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At least 181 records · Page 10Linked to original sources

Modeling thermal dynamics of active layer soils and near-surface permafrost using a fully coupled water and heat transport model

Thawing and freezing processes are key components in permafrost dynamics, and these processes play an important role in regulating the hydrological and carbon cycles in the northern high latitudes. In the present study, we apply a well-developed soil thermal model that fully couples heat and water transport, to simulate the thawing and freezing processes at daily time steps across multiple sites that vary with vegetation cover, disturbance history, and climate. The model performance was evaluated by comparing modeled and measured soil temperatures at different depths. We use the model to explore the influence of climate, fire disturbance, and topography (north- and south-facing slopes) on soil thermal dynamics. Modeled soil temperatures agree well with measured values for both boreal forest and tundra ecosystems at the site level. Combustion of organic-soil horizons during wildfire alters the surface energy balance and increases the downward heat flux through the soil profile, resulting in the warming and thawing of near-surface permafrost. A projection of 21st century permafrost dynamics indicates that as the climate warms, active layer thickness will likely increase to more than 3 meters in the boreal forest site and deeper than one meter in the tundra site. Results from this coupled heat-water modeling approach represent faster thaw rates than previously simulated in other studies. We conclude that the discussed soil thermal model is able to well simulate the permafrost dynamics and could be used as a tool to analyze the influence of climate change and wildfire disturbance on permafrost thawing.

Journal of Geophysical Research D: Atmospheres↗

Origin of two clay-mineral facies of the Potomac Group (Cretaceous) in the Middle Atlantic States

Sedimentary clay that crops out in the coastal plains of New Jersey, Delaware, the part of Maryland north and east of Washington, B.C., and the northeast half of Washington, D.C., in the nonmarine Cretaceous Potomac Group is predominantly kaolinite and illite. In contrast, in part of southeastern Maryland, the southwest half of Washington, D.C., and most of eastern Virginia, Potomac Group clay is predominantly montmorillonite. Kaolinite and illite were probably derived by intense acid weathering of metamorphic and granitic rocks to the west during the Cretaceous and were deposited in a well-drained basin. Montmorillonite was most likely produced by deep weathering of a mainly granitic source. Poor drainage and alkaline surface- and ground-water conditions probably accompanied the production, transportation, deposition, and burial of the montmorillonite. Kaolinization of the montmorillonite is taking place now at the surface in northern Virginia.

Delaware, Maryland, New Jersey, Pennsylvania, Virg↗

Channel incision and patterns of cottonwood stress and mortality along the Mojave River, California

In 1995, mapping and classification of riparian vegetation along the Mojave River in southern California revealed an 8-km reach in which riparian cottonwoods ( Populus fremontii Wats.) were stressed or dying. We tested a set of predictions based on the inference that cottonwood decline was an indirect result of lowered water-table levels following flood-related channel incision. Comparisons of topographic cross-sections from 1963 and 1997, indicated a net change in channel elevation between −0·71 and −3·6 m within zones of cottonwood stress and mortality. Ages of young cottonwood and willow stems adjacent to the present channel and radial stem growth of surviving cottonwoods were consistent with the inference that channel incision, associated with sustained flooding in January and February of 1993, lowered channel elevations throughout the affected reach. Well records and soil redoximorphic features indicate that channel incision caused net water-table declines ⩾1·5 m on portions of the adjacent flood plain where cottonwood stand mortality ranged between 58 and 93%. In areas where water-table declines were estimated to be <1·0 m, stand mortality was 7–13%.

