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323 records · Page 11Linked to original sources

Manipulation of the Symbiodiniaceae microbiome confers multigenerational impacts on symbioses and reproductive ecology of its Exaiptasia diaphana host

Symbiodiniaceae-associated microbiota strongly influence cnidarian symbioses. We systematically reduced the bacterial and fungal communities associated with Symbiodiniaceae to study potential effects on the cnidarian holobiont Exaiptasia diaphana (Aiptasia). Clonal anemones were inoculated with xenic Breviolum minutum (SSB01) and microbiome-manipulated cultures after antibacterial or antifungal treatment. The asexual reproduction of pedal laceration allowed for three generations of clonal aposymbiotic Aiptasia to be utilised in this study, from the initial adult generation (G0), to the first (G1), and second (G2) generation. We inoculated small and large G1 Aiptasia with SSB01 algae and monitored onset of symbiosis, rate of algal proliferation, and holobiont characteristics. Sequencing the 16S and 18S rRNA gene regions identified significant differences in the bacterial and fungal communities of the G0 and G1 generations, alongside differences between the size classes of small and large G1 anemones. The microbiome of larger G1 individuals was distinct to the smaller G1 anemones, suggesting a microbiome maturation process. Control Breviolum minutum cultures exhibited a significantly greater proliferation rate in large G1 anemones when compared to antibacterial or antifungal treated cultures, whereas the opposite trend was documented in the small G1 anemones. Although no differences were observed between algal photochemical parameters, or the growth and polyp activity of G1 juveniles, we observed a significant influence in the production of G2 clones between treatments. Overall, we provide strong ecological implications of manipulating Symbiodiniaceae microbiome, not for the algae themselves, but for the maturation of the host Aiptasia, as well as for the cnidarian holobiont over multiple generations.

The ISME Journal

Extremophile hotspots linked to containerized industrial waste dumping in a deep-sea basin

Decaying barrels on the seafloor linked to DDT contamination have raised concerns about the public health implications of decades old industrial waste dumped off the coast of Los Angeles. To explore their contents, we collected sediment cores perpendicular to five deep-sea barrels. The concentration of DDT and its breakdown products were highly elevated relative to control sites yet did not vary with distance from the barrels, suggesting that they were not associated with the contamination. Sediment cores collected through white halos surrounding three barrels were enriched in calcite and had elevated pH. The associated microbial communities were low diversity and dominated by alkalophilic bacteria with metagenome-assembled genomes adapted to high pH. A solid concretion sampled between a white halo and barrel was composed of brucite, a magnesium hydroxide mineral that forms at high pH. Based on these findings, we postulate that leakage of containerized alkaline waste triggered the formation of mineral concretions that are slowly dissolving and raising the pH of the surrounding sediment pore water. This selects for taxa adapted to extreme alkalinity and drives the precipitation of “anthropogenic” carbonates forming white halos, which serve as a visual identifier of barrels that contained alkaline waste. Remarkably, containerized alkaline waste discarded >50 years ago represents a persistent pollutant creating localized mineral formations and microbial communities that resemble those observed at some hydrothermal systems. These formations were observed at one-third of the visually identified barrels in the San Pedro Basin and have unforeseen, long-term consequences for benthic communities in the region.

California

Light absorbing particles deposited to snow cover across the Upper Colorado River Basin, Colorado Rocky Mountains, 2013-16: Interannual variations from multiple natural and anthropogenic sources

Atmospheric particulate matter (PM) as light-absorbing particles (LAPs) deposited to snow cover can result in early onset and rapid snow melting, challenging management of downstream water resources. We identified LAPs in 38 snow samples (water years 2013–2016) from the mountainous Upper Colorado River basin by comparing among laboratory-measured spectral reflectance, chemical, physical, and magnetic properties. Dust sample reflectance, averaged over the wavelength range of 0.35–2.50 μm, varied by a factor of 1.9 (range, 0.2300–0.4444) and was suppressed mainly by three components: (a) carbonaceous matter measured as total organic carbon (1.6–22.5 wt. %) including inferred black carbon, natural organic matter, and carbon-based synthetic, black road-tire-wear particles, (b) dark rock and mineral particles, indicated by amounts of magnetite (0.11–0.37 wt. %) as their proxy, and (c) ferric oxide minerals identified by reflectance spectroscopy and magnetic properties. Fundamental compositional differences were associated with different iron oxide groups defined by dominant hematite, goethite, or magnetite. These differences in iron oxide mineralogy are attributed to temporally varying source-area contributions implying strong interannual changes in regional source behavior, dust-storm frequency, and (or) transport tracks. Observations of dust-storm activity in the western U.S. and particle-size averages for all samples (median, 25 μm) indicated that regional dust from deserts dominated mineral-dust masses. Fugitive contaminants, nevertheless, contributed important amounts of LAPs from many types of anthropogenic sources.

