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At least 181 records · Page 10Linked to original sources

New isotopic evidence for the origin of groundwater from the Nubian Sandstone Aquifer in the Negev, Israel

The geochemistry and isotopic composition (H, O, S, O sulfate , C, Sr) of groundwater from the Nubian Sandstone (Kurnub Group) aquifer in the Negev, Israel, were investigated in an attempt to reconstruct the origin of the water and solutes, evaluate modes of water–rock interactions, and determine mean residence times of the water. The results indicate multiple recharge events into the Nubian sandstone aquifer characterized by distinctive isotope signatures and deuterium excess values. In the northeastern Negev, groundwater was identified with deuterium excess values of ∼16‰, which suggests local recharge via unconfined areas of the aquifer in the Negev anticline systems. The δ 18 O H2O and δ 2 H values (−6.5‰ and −35.4‰) of this groundwater are higher than those of groundwater in the Sinai Peninsula and southern Arava valley (−7.5‰ and −48.3‰) that likewise have lower deuterium excess values of ∼10‰. Based on the geochemical differences between groundwater in the unconfined and confined zones of the aquifer, a conceptual geochemical model for the evolution of the groundwater in the Nubian sandstone aquifer has been reconstructed. The isotopic composition of shallow groundwater from the unconfined zone indicates that during recharge oxidation of pyrite to SO 4 ( δ 34 S SO4 ∼−13‰; δ 18 O SO4 ∼+7.7‰) and dissolution of CaCO 3 ( 87 Sr/ 86 Sr ∼0.70787; δ 13 C DIC = −3.7‰) occur. In the confined zone of the aquifer, bacterial SO 4 reduction removes a significant part of dissolved SO 4 2 - "> SO42- , thereby modifying its isotopic composition ( δ 34 S SO4 ∼−2‰; δ 18 O SO4 ∼+8.5‰) and liberating dissolved inorganic C that contains little or no radiocarbon ( 14 C-free) with low δ 13 C DIC values (<−12‰). In addition to local recharge, the Sr and S isotopic data revealed contribution of external groundwater sources to the Nubian Sandstone aquifer, resulting in further modifications of the groundwater chemical and isotopic signatures. In the northeastern Negev, it is shown that SO 4 -rich groundwater from the underlying Jurassic aquifer contributes significantly to the salt budget of the Nubian Sandstone aquifer. The unique chemical and isotopic composition of the Jurassic groundwater ( δ 34 S SO4 ∼ +14‰; δ 18 O SO4 ∼ 14‰; 87 Sr/ 86 Sr ∼0.70764) is interpreted as reflecting dissolution of Late Triassic marine gypsum deposits. In the southern Arava Valley the authors postulate that SO 4 -rich groundwater with distinctively high Br/Cl (3 × 10 −3 ) low 87 Sr/ 86 Sr (0.70734), and high δ 34 S SO4 values (+15‰) is derived from mixing with underlying brines from the Paleozoic units. The radiocarbon measurements reveal low 14 C activities (0.2–5.8 pmc) in both the northeastern Negev and southern Arava Valley. Taking into account dissolution of carbonate rocks and bacterial SO 4 reduction in the unconfined area, estimated mean residence times of groundwater in the confined zone in the northeastern Negev are on the order of 21–38 ka, which suggests recharge predominantly during the last glacial period. The 14 C signal in groundwater from the southern Arava Valley is equally low but due to evidence for mixing with external water sources the residence time estimates are questionable.

Applied Geochemistry

Subseasonal variations in marine reservoir age from pre-bomb Donax obesulus and Protothaca asperrima shell carbonate

Two Donax obesulus and two Protothaca asperrima shells collected prior to the nuclear testing of the 1950's were micromilled at sub-seasonal resolution to yield new reservoir effect (ΔR) estimates for the coast of Peru. Shells from northern (4°40′S to 8°14′S) and central (13°52′S) Peru produced ΔR values of 123 ± 50 and 110 ± 49 years respectively. We found such values statistically indistinguishable from each other while reporting intra-annual ΔR variability along shells ontogeny in agreement with previously published regional ΔR values. This similarity suggests radiocarbon dating of short-lived (<1.5 years) mollusks shells is a useful tool for comparing marine radiocarbon signals. Additionally, our analysis of ΔR and δ 18 O changes along shells' ontogeny found a tenuous relationship between them. We are not the first one to report these phenomena in Peruvian upwelling , but we are the first to suggest that fast Lagrangian water mixing as a mechanism behind it.

