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At least 199 records · Page 11Linked to original sources

Thicknesses of lava flows in satellite images: Comparison of layered mare units with terrestrial analogs

Recent advances in satellite imaging technology have greatly improved our observations of planetary surfaces. The Lunar Reconnaissance Orbiter (LRO) Narrow Angle Camera (NAC) records images with resolutions on average of 0.5 m per pixel, resolving meter scale features on the surface of the Moon. NAC images have revealed layered deposits, interpreted to be sequences of mare basalt flows, in the walls of impact craters on the lunar nearside. However, caution must be exercised in the interpretation of surface processes from morphologies of features that are close to the limits of detectability. Our goal is to quantify where that limit is for lava flow stratigraphy. Here we report on a terrestrial analog study conduced to better constrain limitations in the measurements of thicknesses of lava flows observed in high-resolution satellite-collected images. Using WorldView-2 satellite images, we mapped layered basalt flows at three sites in the Wai'anae and Ko'olau Ranges of O'ahu, Hawai'i. Fieldwork conducted at these sites allowed for assessment of the accuracy of image interpretations. We found that flow thickness estimates made using WorldView-2 images overestimated thicknesses of individual lava flows measured in the field at all eight locations visited by a factor of 1.2 to 3.5. A primary reason for this overestimation by remote sensing analysis is that many outcropping “layers” within a transect contain more than one individual flow, a distinction that is not visible in satellite images. However, the mean thickness of the layers seen in the orbital data was 0.8 to 1.7 times the outcrop thickness measured in the field, suggesting that the remote measurements should be considered estimates of the outcrop thickness rather than the thickness of individual lava flows. Measurements of layered lunar mare lava units in LRO NAC images provided layer thicknesses that ranged from <1–6 times greater than those derived from images of the O'ahu study sites. It is reasonable to expect that many lunar outcrops similarly contain more than one individual flow and display similar outcropping patterns. This suggests that many current estimates of layer thicknesses derived by comparable methods actually correspond to outcrop thicknesses. Current interpretations of lava flow thicknesses derived from planetary images should be considered maximums for individual flow thicknesses with uncertainties that may be as high as a factor of 3 or more.

Hawaii↗

Digital data set that describe aquifer characteristics of the Antlers aquifer in southeastern Oklahoma

The data sets in this report include digitized aquifer boundaries and maps of hydraulic conductivity, recharge, and ground-water level elevation contours for the Antlers aquifer in southeastern Oklahoma. The Early Cretaceous-age Antlers Sandstone is an important source of water in an area that underlies about 4,400-square miles of all or part of Atoka, Bryan, Carter, Choctaw, Johnston, Love, Marshall, McCurtain, and Pushmataha Counties. The Antlers aquifer consists of sand, clay, conglomerate, and limestone in the outcrop area. The upper part of the Antlers aquifer consists of beds of sand, poorly cemented sandstone, sandy shale, silt, and clay. The Antlers aquifer is unconfined where it outcrops in an area of about 1,800-square miles (Morton, 1992). The recharge, hydraulic conductivity, and aquifer boundaries data sets include the outcrop area of the Antlers Sandstone in Oklahoma and areas where the Antlers is overlain by alluvial and terrace deposits and a few small thin outcrops of the Goodland Limestone. Most of the lines in the data sets are from the digital data of the surficial geology of the Antlers Sandstone from Cederstrand (1996a, 1996b) except where the Antlers aquifer is overlain by alluvial and terrace deposits near streams and rivers. Morton (1992) interpolated the Antlers aquifer boundaries under the alluvial and terrace deposits where streams cross the aquifer outcrop. Aquifer boundary lines for areas where the aquifer is overlain by alluvial and terrace deposits were digitized and are similar to the aquifer boundaries shown in Morton (1992). A few polygons in this data set represent small and thin outcrops of the Goodland Limestone overlying the Antlers aquifer. The Antlers aquifer in Texas (Morton, 1992) is not included in this data set. The maps from which this data set was derived were scanned or digitized from maps published at a scale of 1:250,000. Hydraulic conductivity and recharge values were used as input to the ground-water model report for the Antlers aquifer by Morton (1992). The water-level elevation contours were digitized from a mylar map at a scale of 1:250,000 that was used to prepare the final map that was published as plate 1, map A, "Observed potentiometric surface, 1970, Antlers aquifer" at a scale of 1:500,000 in Morton (1992). Morton (1992) used water levels measured in wells in 1970 to construct the map. The water-level elevation contours for the Antlers aquifer in Texas (Morton, 1992) are not included in this data set. Ground-water flow models are numerical representations that simplify and aggregate natural systems. Models are not unique; different combinations of aquifer characteristics may produce similar results. The hydraulic conductivity and recharge are closely interrelated. As long as these two model inputs are in balance the model has a small mean residual; it represents the natural system numerically. If the hydraulic conductivity is accurately known, the model can be used to accurately determine recharge. Likewise, if the hydraulic conductivity is poorly known, then the recharge will be poorly determined. Therefore, values of hydraulic conductivity and recharge used in the model and presented in this data set are not precise, but are within a reasonable range when compared to independently collected data. In most aquifers, hydraulic conductivity measurements made in wells or in cores will range over several orders of magnitude, even over short horizontal and vertical distances. Hydraulic conductivity values derived from ground-water flow models represent areal generalizations and do not reflect the large local variance in well or core measurements. Recharge probably varies considerably over the local area, and model recharge is at best an average over an area at least as large as the model grid (and probably much larger than a single cell). Compilation of the data sets was funded under a cooperative Joint Funding Agreement between the U.S. Geological Survey and the State of Oklahoma, Office of the Secretary of Environment.

