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Prioritizing US Geological Survey science on salinization and salinity in candidate and selected priority river basins

The US Geological Survey (USGS) is selecting and prioritizing basins, known as Integrated Water Science basins, for monitoring and intensive study. Previous efforts to aid in this selection process include a scientifically defensible and quantitative assessment of basins facing human-caused water resource challenges (Van Metre et al. in Environmental Monitoring and Assessment , 192(7), 458 2020). In the present work, we explore this ranking process based on water quality considerations, specifically salinity and salinization. We selected top candidate basins to study salinity and salinization issues in 18 hydrologic regions that include 163 candidate basins. Our prioritization is based on quantitative assessment of sources of salinity, drivers of change, and receptors that must respond to those sources and drivers. Source terms represented in the prioritization include geology, depth to brackish groundwater, stream conductivity, chloride in precipitation, urban and agricultural land use, application of road salt as a deicer, and irrigation. Drivers represented in prioritization include changes in chemical weathering as a result of changes in rainwater chemistry. Receptors include measures of water stress, measurements of stream ecological health, and socioeconomic factors. In addition, we present research activities for the USGS on salinity and salinization that can be pursued in these basins including assessment of sources, pathways, and loadings; predicting and understanding changes in sources, peaks, and trends; understanding the components of salinity and mobilization of contaminants; understanding the relationship between salinization and changing ecosystems; and developing knowledge on the causes and distribution of groundwater salinity, brackish water resources, and challenges related to desalination.

Enviornmental Monitoring and Assessment

A time-space model of graphite mineral systems

Increasing demand for graphite in energy storage systems warrants review of graphite ore genesis in a mineral systems framework. Orogenic graphite encompasses the metamorphic and orogenic mineral systems that produce flake graphite and hydrothermal vein (lump and chip) graphite deposits, respectively. A common feature of orogenic graphite deposits is an association with upper amphibolite- to granulite-facies metasedimentary rocks in continent-continent or continent-island arc collisional orogens. Orogenic flake graphite deposits form primarily through graphitization of organic carbon during regional metamorphism, but strain localization and partial melting of pelitic protoliths are likely important processes for graphite grade and quality enrichment. Orogenic vein graphite deposits precipitate from hydrothermal fluids, possibly derived from metamorphism or anatexis at depth. Decarbonation reactions in mixed calcareous-carbonaceous metasedimentary sequences are the most likely carbon sources for the veins. In contrast, intrusion-related graphite includes magmatic-hydrothermal and metamorphic mineral systems that form primarily in continental arc settings via the interaction of magmas with carbonaceous sedimentary packages. Magmatic-hydrothermal flake graphite deposits are hosted in plutonic and volcanic rocks, and result from the exsolution of CO 2 -CH 4 -rich fluids from melts contaminated by such packages. Contact metamorphism of carbonaceous sedimentary rocks by plutons produces some microcrystalline (amorphous) graphite deposits, including many in China. Compilation of geologic data from known graphite deposits globally suggests that pulses of carbon deposition in the Paleoproterozoic, Mesoproterozoic, and Neoproterozoic provided source carbon material. Subsequent supercontinent orogenesis at ca. 2,100 to 1,700 Ma (Columbia), ca. 1,300 to 1,000 Ma (Rodinia), and ca. 650 to 500 Ma (Gondwana) resulted in the genesis of orogenic flake and vein graphite deposits, where favorable geologic components overlapped with organic ± carbonate carbon-rich strata. Cryogenian deposition of graphite protoliths and Cryogenian – Cambrian metamorphic mineralization account for nearly 75% of all known resources globally and coincide with profound carbon isotope excursions and climate variability, implying a link with the global carbon budget. Comparatively few graphite deposits are associated with Pangea-forming orogens, attributed to less exhumation and/or denudation. High-temperature metasedimentary belts containing organic carbon-rich protoliths are most favorable for hosting orogenic flake graphite deposits, whereas sequences that also contain carbonate protoliths are favorable for orogenic graphite veins. Continent-scale orogenic belts may host both deposit types along with vanadium deposits. Use of a time-space mineral systems framework for graphite deposits can improve exploration models needed to ensure future supply of this critical mineral and provide insights into Earth’s long-term carbon cycle.