Chemical Geology

The Missoula and Bonneville floods—A review of ice-age megafloods in the Columbia River basin

The Channeled Scabland of eastern Washington State, USA, brought megafloods to the scientific forefront. A 30,000-km2 landscape of coulees and cataracts carved into the region’s loess-covered basalt attests to overwhelming volumes of energetic water. The scarred landscape, garnished by huge boulder bars and far-travelled ice-rafted erratics, spurred J Harlen Bretz’s vigorously disputed flood hypothesis in the 1920s. First known as the Spokane flood, it was rebranded the Missoula flood once understood that the water came from glacial Lake Missoula, formed when the Purcell Trench lobe of the last-glacial Cordilleran ice sheet dammed the Clark Fork valley in northwestern Idaho with ice a kilometer thick. Bretz’s flood evidence in the once-remote Channeled Scabland, widely seen and elaborated by the 1950s, eventually swayed consensus for cataclysmic flooding. Missoula flood questions then turned to some that continue today: how many? when? how big? what routes? what processes? The Missoula floods passed through eastern Washington by a multitude of valleys, coulees and scabland tracts, some contemporaneously, some sequentially. Which routings and their timing depended on the positions of various lobes of the multi-pronged Cordilleran ice sheet and the erosional development of the channels themselves. The first floods mostly followed the big bend of Columbia valley looping through north-central Washington. But the south-advancing Okanogan ice lobe soon blocked that path, forming long-lasting glacial Lake Columbia in the impounded Columbia valley. Missoula floods into this lake were diverted south out of the Columbia valley and into eastern Washington coulees and scabland tracts. At least four floods entered Moses Coulee, but then as the Okanogan lobe advanced over and blocked the head of that coulee, more eastern paths took the water, including Grand Coulee and the Telford-Crab-Creek and Cheney-Palouse scabland tracts. Flood routing also depended on the erosion of the coulees. At some point, headward erosion of upper Grand Coulee lowered the divide saddle between the west-running Columbia valley and the deep and wide Grand Coulee heading southwest. Still uncertain is when this happened and the consequences with respect to the stage and extent of glacial Lake Columbia and to flood access to the other, higher, flood routes. Downstream, all flood routes converged onto Pasco Basin, flowed through Wallula Gap and the Columbia River Gorge into the Pacific Ocean, following submarine canyons and depositing sediment layers on abyssal plains. Stratigraphic studies indicate dozens—likely more than a hundred—separate Missoula floods during the last glacial period. Over the length of the flood route, backwater areas and depositional basins preserve multiple flood beds, many of which are separated by signs of time, including volcanic ash layers and soil development in subaerial environments; and varve-like beds and pelagic mud layers in lacustrine and marine settings. Evidence also comes from the glacial Lake Missoula basin, where stratigraphy indicates dozens of filling and emptying cycles. Varve counts in conjunction of radiocarbon dating and paleomagnetic secular variation show the repeated filling-and-release cycles of glacial Lake Missoula had intervals possibly as long as 100 years early in the lake’s history but diminished to just one or two years for the last few floods. This behavior accords with jökulhlaup-style floods released by subglacial drainage from a self-dumping ice-dammed lake. But not yet clear is whether such a mechanism applies to all the floods or if some emptied more cataclysmically as hypothesized by some. Radiocarbon dating of sparse organic materials remains key to defining flood chronology but has been lately bolstered by analyses of terrestrial cosmogenic nuclides and optically stimulated luminescence. Varve counts and paleomagnetic secular variation studies help to define durations and intervals represented by sequences of flood beds. The ~16 ka Mount St. Helens Set S tephra is commonly interbedded within flood deposits, enabling correlation of deposits among sites. Tephra from the 13.7–13.4 ka eruption of Glacier Peak overlies all glacial Lake Missoula and Missoula flood deposits, defining an end time. Overall conclusions are that glacial Lake Missoula was extant and producing floods for at least 3–4 ky during 20–14 ka. At least ~75 floods preceded Mount St Helens Set S, followed by 30 or more after the tephra fall. Most floods entered glacial Lake Columbia, impounded by the Okanogan lobe, for 2–5 ky between about 18.5 and 15 ka. Glacial Lake Columbia outlived Lake Missoula by >200–400 yr but may have been born later since at least one flood came down the Columbia valley before the Okanogan ice lobe blocked the Columbia valley at 18.5–18 ka. The maximum extent of the Okanogan and Purcell Trench lobes, many Missoula floods, substantial erosion of upper Grand Coulee, and the widespread tephra falls from Mount St. Helens eruptions all happened about 17–15 ka. People, in the area since 16.6–15.3 ka, almost certainly witnessed the last of the Missoula floods and later large floods from other ice-dammed lakes in the Columbia River basin. Quantitative flow analyses give peak discharge estimates and support understanding of erosional and depositional processes. The first flow assessments were simple cross-section calculations but recent assessments employ two-dimensional hydrodynamic models. The general finding is that emplacement of the maximum stage evidence requires about 20 million m3/s near the Lake Missoula outlet and about 5–15 million m3/s through Wallula Gap and downstream in the Columbia River Gorge. These hydraulic analyses raise still-unresolved questions regarding canyon erosion and possible additional water sources. The large Pleistocene Bonneville flood entered the Columbia River system from the southeast from pluvial Lake Bonneville, the Pleistocene predecessor to Great Salt Lake in the eastern Great Basin. During the last glacial, the lake basin filled, covering >50,000 km2 with 10,400 km3 of water before reaching its maximum possible stage governed by Red Rock Pass, the lowest divide separating the basin from the Snake River basin to the north. The overtopping lake rapidly incised 108–125 m into the Red Rock Pass outlet, spilling half of its total lake volume. G.K. Gilbert described the essential sequence in the 1870s, but the flood was mostly forgotten until the late 1950s when Harold Malde linked the spectacular scabland topography and bouldery “melon gravel” on the Snake River Plain to the Lake Bonneville overflow. The Bonneville flood appears to have been a singular event at about 18 ka. No evidence of multiple or pre-last-glacial spillovers has yet been found. Its total volume was about twice that of a maximum Lake Missoula flood yet its peak discharge was ~1 million m3/s, less than a tenth of the largest Missoula floods. Its comparatively simple flow path and much steadier flow make the Bonneville flood ideal for new studies of erosional and depositional processes. At least two floods seem to have passed down the Columbia valley after the last of the Missoula floods, including a large flood about ~14 ka likely from cataclysmic demise of the thinning Okanogan ice lobe dam impounding glacial Lake Columbia. Floods from earlier glacial ages left scant yet clear evidence in the Channeled Scabland and Columbia valley. But their source, timing, and magnitudes are little understood. Some deposits are paleomagnetically reversed, thus older than ~800 ka. Last-glacial floods and perhaps older ones affected the Snake River Plain, some likely sourced in lakes dammed by alpine glaciers in central Idaho.