Journal of Arid Environments↗

Factors affecting pesticide occurrence and transport in a large Midwestern river basin

Several factors affect the occurrence and transport of pesticides in surface waters of the 29,400 km2 White River Basin in Indiana. A relationship was found between pesticide use and the average annual concentration of that pesticide in the White River, although this relationship varies for different classes of pesticides. About one percent of the mass applied of each of the commonly used agricultural herbicides was transported from the basin via the White River. Peak pesticide concentrations were typically highest in late spring or early summer and were associated with periods of runoff following application. Concentrations of diazinon were higher in an urban basin than in two agricultural basins, corresponding to the common use of this insecticide on lawns and gardens in urban areas. Concentrations of atrazine, a corn herbicide widely used in the White River Basin, were higher in an agricultural basin with permeable, well-drained soils, than in an agricultural basin with less permeable, more poorly drained soils. Although use of butylate and cyanazine was comparable in the White River Basin between 1992 and 1994, concentrations in the White River of butylate, which is incorporated into soil, were substantially less than for cyanazine, which is typically applied to the soil surface.

Indiana↗

Organic substances in produced and formation water from unconventional natural gas extraction in coal and shale

Organic substances in produced and formation water from coalbed methane (CBM) and gas shale plays from across the USA were examined in this study. Disposal of produced waters from gas extraction in coal and shale is an important environmental issue because of the large volumes of water involved and the variable quality of this water. Organic substances in produced water may be environmentally relevant as pollutants, but have been little studied. Results from five CBM plays and two gas shale plays (including the Marcellus Shale) show a myriad of organic chemicals present in the produced and formation water. Organic compound classes present in produced and formation water in CBM plays include: polycyclic aromatic hydrocarbons (PAHs), heterocyclic compounds, alkyl phenols, aromatic amines, alkyl aromatics (alkyl benzenes, alkyl biphenyls), long-chain fatty acids, and aliphatic hydrocarbons. Concentrations of individual compounds range from < 1 to 100 μg/L, but total PAHs (the dominant compound class for most CBM samples) range from 50 to 100 μg/L. Total dissolved organic carbon (TOC) in CBM produced water is generally in the 1–4 mg/L range. Excursions from this general pattern in produced waters from individual wells arise from contaminants introduced by production activities (oils, grease, adhesives, etc.). Organic substances in produced and formation water from gas shale unimpacted by production chemicals have a similar range of compound classes as CBM produced water, and TOC levels of about 8 mg/L. However, produced water from the Marcellus Shale using hydraulic fracturing has TOC levels as high as 5500 mg/L and a range of added organic chemicals including, solvents, biocides, scale inhibitors, and other organic chemicals at levels of 1000 s of μg/L for individual compounds. Levels of these hydraulic fracturing chemicals and TOC decrease rapidly over the first 20 days of water recovery and some level of residual organic contaminants remain up to 250 days after hydraulic fracturing. Although the environmental impacts of the organics in produced water are not well defined, results suggest that care should be exercised in the disposal and release of produced waters containing these organic substances into the environment because of the potential toxicity of many of these substances.

International Journal of Coal Geology↗

Progression of natural attenuation processes at a crude-oil spill site . I. Geochemical evolution of the plume

A 16-year study of a hydrocarbon plume shows that the extent of contaminant migration and compound-specific behavior have changed as redox reactions, most notably iron reduction, have progressed over time. Concentration changes at a small scale, determined from analysis of pore-water samples drained from aquifer cores, are compared with concentration changes at the plume scale, determined from analysis of water samples from an observation well network. The small-scale data show clearly that the hydrocarbon plume is growing slowly as sediment iron oxides are depleted. Contaminants, such as ortho -xylene that appeared not to be moving downgradient from the oil on the basis of observation well data, are migrating in thin layers as the aquifer evolves to methanogenic conditions. However, the plume-scale observation well data show that the downgradient extent of the Fe 2+ and BTEX plume did not change between 1992 and 1995. Instead, depletion of the unstable Fe (III) oxides near the subsurface crude-oil source has caused the maximum dissolved iron concentration zone within the plume to spread at a rate of approximately 3 m/year. The zone of maximum concentrations of benzene, toluene, ethylbenzene and xylene (BTEX) has also spread within the anoxic plume. In monitoring the remediation of hydrocarbon-contaminated ground water by natural attenuation, subtle concentration changes in observation well data from the anoxic zone may be diagnostic of depletion of the intrinsic electron-accepting capacity of the aquifer. Recognition of these subtle patterns may allow early prediction of growth of the hydrocarbon plume.

