg and the Pacific Ocean, for the period August 2003 to September 2004. Field measurements made included streamflow, barometric pressure, dissolved oxygen, pH, specific conductance, and turbidity. Water samples were analyzed for nutrients, major ions, total and dissolved organic carbon, trace elements, mercury, wastewater compounds, total coliform, Escherichia coli, Enterococci, Clostridium perfringens, and the stable isotopes of hydrogen and oxygen. Discharge measurements and sampling techniques were modified to accommodate the very low summer flows at most of the tributaries, and discharge measurements were made with an acoustic Doppler velocity meter at the estuary river site to overcome the complexities associated with tidal influences.

Data Series↗

USGS2012

Hydrogeology, water chemistry, and transport processes in the zone of contribution of a public-supply well in Albuquerque, New Mexico, 2007-9

The National Water-Quality Assessment Program (NAWQA) of the U.S. Geological Survey began a series of groundwater studies in 2001 in representative aquifers across the Nation in order to increase understanding of the factors that affect transport of anthropogenic and natural contaminants (TANC) to public-supply wells. One of 10 regional-scale TANC studies was conducted in the Middle Rio Grande Basin (MRGB) in New Mexico, where a more detailed local-scale study subsequently investigated the hydrogeology, water chemistry, and factors affecting the transport of contaminants in the zone of contribution of one 363-meter (m) deep public-supply well in Albuquerque. During 2007 through 2009, samples were collected for the local-scale study from 22 monitoring wells and 3 public-supply (supply) wells for analysis of major and trace elements, arsenic speciation, nutrients, dissolved organic carbon, volatile organic compounds (VOCs), dissolved gases, stable isotopes, and tracers of young and old water. To study groundwater chemistry and ages at various depths within the aquifer, the monitoring wells were divided into three categories: (1) each shallow well was screened across the water table or had a screen midpoint within 18.3 m of the water level in the well; (2) each intermediate well had a screen midpoint between about 27.1 and 79.6 m below the water level in the well; and (3) each deep well had a screen midpoint about 185 m or more below the water level in the well. The 24-square-kilometer study area surrounding the "studied supply well" (SSW), one of the three supply wells, consists of primarily urban land within the MRGB, a deep alluvial basin with an aquifer composed of unconsolidated to moderately consolidated deposits of sand, gravel, silt, and clay. Conditions generally are unconfined, but are semiconfined at depth. Groundwater withdrawals for public supply have substantially changed the primary direction of flow from northeast to southwest under predevelopment conditions, to west to east under modern conditions. Analysis of age tracers indicates that groundwater from most sampled wells is dominated by old (pre-1950) water, ranging in mean age from about 4,000 years to more than 22,000 years, but includes a fraction of young (post-1950) recharge. Patterns in chemical and isotopic data are consistent with the conclusions that shallow groundwater in the area typically includes a fraction that evaporated prior to recharge and (or) flushed accumulated solutes out of the unsaturated zone during recharge, and that shallow groundwater has mixed to deeper parts of the aquifer, which receives recharge mainly by seepage from the Rio Grande. Among shallow and intermediate wells that produced water with a fraction of young recharge, that fraction ranged between 1.5 and 46 percent. Samples from the two deep wells had groundwater ages exceeding 18,000 years, with no fraction of young recharge. Two supply wells (including the SSW) had a fraction of young recharge, which ranged between about 3 and 11 percent, despite mean groundwater ages exceeding 10,000 years. The fraction of young recharge to the SSW varied seasonally, probably because seasonal pumping patterns affected