Idaho, Oregon, Washington

Guidelines for producing integrated 210Pb and 14C age-models

Accurate reconstructions of past environmental changes are crucial in paleoecological research and require reliable chronologies of sedimentary archives. Establishing robust age-models and obtaining the most appropriate proxies for analysis is a complex scientific endeavor, requiring extensive resources and collaboration among specialists, including radiochronologists. Radiometric dating methods, such as 210 Pb and radiocarbon ( 14 C), are frequently employed to establish chronologies in aquatic sedimentary deposits and peat bogs. In this study, we review key aspects of sampling, analysis, and the principles underlying 210 Pb and 14 C age-models, focusing on methods for developing robust joint chronologies for paleoenvironmental research. Drawing largely from the authors' experiences and group discussions during and after a scientific workshop in 2022, we discuss important considerations for site selection, sampling strategies, and radiometric dating to construct integrated 210 Pb and 14 C age-models. Using expert consensus, this group – called Paleostats – aims to provide a set of best practices for other geochronologists with this methods paper. Among our conclusions, we emphasize the importance of accounting for site-specific factors such as prior information on sedimentation rates to establish appropriate sampling and analytical strategies. The use of appropriate coring devices can minimize disturbance to sediments and ensure the core surface remains intact and preserved until sectioning. Where excess 210 Pb is expected, sectioning at intervals of ≤1 cm provides an adequate sampling resolution for 210 Pb dating. Exceptions are possible, allowing for ~2–3 cm sections in areas with confirmed high sedimentation rates (e.g., > 1 cm yr −1 ). Recovering deeper core sections for 14 C dating with sufficient overlap allows for accounting errors in depth estimates made in the field. Special attention is advised during time intervals where validation proxies, such as the human-made radionuclides 137 Cs or post-bomb 14 C, are expected, and to determine the depth of secular equilibrium between 210 Pb and 226 Ra. Radiocarbon analyses are commonly performed by accelerator mass spectrometry, and age models are constructed mainly using Bayesian statistics with Markov Chain Monte Carlo techniques (e.g., Bacon ). A Bayesian approach ( Plum ) is now available for producing 210 Pb age-models, which infers the 210 Pb ex flux, eliminates the need for selecting an equilibrium depth, and allows dating cores with incomplete 210 Pb ex inventory. Plum offers improved chronologies by integrating raw 210 Pb and 14 C data, and these age-models can be enriched with other dating methodologies, such as identifying tephras and other well-recorded historical events. Harmonized reporting would contribute to making radiometric age-models reproducible, which would benefit from an international effort. Using 210 Pb and 14 C to produce integrated age-models may yield better insights into the interplay between natural and recent anthropogenic forcings on ecosystems. This can enhance our understanding of environmental processes and their impacts on climate change, ultimately supporting science-based assessments and decisions.

Earth-Science Reviews

Deep root activity overprints weathering of petrogenic organic carbon in shale

The oxidation of organic carbon in sedimentary bedrock (petrogenic OC, OC p e t r o "> petro ) is increasingly recognized as a potential source of CO 2 to the atmosphere. Recent studies provide evidence for the mobilization and oxidation of OC p e t r o "> petro in sedimentary bedrock during rock weathering. However, the mechanisms and rates remain uncertain, particularly where overlying soils and vegetation drive contemporaneous oxidation of recently fixed organic carbon. Here, we quantify OC p e t r o "> petro weathering across a 16 m shale depth profile in a steep, rapidly eroding forested hillslope in the Northern California Coast Ranges. We report solid and gas phase radiocarbon and stable isotope analyses of samples extracted from specialized in-situ samplers, and a supporting laboratory incubation experiment of the shale regolith. OC p e t r o "> petro is removed from the weathered bedrock at a rate of approximately 0.12 gC/m 3 yr, which is orders of magnitude lower than the rate of OC p e t r o "> petro oxidation we achieved in the laboratory with crushed samples (557.1 gC/m 3 /yr). This disparity occurs despite high O 2 ( g ) "> 2(g) content across the depth profile, indicating that physical accessibility of OC p e t r o "> petro can regulate oxidative weathering. There is no direct radiocarbon evidence of OC p e t r o "> petro oxidation in CO 2 ( g ) "> 2(g) across the upper 13 m of the weathering profile during both wet and dry seasons. Instead, vadose zone CO 2 ( g ) "> 2(g) production at the site is dominated by respiration of recently fixed carbon associated with deep rooting. OC p e t r o "> petro is clearly mobilized across the vadose zone during weathering in this rapidly eroding, oxygen-rich, biologically dynamic hillslope, but at rates far below what can be measured given the contribution of root-derived CO 2 ( g ) "> 2(g) .

