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At least 217 records · Page 12Linked to original sources

Monitoring land use on military installations

The US Geological Survey's Land Cover Trends is a research projects aimed to understand the rates, trends, causes, and consequences of contemporary US land use and land-cover change. The project is using the EPA Level III eco-regions as a geographic framework to process geospatial data collected between 1973 and 2000 to characterize ecosystem responses to land-use changes. The results are expected to be used for collaborative environmental change consequences research with various partners including the National Science Foundation, the National Oceanic and Atmospheric Administration, and the US Fish and Wildlife Service. The Land Cover project can provide geographic understanding of the state of the nation's ecosystems. The project is scheduled to be completed by 2010 and expected to provide an unbiased, national synthesis of land-cover changes.

Military Engineer

Limnology of the Green Lakes Valley: Phytoplankton ecology and dissolved organic matter biogeochemistry at a long-term ecological research site

Background : Surface waters are the lowest points in the landscape, and therefore serve as excellent integrators and indicators of changes taking place in the surrounding terrestrial and atmospheric environment. Aims : Here we synthesise the findings of limnological studies conducted during the past 15 years in streams and lakes in the Green Lakes Valley, which is part of the Niwot Ridge Long-term Ecological Research (LTER) Site. Methods : The importance of these studies is discussed in the context of aquatic ecosystems as indicators, integrators, and regulators of environmental change. Specifically, investigations into climatic, hydrologic, and nutrient controls on present-day phytoplankton, and historical diatom, community composition in the alpine lake, Green Lake 4, are reviewed. In addition, studies of spatial and temporal patterns in dissolved organic matter (DOM) biogeochemistry and reactive transport modelling that have taken place in the Green Lakes Valley are highlighted. Results and conclusions : The findings of these studies identify specific shifts in algal community composition and DOM biogeochemistry that are indicative of changing environmental conditions and provide a framework for detecting future environmental change in the Green Lakes Valley and in other alpine watersheds. Moreover, the studies summarised here demonstrate the importance of long-term monitoring programmes such as the LTER programme.

Colorado

Developing of 10-year EEZ seafloor mapping and research program

Mapping and research on the seafloor adjacent to the United States has been a national effort involving elements of the Department of the Interior, the Department of Commerce, certain academic institutions, and private industry, the latter primarily for the exploration for oil and gas. These activities were accelerated by the USGS and NOAA in 1983, following the issuance of the EEZ (Exclusive Economic Zone) Proclamation by President Reagan. The intent of expanding the exploration already begun on the outer continental shelf (OCS) to the frontier of the EEZ is to determine the “characteristics”; and resource potential of this region. To coordinate this exploration , a Joint Office for Mapping and Research (JOMAR) has been established by the U.S. Geological Survey (in the Department of the Interior) and the National Oceanic and Atmospheric Administration (in the Department of Commerce). JOMAR's main purpose is to help direct and coordinate ongoing and planned seafloor related activities in the EEZ and prepare a 10 ‐ year plan for mapping and research . JOMAR recently hosted a national symposium to identify the major elements of this plan . A comprehensive mapping and research plan will provide the needed direction and guide this national challenge.

Marine Geodesy

Atmospheric bromine flux from the coastal Abu Dhabi sabkhat: A ground-water mass-balance investigation

A solute mass-balance study of ground water of the 3000 km2 coastal sabkhat (salt flats) of the Emirate of Abu Dhabi, United Arab Emirates, documents an annual bromide loss of approximately 255 metric tons (0.0032 Gmoles), or 85 kg/km2. This value is an order of magnitude greater than previously published direct measurements from the atmosphere over an evaporative environment of a salar in Bolivia. Laboratory evidence, consistent with published reports, suggests that this loss is by vapor transport to the atmosphere. If this bromine flux to the atmosphere is representative of the total earth area of active salt flats then it is a significant, and generally under recognized, input to the global atmospheric bromide flux.

Geophysical Research Letters

An updated model of induced airflow in the unsaturated zone

Simulation of induced movement of air in the unsaturated zone provides a method to determine permeability and to design vapor extraction remediation systems. A previously published solution to the airflow equation for the case in which the unsaturated zone is separated from the atmosphere by a layer of lower permeability (such as a clay layer) has been superseded. The new solution simulates airflow through the layer of lower permeability more rigorously by defining the leakage in terms of the upper boundary condition rather than by adding a leakage term to the governing airflow equation. This note presents the derivation of the new solution. Formulas for steady state pressure, specific discharge, and mass flow in the domain are obtained for the new model and for the case in which the unsaturated zone is in direct contact with the atmosphere.