local hydraulic gradients and (or) because of flow through the well bore when the SSW is not pumping. Well-bore flow data collected during winter (low-pumping season) indicated that about 61 percent of the water pumped from the SSW entered the well from the intermediate part of the aquifer, and that the remaining 39 percent entered from the deep part of the aquifer. Volatile organic compounds (VOCs) were detected in samples from most shallow and intermediate monitoring wells and from two of three supply wells, including the SSW. Detected VOCs were primarily chlorinated solvents or their degradation products. Many of the wells in which most of these VOCs were detected are located near known sites of solvent contamination that were targeted for sampling because trichloroethylene (TCE) and cis-1,2-dichloroethylene had been detected in the SSW, and several of these wells may have become contaminated at least partly because of enhanced vertical migration associated with the pumping of and (or) direct migration down deep well bores. Except for TCE in the sample from a shallow monitoring well, all detections of VOCs were at concentrations below Maximum Contaminant Levels (MCLs) set by the U.S. Environmental Protection Agency. Concentrations of all VOCs detected in the supply wells were less than one-tenth of the corresponding MCLs. However, the presence of VOCs in all but deep groundwater, including the detection of chloroform (a chlorination byproduct) in several shallow wells, indicates that groundwater in the study area commonly is affected by human activities, even to substantial depths. The only natural contaminant detected at concentrations near or above its MCL was arsenic, which has been detected at elevated concentrations across broad areas of the MRGB. Concentrations of arsenic, present primarily as arsenate, exceeded the MCL of 10 micrograms per liter (μg/L) in water from the two deep wells (one of which had the highest concentration, 35 μg/L), from one intermediate well, and from two supply wells, including the SSW. Water-quality and solid-phase data from this study are consistent with elevated arsenic concentrations in groundwater being related to pH-dependent desorption of arsenic from ferric oxyhydroxides in sediments in deep parts of the aquifer. Concentrations of nitrate ranged between 1.3 and 5.4 milligrams per liter (mg/L) in water from shallow wells screened across the water table, but were less than 0.9 mg/L in water from all but one deeper well. Nitrogen isotopes and chloride/bromide ratios for shallow wells were consistent with natural soil nitrogen. Nitrate concentrations and nitrogen isotopes indicated that denitrification is occurring at intermediate aquifer depths, and that the progress of the denitrification reaction typically is greatest for wells that include a fraction of groundwater associated with particular recharge sources or with known sites of contamination contributing organic compounds that can provide a carbon source for microbial respiration. Overall, hydrologic and chemical data from the study area indicate that young recharge is reaching the aquifer across broad areas and is migrating from shallow to intermediate depths of the aquifer as a result of mixing that is associated with human development of groundwater. Consequently, groundwater that human activities in the urban study area have affected is present at depths that are within the screened intervals of public-supply wells, resulting in detections of VOCs and implying greater vulnerability to anthropogenic contamination than might be assumed based on the dominantly old age of the regional groundwater. However, the fractions of old groundwater that public-supply wells produce substantially dilute the anthropogenic contaminants, while contributing natural contaminants (primarily arsenic) to the wells. Based on data from the SSW, vulnerability of public-supply wells to natural and anthropogenic contaminants in the area changes through time, including with seasonal changes in pumping stresses that alter the fractions of young and old water being contributed to wells.