California

An initial investigation into the organic matter biogeochemistry of the Congo River

The Congo River, which drains pristine tropical forest and savannah and is the second largest exporter of terrestrial carbon to the ocean, was sampled in early 2008 to investigate organic matter (OM) dynamics in this historically understudied river basin. We examined the elemental (%OC, %N, C:N), isotopic (&delta; 13 C, &Delta; 14 C, &delta; 15 N) and biochemical composition (lignin phenols) of coarse particulate (>63 &mu;m; CPOM) and fine particulate (0.7&ndash;63 &mu;m; FPOM) OM and DOC, &delta; 13 C, &Delta; 14 C and lignin phenol composition with respect to dissolved OM (<0.7 &mu;m; DOM) from five sites in the Congo River Basin. At all sample locations the organic carbon load was dominated by the dissolved phase (~82&ndash;89% of total organic carbon) and the total suspended sediment load was principally fine particulate material (~81&ndash;91% fine suspended sediment). Distinct compositional and isotopic differences were observed between all fractions. Congo CPOM, FPOM and DOM all originated from vegetation and soil inputs as evidenced by elemental, isotopic and lignin phenol data, however FPOM was derived from much older carbon pools (mean &Delta; 14 C = -62.2 &plusmn; -13.2&permil;, n = 5) compared to CPOM and DOM (mean &Delta; 14 C = 55.7 &plusmn; 30.6&permil;, n = 4 and 73.4 &plusmn; 16.1&permil;, n = 5 respectively). The modern radiocarbon ages for DOM belie a degraded lignin compositional signature (i.e. elevated acid:aldehyde ratios (Ad:Al) relative to CPOM and FPOM), and indicate that the application of OM degradation patterns derived from particulate phase studies to dissolved samples needs to be reassessed: these elevated ratios are likely attributable to fractionation processes during solubilization of plant material. The relatively low DOM carbon-normalized lignin yields (&Lambda;8; 0.67&ndash;1.12 (mg(100 mg OC) -1 )) could also reflect fractionation processes, however, they have also been interpreted as an indication of significant microbial or algal sources of DOM. CPOM appears to be well preserved higher vascular plant material as evidenced by its modern radiocarbon age, elevated C:N (17.2&ndash;27.1) and &Lambda;8 values (4.56&ndash;7.59 (mg(100 mg OC) -1 )). In relation to CPOM, the aged FPOM fraction (320&ndash;580 ybp 14 C ages) was comparatively degraded, as demonstrated by its nitrogen enrichment (C:N 11.4&ndash;14.3), lower &Lambda;8 (2.80&ndash;4.31 (mg(100 mg OC) -1 )) and elevated lignin Ad:Al values similar to soil derived OM. In this study we observed little modification of the OM signature from sample sites near the cities of Brazzaville and Kinshasa to the head of the estuary (~350 km) highlighting the potential for future studies to assess seasonal and long-term OM dynamics from this logistically feasible location and derive relevant information with respect to OM exported to the Atlantic Ocean. The relative lack of OM data for the Congo River Basin highlights the importance of studies such as this for establishing baselines upon which to gauge future change.

Congo River

A sequential selective dissolution method to quantify storage and stability of organic carbon associated with Al and Fe hydroxide phases

