Geology ReportsSearch

SEARCH · Geology Reports

Results for “Minerals and the Environment”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 199 records · Page 11Linked to original sources

PHOTOLYSIS OF GOETHITE WITH SORBED LOW MOLECULAR WEIGHT CARBOXYLATES.

Goethite ( alpha -FeOOH) is a common mineral constituent of suspended and bed sediments in aquatic environments. Many types of naturally-occurring organic molecules, including organic carboxylates, are known to sorb to its surface. Carboxylates should be susceptable to photo-oxidation. An experimental program was conducted with systems containing adsorbed films of oxalate, citrate, tartrate, glycolate, formate, maleate, fumarate, butanoate, and benzoate on Goethite, respectively. Photolytic effects were observed at pH 6. 5 and 5. 5.

Conference Paper

Genesis of the Spar Lake strata-bound copper-silver deposit, Montana: Part I. Controls inherited from sedimentation and preore diagenesis

Mineable zones of the Spar Lake deposit occur where argentiferous copper sulfides and native silver formed cements and replaced certain earlier cements and clasts in the gently dipping middle quartzite beds of the upper member of the Revett Formation, middle Proterozoic Belt Supergroup. The copper sulfides and native silver are part of a large, zoned system of authigenic ore and gangue minerals at Spar Lake. Mineral zone boundaries of ore and gangue phases cross all five stratigraphic units of the upper member.Deduced depositional environments for the host sedimentary rocks include beach and near-shore slope environments for the lower quartzite beds and subtidal(?) channels for the middle quartzite beds. The deposit must be epigenetic because mineral zone boundaries cross every facies in the sequence of beach and nearshore slope sediments.Mineral zonation has been mapped, and seven major associations, each named for its most abundant sulfide and/or most characteristic gangue cement, are recognized. Zones that appear to be developed on a regional scale include, in spatial order, pyrite-calcite, chalcopyrite-ankerite, and the lavender (hematitic) zone. Minor concentrations of base and precious metals occur along boundaries between the hematite and chalcopyrite-ankerite zones, and between the chalcopyrite-ankerite and pyrite-calcite zones; however, at the major concentrations of metals in the Revett Formation, including the Spar Lake deposit, additional mineral zones are developed between the chalcopyrite-ankerite and pyrite-calcite regional zones. Mineral zones at the deposit are, from northwest to southeast: pyrite-calcite, galena-calcite, chalcopyrite-calcite, bornite-calcite, chalcocite-chlorite, and chalcopyrite-ankerite. Gangue minerals, including carbonates, Fe-Ti oxides, chlorite, barite, authigenic feldspars, and apatite, are zonally distributed with boundaries parallel to the sulfide-mineral zone boundaries. Bornite-calcite and chalcocite-chlorite zones form ore grades in certain, but not all, quartzite intervals.As observed at unmetamorphosed deposits where sulfide-mineral zonation is similar, some pyrite-calcite-zone minerals were probably replaced by galena-calcite-zone minerals, which were probably succeeded, in sequence, by minerals of the chalcopyrite-calcite, bornite-calcite, and chalcocite-chlorite zones. This inferred paragenesis suggests that the chalcocite-chlorite zone is more proximal to the source of ore solutions than the galena-calcite or pyrite-calcite zones. The subeconomic chalcopyrite-ankerite zone, found farthest to the southeast at the Spar Lake deposit, was apparently even more proximal to the source than ore. Ore deposition took place during diagenesis from solutions that migrated upward and laterally through the sediments from a southeasterly source.The distributions of mineral zones and ore grades were controlled by two factors, one inherited from sedimentation and the other from preore diagenesis. All mineral zones spread out within coarser grained portions of quartzite units, suggesting that lateral migration of ore solutions was controlled by primary permeability of the sediments. However, high grades of copper and silver are found only in certain of the coarser grained beds. The distributions of higher grades suggest that ore mineral abundances reflect the abundances of preore diagenetic phases which were involved in the ore precipitation reactions. Preore reactant phases were evidently more abundant in sandstones deposited in subtidal(?) channels (the ore-grade middle quartzite beds) than in sandstones deposited in beach and nearshore slope environments (the lower quartzite beds). The identity of the reactant phases and the processes that resulted in their concentration at the site of later ore deposition remain unknown, although a preore sulfide- and hydrocarbon-bearing pore fluid appears to be the best hypothesis as to the identity of the reactants.