Oklahoma↗

Properties and chemical constituents in ground water from the middle Wilcox aquifer, Gulf Coast regional aquifer systems, south-central United States

The Gulf Coast Regional Aquifer-System Analysis is a study of regional aquifers composed of sediments of mostly Cenozoic age that underlie about 230,000 sq mi of the Gulf Coastal Plain. These regional aquifers are part of three aquifer systems: (1) the Mississippi Embayment Aquifer System, (2) the Texas Coastal Uplands Aquifer System, and (3) the Coastal Lowlands Aquifer System. The water chemistry of the Middle Wilcox Aquifer, which is part of the Mississippi Embayment Aquifer System and the Texas Coastal Uplands Aquifer System is presented by a series of maps. These maps show the area1 distribution of (1) the concentration of dissolved solids and temperature, (2) the primary water types and pH, (3) the concentration of major ions and silica, and (4) the milliequivalent ratios of selected ions. Dissolved constituents, pH, temperature, and ratios are based on the median values of all samples in each 100-sq-mi area. The concentration of dissolved solids in water from the Middle Wilcox Aquifer ranges from 26 mg/L in the northern part of the Mississippi Embayment Aquifer System to 125,500 mg/L in a down-dip area in southeastern Texas. The primary water types, which are based on the most frequently observed type in each 100-sq-mi area, are calcium bicarbonate in the outcrop in Missouri, Kentucky, Mississippi, and southern Texas; sodium bicarbonate in the remaining outcrop areas and all areas from outcrop to mid-dip; and sodium chloride in all down-dip areas. The concentrations of major ions in water from the Middle Wilcox Aquifer generally increase from the outcrop area to the down-dip limit of the data. The milliequivalent ratio of magnesium plus calcium to bicarbonate ranges from less than 0.01 to 158 and generally decreases from outcrop to mid-dip and increases from mid-dip to the down-dip limit of the data. From the Sabine Uplift eastward to southwestern Alabama the ratio of bicarbonate to chloride generally decreases from outcrop to down-dip in the area west of the Mississippi River and shows localized trends east of the Mississippi River.

Alabama, Arkansas, Kentucky, Louisiana, Mississipp↗

Properties and chemical constituents in ground water from the lower Wilcox Aquifer, Mississippi Embayment Aquifer System, south-central United States

The Gulf Coast Regional Aquifer-System Analysis is a study of regional aquifers composed of sediments of mostly Cenozoic age that underlie about 230,000 sq mi of the Gulf Coastal Plain. These regional aquifers are part of three aquifer systems: (1) the Mississippi Embayment Aquifer System, (2) the Texas Coastal Uplands Aquifer System, and (3) the Coastal Lowlands Aquifer System. The water chemistry of the Lower Wilcox Aquifer, which is part of the Mississippi Embayment Aquifer System is presented by a series of maps. These maps show the areal distribution of (1) the concentration of dissolved solids and temperature, (2) the primary water types and pH, (3) the concentration of major ions and silica, and (4) the milliequivalent ratios of selected ions. Dissolved constituents, pH, temperature, and ratios are based on the median values of all samples in each 100-sq-mi area. The concentration of dissolved solids in water from the Lower Wilcox Aquifer ranges from 18 mg/L near the outcrop in western Tennessee to 122,000 mg/L in a down-dip area in southern Mississippi. The primary water type is calcium bicarbonate in the outcrop area and sodium bicarbonate in all other areas of the aquifer within the limits of available data. The concentrations of major ions generally increase from the outcrop area to the down-dip limit of the data in the southern part of the aquifer area east of the Mississippi River. The milliequivalent ratio maps of selected ions in water from the Lower Wilcox Aquifer indicate some trends. The milliequivalent ratio of magnesium plus calcium to bicarbonate ranges from less than 0.1 to 40.4 and generally decreases from outcrop to down-dip limit of the data in the southern part of the aquifer area east of the Mississippi River. The milliequivalent ratio of bicarbonate to chloride ranges from 0.01 in southern Mississippi to 52.3 in northwestern Mississippi. This ratio increases from the outcrop toward the Mississippi River and from north to south in the northern part of the aquifer area east of the Mississippi River whereas the ratio increases from outcrop to mid-dip and decreases from mid-dip to down-dip limit of the data in the southern part east of the Mississippi River.

Water-Resources Investigations Report↗

Mineralogical, chemical and K-Ar isotopic changes in Kreyenhagen Shale whole rocks and <2 µm clay fractions during natural burial and hydrous-pyrolysis experimental maturation