Stabilization of SOM (soil organic matter) is regulated in part by sorption and desorption reactions happening at mineral surfaces, as well as precipitation and dissolution of organo-metal complexes. Fe and Al hydroxides play a particularly significant role in SOM stabilization in soils due to their ubiquitous distribution and their highly reactive surface properties. Iron and Al hydroxides exist in soils across a wide spectrum of crystallinity, ranging from dissolved Fe and Al cations which combine with organics to form organo-metal precipitates to the more crystalline end members, goethite and gibbsite, which sorb SOM through a variety of molecular interactions. Though the importance of these sorption and precipitation reactions has long been recognized, the distribution of SOM among Fe and Al hydroxides of differing crystallinity has not been well quantified, nor has the timescale over which these stabilization mechanisms operate. In an attempt to measure the distribution of organic C among (i) Al- and Fe-humus complexes (ii) short-range-order (SRO) Al and Fe hydroxide surfaces and (iii) crystalline Fe oxyhydroxide surfaces, a single method combining several selective mineral dissolutions was applied to soils of four different geneses (a tropical forest Andisol, a temperate forest basaltic Mollisol, a Mediterranean coastal prairie Mollisol, and a northern mixed hardwood forest Spodosol). The traditional reactants used in selective dissolutions were replaced with carbon-free analogues so that the carbon released along with the Fe and Al at each stage of the selective dissolution process could be measured. Selective dissolutions were performed sequentially: Na-pyrophosphate (organo-Al and Fe complexes) followed by hydroxylamine (SRO Al and Fe hydroxides) followed by dithionite-HCl (crystalline Fe hydroxides). Carbon, Al, and Fe concentrations, as well as radiocarbon abundance were measured in the solutions yielded by each stage of the selective dissolution process. Results suggest that precipitation of organo-metal complexes (Na-pyrophosphate extractable C) often accounts for the largest pool of stabilized C among the three selectively dissolved pools, but these complexes were 14 C enriched in comparison to C from the other selectively dissolved pools and the residual C left on crystalline mineral surfaces after all three stages of selective dissolution. Hydroxylamine and dithionite-HCl extractable C pools were, on average, small and often below detection level in temperate soils. However, radiocarbon values for these C pools were generally depleted in comparison to other pools. These results suggest variation in organo-mineral complex stability is associated with degree of crystallinity of the mineral phase. Overall, this work suggests that sequential selective dissolution methods are a promising tool for characterizing the content and isotopic composition of soil C associated with distinct organo-mineral and organo-metal associations.

Geoderma

Uptake and distribution of organo-iodine in deep-sea corals

Understanding iodine concentration, transport, and bioavailability is essential in evaluating iodine's impact to the environment and its effectiveness as an environmental biogeotracer. While iodine and its radionuclides have proven to be important tracers in geologic and biologic studies, little is known about transport of this element to the deep sea and subsequent uptake in deep-sea coral habitats. Results presented here on deep-sea black coral iodine speciation and iodine isotope variability provides key information on iodine behavior in natural and anthropogenic environments, and its geochemical pathway in the Gulf of Mexico. Organo-iodine is the dominant iodine species in the black corals, demonstrating that binding of iodine to organic matter plays an important role in the transport and transfer of iodine to the deep-sea corals. The identification of growth bands captured in high-resolution scanning electron images (SEM) with synchronous peaks in iodine variability suggest that riverine delivery of terrestrial-derived organo-iodine is the most plausible explanation to account for annual periodicity in the deep-sea coral geochemistry. Whereas previous studies have suggested the presence of annual growth rings in deep-sea corals, this present study provides a mechanism to explain the formation of annual growth bands. Furthermore, deep-sea coral ages based on iodine peak counts agree well with those ages derived from radiocarbon ( 14 C) measurements. These results hold promise for developing chronologies independent of 14 C dating, which is an essential component in constraining reservoir ages and using radiocarbon as a tracer of ocean circulation. Furthermore, the presence of enriched 129 I/ 127 I ratios during the most recent period of skeleton growth is linked to nuclear weapons testing during the 1960s. The sensitivity of the coral skeleton to record changes in surface water 129 I composition provides further evidence that iodine composition and isotope variability captured in proteinaceous deep-sea corals is a promising geochronometer as well as an emerging tracer for continental material flux.

Journal of Environmental Radioactivity

Subaqueous clinoforms created by sandy wave-supported gravity flows: Lessons from the central California shelf

Subaqueous clinoforms are an important yet underappreciated shelf feature. Their origins are typically associated with subaerial deltas but recent work has identified similar features in settings without a significant fluvial source. These other studies have shown that such subaqueous clinoforms, also known as infralittoral prograding wedges (IPWs), are created largely by wave-induced processes. This study uses geophysical, sedimentological, and radiocarbon data to determine the sedimentary characteristics and genesis of a shore-parallel subaqueous clinoform developed far from any significant river on the central California continental shelf; a feature known locally as the Cross Hosgri Slope. Sediment cores through the feature reveal that it is composed of beds with an erosive base, followed by a thin coarsening upward sequence of shelly fine sands transitioning to a fining upward sequence marked by alternating parallel and ripple cross laminated very fine sands. The deposit is often capped by fine silts that are commonly interbedded with thin very fine sand beds. Radiocarbon dating of shells within the cores paired with seismic profiles indicate the subaqueous clinoform initiated progradation ~7 ka, nucleating on an older Younger Dryas relict shoreface. We suggest the CHS was created by winter-storm waves mobilizing sands in water depths up to ~ 70 m that transitioned into wave-supported gravity flows. The wave-supported gravity flows traveled downslope to water depths of up to ~85 m, corresponding to the foot of the subaqueous clinoform. They did not travel beyond this depth as wave influence at these depths is negligible and the shelf slope is insufficient to maintain movement of the load alone. Our work suggests that wave-supported gravity flows can entrain very fine sands and silts and build subaqueous clinoforms, even in the absence of a significant river source. Furthermore, we provide a facies model for sandy wave-supported gravity flow deposits.