Economic Geology

Physical-chemical conditions of ore deposition

Ore deposits form under a wide range of physical and chemical conditions, but those precipitating from hot, aqueous fluids—i.e. the hydrothermal deposits—form generally below 700°C and at pressures of only 1 or 2 kbar or less. Natural aqueous fluids in rocks may extract metal and sulfur from a variety of rock types or may acquire them as a residual heritage from a crystallizing silicate magma. Ore-forming hydrothermal fluids never appear as hot springs (except in deep, submarine situations) because they boil, mix with surface waters, and cool, thereby losing their ore-bearing ability before reaching the surface. Mineral systems function as chemical buffers and indicators just as buffers and indicators function in a chemical laboratory. By reading the record written in the buffer/indicator assemblages of minerals one can reconstruct many aspects of the former chemical environment. By studying the record of changing conditions one may deduce information regarding the processes functioning to create the succession of chemical environments and the ore deposits they represent. The example of the OH vein at Creede, Colorado, shows a pH buffered by the K-feldspar + muscovite + quartz assemblage and the covariation of S 2 and O 2 buffered by the assemblage chlorite + pyrite + quartz. Boiling of the ore fluid led to its oxidation to hematite-bearing assemblages and simultaneously produced an intensely altered, sericitic capping over the vein in response to the condensation of vapors bearing acidic components. The solubility of metals as calculated from experimental and theoretical studies of mineral solubility appears too low by at least one or two powers of ten to explain the mineralization at Creede. In contrast to Creede where the mineral stabilities all point to a relatively consistent chemistry, the Mississippi Valley type deposits present a puzzle of conflicting chemical clues that are impossible to reconcile with any single equilibrium situation. Thus we must seriously consider metastable equilibria; those most likely involve redox disequilibrium among the sulfur species in solution and perhaps also involve organic compounds.

Physics and Chemistry of the Earth

Mobilization of radionuclides from uranium mill tailings and related waste materials in anaerobic environments

Specific extraction studies in our laboratory have shown that iron and manganese oxide- and alkaline earth sulfate minerals are important hosts of radium in uranium mill tailings. Iron- and sulfate-reducing bacteria may enhance the release of radium (and its analog barium) from uranium mill tailings, oil field pipe scale [a major technologically enhanced naturally occurring radioactive material (TENORM) waste], and jarosite (a common mineral in sulfuric acid processed-tailings). These research findings are reviewed and discussed in the context of nuclear waste forms (such as barium sulfate matrices), radioactive waste management practices, and geochemical environments in the Earth's surficial and shallow subsurface regions.

Journal of Radioanalytical and Nuclear Chemistry

Manganese carbonate mineralization in the Molango district, Mexico

The Molango manganese deposit in Mexico is by far the largest known Mn deposit in North America. Mn carbonate mineralization is hosted by a finely laminated Upper Jurassic marine sedimentary sequence that forms the base of the Chipoco facies of the Taman Formation (Kimmeridgian). Manganese enrichment occurs over a total stratigraphic thickness of approximately 50 m, and a length of over 50 km along strike and serves as the protore for supergene Mn oxide ore. The carbonate ore zone comprises the basal 1 to 10 m of the Chipoco facies.The carbonate ore bed consists of fine-grained rhodochrosite and dispersed organic matter, magnetite, and maghemite but generally only trace quantities of pyrite. Fine laminations and clotted textures suggest deposition in a restricted marine environment. Manganese content is highest at the base of the mineralized interval, drops abruptly to subore grade, Mn-rich carbonates, and then gradually decreases upward to background levels (i.e., trace Mn in calcite). Chemical and mineralogical studies indicate that the predominant mineralogy changes upward from rhodochrosite in the ore zone, to mixed carbonates (Mn calcite, kutnohorite, + or - rhodochrosite), to Mn calcite.Several geologic and geochemical processes resulted in the formation of Mn carbonate by the early diagenetic reduction of Mn oxides through the oxidation of organic matter and iron sulfide. Mn oxides were concentrated at the margins of a dysaerobic to mildly anoxic stratified basin and became an important oxidizing agent of organic matter in the sediment pile. Effects of organic matter oxidation reactions included production of manganous ion (Mn (super +2) ), MnCO 3 precipitation, oxidation of iron monosulfide (precursor to pyrite), and formation of Fe oxide. The latter two processes explain the anomalously low pyrite and abundant magnetite content in the ore zone. The observed vertical variation of Mn carbonate mineralogy and the mineral compositions reflect variations in the concentrations of reduced manganese in the pore waters. Thus, Mn carbonate precipitated from pore water and did not form as a chemical sediment in the water column. The ultimate source of the manganese is uncertain but may have been fluvial-sediment loads or hydrothermal activity associated with the rifting of the Gulf of Mexico.