Water Resources Research

Meeting summary - Coastal meteorology and oceanography: Report of the third prospectus development team of the U.S. Weather Research Program to NOAA and NSF

U.S. Weather Research Program (USWRP) prospectus development teams (PDTs) are small groups of scientists that are convened by the USWRP lead scientist on a one-time basis to discuss critical issues and to provide advice related to future directions of the program. PDTs are a principal source of information for the Science Advisory Committee, which is a standing committee charged with the duty of making recommendations to the Program Office based upon overall program objectives. PDT-1 focused on theoretical issues, and PDT-2 on observational issues; PDT-3 is the first of several to focus on more specialized topics. PDT-3 was convened to identify forecasting problems related to U.S. coastal weather and oceanic conditions, and to suggest likely solution strategies. There were several overriding themes that emerged from the discussion. First, the lack of data in and over critical regions of the ocean, particularly in the atmospheric boundary layer, and the upper-ocean mixed layer were identified as major impediments to coastal weather prediction. Strategies for data collection and dissemination, as well as new instrument implementation, were discussed. Second, fundamental knowledge of air-sea fluxes and boundary layer structure in situations where there is significant mesoscale variability in the atmosphere and ocean is needed. Companion field studies and numerical prediction experiments were discussed. Third, research prognostic models suggest that future operational forecast models pertaining to coastal weather will be high resolution and site specific, and will properly treat effects of local coastal geography, orography, and ocean state. The view was expressed that the exploration of coupled air-sea models of the coastal zone would be a particularly fruitful area of research. PDT-3 felt that forecasts of land-impacting tropical cyclones, Great Lakes-affected weather, and coastal cyclogenesis, in particular, would benefit from such coordinated modeling and field efforts. Fourth, forecasting for Arctic coastal zones is limited by our understanding of how sea ice forms. The importance of understanding air-sea fluxes and boundary layers in the presence of ice formation was discussed. Finally, coastal flash flood forecasting via hydrologic models is limited by the present accuracy of measured and predicted precipitation and storm surge events. Strategies for better ways to improve the latter were discussed.

Conference Paper

Nutrient pollution of coastal rivers, bays, and seas

Over the past 40 years, antipollution laws have greatly reduced discharges of toxic substances into our coastal waters. This effort, however, has focused largely on point-source pollution of industrial and municipal effluent. No comparable effort has been made to restrict the input of nitrogen (N) from municipal effluent, nor to control the flows of N and phosphorus (P) that enter waterways from dispersed or nonpoint sources such as agricultural and urban runoff or as airborne pollutants. As a result, inputs of nonpoint pollutants, particularly N, have increased dramatically. Nonpoint pollution from N and P now represents the largest pollution problem facing the vital coastal waters of the United States. Nutrient pollution is the common thread that links an array of problems along the nation’s coastline, including eutrophication, harmful algal blooms, ”dead zones,” fish kills, some shellfish poisonings, loss of seagrass and kelp beds, some coral reef destruction, and even some marine mammal and seabird deaths. More than 60 percent of our coastal rivers and bays in every coastal state of the continental United States are moderately to severely degraded by nutrient pollution. This degradation is particularly severe in the mid Atlantic states, in the southeast, and in the Gulf of Mexico. A recent report from the National Research Council entitled “Clean Coastal Waters: Understanding and Reduc- ing the Effects of Nutrient Pollution” concludes that: Nutrient over-enrichment of coastal ecosystems generally triggers ecological changes that decrease the biologi- cal diversity of bays and estuaries. While moderate N enrichment of some coastal waters may increase fish production, over-enrichment generally degrades the marine food web that supports commercially valuable fish. The marked increase in nutrient pollution of coastal waters has been accompanied by an increase in harmful algal blooms, and in at least some cases, pollution has triggered these blooms. High nutrient levels and the changes they cause in water quality and the makeup of the algal community are detrimental to the health of coral reefs and the diversity of animal life supported by seagrass and kelp communi- ties. Research during the past decade confirms that N is the chief culprit in eutrophication and other impacts of nutrient over-enrichment in temperate coastal waters, while P is most problematic in eutrophication of freshwa- ter lakes. Human conversion of atmospheric N into biologically useable forms, principally synthetic inorganic fertilizers, now matches the natural rate of biological N fixation from all the land surfaces of the earth. Both agriculture and the burning of fossil fuels contribute significantly to nonpoint flows of N to coastal waters, either as direct runoff or airborne pollutants. N from animal wastes that leaks directly to surface waters or is volatilized to the atmosphere as ammonia may be the largest single source of N that moves from agricultural operations into coastal waters. The National Research Council report recommended that, as a minimum goal, the nation should work to reverse nutrient should be taken to assure that the 40 percent of coastal areas now ranked as healthy do not develop symptoms of nutrient pollution in 10 percent of its degraded coastal systems by 2010 and 25 percent of them by 2020. Also, action should be taken to assure that the 40 percent of coastal areas now ranked as healthy do not develop symptoms of nutrient pollution. Meeting these goals will require an array of strategies and approaches tailored to specific regions and coastal ecosystems. There is an urgent need for development and testing of techniques that can reliably pinpoint the sources of N pollutants to an estuary. For some coastal systems, N removal during treatment of human sewage may be sufficient to reverse nutrient pollution. For most coastal systems, however, the solutions will be more complex and may involve controls on N compounds emitted during fossil fuel combustion as well as incentives to reduce over-fertilization of agricul- tural fields and nutrient pollution from animal wastes in livestock feedlot operations.