Mineralium Deposita

Reaction kinetics and accelerant effects of sulfides in early mature hydrocarbon generation using hydrous pyrolysis

Hydrocarbon generation in organic-rich sediments is influenced by the molecular organic composition and relative abundance of associated minerals. Certain mineral-derived elements act as catalysts and reaction intermediaries, facilitating early-stage hydrocarbon formation in potential source rocks. This study investigated the role of sulfur contributed from pyrite as an accelerant in thermal reaction, focusing on its effects on early maturation and consequent hydrocarbon generation from gilsonite (low-sulfur solid petroleum). Hydrous pyrolysis (HP) experiments were conducted on mixtures of gilsonite and pyrite in varying ratios (1:0.1, 1:0.5, 1:1, 1:2, and 1:10 w/w gilsonite:pyrite) at 320, 350, and 370 °C for 72 h. Untreated and thermally altered residues were analyzed using solid bitumen reflectance (BR o , %), total organic carbon (TOC) content, programmed temperature pyrolysis, scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS), and X-ray diffraction (XRD) to evaluate the potential accelerant role of pyritic sulfur in hydrocarbon formation. The results show HP residues at 320 and 350 °C with greater pyrite concentrations had higher BR o , while reflectance values were similar in the 370 °C residues, regardless of pyrite concentration, suggesting enhanced reaction at lower thermal conditions. Increasing pyrite content systematically decreased hydrogen index (HI) values while increasing the transformation ratio (TR) and production index (PI), indicating enhanced conversion of organic matter to hydrocarbons with increasing pyrite concentrations. Gas yields increased with pyrite addition, particularly at 350 °C, confirming secondary cracking effects. However, gas production stabilized or declined at higher pyrite loadings (1:10), suggesting alternative reaction pathways such as coke formation. Our data indicate the presence of pyrite lowers the activation energy for thermal cracking, shifting peak experimental hydrocarbon generation temperatures downward by 20–30 °C, with the most pronounced accelerant effects observed at moderate pyrite concentrations (1:0.5 and 1:1). The thermodynamic framework reveals that pyrite stability is influenced by experimental conditions, with pyrrhotite formation favored in the presence of gilsonite due to reduced oxygen fugacity. Pyrite transformation to pyrrhotite, as observed through XRD, SEM-EDS, and predicted by thermodynamic data, further supports the accelerant role of S, as pyrrhotite exhibits a higher hydrogen transfer potential, promoting early oil generation. These findings highlight the importance of pyrite in modulating hydrocarbon generation pathways in organic-rich systems.

Journal of Analytical and Applied Pyrolysis

Modeling interconnected minerals markets with multicommodity supply curves: Examining the copper-cobalt-nickel system

Demand for many of the metals used in the energy transition is expected to grow rapidly. Many of these are by-products, often considered critical because their production responds weakly to prices and is instead tied to the economics of the host mineral. We present a model of prices and production for jointly produced commodities that accounts for interconnectivity between host and by-product markets at the mine level. We demonstrate this method using the copper–cobalt–nickel system, in which approximately 99% of cobalt is a by-product of copper or nickel mining. Our results show that the model more accurately captures the economic benefits of diversified mine outputs than previous approaches. Furthermore, changes in demand drivers for any two commodities produce non-linear effects on production and price. We challenge the prior best-practice assumption that cobalt cannot impact the copper or nickel markets. Recognizing the importance of both copper and cobalt for future electrification, we emphasize that incentivizing the copper industry to reduce cobalt supply risks could inadvertently undermine copper supply.

Nature Communications

Introduction to the special section on improving measurements of earthquake source parameters

Earthquake source parameters such as magnitude, seismic moment, source dimension, stress drop, and radiated energy are fundamental to understanding earthquake physics, and are also key ingredients in earthquake ground‐motion modeling, rupture simulation, and statistical seismology. However, the uncertainties in these parameters estimated from the radiated seismic wavefield are large due to variability in approaches, including site and attenuation characterizations, and so estimates for an individual earthquake made by different studies can vary greatly. Estimating spectral source parameters remains a popular topic, due to a combination of their intrinsic importance and their apparent ease of measurement, but also a controversial one, due to many sources of variability and large uncertainty. The available methods coupled with necessary parameter choices and assumptions in the analysis make it challenging for researchers to apply methods or understand the reliability in results or reported source parameters. This Special Section on Improving Measurements of Earthquake Source Parameters showcasing comparisons between methods and studies seeks to alleviate some of these difficulties to help the community identify the important components and trade‐offs of decomposing recorded seismograms into their source, path, and site components.

Bulletin of the Seismological Society of America

Summary of annual repeat magnetotelluric surveys of the Geysers geothermal field

As part of a multi-year project, funded by the California Energy Commission, annual magnetotelluric (MT) surveys have been collected at The Geysers geothermal field in northern California with the goal of measuring temporal changes within the steam field. The repeat surveys started in 2021 and repeated a 2017 survey (Peacock et al., 2020) with further extension to the southern part of the geothermal field. Temporal variations in the MT transfer functions are observed to be spatially coherent and compartmentalized. Mapping residual phase tensor ellipses demonstrates the direction of maximum change is often aligned with existing fracture orientations. Three dimensional inversion of the MT data, using the inversion results from previous years as the starting model, indicates that the steam reservoir has generally become more resistive over time (~10%), suggesting more steam in the field. A few pockets within the steam field have become more electrically conductive over time and are collocated with injection wells, suggesting either more fluid content in those zones, less steam, or more saline fluids.