Progressive maturation of the Eocene Kreyenhagen Shale from the San Joaquin Basin of California was studied by combining mineralogical and chemical analyses with K&ndash;Ar dating of whole rocks and <2 &mu;m clay fractions from naturally buried samples and laboratory induced maturation by hydrous pyrolysis of an immature outcrop sample. The K&ndash;Ar age decreases from 89.9 &plusmn; 3.9 and 72.4 &plusmn; 4.2 Ma for the outcrop whole rock and its <2 &mu;m fraction, respectively, to 29.7 &plusmn; 1.5 and 21.0 &plusmn; 0.7 Ma for the equivalent materials buried to 5167 m. The natural maturation does not produce K&ndash;Ar ages in the historical sense, but rather K/Ar ratios of relative K and radiogenic 40 Ar amounts resulting from a combined crystallization of authigenic and alteration of initial detrital K-bearing minerals of the rocks. The Al/K ratio of the naturally matured rocks is essentially constant for the entire depth sequence, indicating that there is no detectable variation in the crystallo-chemical organization of the K-bearing alumino-silicates with depth. No supply of K from outside of the rock volumes occurred, which indicates a closed-system behavior for it. Conversely, the content of the total organic carbon (TOC) content decreases significantly with burial, based on the progressive increasing Al/TOC ratio of the whole rocks. The initial varied mineralogy and chemistry of the rocks and their <2 &mu;m fractions resulting from differences in detrital sources and depositional settings give scattered results that homogenize progressively during burial due to increased authigenesis, and concomitant increased alteration of the detrital material. Hydrous pyrolysis was intended to alleviate the problem of mineral and chemical variations in initially deposited rocks of naturally matured sequences. However, experiments on aliquots from thermally immature Kreyenhagen Shale outcrop sample did not mimic the results from naturally buried samples. Experiments conducted for 72 h at temperatures from 270 to 365 &deg;C did not induce significant changes at temperatures above 310 &deg;C in the mineralogical composition and K&ndash;Ar ages of the rock and <2 &mu;m fraction. The K&ndash;Ar ages of the <2 &mu;m fraction range from 72.4 &plusmn; 4.2 Ma in the outcrop sample to 62.4 &plusmn; 3.4 Ma in the sample heated the most at 365 &deg;C for 216 h. This slight decrease in age outlines some loss of radiogenic 40 Ar, together with losses of organic matter as oil, gas, and aqueous organic species. Large amounts of smectite layers in the illite&ndash;smectite mixed layers of the pyrolyzed outcrop <2 &mu;m fraction remain during thermal experiments, especially above 310 &deg;C. With no illitization detected above 310 &deg;C, smectite appears to have inhibited rather than promoted generation of expelled oil from decomposition of bitumen. This hindrance is interpreted to result from bitumen impregnating the smectite interlayer sites and rock matrix. Bitumen remains in the <2 &mu;m fraction despite leaching with H 2 O 2 . Its presence in the smectite interlayers is apparent by the inability of the clay fraction to fully expand or collapse once bitumen generation from the thermal decomposition of the kerogen is completed, and by almost invariable K&ndash;Ar ages confirming for the lack of any K supply and/or radiogenic 40 Ar removal. This suggests that once bitumen impregnates the porosity of a progressively maturing source rock, the pore system is no longer wetted by water and smectite to illite conversion ceases. Experimental attempts to evaluate the smectite conversion to illite should preferentially use low-TOC rocks to avoid inhibition of the reaction by bitumen impregnation.

California↗

Fracture network of the Ferron Sandstone Member of the Mancos Shale, east-central Utah, USA

The fracture network at the outcrop of the Ferron Sandstone Member of the Mancos Shale was studied to gain an understanding of the tectonic history of the region and to contribute data to studies of gas and water transmissivity related to the occurrence and production of coal-bed methane. About 1900 fracture readings were made at 40 coal outcrops and 62 sandstone outcrops in the area from Willow Springs Wash in the south to Farnham dome in the north of the study area in east-central Utah.Two sets of regional, vertical to nearly vertical, systematic face cleats were identified in Ferron coals. A northwest-striking set trends at a mean azimuth of 321??, and a northeast-striking set has a mean azimuth of 55??. Cleats were observed in all coal outcrops examined and are closely spaced and commonly coated with thin films of iron oxide.Two sets of regional, systematic joint sets in sandstone were also identified and have mean azimuths of 321?? and 34??. The joints of each set are planar, long, and extend vertically to nearly vertically through multiple beds; the northeast-striking set is more prevalent than the northwest-striking set. In some places, joints of the northeast-striking set occur in closely spaced clusters, or joint zones, flanked by unjointed rock. Both sets are mineralized with iron oxide and calcite, and the northwest-striking set is commonly tightly cemented, which allowed the northeast-striking set to propagate across it. All cleats and joints of these sets are interpreted as opening-mode (mode I) fractures. Abutting relations indicate that the northwest-striking cleats and joints formed first and were later overprinted by the northeast-striking cleats and joints. Burial curves constructed for the Ferron indicate rapid initial burial after deposition. The Ferron reached a depth of 3000 ft (1000 m) within 5.2 million years (m.y.), and this is considered a minimum depth and time for development of cleats and joints. The Sevier orogeny produced southeast-directed compressional stress at this time and is thought to be the likely mechanism for the northwest-striking systematic cleats and joints. The onset of the Laramide orogeny occurred at about 75 Ma, within 13.7 m.y. of burial, and is thought to be the probable mechanism for development of the northeast-striking systematic cleats and joints. Uplift of the Ferron in the late Tertiary contributed to development of butt cleats and secondary cross-joints and probably enhanced previously formed fracture sets. Using a study of the younger Blackhawk Formation as an analogy, the fracture pattern of the Ferron in the subsurface is probably similar to that at the surface, at least as far west as the Paradise fault and Joe's Valley graben. Farther to the west, on the Wasatch Plateau, the orientations of Ferron fractures may diverge from those measured at the outcrop. ?? 2003 Elsevier B.V. All rights reserved.