Colorado

Triggering the 2022 eruption of Mauna Loa

Distinguishing periods of intermittent unrest from the run-up to eruption is a major challenge at volcanoes around the globe. Comparing multidisciplinary monitoring data with mineral chemistry that records the physical and spatio-temporal evolution of magmas fundamentally advances our ability to forecast eruptions. The recent eruption of Mauna Loa, Earth’s largest active volcano, provides a unique opportunity to differentiate unrest from run-up and improve forecasting of future eruptions. After decades of intermittent seismic and geodetic activity over 38 years of repose, Mauna Loa began erupting on 27 November 2022. Here we present a multidisciplinary synthesis that tracks the spatio-temporal evolution of precursory activity by integrating mineral and melt chemistry, fluid inclusion barometry, numerical modeling of mineral zoning, syn-eruptive gas plume measurements, the distribution and frequency of earthquake hypocenters, seismic velocity changes, and ground deformation. These diverse data indicate that the eruption occurred following a 2-month period of sustained magma intrusion from depths of 3–5 km up to 1–2 km beneath the summit caldera, providing a new model of the plumbing system at this very high threat volcano. Careful correlation of both the geochemistry and instrumental monitoring data improves our ability to distinguish unrest from the run-up to eruption by providing deeper understanding of the both the monitoring data and the magmatic system—an approach that could be applied at other volcanic systems worldwide.

Hawaii

USGS—An Unparalleled Scientific Asset

The U.S. Geological Survey (USGS) delivers information critical to powering our economy, managing our natural resources, and keeping Americans safe and healthy. 1 Mapping the Nation $21B Geologic maps save users an estimated 15% in annual costs: a value of between $14B and $21B. $25.6B in annual value to users of imagery from Landsat satellites, which were codeveloped by NASA and the USGS and operated through their lifespans by the USGS. $13.5B in annual benefits is generated by the USGS's 3D Elevation Program. Securing America’s Energy Independence 44% USGS-identified undiscovered geothermal energy is equal to 44% of current U.S. electricity generation. 29.4B barrels of oil and 391.6 trillion cubic feet of gas in recoverable resources are available on U.S. public lands based on USGS assessments. Protecting Americans’ Health and Safety $424B in recent wildland fire damages highlight the need for USGS fire science, which supports efforts to protect communities and reduce risk. USGS earthquake, volcano, landslide, and coastal hazard monitoring and information save lives and minimize costs; for example, $2.8M can be saved because of USGS enhanced information about a Mauna Loa eruption. $4.5B is the estimated cost of annual flooding. Through a network of over 11,885 streamgages, the USGS supports public safety and enables forecasts, early warning systems, and management actions that protect lives and property. Supporting National Security $3.1B The USGS identified a $3.1B risk to the American economy if China restricts gallium imports. This is one example underscoring the importance of the USGS mapping critical minerals, investigating supply chains, and producing the Nation’s critical minerals list. Enhancing Our Lands and Waters $21B in estimated annual costs results from invasive species. The USGS’s invasive species research informs approaches used to reduce their effects on agriculture, water infrastructure, disease transmission, fisheries, and outdoor recreation. USGS innovations support early warnings for harmful algal blooms—over $2M in yearly benefits are provided to Kansas alone. $45B USGS science informs the management of big game (such as deer and elk). The big-game hunting industry contributes $45B to the U.S. economy. Fostering American Prosperity $4.1T Mineral commodities are necessary for the $4.1T in value added to the GDP by major industries that consume processed mineral materials and employ 1 million workers. Because of this, USGS data on mineral supply, demand, and trade are highly valued. 45,000 metric tons Rare earths power the growing technology economy, including cell phones, electric vehicles, and medical devices. For over 70 years, USGS work has supported the discovery of rare earth resources in California’s Mountain Pass area, which produced 45,000 metric tons of rare earth concentrates in 2024—over 11% of the global supply. Guarding American Food Security $70.2B USGS science informs early warning systems and management strategies to mitigate disease outbreaks in agriculture—critical research on highly pathogenic avian influenza, for example, helps safeguard the $70B value in poultry and egg production. $11.8B USGS groundwater tools are vital for agriculture; for example, in the Mississippi Alluvial Plain, 65% of farming relies on groundwater to support its $11.8B annual industry. 1 Values throughout are given in billions (B), millions (M), and trillions (T) of U.S. dollars. GDP is “Gross Domestic Product.” Percentages are shown as %.