California

Stratigraphy and chronology of offshore to nearshore deposits associated with the Provo shoreline, Pleistocene Lake Bonneville, Utah

Stratigraphic descriptions and radiocarbon data from eleven field locations are presented in this paper to establish a chronostratigraphic framework for offshore to nearshore deposits of Lake Bonneville. Based on key marker beds and geomorphic position, the deposits are interpreted to have accumulated during the period from the late transgressive phase, through the overflowing phase, into the regressive phase of the lake. Radiocarbon ages of sediments associated with the Provo shoreline indicate that Lake Bonneville dropped rapidly from the Provo shoreline at about 12,600 14 C yr BP (15,000 cal yr B.P.). The presence of one or more sand beds in the upper part of the Provo-aged marl indicates rapid lowering of lake level or storm events at the end of the Provo episode. An accurate understanding of the timing and nature of Lake Bonneville's climate-driven regression from the Provo shoreline is critical to correlations with records of regional and hemispheric climate change. The rapid descent of the lake from the Provo shoreline correlates with the decline of Lakes Lahontan and Estancia, and with the onset of the B Ø lling–Aller Ø d warming event.

Utah

Age model for a continuous, ca 250-ka Quaternary lacustrine record from Bear Lake, Utah-Idaho

The Quaternary sediments sampled by continuous 120-m-long drill cores from Bear Lake (Utah-Idaho) comprise one of the longest lacustrine sequences recovered from an extant lake. The cores serve as a good case study for the construction of an age model for sequences that extend beyond the range of radiocarbon dating. From a variety of potential age indicators, we selected a combination of radiocarbon ages, one magnetic excursion (correlated to a standard sequence), and a single Uranium-series age to develop an initial data set. The reliability of the excursion and U-series data require consideration of their position with respect to sediments of inferred interglacial character, but not direct correlation with other paleoclimate records. Data omitted from the age model include amino acid age estimates, which have a large amount of scatter, and tephrochronology correlations, which have relatively large uncertainties. Because the initial data set was restricted to the upper half of the BL00-1 core, we inferred additional ages by direct correlation to the independently dated paleoclimate record from Devils Hole. We developed an age model for the entire core using statistical methods that consider both the uncertainties of the original data and that of the curve-fitting process, with a combination of our initial data set and the climate correlations as control points. This age model represents our best estimate of the chronology of deposition in Bear Lake. Because the age model contains assumptions about the correlation of Bear Lake to other climate records, the model cannot be used to address some paleoclimate questions, such as phase relationships with other areas.

Idaho, Utah

Late Pleistocene glaciation of the Mt Giluwe volcano, Papua New Guinea

The Mt Giluwe shield volcano was the largest area glaciated in Papua New Guinea during the Pleistocene. Despite minimal cooling of the sea surface during the last glacial maximum, glaciers reached elevations as low as 3200 m. To investigate changes in the extent of ice through time we have re-mapped evidence for glaciation on the southwest flank of Mt Giluwe. We find that an ice cap has formed on the flanks of the mountain on at least three, and probably four, separate occasions. To constrain the ages of these glaciations we present 39 new cosmogenic 36 Cl exposure ages complemented by new radiocarbon dates. Direct dating of the moraines identifies that the maximum extent of glaciation on the mountain was not during the last glacial maximum as previously thought. In conjunction with existing potassium/argon and radiocarbon dating, we recognise four distinct glacial periods between 293–306 ka (Gogon Glaciation), 136–158 ka (Mengane Glaciation), centred at 62 ka (Komia Glaciation) and from >20.3–11.5 ka (Tongo Glaciation). The temperature difference relative to the present during the Tongo Glaciation is likely to be of the order of at least 5 °C which is a minimum difference for the previous glaciations. During the Tongo Glaciation, ice was briefly at its maximum for less than 1000 years, but stayed near maximum levels for nearly 4000 years, until about 15.4 ka. Over the next 4000 years there was more rapid retreat with ice free conditions by the early Holocene.

Quaternary Science Reviews

Late Quaternary chronostratigraphic framework of terraces and alluvium along the lower Ohio River, southwestern Indiana and western Kentucky, USA