International Journal of Coal Geology↗

Chapter 14 Rex Chert member of the Permian Phosphoria Formation: Composition, with emphasis on elements of environmental concern

We present bulk chemical and mineralogical compositions, as well as petrographic and outcrop descriptions, of rocks collected from three measured outcrop sections of the Rex Chert Member of the Phosphoria Formation in southeast Idaho. The three measured sections were chosen from 10 outcrops of Rex Chert that were described in the field. The Rex Chert overlies the Meade Peak Phosphatic Shale Member of the Phosphoria Formation, the source of phosphate ore in the region. Rex Chert removed as overburden constitutes part of the material transferred to waste-rock piles during phosphate mining. It is also used to surface roads in the mining district. It has been proposed that the chert be used to cap and isolate waste piles, thereby inhibiting the leaching of potentially toxic elements into the environment. The rock samples studied here are from individual chert beds representative of each stratigraphic section sampled. The Cherty Shale Member of the Phosphoria Formation that overlies the Rex Chert in measured section 1 and the upper Meade Peak and the transition zone to the Rex Chert in section 7 were also described and sampled. The cherts are predominantly spiculite composed of granular and mosaic quartz, and sponge spicules, with various but minor amounts of other fossils and detrital grains. The Cherty Shale Member and transition rocks between the Meade Peak and Rex Chert are siliceous siltstones and argillaceous cherts with ghosts of sponge spicules and somewhat more detrital grains than the chert. The dominant mineral is quartz. Carbonate beds are rare in each section and are composed predominantly of calcite and dolomite in addition to quartz. Feldspar, mica, clay minerals, calcite, dolomite, and carbonate fluorapatite are minor to trace minerals in the chert. The concentration of SiO 2 in the chert averages 94.6 wt.%. Organic-carbon content is generally very low, but can be as much as 1.8% in Cherty Shale Member samples and as much as 3.3% in samples from the transition between the Meade Peak and Rex Chert. Likewise, phosphate (P 2 O 5 ) is generally low in the chert, but can be as much as 3.1% in individual chert beds. Selenium concentrations in Rex Chert and Cherty Shale Member samples vary from <0.2 to 138 ppm, with a mean concentration of 7.0 ppm. This mean Se content is heavily dependent on two values of 101 and 138 ppm for siliceous siltstone from the lower part of the Rex Chert, which contains rocks that are transitional in character between the Meade Peak and Rex Chert Members. Without those two samples, the mean Se concentration is < 1.0 ppm. Other elements of environmental interest, As, Cr, V, Zn, Hg, and Cd, generally occur in concentrations near or below that in average continental shale. Stratigraphic changes, equivalent to temporal changes in the depositional basin, in chemical composition of rocks are notable either as uniform changes through the sections or as distinct differences in the mean composition of rocks that comprise the upper and lower halves of the sections. Q-mode factors are interpreted to represent the following rock and mineral components: chert-silica component consisting of Si (±Ba); phosphorite-carbonate fluorapatite component composed of P, Ca, As, Y, V, Cr, Sr, and La (± Fe, Zn, Cu, Ni, Li, Se, Nd, Hg); shale component composed of Al, Na, Zr, K, Ba, Li, and organic C (± Ti, Mg, Se, Ni, Fe, Sr, V, Mn, Zn); carbonate component (dolomite, calcite, silicified carbonates) composed of carbonate C, Mg, Ca, and Si (±Mn); and, tentatively, organic matter-hosted elements (and/or sulfide-sulfate phases) composed of Cu (± organic C, Zn, Mn, Si, Ni, Hg, Li). Selenium shows a dominant association with organic matter and to lesser degrees associations with other shale components and carbonate fluorapatite. Consideration of larger numbers of factors in Q-mode analysis indicates that native Se (a factor containing Se (± Ba)) may also comprise a minor component of the Se complement. Comparison of our data with those from newly exposed outcrops in active phosphate mines indicates that weathering of typical Rex Chert outcrops likely plays an important role in removing environmentally sensitive elements.

Idaho↗

Soil grain analyses at Meridiani Planum, Mars

Grain‐size analyses of the soils at Meridiani Planum have been used to identify rock sources for the grains and provide information about depositional processes under past and current conditions. Basaltic sand, dust, millimeter‐size hematite‐rich spherules interpreted as concretions, spherule fragments, coated partially buried spherules, basalt fragments, sedimentary outcrop fragments, and centimeter‐size cobbles are concentrated on the upper surfaces of the soils as a lag deposit, while finer basaltic sands and dust dominate the underlying soils. There is a bimodal distribution of soil grain sizes with one population representing grains <125 μm and the other falling between 1–4.5 mm. Soils within craters like Eagle and Endurance show a much greater diversity of grain morphologies compared to the plains. The spherules found in the plains soils are approximately 1–2 mm smaller in size than those seen embedded in the outcrop rocks of Eagle and Endurance craters. The average major axis for all unfractured spherules measured in the soils and outcrop rocks is 2.87 ± 1.18 mm, with a trend toward decreasing spherule sizes in both the soils and outcrop rocks as the rover drove southward. Wind ripples seen across the plains of Meridiani are dominated by similar size (1.3–1.7 mm) hematite‐rich grains, and they match in size the larger grains on plains ripples at Gusev Crater. Larger clasts and centimeter‐size cobbles that are scattered on the soils have several spectral and compositional types, reflecting multiple origins. The cobbles tend to concentrate within ripple troughs along the plains and in association with outcrop exposures.