Journal of Contaminant Hydrology↗

Bayesian hierarchical modeling for probabilistic estimation of tsunami amplitude from far-field earthquake sources

Evaluation of tsunami disaster risk for a coastal region requires reliable estimation of tsunami hazard, for example, wave amplitude close to the shore. Observed tsunami data are scarce and have poor spatial coverage, and for this reason probabilistic tsunami hazard analysis (PTHA) traditionally relies on numerical simulation of “synthetic” tsunami generation and propagation toward the coast. Such an approach has been extensively studied in the past and it is widely recognized as an important disaster-risk mitigation tool. PTHA can not only provide less uncertain and spatially coherent hazard estimates in comparison with classical empirical data analysis which is restricted at the tide gauge stations, but also local inundation information. In this paper, we explore a purely statistical alternative to traditional PTHA for evaluation of tsunami amplitude hazard. Here, we use tide gauge measurements of tsunami amplitude along the western United States, specifically California and Oregon, and develop a spatial Bayesian hierarchical model (BHM) to assess tsunami hazard from far-field earthquake sources at various recurrence intervals. The configuration of our model incorporates latent Gaussian fields that utilize information on the distance between tide gauges as well as on the continental shelf width, that is, a covariate linked to potential dissipative effects on wave energy as the tsunami travels over shallow water. Through our BHM, we produce spatially continuous probabilistic maps of far-field tsunami hazard which can aid comprehensive tsunami disaster risk reduction and management.

California, Oregon, Washington↗

Phytoremediation of a petroleum-hydrocarbon contaminated shallow aquifer in Elizabeth City, North Carolina, USA

A former bulk fuel terminal in North Carolina is a groundwater phytoremediation demonstration site where 3,250 hybrid poplars, willows, and pine trees were planted from 2006 to 2008 over approximately 579,000 L of residual gasoline, diesel, and jet fuel. Since 2011, the groundwater altitude is lower in the area with trees than outside the planted area. Soil-gas analyses showed a 95 percent mass loss for total petroleum hydrocarbons (TPH) and a 99 percent mass loss for benzene, toluene, ethylbenzene, and xylenes (BTEX). BTEX and methyl tert-butyl ether concentrations have decreased in groundwater. Interpolations of free-phase, fuel product gauging data show reduced thicknesses across the site and pooling of fuel product where poplar biomass is greatest. Isolated clusters of tree mortalities have persisted in areas with high TPH and BTEX mass. Toxicity assays showed impaired water use for willows and poplars exposed to the site's fuel product, but Populus survival was higher than the willows or pines on-site, even in a noncontaminated control area. All four Populus clones survived well at the site.

North Carolina↗

Successional trends in Sonoran Desert abandoned agricultural fields in northern Mexico

Excessive ground-water use and saline intrusion to the aquifer led, in less than three decades, to an increase in abandoned agricultural fields at La Costa de Hermosillo, within the Sonoran Desert. Using a chronosequence from years since abandonment, patterns of field succession were developed. Contrary to most desert literature, species replacement was found, both in fields with and without saline intrusion. Seasonal photosynthetic capacity as well as water and nitrogen use efficiencies were different in dominant early and late successional plant species. These ecological findings provided a framework for a general explanation of species dominance and replacement within abandoned agricultural fields in the Sonoran Desert. ?? 2004 Elsevier Ltd. All rights reserved.