California

Geochemistry of quartz and fluid inclusions associated with gold, tungsten, and antimony in the Stibnite-Yellow Pine district, Idaho

Deposits in the historic Stibnite-Yellow Pine district in east-central Idaho were mined for Ag, Au, Hg, Sb, and W. Ore is hosted in breccia and fault zones along NE-striking faults that transect the Atlanta lobe of the Late Cretaceous Idaho batholith and metamorphosed Neoproterozoic to lower Paleozoic rocks. Geochronological studies have delineated five superimposed and zoned hydrothermal events in the mining district which range in age from Late Cretaceous to the Eocene. They formed the following consecutive assemblages: (1) vein and disseminated pre-ore milky quartz (± calcite), muscovite, and brassy pyrite with minor molybdenite and base metal sulfides; (2) vein and disseminated quartz, calcite, sericite, auriferous-pyrite, and arsenopyrite; (3) potassium feldspar, quartz, dolomite, and calcite with vein and disseminated scheelite ± pyrite and arsenopyrite; (4) Au-Ag veins that contain adularia; and (5) breccia, vein, and disseminated quartz, calcite, and stibnite with minor Ag sulfosalts and distal zones of cinnabar and realgar at Fern and Hermes mines. In this study, the pressure, temperature, and composition of ore-forming fluids were measured in Au-, W-, and Sb-bearing samples collected from drill core and surface exposures. Using optical petrography, scanning electron microscopy cathodoluminescence (SEM-CL) and electron microprobe cathodoluminescence (EMPA-CL) imaging, as well as electron microprobe (EMP) and laser ablation-inductively coupled plasma-mass spectrometry trace element analyses, four major overprinting generations of hydrothermal quartz are defined. Fluid inclusion assemblages (FIAs) in each generation of quartz were characterized by microthermometry and laser Raman spectroscopy. Quartz and fluid inclusion paragenesis are as follows: (Qi) altered and overprinted Qi with no coeval FIAs that formed before or during event 1; (Q1) early veins as well as disseminated quartz with dull gray SEM-CL and H 2 O-NaCl-CO 2 FIAs that formed at minimum temperatures and pressures of 281° to 358°C and 1346 to 1789 bar during event 2 (Au); (Q2) vein and disseminated quartz, often euhedral, with H 2 O-NaCl ± CO 2 ± CH 4 FIAs that formed at minimum temperatures and pressures of 183° to 213°C and 72 to 602 bar during event 3 (W); and (Q3) euhedral and disseminated quartz with H 2 O-NaCl FIAs that formed at minimum temperature and pressures of 156° to 161°C and 5 to 6 bar during event 5 (Sb). Stibnite hosts H 2 O-NaCl FIAs trapped at minimum temperatures and pressures of 150° to 189°C and 5 to 12 bar that are similar to those of Q3-hosted FIAs. The quartz paragenetic history in the district follows a progressive temporal path from Tienriched quartz deposited by a relatively deep and higher temperature aqueous-carbonic fluid to a Li, Al, and Sb enriched quartz precipitated from a lower temperature aqueous fluid. Gases in fluid inclusion extracts from ore and gangue minerals were analyzed by mass spectrometry. Noble gas isotope analysis of fluid inclusion extracts revealed three signatures. Pre-ore Qi has R/R A (the isotopic ratio of the sample 3 He/ 4 He to atmospheric 3 He/ 4 He (1.384 × 10 −6 )) values that reflect the composition of the crustal melt-derived Atlanta lobe of the Idaho batholith. Quartz (Q1) and auriferous arsenian pyrite of hydrothermal event 2 have 20 Ne/ 4 He and R/R A values that plot along the air-crust mixing line, and these gases were likely introduced by metamorphic fluids derived from metasedimentary rocks. Stibnite with associated quartz (Q3 ± Q2) have 20 Ne/ 4 He and R/R A values that extend from the air-crust mixing line to the air-mantle mixing line, showing a shift from a crustal signature to an overprinting mantle signature. Late calcite has 20 Ne/ 4 He and R/R A values that extend from air toward the mantle end member, which suggests that magmatic volatiles condensed into meteoric groundwater late in the paragenesis. A mantle volatile source is also supported by high 20 Ne/ 22 Ne ratios. The Stibnite-Yellow Pine district is similar to other Au-W-Sb districts around the world in ore fluid chemistries, with late-stage stibnite being a product of cooling. The fluid pressure-temperature-composition (P-T-X) estimates and the crustal source of He during hydrothermal event 2 gold mineralization are characteristic of orogenic Au deposits, and the observed inclusion reequilibration textures indicate that trapped fluid inclusions were deformed during transitions between the brittle-ductile environment. Scheelite was deposited during event 3 with Q2 quartz and is overgrown by Q3 quartz and stibnite. Our interpretation of the quartz texture, chemistry, and fluid inclusion P-T-X data suggest that Au, W, and Sb mineralization occurred as hydrothermal fluids evolved from H 2 O-NaCl-CO 2 at >300°C and depths of ~4 to 6 km near the ductile to brittle transition to H 2 O-NaCl at ~150°C and epithermal depths as the Idaho batholith was exhumed. Geochronology indicates that from the Late Cretaceous to early Eocene, overprinting hydrothermal events formed deep orogenic Au, intermediate W, and shallow epithermal Au-Ag and Sb. Without comprehensive geochronologic constraints, our fluid inclusion data and textural observations could be interpreted as a single evolving hydrothermal system, as has been done in many other mining districts with similar mineralization.