Journal of Geophysical Research E: Planets↗

Veneers, rinds, and fracture fills: Relatively late alteration of sedimentary rocks at Meridiani Planum, Mars

Veneers and thicker rinds that coat outcrop surfaces and partially cemented fracture fills formed perpendicular to bedding document relatively late stage alteration of ancient sedimentary rocks at Meridiani Planum, Mars. The chemistry of submillimeter thick, buff-colored veneers reflects multiple processes at work since the establishment of the current plains surface. Veneer composition is dominated by the mixing of silicate-rich dust and sulfate-rich outcrop surface, but it has also been influenced by mineral precipitation, including NaCl, and possibly by limited physical or chemical weathering of sulfate minerals. Competing processes of chemical alteration (perhaps mediated by thin films of water or water vapor beneath blanketing soils) and sandblasting of exposed outcrop surfaces determine the current distribution of veneers. Dark-toned rinds several millimeters thick reflect more extensive surface alteration but also indicate combined dust admixture, halite precipitation, and possible minor sulfate removal. Cemented fracture fills that are differentially resistant to erosion occur along the margins of linear fracture systems possibly related to impact. These appear to reflect limited groundwater activity along the margins of fractures, cementing mechanically introduced fill derived principally from outcrop rocks. The limited thickness and spatial distribution of these three features suggest that aqueous activity has been rare and transient or has operated at exceedingly low rates during the protracted interval since outcropping Meridiani strata were exposed on the plains surface.

Journal of Geophysical Research E: Planets↗

Shaler: in situ analysis of a fluvial sedimentary deposit on Mars

This paper characterizes the detailed sedimentology of a fluvial sandbody on Mars for the first time and interprets its depositional processes and palaeoenvironmental setting. Despite numerous orbital observations of fluvial landforms on the surface of Mars, ground-based characterization of the sedimentology of such fluvial deposits has not previously been possible. Results from the NASA Mars Science Laboratory Curiosity rover provide an opportunity to reconstruct at fine scale the sedimentary architecture and palaeomorphology of a fluvial environment on Mars. This work describes the grain size, texture and sedimentary facies of the Shaler outcrop, reconstructs the bedding architecture, and analyses cross-stratification to determine palaeocurrents. On the basis of bedset geometry and inclination, grain-size distribution and bedform migration direction, this study concludes that the Shaler outcrop probably records the accretion of a fluvial barform. The majority of the outcrop consists of large-scale trough cross-bedding of coarse sand and granules. Palaeocurrent analyses and bedform reconstruction indicate that the beds were deposited by bedforms that migrated towards the north-east, across the surface of a bar that migrated south-east. Stacked cosets of dune cross-bedding suggest aggradation of multiple bedforms, which provides evidence for short periods of sustained flow during Shaler deposition. However, local evidence for aeolian reworking and the presence of potential desiccation cracks within the outcrop suggest that fluvial deposition may have been intermittent. The uppermost strata at Shaler are distinct in terms of texture and chemistry and are inferred to record deposition from a different sediment dispersal system with a contrasting provenance. The outcrop as a whole is a testament to the availability of liquid water on the surface of Mars in its early history.

Sedimentology↗

Western frontal fault of the Canyon Range: Is it the breakaway zone of the Sevier Desert detachment?

Geologic evidence developed from surface exposures demonstrates that the western frontal fault of the Canyon Range is a major structure representing the eastern breakaway zone of the Sevier Desert detachment. The western frontal fault of the Canyon Range east of Delta, Utah, is a north-trending, west-dipping, low-angle (18 °–24 ° ) normal fault that juxtaposes syntectonic conglomerates and large-rock avalanches of the Miocene Oak City Formation against footwall rocks that have been ductilely, cataclastically, and brittlely deformed. The Oak City strata dip variably to the east; dips are shallow in eastern outcrops (5 ° –15 ° ), steeper in central outcrops (20 ° –60 ° ), and shallow in the western outcrops (10 ° –20 ° ). In eastern exposures, the shallow dips of the Oak City Formation (5 ° –15 ° ) and the acute angle of 20 ° –35 ° between the western frontal fault and Oak City units limit past rotation of the fault to ≤15 ° . The systematic variation in the dip of Oak City units from east to west suggests that the western frontal fault probably flattens beneath present Oak City outcrops, linking the fault to the shallow reflector seen in the COCORP (Consortium for Continental Reflection Profiling) Utah line 1 seismic line beneath the westernmost outcrops of the Oak City Formation. Upper plate movement is constrained by Oak City clast compositions and rock-avalanche lithologies, fault geometry, and lower plate reconstruction to a maximum of 6–7 km since Oak City syntectonic deposition at ∼12–13 Ma. Maximum upper plate displacement for the entire Sevier Desert detachment cannot be determined from these breakaway-zone exposures.