Alabama, California, Connecticut, Delaware, Florid

Vulnerability assessment of a port and harbor community to earthquake and tsunami hazards: Integrating technical expert and stakeholder input

Research suggests that the Pacific Northwest could experience catastrophic earthquakes and tsunamis in the near future, posing a significant threat to the numerous ports and harbors along the coast. A collaborative, multiagency initiative is underway to increase the resiliency of Pacific Northwest ports and harbors to these hazards, involving Oregon Sea Grant, Washington Sea Grant, the National Oceanic and Atmospheric Administration Coastal Services Center, and the U.S. Geological Survey Center for Science Policy. One element of this research, planning, and outreach initiative is a natural hazard mitigation and emergency preparedness planning process that combines technical expertise with local stakeholder values and perceptions. This paper summarizes and examines one component of the process, the vulnerability assessment methodology, used in the pilot port and harbor community of Yaquina River, Oregon, as a case study of assessing vulnerability at the local level. In this community, stakeholders were most concerned with potential life loss and other nonstructural vulnerability issues, such as inadequate hazard awareness, communication, and response logistics, rather than structural issues, such as damage to specific buildings or infrastructure.

Oregon

Lake oxygen isotopes as recorders of North American Rocky Mountain hydroclimate: Holocene patterns and variability at multi-decadal to millennial time scales

Lake sediment oxygen isotope records (calcium carbonate-δ 18 O) in the western North American Cordillera developed during the past decade provide substantial evidence of Pacific ocean–atmosphere forcing of hydroclimatic variability during the Holocene. Here we present an overview of 18 lake sediment δ 18 O records along with a new compilation of lake water δ 18 O and δ 2 H that are used to characterize lake sediment sensitivity to precipitation-δ 18 O in contrast to fractionation by evaporation. Of the 18 records, 14 have substantial sensitivity to evaporation. Two records reflect precipitation-δ 18 O since the middle Holocene, Jellybean and Bison Lakes, and are geographically positioned in the northern and southern regions of the study area. Their comparative analysis indicates a sequence of time-varying north–south precipitation-δ 18 O patterns that is evidence for a highly non-stationary influence by Pacific ocean–atmosphere processes on the hydroclimate of western North America. These observations are discussed within the context of previous research on North Pacific precipitation-δ 18 O based on empirical and modeling methods. The Jellybean and Bison Lake records indicate that a prominent precipitation-δ 18 O dipole (enriched-north and depleted-south) was sustained between ~ 3.5 and 1.5 ka, which contrasts with earlier Holocene patterns, and appears to indicate the onset of a dominant tropical control on North Pacific ocean–atmosphere dynamics. This remains the state of the system today. Higher frequency reversals of the north–south precipitation-δ 18 O dipole between ~ 2.5 and 1.5 ka, and during the Medieval Climate Anomaly and the Little Ice Age, also suggest more varieties of Pacific ocean–atmosphere modes than a single Pacific Decadal Oscillation (PDO) type analogue. Results indicate that further investigation of precipitation-δ 18 O patterns on short (observational) and long (Holocene) time scales is needed to improve our understanding of the processes that drive regional precipitation-δ 18 O responses to Pacific ocean–atmosphere variability, which in turn, will lead to a better understanding of internal Pacific ocean–atmosphere variability and its response to external climate forcing mechanisms.