Journal of Arid Environments↗

Rapid fluid disruption: A source for self-potential anomalies on volcanoes

Self-potential (SP) anomalies observed above suspected magma reservoirs, dikes, etc., on various volcanoes (Kilauea, Hawaii; Mount Unzen, Japan; Piton de la Fournaise, Reunion Island, Miyake Jima, Japan) result from transient surface electric fields of tens of millivolts per kilometer and generally have a positive polarity. These SP anomalies are usually attributed to electrokinetic effects where properties controlling this process are poorly constrained. We propose an alternate explanation that contributions to electric fields of correct polarity should be expected from charge generation by fluid vaporization/disruption. As liquids are vaporized or removed as droplets by gas transport away from hot dike intrusions, both charge generation and local increase in electrical resistivity by removal of fluids should occur. We report laboratory observations of electric fields in hot rock samples generated by pulses of fluid (water) through the rock at atmospheric pressure. These indicate the relative amplitudes of rapid fluid disruption (RFD) potentials and electrokinetic potentials to be dramatically different and the signals are opposite in sign. Above vaporization temperatures, RFD effects of positive sign in the direction of gas flow dominate, whereas below these temperatures, effects of negative sign dominate. This suggests that the primary contribution to observed self-potential anomalies arises from gas-related charge transport processes at temperatures high enough to produce vigorous boiling and vapor transport. At lower temperatures, the primary contribution is from electrokinetic effects modulated perhaps by changing electrical resistivity and RFD effects from high-pressure but low-temperature CO2 and SO2 gas flow ripping water molecules from saturated crustal rocks. If charge generation is continuous, as could well occur above a newly emplaced dike, positive static potentials will be set up that could be sustained for many years, and the simplest method for identifying these hot, active regions would be to identify the SP anomalies they generate.

Hawai'i↗

Temperature dependence of unsaturated hydraulic conductivity of two soils

Packed columns of Oakley sand (mixed, mesic Typic Paleudalfs) and Hanford sandy loam (mixed, nonacid, thermic Typic Xerorthents) were used to develop isothermal steady-state fluxes. Soil matric potentials were measured and unsaturated hydraulic conductivities were calculated over a range of matric potentials at 2°, 25°, and 45° ± 0.5°C. In addition, water retention characteristics (to −100 kPa) were measured at these same temperatures for both soils. In this paper, the calculated results are compared to an equation that relates unsaturated conductivity to the intrinsic permeability, the relative permeability, and the viscosity of water. The equation considers viscosity to be the only parameter that changes with temperature. The results show a much greater temperature dependence in the unsaturated conductivity than would be predicted by this equation. The results indicate that the relative permeability may be a function of temperature. The temperature dependence of the soil water matric potential, surface tension, and diffuse double-layer thickness are discussed in terms of their possible interaction with the unsaturated conductivity values obtained. A case is presented for further study to isolate these temperature-sensitive parameters as well as additional parameters related to fluid flow path changes with temperature.

Soil Science Society of America Journal↗

Map visualization of groundwater withdrawals at the sub-basin scale

A simple method is proposed to visualize the magnitude of groundwater withdrawals from wells relative to user-defined water-resource metrics. The map is solely an illustration of the withdrawal magnitudes, spatially centered on wells—it is not capture zones or source areas contributing recharge to wells. Common practice is to scale the size (area) of withdrawal well symbols proportional to pumping rate. Symbols are drawn large enough to be visible, but not so large that they overlap excessively. In contrast to such graphics-based symbol sizes, the proposed method uses a depth-rate index (length per time) to visualize the well withdrawal rates by volumetrically consistent areas, called “footprints”. The area of each individual well’s footprint is the withdrawal rate divided by the depth-rate index. For example, the groundwater recharge rate could be used as a depth-rate index to show how large withdrawals are relative to that recharge. To account for the interference of nearby wells, composite footprints are computed by iterative nearest-neighbor distribution of excess withdrawals on a computational and display grid having uniform square cells. The map shows circular footprints at individual isolated wells and merged footprint areas where wells’ individual footprints overlap. Examples are presented for depth-rate indexes corresponding to recharge, to spatially variable stream baseflow (normalized by basin area), and to the average rate of water-table decline (scaled by specific yield). These depth-rate indexes are water-resource metrics, and the footprints visualize the magnitude of withdrawals relative to these metrics.