Idaho

Upper crustal seismic velocity structure of the Hayward fault zone, San Francisco Bay, California, USA: Results from the 2016 East Bay Seismic Experiment (EBSI-16)

We developed Vp, Vs, Vp / Vs ratio, and Poisson’s ratio models of the uppermost crust (<4 km depth) from the eastern San Francisco (SF) Bay (California, USA) to near the Calaveras fault along a 15-km-long, linear profile. Upper crustal velocities are highly variable beneath, west, and well east of the Hayward fault. We observe eight notable features, from west to east: (1) Near San Francisco Bay, there is an ~2-km-wide structure with high Vp / Vs ratios (up to 5) and Poisson’s ratios (up to 0.48) extending from the surface to the base of our model, which we suggest the structure is a near-vertical fault that lies along a straight-line projection between the Silver Creek fault to the south and the Point Richmond fault to the north. The structure may be part of an ~90-km-long fault along the eastern SF Bay. (2) The western East Bay Plain, the lower lying area between the bay and the hills, includes up to 800 m of low-velocity sediments ( Vp ~1600–3000 m/s, Vs ~500 m/s to ~1000 m/s), underlain by higher velocity basement rocks ( Vp ~3000–5800 m/s; Vs ~1000–1500 m/s). (3) Between ~1 km and 3 km east of the Bay shoreline, sediments thin in a series of steps (likely faults) toward the Hayward fault. (4) Between ~3 km west and ~1 km east of the Hayward fault (at the East Chabot fault) at depths greater than 1 km, basement Vp (up to 6000 m/s) and Vs (up to 2800 m/s) are high, and Vp / Vs ratios (<2) and Poisson’s ratios (<0.3) are low, suggesting crystalline rocks. Furthermore, a near-vertical zone of low Vp / Vs ratios and Poisson’s ratios is between near-surface traces of the Hayward and East Chabot faults, likely corresponding to the San Leandro Gabbro of Ponce et al. (2003) . (5) Eastward of the East Chabot fault in the upper 1.5 km, basement Vp (~3000 m/s to ~4200 m/s) and Vs (~1200–2000 m/s) are lower than those west of the fault. (6) In the eastern Hayward/Oakland Hills, there are zones of laterally varying, high- and low-velocity ( Vp ~2500–3000 m/s) Jurassic–Cretaceous and Tertiary sediments in the shallow subsurface that likely extend much deeper than imaged. (7) Seismic energy that propagates westward from sources east of the Hayward fault (HF) appear weaker than energy that propagates eastward from sources west of the HF, suggesting that the HF acts as a partial barrier to shallow seismic energy propagation into the more populated eastern SF Bay area. (8) Unlike many fault zones, it appears that the active trace of the Hayward fault (in our study area) is not cored by a prominent, low-velocity zone relative to rocks to the east and west of the active trace. However, the active trace does mark a prominent change from relatively higher velocities to the west and lower velocities to the east.

California

Effects of human activity on Khumbu Glacier: Towards a sustainable Everest Base Camp