North American Rocky Mountain

DLR Earth Sensing Imaging Spectrometer (DESIS) level 1 product evaluation using RadCalNet measurements

The DLR Earth Sensing Imaging Spectrometer (DESIS) is the first hyperspectral imaging spectrometer installed in the Multi-User System for Earth Sensing (MUSES) on the International Space Station (ISS) for acquiring routine science grade images from orbit. It was launched on 29 June 2018 and integrated into MUSES. DESIS measures energy in the spectral range of 400 to 1000 nm with high spatial and spectral resolution: 30 m and 2.55 nm, respectively. DESIS data should be sufficiently quantitative and accurate to use it for different applications and research. This work performs a radiometric evaluation of DESIS Level 1 product (Top of Atmosphere (TOA) reflectance) by comparing it with coincident Radiometric Calibration Network (RadCalNet) measurements at Railroad Valley Playa (RVUS), Gobabeb (GONA), and La Crau (LCFR). RVUS, GONA, and LCFR offer 4, 15, and 5 coincident datasets between DESIS and RadCalNet measurements, respectively. The results show an agreement between DESIS and RadCalNet TOA reflectance within ~5% for most spectral regions. However, there is an additional ~5% disagreement across the wavelengths affected by water vapor absorption and atmospheric scattering. Among the three RadCalNet sites, RVUS and GONA show a similar measurement disagreement with DESIS of ~5%, while LCFR differs by ~10%. Agreement between DESIS and RadCalNet measurements is variable across all three sites, likely due to surface type differences. DESIS and RadCalNet agreement show a precision of ~2.5%, 4%, and 7% at RVUS, GONA, and LCFR, respectively. RVUS and GONA, which have a similar surface type, sand, have a similar level of radiometric accuracy and precision, whereas LCFR, which consists of sparse vegetation, has lower accuracy and precision. The observed precision of DESIS Level 1 products from all the sites, especially LCFR, can be improved with a better Bidirectional Reflection Distribution Function (BRDF) characterization of the RadCalNet sites.

Remote Sensing

Insights and strategic opportunities from the USGS 2024 Per- and Polyfluoroalkyl Substances (PFAS) Interagency Workshop