Economic Geology

The paleohydrology of unsaturated and saturated zones at Yucca Mountain, Nevada, and vicinity

Surface, unsaturated-zone, and saturated-zone hydrologic conditions at Yucca Mountain responded to past climate variations and are at least partly preserved by sediment, fossil, and mineral records. Characterizing past hydrologic conditions in surface and subsurface environments helps to constrain hydrologic responses expected under future climate conditions and improve predictions of repository performance. Furthermore, these records provide a better understanding of hydrologic processes that operate at time scales not readily measured by other means. Pleistocene climates in southern Nevada were predominantly wetter and colder than the current interglacial period. Cyclic episodes of aggradation and incision in Fortymile Wash, which drains the eastern slope of Yucca Mountain, are closely linked to Pleistocene climate cycles. Formation of pedogenic cement is favored under wetter Pleistocene climates, consistent with increased soil moisture and vegetation, higher chemical solubility, and greater evapotranspiration relative to Holocene soil conditions. The distribution and geochemistry of secondary minerals in subsurface fractures and cavities reflect unsaturated-zone hydrologic conditions and the response of the hydrogeologic system to changes in temperature and percolation flux over the last 12.8 m.y. Physical and fluid-inclusion evidence indicates that secondary calcite and opal formed in air-filled cavities from fluids percolating downward through connected fracture pathways in the unsaturated zone. Oxygen, strontium, and carbon isotope data from calcite are consistent with a descending meteoric water source but also indicate that water compositions and temperatures evolved through time. Geochronological data indicate that secondary mineral growth rates are less than 1–5 mm/m.y., and have remained approximately uniform over the last 10 m.y. or longer. These data are interpreted as evidence for hydrological stability despite large differences in surface moisture caused by climate shifts between the Miocene and Pleistocene and between Pleistocene glacial-interglacial cycles. Secondary mineral distribution and δ18O profiles indicate that evaporation in the shallower welded tuffs reduces infiltration fluxes. Several near-surface and subsurface processes likely are responsible for diverting or dampening infiltration and percolation, resulting in buffering of percolation fluxes to the deeper unsaturated zone. Cooler and wetter Pleistocene climates resulted in increased recharge in upland areas and higher water tables at Yucca Mountain and throughout the region. Discharge deposits in the Amargosa Desert were active during glacial periods, but only in areas where the modern water table is within 7–30 m of the surface. Published groundwater models simulate water-table rises beneath Yucca Mountain of as much as 150 m during glacial climates. However, most evidence from Fortymile Canyon up gradient from Yucca Mountain limits water-table rises to 30 m or less, which is consistent with evidence from discharge sites in the Amargosa Desert. The isotopic compositions of uranium in tuffs spanning the water table in two Yucca Mountain boreholes indicate that Pleistocene water-table rises likely were restricted to 25–50 m above modern positions and are in approximate agreement with water-table rises estimated from zeolitic-to-vitric transitions in the Yucca Mountain tuffs (less than 60 m in the last 11.6 m.y.).

Nevada

Metal dispersion resulting from mining activities in coastal environments: A pathways approach

Acid rock drainage (ARD) and disposal of tailings that result from mining activities impact coastal areas in many countries. The dispersion of metals from mine sites that are both proximal and distal to the shoreline can be examined using a pathways approach in which physical and chemical processes guide metal transport in the continuum from sources (sulfide minerals) to bioreceptors (marine biota). Large amounts of metals can be physically transported to the coastal environment by intentional or accidental release of sulfide-bearing mine tailings. Oxidation of sulfide minerals results in elevated dissolved metal concentrations in surface waters on land (producing ARD) and in pore waters of submarine tailings. Changes in pH, adsorption by insoluble secondary minerals (e.g., Fe oxyhydroxides), and precipitation of soluble salts (e.g., sulfates) affect dissolved metal fluxes. Evidence for bioaccumulation includes anomalous metal concentrations in bivalves and reef corals, and overlapping Pb isotope ratios for sulfides, shellfish, and seaweed in contaminated environments. Although bioavailability and potential toxicity are, to a large extent, functions of metal speciation, specific uptake pathways, such as adsorption from solution and ingestion of particles, also play important roles. Recent emphasis on broader ecological impacts has led to complementary methodologies involving laboratory toxicity tests and field studies of species richness and diversity.