Hydrogeology Journal↗

Change in potentiometric head in the Lloyd Aquifer, Long Island, N.Y

The potentiometric surface of the Lloyd aquifer in 1970 locally was as much as 40 feet lower than in 1900. During this period, withdrawal of water from wells was estimated to exceed 300 billion gallons, and the amount of water released from aquifer storage by compressive forces was estimated to be 1.6 billion gallons (about 0.5 percent of the withdrawal). The remainder of the withdrawal was derived from downward leakage through overlying aquifers and confining layers and by the displacement of fresh water in the aquifer by landward movement of salty ground water

New York↗

Comparison of two parametric methods to estimate pesticide mass loads in California's Central Valley

Mass loadings were calculated for four pesticides in two watersheds with different land uses in the Central Valley, California, by using two parametric models: (1) the Seasonal Wave model (SeaWave), in which a pulse signal is used to describe the annual cycle of pesticide occurrence in a stream, and (2) the Sine Wave model, in which first-order Fourier series sine and cosine terms are used to simulate seasonal mass loading patterns. The models were applied to data collected during water years 1997 through 2005. The pesticides modeled were carbaryl, diazinon, metolachlor, and molinate. Results from the two models show that the ability to capture seasonal variations in pesticide concentrations was affected by pesticide use patterns and the methods by which pesticides are transported to streams. Estimated seasonal loads compared well with results from previous studies for both models. Loads estimated by the two models did not differ significantly from each other, with the exceptions of carbaryl and molinate during the precipitation season, where loads were affected by application patterns and rainfall. However, in watersheds with variable and intermittent pesticide applications, the SeaWave model is more suitable for use on the basis of its robust capability of describing seasonal variation of pesticide concentrations.

California↗

Estimation of the depth to the fresh-water/salt-water interface from vertical head gradients in wells in coastal and island aquifers

An accurate estimate of the depth to the theoretical interface between fresh, water and salt water is critical to estimates of well yields in coastal and island aquifers. The Ghyben–Herzberg relation, which is commonly used to estimate interface depth, can greatly underestimate or overestimate the fresh-water thickness, because it assumes no vertical head gradients and no vertical flow. Estimation of the interface depth needs to consider the vertical head gradients and aquifer anisotropy that may be present. This paper presents a method to calculate vertical head gradients using water-level measurements made during drilling of a partially penetrating well; the gradient is then used to estimate interface depth. Application of the method to a numerically simulated fresh-water/salt-water system shows that the method is most accurate when the gradient is measured in a deeply penetrating well. Even using a shallow well, the method more accurately estimates the interface position than does the Ghyben–Herzberg relation where substantial vertical head gradients exist. Application of the method to field data shows that drilling, collection methods of water-level data, and aquifer inhomogeneities can cause difficulties, but the effects of these difficulties can be minimized.

Hydrogeology Journal↗

Wildlife, urban inputs, and landscape configuration are responsible for degraded swimming water quality at an embayed beach

Jeorse Park Beach, on southern Lake Michigan, experiences frequent closures due to high Escherichia coli ( E. coli ) levels since regular monitoring was implemented in 2005. During the summer of 2010, contaminant source tracking techniques, such as the conventional microbial and physical surveys and hydrodynamic models, were used to determine the reasons for poor water quality at Jeorse Park. Fecal indicator bacteria ( E. coli , enterococci) were high throughout the season, with densities ranging from 12&ndash;2419 (culturable E. coli ) and 1&ndash;2550 and < 1&ndash;5831 (culturable and qPCR enterococci, respectively). Genetic markers for human ( Bacteroides HF183) and gull ( Catellicoccus marimammalium ) fecal contamination were found in 15% and 37% of the samples indicating multiple sources contributing to poor water quality. Nesting colonies of double-crested cormorants ( Phalacrocorax auritus ) have steadily increased since 2005, coinciding with high E. coli levels. A hydrodynamic model indicated that limited circulation allows bacteria entering the embayed area to be retained in nearshore areas; and bacterial resuspension from sand and stranded beach wrack during storm events compounds the problem. The integration of hydrodynamics, expanded use of chemical and biological markers, as well as more complex statistical multivariate techniques can improve microbial source tracking, informing management actions to improve recreational water quality. Alterations to embayed structures to improve circulation and reduce nuisance algae as well as growing native plants to retain sand to improve beach morphometry are among some of the restoration strategies under consideration in ongoing multi-agency collaborations.