Geology↗

A far-traveled basalt lava flow in north-central Oregon, USA

Widely separated basalt lava-flow outcrops in north-central Oregon, USA, expose products of a single eruptive episode. A Pliocene lava flow, here informally termed the Tetherow basalt, issued from vents near Redmond, in the Deschutes basin of Oregon, as a plains-forming basalt now exposed in continuous outcrops northward for 60 km. A similar basalt crops out 47 km farther north, near Maupin, within what was then a slightly incised ancestral Deschutes River canyon. The northernmost outcrops of this lava flow lie on Fulton Ridge, in the Dalles basin, near the confluence of the Deschutes and Columbia Rivers. Complementary lines of evidence confirm these rocks are all from the same volcanic eruption. Outcrops in the Deschutes and Dalles basins are chemically similar high-titanium basalts, petrographically similar to each other and distinct from other lava flows in the area. Paleomagnetic directions from 11 scattered sites are similar and indistinguishable by various tests for a common mean. Three new 40 Ar/ 39 Ar ages indicate the Tetherow basalt eruption occurred between 5.5 Ma and 5.0 Ma, likely at ca. 5.2 Ma. The widely separated outcrops of this lava flow span 160–180 km along the ancestral Deschutes River and downstream Columbia River. The lava flow’s length and erupted volume of 15–20 km 3 are extraordinarily large in a non-flood-basalt setting. This lava flow provides a datum with which to describe regional physiographic history, assess incision rates, and infer tectonic history. Spanning different depositional basins, the Tetherow basalt is a useful chronologic and stratigraphic marker bed.

Oregon↗

Bottom-up characterization of geologic methane emissions in the San Juan Basin in the southwestern USA

Methane is a potent greenhouse gas that plays an important role in atmospheric chemistry and global warming. The current global methane budget has large uncertainties, and a better understanding of the budget would help to guide strategies for reducing anthropogenic emissions to fight climate change. Natural geologic methane emissions are a particularly poorly constrained source, with top-down estimates from 14 C in ice cores suggesting much lower geologic emissions than bottom-up scaling of direct flux measurements. Our study aims to contribute to resolving this discrepancy through improved bottom-up characterization of geologic methane seepage in the San Juan Basin in southwestern Colorado and northwestern New Mexico, USA. We performed 983 new flux chamber measurements in this basin during summer 2022 and winter 2023 field campaigns. Our results, in combination with prior measurements, suggest that natural seepage in the San Juan Basin only occurs on or near the Fruitland coal outcrop. Specifically, our new measurements confirm previous measurements of seepage along the northwestern exposure of the Fruitland outcrop in Colorado (a known hydrodynamic overpressure region) and for the first time, identified seepage locations along the southernmost Fruitland outcrop exposure in New Mexico, in association with a coal cleat and a fault. Overall, seepage along the Fruitland coal outcrop is heterogeneously distributed, with both positive and negative (interpreted as microbial soil sink) methane fluxes. Features that are hypothesized to be predictive of seepage (e.g., faults) were not associated with positive methane fluxes in areas outside of the Fruitland outcrop. Our best estimate for total geologic methane seepage in the San Juan Basin from spatial interpolation and statistical upscaling is approximately 0.14 Tg CH 4 /yr, with a range from 0.029 to 0.48 Tg CH 4 /yr. This best-estimate value is lower than a previous bottom-up estimate from a gridded seepage inventory, but higher than a previous top-down estimate.

Colorado, New Mexico↗

Hydrology of the Arbuckle Mountain area, south-central Oklahoma

Rocks that make up the Arbuckle-Simpson aquifer crop out over about 500 square miles in the Arbuckle Mountains province in south-central Oklahoma. The aquifer consists of limestone, dolomite, and sandstone of the Arbuckle and Simpson Groups of Late Cambrian to Middle Ordovician age and is about 5,000 to 9,000 feet thick. The rocks were subjected to intensive folding and faulting associated with major uplift of the area during Early to Late Pennsylvanian time. Water in the aquifer is confined in some parts of the area, while in other parts it is unconfined. The average saturated thickness of the aquifer is about 3,500 feet in the outcrop area. Water levels measured in wells fluctuated from 8 to 53 feet each year, primarily in response to recharge from rainfall. Recharge to the aquifer is estimated at about 4.7 inches per year. The average storage coefficient of the aquifer is estimated at 0.008, and the average transmissivity is estimated at 15,000 feet squared per day. Based on an average saturated thickness of about 3,500 feet and a storage coefficient of 0.008, the volume of ground water contained in the 500-square-mile outcrop area is about 9 million acre-feet. An undetermined amount of fresh water probably exists in the aquifer around the periphery of the aquifer outcrop. Base flow of streams that drain the aquifer accounts for about 60 percent of the total annual runoff from the outcrop area and is maintained by numerous springs. The close hydraulic connection between streams in the outcrop area and the aquifer is shown by a close correlation between base flow in Blue River and the fluctuation of ground-water levels in five wells in the Blue River basin. This correlation also exists between the discharge by Byrds Mill Spring and the fluctuation in water level in a nearby observation well; increase and decrease in spring discharge correspond to rise and fall of the water level in the well. The chemical quality of water from the Arbuckle-Simpson aquifer is suitable for most industrial and municipal uses. The water is hard and of the bicarbonate type; the average hardness is about 340 milligrams per liter, and the average dissolved-solids concentration is about 360 milligrams per liter. Because springs issue from the aquifer and discharge to streams in the area, the quality of water from springs and base flow in streams is similar to that of ground water. The average dissolved-solids concentration of stream water is slightly less than that of water from wells and springs.