The lower Ohio River valley is a terraced fluvial landscape that has been profoundly influenced by Quaternary climate change and glaciation. A modern Quaternary chronostratigraphic framework was developed for the lower Ohio River valley using optically stimulated luminescence (OSL) dating and allostratigraphic mapping to gain insights into the nature of fluvial responses to glacial&ndash;interglacial/stadial&ndash;interstadial transitions and Holocene climate change. River deposits, T0 (youngest) to T7 (oldest), were mapped along a 75 km reach of the lower Ohio River and were dated using 46 OSL and 5 radiocarbon samples. The examination of cores combined with OSL and radiocarbon dating shows that fluvial sediments older than marine oxygen isotope stage (MIS) 2 are present only in the subsurface. Aggradation during MIS 6 (Illinoian glaciation) filled the valley to within &sim;7 m of the modern floodplain, and by &sim;114 ka (MIS 5e/Sangamon interglacial) the Ohio River had scoured the MIS 6 sediments to &sim;22 m below the modern floodplain surface. There were no fluvial sediments in the valley with ages between MIS 5e and the middle of MIS 3. The MIS 3 ages (&sim;39 ka) and stratigraphic position of T5 deposits suggest the Ohio River aggraded 8&ndash;14 m during MIS 4 or MIS 3. Near the end of MIS 3, the Ohio River incised the mid Last Glacial (mid-Wisconsinan) deposits &sim;10 m and began aggrading again by &sim;30 ka. Aggradation continued into MIS 2, with maximum MIS 2 aggradation occurring before &sim;21 ka, which is coincident with the global Last Glacial Maximum (LGM). As the Ohio River adjusted to changing fluxes in sediment load and discharge following the LGM, it formed a sequence of fill-cut terraces in the MIS 2 outwash that get progressively younger with decreasing elevation, ranging in age from &sim;21 ka to &sim;13 ka. From &sim;14 ka to &sim;13 ka the Ohio River rapidly incised &sim;3 m to form a new terrace, and by &sim;12 ka at the onset of the Holocene, the Ohio River established a meandering channel pattern. The river formed a broad floodplain surface from &sim;12 ka to &sim;6 ka, and then incised &sim;1 m and formed a fill-cut terrace from &sim;6 ka to &sim;5 ka. After &sim;5 ka, likely in response to mid-Holocene drought in North America, the Ohio River incised &sim;5 m, and by &sim;4 ka the river began aggrading again. The Ohio River has aggraded &sim;4 m since aggradation began at &sim;4 ka. The chronostratigraphic framework and reconstructed history developed here suggest that the lower Ohio River is highly sensitive to glacial&ndash;interglacial transitions and abrupt Holocene climate change and responds rapidly to these allogenic forcings.

Indiana, Kentucky

Late Quaternary glaciation of the Upper Soca River Region (Southern Julian Alps, NW Slovenia)

Extent of Late Quaternary glaciers in the Upper Soc??a River Region (Southern Julian Alps, SE Europe) has been analyzed using a combination of geological mapping, glaciological modeling, and sediment dating (radiocarbon, U/Th series and Infrared Stimulated Luminescence-IRSL). Field investigations focused mainly on relatively well preserved Quaternary sequences in the Bovec Basin, an intramontane basin located SW of the Mediterranean/Black Sea divide and surrounded by mountain peaks reaching from approximately 2100 up to 2587 m a.s.l. Within the Basin we recognized two Late Quaternary sedimentary assemblages, which consist of the same facies association of diamictons, laminated lacustrine deposits and sorted fluvial sediments. Radiocarbon dating of the upper part of the lake sediments sequence (between 12790??85 and 5885??60 14C years b.p.) indicates that the younger sedimentary assemblage was deposited during the last glacial maximum and through early Holocene (Marine Isotope Stage 21, MIS 2-1). Sediment ages obtained for the older assemblage with U/Th and IRSL techniques (between 154.74??22.88 and 129.93??7.90 ka b.p. for selected samples) have large errors but both methods yield results consistent with deposition during the penultimate glacial-interglacial transition (MIS 6-5). Based on analyses of field data combined with glaciological modeling, we argue that both sediment complexes formed due to high sediment productivity spurred by paraglacial conditions with glaciers present in the uplands around the Bovec Basin but not extending down to the basin floor. Our study shows that the extent and intensity of direct glacial sedimentation by Late Quaternary glaciers in the region was previously significantly overestimated. ?? 2004 Elsevier B.V. All rights reserved.

Sedimentary Geology

Geochronology and paleoenvironment of pluvial Harper Lake, Mojave Desert, California, USA

Accurate reconstruction of the paleo-Mojave River and pluvial lake (Harper, Manix, Cronese, and Mojave) system of southern California is critical to understanding paleoclimate and the North American polar jet stream position over the last 500 ka. Previous studies inferred a polar jet stream south of 35°N at 18 ka and at ~ 40°N at 17–14 ka. Highstand sediments of Harper Lake, the upstream-most pluvial lake along the Mojave River, have yielded uncalibrated radiocarbon ages ranging from 24,000 to > 30,000 14 C yr BP. Based on geologic mapping, radiocarbon and optically stimulated luminescence dating, we infer a ~ 45–40 ka age for the Harper Lake highstand sediments. Combining the Harper Lake highstand with other Great Basin pluvial lake/spring and marine climate records, we infer that the North American polar jet stream was south of 35°N about 45–40 ka, but shifted to 40°N by ~ 35 ka. Ostracodes ( Limnocythere ceriotuberosa ) from Harper Lake highstand sediments are consistent with an alkaline lake environment that received seasonal inflow from the Mojave River, thus confirming the lake was fed by the Mojave River. The ~ 45–40 ka highstand at Harper Lake coincides with a shallowing interval at downstream Lake Manix.