Oceanography

Sequential extraction techniques applied to a porphyry copper deposit in the basin and range province

Samples of minus-80-mesh (<180 μm) stream sediment, rock containing exposed fracture coatings, and jarosite and chrysocolla were collected from an area surrounding the North Silver Bell porphyry Cu deposit near Tucson, Arizona. The samples were subjected to a series of extractions in a scheme originally designed for use on samples from humid or sub-humid environments, in which the following fractions can effectively be separated: (1) carbonates and exchangeable metals; (2) Mn oxides; (3) organic compounds and sulfides; (4) hydrous Fe oxides; and (5) residual crystalline minerals. Jarosite and chrysocolla, two major minerals of the North Silver Bell area, were found to dissolve over two or more steps of the extraction scheme. The results represent only a limited number of samples from one copper deposit. Nevertheless, they do suggest that in a semiarid to arid environment, where mechanical dispersion of such minerals predominates, uncritical assignment of unique phases, such as Mn oxides or organics to a given extraction would lead to false interpretations of weathering processes. However, the relative proportions of elements dissolved in each step of the jarosite and chrysocolla extractions could be used as a “fingerprint” for recognition of the presence of these two minerals in the stream-sediment and rock samples. The relative abundance of hydrous Fe oxide and jarosite and the alteration zoning could be mapped using data from jarosite and chrysocolla extractions. Manganese oxides were also found to have a greater influence on Zn than on Cu or Pb during supergene alteration. The rapid change in relative importance of the first (1 M -acetic acid) extraction for Cu, Zn, and Pb near the mineralized zone suggested the occurrence of minor hydromorphic processes within the stream sediments. Thus, the acetic acid extraction proved the most effective for pinpointing mineralization in sediments. In contrast, the residual fraction had the longest dispersion train, suggesting that total metal concentrations are most effective in arid environments for reconnaissance surveys.

Journal of Geochemical Exploration

Geology and geochemistry of Summitville, Colorado: An epithermal acid sulfate deposit in a volcanic dome

Geologic studies during recent open-pit mining at Summitville, Colorado, have provided new information on an epithermal acid sulfate Au-Ag-Cu deposit formed in a volcanic dome. Geologic mapping, geochemical studies of whole-rock samples from blast holes, and geologic and geochemical traverse studies refine the details of the evolution of the Summitville deposit. Six distinct events followed emplacement of the quartz latite volcanic dome and define the development of the Summitville deposit: (1) an early stage of acid sulfate alteration, (2) subsequent Cu sulfide and gold mineralization, (3) widespread hydrothermal brecciation, (4) volumetrically minor, base metal sulfide-bearing barite veining, (5) volumetrically minor, kaolinite matrix brecciation, and finally, (6) supergene oxidation. Events 1 and 2 were the most important for the formation of the Summitville deposit. Acid sulfate altered rock is primarily found in the quartz latite volcanic dome rock and consists of vuggy silica (central), quartz-alunite, quartz-kaolinite, argillic, and propylitic (distal) zones. Ore deposition (event 2) of enargite, luzonite, covellite, pyrite, native sulfur, marcasite, and minor sphalerite, native gold, + or - barite and galena overprinted the acid sulfate altered rocks. Events 3, 4, and 5 are geologically important but rarely formed units large enough to be considered mineable ore by open-pit mining. The final supergene oxidation event affected much of the near-surface portion of the deposit and leached copper and sulfide minerals forming oxide zones. Near-surface oxide zones contain the highest Au grades and decrease progressively with depth.Fractures were important fbr localizing both the acid sulfate altered rock and ore deposition at Summitville. Such fracture control is apparent despite a lack of distinct throughgoing open-space quartz veins; instead, laterally and vertically extensive ore zones are identified by their highly silicified character that can be traced laterally for up to 500 m and vertically up to 200 m. Ore zones strike parallel to regional faults related to rifting and basin and range development, suggesting that hydrothermal fluids followed preexisting fractures. Ore zones follow two northwest trends, a N 30 degrees W + or - 20 degrees trend, and a N 60 degrees W trend. Most fractures and faults in the open pit dip steeply from 65 degrees to vertical. Ore zones intersect near the center of the deposit to form a large zone approximately 150 by 400 m. Ore zones form a rough radial pattern located near the center of the deposit and a discontinuous arcuate feature on the northern side. This radial pattern, arcuate feature, and the intersection of ore zones near the center of the deposit are probably related to the intrusion of a porphyry below the deposit. The overall low Au-grade, high-tonnage character of the Summitville deposit is related to low permeability in the quartz latite volcanic dome rock and absence of well-developed open-space hydrothermal veins.Gold analyses of development drill holes and blast hole samples, in conjunction with geologic mapping in the open pit, indicate that vuggy silica, quartz-alunite, and quartz-kaolinite altered rock constitute most of the Au ore. Vuggy silica averaged 2.4 ppm Au, quartz-alunite averaged 1.2 ppm Au, and quartz-kaolinite averaged 0.86 ppm Au during open-pit mining. Grades for argillically altered rock were usually below the ore cutoff of 0.34 ppm Au. Propylitically altered rock rarely contained detectable Au concentrations (0.03 ppm Au) and constituted only waste rock. Although volumetrically minor, event 4 base metal sulfide-bearing barite veins and event 5 kaolinite matrix breccias contained high Au grades (up to about 800 ppm Au), producing approximately 5 to 15 percent of the total Au mined in the deposit.Geochemical studies of samples collected across traverses of altered and mineralized ore zones indicate that Te, Bi, and Pb are characteristic trace elements, in addition to Au, Ag, Cu, and As that are typical of acid sulfate mineral deposits. Anomalous Te is associated with Cu sulfides and gold in vuggy silica zones. Anomalous Bi and Pb concentrations correlate most consistently with quartz-alunite zones. Thallium is also anomalous at Summitville. Highest concentrations of Tl are found in argillic rock, whereas silicified zones are depleted in it. The anomalous Tl in distal zones is similar to observations in some porphyry Cu systems. Pronounced lateral zonation of Ag/Au ratios is present in the deposit. The Ag/Au ratios vary from about 2:1 near the center of the orebody to greater than 20:1 on the periphery.The Summitville deposit is located in the midlevel portion of a mineralized volcanic dome, with a porphyry system at depth, and a hot springs environment at the surface. Drill holes through the volcanic dome intersected a quartz monzonite porphyry approximately 600 m below the surface that is altered to sericite and pyrite similar to some porphyry deposits. Laterally extensive cristobalite and opal replacing quartz latite are found southwest of the deposit and represent a hot-spring environment. Bedded siliceous sinter, some of which contains plant debris, overlies the cristobalite and opal at some localities. These deposits may represent surface vents for the fluids responsible for acid sulfate alteration or mineralization of the volcanic dome.