The Everest Base Camp (EBC), a critical staging area for mountaineers attempting to summit Mount Everest, has seen a significant increase in human activity over the past few decades. The increasing number of climbers, trekkers, and support staff, particularly at the campsite area, has intensified environmental impacts on the Khumbu Glacier. This study investigates the effects of human activity at EBC, focusing on three contributors to glacier melt: global climate change, local fossil fuel consumption, and human urinary discharge. Through field data collected during the spring 2023 climbing season, this study examines the energy released through the use of liquefied petroleum gas (LPG), kerosene, and petrol for cooking, heating, and electricity, as well as the heat generated by human urinary discharge. The total heat energy released from these activities at EBC in the spring of 2023 was 849,174 ± 179,774 MJ, which would be sufficient to melt 2492 ± 528 tons of glacier ice and snow. Trends in land surface temperature at EBC and adjacent environments during the 1991–2023 period were calculated from Landsat 5, 7, and 9 satellite data. The 32-year Landsat record reveals that EBC surface temperature increased by 0.28 °C year −1 , which was roughly twice the rate of warming at the surface of Khumbu Glacier adjacent to EBC and about 15% higher than the temperature increase of the debris-covered terrain immediately to the north of EBC. The findings suggest that addressing these anthropogenic influences could help to preserve the Khumbu Glacier and support the sustainability of mountaineering in the region. This paper also takes a transformative approach and explores stable and safer locations in case there is a necessity to relocate the current EBC. Two sites have been identified southwest of the existing EBC, which, unlike the current supraglacial site, are situated on stable ground.

Everest Base Camp, Khumbu Glacier

Geologic input databases for the 2025 Puerto Rico – U.S. Virgin Islands National Seismic Hazard Model update: Crustal faults component

The last National Seismic Hazard Model (NSHM) for Puerto Rico and the U.S. Virgin Islands (PRVI) was published in 2003. In advance of the 2025 PRVI NSHM update, we created three geologic input databases to summarize new onshore and offshore fault source information in the northern Caribbean region between 62°–70° W and 16°–21° N. These databases, of fault sections, fault‐zone polygons, and geologic estimates of fault activity (fault‐slip rate and earthquake recurrence intervals) at specific sites, document updates to fault parameters used in prior seismic hazard models in PRVI. Fault sources were reviewed from published studies since 2003, which document substantial changes to the understanding of fault location, geometry, or activity. New fault section sources were added for features that meet the criteria of (1) length ≥7 km, (2) unequivocal evidence of recurrent tectonic Quaternary activity, and (3) documentation that is publicly available in a peer‐reviewed source. In addition, we revised several broad areal sources, such as the Mona and Anegada extensional zones. The 2003 model included three fault sections and two fault‐zone polygons (areal sources). These databases include 35 fault sections, 6 fault‐zone polygons, and 51 earthquake geology sites. To characterize fault activity rates, slip‐rate bins were assigned based on landscape expression and paleoseismic trench observations for faults without published slip‐rate sites. Additional fault sources were evaluated but not included in these databases due to a lack of published information about fault location, geometry, or recurrent Quaternary activity. The PRVI NSHM 2025 geologic input databases describe crustal faulting; the geometries and coupling of Puerto Rico subduction zone and Muertos Trough models are considered in a separate database. Updates to the fault sections, fault‐zone polygons, and earthquake geology databases can help inform the location and recurrence rate of damaging earthquakes in the PRVI NSHM implementation.

Puerto Rico, U.S. Virgin Islands

Petrography and mineralogy of selected pre-Middle Jurassic basement rocks beneath the Atlantic and Gulf Coastal Plains in Florida

Florida is covered by flat-lying sedimentary strata of the Atlantic and Gulf Coastal Plains. These strata have accumulated since Middle Jurassic time. The pre-Middle Jurassic, or basement, rocks that underlie the Coastal Plain in Florida are known only from drill cores and cuttings recovered from a relatively small number of boreholes. This data report presents petrographic observations and the results of X-ray diffraction analyses of basement rocks from 18 boreholes across Florida in support of the identification, discrimination, and correlation of units for a subcrop geologic map of pre-Middle Jurassic rocks composing Florida’s sub-Coastal Plain geology.

Florida

Importance of fish in the diet of Adélie penguins across multiple life stages

Over recent decades, the Adélie penguin ( Pygoscelis adeliae ) population has grown across most of its range, the exception being the northern coast of the western Antarctic Peninsula (WAP). In the Ross Sea, the very large Cape Crozier colony grew to reach ~9% of the global population. Demographic factors driving the Cape Crozier trend have yet to be identified. However, low chick fledging mass - a negative influence in the northern WAP where the diet is mostly less-energy-dense krill - is not showing an effect in the Cape Crozier colony. Previously, we hypothesized that Cape Crozier fledglings, and post-breeding adults, must be finding sufficient higher-quality prey once free of the prey-depleted colony foraging area, with subsequent higher survival. Here we explore penguin diet within and outside the colony foraging area using stable isotope analysis (SIA) of feathers: those grown by post-breeding adults outside the foraging area, prior to moult, compared to those of near-fledged chicks raised on meals obtained within the foraging area. Second, we explore whether a major difference occurs between breeding and post-breeding diet of adults from a small, nearby colony (Cape Royds) that exploits a smaller, little-depleted preyscape. Finally, we compare the results to SIA analyses published by others to explore whether the pre-moult diet of Ross Island adults, mostly foraging within the north-eastern Ross Sea, compares with that of adults nesting in the southern WAP (Bellingshausen Sea coast). At the latter, populations are not decreasing, with diet containing an appreciable contribution of fish. The results confirmed that fish contributed greatly to chick diets at both Ross Island colonies (δ 15 N 10.6–11.4). Once adults were released from central-place foraging, SIA levels (δ 15 N 9.7–12.9) were similar to those of the southern WAP. Foraging on energy-dense fish in coastal Antarctic waters could be one reason Adélie penguins are among the most abundant and therefore most ecologically successful penguin species.