New Mexico↗

USGS2012

Groundwater data for selected wells within the Eastern San Joaquin Groundwater Subbasin, California, 2003-8

Data were collected by the U.S. Geological Survey from 2003 through 2008 in the Eastern San Joaquin Groundwater Subbasin, 80 miles east of San Francisco, California, as part of a study of the increasing chloride concentrations in groundwater processes. Data collected include geologic, geophysical, chemical, and hydrologic data collected during and after the installation of five multiple-well monitoring sites, from three existing multiple-well sites, and from 79 selected public-supply, irrigation, and domestic wells. Each multiple-well monitoring site installed as part of this study contained three to five 2-inch diameter polyvinyl chloride (PVC)-cased wells ranging in depth from 68 to 880 feet below land surface. Continuous water-level data were collected from the 19 wells installed at these 5 sites and from 10 existing monitoring wells at 3 additional multiple-well sites in the study area. Thirty-one electromagnetic logs were collected seasonally from the deepest PVC-cased monitoring well at seven multiple-well sites. About 200 water samples were collected from 79 wells in the study area. Coupled well-bore flow data and depth-dependent water-quality data were collected from 12 production wells under pumped conditions, and well-bore flow data were collected from 10 additional wells under unpumped conditions.

California↗

USGS2008

Hydrologic connections and dynamics of water movement in the classical Karst (Kras) aquifer: Evidence from frequent chemical and stable isotope sampling

A review of past researchon the hydrogeology of the Classical Karst (Kras) region and new information obtained from a two-year study using environmental tracers are presented in this paper. The main problems addressed are 1) the sources of water to the Kras aquifer resurgence zone—including the famous Timavo springs—under changing flow regimes; 2) a quantification of the storage volumes of the karst massif corresponding to flow regimes defined by hydrographrecessions of the Timavo springs; and 3) changing dynamics between deep phreatic conduit flow and shallow phreatic and epiphreatic storage within the aquifer resurgence zone as determined throughchanges in chemical and isotopic composition at springs and wells. Particular focus was placed on addressing the long-standing question of the influence of the Soča River on the ground waters of the aquifer resurgence zone. The results indicate that the alluvial aquifer supplied by the sinking of the Soča River on the northwestern edge of the massif contributes approximately 75% of the mean annual outflow to the smaller springs of the aquifer resurgence zone, and as muchas 53% to the mean annual outflow of the Timavo springs. As a whole, the Soča River is estimated to contribute 56% of the average outflow of the Kras aquifer resurgence. The proportions of Soča River water increase under drier conditions, and decrease under wetter conditions. Time series analysis of oxygen stable isotope records indicate that the transit time of Soča River water to the Timavo springs, Sardos spring, and well B-4 is on the order of 1-2 months, depending on hydrological conditions. The total baseflow storage of the Timavo springs is estimated to be 518 million m3, and represents 88.5% of the storage capacity estimated for all flow regimes of the springs. The ratio of baseflow storage volume to the average annual volume discharged at the Timavo springs is 0.54. The Reka River sinking in Slovenia supplies substantial allogenic recharge to the aquifer; however, its influence on the northwest resurgence zone is limited to the Timavo springs, and is only a significant component of the spring discharge under flood conditions for relatively brief periods (several days to weeks). Sustainability of the trans-boundary aquifer of the Kras will benefit from maintaining highwater quality in the Soča River, as well as focused water tracing experiments within the epiphreatic zone of the aquifer to better delineate the recharge zone and to identify sources of potential contamination to the Brestovica water supply well.

Acta Carsologica↗

USGS2009

Continuous and discrete water-quality data collected at five sites on Lake Houston near Houston, Texas, 2006-08

Lake Houston, a reservoir impounded in 1954 by the City of Houston, Texas, is a primary source of drinking water for Houston and surrounding areas. The U.S. Geological Survey, in cooperation with the City of Houston, developed a continuous water-quality monitoring network to track daily changes in water quality in the southwestern quadrant of Lake Houston beginning in 2006. Continuous water-quality data (the physiochemical properties water temperature, specific conductance, pH, dissolved oxygen concentration, and turbidity) were collected from Lake Houston to characterize the in-lake processes that affect water quality. Continuous data were collected hourly from mobile, multi-depth monitoring stations developed and constructed by the U.S. Geological Survey. Multi-depth monitoring stations were installed at five sites in three general locations in the southwestern quadrant of the lake. Discrete water-quality data (samples) were collected routinely (once or twice each month) at all sites to characterize the chemical and biological (phytoplankton and bacteria) response to changes in the continuous water-quality properties. Physiochemical properties (the five continuously monitored plus transparency) were measured in the field when samples were collected. In addition to the routine samples, discrete water-quality samples were collected synoptically (one or two times during the study period) at all sites to determine the presence and levels of selected constituents not analyzed in routine samples. Routine samples were measured or analyzed for acid neutralizing capacity; selected major ions and trace elements (calcium, silica, and manganese); nutrients (filtered and total ammonia nitrogen, filtered nitrate plus nitrite nitrogen, total nitrate nitrogen, filtered and total nitrite nitrogen, filtered and total orthophosphate phosphorus, total phosphorus, total nitrogen, total organic carbon); fecal indicator bacteria (total coliform and Escherichia coli); sediment (suspended-sediment concentration and loss-on-ignition); actinomycetes bacteria; taste-and-odor-causing compounds (2-methylisoborneol and geosmin); cyanobacterial toxins (total microcystins); and phytoplankton abundance, biovolume, and community composition (taxonomic identification to genus). Synoptic samples were analyzed for major ions, trace elements, wastewater indicators, pesticides, volatile organic compounds, and carbon. The analytical data are presented in tables by type (continuous, discrete routine, discrete synoptic) and listed by station number. Continuously monitored properties (except pH) also are displayed graphically.

Texas↗