Introduction In 2021, the U.S. Geological Survey (USGS) published Circular 1490 titled, “Integrated Science for the Study of Perfluoroalkyl and Polyfluoroalkyl Substances (PFAS) in the Environment: A Strategic Science Vision for the U.S. Geological Survey” (Tokranov and others, 2021). Circular 1490 was created to be a resource for USGS scientists prioritizing and planning research related to per- and polyfluoroalkyl substances (PFAS) and to be a guide for developing partnerships with other scientists, State and Federal agencies, and stakeholders engaged in PFAS research and management and mitigation of the environmental and human-health effects of PFAS. This USGS PFAS Strategic Science Vision document was intended to be the foundation for a “living strategic vision,” periodically providing updates on the state of USGS PFAS research, emerging PFAS data gaps and needs, and progress on interagency and stakeholder PFAS partnerships and priorities. To meet this objective, the USGS planned to host an Interagency and Stakeholder PFAS Workshop every 2–3 years. During September 10–12, 2024, the USGS hosted the first Interagency and Stakeholder PFAS Workshop in Reston, Virginia. The Workshop brought together experts from other Federal agencies (U.S. Environmental Protection Agency, National Institute of Environmental Health Sciences, Food and Drug Administration, Department of Defense [Air Force, Army]), State agencies (Washington Fish and Wildlife, Virginia Department of Transportation), and academia (Harvard University, University of Maryland) to address key challenges relating to the measurement and modeling of PFAS and the implications for environmental health. Participants engaged in in-depth discussions centered around six pivotal topics related to PFAS: (1) sampling protocols, methods and interpretation; (2) environmental sources, source apportionment, and occurrence; (3) environmental fate and transport; (4) human and wildlife exposure routes and risk; (5) bioconcentration, bioaccumulation, and biomagnification; and (6) ecotoxicology and effects. Each topic had three breakout sessions. A recurrent theme of workshop discussions was how data on a nationwide scale for PFAS occurrence in various environmental matrices, including air, water, food crops, biota, soil, and streambed sediment could help to advance scientific understanding. Participants noted significant geospatial data gaps, particularly in the midwestern and southern United States and the Pacific Northwest. PFAS data collection tends to be more robust along the eastern seaboard and in California. Participants stressed how enhancing the integration of large and small datasets across various agencies could help to support national scale understanding of PFAS. To address these gaps, attendees suggested leveraging datasets from Federal entities like the USGS and the U.S. Department of Defense, State agencies, and municipal utility services to develop predictive contaminant detection and transport models. Improved coordination between water quality programs and USGS research could help to facilitate access to valuable data, leading to comprehensive databases that inform PFAS point (wastewater treatment plants and landfills) and nonpoint (runoff from land, atmospheric deposition, food packaging) sources, environmental transport mechanisms, environmental detection and concentrations, potential exposure routes, and health effects on different biota, including humans. A specific request was made to develop a map demarking the depth of modern (1953 or later) groundwater, which is susceptible to surface-derived anthropogenic (that is, human-made) contamination, based on tritium-age dating. Emphasis was placed on incorporation of hydrology, groundwater flow paths, groundwater–surface water interactions, and landscape factors in predictive statistical models as a step to improve contaminant source identification and tracking. Molecular fingerprinting approaches garnered attention as techniques to link specific PFAS mixtures detected in a sample to environmental sources and levels in biota (Dávila-Santiago and others, 2022). Integrating data from abiotic (that is, water, soil, and air) and biotic (that is, living organisms) systems identified as a research opportunity. For example, understanding the composition of soils and sediments, which include a mixture of mineral, plant, and animal components, could advance understanding of exposure pathways. The discussions highlighted opportunities to explore and understand the potential redistribution and biotic exposures of PFAS from biosolid and wastewater treatment plant effluent land application practices, in addition to atmospheric releases and discharges from landfill and wastewater treatment plants. Participants identified research gaps surrounding how these sources may contribute to contamination and may affect surrounding ecosystems, including a better definition of anthropogenic background concentrations. Moving forward, the collection of co-occurrence data was noted as a means to improve understanding of complex mixtures and to leverage companion modeling efforts focused on areas with high and low contamination levels to identify areas of concern and unaffected resources. Participants emphasized how centralized USGS databases and the establishment of sample-metadata archives can help to ensure that samples are preserved and accessible for future research. In conclusion, the workshop participants identified opportunities to bridge data gaps and improve measurement techniques, modeling frameworks, databases, and communication, to enhance the understanding of PFAS and their effects on environmental and human health. Upon completion of the workshop, participants indicated an interest in developing strategic data collection, modeling, and analytical approaches to address these challenges.

Open-File Report

Patterns and drivers of atmospheric river precipitation and hydrologic impacts across the western United States

Atmospheric rivers (ARs) significantly influence precipitation and hydrologic variability in many areas of the world, including the western United States. As ARs are increasingly recognized by the research community and the public, there is a need to more precisely quantify and communicate their hydrologic impacts, which can vary from hazardous to beneficial depending on location and on the atmospheric and land surface conditions prior to and during the AR. This study leverages 33 years of atmospheric and hydrologic data for the western United States to 1) identify how water vapor amount, wind direction and speed, temperature, and antecedent soil moisture conditions influence precipitation and hydrologic responses (runoff, recharge, and snowpack) using quantile regression and 2) identify differences in hydrologic response types and magnitudes across the study region. Results indicate that water vapor amount serves as a primary control on precipitation amounts. Holding water vapor constant, precipitation amounts vary with wind direction, depending on location, and are consistently greater at colder temperatures. Runoff efficiencies further covary with temperature and antecedent soil moisture, with precipitation falling as snow and greater available water storage in the soil column mitigating flood impacts of large AR events. This study identifies the coastal and maritime mountain ranges as areas with the greatest potential for hazardous flooding and snowfall impacts. This spatially explicit information can lead to better understanding of the conditions under which ARs of different precipitation amounts are likely to be hazardous at a given location.