Antarctic Science

Recent advances in characterizing the crustal stress field and future applications of stress data: Perspectives from North America

The stress field controls patterns of crustal deformation, including which faults are likeliest to cause earthquakes or transmit fluids. Since the 1950s, maps of maximum horizontal stress ( S Hmax ) orientations have advanced dramatically, and the style of faulting (relative principal stress magnitudes) has recently been mapped in some regions as well. This perspectives paper summarizes developments in characterizing stress orientations and (relative) magnitudes, including new seismic and borehole methods, as well as progress in identifying the causes of stress variations. Despite these advances, adding far more spatiotemporal detail would allow geoscientists to address many of today's key challenges regarding natural hazards, energy development, and geodynamics. In particular, it is critically important to characterize stress heterogeneity at multiple scales while also recognizing the coherent variability of the stress field. The second part of the paper considers how more detailed stress datasets could prove essential to addressing some of the grand questions in geoscience, including deciphering the poorly understood feedbacks between crustal dynamics and surface processes, improving earthquake and eruption forecasts, and determining the origins and shared properties of plate boundaries.

Geological Society, London, Special Publications

Generalized potentiometric maps of the Fort Union, Hell Creek, and Fox Hills aquifers within the Standing Rock Reservation

Generalized potentiometric surfaces of the Fort Union, Hell Creek, and Fox Hills aquifers were constructed to assess the groundwater resources of the Standing Rock Reservation. Additionally, this information can provide water managers with tools and data to effectively manage water resources in the future. Previous studies that mapped the geology and hydrogeology of the area at differing scales were used to confirm in which aquifer the study wells were completed. Water-level data from wells are provided by the U.S. Geological Survey Groundwater System Inventory database, the South Dakota Department of Agriculture and Natural Resources, and the North Dakota Department of Water Resources. Hydrographs were constructed for five selected observation wells to evaluate historical water-level fluctuations and trends. Hydrographs for the Hell Creek aquifer showed a flat trend with a rise in 2020. Hydrographs for the deeper Fox Hills aquifer showed that water levels fluctuated in response to climatic conditions and demonstrated an increasing trend in water-level elevations starting in 2010. Hydrographs were not constructed for any wells completed in the Fort Union Formation because none of the wells had continuous long-term measurements. Generalized potentiometric surfaces, constructed from interpolating water-level elevations, gave insight into groundwater flow directions. Groundwater in the Fort Union aquifer likely flows radially outward from the northwest part of the study area to the northeast and south-southeast parts. Groundwater in the Hell Creek aquifer generally flows from higher elevations in the northwest towards lower areas, where surface-water tributaries have incised into the aquifer. Groundwater in the Fox Hills aquifer likely flows from higher elevations in the west, southwest, and central parts of the study area towards the valleys of the Grand River and Missouri River. Most wells used for constructing potentiometric maps had only one recorded water-level measurement from drillers at the time of well construction. These measurements are often subject to error because the well is still recovering and because of spatial limitations of data availability. Also, because single water-level measurements were recorded at different points in time, additional uncertainty is introduced by fluctuating climatic conditions effect on water levels. Potentiometric map interpretation limitations are a result of areas with sparse data. Limitations also arise from potentiometric surfaces generalizing a complex and dynamic hydrogeologic system; however, the generalized potentiometric surface maps can be used to assist water managers and can help prioritize locations for future monitoring in areas with high uncertainty from sparse existing data.