General Information Product

Concentration-discharge relations and transient metal loads reveal spatiotemporal variability in solute-generation mechanisms in a mine-affected watershed

Concentration-discharge (CQ) relations are commonly used to understand geochemical and hydrologic controls on the generation of solutes in watersheds. Despite the widespread application of CQ relations, this technique has been infrequently applied to acid mine drainage (AMD) sites, but the CQ framework may allow mechanistic understanding of remedial outcomes such as impoundment of water within underground mines. Results of CQ analyses and changes in metal loads in an AMD affected watershed in Colorado, USA indicate that dissolved loads increased at many individual locations following water impoundment within mine workings. Although increased loads were observed at most individual locations, these increases were offset by a large decrease in loading from the largest mine. A loading analysis that included data from an instream monitoring location showed a statistically significant decrease in Fe and Zn after bulkhead emplacement, indicating a net positive effect of bulkheads. Streams generally displayed dilution CQ patterns whereas mines and springs showed either flushing or chemostatic patterns prior to bulkheading, which transitioned to chemostatic patterns following bulkheading, indicating a transition from dynamic to equilibrium geochemical processes. Saturation indices for sulfide and secondary minerals indicated that mines and springs were near equilibrium for phases including schwertmannite, fluorite, and gypsum. Saturation indices vary through time for mines suggesting progressive leaching of sulfide minerals as the mass of available minerals in the mine workings decreases. Together, these diverse analyses provide an integrated understanding of the variability in solute generating processes in this watershed and may inform remediation plans for similarly affected sites by indicating the nature of mineralogic controls on water quality.

Colorado

Remote sensing-based actual evapotranspiration assessment in a data-scarce area of Brazil: A case study of the Urucuia Aquifer System

The large groundwater reserves of the Urucuia Aquifer System (UAS) enabled agricultural development and economic growth in the western Bahia State, in northeastern Brazil. Over the last several years, concern has grown around the aquifer’s diminishing water levels, and water balance (WB) studies are in demand. Considering the lack of measured actual evapotranspiration (ET a ), a major component of the water cycle, this work uses the Operational Simplified Surface Energy Balance (SSEBop) model to estimate ET a , and compares it to basin-scale estimates from the Soil Moisture Accounting Procedure (SMAP) monthly model and from an annual WB closure method, based on gridded meteorological data and the Gravity Recovery and Climate Experiment (GRACE) product. Additionally, a comparative assessment of different versions of the SSEBop parameterization was performed. Moderate Resolution Imaging Spectroradiometer (MODIS) imagery was used to implement eight different versions of the SSEBop algorithm over the UAS between 2000 and 2013. SSEBop and SMAP ET a yielded similar seasonal patterns, with correlation coefficient (r) up to 0.65, mean difference (MD) of 0.8 mm/month and mean absolute difference (MAD) of 18.5 mm/month. Comparison of SSEBop annual ET a estimates to annual SMAP and WB closure estimates yielded low MD (12.1 and −7.3 mm/year, respectively) and MAD (82.5 and 82.8 mm/year, respectively), but also low r values (0.00 and 0.37, respectively). The comparison of the different SSEBop versions indicated the need to incorporate a calibration step of the aerodynamic heat resistance (r ah ) parameter. SSEBop results were also used for land cover and drought monitoring. Analysis indicates that agriculture, associated with an increasing trend of atmospheric evaporative demand, is responsible for the decrease in groundwater levels and streamflow in the studied time period.