California

An updated Holocene sea-level curve for the Delaware coast

We present an updated Holocene sea-level curve for the Delaware coast based on new calibrations of 16 previously published radiocarbon dates (Kraft, 1976; Belknap and Kraft, 1977) and 22 new radiocarbon dates of basal peat deposits. A review of published and unpublished 137Cs and 210Pb analyses, and tide gauge data provide the basis for evaluating shorter-term (102 yr) sea-level trends. Paleosea-level elevations for the new basal peat samples were determined from the present vertical zonation of marsh plants relative to mean high water along the Delaware coast and the composition of plant fossils and foraminifera. Current trends in tidal range along the Delaware coast were used to reduce elevations from different locations to a common vertical datum of mean high water at Breakwater Harbor, Delaware. The updated curve is similar to Belknap and Kraft's [J. Sediment. Petrol., 47 (1977) 610-629] original sea-level curve from 12,000 to about 2000 yr BP. The updated curve documents a rate of sea-level rise of 0.9 mm/yr from 1250 yr BP to present (based on 11 dates), in good agreement with other recent sea-level curves from the northern and central U.S. Atlantic coast, while the previous curve documents rates of about 1.3 mm/yr (based on 4 dates). The precision of both estimates, however, is very low, so the significance of these differences is uncertain. A review of 210Pb and 137Cs analyses from salt marshes of Delaware indicates average marsh accretion rates of 3 mm/yr for the last 100 yr, in good agreement with shorter-term estimates of sea-level rise from tide gauge records. ?? 2000 Elsevier Science B.V.

Marine Geology

Chlorine-36 and 14C chronology support a limited last glacial maximum across central Chukotka, northeastern Siberia, and no Beringian ice sheet

The Pekulney Mountains and adjacent Tanyurer River valley are key regions for examining the nature of glaciation across much of northeast Russia. Twelve new cosmogenic isotope ages and 14 new radiocarbon ages in concert with morphometric analyses and terrace stratigraphy constrain the timing of glaciation in this region of central Chukotka. The Sartan Glaciation (Last Glacial Maximum) was limited in extent in the Pekulney Mountains and dates to ???20,000 yr ago. Cosmogenic isotope ages > 30,000 yr as well as non-finite radiocarbon ages imply an estimated age no younger than the Zyryan Glaciation (early Wisconsinan) for large sets of moraines found in the central Tanyurer Valley. Slope angles on these loess-mantled ridges are less than a few degrees and crest widths are an order of magnitude greater than those found on the younger Sartan moraines. The most extensive moraines in the lower Tanyurer Valley are most subdued implying an even older, probable middle Pleistocene age. This research provides direct field evidence against Grosswald's Beringian ice-sheet hypothesis. ?? 2003 Elsevier Science (USA). All rights reserved.

Quaternary Research

Quaternary glacial, lacustrine, and fluvial interactions in the western Noatak basin, Northwest Alaska

The 130 km long Noatak basin is surrounded by mountains of the western Brooks Range. Middle and late Pleistocene glaciers flowing southeast into the basin dammed a succession of proglacial lakes defined by shorelines, outlet channels, and upper limits of wave erosion. More than 60 bluffs along the Noatak River and its principal tributaries expose glacial and glaciolacustrine sediments that exhibit cut-and-fill relationships with interglacial and interstadial river-channel and floodplain deposits. This report focuses on the western Noatak basin, where high bluffs created by deep postglacial erosion record four major glacial advances. During the Cutler advance, a floating ice tongue terminated in a large proglacial lake that filled the Noatak basin. The retreating glacier abandoned a trough along the valley center that subsequently filled with about 40 m of sediment during several younger glaciations and probably two major interglacial episodes. Alluvium that formed near the beginning of the younger interglaciation contains the 140,000 yr old Old Crow tephra. The subsequent closely spaced Okak and Makpik advances are clearly younger than the maximum of the last interglaciation, but they preceded a middle Wisconsin (36-30 ka) nonglacial interval in the Noatak basin. The Okak advance terminated in an extensive lake, whereas glaciers of the Makpik and the subsequent Anisak advances flowed into much narrower lakes that filled only the basin center. The Anisak advance, bracketed by radiocarbon ages of about 35 and 13.6 ka, represents the Last Glacial Maximum (LGM) in the western Noatak basin. Correlations with the oldest and youngest glacial deposits of the central Brooks Range are clear, but relationships to events of intermediate age are more tenuous. Early Pleistocene and older glacial advances from the central Brooks Range must have filled the Noatak basin and overflowed northward through Howard Pass. A younger glacial advance, of inferred middle Pleistocene (Sagavanirktok River) age, extended down the Noatak valley into the basin center, but its deposits are deeply buried beneath the basin floor and must be older than the Cutler moraine. The Cutler advance may have been synchronous with the older of two advances of Itkillik I age in the Atongarak Creek area, but other evidence indicates that the Okak-Makpik moraine succession more likely was synchronous with the two Atongarak Creek moraines. Radiocarbon ages, surface morphology, soil and weathering profiles, and lake-level history all support correlation of the last (Anisak) major glacial advance in the western basin with the Douglas Creek moraine farther east and with Itkillik II (late Wisconsin) glaciation of the central Brooks Range.

Alaska