Economic Geology

Preliminary report on the geology and gold mineralization of the Gold Basin-Lost Basin mining districts, Mohave County, Arizona

The Gold Basin-Lost Basin mining districts are adjacent to each other in northwestern Arizona, south of Lake Mead, and just west of the Grand Wash Cliffs. Most recorded production from lode deposits is credited to mines in the Gold Basin district, which is in the southern White Hills, whereas the bulk of the placer production has been from placers worked along the eastern flank of the Lost Basin range, about 16 km to the northeast across Hualapai Valley. Gold in quartz veins apparently was first discovered in the 1870's. Recorded production from the districts between 1901 and 1942 includes 13,508 oz gold and 6,857 oz silver, and this recorded production has a dollar value of about $359,000 of which 98 percent is credited to gold. Most known occurrences of lode gold in the districts are associated with widespread quartz-cored pegmatite-vein systems, presumably emplaced episodically during Proterozoic X, Proterozoic Y, and Late Cretaceous time into Proterozoic X metamorphic and igneous rocks. The bulk of the veins apparently were emplaced during the Late Cretaceous, and they were localized along both high- and low-angle structures in the Proterozoic X terrane. These veins appear to be associated genetically with presumably Late Cretaceous, two-mica magmatism. A Late Cretaceous two-mica monzogranite crops out in an approximately 4 to 5 km 2 area in the southern part of the Gold Basin district and includes some facies of episyenite. Some gold is found also in small episyenitic alteration pipes, or in veins caught up tectonically along a regionally extensive, low-angle detachment surface which crops out prominently in the southern White Hills, and has been traced for at least 30 km along the western flank of the White Hills. Hydrothermal micas from selected veins in the districts give K-Ar ages of 822, 712, 69, 68, and 65 m.y. (million years), and from the pipes, ages of 130 and 127 m.y. The oldest ages (822 and 712 m.y.) presumably reflect resetting of veins that probably were emplaced penecontemporaneous with emplacement of the 1,400-m.y. granite of Gold Butte, which crops out just to the north of Lake Mead. The latter ages (130 and 127 m.y.) must reflect either the presence of excess radiogenic argon in the hydrothermal environment of the evolving pipes, or contamination of the dated mineral separates by Proterozoic mica and (or) feldspar. Primary white mica from the two-mica monzogranite gives a K-Ar age of 72 m.y.. Most occurrences of gold in the veins and pipes probably reflect either remobilization of gold from gold-bearing, near-surface Proterozoic source areas, or anatectic incorporation of gold into Late Cretaceous, two-mica magmas from very deep gold-bearing Proterozoic sources. Deposition of gold occurred in a mesothermal environment during the galena-, chalcopyrite-, ferroan-carbonate-bearing stages of the veins. Homogenization studies of fluid inclusions prominent in the veins and pipes yield temperatures mostly in the range 150 to 280°C. Early-stage, trapping temperatures at the pipes probably were about 330°C and pressures in the range 500 to 700 bars can be inferred. Fluids were moderately saline, mostly 4 to 16 weight percent NaC1 equivalent, nonboiling, and also contain appreciable amounts of carbon dioxide and, in places, fluorine. Such fluids associated with the deposition of gold in these districts largely bridge the fluid composition interval between many other epithermal precious-metal and porphyry coper deposits. Approximately 350 compositional analyses obtained from native-gold samples from 20 mines in the Gold Basin district and 48 veins in the Lost Basin district show silver contents that range from 6 to approximately 50 weight percent, and copper from 0.01 to 0.5 weight percent. Metal zonation and possible relation to a porphyry copper system at depth can be inferred from some of these chemical data. The differences in the composition of placer gold from 24 occurrences in the Lost Basin district from that of nearby lode sources suggest that other sources contributed gold to the placers or that locally derived grains were enriched by oxidation and weathering of the lodes.