Urucuia Aquifer System

Global pegmatite-hosted lithium, cesium, and rubidium resources: A dataset for grade and tonnage modeling

Quantitative mineral resource assessments of potential undiscovered deposits can inform future mineral supply scenarios, but their accuracy is conditional on building robust grade and tonnage models of known deposits. This study presents an up-to-date global compilation and analysis of recently discovered and original, in-situ pegmatite-hosted Li, Cs, and Rb resources prior to historic production. Our analysis yields a median tonnage of 21.2 million tons (Mt) and grade of 1.12% Li 2 O, respectively, for global Li pegmatite deposits ( n = 73). The grades and tonnages of Li pegmatite resources vary depending on the age of the bedrock host domain, pegmatite crystallization age, and primary ore mineralogy. Lithium pegmatite resources hosted in Archean to transitional Archean-Paleoproterozoic domains have the largest median tonnage (29.8 Mt; n = 38), and those hosted in Paleoproterozoic to Mesoproterozoic domains have smaller median tonnages (6.5 Mt; n = 16). Cesium deposits where pollucite is the primary ore mineral have a bimodal grade distribution, with modes of 2.40 and 0.035 wt% Cs 2 O for high- and low-grade deposits, respectively, while Rb deposits are more unimodal with a median grade of 0.247 wt% Rb 2 O. Pegmatite-hosted Cs and Rb resources have median tonnages of 7.6 and 6.3 Mt, respectively. Covariation between ore mineralogy and the degree of crustal enrichment in pegmatite-hosted deposits is diagnostic of petrogenetic differences, including melt source characteristics, magma evolution, or variable degrees of volatile solubility. The Li pegmatite compilation is suitable for fitting robust numerical models to support quantitative assessments. More well-defined Rb and Cs pegmatite resources are required for quantitative assessments, but these data provide useful information about original in-place resources for framing supply discussions.

Ore Geology Reviews

Generating geochemical and mineralogy distributions of soil in the conterminous United States using Bayesian hierarchical spatial models

Characterizing geochemical and mineralogical soil distributions across large spatial extents is essential for understanding mineral resources, ecosystem processes, and environmental risks. Rasters of soil geochemical distributions for the conterminous United States, however, are limited. We present a Bayesian modeling workflow and tool for generating predictive geochemical and mineralogy distribution maps for the conterminous United States using integrated nested Laplace approximation (INLA) with the stochastic partial differential equation approach. By modeling soil geostatistical data with environmental covariates (soil properties, topography, climate, and land cover), we generate predictive distributions of soil geochemistry that can be mapped or extracted for further analyses. As an example, we model the spatial distribution of trace elements in soil relevant to vertebrate health (cobalt, copper, iron, manganese, selenium, and zinc) and provide a workflow that can be used to generate and visualize predictive distributions of 39 other major and trace elements and 21 minerals of the soil survey, supporting a variety of ecological, environmental, and agricultural applications.

MethodsX

Ground magnetic and VLF studies at Midnite uranium mine, Stevens County, Washington

Ground magnetic and E-mode VLF measurements were made at more than 200 stations at the Midnite uranium Mine, Stevens County, Washington. The equipment was found to be light and foolproof, and each set of data was collected in one day, exclusive of surveying and marking the station points. The maps of contoured magnetic and VLF data resembled geologic maps of the area, showing many common features, as well as a few unique features on each map. Each showed some evidence of a small normal fault cutting the region; taken together, the evidence for this fault was judged to be much stronger, so that further structural details were inferred. Because of soil cover and inadequate outcrops, the presence of this fault had hitherto been unsuspected. A target area for further uranium mineralization north of the fault was indicated by this quick, inexpensive geophysical survey. The drilling program which Midnite Mine management had underway at that time had already outlined a mineralized zone in the indicated area.