Oklahoma↗

Hydrogeology and simulation of ground-water flow and land-surface subsidence in the northern part of the Gulf Coast aquifer system, Texas

As a part of the Texas Water Development Board Ground- Water Availability Modeling program, the U.S. Geological Survey developed and tested a numerical finite-difference (MODFLOW) model to simulate ground-water flow and land-surface subsidence in the northern part of the Gulf Coast aquifer system in Texas from predevelopment (before 1891) through 2000. The model is intended to be a tool that water-resource managers can use to address future ground-water-availability issues. From land surface downward, the Chicot aquifer, the Evangeline aquifer, the Burkeville confining unit, the Jasper aquifer, and the Catahoula confining unit are the hydrogeologic units of the Gulf Coast aquifer system. Withdrawals of large quantities of ground water have resulted in potentiometric surface (head) declines in the Chicot, Evangeline, and Jasper aquifers and land-surface subsidence (primarily in the Houston area) from depressurization and compaction of clay layers interbedded in the aquifer sediments. In a generalized conceptual model of the aquifer system, water enters the ground-waterflow system in topographically high outcrops of the hydrogeologic units in the northwestern part of the approximately 25,000-square-mile model area. Water that does not discharge to streams flows to intermediate and deep zones of the system southeastward of the outcrop areas where it is discharged by wells and by upward leakage in topographically low areas near the coast. The uppermost parts of the aquifer system, which include outcrop areas, are under water-table conditions. As depth increases in the aquifer system and as interbedded sand and clay accumulate, water-table conditions evolve into confined conditions. The model comprises four layers, one for each of the hydrogeologic units of the aquifer system except the Catahoula confining unit, the assumed no-flow base of the system. Each layer consists of 137 rows and 245 columns of uniformly spaced grid blocks, each block representing 1 square mile. Lateral no-flow boundaries were located on the basis of outcrop extent (northwestern), major streams (southwestern, northeastern), and downdip limit of freshwater (southeastern). The MODFLOW general-head boundary package was used to simulate recharge and discharge in the outcrops of the hydrogeologic units. Simulation of land-surface subsidence (actually, compaction of clays) and release of water from storage in the clays of the Chicot and Evangeline aquifers was accomplished using the Interbed-Storage Package designed for use with the MODFLOW model. The model was calibrated by trial-anderror adjustment of selected model input data in a series of transient simulations until the model output (potentiometric surfaces, land-surface subsidence, and selected water-budget components) reasonably reproduced field measured (or estimated) aquifer responses. Model calibration comprised four elements: The first was qualitative comparison of simulated and measured heads in the aquifers for 1977 and 2000; and quantitative comparison by computation and areal distribution of the root-mean-square error between simulated and measured heads. The second calibration element was comparison of simulated and measured hydrographs from wells in the aquifers in a number of counties throughout the modeled area. The third calibration element was comparison of simulated water-budget componentsprimarily recharge and dischargeto estimates of physically reasonable ranges of actual water-budget components. The fourth calibration element was comparison of simulated land-surface subsidence from predevelopment to 2000 to measured land surface subsidence from 1906 through 1995.

Texas↗

Characterization of ground-water flow and water quality for the Madison and Minnelusa aquifers in northern Lawrence County, South Dakota

The Madison and Minnelusa aquifers are used extensively for water supplies for the city of Spearfish and other users in northern Lawrence County, South Dakota. Ground water in the Madison and Minnelusa aquifers in the study area generally flows north from outcrop areas where recharge from sinking streams and infiltration of precipitation occurs. Ground water that moves northward and eastward around the Black Hills enters the study area from the west and results in hydraulic heads that are several hundred feet higher on the western side of the study area than on the eastern side. The estimated average recharge rate of 38 cubic feet per second (ft3/s) on outcrops of the Madison Limestone and Minnelusa Formation is less than the total estimated average spring discharge rate of 51 ft3/s in the northwestern part of the study area. Sixteen pounds of fluorescein dye were injected into Spearfish Creek on March 25, 2003, when streamflow was 6.6 ft3/s. The dye was detected in water samples from four wells completed in the Madison aquifer ranging from 2.6 to 4.5 miles north of the injection site. First arrival times ranged from 5 to 169 days, and ground-water velocities ranged from about 0.1 to 0.5 mile per day. Sixty-four pounds of Rhodamine WT was injected into Spearfish Creek at the same location on May 9, 2003, when streamflow was 5.6 ft3/s. Rhodamine WT dye concentrations measured in samples from the same four wells were about an order of magnitude less than measured fluorescein concentrations. Oxygen- and deuterium-isotope values for samples from Cox Lake and McNenny Pond springs indicated a probable component of spring discharge that originates from outcrops of the Madison Limestone and Minnelusa Formation on the Limestone Plateau south of the study area. Oxygen- and deuterium-isotope values for samples from Mirror Lake spring indicated possible contributions from overlying aquifers and local recharge. Oxygen- and deuterium-isotope values for the combined springflow contributing to Crow Creek in the northwestern part of the study area indicated that the primary source of water is the Madison and Minnelusa aquifers. Oxygen- and deuterium-isotope values for Old Hatchery and Higgins Gulch springs, located north of Spearfish, indicated a source water originating from the outcrops of the Madison Limestone and Minnelusa Formation within the study area. Concentrations of three chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) were used to characterize ground-water residence times in the study area. For the four wells where dye was detected, CFC-11 apparent ages ranged from 12 to 26 years, indicating that the wells contained months-old water mixed with years- to decades-old water. Logarithmic regression analysis of the CFC-11 apparent ages for water from 10 wells and distance to a possible conduit trending north through the area where dye was detected, yielded an r2 value of 0.71. Straight-line regression analysis of the CFC-11 apparent ages for the six wells closest to the possible conduit had an r2 value of 0.96. Two wells located relatively close to the outcrop areas had no or very low tritium values indicating relatively long residence times and diffuse ground-water flow. The tritium value of 7.2 TU in water from well COL where dye was detected, indicated that the water probably is a bimodal mixture, with a substantial portion that is older than 50 years. Water from well ELL, where dye was detected, had a tritium value of 19.7 TU and a CFC apparent age of 15 years, indicating that the sample from this well probably is a unimodal mixture with very little water older than 50 years. Comparison of the CFC apparent age for three spring sites (Cox Lake, 26 years; McNenny Pond, 26 years; Mirror Lake, 13 years) also indicated that Mirror Lake spring probably has a component of local recharge from formations that overlie the Minnelusa Formation. In the Madison aquifer, specific conductance ranges from 18 to 945 microsiemens per cen