Arizona

Challenge theme 5: Current and future needs of energy and mineral resources in the Borderlands and the effects of their development: Chapter 7 in United States-Mexican Borderlands: Facing tomorrow's challenges through USGS science

Exploration and extraction activities related to energy and mineral resources in the Borderlands—such as coal-fired power plants, offshore drilling, and mining—can create issues that have potentially major economic and environmental implications. Resource assessments and development projects, environmental studies, and other related evaluations help to understand some of these issues, such as power plant emissions and the erosion/denudation of abandoned mine lands. Information from predictive modeling, monitoring, and environmental assessments are necessary to understand the full effects of energy and mineral exploration, development, and utilization. The exploitation of these resources can negatively affect human health and the environment, its natural resources, and its ecological services (air, water, soil, recreation, wildlife, etc.). This chapter describes the major energy and mineral issues of the Borderlands and how geologic frameworks, integrated interdisciplinary (geobiologic) investigations, and other related studies can address the anticipated increases in demands on natural resources in the region.

United States-Mexico Borderlands

Geochemical sampling in arid environments by the U.S. Geological Survey

The U.S. Geological Survey (USGS) is responsible for the geochemical evaluations used for mineral resource assessments of large tracts of public lands in the Western United States. Many of these lands are administered by the Bureau of Land Management (BLM) and are studied to determine their suitability or nonsuitability for wilderness designation. Much of the Western United States is arid or semiarid. This report discusses various geochemical sample media that have been used for evaluating areas in arid environments and describes case histories in BLM wilderness study areas in which stream-sediment and heavy-mineral-concentrate sample media were compared. As a result of these case history studies, the nonmagnetic fraction of panned heavy-mineral concentrates was selected as the most effective medium for reconnaissance geochemical sampling for resources other than gold, in arid areas. Nonmagnetic heavy-mineral-concentrate samples provide the primary analytical information currently used in geochemical interpretations of mineral resource potential assessment of BLM lands.

Circular

Controls on pore types and pore-size distribution in the Upper Triassic Yanchang Formation, Ordos Basin, China: Implications for pore-evolution models of lacustrine mudrocks

Our main objectives are to (1) learn if pore-evolution models developed from marine mudrocks can be directly applied to lacustrine mudrocks, (2) investigate what controls the different pore types and sizes of Chang 7 organic matter (OM)-rich argillaceous mudstones of the Upper Triassic Yanchang Formation, and (3) describe the texture, fabric, mineralogy, and thermal maturity variation in the Chang 7 mudstones. Lacustrine mudstones from nine cored wells along a depositional dip in the southeastern Ordos Basin, China, were investigated. Helium porosimetry, nitrogen adsorption, and field-emission scanning electron microscopy of Ar-ion milled samples were applied. Measured average total porosity of samples from a proximal to distal transect ( &#x3D5; = 5.0 % "> ϕ = 5.0 % ) is higher than those from the two adjacent cored wells ( &#x3D5; = 2.3 % "> ϕ = 2.3 % ). This difference in porosity partly caused by differences in the clay mineral content implies that in the fluvial-deltaic-lacustrine depositional environment, reservoir quality can vary significantly in a short distance. Owing to the uneven distribution of the sample set from proximal to distal area, we mainly evaluate variations in the proximal setting. Results from nitrogen-gas adsorption experiments show that there are four distinct patterns of pore-size distribution within the Chang 7 member of the Yanchang Formation with no particular correlation with mineralogical composition and thermal maturity. The pore network within Chang 7 mudstones is dominated by OM-hosted pores, with a lesser abundance of interparticle and intraparticle pores. The size distribution of mineral-hosted pores within these mudstones is found to be closely related to the rock texture (sorting and grain size) and fabric. Mudstones with well-sorted grains and a higher percentage of coarser grains have more abundant mineral pores. The sizes of OM-hosted pores in these compaction-dominated lacustrine mudstones were one to two orders of magnitude smaller than those in the marine mudstones that display abundant early cementation.