Journal of Hydrometeorology

Sediment dynamics in the Adriatic Sea investigated with coupled models

Several large research programs focused on the Adriatic Sea in winter 2002-2003, making it an exciting place for sediment dynamics modelers (Figure 1). Investigations of atmospheric forcing and oceanic response (including wave generation and propagation, water-mass formation, stratification, and circulation), suspended material, bottom boundary layer dynamics, bottom sediment, and small-scale stratigraphy were performed by European and North American researchers participating in several projects. The goal of EuroSTRATAFORM researchers is to improve our ability to understand and simulate the physical processes that deliver sediment to the marine environment and generate stratigraphic signatures. Scientists involved in the Po and Apennine Sediment Transport and Accumulation (PASTA) experiment benefited from other major research programs including ACE (Adriatic Circulation Experiment), DOLCE VITA (Dynamics of Localized Currents and Eddy Variability in the Adriatic), EACE (the Croatian East Adriatic Circulation Experiment project), WISE (West Istria Experiment), and ADRICOSM (Italian nowcasting and forecasting) studies.

Adriatic Sea

Decreased atmospheric nitrogen deposition in eastern North America: Predicted responses of forest ecosystems

Historical increases in emissions and atmospheric deposition of oxidized and reduced nitrogen (N) provided the impetus for extensive, global-scale research investigating the effects of excess N in terrestrial and aquatic ecosystems, with several regions within the Eastern Deciduous Forest of the United States found to be susceptible to negative effects of excess N. The Clean Air Act and associated rules have led to decreases in emissions and deposition of oxidized N, especially in eastern U.S., representing a research challenge and opportunity for ecosystem ecologists and biogeochemists. The purpose of this paper is to predict changes in the structure and function of North American forest ecosystems in a future of decreased N deposition. Hysteresis is a property of a system wherein output is not a strict function of corresponding input, incorporating lag, delay, or history dependence, particularly when the response to decreasing input is different from the response to increasing input. We suggest a conceptual hysteretic model predicting varying lag times in recovery of soil acidification, plant biodiversity, soil microbial communities, forest carbon (C) and N cycling, and surface water chemistry toward pre-N impact conditions. Nearly all of these can potentially respond strongly to reductions in N deposition. Most responses are expected to show some degree of hysteresis, with the greatest delays in response occurring in processes most tightly linked to “slow pools” of N in wood and soil organic matter. Because experimental studies of declines in N loads in forests of North America are lacking and because of the expected hysteresis, it is difficult to generalize from experimental results to patterns expected from declining N deposition. These will likely be long-term phenomena, difficult to distinguish from other, concurrent environmental changes, including elevated atmospheric CO 2 , climate change, reductions in acidity, invasions of new species, and long-term vegetation responses to past disturbance.

Environmental Pollution

A synthesis of patterns of environmental mercury inputs, exposure and effects in New York State

Mercury (Hg) pollution is an environmental problem that adversely affects human and ecosystem health at local, regional, and global scales—including within New York State. More than two-thirds of the Hg currently released to the environment originates, either directly or indirectly, from human activities. Since the early 1800s, global atmospheric Hg concentrations have increased by three- to eight-fold over natural levels. In the U.S., atmospheric emissions and point-source releases to waterways increased following industrialization into the mid-1980s. Since then, water discharges have largely been curtailed. As a result, Hg emissions, atmospheric concentrations, and deposition over the past few decades have declined across the eastern U.S. Despite these decreases, Hg pollution persists. To inform policy efforts and to advance public understanding, the New York State Energy Research and Development Authority (NYSERDA) sponsored a scientific synthesis of information on Hg in New York State. This effort includes 23 papers focused on Hg in atmospheric deposition, water, fish, and wildlife published in Ecotoxicology . New York State experiences Hg contamination largely due to atmospheric deposition. Some landscapes are inherently sensitive to Hg inputs driven by the transport of inorganic Hg to zones of methylation, the conversion of inorganic Hg to methylmercury, and the bioaccumulation and biomagnification along food webs. Mercury concentrations exceed human and ecological risk thresholds in many areas of New York State, particularly the Adirondacks, Catskills, and parts of Long Island. Mercury concentrations in some biota have declined in the Eastern Great Lakes Lowlands and the Northeastern Highlands over the last four decades, concurrent with decreases in water releases and air emissions from regional and U.S. sources. However, widespread changes have not occurred in other ecoregions of New York State. While the timing and magnitude of the response of Hg levels in biota varies, policies expected to further diminish Hg emissions should continue to decrease Hg concentrations in food webs, yielding benefits to the fish, wildlife, and people of New York State. Anticipated improvements in the Hg status of aquatic ecosystems are likely to be greatest for inland surface waters and should be roughly proportional to declines in atmospheric Hg deposition. Efforts that advance recovery from Hg pollution in recent years have yielded significant progress, but Hg remains a pollutant of concern. Indeed, due to this extensive compilation of Hg observations in biota, it appears that the extent and intensity of the contamination on the New York landscape and waterscape is greater than previously recognized. Understanding the extent of Hg contamination and recovery following decreases in atmospheric Hg deposition will require further study, underscoring the need to continue existing monitoring efforts.