Washington

Evaluating machine learning approaches to identify and predict oil and gas produced water lithium concentrations

Recently, the demand for battery-grade lithium has substantially increased, largely due to electrification of the transportation sector. The search for new lithium sources has turned to produced waters (frequently brines), a large-volume wastewater by-product of oil and gas extraction. Geochemical analysis indicates the presence of varying concentrations of lithium from produced water samples collected across the United States and represented in the U.S. Geological Survey’s National Produced Water Geochemical Database, as well as mixtures of Marcellus Shale produced water included in the Pennsylvania Department of Environmental Protection’s Oil and Gas Well Waste Reports. We first examined whether the geochemical signature of the lithium-bearing produced waters is sufficiently distinct so that machine learning (ML) can be used to correctly classify samples to the formation of origin. The produced water sample data used to assess classification accuracy were from the Marcellus Shale, Utica Shale and Point Pleasant Formation (Utica), and Smackover Formation oil and gas wells. Further, we evaluated the potential for ML to accurately classify Marcellus Shale produced water spatially (i.e., northeast versus southwest Pennsylvania). We then investigated whether ML algorithms applied to a suite of geochemical concentration data (i.e. Ba, Br, Cl, K, Mg, Sr) may be used to predict the lithium concentration of an unknown sample. Finally, we applied an estimated economic lithium grade cutoff of 150 milligrams per liter (mg/l) and assessed the utility of ML to predict whether a produced water sample would fall above or below the grade cutoff based on the suite of geochemical parameters. Four machine learning algorithms—Random Forest (RF), Gradient Boosting Trees (GBT), Extreme Boosting (XGBoost), and Deep Neural Networks (DNN) were assessed. This study successfully demonstrates that all four machine learning methods can precisely and accurately estimate lithium concentrations and geologic formation classification. The products of this study contribute to the growing body of knowledge aimed at expanding the lithium resource base within the United States.

Alabama, Arkansas, Florida, Georgia, Louisiana, Mi

Earth Mapping Resources Initiative protocols—Sampling hard-rock mine waste and perpetual mine water sources

Supporting the overarching goal to evaluate critical minerals nationwide, the mine waste characterization effort in the U.S. Geological Survey (USGS) Earth Mapping Resources Initiative has created a series of protocols to standardize sampling carried out under this effort by the participating State geological surveys and their cooperators. The protocols are based on published, reviewed methods that can be deployed in the field. The protocols include (1) collecting and processing composite samples of mine and mill waste, including tailings, waste rock, gangue, heap leach piles, ore stockpiles, slag, or other mineralized and processed materials and (2) collecting and preserving water samples from perpetual or long-term mine water sources. The protocols also specify information to document on field sheets and detail the collection of geospatial data. The analytical methods used by the USGS and USGS contract laboratories are described in this report, including the data delivery pathway for USGS-derived data.

Scientific Investigations Report

Potentially toxic elements in wild Agassiz’s desert tortoises: Tissue concentrations and association with disease

Background: Desert tortoise ( Gopherus agassizii ) populations have continued to decline due to infectious and other diseases, predation, and habitat alteration. The potential contribution of minerals and heavy metals to tortoise health and susceptibility to disease remains uncertain. Objective: The objective of this study was to evaluate the results of elemental analysis of trace minerals and macrominerals in scute keratin, kidney, and liver tissue from ill and dying desert tortoises salvaged for necropsy between 1993 and 2000. Methods: Salvaged tortoises were categorized by age (adult, juvenile), geographic location, and primary disease based on necropsy findings. A subset of tortoises that were injured or killed by vehicular trauma or predation but with no notable pathologic abnormalities were used as controls. A panel of 21 trace minerals and 6 macrominerals was analyzed in scute keratin, kidney, and liver tissue samples by inductively-coupled plasma spectrometry and atomic absorption spectrophotometry. Results: Necropsies were done on 46 tortoises, including 9 juveniles salvaged from 5 regions in the Colorado and Mojave deserts of California. Primary diseases were cutaneous dyskeratosis (n=9), infection/ inflammation (n=8), malnutrition (n=7), mycoplasmosis (n=5), and urolithiasis (n=3); 14 tortoises were classified as controls. Concentrations of elements differed significantly by tissue, age, desert region, and disease (P < 0.05). Tortoises with cutaneous dyskeratosis had significantly higher Se concentrations, primarily in keratin and liver, than tortoises with other diseases (P < 0.001). Juveniles were more likely than adults to have high Pb, Sn, and Zn levels (P < 0.05). All tortoises had detectable levels of more than one potentially toxic heavy metal, including As, Cd, Cr, Hg, Ni, Pb, Sn and V. Conclusions: Potentially toxic elements are frequently found in tissue from tortoises in desert regions of California, with significantly higher concentrations in diseased tortoises. Metal exposure from soils, mining, historic and ongoing military activities, and other human activities could increase susceptibility to disease in desert tortoises.