North Dakota, South Dakota

Bedrock geologic map of the Eagle Lake quadrangle, Essex County, New York

The bedrock geology of the 7.5-minute Eagle Lake quadrangle, Essex County, New York, consists of deformed and metamorphosed Mesoproterozoic gneisses of the Adirondack Highlands unconformably overlain by weakly deformed lower Paleozoic sedimentary rocks of the Champlain Valley. The Mesoproterozoic rocks occur on the eastern edge of the Adirondack Highlands and represent an extension of the Grenville Province of Laurentia. Granulite facies Mesoproterozoic paragneiss, marble, and amphibolite hosted the emplacement of an anorthosite-mangerite-charnockite-granite (AMCG) suite, now exposed mostly as orthogneiss, at approximately 1.18–1.15 giga-annum (Ga, billion years before present). The earliest of four phases of deformation (D1) predated AMCG magmatism and is characterized by gneissosity, rarely preserved F1 isoclinal folds, and migmatite in the paragneiss host rocks. A sample of hornblende quartz syenite from the AMCG suite, collected from an abandoned railroad cut on Old Furnace Road, yielded a U-Pb zircon age of 1,149±10 million years before present. D2 deformation produced a composite penetrative gneissosity, migmatite, and isoclinal F2 folds. Towards the end of D2, felsic magmatism (including the regionally extensive Lyon Mountain Granite Gneiss, abbreviated “LMG”) spread by penetrative migration as semiconcordant alkali feldspar granite sheets subparallel to S2 into the previously deformed lithologies. The LMG crystallized at approximately 1.15 to 1.14 Ga and displays synkinematic F2 folds thus constraining the time of D2 deformation. Exhumation of the Marcy anorthosite began during D3 along a mylonitic extensional detachment, as a type of core complex. Protracted D3 produced F3 folds exhibited in regional domes and basins, such as the Hammondville antiform, reactivation of the S2 foliation, partial melting, metamorphism, metasomatism, iron ore remobilization, and intrusion of magnetite-bearing pegmatite both as layer-parallel sills and crosscutting dikes. D4 created NE- and NW-trending boudinage, local high-grade ductile shear zones, and crosscutting granitic pegmatite dikes. Kilometer (km)-scale lineaments readily observed in lidar data are Ediacaran mafic dikes and Phanerozoic brittle faults. Lower Paleozoic rocks are part of the Early Cambrian to Late Ordovician great American carbonate bank on the ancient margin of Laurentia. The Potsdam Sandstone preserves the Cambrian stratigraphy in outliers above the Great Unconformity. The Paleozoic rocks are weakly folded and block faulted. Parts of the quadrangle are covered by undifferentiated glacial deposits, but much of the quadrangle contains only a variably thick, veneer of unmapped glacial till over significant areas of exposed bedrock. The map also shows waste rock piles and locations of historical mining operations. This study was undertaken to improve our understanding of the bedrock geology in the Adirondack Highlands, establish a modern framework for 1:24,000-scale bedrock geologic mapping in the Adirondack Mountains, and provide a modern context for historical mines. This Scientific Investigations Map of the Eagle Lake 7.5-minute quadrangle consists of a map sheet, an explanatory pamphlet, and a geographic information system database that includes bedrock geologic units, faults, outcrops, and structural geologic information. The map sheet includes a bedrock geologic map, a correlation of map units, a description of map units, an explanation of map symbols, and two cross sections. The explanatory pamphlet includes a discussion of the geology.

New York

The influence of pre-existing structures on geothermal springs: Inferences from potential field mapping in Surprise Valley, CA and other sites In the northwestern Great Basin

Surprise Valley, located in the northwestern Great Basin, is an asymmetric extensional basin that marks a major tectonic transition between the relatively un-extended volcanic Modoc Plateau to the west, and the Basin and Range to the east that has undergone 10-15% extension. In addition, it sits just north of the Walker Lane which accommodates up to 20% of dextral slip associated with Pacific-North American plate interactions. Thermal springs issue from eight areas within Surprise Valley. Most of these occur within the basin and are not situated on the main basin forming range-front faults. As a result, efforts to resolve the structural setting of the valley’s hydrothermal system have relied on geophysics to characterize basin structure and geology. Extensive efforts to map the basin with ground and airborne magnetics have revealed a >35 km-long linear, intra-basin magnetic high, interpreted as a buried dike swarm. Geothermal springs on the eastern side of the valley, including Seifert hot springs, Leonards hot springs, and Surprise Valley hot springs (SVHS), are all situated along the magnetic high and occur at local breaks and bends in the anomaly, suggesting that fracture permeability is enhanced along the feature and particularly at these discontinuities. Recent studies, including drilling over the anomaly near SVHS that likely intersected dike material, as well as subsequent mapping and sampling of dikes outcropping along the anomaly on the playa surface south of SVHS, confirm (as previously inferred) that mafic intrusives are the principal source of the anomaly. Similar interpretations made in two other valleys (in southern Oregon and northwestern Nevada), where inferred intra-basin dikes appear to be spatially correlated with hot springs or prospective geothermal resource areas, suggest that the impact of pre-existing basement structure on hydrothermal activity may pertain more generally to other hydrothermal settings throughout the Great Basin. If so, efforts to map basement may enhance understanding structural controls on some geothermal systems. Furthermore, similarities across these disparate sites suggest that magmatism may play a much larger role in accommodating extension and influencing basin evolution across the western Great Basin than previously recognized.