South Dakota↗

Preliminary study of radioactive limonite localities in Colorado, Utah, and Wyoming

Nine radioactive limonite localities of different types were sampled during the spring and fall of 1953 in an effort to establish criteria for differentiating limonite outcrops associated with uranium or thorium deposits from limonite outcrops not associated with such deposits. The samples were analyzed for uranium and thorium by standard chemical methods, for equivalent uranium by the radiometric method, and for a number of common metals by semiquantitative geochemical methods. Correlation coefficients were then calculated for each of the metals with respect to equivalent uranium, and to uranium where present, for all of the samples from each locality. The correlation coefficients may indicate a significant association between uranium or thorium and certain metals. Occurrences of specific that are interpreted as significant very considerably for different uranium localities but are more consistent for the thorium localities. Samples taken from radioactive outcrops in the vicinity of uranium or thorium deposits can be quickly analyzed by geochemical methods for various elements. Correlation coefficients can then be determined for the various elements with respect to uranium or thorium; if any significant correlations are obtained, the elements showing such correlation may be indicators of uranium or thorium. Soil samples of covered areas in the vicinity of the radioactive outcrop may then be analyzed for the indicator elements and any resulting anomalies used as a guide for prospecting where the depth of overburden is too great to allow the use of radiation-detecting instruments. Correlation coefficients of the associated indicator elements, used in conjunction with petrographic evidence, may also be useful in interpreting the origin and paragenesis of radioactive deposits. Changes in color of limonite stains on the outcrop may also be a useful guide to ore in some areas.

Colorado;Utah;Wyoming↗

Geochemistry of the Madison and Minnelusa aquifers in the Black Hills area, South Dakota

The Madison and Minnelusa aquifers are two of the most important aquifers in the Black Hills area because of utilization for water supplies and important influences on surface-water resources resulting from large springs and streamflow- loss zones. Examination of geochemical information provides a better understanding of the complex flow systems within these aquifers and interactions between the aquifers. Major-ion chemistry in both aquifers is dominated by calcium and bicarbonate near outcrop areas, with basinward evolution towards various other water types. The most notable differences in major-ion chemistry between the Madison and Minnelusa aquifers are in concentrations of sulfate within the Minnelusa aquifer. Sulfate concentrations increase dramatically near a transition zone where dissolution of anhydrite is actively occurring. Water chemistry for the Madison and Minnelusa aquifers is controlled by reactions among calcite, dolomite, and anhydrite. Saturation indices for gypsum, calcite, and dolomite for most samples in both the Madison and Minnelusa aquifers are indicative of the occurrence of dedolomitization. Because water in the Madison aquifer remains undersaturated with respect to gypsum, even at the highest sulfate concentrations, upward leakage into the overlying Minnelusa aquifer has potential to drive increased dissolution of anhydrite in the Minnelusa Formation. Isotopic information is used to evaluate ground-water flowpaths, ages, and mixing conditions for the Madison and Minnelusa aquifers. Distinctive patterns exist in the distribution of stable isotopes of oxygen and hydrogen in precipitation for the Black Hills area, with isotopically lighter precipitation generally occurring at higher elevations and latitudes. Distributions of 18O in ground water are consistent with spatial patterns in recharge areas, with isotopically lighter 18O values in the Madison aquifer resulting from generally higher elevation recharge sources, relative to the Minnelusa aquifer. Three conceptual models, which are simplifications of lumped-parameter models, are considered for evaluation of mixing conditions and general ground-water ages. For a simple slug-flow model, which assumes no mixing, measured tritium concentrations in ground water can be related through a first-order decay equation to estimated concentrations at the time of recharge. Two simplified mixing models that assume equal proportions of annual recharge over a range of years also are considered. An ?immediate-arrival? model is used to conceptually represent conditions in outcrop areas and a ?time-delay? model is used for locations removed from outcrops, where delay times for earliest arrival of ground water generally would be expected. Because of limitations associated with estimating tritium input and gross simplifying assumptions of equal annual recharge and thorough mixing conditions, the conceptual models are used only for general evaluation of mixing conditions and approximation of age ranges. Headwater springs, which are located in or near outcrop areas, have the highest tritium concentrations, which is consistent with the immediate-arrival mixing model. Tritium concentrations for many wells are very low, or nondetectable, indicating general applicability of the timedelay conceptual model for locations beyond outcrop areas, where artesian conditions generally occur. Concentrations for artesian springs generally are higher than for wells, which indicates generally shorter delay times resulting from preferential flowpaths that typically are associated with artesian springs. In the Rapid City area, a distinct division of isotopic values for the Madison aquifer corresponds with distinguishing 18O signatures for nearby streams, where large streamflow recharge occurs. Previous dye testing in this area documented rapid ground-water flow (timeframe of weeks) from a streamflow loss zone to sites located several miles away. These results are used to ill

Water-Resources Investigations Report↗