California

Geochemistry and thermometry of magnetite veins and replacements in iron ore deposits from the Iron Springs district, SW Utah, USA: Relation to magmatic and hydrothermal processes

Ore-genesis, texture, chemical compositions, and thermometry of magnetite were used to better evaluate the origins of iron ore deposits across the Iron Spring district, Utah. Trace element compositions, determined by LA-ICP-MS, were used to calculate temperatures based on X Mg numbers and characterize the trace element signatures of magmatic and hydrothermal magnetite. Magnetite occurs as coarser crystalline grains within veins, breccias, and cavities along with finer crystalline replacements. Magnetite is most commonly intergrown with apatite, phlogopite, and carbonate in veins, breccias, and cavities where apatite occurs separately from the other gangue minerals. The results using empirical trace element discrimination diagrams generally suggest that the magnetite is overall of hydrothermal origin regardless of textural variations or field relationships. The X Mg numbers of the magnetite in the magnetite-apatite ores, however, are suggestive of high temperature magmatic conditions; whereas those of vein, breccia, and replacement occurrences containing other gangue minerals are suggestive of lower temperature hydrothermal processes.

Utah

Reservoir thermal energy storage pre-assessment for the United States

Storing thermal energy underground for later use in electricity production or direct-use heating/cooling is a promising, viable, and economical green energy option. Reservoir thermal energy storage (RTES) is one such option, which stores energy in underutilized permeable strata with low ambient groundwater flow rates and more geochemically evolved (e.g. brackish/saline) waters relative to overlying principal aquifer systems. The U.S. Geological Survey has begun assessing RTES potential nationally by focusing on five generalized geologic regions (Basin and Range, Coastal Plain, Illinois Basin, Michigan Basin, Pacific Northwest) across the United States. Hydrogeologic reservoir models are developed for the following eight metropolitan area cities within those regions to evaluate RTES performance across different climates and subsurface conditions: Albuquerque, New Mexico; Charleston, South Carolina; Chicago and Decatur, Illinois; Lansing, Michigan; Memphis, Tennessee; Phoenix, Arizona; and Portland, Oregon. Evaluated metrics include estimated required well spacing, thermal storage capacity, and thermal recovery efficiency through time. Also considered for each reservoir are potential complicating factors, including reservoir depth, thermally driven free convection, and groundwater salinity. This work focuses on direct-use cooling because the need for cooling modern office buildings greatly exceeds that for heating in most parts of the country (Falta and others, 2016); however, the evaluated metrics are also relevant to heating and electricity applications. Results indicate that favorable RTES conditions exist in each region, with the Coastal Plain and Basin and Range being especially favorable for thermal storage capacity, while the Pacific Northwest and Michigan Basin excel at energy recovery for the evaluated cooling application. The results underscore the utility of developing maps of thermal storage capacity, subsurface temperature models, and volumetric estimates of thermal storage capacity to serve as key RTES resource classification standards. Overall, this pre-assessment provides a basic understanding of RTES potential in several cities and geologic regions throughout the country and will aid ongoing thermal energy storage assessment efforts.