New York

Transport of elemental mercury in the unsaturated zone from a waste disposal site in an arid region

Mercury contained in buried landfill waste may be released via upward emission to the atmosphere or downward leaching to groundwater. Data from the US Geological Survey’s Amargosa Desert Research Site (ADRS) in arid southwestern Nevada reveal another potential pathway of Hg release: long-distance (10 2 m) lateral migration of elemental Hg (Hg 0 ) through the unsaturated zone. Gas collected from multiple depths from two instrumented boreholes that sample the entire 110-m unsaturated zone thickness and are located 100 and 160 m away from the closest waste burial trench exhibit gaseous Hg concentrations of up to 33 and 11 ng m −3 , respectively. The vertical distribution of gaseous Hg in the borehole closest to the disposal site shows distinct subsurface peaks in concentration at depths of 1.5 and 24 m that cannot be explained by radial diffusive transport through a heterogeneous layered unsaturated zone. The inability of current models to explain gaseous Hg distribution at the ADRS highlights the need to advance the understanding of gas-phase contaminant transport in unsaturated zones to attain a comprehensive model of landfill Hg release.

Applied Geochemistry

Volcanic hail detected with GPS: The 2011 eruption of Grímsvötn Volcano, Iceland

Volcanic plumes are challenging to detect and characterize rapidly, but insights into processes such as hail formation or ash aggregation are valuable to hazard forecasts during volcanic crises. Global Navigation Satellite System (GNSS, which includes GPS) signals traveling from satellites to ground receivers can be disturbed by volcanic plumes. To date, two effects aiding plume detection from GNSS observations have been described: (a) ash‐rich plumes scatter the signal, lowering the signal‐to‐noise ratio (SNR), and (b) some plumes refract and thus delay GNSS signals. Using GNSS data from the VEI 4 2011 Grímsvötn eruption, we show that tephra and water contents of plumes distinctly affect SNR and phase residuals. The signals suggest high‐altitude freezing of plume water into volcanic hail—corroborated by 1‐D modeling and volcanic hail deposits. Combining GNSS SNR and phase residual analyses is valuable for detecting processes that rapidly scrub fine ash out of the atmosphere.

Grímsvötn Volcano

Sea-floor geology and sedimentary processes in the vicinity of Cross Rip Channel, Nantucket Sound, offshore southeastern Massachusetts

Gridded multibeam bathymetry covers approximately 10.4 square kilometers of sea floor in the vicinity of Cross Rip Channel in Nantucket Sound, offshore southeastern Massachusetts. Although originally collected for charting purposes during National Oceanic and Atmospheric Administration hydrographic survey H12007, these acoustic data, and the sea-floor sediment sampling and bottom photography stations subsequently occupied to verify them, show the composition and terrain of the seabed and provide information on sediment transport and benthic habitat. This report is part of an expanding series of cooperative studies by the U.S. Geological Survey, National Oceanic and Atmospheric Administration, and Massachusetts Office of Coastal Zone Management that provide a fundamental framework for research and resource-management activities (for example, windfarms, pipelines, and dredging) along the inner continental shelf offshore of Massachusetts.

Massachusetts