Ordos basin

Isolating detrital and diagenetic signals in magnetic susceptibility records from methane-bearing marine sediments

Volume-dependent magnetic susceptibility (κ) is commonly used for paleoenvironmental reconstructions in both terrestrial and marine sedimentary environments where it reflects a mixed signal between primary deposition and secondary diagenesis. In the marine environment, κ is strongly influenced by the abundance of ferrimagnetic minerals regulated by sediment transport processes. Post-depositional alteration by H 2 S, however, can dissolve titanomagnetite, releasing reactive Fe that promotes pyritization and subsequently decreases κ. Here, we provide a new approach for isolating the detrital signal in κ and identifying intervals of diagenetic alteration of κ driven by organoclastic sulfate reduction (OSR) and the anaerobic oxidation of methane (AOM) in methane-bearing marine sediments offshore India. Using the correlation of a heavy mineral proxy from X-ray fluorescence data (Zr/Rb) and κ in unaltered sediments, we predict the primary detrital κ signal and identify intervals of decreased κ, which correspond to increased total sulfur content. Our approach is a rapid, high-resolution method that can identify overprinted κ resulting from pyritization of titanomagnetite due to H 2 S production in marine sediments. In addition, total organic carbon, total sulfur, and authigenic carbonate δ 13 C measurements indicate that both OSR and AOM can drive the observed κ loss, but AOM drives the greatest decreases in κ. Overall, our approach can enhance paleoenvironmental reconstructions and provide insight into paleo-positions of the sulfate-methane transition zone, past enhancements of OSR or paleo-methane seepage, and the role of detrital iron oxide minerals on the marine sediment sulfur sink, with consequences influencing the development of chemosynthetic biological communities at methane seeps.

Geochemistry, Geophysics, Geosystems

Initial report of the Petrophysics Laboratory

Current national requirements for energy and mineral resources, and for protection of the quality of the environment, have focused attention on the need to develop new methods and interpretation techniques to be used in understanding geologic systems. Geophysical surveys play a significant role in acquiring this information, particularly by providing data in the third dimension--at depth beneath the surface.

Circular

Geology of areas marked by geophysical anomalies (B-35 and B-34), Wadi Bidah District, Kingdom of Saudi Arabia

Geophysical surveys in the Wadi Bidah district, in the southwestern part of the Kingdom of Saudi Arabia, have revealed anomalies of the type that may be caused by deposits of massive sulfides. Accordingly, a study was undertaken to investigate the geologic environment associated with the geophysical anomalies and to determine whether mineral exploration of the anomalous areas might be warranted. An extensive geochemical sampling program did not disclose any evidence of ore mineral concentrations in the rocks. Detailed geologic mapping shows the anomalous areas to be underlain by Precambrian carbonaceous graywacke, the outcrop patterns of which closely fit the anomaly patterns. Field evidence and petrologic studies indicate that carbonaceous material in the rocks is the cause of the geophysical anomalies. Nothing was found in the anomalous areas that suggests the presence of mineral deposits of commercial grade, and further mineral investigations or exploration in the areas is not recommended.