Conference Paper

Environmental setting and water-quality issues in the lower Tennessee River basin

The goals of the National Water-Quality Assessment Program are to describe current water-quality conditions for a large part of the Nation's water resources, identify water-quality changes over time, and identify the primary natural and human factors that affect water quality. The lower Tennessee River Basin is one of 59 river basins selected for study. The water-quality assessment of the lower Tennessee River Basin study unit began in 1997. The lower Tennessee River Basin study unit encompasses an area of about 19,500 square miles and extends from Chattanooga, Tennessee, to Paducah, Kentucky. The study unit had a population of about 1.5 million people in 1995. The study unit was subdivided into subunits with relatively homogeneous geology and physiography. Subdivision of the study unit creates a framework to assess the effects of natural and cultural settings on water quality. Nine subunits were delineated in the study unit; their boundaries generally coincide with level III and level IV ecoregion boundaries. The nine subunits are the Coastal Plain, Transition, Western Highland Rim, Outer Nashville Basin, Inner Nashville Basin, Eastern Highland Rim, Plateau Escarpment and Valleys, Cumberland Plateau, and Valley and Ridge.The lower Tennessee River Basin consists of predominantly forest (51 percent) and agricultural land (40 percent). Activities related to agricultural land use, therefore, are the primary cultural factors likely to have a widespread effect on surface- and ground-water quality in the study unit. Inputs of total nitrogen and phosphorus from agricultural activities in 1992 were about 161,000 and 37,900 tons, respectively. About 3.7 million pounds (active ingredient) of pesticides was applied to crops in the lower Tennessee River Basin in 1992. State water-quality agencies identified nutrient enrichment and pathogens as water-quality issues affecting both surface and ground water in the lower Tennessee River Basin. Water-quality data collected by State and Federal agencies between 1980 and 1996 were summarized to characterize surface- and ground-water quality of the subunits with respect to these issues. Median concentrations of nitrogen species generally were less than 1 milligram per liter in surface and ground water in all subunits, and were highest throughout the subunits that had the largest percentages of agricultural land use. Median phosphorus concentrations also were less than 1 milligram per liter in all subunits. Phosphatic limestones present in two subunits had a larger effect on phosphorus concentrations in surface and ground water than did the amount of agricultural land use in these subunits. Median counts of fecal coliform were higher in surface water than in ground water in all subunits. The highest median counts in surface water were in the Valley and Ridge (7,500 colonies per 100 milliliters) and the Outer Nashville Basin subunits (5,000 colonies per 100 milliliters). Highest median counts in ground water were in the Inner and Outer Nashville Basin subunit. Natural setting likely has an important effect with respect to fecal contamination of surface and ground water in the lower Tennessee River Basin.

Alabama, Georgia, Kentucky, Mississippi, Tennessee

Geophysical modeling of a possible blind geothermal system near Battle Mountain, NV

The northeastern portion of the Reese River basin in north-central Nevada is the focus of detailed geophysical and geological studies as part of the INGENIOUS project, which aims to identify new, commercially viable hidden geothermal systems in the Great Basin region of the western U.S. This location, herein referred to as Argenta Rise, occupies a broad (~15km wide) left-step between major range-front fault systems along the northwestern edge of the Shoshone Range and Argenta Rim, with numerous ENE-striking intra-basin faults presumably accommodating sinistral-normal oblique slip across the step-over. Four discrete regions have been identified within the study area that have favorable structural settings for hosting a blind hydrothermal system. However, with no definitive or extensive surface manifestations of an active hydrothermal system (e.g., geysers, steam vents, sinter, etc.), detailed geophysical studies are necessary to resolve subsurface geology and structure, and identify zones of enhanced structural complexity that may promote hydrothermal fluid flow. Hence, we collected high-resolution gravity, MT, and rock property data (density, magnetic susceptibility), and analyzed the recently acquired GeoDAWN aeromagnetic data to characterize potential geothermal resources in this region. Using the new geophysical datasets, we jointly modeled gravity and magnetic data along a series of intersecting 2D profiles that integrated information from recent, local-scale fault mapping. Rock property measurements performed on outcrops and hand samples throughout the study area constrained the models. The MT data were used to construct a 3D resistivity model that highlights the location of inferred alteration and fluids in the subsurface. Combined MT and potential field results reveal which structures may be most important for controlling hydrothermal fluid migration, as well as which geologic units may host hydrothermal fluids. Our gravity derived depth to basement surface coincides well with the base of shallow conductive anomalies, suggesting hydrothermal fluids may be confined to basin fill sediments and volcanics. This work supports our development of 3D geophysical and geologic models that are focused along the western flank of the northern Shoshone Range and aids the process of selecting sites for temperature gradient drilling.

Nevada