Indiana↗

The Miocene Atastra Creek sinter (Bodie Hills volcanic field, California and Nevada): 4D evolution of a geomorphically intact siliceous hot spring deposit

The Atastra Creek siliceous hot spring deposit, or sinter, occurs in the Paramount-Bald Peak alteration zone, due north of the Bodie precious metals mining district in the Miocene Bodie Hills volcanic field, California and Nevada, U.S.A. Distinctive features include its geomorphically intact geyser vent mounds, the presence of growth-fault-stepped sinter terraces that developed westward along a NNW trending fault, and atypical Hg, Sb and As concentrations. High-temperature (>75 °C), subaerial, proximal apron sinter occurs in two settings – (1) radiating botryoidal geyserite in vent mounds and (2) bedded geyserite (columnar, nodular, size-sorted geyser eggs) intercalated with mid- to low-temperature (<60 °C), middle to distal apron terrace sinter. The active geyser vent mounds migrated from south to north across the apron terrace through time. A newly recognized, visually striking type of sinter – termed silica infiltrate herein – formed directly beneath the subaerial geyserite deposits. It is characterized by mainly parallel, thin, irregular beds of white silica with narrow borders of dark blue-gray silica, as well as swirly to globular white silica, all chaotically linked together by silica ‘necks’ and ‘bridges’. The silica infiltrate permeates the pre-existing sinter, and is interpreted to represent super-heated fluid injections into the immediately overlying geyser vent mounds and pools. The adjacent sinter sheets preserve fluid-flow directions of warm-water channels that traversed the discharge apron, including microbial streamer fabric and wavy laminated sinter with flattened bubbles. More distal sinter textures are recorded by rimmed terracettes with mammillated and palisade microbial fabrics and rare, warm pool-related stromatolites. However, plants are absent, probably due to the high metalloids, in particular As. Post-depositional events include an inferred hydrothermal eruption breccia and an interpreted drop in the water table accompanied by incursion of steam acid condensate, as evidenced by pervasive hydrothermal alteration of the Atastra Creek deposits. Hence, the well-exposed sedimentary facies distributions, well-preserved geomorphology, and stratigraphic and structural relationships together allow an unusually complete, paleoenvironmental reconstruction of the Atastra Creek paleohydrothermal deposit.

Journal of Volcanology and Geothermal Research↗

Multicriteria decision analysis applied to Glen Canyon Dam

Conflicts in water resources exist because river-reservoir systems are managed to optimize traditional benefits (e.g., hydropower and flood control), which are historically quantified in economic terms, whereas natural and environmental resources, including in-stream and riparian resources, are more difficult or impossible to quantify in economic terms. Multicriteria decision analysis provides a quantitative approach to evaluate resources subject to river basin management alternatives. This objective quantification method includes inputs from special interest groups, the general public, and concerned individuals, as well as professionals for each resource considered in a trade-off analysis. Multicriteria decision analysis is applied to resources and flow alternatives presented in the environmental impact statement for Glen Canyon Dam on the Colorado River. A numeric rating and priority-weighting scheme is used to evaluate 29 specific natural resource attributes, grouped into seven main resource objectives, for nine flow alternatives enumerated in the environmental impact statement.

Journal of Water Resources Planning and Management↗