Open-File Report

Secular variation in economic geology

The temporal pattern of ore deposits on a constantly evolving Earth reflects the complex interplay between the evolving global tectonic regime, episodic mantle plume events, overall changes in global heat flow, atmospheric and oceanic redox states, and even singular impact and glaciation events. Within this framework, a particular ore deposit type will tend to have a time-bound nature. In other words, there are times in Earth history when particular deposit types are absent, times when these deposits are present but scarce, times when they are abundant, and still other times for which we lack sufficient data. Understanding of such secular variation provides a critical first-order tool for exploration targeting, because rocks that have formed or were deformed during a certain time slice may be very permissive for a given deposit type, whereas identification of rocks of less favorable ages would help eliminate large areas during exploration programs. Secular analysis, therefore, is potentially a powerful tool for mineral resource assessment in poorly known terranes, providing a quick filter for favorability of a given deposit type using age of host rocks. Factors bearing on the known age distribution of a particular type of deposit include the following: (1) uneven preservation, (2) data gaps, (3) contingencies of plate motions, and (4) long-term secular changes in the Earth System. The present special issue of Economic Geology is focused on the latter factor, although all of these are interrelated. The selective preservation of certain mineral deposit types and the greater susceptibility for shallowly formed ores in tectonically active environments to be lost to erosion define a pattern that is superimposed on the secular formational trends (e.g., Groves et al., 2005a , b ; Kerrich et al., 2005 ). With improved geochronological methods and the availability of information on important mineral deposits from most parts of the world, data gaps for defining broad temporal distributions of ore types are becoming smaller. It has been increasingly recognized that ore deposit formation is also correlated with plate tectonic setting. Nevertheless, a complex Earth history of supercontinent assembly and breakup has led to the fragmentation of many Paleozoic and Precambrian mineral provinces. The use of plate reconstructions in economic geology, although extremely controversial and conjectural before the late Paleozoic, is critical for defining these provinces prior to the added complications resulting from post-ore plate motions. It is now well established that the temporal patterns of many types of mineral deposits (Fig. 1 1 ) reflect the formation or break-up of supercontinents and the preservation potential of deposits formed during these periods ( Barley and Groves, 1992 ; Titley, 1993 ; Kerrich et al., 2005 ; Goldfarb et al., 2009 ). Approximate time periods for such formation and break-up, respectively, include 2800–2500 and 2450–2100 Ma for Kenorland, 2100–1800 and 1600–1300 Ma for Nuna/Columbia, 1300–1100 and 850–600 Ma for Rodinia, and 600–300 Ma and 200–60 Ma for Gondwanaland-Pangea. A new supercontinent, Amasia, has begun to form during the past 250 m.y., thus overlapping Pangea break-up. Many of the formation-preservation patterns are themselves controlled by progressive cooling of Earth, the change from a mantle-plume buoyancy style to subduction-dominated tectonics, a decreasing buoyancy of the subcontinental lithospheric mantle, and depth of ore formation. In general, orogenic Au, volcanogenic massive sulfide (VMS), epithermal Au-Ag, and porphyry Cu±Au and Mo porphyry deposits form in active margins during periods of supercontinent assembly. Numerous other ore deposit types show an association with supercontinent formation, but develop inland of the active margin. These include many of the MVT Pb-Zn deposits and unconformity-type U deposits. The Tertiary Carlin-type deposits within the deformed shelf sequences along the North American craton margin also appear to have formed during the ongoing growth of Amasia. Those ores associated with periods of supercontinent breakup or attempted breakup are more difficult to define. They probably include diamond, Bushveld-type Ni-Cu-PGE, IOCG, and clastic-dominated Pb-Zn (or SEDEX) deposits in intracontinental areas of failed rifting, and other clastic-dominated Pb-Zn deposits in areas of actual breakup. In all cases, however, these temporal/spatial distributions are ultimately controlled by the secular character of Earth history.

Economic Geology

Interpretation of the regional geochemistry of the Tonopah 1 degree by 2 degrees Quadrangle, Nevada, based on analytical results from stream-sediment and nonmagnetic heavy-mineral-concentrate samples

Results of more than 2,400 analyses of <0.25-mm fraction of stream sediments and nonmagnetic heavy-mineral concentrates from stream sediments from 1,217 sites in the Tonopah quadrangle demonstrate the existence of anomalous concentrations of many metals of economic interest in many areas. Single-element anomalies of As, Pb, or Sb in stream sediment provide general guides to possible mineralization, but multi-element suites are more reliable to characterize types of mineralization. Various combinations of Ag, As, Bi, Cu, Mo, Pb, Sb, and W in stream sediments and concentrates provide guides to five general types of deposits and their geologic environments. Multi-element suites that recur in stream-sediment media resemble those observed in mineralized rock samples, and the distribution of the suites corresponds to the distribution of known types of deposits and to the general geology of the region. Multi-element geochemical anomalies are prominent in the Pilot Mountains, Monte Cristo Range, Paradise Range, Lone Mountain, northeastern Toiyabe Range, Cedar Mountains, and Toquima Range. Strongest multi-element anomalies are associated with plutonic rocks in the western part of the quadrangle. Two base-metal suites are enriched in and around plutons: (1) Bi + W + Pb + Mo ± As, Cu, Sb, a suite that resembles metals enriched in rocks samples from skarn deposits; and (2) Pb + Mo ± As,Cu,Sb, which resembles base-metal enrichments in sulfide vein and replacement deposits, generally associated with intrusions. A third variety of base-metal enrichment that contains Ag is distinguished for its possible economic importance. This Ag-Pb-rich suite occurs both near plutons and in volcanic terrane and generally is near areas of known Ag-rich polymetallic deposits. Many sites are characterized by modest enrichments of two to five elements in the suite As-Mo-Sb-Zn-Ag that resemble enrichments in epithermal ore deposits. Many anomalies of this type are from drainages underlain by Tertiary welded tuff, commonly lacking alteration and mineral prospects. Some of these anomalous sites correlate with areas of known epithermal deposits or siliceous alteration of calcareous rocks, thus this suite may be a guide to precious-metal deposits if there is supporting geologic evidence. The results from regional sampling of stream sediments, utilizing the <0.25-mm fraction and nonmagnetic heavy-mineral-concentrate media, effectively outline most areas of known deposits or alteration in the Tonopah quadrangle. Some clusters of anomalies are larger than the area of known mineral prospects, suggesting that other deposits remain to be discovered. This regional geochemical information is most effective for exploration and resource analysis when integrated with other geologic information, especially rock alteration.

Nevada