Arizona, Illinois, Michigan, New Mexico, Oregon, S

Metal mobilization from thawing permafrost to aquatic ecosystems is driving rusting of Arctic streams

Climate change in the Arctic is altering watershed hydrologic processes and biogeochemistry. Here, we present an emergent threat to Arctic watersheds based on observations from 75 streams in Alaska’s Brooks Range that recently turned orange, reflecting increased loading of iron and toxic metals. Using remote sensing, we constrain the timing of stream discoloration to the last 10 years, a period of rapid warming and snowfall, suggesting impairment is likely due to permafrost thaw. Thawing permafrost can foster chemical weathering of minerals, microbial reduction of soil iron, and groundwater transport of metals to streams. Compared to clear reference streams, orange streams have lower pH, higher turbidity, and higher sulfate, iron, and trace metal concentrations, supporting sulfide mineral weathering as a primary mobilization process. Stream discoloration was associated with dramatic declines in macroinvertebrate diversity and fish abundance. These findings have considerable implications for drinking water supplies and subsistence fisheries in rural Alaska.

Alaska

Climate-driven sulfate export in alpine watersheds may stimulate methylmercury production

Climate change is increasing sulfate export and changing wetland extent in mountain regions. These changes may increase microbially mediated production of the neurotoxic substance methylmercury due to enhanced sulfate metabolism in mountain environments. Here, we assess methylmercury concentrations and formation rates across high-elevation wetlands in the Colorado Rocky Mountains. We also investigate sulfate controls on methylmercury production within subalpine peatlands by amending soils with sulfate to mimic increased stream export of sulfate from the alpine zone and measuring methylmercury formation rates for different sulfate treatments. We found that subalpine peatlands have statistically significant higher methylmercury concentrations and formation rates compared to alpine, mineral-soil wetlands. Methylmercury production in subalpine peatlands also increased significantly ( p < 0.05) following sulfate additions; the highest rates occurred in sediments with intermediate extractable sulfate concentrations (∼0.60–1.4 mg sulfate g −1 dry soil). Our study is the first to identify soil sulfate-related thresholds for methylmercury production and sulfate-limitation of methylmercury production in subalpine peatlands. These findings highlight important linkages between climate-driven mineral weathering and mercury cycling in mountain regions globally.

Colorado

Shallow storage of the explosive Earthquake Flat Pyroclastics magma body, Okataina Volcanic Center, Taupo Volcanic Zone, New Zealand: Evidence from phase-equilibria experiments

Rhyolitic tuffs range widely in their crystal contents from nearly aphyric to crystal-rich, and their crystal cargoes inform concepts of upper crustal magma reservoirs. The Earthquake Flat pyroclastics (Okataina Volcanic Center, Taupo Volcanic Zone, New Zealand) are 10 km 3 of rhyolitic tuffs with abundant (~ 40 vol.%) plagioclase and quartz, minor biotite, hornblende, and orthopyroxene, and accessory Fe-Ti oxides, apatite, and zircon, set in high-silica rhyolitic glass. Major minerals form large, euhedral phenocrysts and abundant glomerocrysts with few disequilibrium textures excepting some faintly resorbed quartz. Plagioclase phenocrysts have thick rims of nearly constant composition near An 30 , and hornblende is weakly zoned or unzoned. The abundant and texturally complex mineral assemblage contrasts with the nearby (~ 25 km), nearly synchronous, but more voluminous and crystal-moderate rhyolite tuffs from Rotoiti caldera. New H 2 O-saturated phase-equilibria results on the erupted Earthquake Flat melt (glass) determine its co-saturation with the partial phenocryst assemblage of plagioclase, quartz, biotite, and Fe-Ti oxides at: 140 MPa, 755 ºC. These closely approximate the conditions of the pre-eruptive magma body assuming it was saturated with nearly pure H 2 O and at an f O 2 of ~ Ni–NiO. Absence of hornblende and orthopyroxene from the synthesized assemblages may result from those minerals being in a peritectic reaction relation with melt to produce biotite, so they would not grow from the liquid used as starting material. Experimental results on Rotoiti rhyolite (Nicholls et al. 1992) show that the two bodies resided at similar pressures, temperatures, and f O 2 s. Lower crystal abundance of the Rotoiti tuffs may result from slight compositional differences. We interpret that the Earthquake Flat pyroclastics were sourced from the crystal-rich periphery of a mushy reservoir system with the Rotoiti occupying a more melt-rich central location. Uncertain is whether this was a single intrusion zoned continuously in crystallinity, or discrete adjacent intrusions, but our results illustrate and quantify complexities of magma storage across relatively short distances.

North Island, Taupo Volcanic Zone